9

9.1

PV T , P, N1, N 2 = Ni RT

Vi (T , P, x) = V i (T , P)

U T , P, N1, N 2 = Ni U i (T , P) Ui (T , P, x) = U i (T , P)

Also Si (T , P, x ) = S i (T , P) R ln xi

x U (T , P, x ) U (T , P ) = x [0] = 0
V = x V (T , P, x ) V (T , P ) = x [ 0] = 0

mix U =

mix

mix H = mix U + mix V = 0

x S (T , P, x ) S (T , P ) = x [ R ln x ] = R x ln x
G = x G (T , P, x ) G (T , P ) = x ( H TS ) ( H T S )
= x (H H ) T x (S S )
= H T S = RT x ln x

mix S =

mix

mix

mix

Similarly
mix A = mix U T mix S = RT

x ln x
i