SISTEMA S - H2O

HSO4(-a) = SO4(-2a) + H(+a)

deltaH
deltaS
kJ
J/K

deltaG
kJ

278.150
283.150
288.150
293.150

-13.635
-15.623
-17.400
-19.013

-82.799
-89.884
-96.105
-101.656

9.396
9.828
10.293
10.788

298.150
303.150
308.150
313.150
318.150
323.150
328.150
333.150
338.150
343.150
348.150
353.150
358.150
363.150
368.150

-20.502
-21.898
-23.226
-24.506
-25.750
-26.965
-28.154
-29.315
-30.461
-31.600
-32.735
-33.869
-35.004
-36.144
-37.291

-106.692
-111.336
-115.683
-119.803
-123.743
-127.533
-131.184
-134.696
-138.110
-141.454
-144.738
-147.972
-151.165
-154.326
-157.463

11.309
11.854
12.422
13.010
13.619
14.247
14.894
15.559
16.241
16.940
17.656
18.387
19.135
19.899
20.678

1/T
0.00359518
0.0035317
0.00347041
0.00341122
0.00335402
0.0032987
0.00324517
0.00319336
0.00314317
0.00309454
0.00304739
0.00300165
0.00295727
0.00291418
0.00287233
0.00283166
0.00279213
0.00275368
0.00271628

T
K

2
1/T
0.00359518
0.0035317
0.00347041
0.00341122
0.00335402
0.0032987
0.00324517
0.00319336
0.00314317
0.00309454
0.00304739
0.00300165
0.00295727

T
K
278.150
283.150
288.150
293.150
298.150
303.150
308.150
313.150
318.150
323.150
328.150
333.150
338.150

HSO4(-a) + 9H(+a) + 8e- = H2S(a) + 4H2O

deltaH
deltaS
deltaG
kJ
J/K
kJ
-301.497
-299.446
-297.520
-295.687
-293.926
-292.220
-290.552
-288.914
-287.297
-285.696
-284.107
-282.528
-280.955

-269.253
-261.943
-255.199
-248.893
-242.935
-237.261
-231.804
-226.529
-221.406
-216.412
-211.533
-206.758
-202.073

-226.605
-225.277
-223.984
-222.724
-221.495
-220.295
-219.122
-217.976
-216.856
-215.762
-214.692
-213.646
-212.624

0.00291418
0.00287233
0.00283166
0.00279213
0.00275368
0.00271628

343.150
348.150
353.150
358.150
363.150
368.150

3
1/T
0.00359518
0.0035317
0.00347041
0.00341122
0.00335402
0.0032987
0.00324517
0.00319336
0.00314317
0.00309454
0.00304739
0.00300165
0.00295727
0.00291418
0.00287233
0.00283166
0.00279213
0.00275368
0.00271628

T
K
278.150
283.150
288.150
293.150
298.150
303.150
308.150
313.150
318.150
323.150
328.150
333.150
338.150
343.150
348.150
353.150
358.150
363.150
368.150

4
1/T
0.00359518
0.0035317
0.00347041
0.00341122
0.00335402
0.0032987
0.00324517
0.00319336
0.00314317
0.00309454

T
K
278.150
283.150
288.150
293.150
298.150
303.150
308.150
313.150
318.150
323.150

-279.384
-277.813
-276.239
-274.660
-273.074
-271.479

-197.461
-192.915
-188.426
-183.986
-179.589
-175.227

-211.626
-210.650
-209.696
-208.765
-207.856
-206.969

SO4(-2a) + 10H(+a) + 8e- = H2S(a) + 4H2O

deltaH
deltaS
deltaG
kJ
J/K
kJ
-287.862
-283.823
-280.120
-276.674
-273.425
-270.322
-267.326
-264.408
-261.547
-258.731
-255.953
-253.213
-250.495
-247.785
-245.078
-242.370
-239.656
-236.930
-234.188

-186.454
-172.059
-159.093
-147.236
-136.243
-125.924
-116.121
-106.726
-97.663
-88.879
-80.349
-72.062
-63.963
-56.008
-48.177
-40.454
-32.821
-25.263
-17.764

-236.000
-235.105
-234.277
-233.512
-232.804
-232.148
-231.543
-230.987
-230.476
-230.009
-229.586
-229.206
-228.866
-228.566
-228.305
-228.084
-227.901
-227.755
-227.648

SO4(-2a) + 9H(+a) + 8e- = HS(-a) + 4H2O

deltaH
deltaS
deltaG
kJ
J/K
kJ
-257.772
-255.586
-253.556
-251.646
-249.827
-248.076
-246.371
-244.699
-243.050
-241.419

-221.167
-213.379
-206.270
-199.697
-193.544
-187.719
-182.141
-176.758
-171.535
-166.449

-196.254
-195.168
-194.119
-193.105
-192.122
-191.169
-190.244
-189.347
-188.476
-187.631

0.00304739
0.00300165
0.00295727
0.00291418
0.00287233
0.00283166
0.00279213
0.00275368
0.00271628

328.150
333.150
338.150
343.150
348.150
353.150
358.150
363.150
368.150

5
1/T
0.00359518
0.0035317
0.00347041
0.00341122
0.00335402
0.0032987
0.00324517
0.00319336
0.00314317
0.00309454
0.00304739
0.00300165
0.00295727
0.00291418
0.00287233
0.00283166
0.00279213
0.00275368
0.00271628

T
K
278.150
283.150
288.150
293.150
298.150
303.150
308.150
313.150
318.150
323.150
328.150
333.150
338.150
343.150
348.150
353.150
358.150
363.150
368.150

6
1/T
0.00359518
0.0035317
0.00347041
0.00341122
0.00335402
0.0032987
0.00324517

T
K
278.150
283.150
288.150
293.150
298.150
303.150
308.150

-239.805
-238.208
-236.619
-235.031
-233.443
-231.852
-230.256
-228.652
-227.039

-161.491
-156.660
-151.927
-147.266
-142.672
-138.135
-133.647
-129.200
-124.787

-186.811
-186.016
-185.245
-184.497
-183.772
-183.070
-182.390
-181.733
-181.098

SO4(-2a) + 8H(+a) + 8e- = S(-2a) + 4H2O

deltaH
deltaS
deltaG
kJ
J/K
kJ
-208.691
-206.252
-204.135
-202.275
-200.623
-199.135
-197.773
-196.512
-195.332
-194.219
-193.169
-192.178
-191.230
-190.310
-189.413
-188.533
-187.662
-186.797
-185.930

-304.441
-295.750
-288.334
-281.936
-276.346
-271.394
-266.939
-262.879
-259.139
-255.670
-252.443
-249.446
-246.622
-243.922
-241.327
-238.816
-236.369
-233.969
-231.598

-124.011
-122.511
-121.051
-119.626
-118.231
-116.861
-115.516
-114.191
-112.886
-111.600
-110.329
-109.075
-107.835
-106.608
-105.395
-104.195
-103.007
-101.831
-100.667

H2S(a) = HS(-a) + H(+a)

deltaH
deltaS
deltaG
kJ
J/K
kJ
30.091
28.237
26.564
25.028
23.598
22.247
20.955

-34.713
-41.320
-47.177
-52.461
-57.301
-61.794
-66.020

39.746
39.937
40.158
40.407
40.682
40.980
41.299

0.00319336
0.00314317
0.00309454
0.00304739
0.00300165
0.00295727
0.00291418
0.00287233
0.00283166
0.00279213
0.00275368
0.00271628

313.150
318.150
323.150
328.150
333.150
338.150
343.150
348.150
353.150
358.150
363.150
368.150

7
1/T
0.00359518
0.0035317
0.00347041
0.00341122
0.00335402
0.0032987
0.00324517
0.00319336
0.00314317
0.00309454
0.00304739
0.00300165
0.00295727
0.00291418
0.00287233
0.00283166
0.00279213
0.00275368
0.00271628

T
K
278.150
283.150
288.150
293.150
298.150
303.150
308.150
313.150
318.150
323.150
328.150
333.150
338.150
343.150
348.150
353.150
358.150
363.150
368.150

19.709
18.497
17.311
16.148
15.005
13.876
12.754
11.635
10.518
9.399
8.277
7.149

-70.032
-73.873
-77.570
-81.142
-84.598
-87.963
-91.259
-94.495
-97.681
-100.825
-103.937
-107.023

41.640
42.000
42.378
42.775
43.189
43.621
44.069
44.533
45.014
45.510
46.022
46.549

HS(-a) = S(-2a) + H(+a)

deltaH
deltaS
deltaG
kJ
J/K
kJ
49.081
49.334
49.421
49.370
49.204
48.941
48.598
48.187
47.719
47.200
46.636
46.030
45.389
44.721
44.030
43.320
42.594
41.855
41.109

-83.273
-82.371
-82.063
-82.238
-82.801
-83.675
-84.798
-86.120
-87.604
-89.221
-90.952
-92.786
-94.695
-96.656
-98.655
-100.681
-102.722
-104.769
-106.811

72.243
72.657
73.068
73.479
73.891
74.307
74.728
75.155
75.590
76.032
76.482
76.941
77.410
77.888
78.377
78.875
79.384
79.902
80.431

2O

)
K

Log(K)

1.720E-002
1.538E-002
1.361E-002
1.196E-002

-1.765
-1.813
-1.866
-1.922

1.044E-002
9.064E-003
7.839E-003
6.755E-003
5.805E-003
4.975E-003
4.255E-003
3.633E-003
3.097E-003
2.637E-003
2.243E-003
1.906E-003
1.618E-003
1.373E-003
1.164E-003

-1.981
-2.043
-2.106
-2.170
-2.236
-2.303
-2.371
-2.440
-2.509
-2.579
-2.649
-2.720
-2.791
-2.862
-2.934

B'

A'

1 1345.88698 -6.51420368

38.8631899 0.12158046
0.98602358 0.04513728
1199.33442
17
2.44349318 0.03463536
0.12614837 -26.2303683
0.0023027 0.74678531
0.99436742 0.2748812
3001.1527
17
226.766116 1.28451443

H2S(a) + 4H2O
K
3.617E+042
3.647E+041
4.040E+040
4.889E+039
6.430E+038
9.147E+037
1.401E+037
2.303E+036
4.046E+035
7.570E+034
1.504E+034
3.166E+033
7.034E+032

E vs. SHE
V
0.294
0.292
0.290
0.289
0.287
0.286
0.284
0.283
0.281
0.280
0.278
0.277
0.276

Log(K)

42.558
41.562
40.606
39.689
38.808
37.961
37.147
36.362
35.607
34.879
34.177
33.500
32.847

B'

A'

2 14994.8371 -11.4625393

50.2949766 0.15734391
0.99980878 0.05841462
88886.1881
17
303.303518 0.05800856
0.21754581 -286.437958
0.00299191 0.97030105
0.99679484 0.3571542
5286.94492
17
674.398071 2.16850513

1.646E+032
4.050E+031
1.044E+031
2.819E+030
7.944E+029
2.334E+029

0.274
0.273
0.272
0.271
0.269
0.268

32.217
31.607
31.019
30.450
29.900
29.368

H2S(a) + 4H2O
K
2.103E+044
2.371E+043
2.967E+042
4.088E+041
6.161E+040
1.009E+040
1.788E+039
3.409E+038
6.970E+037
1.522E+037
3.535E+036
8.713E+035
2.271E+035
6.243E+034
1.806E+034
5.480E+033
1.742E+033
5.788E+032
2.006E+032

E vs. SHE
V
0.306
0.305
0.304
0.303
0.302
0.301
0.300
0.299
0.299
0.298
0.298
0.297
0.297
0.296
0.296
0.296
0.295
0.295
0.295

Log(K)

44.323
43.375
42.472
41.612
40.790
40.004
39.252
38.533
37.843
37.182
36.548
35.940
35.356
34.795
34.257
33.739
33.241
32.763
32.302

B'
A'
3 13648.9501 -4.9483356
89.1498674 0.2788984
0.99927527 0.10354227
23439.972
17
251.29997 0.18225702
0.09139744
0.00529414
0.94603886
298.041528
119.037264

-260.20759
1.71693482
0.63197962
17
6.78977018

B'
4 12684.8592
51.286704
0.99972218
61173.2739
217.052728

A'
-8.8606227
0.16044645
0.05956646
17
0.06031877

HS(-a) + 4H2O
K
7.215E+036
1.016E+036
1.556E+035
2.576E+034
4.589E+033
8.755E+032
1.782E+032
3.858E+031
8.852E+030
2.146E+030

E vs. SHE
V
0.254
0.253
0.252
0.250
0.249
0.248
0.247
0.245
0.244
0.243

Log(K)

36.858
36.007
35.192
34.411
33.662
32.942
32.251
31.586
30.947
30.332

0.16770143 -242.206805
0.00304917
0.988872
0.99441137 0.36398991

5.482E+029
1.472E+029
4.144E+028
1.221E+028
3.754E+027
1.203E+027
4.009E+026
1.388E+026
4.979E+025

0.242
0.241
0.240
0.239
0.238
0.237
0.236
0.236
0.235

29.739
29.168
28.617
28.087
27.574
27.080
26.603
26.142
25.697

3024.89092
17
400.763732 2.25230715

4H2O
K
1.951E+023
4.002E+022
8.821E+021
2.076E+021
5.191E+020
1.373E+020
3.826E+019
1.120E+019
3.432E+018
1.098E+018
3.661E+017
1.268E+017
4.558E+016
1.696E+016
6.520E+015
2.587E+015
1.058E+015
4.450E+014
1.924E+014

K
3.430E-008
4.286E-008
5.244E-008
6.301E-008
7.449E-008
8.676E-008
9.971E-008

E vs. SHE
V
0.161
0.159
0.157
0.155
0.153
0.152
0.150
0.148
0.146
0.145
0.143
0.141
0.140
0.138
0.137
0.135
0.134
0.132
0.131

Log(K)

23.290
22.602
21.945
21.317
20.715
20.138
19.583
19.049
18.536
18.041
17.564
17.103
16.659
16.229
15.814
15.413
15.024
14.648
14.284

B'
A'
5 10222.7923 -13.5515546
36.8120829 0.11516373
0.99977961 0.04275504
77118.4501
17
140.972052 0.0310759
0.25805314
0.00216296
0.99880709
14233.8644
948.927765

-195.254417
0.70146483
0.25819936
17
1.13333748

B'
6 -964.090881
37.8670111
0.97444406
648.207267
1.2538047

A'
-3.9122871
0.11846399
0.04398028
17
0.03288251

Log(K)
-7.465
-7.368
-7.280
-7.201
-7.128
-7.062
-7.001

1.132E-007
1.270E-007
1.410E-007
1.551E-007
1.690E-007
1.825E-007
1.955E-007
2.079E-007
2.195E-007
2.301E-007
2.397E-007
2.482E-007

K
2.704E-014
3.938E-014
5.668E-014
8.057E-014
1.131E-013
1.568E-013
2.146E-013
2.902E-013
3.877E-013
5.117E-013
6.678E-013
8.617E-013
1.100E-012
1.389E-012
1.737E-012
2.151E-012
2.638E-012
3.207E-012
3.865E-012

-6.946
-6.896
-6.851
-6.809
-6.772
-6.739
-6.709
-6.682
-6.659
-6.638
-6.620
-6.605

B
0.07630399
0.00224519
R ^2 0.9854951
1155.01806
82.9677644

A
18.0007842
0.72813355
0.26801574
17
1.22115147

Log(K)
-13.568
-13.405
-13.247
-13.094
-12.946
-12.805
-12.668
-12.537
-12.412
-12.291
-12.175
-12.065
-11.959
-11.857
-11.760
-11.667
-11.579
-11.494
-11.413

B'
A'
7 -2462.0669 -4.69093192
14.8828026 0.04655969
0.9993792 0.01728549
27367.1931
17
8.17699334 0.0050794
0.0903517
0.00090918
0.9982816
9875.91757
116.328886

46.9523888
0.29485316
0.10853131
17
0.20024378

2,303
8,314
1.00E+09

R ^2
0.99466476

R ^2
0.99988525

T5

278

T25
T95

298
368

1
2
3
4
5
6
7

log=(^0)/(2.303)

LogK= A + B*(1/T)
A
B
-6.5142
1345.8870
-11.4625
14994.8371
-4.9483
13648.9501
-8.8606
12684.8592
-13.5516
10222.7923

G=
r2

A
-31.1609

0.9999
0.9996
0.9998
0.9999
18.0008

-4.6909

-2462.0669

0.9994

R ^2
0.99956145

R ^2
0.99983289

R ^2
0.99989678

R ^2
0.97707918

R ^2
0.99939296

A + B*T
B
0.1403

r2
0.9977

0.0763

0.9940

LogK
5C
-1.6729
42.4757
44.1486
36.7684
23.2211
-7.3669
-13.5473

LogK
25C
-1.6729
38.8557
40.8535
33.7060
20.7531
-7.1399
-12.9529

LogK
95C
-1.6729
29.2843
32.1412
25.6091
14.2278
-6.5398
-11.3813

T1

[S]

0.01

[Hg]

1.00E-05

T0

F
R

96500
8.314
2.303

Tf

273

1
2
3
4
5
6
7

Sistema S-H2O
HSO4(-a) = SO4(-2a) + H(+a)
HSO4(-a) + 9H(+a) + 8e-= H2S(a) + 4H2O
SO4(-2a) + 10H(+a) + 8e-= H2S(a) + 4H2O
SO4(-2a) + 9H(+a) + 8e- = HS(-a) + 4H2O
SO4(-2a) + 8H(+a) + 8e- = S(-2a) + 4H2O
H2S(a) = HS(-a) + H(+a)
HS(-a) = S(-2a) + H(+a)

25
cal
H2S(a)
HS(-a)
HSO4(-a)
SO4(-2a)

J
-6.607
2.973
-180.524
-177.907

-27.66
12.44
-755.63
-744.68

273

0.003663004

25

298

0.003355705

95

368

0.002717391

LogK
5C
25C
95C
-1.672883594 -1.672883594 -1.672883594
42.47572361 38.85570596 29.28430062
44.1486072 40.85351037 32.14120271
36.76836729 33.70601897 25.60910343
23.22107961 20.75311758 14.22777233
-7.366896569 -7.139932869 -6.539835912
-13.54728768 -12.95290138 -11.3813311

a) + H(+a)
= H2S(a) + 4H2O
-= H2S(a) + 4H2O
= HS(-a) + 4H2O
= S(-2a) + 4H2O
+ H(+a)
+ H(+a)

5
cal
-6.807
2.541
-182.619
-180.488

95
J
-28.49
10.64
-764.41
-755.49

cal
-6.190
4.820
-172.978
-168.017

J
-25.91
20.18
-724.05
-703.51

n
0
8
8
8
8
0
0

a
0
5.3095
5.5186
4.5960
2.9026
0
0

5C
b
-1.00
-1.13
-1.25
-1.13
-1.00
-1.00
-1.00

5C
ph
1.6729

7.3669
13.5473

pE = a + b*pH
25C
a
b
ph
0
-1
1.6729
4.8570
-1.13
5.1067
-1.25
4.2133
-1.13
2.5941
-1.00
0
-1
7.1399
0
-1
12.9529

95C
b
-1
-1.13
-1.25
-1.13
-1.00
-1
-1

a
0
3.6605
4.0177
3.2011
1.7785
0
0

Eh (Volts)
2.0

5C
ph
2.9054

a'
0.03595
0.03737
0.03112
0.01965

6.5398
11.3813

S - H2O - System at 5.00 C

1.5
HSO4(-a)
5

1.0

SO4(-2a)
5

0.5

a
b

0.0

d
5

-0.5

H2S(a)

-1.0

-1.5

HS(-a)

-2.0
0

10

12

14

C:\HSC5\EpH\CEpHSD1.EPT

ELEMENTS
S

Molality
1.000E-02

P
1.

Eth = a' + b'*pH

25C
a'
b'

5C
b'
-0.00762
-0.00846
-0.00762
-0.00677

0.03289
0.03458
0.02853
0.01756

95C
a'

-0.00762
-0.00846
-0.00762
-0.00677

0.02479
0.02720
0.02167
0.01204

5.00 C

SO4(-2a)
5

f
HS(-a)

S(-2a)

h
10

12

H2O limits

14

16

18

20
pH

Pressure
1.000E+00

b'
-0.00762
-0.00846
-0.00762
-0.00677

redox
a
b
d
e
f
no redox
b
c
d
g
e
h

5C
pH
0.000
1.673
7.367
13.547
20.000

Eth
0.360
0.232
-0.250
-0.721
-1.158

1.673
1.673
7.367
7.367
13.547
13.547

0.232
2.0
-0.250
-2
-0.721
-2

2.0

1.5

HSO4(a)
1.0

0.5

0.0

Eh (volts)

-0.5

H2S(a)
-1.0

-1.5

-2.0

redox
a
b
d
e
f
no redox

25C
pH
0
1.6729
7.1399
12.9529
20

Eth
0.328862324
0.204183563
-0.258594054
-0.701386087
-1.178541279

1.5

HSO4(-

1a)
0.5

1.5

b
c
d
g
e
h

1.6729
1.6729
7.1399
7.1399
12.9529
12.9529

0.204183563
2
-0.258594054
-2
-0.701386087
-2

HSO4(-

1a)
0.5

Eh (Volts)

-0.5

H2S(a)

-1

-1.5

-2

redox
a
b
d
e
f
no redox
b
c
d
g
e
h

95C
pH
0
2.9054
6.5398
11.3813
20
2.9054
2.9054
6.5398
6.5398
11.3813
11.3813

Eth
0.247852997
0.026128205
-0.281412503
-0.650204368
-1.233769723
0.026128205
2
-0.281412503
-2
-0.650204368
-2

1.5

HSO4(1
a)
0.5

Eh (Volts)

-0.5

-1

H2S(a)

-1.5

-2

-1.5

-2

SISTEMA S - H2O A 5C

SO4(-2a)

H2S(a)
HS(-a)
S(-2a)

10

pH

SISTEMA S - H2O A 25C

SO4(-2a)

12

14

SO4(-2a)

H2S(a)
HS(-a)

S(-2a)

10

12

14

16

pH

SISTEMA S - H2O A 95C

(-

SO4(-2a)

H2S(a)
HS(-a)
S(-2a)

10

pH

12

14

16

HS(-a)
S(-2a)

10

pH

12

14

16

A 5C

a-b
b-d
d-e
e-f
b-c
g-d
h-e

S(-2a)

12

14

16

18

20

5C

a-b
b-d

a-b
b-d
d-e
e-f
b-c
g-d
h-e

S(-2a)

14

16

18

20

5C

a-b
b-d
d-e
e-f
b-c
g-d
h-e

(-2a)

12

14

16

18

20

(-2a)

12

14

16

18

20

T = 5C
1

HSO4(-a) = SO4(-2a) + H(+a)

logK =

pH = -logK
pH= 1.67288359

HSO4(-a) + 9H(+a) + 8e- = H2S(a) + 4H2O

logK =
5.30946545

pE = logK/8 - 9/8pH
pE= 5.282 - 1.125pH

SO4(-2a) + 10H(+a) + 8e- = H2S(a) + 4H2O

logK =
5.5185759

pE = logK/8 -10/8pH
pE= 5.472 - 1.25pH

SO4(-2a) + 9H(+a) + 8e- = HS(-a) + 4H2O

logK =
4.59604591

pE = logK/8 - 9/8pH
pE= 4.5718 - 1.125pH

SO4(-2a) + 8H(+a) + 8e- = S(-2a) + 4H2O

logK =
2.90263495

pE = logK/8 -pH
pE= 2.8906 - pH

H2S(a) = HS(-a) + H(+a)

logK =

pH = -logK
pH= 7.36689657

HS(-a) = S(-2a) + H(+a)

logK =

pH = -logK
pH= 13.5472877

1.00E-05
T = 5C
1

Hg(+2a) + H2O = HgO(a) +2H(+a)

logK =

-6.5718

pH = -logK/2
pH= 3.28592447

HgO(a) + H2O = HHgO2(-a) + H(+a)

logK =

-15.7058

pH = -logK
pH= 15.7057898

Hg(+2a) + Hg = Hg2(+2a)
Eth = Eth

logK =

-1.9744

Eth =

Hg2(+2a) + 2e- = 2Hg

logK =

29.0450

pE = logK/2 + log [a]/2

pE =

12.0225045

logK =

46.1398
20.5699114

2e- + 2HgO(a) + 4H(+a) = Hg2(+2a) + 2H2

pE = (logK + log[a])/2 -2pH

pE = 20.569 - 2pH

HgO(a) + 2H(+a) + 2e- = Hg + H2O

logK =

37.5924
16.296208

pE = (logK + log[a])/2 -pH

pE = 16.2962 - pH

HHgO2(-a) + 3H(+a) + 2e- = Hg + 2H2O

logK =

53.2982
24.1491029

pE = (logK + log[a])/2 -3/2pH

pE = 24.1491 -1.5pH

T = 25C
-1.67288359

HSO4(-a) = SO4(-2a) + H(+a)

pH = -logK

42.4757236

HSO4(-a) + 9H(+a) + 8e- = H2S(a) + 4H2O

pE = logK/8 - 9/8pH

82 - 1.125pH

44.1486072

SO4(-2a) + 10H(+a) + 8e- = H2S(a) + 4H2O

pE = logK/8 -10/8pH

72 - 1.25pH

36.7683673

SO4(-2a) + 9H(+a) + 8e- = HS(-a) + 4H2O

pE = logK/8 - 9/8pH

718 - 1.125pH

23.2210796

SO4(-2a) + 8H(+a) + 8e- = S(-2a) + 4H2O

pE = logK/8 -pH

-7.36689657

H2S(a) = HS(-a) + H(+a)

pH = -logK

-13.5472877

HS(-a) = S(-2a) + H(+a)

pH = -logK

T = 25C
1

Hg(+2a) + H2O = HgO(a) +2H(+a)

pH = -logK/2

HgO(a) + H2O = HHgO2(-a) + H(+a)

pH = -logK

Hg(+2a) + Hg = Hg2(+2a)
Eth = Eth

Hg2(+2a) + 2e- = 2Hg

pE = logK/2 + log [a]/2

2e- + 2HgO(a) + 4H(+a) = Hg2(+2a) +

pE = (logK + log[a])/2 -2pH

HgO(a) + 2H(+a) + 2e- = Hg + H2O

pE = (logK + log[a])/2 -pH

1491 -1.5pH

HHgO2(-a) + 3H(+a) + 2e- = Hg + 2H2

pE = (logK + log[a])/2 -3/2pH

T = 25C

a) + H(+a)

logK =

-1.67288359

HSO4(-a) = SO4(-2a) + H

pH = -logK
pH= 1.67288359

H2S(a) + 4H2O

logK =
4.85696325

38.855706

HSO4(-a) + 9H(+a) + 8e- = H2S(

pE = logK/8 - 9/8pH
pE= 4.8337 - 1.125pH

H2S(a) + 4H2O

logK =
40.8535104
5.1066888

SO4(-2a) + 10H(+a) + 8e- = H2S

pE = logK/8 -10/8pH
pE= 5.0677 - 1.25pH

HS(-a) + 4H2O

logK =
4.21325237

33.706019

SO4(-2a) + 9H(+a) + 8e- = HS(-

pE = logK/8 - 9/8pH
pE= 4.1851 - 1.125pH

S(-2a) + 4H2O

logK =
20.7531176
2.5941397

SO4(-2a) + 8H(+a) + 8e- = S(-2a

pE = logK/8 -pH
pE= 2.5866 - pH

+ H(+a)

logK =

-7.13993287

H2S(a) = HS(-a) + H(+

pH = -logK
pH= 7.13993287

H(+a)

logK =

-12.9529014

HS(-a) = S(-2a) + H(+a

pH = -logK
pH= 12.9529014

T = 25C
logK = -6.17049218

Hg(+2a) + H2O = HgO(a) +2H(+a

pH = -logK/2

pH= 3.08524609

logK = -15.0086149

HgO(a) + H2O = HHgO2(-a) + H(+

pH = -logK

pH= 15.0086149

logK = -1.93699502

Eth =

Hg(+2a) + Hg = Hg2(+2a)
Eth = Eth

logK =

26.9332419

pE =

10.9666209

logK =

43.1498388
19.0749194

Hg2(+2a) + 2e- = 2Hg

pE = logK/2 + log [a]/2

2e- + 2HgO(a) + 4H(+a) = Hg2(+2

pE = (logK + log[a])/2 -2pH

pE = 19.0749 - 2pH

logK =

35.0415403
15.0207702

HgO(a) + 2H(+a) + 2e- = Hg + H2

pE = (logK + log[a])/2 -pH

pE = 15.0208 - pH

logK =

50.0501553
22.5250776

HHgO2(-a) + 3H(+a) + 2e- = Hg +

pE = (logK + log[a])/2 -3/2pH

pE = 22.5251 -1.5pH

T = 95C
HSO4(-a) = SO4(-2a) + H(+a)

logK =

-2.90541058

pH= 2.90541058

HSO4(-a) + 9H(+a) + 8e- = H2S(a) + 4H2O

logK =
29.2843006
3.66053758

= logK/8 - 9/8pH
pE= 3.6484 - 1.125pH

SO4(-2a) + 10H(+a) + 8e- = H2S(a) + 4H2O

logK =
32.1412027
4.01765034

= logK/8 -10/8pH
pE= 4.0112 - 1.25pH

SO4(-2a) + 9H(+a) + 8e- = HS(-a) + 4H2O

logK =
25.6091034
3.20113793

= logK/8 - 9/8pH
pE= 3.1989 - 1.125pH

SO4(-2a) + 8H(+a) + 8e- = S(-2a) + 4H2O

logK =
14.2277723
1.77847154

= logK/8 -pH
pE= 1.7826 - pH

H2S(a) = HS(-a) + H(+a)

logK =

-6.53983591

pH= 6.53983591

HS(-a) = S(-2a) + H(+a)

logK =

pH= 11.3813311

-11.3813311

T = 95C

+2a) + H2O = HgO(a) +2H(+a)

O(a) + H2O = HHgO2(-a) + H(+a)

+2a) + Hg = Hg2(+2a)

logK = -5.10929617

pH= 2.55464809

logK = -13.1652695

pH= 13.1652695

logK = -1.83814847
Eth =

(+2a) + 2e- = 2Hg

logK =

21.3496836

= logK/2 + log [a]/2

pE =

8.17484181

logK =

35.2442558
15.1221279

+ 2HgO(a) + 4H(+a) = Hg2(+2a) +

= (logK + log[a])/2 -2pH

O(a) + 2H(+a) + 2e- = Hg + H2O

pE = 15.1221 - 2pH

logK =

28.2969697
11.6484849

= (logK + log[a])/2 -pH

pE = 11.6485 - pH

gO2(-a) + 3H(+a) + 2e- = Hg + 2H2

logK =

41.4622392
18.2311196

= (logK + log[a])/2 -3/2pH

pE = 18.2311 -1.5pH

T1

[S]

0.01

[Hg]

1.00E-05

T0

F
R

96500
8.314
2.303

Tf

1
2
3
4
5
6
7

Sistema Hg-H2O
Hg(+2a) + H2O = HgO(a) +2H(+a)
HgO(a) + H2O = HHgO2(-a) + H(+a)
Hg(+2a) + Hg = Hg2(+2a)
Hg2(+2a) + 2e- = 2Hg
2e- + 2HgO(a) + 4H(+a) = Hg2(+2a) + 2H2O
HgO(a) + 2H(+a) + 2e- = Hg + H2O
HHgO2(-a) + 3H(+a) + 2e- = Hg + 2H2O

273

5C

LogK
25C

-6.572
-15.706
-1.974
29.045
46.140
37.592
53.298

-6.170
-15.009
-1.937
26.933
43.150
35.042
50.050

273

0.003663

25

298

0.0033557

95

368

0.00271739

LogK
95C

-5.109
-13.165
-1.838
21.350
35.244
28.297
41.462

0
0
0
2
2
2
2

5C
b

a
0
0

pE = a + b*pH
25C
ph
-1 3.28592447
-1 15.7057898

pE = a + b*pH
25C
b

Eth
ph

95C
b

5C
ph

a'

5C
b'

Eth = a' + b'*pH

25C
a'
b'

95C
a'

b'

redox

5C
pH

Eth

Eh (Volts)
2.0

Hg - H2O - System at 5.00 C

1.5
Hg(+2a)

HgO(a)

HHgO2(-a)

1.0

5
5

0.5
5

0.0
5

-0.5

-1.0
Hg(a)

-1.5

H2O lim

-2.0
-2

10

12

14

16

18

C:\HSC5\EpH\Hg25POURBAIX.iep

ELEMENTS
Hg

pH

Molality
1.000E-05

Eh (Volts)
2.0

20

Pressure
1.000E+00

Hg - H2O - System at 25.00 C

1.5
Hg(+2a)

25

HgO(a)
HHgO2(-a)

1.0

25
25

25

0.5
25

0.0
25

-0.5

25

-1.0
Hg(a)

-1.5

H2O lim

-2.0
-2

10

12

14

C:\HSC5\EpH\Hg25POURBAIX.iep

ELEMENTS

16

18

20
pH

Molality

Pressure

Hg(a)

-1.5

H2O lim

-2.0
-2

10

12

14

16

18

C:\HSC5\EpH\Hg25POURBAIX.iep

ELEMENTS
Hg
Eh (Volts)
2.0

20
pH

Molality
1.000E-05

Pressure
1.000E+00

Hg - H2O - System at 95.00 C

1.5
95

Hg(+2a)

HgO(a)

1.0

HHgO2(-a)

95
95

0.5

95

95

0.0
-0.5

95
95

-1.0
Hg(a)

-1.5

H2O lim

-2.0
-2

10

12

14

16

C:\HSC5\EpH\Hg25POURBAIX.iep

ELEMENTS
Hg

Molality
1.000E-05

18

20
pH

Pressure
1.000E+00

Eh (Volts )
2.0

Hg - H2O - System at 5.00 C

1.5
HHgO2(-a)

Hg(+2a)

HgO(a)

1.0

5
Hg2(+2a)

0.5
5

0.0
5

-0.5

-1.0

Hg

-1.5
H2O limits

-2.0
16

18

20

-2

pH

10

12

C:\HSC5\EpH\Hg25POURBAIX.iep

ssure
0E+00

ELEMENTS
Hg

Molality
1.000E-05

Eh (Volts)
2.0

1.5
HHgO2(-a)

Hg - H2O - System at 25.00 C

Hg(+2a)

25

HgO(a)

1.0

25

ssure

25
Hg2(+2a)
25

0.5

25

25

25

0.0
25

-0.5

25

-1.0
Hg

-1.5
H2O limits

-2.0
16

18

20
pH

-2

C:\HSC5\EpH\CEpHSD2.EPT

ELEMENTS

Molality

10

Hg

-1.5
H2O limits

-2.0
16

18

20

-2

pH

10

C:\HSC5\EpH\CEpHSD2.EPT

ssure
0E+00

ELEMENTS
Hg

Eh (Volts)
2.0

1.5

Molality
1.000E-05

Hg - H2O - System at 95.00 C

Hg(+2a)

HHgO2(-a)

95

HgO(a)

95

1.0
95
Hg2(+2a)
95

0.5

95

95

95

0.0
95

-0.5
95

-1.0

H2O limits

16

ssure
0E+00

18

20
pH

Hg

-1.5
-2.0
-2

C:\HSC5\EpH\CEpHSD2.EPT

ELEMENTS
Hg

Molality
1.000E-05

10

H2O - System at 5.00 C

HgO(a)
HHgO2(-a)
5
5

Hg

H2O limits

10

12

14

16

18

AIX.iep

20
pH

Molality
1.000E-05

Pressure
1.000E+00

Hg - H2O - System at 25.00 C

HgO(a)
25

25

HHgO2(-a)

25

25

25
25

Hg
H2O limits

10

12

14

2.EPT

16

18

20
pH

Molality

Pressure

Hg
H2O limits

10

12

14

16

18

2.EPT

20
pH

Molality
1.000E-05

Pressure
1.000E+00

Hg - H2O - System at 95.00 C

HgO(a)
HHgO2(-a)

95
95

95

95

95
95

Hg
H2O limits

10

12

14

16

2.EPT

18

20
pH

Molality
1.000E-05

Pressure
1.000E+00

Eh (Volts)
2.0

S - H2O - System at 5.00 C

1.5
HSO4(-a)
5

1.0

SO4(-2a)
5

0.5
5

0.0

-0.5

5
5

H2S(a)

-1.0

HS(-a)

S(-2a)

-1.5

H2O lim

-2.0
0

10

12

14

16

18

C:\HSC5\EpH\CEpHSD1.EPT

pH

ELEMENTS
S

Molality
1.000E-02

Eh (Volts)
2.0

20

Pressure
1.000E+00

S - H2O - System at 25.00 C

1.5
SO4(-2a)

HSO4(-a)

25

1.0

25

0.5
25

0.0

25

25

-0.5

25
25

H2S(a)

-1.0

25

HS(-a)

25

S(-2a)

-1.5

H2O lim

-2.0
0

10

12

14

16

C:\HSC5\EpH\CEpHSD0.EPT

ELEMENTS

18

20
pH

Molality

Pressure

HS(-a)

25

S(-2a)

-1.5

H2O lim

-2.0
0

10

12

14

16

18

C:\HSC5\EpH\CEpHSD0.EPT

pH

ELEMENTS
S

Molality
1.000E-02

Eh (Volts)
2.0

20

Pressure
1.000E+00

S - H2O - System at 95.00 C

1.5
HSO4(-a)
SO4(-2a)

95

1.0
0.5

95
95

0.0

95

95

-0.5

95

H2S(a)

-1.0

95
95

HS(-a)

95

-1.5

S(-2a)

H2O lim

-2.0
0

10

12

14

16

C:\HSC5\EpH\CEpHSD0.EPT

ELEMENTS
S

18

20
pH

Molality
1.000E-02

Pressure
1.000E+00

Eh (Volts)
2.0

1.5

Hg - S - H2O - Syste

Hg(+2a)

Hg

HgO(

1.0
Hg
Hg2(+2a)

Hg
Hg

Hg

Hg

0.5
Hg

0.0

HgS
Hg

Hg

-0.5

-1.0

S(-2a)
H2O limits

16

18

20

-1.5
-2.0
0

pH

C:\HSC5\EpH\HgS25595.iep

ssure
0E+00

ELEMENTS
Hg
S

Eh (Volts)
2.0

1.5

Molality
1.000E-0
1.000E-0

Hg - S - H2O - Syste

Hg(+2a)

25

HgO(

1.0
25
25
Hg2(+2a)
25

0.5

25

25

25

0.0

HgS
25

25

25

-0.5
-1.0

S(-2a)
H2O limits

-1.5
16

ssure

18

20
pH

-2.0
0

-1.0

S(-2a)
H2O limits

-1.5
16

18

20
-2.0

pH

ssure
0E+00

C:\HSC5\EpH\HgS25595.iep

ELEMENTS
Hg
S

Eh (Volts)
2.0

1.5

Molality
1.000E-0
1.000E-0

Hg - S - H2O - Syste

Hg(+2a)

HgO(

95

1.0
95
95
Hg2(+2a)
95

0.5

95
95

95

HgS

0.0
95

95

95

-0.5
S(-2a)

16

ssure
0E+00

H2O limits

18

20

-1.0
-1.5

pH

-2.0
0

C:\HSC5\EpH\HgS25595.iep

ELEMENTS
Hg
S

Molality
1.000E-0
1.000E-0

Hg - S - H2O - System at 5.00 C

a)

Hg

HgO(a)

HHgO2(-a)
Hg

Hg
(+2a)
Hg

Hg

Hg
Hg

HgS

Hg

Hg

Hg

Hg

Hg

Hg
H2O limits

10

12

14

16

18

\EpH\HgS25595.iep

ELEMENTS
Hg
S

a)

25
+2a)

20
pH

Molality
1.000E-05
1.000E-02

Pressure
1.000E+00
1.000E+00

Hg - S - H2O - System at 25.00 C

25

HgO(a)
25

25

25

HHgO2(-a)

25
25

HgS
25

25

25

25

25

Hg
H2O limits

10

12

14

16

18

20

Hg
H2O limits

10

12

14

16

18

\EpH\HgS25595.iep

ELEMENTS
Hg
S

20
pH

Molality
1.000E-05
1.000E-02

Pressure
1.000E+00
1.000E+00

Hg - S - H2O - System at 95.00 C

2a)

HgO(a)

95

95

(+2a)95

95
95

HHgO2(-a)

95
95

HgS

95

95

95
95
95

Hg
H2O limits

10

12

14

16

\EpH\HgS25595.iep

ELEMENTS
Hg
S

18

20
pH

Molality
1.000E-05
1.000E-02

Pressure
1.000E+00
1.000E+00

Eh (Volts)
2.0

S - Hg - H2O - System at 5.00 C

1.5

HSO4(-a)

SO4(-2a)

1.0
5

0.5

5
5

0.0

HgS
5

-0.5

5
5

-1.0

H2S(a)

HS(-a)

-1.5

O limits

-2.0
0

10

12

14

16

18

C:\HSC5\EpH\HgS25595.iep

ELEMENTS
Hg
S

Eh (Volts)
2.0

Molality
1.000E-05
1.000E-02

Pressure
1.000E+00
1.000E+00

S - Hg - H2O - System at 25.00 C

1.5

25

HSO4(-a)

SO4(-2a)

1.0
25

0.5

25

25
25

0.0

HgS
25

25

-0.5

25

25
25

-1.0

H2S(a)

25

HS(-a)

-1.5

O limits

-2.0
0

10

12

14

16

18

25

-1.0

H2S(a)

25

HS(-a)

-1.5

O limits

-2.0
0

10

12

14

16

18

C:\HSC5\EpH\HgS25595.iep

ELEMENTS
Hg
S

Eh (Volts)
2.0

1.5

Molality
1.000E-05
1.000E-02

Pressure
1.000E+00
1.000E+00

S - Hg - H2O - System at 95.00 C

HSO4(-a)

95

SO4(-2a)

1.0
95

0.5

95
95

95

HgS

0.0

95

95

-0.5
95
95

-1.0

95

H2S(a)
95

-1.5

HS(-a)

O limits

-2.0
0

10

12

14

16

C:\HSC5\EpH\HgS25595.iep

ELEMENTS
Hg
S

Molality
1.000E-05
1.000E-02

Pressure
1.000E+00
1.000E+00

18

Eh (Volts)
2.0

1.5

Hg - S - H2O - Syste

Hg(+2a)
5

HgO(

HSO4(-a)

1.0
5
Hg2(+2a)
5

5
5

0.5

5
5

0.0

HgS
5

-0.5
5

-1.0
HS(-a)

H2S(a)

-1.5
H2O limits

-2.0
12

14

16

18

20

pH

C:\HSC5\EpH\HgS25595.iep

Pressure
1.000E+00
1.000E+00

ELEMENTS
Hg
S

0C

Eh (Volts)
2.0

1.5

Molality
1.000E-0
1.000E-0

Hg - S - H2O - Syste

Hg(+2a)
25

25

HgO(

HSO4(-a)

a)

1.0
25
25
Hg2(+2a)
25
25

0.5

25

25

25
25

25

0.0

HgS
25

25

-0.5
25

-1.0

HS(-a)

H2S(a)

25

-1.5
H2O limits

-2.0
12

14

16

18

20

25

-1.0

HS(-a)

H2S(a)

25

-1.5
H2O limits

-2.0
12

14

16

18

20

pH

C:\HSC5\EpH\HgS25595.iep

Pressure
1.000E+00
1.000E+00

ELEMENTS
Hg
S

0C

Eh (Volts)
2.0

1.5

Molality
1.000E-0
1.000E-0

Hg - S - H2O - Syste

Hg(+2a)

HgO(

95 95

HSO4(-a)

-2a)

1.0
95
95
Hg2(+2a)
95
95

0.5

95
95

95

95

95

HgS

0.0

95

95

-0.5
-1.0

95

H2S(a)
95

-1.5

HS(-a)
H2O limits

-2.0
12

14

16

18

20
pH

Pressure
1.000E+00
1.000E+00

C:\HSC5\EpH\HgS25595.iep

ELEMENTS
Hg
S

Molality
1.000E-0
1.000E-0

Hg - S - H2O - System at 5.00 C

a)

HgO(a)

a)

SO4(-2a)

HHgO2(-a)
5

5
+2a)

5
5

HgS

5
5

H2S(a)

Hg

HS(-a)
H2O limits

10

12

14

16

18

\EpH\HgS25595.iep

pH

ELEMENTS
Hg
S

Molality
1.000E-05
1.000E-02

Pressure
1.000E+00
1.000E+00

Hg - S - H2O - System at 25.00 C

a)

25

25

HgO(a)

a)

SO4(-2a)
25

25
+2a)

25

20

25

25

HHgO2(-a)

25

25
25

25

HgS
25

25

25

25

25
25

H2S(a)

25

Hg

HS(-a)
H2O limits

10

12

14

16

18

20

25

H2S(a)

25

Hg

HS(-a)
H2O limits

10

12

14

16

18

\EpH\HgS25595.iep

20
pH

ELEMENTS
Hg
S

Molality
1.000E-05
1.000E-02

Pressure
1.000E+00
1.000E+00

Hg - S - H2O - System at 95.00 C

2a)

HgO(a)

95 95

-a)

SO4(-2a)
95

95
(+2a)
95

95
95

HHgO2(-a)

95

95
95

95

HgS

95

95

95
95
95
95

H2S(a)
95

Hg
HS(-a)
H2O limits

10

12

14

16

\EpH\HgS25595.iep

ELEMENTS
Hg
S

18

20
pH

Molality
1.000E-05
1.000E-02

Pressure
1.000E+00
1.000E+00

O limits

O limits

O limits

O limits

SISTEMA Hg - H2O
1

Hg(+2a) + H2O = HgO(a) +2H(+a)

deltaH
deltaS
deltaG
kJ
J/K
kJ

1/T

T
K

0.003595182
0.003531697
0.003470415
0.003411223
0.003354016
0.003298697
0.003245173
0.003193358
0.003143171
0.003094538
0.003047387
0.003001651
0.002957267
0.002914177
0.002872325
0.002831658
0.002792126
0.002753683
0.002716284

278.150

39.490

15.123

35.283

283.150

38.360

11.097

35.218

288.150
293.150
298.150
303.150
308.150
313.150
318.150

37.299
36.293
35.334
34.413
33.524
32.662
31.825

7.381
3.921
0.676
-2.388
-5.297
-8.070
-10.723

35.172
35.144
35.132
35.137
35.156
35.189
35.237

323.150
328.150
333.150
338.150
343.150
348.150
353.150
358.150
363.150
368.150

31.010
30.217
29.447
28.694
27.959
27.241
26.541
25.857
25.190
24.541

-13.265
-15.700
-18.030
-20.273
-22.431
-24.507
-26.505
-28.427
-30.276
-32.052

35.297
35.369
35.453
35.549
35.656
35.773
35.901
36.038
36.185
36.341

FM
g/mol

Conc.
wt-%

Amount
mol

Hg(+2a)
H2O

200.590
18.015
g/mol

91.759
8.241
wt-%

1.000
1.000
mol

HgO(a)
H(+a)

216.589
1.008

99.078
0.922

1.000
2.000

Formula

2
1/T

T
K

0.003595182
0.003531697
0.003470415
0.003411223
0.003354016
0.003298697

278.150
283.150
288.150
293.150
298.150
303.150

HgO(a) + H2O = HHgO2(-a) + H(+a)

deltaH
deltaS
deltaG
kJ
J/K
kJ
59.292
58.799
58.320
57.850
57.384
56.916

-88.007
-89.764
-91.440
-93.057
-94.636
-96.190

83.771
84.216
84.669
85.130
85.599
86.076

0.003245173
0.003193358
0.003143171
0.003094538
0.003047387
0.003001651
0.002957267
0.002914177
0.002872325
0.002831658
0.002792126
0.002753683
0.002716284

308.150
313.150
318.150
323.150
328.150
333.150
338.150
343.150
348.150
353.150
358.150
363.150
368.150

56.445
55.968
55.482
54.988
54.484
53.971
53.448
52.912
52.364
51.801
51.223
50.630
50.019

-97.731
-99.268
-100.806
-102.348
-103.896
-105.448
-107.006
-108.578
-110.165
-111.770
-113.394
-115.040
-116.710

86.561
87.054
87.554
88.062
88.577
89.101
89.632
90.171
90.718
91.272
91.835
92.406
92.986

FM

Conc.

Amount

g/mol

wt-%

mol

HgO(a)
H2O

216.589
18.015
g/mol

92.321
7.679
wt-%

1.000
1.000
mol

HHgO2(-a)
H(+a)

233.597
1.008

99.570
0.430

1.000
1.000

Formula

3
1/T

T
K

deltaH
kJ

0.003595182
0.003531697
0.003470415
0.003411223
0.003354016
0.003298697
0.003245173
0.003193358
0.003143171
0.003094538
0.003047387
0.003001651
0.002957267
0.002914177
0.002872325
0.002831658
0.002792126
0.002753683
0.002716284

278.150
283.150
288.150
293.150
298.150
303.150
308.150
313.150
318.150
323.150
328.150
333.150
338.150
343.150
348.150
353.150
358.150
363.150
368.150

-3.873
-3.691
-3.541
-3.414
-3.305
-3.210
-3.124
-3.045
-2.971
-2.901
-2.834
-2.771
-2.710
-2.649
-2.588
-2.527
-2.465
-2.402
-2.337

Hg(+2a) + Hg = Hg2(+2a)
deltaS
deltaG
J/K
kJ
24.000
24.647
25.175
25.611
25.978
26.295
26.575
26.829
27.064
27.283
27.488
27.680
27.862
28.041
28.217
28.391
28.565
28.740
28.917

-10.548
-10.670
-10.795
-10.922
-11.051
-11.181
-11.314
-11.447
-11.582
-11.718
-11.855
-11.993
-12.131
-12.271
-12.412
-12.553
-12.696
-12.839
-12.983

FM
g/mol

Conc.
wt-%

Amount
mol

Hg(+2a)
Hg

200.590
200.590
g/mol

50.000
50.000
wt-%

1.000
1.000
mol

Hg2(+2a)

401.180

100.000

1.000

Formula

Hg2(+2a) + 2e- = 2Hg

deltaS
deltaG
J/K
kJ

1/T

T
K

deltaH
kJ

0.003595182
0.003531697
0.003470415
0.003411223
0.003354016
0.003298697
0.003245173
0.003193358
0.003143171
0.003094538
0.003047387
0.003001651
0.002957267
0.002914177
0.002872325
0.002831658
0.002792126
0.002753683
0.002716284

278.150
283.150
288.150
293.150
298.150
303.150
308.150
313.150
318.150
323.150
328.150
333.150
338.150
343.150
348.150
353.150
358.150
363.150
368.150

-166.253
-166.399
-166.549
-166.703
-166.858
-167.012
-167.163
-167.311
-167.454
-167.592
-167.725
-167.853
-167.976
-168.093
-168.203
-168.306
-168.402
-168.489
-168.569

-42.214
-42.731
-43.259
-43.788
-44.312
-44.824
-45.319
-45.794
-46.247
-46.678
-47.086
-47.474
-47.841
-48.183
-48.502
-48.795
-49.064
-49.308
-49.525

-154.512
-154.299
-154.084
-153.867
-153.646
-153.424
-153.198
-152.970
-152.740
-152.508
-152.274
-152.037
-151.799
-151.559
-151.317
-151.074
-150.829
-150.583
-150.336

Formula

FM
g/mol

Conc.
wt-%

Amount
mol

Hg2(+2a)
e-

401.180
0.001
g/mol

100.000
0.000
wt-%

1.000
2.000
mol

Hg

200.590

100.000

2.000

5
1/T

T
K

0.003595182
0.003531697

278.150
283.150

2e- + 2HgO(a) + 4H(+a) = Hg2(+2a) + 2H2O

deltaH
deltaS
deltaG
kJ
J/K
kJ
-252.978
-250.501

-24.458
-15.631

-246.175
-246.075

0.003470415
0.003411223
0.003354016
0.003298697
0.003245173
0.003193358
0.003143171
0.003094538
0.003047387
0.003001651
0.002957267
0.002914177
0.002872325
0.002831658
0.002792126
0.002753683
0.002716284

288.150
293.150
298.150
303.150
308.150
313.150
318.150
323.150
328.150
333.150
338.150
343.150
348.150
353.150
358.150
363.150
368.150

-248.228
-246.117
-244.136
-242.258
-240.460
-238.726
-237.046
-235.414
-233.827
-232.288
-230.783
-229.308
-227.862
-226.441
-225.046
-223.674
-222.325

-7.671
-0.409
6.292
12.541
18.425
24.006
29.328
34.418
39.291
43.946
48.430
52.760
56.946
60.997
64.921
68.724
72.414

-246.018
-245.998
-246.013
-246.060
-246.137
-246.244
-246.377
-246.536
-246.721
-246.929
-247.160
-247.413
-247.687
-247.982
-248.297
-248.631
-248.984

FM
g/mol

Conc.
wt-%

Amount
mol

eHgO(a)
H(+a)

0.001
216.589
1.008
g/mol

0.000
99.078
0.922
wt-%

2.000
2.000
4.000
mol

Hg2(+2a)
H2O

401.180
18.015

91.759
8.241

1.000
2.000

Formula

6
1/T

T
C

0.003595182
0.003531697
0.003470415
0.003411223
0.003354016
0.003298697
0.003245173
0.003193358
0.003143171
0.003094538
0.003047387
0.003001651
0.002957267
0.002914177

278.150
283.150
288.150
293.150
298.150
303.150
308.150
313.150
318.150
323.150
328.150
333.150
338.150
343.150

HgO(a) + 2H(+a) + 2e- = Hg + H2O

deltaH
deltaS
deltaG
kcal
cal/K
kcal
-209.616
-208.450
-207.389
-206.410
-205.497
-204.635
-203.811
-203.018
-202.250
-201.503
-200.776
-200.071
-199.380
-198.701

-33.336
-29.181
-25.465
-22.099
-19.010
-16.141
-13.447
-10.894
-8.460
-6.130
-3.898
-1.764
0.295
2.289

-200.343
-200.187
-200.051
-199.932
-199.829
-199.742
-199.668
-199.607
-199.559
-199.522
-199.497
-199.483
-199.479
-199.486

0.002872325
0.002831658
0.002792126
0.002753683
0.002716284

348.150
353.150
358.150
363.150
368.150

-198.032
-197.374
-196.724
-196.082
-195.447

4.222
6.101
7.928
9.708
11.445

-199.502
-199.528
-199.563
-199.607
-199.660

FM
g/mol

Conc.
wt-%

Amount
mol

HgO(a)
H(+a)
e-

216.589
1.008
0.001
g/mol

99.077
0.922
0.001
wt-%

1.000
2.000
2.000
mol

Hg
H2O

200.590
18.015

91.759
8.241

1.000
1.000

Formula

7
1/T

T
C

0.003595182
0.003531697
0.003470415
0.003411223
0.003354016
0.003298697
0.003245173
0.003193358
0.003143171
0.003094538
0.003047387
0.003001651
0.002957267
0.002914177
0.002872325
0.002831658
0.002792126
0.002753683
0.002716284

278.150
283.150
288.150
293.150
298.150
303.150
308.150
313.150
318.150
323.150
328.150
333.150
338.150
343.150
348.150
353.150
358.150
363.150
368.150
Formula
HHgO2(-a)
H(+a)
e-

HHgO2(-a) + 3H(+a) + 2e- = Hg + 2H2O

deltaH
deltaS
deltaG
kcal
cal/K
kcal
-268.908
-267.249
-265.709
-264.261
-262.881
-261.551
-260.257
-258.986
-257.732
-256.491
-255.260
-254.041
-252.828
-251.613
-250.396
-249.174
-247.947
-246.711
-245.466

54.671
60.583
65.975
70.959
75.626
80.048
84.284
88.374
92.346
96.218
99.998
103.684
107.300
110.866
114.387
117.871
121.322
124.748
128.155

-284.115
-284.403
-284.720
-285.062
-285.429
-285.818
-286.229
-286.661
-287.112
-287.584
-288.074
-288.584
-289.111
-289.657
-290.220
-290.800
-291.398
-292.014
-292.646

FM
g/mol

Conc.
wt-%

Amount
mol

233.597
1.008
0.001
g/mol

98.722
1.278
0.000
wt-%

1.000
3.000
2.000
mol

Hg
H2O

200.590
18.015

84.773
15.227

1.000
2.000

2O

(a) +2H(+a)
K

Log(K)

2.363E-007

-6.627

3.181E-007

-6.497

4.204E-007
5.463E-007
6.989E-007
8.815E-007
1.097E-006
1.348E-006
1.638E-006

-6.376
-6.263
-6.156
-6.055
-5.960
-5.870
-5.786

1.968E-006
2.342E-006
2.759E-006
3.223E-006
3.732E-006
4.289E-006
4.891E-006
5.540E-006
6.234E-006
6.972E-006

-5.706
-5.630
-5.559
-5.492
-5.428
-5.368
-5.311
-5.256
-5.205
-5.157

Amount
g

Volume
l or ml

200.590
18.015
g

0.000 ml
19.646 ml
l or ml

216.589
2.016

0.000 ml
0.000 ml

B
-1662.499975
25.44946984
0.996032139
4267.424197
3.728354845

A
-0.5916332
0.07961668
0.029558045
17
0.014852527

0.012273849
0.001507538
0.795885172
66.286453
2.146724886

31.51954147
0.488907318
0.179959926
17
0.550554773

2(-a) + H(+a)
K
1.849E-016
2.903E-016
4.470E-016
6.760E-016
1.005E-015
1.470E-015

Log(K)
-15.733
-15.537
-15.350
-15.170
-14.998
-14.833

B
A
-2887.837624 -5.317884661
15.4368917 0.048293111
0.999514474 0.017929031
34996.59775
17
11.24966229 0.005464653

2.117E-015
3.005E-015
4.207E-015
5.812E-015
7.928E-015
1.068E-014
1.423E-014
1.875E-014
2.444E-014
3.153E-014
4.028E-014
5.098E-014
6.393E-014

-14.674
-14.522
-14.376
-14.236
-14.101
-13.971
-13.847
-13.727
-13.612
-13.501
-13.395
-13.293
-13.194

Amount

Volume

l or ml

216.589
18.015
g

0.000 ml
19.646 ml
l or ml

233.597
1.008

0.000 ml
0.000 ml

0.102377409
0.000924384
0.998615973
12266.0007
149.356157

55.09507864
0.299785626
0.110346884
17
0.206999391

B
156.3751257
2.386082516
0.996057525
4295.012445
0.032985972

A
1.413057531
0.007464673
0.002771293
17
0.000130561

-0.027138097
0.000140208
0.999546436
37463.93142
10.49478769

-2.96504677
0.045470621
0.016737098
17
0.004762218

g2(+2a)
K
9.574E+001
9.301E+001
9.057E+001
8.835E+001
8.634E+001
8.449E+001
8.278E+001
8.120E+001
7.974E+001
7.838E+001
7.712E+001
7.594E+001
7.484E+001
7.380E+001
7.284E+001
7.193E+001
7.108E+001
7.029E+001
6.954E+001

Log(K)
1.981
1.969
1.957
1.946
1.936
1.927
1.918
1.910
1.902
1.894
1.887
1.880
1.874
1.868
1.862
1.857
1.852
1.847
1.842

Amount
g

Volume
l or ml

200.590
200.590
g

0.000 ml
14.822 ml
l or ml

401.180

0.000 ml

2Hg
K

E vs. SHE
V

LogK

1.044E+029
2.931E+028
8.592E+027
2.623E+027
8.326E+026
2.742E+026
9.351E+025
3.297E+025
1.200E+025
4.506E+024
1.741E+024
6.917E+023
2.822E+023
1.181E+023
5.067E+022
2.225E+022
9.991E+021
4.585E+021
2.148E+021

0.801
0.800
0.799
0.798
0.797
0.796
0.794
0.793
0.792
0.791
0.790
0.788
0.787
0.786
0.785
0.783
0.782
0.781
0.780

29.019
28.467
27.934
27.419
26.920
26.438
25.971
25.518
25.079
24.654
24.241
23.840
23.451
23.072
22.705
22.347
22.000
21.661
21.332

Amount
g

Volume
l or ml

401.180
0.001
g

0.000 ml
0.000 ml
l or ml

401.180

29.643 ml

B
8747.361913
4.171666102
0.999996134
4396783.79
103.216264

A
-2.420321586
0.013050732
0.004845142
17
0.000399082

0.046487055
0.000246908
0.999520656
35448.12087
30.79490948

-167.4989296
0.080074381
0.029474256
17
0.01476844

g2(+2a) + 2H2O
K
1.713E+046
2.506E+045

Log(K)
V
46.234
45.399

B
A
12385.11211 1.589059876
51.49212196 0.161089085

3.988E+044
6.863E+043
1.270E+043
2.519E+042
5.325E+041
1.196E+041
2.845E+040
7.145E+039
1.888E+039
5.239E+038
1.522E+038
4.620E+037
1.462E+037
4.811E+036
1.645E+036
5.828E+035
2.137E+035

44.601
43.836
43.104
42.401
41.726
41.078
40.454
39.854
39.276
38.719
38.182
37.665
37.165
36.682
36.216
35.766
35.330

Amount
g

Volume
l or ml

0.001
433.179
4.032
g

0.000 ml
0.000 ml
0.000 ml
l or ml

401.180
36.030

0.000 ml
39.292 ml

0.999706233 0.059805037
57851.99049
17
206.9158833 0.060802921
-0.032336837 -236.4681061
0.003048194 0.988554921
0.868767163 0.3638732
112.5407492
17
14.90081221 2.250862991

= Hg + H2O
K

E vs. SHE
V

Log(K)

4.229E+037
8.571E+036
1.851E+036
4.243E+035
1.029E+035
2.628E+034
7.056E+033
1.986E+033
5.845E+032
1.794E+032
5.734E+031
1.904E+031
6.554E+030
2.336E+030

1.039
1.038
1.037
1.037
1.036
1.036
1.035
1.035
1.035
1.035
1.035
1.034
1.034
1.034

37.626
36.933
36.267
35.628
35.012
34.420
33.849
33.298
32.767
32.254
31.758
31.280
30.817
30.368

10566.23701
23.66054737
0.999914764
199430.2902
150.603353

-0.415630855
0.074020176
0.027480318
17
0.012837854

0.007075109
0.001400662
0.60014333
25.5152343
0.713314624

-201.9835178
0.454246423
0.167201737
17
0.475259152

8.606E+029
3.272E+029
1.282E+029
5.169E+028
2.143E+028

1.035
1.035
1.035
1.035
1.035

Amount
g

Volume
l or ml

216.589
2.016
0.001
g

0.000 ml
0.000 ml
0.000 ml
l or ml

200.590
18.015

14.822 ml
19.646 ml

29.935
29.515
29.108
28.713
28.331

= Hg + 2H2O
K

E vs. SHE
V

Log(K)

2.287E+053
2.952E+052
4.141E+051
6.277E+050
1.023E+050
1.788E+049
3.333E+048
6.608E+047
1.389E+047
3.087E+046
7.232E+045
1.782E+045
4.605E+044
1.246E+044
3.521E+043
1.038E+043
3.182E+042
1.014E+042
3.352E+041

1.473
1.475
1.476
1.478
1.480
1.482
1.484
1.487
1.489
1.491
1.494
1.496
1.499
1.502
1.505
1.508
1.511
1.514
1.518

53.359
52.470
51.617
50.798
50.010
49.252
48.523
47.820
47.143
46.490
45.859
45.251
44.663
44.095
43.547
43.016
42.503
42.006
41.525

Amount
g

Volume
l or ml

233.597
3.024
0.001
g

0.000 ml
0.000 ml
0.000 ml
l or ml

13454.07464
39.06961736
0.999856663
118584.8885
244.1752325

4.902253805
0.122226249
0.045377037
17
0.035004283

-0.0953023
0.002323402
0.98999713
1682.512206
129.426029

-257.0785965
0.753498573
0.277352255
17
1.307712648

200.590
36.030

14.822 ml
39.292 ml

2,303
8,314
1.00E+09

T5
T25
T95

278
298
368

log=(^0)/(2.303)

1
2
3
4
5
6
7

LogK=
A + B*(1/T)
B
A
-1662.5000
-0.5916
-2887.8376
-5.3179
8747.3619
12385.1121
10566.2370
13454.0746

-2.4203
1.5891
-0.4156
4.9023

G=
B

A + B*T
A

-0.0271

-2.9650

LogK
5C
-6.5718
-15.7058
-1.9744
29.0450
46.1398
37.5924
53.2982

LogK
25C
-6.1705
-15.0086
-1.9370
26.9332
43.1498
35.0415
50.0502

LogK
95C
-5.1093
-13.1653
-1.8381
21.3497
35.2443
28.2970
41.4622

SISTEMA Hg - S - H2O
1

HSO4(-a) + Hg + 7H(+a) + 6e- = HgS + 4H2O

T
deltaH
deltaS
K
kJ
J/K
278.150
283.150
288.150
293.150
298.150
303.150
308.150
313.150
318.150
323.150
328.150
333.150
338.150
343.150
348.150
353.150
358.150
363.150
368.150

deltaG
kJ

-317.579
-316.457
-315.361
-314.284
-313.220
-312.163
-311.108
-310.051
-308.990
-307.925
-306.854
-305.778
-304.696
-303.605
-302.504
-301.393
-300.270
-299.135
-297.987

-243.583
-239.585
-235.749
-232.044
-228.445
-224.930
-221.477
-218.074
-214.714
-211.391
-208.102
-204.849
-201.625
-198.421
-195.237
-192.068
-188.912
-185.765
-182.625

-249.826
-248.618
-247.430
-246.260
-245.109
-243.976
-242.860
-241.761
-240.679
-239.614
-238.565
-237.533
-236.517
-235.516
-234.532
-233.564
-232.612
-231.675
-230.754

Formula

FM
g/mol

Conc.
wt-%

Amount
mol

HSO4(-a)
Hg
H(+a)
e-

97.066
200.590
1.008
0.001
g/mol

31.855
65.829
2.315
0.001
wt-%

1.000
1.000
7.000
6.000
mol

HgS
H2O

232.650
18.015

76.351
23.649

1.000
4.000

SO4(-2a) + Hg + 8H(+a) + 6e- = HgS + 4H2O

T
deltaH
deltaS
K
kJ
J/K

deltaG
kJ

278.150
283.150
288.150
293.150
298.150
303.150

-303.944
-300.834
-297.961
-295.271
-292.718
-290.266

-160.784
-149.701
-139.644
-130.388
-121.753
-113.594

-259.222
-258.446
-257.723
-257.048
-256.418
-255.830

308.150
313.150
318.150
323.150
328.150
333.150
338.150
343.150
348.150
353.150
358.150
363.150
368.150

-287.882
-285.545
-283.241
-280.960
-278.700
-276.463
-274.235
-272.005
-269.769
-267.524
-265.266
-262.991
-260.696

-105.793
-98.271
-90.971
-83.858
-76.918
-70.153
-63.515
-56.968
-50.499
-44.096
-37.747
-31.439
-25.162

-255.281
-254.771
-254.298
-253.861
-253.459
-253.092
-252.758
-252.457
-252.188
-251.951
-251.747
-251.574
-251.432

FM

Conc.

Amount

g/mol

wt-%

mol

SO4(-2a)
Hg
H(+a)
e-

96.058
200.590
1.008
0.001
g/mol

31.524
65.829
2.646
0.001
wt-%

1.000
1.000
8.000
6.000
mol

HgS
H2O

232.650
18.015

76.351
23.649

1.000
4.000

HgS + 2H(+a) + 2e- = H2S(a) + Hg

T
deltaH
K
kJ

deltaS
J/K

deltaG
kJ

-25.670
-22.358
-19.450
-16.848
-14.491
-12.331
-10.328
-8.455
-6.692
-5.022
-3.431
-1.909
-0.448
0.960
2.322
3.642
4.926

23.221
23.341
23.445
23.536
23.614
23.681
23.738
23.785
23.823
23.852
23.873
23.886
23.892
23.891
23.883
23.868
23.846

Formula

278.150
283.150
288.150
293.150
298.150
303.150
308.150
313.150
318.150
323.150
328.150
333.150
338.150
343.150
348.150
353.150
358.150

16.081
17.010
17.841
18.597
19.294
19.943
20.555
21.137
21.694
22.229
22.747
23.250
23.741
24.220
24.691
25.154
25.610

363.150
368.150

26.061
26.508

6.176
7.398

23.818
23.785

FM
g/mol

Conc.
wt-%

Amount
mol

HgS
H(+a)
e-

232.650
1.008
0.001
g/mol

99.141
0.859
0.000
wt-%

1.000
2.000
2.000
mol

H2S(a)
Hg

34.076
200.590

14.521
85.479

1.000
1.000

HgS + H(+a) + 2e- = HS(-a) + Hg

T
deltaH
K
kJ

deltaS
J/K

deltaG
kJ

46.172
45.247
44.405
43.625
42.892
42.190
41.511
40.846
40.190
39.541
38.895
38.256
37.617
36.974
36.326
35.672
35.010
34.339
33.657

-60.383
-63.678
-66.627
-69.309
-71.792
-74.125
-76.348
-78.487
-80.565
-82.592
-84.573
-86.508
-88.412
-90.299
-92.173
-94.039
-95.900
-97.761
-99.626

62.967
63.278
63.604
63.943
64.296
64.661
65.037
65.424
65.822
66.230
66.648
67.076
67.513
67.960
68.416
68.881
69.356
69.840
70.334

FM
g/mol

Conc.
wt-%

Amount
mol

HgS
H(+a)
e-

232.650
1.008
0.001
g/mol

99.568
0.431
0.000
wt-%

1.000
1.000
2.000
mol

HS(-a)
Hg

33.068
200.590

14.152
85.848

1.000
1.000

Formula

278.150
283.150
288.150
293.150
298.150
303.150
308.150
313.150
318.150
323.150
328.150
333.150
338.150
343.150
348.150
353.150
358.150
363.150
368.150
Formula

H2O
K

E vs. SHE
V

8.308E+046
7.381E+045
7.191E+044
7.644E+043
8.825E+042
1.102E+042
1.482E+041
2.138E+040
3.300E+039
5.431E+038
9.501E+037
1.762E+037
3.453E+036
7.137E+035
1.552E+035
3.544E+034
8.477E+033
2.120E+033
5.534E+032

0.432
0.430
0.428
0.426
0.424
0.422
0.420
0.418
0.416
0.414
0.412
0.411
0.409
0.407
0.405
0.404
0.402
0.400
0.399

Amount
g

Volume
l or ml

97.066
200.590
7.055
0.003
g

0.000 ml
14.822 ml
0.000 ml
0.000 ml
l or ml

232.650
72.061

28.476 ml
78.583 ml

E vs. SHE
V

4.831E+048
4.800E+047
5.282E+046
6.392E+045
8.455E+044
1.215E+044

0.448
0.447
0.445
0.444
0.443
0.442

1.890E+043
3.165E+042
5.686E+041
1.092E+041
2.233E+040
4.849E+039
1.115E+039
2.706E+038
6.920E+037
1.860E+037
5.239E+036
1.545E+036
4.756E+035

0.441
0.440
0.440
0.439
0.438
0.437
0.437
0.436
0.436
0.436
0.435
0.435
0.435

Amount

Volume

l or ml

96.058
200.590
8.063
0.003
g

0.000 ml
14.822 ml
0.000 ml
0.000 ml
l or ml

232.650
72.061

28.476 ml
78.583 ml

E vs. SHE
V

4.354E-005
4.940E-005
5.618E-005
6.396E-005
7.287E-005
8.303E-005
9.459E-005
1.077E-004
1.226E-004
1.394E-004
1.583E-004
1.797E-004
2.037E-004
2.307E-004
2.609E-004
2.947E-004
3.325E-004

-0.120
-0.121
-0.122
-0.122
-0.122
-0.123
-0.123
-0.123
-0.124
-0.124
-0.124
-0.124
-0.124
-0.124
-0.124
-0.124
-0.124

3.747E-004
4.218E-004

-0.124
-0.123

Amount
g

Volume
l or ml

232.650
2.016
0.001
g

28.476 ml
0.000 ml
0.000 ml
l or ml

34.076
200.590

0.000 ml
14.822 ml

E vs. SHE
V

1.493E-012
2.117E-012
2.946E-012
4.030E-012
5.428E-012
7.204E-012
9.431E-012
1.219E-011
1.557E-011
1.966E-011
2.456E-011
3.036E-011
3.718E-011
4.511E-011
5.425E-011
6.469E-011
7.653E-011
8.984E-011
1.047E-010

-0.327
-0.328
-0.330
-0.332
-0.333
-0.335
-0.337
-0.339
-0.341
-0.343
-0.346
-0.348
-0.350
-0.352
-0.355
-0.357
-0.360
-0.362
-0.365

Amount
g

Volume
l or ml

232.650
1.008
0.001
g

28.476 ml
0.000 ml
0.000 ml
l or ml

33.068
200.590

0.000 ml
14.822 ml

C:\HSC6\EpH\Hg25.iep
Temperature
= 25.000 C
Delta G of H2O
= -56.678 kcal/mol
Dielectric Constant = 78.382
Ion Strenght
= 0.000
pH min V min pH max V max
0.000 -2.000 20.000 2.000
ELEMENTS
Hg
SPECIES
Hg
HHgO2(-a)
Hg(+2a)
Hg2(+2a)
HgO(a)
Hg(OH)2(a)
HgOH(+a)
LABELS
Hg
HHgO2(-a)
Hg(+2a)
Hg2(+2a)
HgO(a)
LINES
Hg
Hg
Hg
Hg
Hg
Hg
HHgO2(-a)
HHgO2(-a)
HHgO2(-a)
HHgO2(-a)
Hg(+2a)
Hg(+2a)
Hg(+2a)
Hg(+2a)
Hg2(+2a)

Molality Pressure
0.000
1.000
DeltaG / T1
kcal/mol
0.000
-45.137
39.364
36.722
-8.918
-64.559
-12.652

Hg
HHgO2(-a)
Hg(+2a)
Hg2(+2a)
HgO(a)
Hg(OH)2(a)
HgOH(+a)

Area No
X pH
YV
1
10.000
-1.478
2
17.498
1.011
3
1.539
1.245
4
2.098
0.610
5
9.037
1.188
Area No
X1 pH
Y1 V
X2 pH
Y2 V
1
20.000
-0.473
14.996
-0.029
1
14.996
-0.029
4.196
0.610
1
4.196
0.610
0.000
0.610
1
0.000
-2.000
0.000
0.610
1
20.000
-0.473
20.000
-2.000
1
20.000
-2.000
0.000
-2.000
2
20.000
-0.473
14.996
-0.029
2
14.996
-0.029
14.996
2.000
2
14.996
2.000
20.000
2.000
2
20.000
2.000
20.000
-0.473
3
3.077
2.000
3.077
0.742
3
3.077
0.742
0.000
0.742
3
0.000
0.742
0.000
2.000
3
0.000
2.000
3.077
2.000
4
0.000
0.742
3.077
0.742

Hg2(+2a)
Hg2(+2a)
Hg2(+2a)
HgO(a)
HgO(a)
HgO(a)
HgO(a)
HgO(a)
3.07706999778748
3.07706999778748
14.9961004257202

4
4
4
5
5
5
5
5

3.077
0.742
4.196
0.610
4.196
0.610
0.000
0.610
0.000
0.610
0.000
0.742
14.996
2.000
14.996
-0.029
14.996
-0.029
4.196
0.610
4.196
0.610
3.077
0.742
3.077
0.742
3.077
2.000
3.077
2.000
14.996
2.000
0
0.000
0.000
0.000
0.000
0
0.000
0.000
0.000
0.000
0
0.000
0.000
0.000
0.000

25

95

0.000
-45.137
39.363
36.722
-8.918
-64.559
-12.652

0.000
-47.023
39.450
36.929
-9.581
-65.909
-13.199

0.000
-38.064
39.034
35.931
-6.284
-59.625
-11.070

Hg
HgS
HgSO4
S
HHgO2(-a)
H2S(a)
HS(-a)
HSO4(-a)
Hg(+2a)
Hg2(+2a)
HgO(a)
Hg(OH)2(a)
SO4(-2a)

25

95

0.000
-12.480
-131.179
0.000
-45.137
-6.607
2.973
-180.524
39.363
36.722
-8.918
-64.559
-177.907

0.000
-12.588
-132.494
0.000
-47.023
-6.807
2.541
-182.619
39.450
36.929
-9.581
-65.909
-180.488

0.000
-12.096
-126.565
0.000
-38.064
-6.190
4.820
-172.978
39.034
35.931
-6.284
-59.625
-168.017