Complete and Balanced Chemical Equation

Copper (II)
1. CuSO4 + 2KI --> CuI2 + K2SO4
2CuI2 ---> 2CuI

+ 2I2

Theoretical Result

(Soine & Wilson, 1961, p. 328)

a. Starch + I2 --> Starch-iodine complex (Gopalan, 2009, p.

118)
b. Chloroform + I2 --> violet chloroform (Berry, 1948, p. 83)
2. CuSO4 + Fe --> FeSO4 + Cu

(Svehla, 1996, p. 86)

3. CuSO4 + 2NaOH ---> Cu(OH)2 + Na2SO4 (Svehla, 1996, p. 85)

Cu(OH)2 + excess NaOH --> no reaction (Svehla, 1996, p. 85)
4. 2CuSO4 + 2NH3 + 2H2O---> Cu(OH)2CuSO4 + 2NH4SO4

White precipitate forms in an intensely brown solution

(Svehla, 1996, p. 85)
Formation of a blue colored solution (Soine & Wilson,
1961, p.104)
Formation of violet coloration (Soine & Wilson, 1961, p.
104)
Formation of red deposits (Svehla, 1996, p. 86)
Formation of blue precipitates (Svehla, 1996, p. 85)
Precipitates do not dissolve (Svehla, 1996, p. 85)
Formation of blue precipitates (Svehla, 1996, p. 84)

(Svehla, 1996, p. 84)

Cu(OH)2 + 4 NH3 --> [Cu(NH3)4](OH)2 (Soine & Wilson, 1961,
p. 329)
5. CuSO4 + Na2CO3 CuCO3

+ Na2SO4

(Leong & Sai, 2007, p. 176)

6. CuSO4 + 4 HCl H2(CuCl4) (Ebbing & Gammon,2007, p. 582)
7. 2 CuSO4 + K4[Fe(CN)6] --> Cu2[Fe(CN)6]

+ K2SO4 (Svehla,

Precipitate dissolves; formation of blue solution (Svehla,

1996, p. 84)
Formation of copper (II) carbonate (Leong & Sai, 2007,
p. 176)
Cupric carbonate is a green to blue colored solid (ONeil,
2006, p. 442)
Formation of a green solution (Ebbing & Gammon, 2007,
p. 582)
Formation of Brown precipitate (Svehla, 1996, p. 187)

1996, p. 187)
Cu2[Fe(CN)6]

+ HCl --> no reaction (Svehla, 1996, p. 187)

Precipitates do not dissolve (Svehla, 1996, p. 187)

Manganese (II)
1. a. MnCl2 + 2NaOH ---> Mn(OH)2

+ NaCl (Svehla, 1996, p.

Formation of white precipitate (Svehla, 1996, p. 136)

136)
b. MnCl2 + (NH4)2S ---> MnS
MnS

+ NH4Cl (Svehla, 1996, p. 137)

+ 2CH3COOH --> Mn(CH3COO)2 + H2S

(Svehla,

Formation of pink precipitate (Svehla, 1996, p. 137)

Precipitate dissolves (Svehla, 1996, p. 137)

1996, p. 137)
c. Na2CO3 + MnCl2 --> 2NaCl + MnCO3
1961, p. 601)

(Soine & Wilson,

Formation of white precipitate (Soine & Wilson, 1961, p.

601)

References:
Berry, A.J. (1948). Qualitative inorganic analysis [Google Books], (p. 83). Retrieved from https://books.google.com.ph/books?
id=idjrCgAAQBAJ&printsec=frontcover&source=gbs_ge_summary_r&cad=0#v=onepage&q&f=false
Doc Browns Chemistry (n.d.). Part 10. Transition metals 3dblock: 10.7 Manganese Chemistry. In Doc Browns Chemistry Clinic
Website. Retrieved from http://www.docbrown.info/page07/transition05Mn.htm
Ebbing, D. & Gammon, S.D. (2007). General Chemistry (11th edition) [Google Books], (p. 587). Retrieved from
https://books.google.com.ph/books?
id=BnccCgAAQBAJ&printsec=frontcover&dq=isbn:1305887298&hl=en&sa=X&redir_esc=y#v=onepage&q&f=false
Gopalan, R. (2009). Inorganic Chemistry for undergraduates [Google Books], (p. 118). Retrieved from
https://books.google.com.ph/books?id=Fs4zQhNTz8C&printsec=frontcover&source=gbs_ge_summary_r&cad=0#v=onepage&q&f=false
Leong, O.H. & Sai, C.L. (2007). Chemistry expression: An inquiry approach [Google Books], (p. 176). Retrieved from
https://books.google.com.ph/books?id=jd-BRnfzIoC&printsec=frontcover&dq=isbn:9812711627&hl=en&sa=X&redir_esc=y#v=onepage&q&f=false
ONeil, M.J. (Ed.). (2006). The Merck index: An encyclopedia of chemicals, drugs and biologicals (14th Edition). Whitehouse
Station, NJ: Merck Research Laboratories, p 442.
Soine, T.O. & Wilson, C.O. (1961). Rogers inorganic Pharmaceutical Chemistry (7th edition). Philadelphia: Lea & Febiger, pp. 104,
328-329, 601
Svehla, G. (1996). Vogels qualitative inorganic analysis (7th edition). Essex, England: Addison Wesley Longman Ltd, pp. 84-86,
136-137, 187