Constantes de Antoine

presin en KiloPa y T en C

Sistema:
A1
A2
A3

Acetonitrilo(A)
14.2724
2945.47
224

Nitrometano(B)
14.2043
2972.64
209

Constantes de Antoine
presin en KiloPa y T en C

Sistema:
A1
A2
A3

Benceno(A)
13.8858
2788.51
220.79

Etilbenceno(B)
14.0045
3279.47
213.2

Constantes de Antoine
presin en KiloPa y T en C

Sistema: 1-Clorobutano(A) Clorobenceno(B)

A1
13.96
13.9926
A2
2826.26
3295.12
A3
224.1
217.55

Constantes de Antoine
presin en KiloPa y T en C

Sistema:
A1
A2
A3

Acetona(A)
14.5463
2940.46
237.22

Acetonitrilo(B)
14.2724
2945.47
224

Constantes de Antoine
presin en KiloPa y T en C

Sistema:
A1
A2
A3

n-Pentano(A)
13.8183
2477.07
233.21

n-Heptano(B)
13.8587
2911.32
216.64

Constantes de Antoine
presin en KiloPa y T en C

Sistema:
A1
A2
A3

Benceno(A)
13.8858
2788.51
220.79

Tolueno(B)
13.9987
3096.52
219.48

Constantes de Antoine
presin en KiloPa y T en C

Sistema:
A1
A2
A3

Constantes de Antoine
presin en KiloPa y T en C

Sistema: 1-Clorobutano(A)
A1
13.96
A2
2826.26
A3
224.1

Benceno(B)
13.8858
2788.51
220.79

Constantes de Antoine
presin en KiloPa y T en C

Sistema:
A1
A2
A3

n-Pentano(A)
13.8183
2477.07
233.21

n-Hexano(B)
13.8216
2697.55
224.37

Sistema:
A1
A2
A3

n-Hexano(A)

Trietilamina(B)

lnP sat A1

A2
T A3

Benceno(A)
13.8858
2788.51
220.79

Etilbenceno(B)
14.0045
3279.47
213.2

Constantes de Antoine
presin en KiloPa y T en C

lnP sat A1

xA
yA

Sistema: Etanol(A)
A1 16.8958
A2 3795.17
A3 230.918

Agua(B)
16.2886
3816.44
227.02

A2
T A3

P PvB
PvA PvB
PvA
xA
P

DIAGRAMA T-x,y a Presin constante

Ingrese la Presin, KiloPascal, =

i
0
0.01
1bar=

100 Kpa

0.02

1atm=
1atm=
1atm=
1atm=

760 mm Hg
14,696 psi
1,01325 bar
101,325 Kpa

0.03
0.04
0.05
0.06
0.07
0.08
0.09
0.1
0.11
0.12
0.13
0.14
0.15
0.16
0.17
0.18
0.19
0.2
0.21
0.22
0.23
0.24
0.25
0.26
0.27
0.28
0.29
0.3
0.31
0.32
0.33
0.34
0.35
0.36
0.37
0.38
0.39
0.4
0.41
0.42
0.43
0.44
0.45

53.82

0.5045

0.46
0.47
0.48
0.49
0.5
0.51
0.52
0.53
0.54
0.55
0.56
0.57
0.58
0.59
0.6
0.61
0.62
0.63
0.64
0.65
0.66
0.67
0.68
0.69
0.7
0.71
0.72
0.73
0.74
0.75
0.76
0.77
0.78
0.79
0.8
0.81
0.82
0.83
0.84
0.85
0.86
0.87
0.88
0.89
0.9
0.91
0.92
0.93
0.94
0.95
0.96
0.97
0.98
0.99

DIAGRAMA T-x,y a Presin constante

ngrese la Presin, KiloPascal, =

TsA=
TsB=

101.325
78.1986976 C
100.002514 puro

1 atm

T C
PsA
PsB
xA
yA
diagonal
78.1986976
101.325 44.0201646
1
1
1
78.4167357 102.205663 44.414849 0.98476119 0.99332021 0.98476119
78.6347739 103.092723 44.8125014 0.96966855 0.98658546 0.96966855
37.5
79.0708502
79.2888884
79.5069266
79.7249647
79.9430029
80.1610411
80.3790792
80.5971174
80.8151556
81.0331937
81.2512319
81.4692701
81.6873082
81.9053464
82.1233846
82.3414227
82.5594609
82.7774991
82.9955372
83.2135754
83.4316136
83.6496517
83.8676899
84.0857281
84.3037662
84.5218044
84.7398426
84.9578807
85.1759189
85.3939571
85.6119952
85.8300334
86.0480716
86.2661097
86.4841479
86.7021861
86.9202242
87.1382624
87.3563006
87.5743387
87.7923769
88.0104151

15.7489009
104.886183
105.792655
106.705671
107.625269
108.551485
109.484357
110.423922
111.370218
112.323283
113.283154
114.24987
115.223468
116.203988
117.191468
118.185945
119.18746
120.196051
121.211757
122.234617
123.26467
124.301957
125.346516
126.398388
127.457613
128.52423
129.59828
130.679803
131.768839
132.865431
133.969617
135.08144
136.20094
137.328158
138.463137
139.605917
140.75654
141.915049
143.081485
144.25589
145.438307
146.628778
147.827345

6.42891806
45.616781
46.0234437
46.4331454
46.845904
47.2617376
47.6806642
48.1027019
48.527869
48.9561838
49.3876645
49.8223298
50.260198
50.7012877
51.1456177
51.5932066
52.0440732
52.4982365
52.9557154
53.4165289
53.8806961
54.3482363
54.8191686
55.2935125
55.7712872
56.2525124
56.7372075
57.2253921
57.7170861
58.2123092
58.7110812
59.2134221
59.7193519
60.2288907
60.7420587
61.2588761
61.7793631
62.3035404
62.8314282
63.3630471
63.8984178
64.437561
64.9804975

10.1820018
0.93991533
0.92525157
0.91072763
0.89634198
0.88209309
0.86797946
0.85399962
0.84015209
0.82643544
0.81284823
0.79938905
0.78605652
0.77284924
0.75976586
0.74680505
0.73396546
0.72124579
0.70864474
0.69616103
0.68379341
0.6715406
0.65940139
0.64737456
0.63545889
0.6236532
0.61195631
0.60036705
0.58888429
0.57750687
0.56623369
0.55506364
0.54399561
0.53302853
0.52216133
0.51139295
0.50072234
0.49014848
0.47967034
0.46928692
0.45899722
0.44880026
0.43869506

1.58258414
0.97294972
0.96604806
0.95909009
0.95207546
0.94500384
0.93787489
0.93068825
0.92344359
0.91614055
0.90877879
0.90135796
0.8938777
0.88633767
0.8787375
0.87107684
0.86335533
0.85557262
0.84772834
0.83982213
0.83185363
0.82382246
0.81572828
0.8075707
0.79934935
0.79106387
0.78271389
0.77429902
0.76581889
0.75727313
0.74866135
0.73998318
0.73123823
0.72242612
0.71354646
0.70459887
0.69558297
0.68649835
0.67734463
0.66812141
0.65882831
0.64946492
0.64003085

10.1820018
0.93991533
0.92525157
0.91072763
0.89634198
0.88209309
0.86797946
0.85399962
0.84015209
0.82643544
0.81284823
0.79938905
0.78605652
0.77284924
0.75976586
0.74680505
0.73396546
0.72124579
0.70864474
0.69616103
0.68379341
0.6715406
0.65940139
0.64737456
0.63545889
0.6236532
0.61195631
0.60036705
0.58888429
0.57750687
0.56623369
0.55506364
0.54399561
0.53302853
0.52216133
0.51139295
0.50072234
0.49014848
0.47967034
0.46928692
0.45899722
0.44880026
0.43869506

88.2284532
88.4464914
88.6645296
88.8825677
89.1006059
89.3186441
89.5366822
89.7547204
89.9727586
90.1907967
90.4088349
90.6268731
90.8449112
91.0629494
91.2809876
91.4990257
91.7170639
91.9351021
92.1531402
92.3711784
92.5892166
92.8072547
93.0252929
93.2433311
93.4613692
93.6794074
93.8974456
94.1154837
94.3335219
94.5515601
94.7695982
94.9876364
95.2056746
95.4237128
95.6417509
95.8597891
96.0778273
96.2958654
96.5139036
96.7319418
96.9499799
97.1680181
97.3860563
97.6040944
97.8221326
98.0401708
98.2582089
98.4762471
98.6942853
98.9123234
99.1303616
99.3483998
99.5664379
99.7844761

149.034052
150.248942
151.472057
152.70344
153.943136
155.191187
156.447637
157.71253
158.985911
160.267822
161.558309
162.857415
164.165186
165.481666
166.8069
168.140933
169.48381
170.835576
172.196277
173.565959
174.944667
176.332448
177.729347
179.135411
180.550685
181.975218
183.409054
184.852242
186.304828
187.766859
189.238383
190.719447
192.210099
193.710387
195.220358
196.74006
198.269543
199.808854
201.358041
202.917154
204.486242
206.065353
207.654536
209.253842
210.863318
212.483016
214.112985
215.753275
217.403936
219.065018
220.736571
222.418647
224.111296
225.814569

65.5272481
66.0778338
66.6322755
67.1905944
67.7528116
68.3189485
68.8890262
69.4630663
70.0410901
70.6231194
71.2091756
71.7992805
72.393456
72.9917239
73.5941061
74.2006247
74.8113017
75.4261595
76.0452202
76.6685062
77.2960399
77.9278439
78.5639407
79.204353
79.8491035
80.4982151
81.1517106
81.8096131
82.4719456
83.1387312
83.8099933
84.485755
85.1660399
85.8508712
86.5402727
87.2342679
87.9328805
88.6361344
89.3440533
90.0566612
90.7739823
91.4960405
92.2228601
92.9544653
93.6908806
94.4321303
95.1782389
95.9292311
96.6851316
97.4459651
98.2117564
98.9825305
99.7583124
100.539127

0.42868066
0.41875612
0.40892049
0.39917284
0.38951227
0.37993785
0.3704487
0.36104393
0.35172267
0.34248405
0.33332721
0.32425131
0.31525551
0.306339
0.29750094
0.28874054
0.280057
0.27144952
0.26291734
0.25445967
0.24607576
0.23776485
0.2295262
0.22135908
0.21326275
0.2052365
0.19727962
0.18939139
0.18157114
0.17381816
0.16613179
0.15851134
0.15095616
0.14346559
0.13603897
0.12867568
0.12137506
0.11413651
0.10695938
0.09984308
0.09278699
0.08579051
0.07885305
0.07197403
0.06515286
0.05838897
0.05168179
0.04503077
0.03843534
0.03189496
0.02540909
0.01897718
0.01259871
0.00627316

0.63052569
0.62094906
0.61130054
0.60157973
0.59178623
0.58191962
0.57197951
0.56196548
0.55187712
0.54171401
0.53147575
0.52116191
0.51077207
0.50030582
0.48976274
0.4791424
0.46844438
0.45766825
0.44681359
0.43587996
0.42486693
0.41377408
0.40260096
0.39134715
0.3800122
0.36859568
0.35709714
0.34551615
0.33385225
0.32210501
0.31027398
0.2983587
0.28635873
0.27427362
0.26210291
0.24984615
0.23750287
0.22507263
0.21255496
0.1999494
0.18725548
0.17447275
0.16160073
0.14863895
0.13558696
0.12244426
0.10921039
0.09588488
0.08246725
0.06895702
0.05535371
0.04165684
0.02786592
0.01398047

0.42868066
0.41875612
0.40892049
0.39917284
0.38951227
0.37993785
0.3704487
0.36104393
0.35172267
0.34248405
0.33332721
0.32425131
0.31525551
0.306339
0.29750094
0.28874054
0.280057
0.27144952
0.26291734
0.25445967
0.24607576
0.23776485
0.2295262
0.22135908
0.21326275
0.2052365
0.19727962
0.18939139
0.18157114
0.17381816
0.16613179
0.15851134
0.15095616
0.14346559
0.13603897
0.12867568
0.12137506
0.11413651
0.10695938
0.09984308
0.09278699
0.08579051
0.07885305
0.07197403
0.06515286
0.05838897
0.05168179
0.04503077
0.03843534
0.03189496
0.02540909
0.01897718
0.01259871
0.00627316

100.002514 227.528516

101.325

0.00

0.00

DIAGRAMA P-x,y a Temperatura constante

Ingrese laTemperatura, C

=
PsA=
PsB=

80
108.794702 Kpascal
47.3709494

puro
puro

P, Kpa
PsA
PsB
xA
0 47.3709494 108.794702 47.3709494
0.01 47.9851869 108.794702 47.3709494

0
0
0.01 0.02267256

0.02 48.5994245 108.794702 47.3709494

0.02 0.04477201

0.03
0.04
0.05
0.06
0.07
0.08
0.09
0.1
0.11
0.12
0.13
0.14
0.15
0.16
0.17
0.18
0.19
0.2
0.21
0.22
0.23
0.24
0.25
0.26
0.27
0.28
0.29
0.3
0.31
0.32
0.33
0.34
0.35
0.36
0.37
0.38
0.39
0.4
0.41
0.42
0.43
0.44
0.45

0.03
0.04
0.05
0.06
0.07
0.08
0.09
0.1
0.11
0.12
0.13
0.14
0.15
0.16
0.17
0.18
0.19
0.2
0.21
0.22
0.23
0.24
0.25
0.26
0.27
0.28
0.29
0.3
0.31
0.32
0.33
0.34
0.35
0.36
0.37
0.38
0.39
0.4
0.41
0.42
0.43
0.44
0.45

49.213662
49.8278995
50.442137
51.0563746
51.6706121
52.2848496
52.8990871
53.5133247
54.1275622
54.7417997
55.3560372
55.9702748
56.5845123
57.1987498
57.8129873
58.4272249
59.0414624
59.6556999
60.2699374
60.884175
61.4984125
62.11265
62.7268875
63.3411251
63.9553626
64.5696001
65.1838376
65.7980752
66.4123127
67.0265502
67.6407877
68.2550253
68.8692628
69.4835003
70.0977378
70.7119754
71.3262129
71.9404504
72.5546879
73.1689255
73.783163
74.3974005
75.011638

108.794702
108.794702
108.794702
108.794702
108.794702
108.794702
108.794702
108.794702
108.794702
108.794702
108.794702
108.794702
108.794702
108.794702
108.794702
108.794702
108.794702
108.794702
108.794702
108.794702
108.794702
108.794702
108.794702
108.794702
108.794702
108.794702
108.794702
108.794702
108.794702
108.794702
108.794702
108.794702
108.794702
108.794702
108.794702
108.794702
108.794702
108.794702
108.794702
108.794702
108.794702
108.794702
108.794702

47.3709494
47.3709494
47.3709494
47.3709494
47.3709494
47.3709494
47.3709494
47.3709494
47.3709494
47.3709494
47.3709494
47.3709494
47.3709494
47.3709494
47.3709494
47.3709494
47.3709494
47.3709494
47.3709494
47.3709494
47.3709494
47.3709494
47.3709494
47.3709494
47.3709494
47.3709494
47.3709494
47.3709494
47.3709494
47.3709494
47.3709494
47.3709494
47.3709494
47.3709494
47.3709494
47.3709494
47.3709494
47.3709494
47.3709494
47.3709494
47.3709494
47.3709494
47.3709494

yA

0.06631982
0.08733637
0.10784109
0.12785244
0.14738802
0.16646459
0.18509815
0.20330395
0.22109655
0.23848986
0.25549718
0.2721312
0.2884041
0.3043275
0.31991253
0.33516989
0.35010978
0.36474202
0.37907601
0.39312078
0.406885
0.42037698
0.43360474
0.44657594
0.45929799
0.471778
0.4840228
0.49603899
0.5078329
0.51941066
0.53077814
0.54194103
0.5529048
0.56367472
0.5742559
0.58465326
0.59487154
0.60491532
0.61478905
0.624497
0.63404332
0.64343201
0.65266693

0.46
0.47
0.48
0.49
0.5
0.51
0.52
0.53
0.54
0.55
0.56
0.57
0.58
0.59
0.6
0.61
0.62
0.63
0.64
0.65
0.66
0.67
0.68
0.69
0.7
0.71
0.72
0.73
0.74
0.75
0.76
0.77
0.78
0.79
0.8
0.81
0.82
0.83
0.84
0.85
0.86
0.87
0.88
0.89
0.9
0.91
0.92
0.93
0.94
0.95
0.96
0.97
0.98
0.99

75.6258756
76.2401131
76.8543506
77.4685881
78.0828257
78.6970632
79.3113007
79.9255382
80.5397758
81.1540133
81.7682508
82.3824883
82.9967259
83.6109634
84.2252009
84.8394384
85.453676
86.0679135
86.682151
87.2963885
87.9106261
88.5248636
89.1391011
89.7533386
90.3675762
90.9818137
91.5960512
92.2102887
92.8245263
93.4387638
94.0530013
94.6672388
95.2814764
95.8957139
96.5099514
97.1241889
97.7384265
98.352664
98.9669015
99.5811391
100.195377
100.809614
101.423852
102.038089
102.652327
103.266564
103.880802
104.495039
105.109277
105.723514
106.337752
106.951989
107.566227
108.180464

108.794702
108.794702
108.794702
108.794702
108.794702
108.794702
108.794702
108.794702
108.794702
108.794702
108.794702
108.794702
108.794702
108.794702
108.794702
108.794702
108.794702
108.794702
108.794702
108.794702
108.794702
108.794702
108.794702
108.794702
108.794702
108.794702
108.794702
108.794702
108.794702
108.794702
108.794702
108.794702
108.794702
108.794702
108.794702
108.794702
108.794702
108.794702
108.794702
108.794702
108.794702
108.794702
108.794702
108.794702
108.794702
108.794702
108.794702
108.794702
108.794702
108.794702
108.794702
108.794702
108.794702
108.794702

47.3709494
47.3709494
47.3709494
47.3709494
47.3709494
47.3709494
47.3709494
47.3709494
47.3709494
47.3709494
47.3709494
47.3709494
47.3709494
47.3709494
47.3709494
47.3709494
47.3709494
47.3709494
47.3709494
47.3709494
47.3709494
47.3709494
47.3709494
47.3709494
47.3709494
47.3709494
47.3709494
47.3709494
47.3709494
47.3709494
47.3709494
47.3709494
47.3709494
47.3709494
47.3709494
47.3709494
47.3709494
47.3709494
47.3709494
47.3709494
47.3709494
47.3709494
47.3709494
47.3709494
47.3709494
47.3709494
47.3709494
47.3709494
47.3709494
47.3709494
47.3709494
47.3709494
47.3709494
47.3709494

0.46
0.47
0.48
0.49
0.5
0.51
0.52
0.53
0.54
0.55
0.56
0.57
0.58
0.59
0.6
0.61
0.62
0.63
0.64
0.65
0.66
0.67
0.68
0.69
0.7
0.71
0.72
0.73
0.74
0.75
0.76
0.77
0.78
0.79
0.8
0.81
0.82
0.83
0.84
0.85
0.86
0.87
0.88
0.89
0.9
0.91
0.92
0.93
0.94
0.95
0.96
0.97
0.98
0.99

0.66175185
0.67069037
0.67948602
0.68814219
0.69666217
0.70504916
0.71330623
0.72143639
0.72944255
0.7373275
0.745094
0.75274468
0.76028213
0.76770882
0.77502719
0.7822396
0.78934832
0.79635557
0.80326351
0.81007425
0.81678981
0.82341217
0.82994327
0.83638498
0.84273912
0.84900746
0.85519173
0.86129361
0.86731474
0.8732567
0.87912105
0.8849093
0.89062293
0.89626336
0.90183199
0.90733019
0.91275928
0.91812056
0.92341529
0.9286447
0.93380999
0.93891234
0.94395289
0.94893275
0.95385302
0.95871475
0.963519
0.96826676
0.97295903
0.97759678
0.98218095
0.98671246
0.99119223
0.99562112

1 108.794702 108.794702 47.3709494

Diagrama a P cte
120.00
V

110.00
100.00

90.00

80.00

70.00
60.00
50.00
L

40.00
30.00
20.00
0

0.1

0.2

0.3

0.4 x, y0.5

0.6

0.7

0.8

Diagrama a T cte

120

100
80

P 60
L

40
20
0
0

1
0.9
0.8
0.7
0.6
y

0.5
0.4

0.1

0.2

0.3

0.4

0.5
x,y

0.6

0.7

Diagrama composicin

0.8

0.9

0.9

Diagrama composicin

0.9
0.8
0.7
0.6
y

0.5
0.4
0.3
0.2
0.1
0
0

0.1

0.2

0.3

0.4

0.5
x

0.6

0.7

0.8

0.9

x ,y

0.7

0.9

0.8

0.9

0.9

Condiciones del separador ADIABATICO

P, psia =
1
T, F =
82.19

Metanol(A)
Agua(B)

Pv
x
gamma
K
1.36206584 0.09619074 1.8276233 2.48934327
0.54659643 0.90380926 1.01117805 0.55270632

Fracc V/F

zF*K
zF/K
0.99573731 0.16068495
0.33162379 1.08556748
1.3273611 1.24625243

1 Nuevo V/F

0.54069282

g
g^2/zF
x
y
0.23931505 0.14317923 0.16068495
-0.48556748 0.39295962 1.08556748
G1 -0.24625243 -0.53613886 1.24625243

Hv
0.4 766.371356
0.6 402.376451
1 547.974413
Entalpia mezcla

Lambda
Hl
18433.282 -17666.9107
18807.9624 -18405.5859
-22819.3122
ntalpia mezcla
Entalpia mezcla
G2
Q

1.03176065
3560244.4

Sistema:
A1
A2
A3

Constantes de Antoine
presin en mm Hg y T en C

Etanol(A)
8.1122
1592.864
226.184

alfa=
beta=

1.54
0.97

lnP sat A1

1bar=
1atm=
1atm=
1atm=
1atm=

ln

Agua(B)
7.96681
1668.21
228

A2
T A3

100 Kpa
760 mm Hg
14,696 psi
1,01325 bar
101,325 Kpa

x
A

x
B

L
ln

2
B

xB

1
x A

P B PvB
xA
A PvA B PvB

A PvA
yA
xA
P

xA

A PvA B PvB
A PvA
yA
xA
P

Ingrese la Presin,mm Hg =
TsA=
TsB=

T C

760
78.2981919
100.000625

PsA
PsB
xAsupuesto
99.9 1688.0013 757.2736020516 0.00038282
95 1421.8363 633.9764970476 0.023657785
94.5 1396.74505 622.3945970869 0.02669292
94 1372.02029 610.9892968949 0.02988186
93.2 1333.21271 593.1029031065 0.03535621
91.3 1244.66558 552.3634967319 0.05051675
89 1144.03925 506.1950412446 0.07459234
88.4 1118.92761 494.6960526653 0.08233735
87.7 1090.20956 481.5571336028 0.09237801
86.1 1026.85614 452.6168584085 0.12082742
84.3 959.265575 421.8123761431 0.16743698
84.2 955.621658 420.1538373542 0.17071332
83.1 916.29182 402.2674736651 0.21387525
81.6 864.836935 378.9088998977 0.30565151
81 844.939789 369.8896130097 0.35852009
80.6 831.887918 363.9774013299 0.39977849
80.1 815.809583 356.6988617407 0.45786164
79.8 806.287445 352.3906891239 0.49765914
79.3 790.623042 345.3075148758 0.57023725
78.9 778.274884 339.7274392838 0.637530322
78.5 766.087917 334.2233236324 0.71570503
78.3 760.054366 331.4994939239 0.77155508
78.25 758.552186 330.8214596203 0.78887579
78.241 758.282057 330.699537328 0.79265886
78.23 757.952008 330.5505724862 0.79606313
78.19 756.752839 330.0093575222
0.8139146
78.15 755.555254 329.4688876193 0.83555313

PsA=
PsB=

84.2
955.6216577
420.1538374

P mm Hg
PsA
PsB
DIAGRAMA P-x,y
420 955.6216577121 420.1538374
430 955.6216577121 420.1538374
Ingrese la Temp
455 955.6216577121 420.1538374
480 955.6216577121 420.1538374
505 955.6216577121 420.1538374
530 955.6216577121 420.1538374
555 955.6216577121 420.1538374
575 955.6216577121 420.1538374
605 955.6216577121 420.1538374

630 955.6216577121
655 955.6216577121
680 955.6216577121
705 955.6216577121
730 955.6216577121
755 955.6216577121
780 955.6216577121
805 955.6216577121
830 955.6216577121
855 955.6216577121
880 955.6216577121
905 955.6216577121
930 955.6216577121
955.62 955.6216577121
956.62 955.6216577121

420.1538374
420.1538374
420.1538374
420.1538374
420.1538374
420.1538374
420.1538374
420.1538374
420.1538374
420.1538374
420.1538374
420.1538374
420.1538374
420.1538374
420.1538374

1 Xa
95.5
89
86.7
85.3
84.1
82.7
82.3
81.5
80.7
79.8
79.7
79.3
78.74
78.41
78.15

0.019
0.0721
0.0966
0.1238
0.1661
0.2337
0.2608
0.3273
0.3965
0.5079
0.5198
0.5732
0.6763
0.7472
0.8943

Chart Title
110

105

A
B
4.6558711649
4.1704144796
4.1130756872
4.0541852124
3.9562138356
3.7041086158
3.3547913769
3.2540578461
3.1309650146
2.8228310746
2.4224804236
2.3983299179
2.1192440899
1.705024413
1.5408666101
1.4387894613
1.324518183
1.2619361048
1.1730095232
1.1130187143
1.0636204329
1.0387800681
1.0325648676
1.0312937061
1.0301756192
1.0247025491
1.0189100977

xA calculado yA
1.0000003581
0.000383862 0.00395872
100
1.001332033 0.023641765 0.18458198
1.001690091 0.026662942 0.20177452
1.0021106844
0.029841769 0.21870472
95
1.0029374942 0.035292295 0.24537557
1.0059021487 0.05040415
0.306449
1.012563493
0.074409405 0.3766926
90
1.0151950359 0.082128061 0.39446688
1.0189484714 0.092146197 0.41489979
85
1.0316078718
0.120522548
0.460836
1.0584593797 0.167007718 0.51196106
1.0606194625 0.170276399 0.51481208
80
1.0922715226
0.213393062 0.54646422
1.1783934113 0.304938356 0.59303153
1.2391276926 0.35758639 0.61417299
75
1.292049833
0.398719037 0.62960461
1.3747304641 0.45686183 0.65097962
1.4369239856 0.496241746 0.66626294
70
1.5620936843
0.568541465
0
0.1
0.2 0.69584578
0.3
0.4
0.5
1.6919723837 0.635465432 0.72664575
H
Column H
1.8600475832 0.716152175 Column
0.76733633
1.9917897848 0.771536835 0.80153337
2.0346694838
0.7888695 0.81301366
2.0441639704 0.792358783 0.81561626
2.0527474621 0.796418768 0.81787492
2.0983760116 0.813813476 0.83045695
2.1550858506 0.835428538 0.84637451

0.6

0.7

exp

0.8

0.9

exp vap

gE
RT
temperatura
puro
puro
A
xAsupuesto
-0.00021149
0.0026925
0.00927324
0.016324565
0.0239133992
0.032126954
0.041046355
0.048773641
0.061564463

B
xA calculado yA
4.6694181301 1.000000109 -3.807E-005 -0.00224693
4.6038034666 1.000017669 0.00247246
0.027548
4.4603656964 1.000207997 0.00904663 0.08687135
4.3143552826 1.000639439 0.01609129 0.14021752
4.1655361566 1.001360589 0.02367294 0.18849804
4.0135361767 1.002433839 0.03187339 0.23249138
3.8583905926 1.003935232 0.04078968 0.27269287
3.7317362485 1.005511754 0.04852002 0.30249225
3.5366134304 1.008668371 0.06130317 0.34391277

-5.856E-005
0.00379278
1200
0.01373289
0.02415358
0.03510509
0.04664698
1000
0.05884358
0.06912466
0.08553821
0.10025478
800
0.11603879
0.13303308
0.15144511
600

400

Column I

800

0.07356344
0.087014318
0.102254977
0.11986114
0.140478642
0.165113432
0.1951256
0.231284857
0.277895194
0.341105122
0.414016621
0.505422008
0.61213395
0.762395102
0.77

Ya
0.17
0.3891
0.4375
0.4704
0.5089
0.5445
0.558
0.5823
0.6122
0.6564
0.6599
0.6841
0.7385
0.7815
0.8943

3.3685726167
3.1957030967
3.0175402273
2.8324054594
2.6401083465
2.4398916957
2.2321262671
2.0244214652
1.810109569
1.5903410074
1.4078951764
1.2509819553
1.1335022329
1.0423376233
1.039370571

1.012231448
1.016895842
1.023009329
1.031130104
1.042030625
1.056948671
1.077800618
1.106677535
1.149726389
1.218239983
1.311432546
1.449584095
1.641371028
1.969503069
1.987987235

0.07327223
0.08670703
0.10195539
0.11953805
0.14012873
0.16472246
0.19471066
0.23137164
0.2782811
0.3404567
0.41413864
0.50467775
0.61074545
0.76000157
0.76817337

0.3758836
0.40569703
0.43362528
0.46018313
0.48550664
0.50990819
0.53361053
0.5558252
0.57915364
0.60631508
0.63298207
0.66764038
0.71297103
0.79467448
0.79948012

600
0.17144181

400

200

-0.1

0.1

0.2

0.3

0.

0.7

00

00

00

00

00

0.8

0.9

exp vap

xi ln xi
temperatura

g
RT
constante

Err:502
Err:502
-0.01731044 -0.01351766
-0.05157324
Column I -0.03784036
Column I
-0.08240974 -0.05825616
-0.11200832 -0.07690322
-0.14119513 -0.09454815
-0.17044572 -0.11160215
-0.19413427 -0.12500961
-0.23053829 -0.14500008
-0.2620221 -0.16176732
-0.29485214 -0.17881336
-0.32935829 -0.19632521
-0.36600357 -0.21455846

00

00

-0.4051971 -0.23375528

00

00

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

SEPARACIN FLASH
Constantes de Antoine
presin en PSIA y T en F

Sistema:
A1
A2
A3
Pc, psia

Calor especifico vapores ideales

T en F, Cp en Btu/lbmolF

Constantes de van Laar

etanol(A)
7.43437
6162.36
359.3826
925.3

Agua(B)
6.53247
7173.79
389.4747
3206.7

a1 1.40485300E+01
a2 2.15314900E-02
a3 -2.15344200E-06
a4 -4.60725900E-09
a5 1.89369200E-12

7.98574200E+00
4.63319100E-04
1.40284100E-06
-6.57838700E-10
9.79528800E-14

0.83
0.51

Pv
A2
A1
A3 T
Pc

ln
C

ideal
pv

L
ln

a1 a2T a3T a4T a5T

2

Mezcla
H v yi H viideal

ln( Pv )
T
T temperatura absoluta

H L xi ( H viideal i )

RT 2

100 Kpa
760 mm Hg
14,696 psi
1,01325 bar
101,325 Kpa

x
A

1
xB

L
ln

2
B
x
B

1
x A

R (T 459.6) 2 A2

( A3 T ) 2
1bar=
1atm=
1atm=
1atm=
1atm=

C
185.245 85.1361111
327.245
164.025

L
n

Ingresa
Presin , psia=
Tempe, F=

300
367

Compuesto zF
A
B

Ingresa
Presin , psia=
Tempe, F=

x
A

1
xB

L
n

2
B
x
B

1
x A

0.5
0.5

gamma
1.1277549571
1.2161214188

300
386
Compuesto zF
A
B

Pvapor, psia
x=zF
0.6 324.037640834
0.4 167.717669311

Pvapor, psia
xsupuesto
gamma
0.4 402.264413978
0.14634026 1.6609555592
0.6
211.5858256
0.85365974 1.0245635197

PUNTO DE BURBUJA
K
zF*K
1.218116852
0.7308701115
0.6798835
0.2719533999
1.0028235114
-0.0028235114

PUNTO DE ROCIO
K
zF/K
2.227144382
0.1796021862
0.722610394
0.8303229583
1.0099251444
-9.92514E-03

y
0.6 0.730870111
0.4
0.2719534
1 1.002823511

x
0.4 0.179602186
0.6 0.830322958
1 1.009925144

TR,F

F, lbmol/h =
zF(A)=
PF, psia=
TF, F=
Pv A
Pv B
Gamma A
Gamma B
suma(z*K)
suma(z/K)
Hv A Btu/lb mol
Hv B Btu/lbmol
lambda A Btu/lb mol
lambda B Btu/lbmol
Hv mezcla
Hl mezcla
HF

32

200
0.4
300
120
4.0947413083
1.6899679549
1.2103776045
1.1480944817
0.01048873 en caso de vapor sobrecalenta
116.9840705 No usar la tabla de criterio
1378.8281628
706.63717461
17899.345601
18448.371499
975.5135699
-17253.24757
-17253.2476

Condiciones del separador ISOTRMICO

P, psia =
300
T, F =
370

Metanol(A)
Agua(B)
Q Btu/h

Pv
x
335.54411
174.119448

gamma
0.1 1.8134978962
0.9 1.0120317123

2223123.68

en caso de vapor sobrecalentado

No usar la tabla de criterio

T de burbuja
t de rocio
T( C)

242
260
V/F

242
243
244
245
246
247
248
249
250
251
252
253
254
255
256
257
258
259

Fracc V/F

K
zF*K
zF/K
2.02836179 0.81134472 0.19720348
0.58738134 0.35242881 1.0214829
1.16377352 1.21868638

0.38501218 Nuevo V/F

0.38596564

g
g^2/zF
x
y
0.2946739314 0.21708181 0.28654695 0.58122088
-0.29432929 0.14438288 0.71332036 0.41899107
G1 0.0003446416 -0.3614647 0.99986731 1.00021195

G1

Hv
Lambda
Hl
6155.91425 15840.5998 -9684.6855636
2754.46433 17008.1623 -14253.6979604
4732.04185
-12942.5700655
Entalpia mezcla
Entalpia mezcla

x
V/F
-0.06936
0.25
0.6
-0.0156
0.290472
0.48329
-0.0116
0.326965 0.45416223
-0.0046
0.342481 0.43073692
-0.0025
0.351451 0.42119217
-0.0011 0.35561307 0.41581023

0.02

0.01

0
0.25
-0.01

-0.02

0.3

0.35

0.4

0.45

0.5

0.55

0.6