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Molar mass

12.01 CO2
1 CH4
14.01 CO
32.07 H2
16 H2O
75.929 CaCO3
28.02 SO2

C
H
N
S
O
Ash
N2
O2

32 CaSO3

CA(OH)2

74 NH3

Feed

C
H
N
S
O
Ash
H2O
H2
CH4
CO
CO2
N2
SO2
O2
Ca(OH)2
CaCO3
CaSO3
Purge
NH3
Total
Vol Flow (m3/h)
Average MW
Temp(C)
Pressure(Mpa)
Density

11415.5 empty fruit bunch entering crusher

Mass fraction
0.3273
0.0422
0.0047
0.0014
0.2457
0.0288
0.35
0
0
0
0
0
0
0
0
0
0
0
0
1

Stream 1
Mass (kg/h)
3736.29
481.73
53.65
15.98
2804.79
328.77
3995.43
0
0
0
0
0
0
0
0
0
0
0
0
11416.64155

44
16
28
2
18
100
64
120.2
31.02

fruit bunch entering crusher


Stream 1
Mol Fraction
0.20
0.00
0.00
0.00
0.20
0.11
0.49
0
0
0
0
0
0
0
0
0
0
0
0
1

Mole (kmol/h)
44872.88
481.73
751.68
512.53
44876.61
24962.90
111951.81
0
0
0
0
0
0
0
0
0
0
0
0
228410.1504646

feed entering dryer

Mass fraction
0.3273
0.0422
0.0047
0.0014
0.2457
0.0288
0.3500
0
0
0
0
0
0
0
0
0
0
0
0
1

Stream 2
Mass (kg/h) Mol Fraction
3736.29
0.20
481.73
0.00
53.65
0.00
15.98
0.00
2804.79
0.20
328.77
0.11
3995.43
0.49
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
11416.64155
1

Stream 1
Feed
C
H
N
S
O
Ash

10502.3
0.5036
0.0649
0.0072
0.0021
0.3779
0.0443

water out of dryer

Mole (kmol/h)
Mass fraction
44872.88
0.3273
481.73
0.0422
751.68
0.0047
512.53
0.0014
44876.61
0.2457
24962.90
0.0288
111951.81
0.35
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
228410.1504646
1

Stream 3
Mass (kg/h) Mol
0
0
0
0
0
0
3995.425
0
0
0
0
0
0
0
0
0
0
0
0
3995.425

Fraction
0
0
0
0
0
0
1
0
0
0
0
0
0
0
0
0
0
0
0
1

Mole (kmol/h)
0
0
0
0
0
0
111951.8085
0
0
0
0
0
0
0
0
0
0
0
0
111951.8085

kg/h

Syngas
H2
CH4
CO
CO2
N2
SO2
O2

0.3802
0.1472
0.2636
0.105
0.0285
0.0705

Air suppied
oxygen in air
N2 in air
Gasifier Conversion
Yield of Syngas from crude gas
Crude gas recycled
Ash produced
Haber process reactor conversion

0.005

Product of hammer mill/ feed of reactor


(gasification)
Stream 4,5
Mass fraction Mass (kg/h) Mol Fraction
0.5035
3736.29
0.39
0.0649
481.73
0.00
0.0072
53.65
0.01
0.0022
15.98
0.00
0.3779
2804.79
0.39
0.0443
328.77
0.21
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1
7421.217
1

Air supplied into reactor (gasification)


Stream 6
Mole (kmol/h)
Mass fraction
44872.88
0
481.73
0
751.68
0
512.53
0
44876.61
0
24962.90
0
0
0
0
0
0
0
0
0
0
0
0
0.79
0
0
0
0.21
0
0
0
0
0
0
0
0
0
0
116458.3419646
1

er Conversion
f Syngas from crude gas
gas recycled
process reactor conversion

pplied into reactor (gasification)


Stream 6
Mass (kg/h)
Mol Fraction
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
182.529974
0.34135
0
0
48.520626
0.659513338
0
0
0
0
0
0
0
0
0
0
231.0506
1.000863338

0.022
21%
79%
85%
98%
2%
15%
90%

C+O2 = CO2
C+(1/2)O2 = CO
C+CO 2 = 2CO
C+H2O = CO+ H2
C+ 2H2 = CH4
CO + H2O = CO2 +H2

temperature of reactor (gasificatio


Pressure in the reactor

crude gas entering cyclone

Mole (kmol/h) Mass fraction


0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0.3802
0
0.1472
0
0.2636
0
0.105
144.19867946
0.0285
0
0.0705
10.18933146
0.005
0
0
0
0
0
0
0
0
0
0
154.38801092
1

Stream 7
Mass (kg/h)
0
0
0
0
0
0
0
3394.028291
1314.047776
2353.145338
937.330275
254.4182175
629.3503275
44.634775
0
0
0
0
0
8926.955

/2)O2 = CO
O 2 = 2CO
2O = CO+ H2
H2 = CH4
H2O = CO2 +H2

erature of reactor (gasification )


ure in the reactor

800 degree C
3.45 Mpa

ash flowing out of reactor


Stream 7
Mol Fraction
0
0
0
0
0
0
0
0.0005892703
0.0121761174
0.0118989675
0.0469418317
0.1101336228
0.1016921692
0.716929793
0
0
0
0
0
1.0003617719

Mole (kmol/h) Mass fraction


0
0
0
0
0
0
0
0
0
0
0
1
0
0
1290.40955624
0
193.427832627
0
620.289111097
0
98.419678875
0
7.2509191988
0
44.3691980888
0
0.223173875
0
0
0
0
0
0
0
0
0
0
0
2254.38947
1

Stream 8
Mass (kg/h) Mol Fraction
0
0
0
0
0
0
0
0
0
0
1904.1114
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1904.1114
1

syngas out from cyclone

8
Mole (kmol/h)
0
0
0
0
0
1904.1114
0
0
0
0
0
0
0
0
0
0
0
0
0
1904.1114

Mass fraction
0
0
0
0
0
0
0
0.3802
0.1472
0.2636
0.105
0.0285
0.0705
0.005
0
0
0
0
0
1

Stream 9
Mass (kg/h)
Mol Fraction
0
0
0
0
0
0
0
0
0
0
0
0
0
0
3326.1477252 0.0006012962
1287.7668205 0.0124246096
2306.0824312 0.0121418036
918.5836695 0.0478998282
249.32985315 0.1123812478
616.76332095 0.1037675196
43.7420795 0.7315610132
0
0
0
0
0
0
0
0
0
0
8748.4159 1.0207773183

Mole (kmol/h)
0
0
0
0
0
0
0
1264.60136511
189.559275975
607.883328875
96.4512852975
7.1059008148
43.481814127
0.2187103975
0
0
0
0
0
2209.3016806

0.98
0.98
0.98
0.98

crude gas recycled

Ht out

Stream 10
Stream 11
Mass fraction
Mass (kg/h)Mol Fraction Mole (kmol/h)Mass fraction
Mass (kg/h)Mol Fraction
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0.3802 67.88057 0.029464 25.8081911248 0.3802 3326.148 0.086252
0.1472 26.28096 0.608806 3.8685566525 0.1472 1287.767 0.453717
0.2636 47.06291 0.594948 12.4057822219 0.2636 2306.082 0.004271
0.105
18.74661 0.426059 1.9683935775
0.105
918.5837 0.001083
0.0285 5.088364 0.181598 0.145018384
0.0285 249.3299 0.000461
0.0705 12.58701 0.196672 0.8873839618 0.0705 616.7633 0.0005
0.005
0.892696 0.027897 0.0044634775
0.005
43.74208 0.453717
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1
178.5391
1
45.0877894
1
8748.416
1

155
2.33

m 11

Ca(OH)2(aq) + CO2(g) = CaCO3(s) + H2O(l)


Ca(OH)2(aq) + SO2(g) = CaSO3(s) + H2O(l)
Ca(OH)2(aq) + CO(g) = CaCO3(s) + H2(g)
CH4(g) + 2H2O(g) = CO2(g) +4H2(g)
Oh srubber out

CW in

Stream 12
Mole (kmol/h)
Mass fraction
Mass (kg/h)Mol Fraction
Mole (kmol/h)
Mass
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1663.074 0.98335 17308.32 0.497038 8654.16
8748.416
0
0
0
0
82.36009
0
0
0
0
20.8769
0
0
0
0
8.898282 0.014165 249.3299 0.000511 8.898282
9.636927
0
0
0
0
8748.416 0.002485 43.74208 0.502451 8748.416
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
19281.68
1
17601.39
1
17411.47

35
0.101

Stream 13
fraction
Mass (kg/h)Mol Fraction
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1
25200
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1
25200
1

115.6
1.01

m 13

RCW out

OH in

Stream 14
Mole (kmol/h)
Mass fraction
Mass (kg/h)Mol Fraction
Mole (kmol/h)
Mass
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1400
1
25200
1
1400
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1400
1
25200
1
1400

153.3
0.54

Stream 15
fraction
Mass (kg/h)Mol Fraction
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1
28000
1
0
0
0
0
0
0
0
0
0
0
0
0
1
28000
1

27
0.5

m 15

Oh out

N2 in

Stream 16
Mole (kmol/h)Mass fraction Mass (kg/h) Mol Fraction
Mole (kmol/h) Mass fraction
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0.0317865986 538.2639342 0.093447647
29.9035519
0
0
0
0
0
0
0
0
0.2893118515 4899.112904 0.546770418
174.968318
0
0
0.0027236644 46.12164862 0.005147453 1.6472017366
0
0
0.0010849194 18.37167339 0.001304793 0.4175380316
0
0
0
0
0
0
1
0
0.0007284459 12.33526642 0.000602302 0.1927385378
0
0
0
0
0
0
0
378.3784 0.0098651588 167.0533946 0.007054548 2.257478306
0
0
0.5974618498 10117.22486 0.316160053 101.1722486414
0
0
0.0670375114 1135.19144 0.029512788 9.444188352
0
0
0
0
0
0
0
0
0
0
0
0
0
378.3784
1
16933.67513
1
320.0032635054
1

35
0.33

27
0.101325

Strea

Befor Compressor
Stream 17
Stream 18
Mass (kg/h) Mol FractionMole (kmol/h)Mass fraction
Mass (kg/h)Mol FractionMole (kmol/h)
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0.748581 17308.32 0.97661 8654.16047
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
5520.110458
1
197.00608345 0.249527 5769.44 0.023236 205.904365
0
0
0
0
0
0
0
0
0
0
0.001892 43.74208 0.000154 1.36693998
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
5520.110458
1
197.00608345
1
23121.5
1
8861.43177

27
0.101

N2 + 3H2 = 2NH3

Ratio

N2:NH3=1:2
H2:NH3=3:2

After compressor

After HB Reactor

Stream 19
Stream 20
Mass fraction Mass (kg/h)
Mol Fraction
Mole (kmol/h) Mass fraction Mass (kg/h)
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0.74858112 17308.32093 0.9766097274 8654.16046709
0.075
865.416
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0.24952704 5769.440311 0.0232360154 205.904365146
0.025
288.472
0
0
0
0
0
0
0.00189184 43.7420795 0.0001542572 1.3669399844
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0.9
10384.99
1
23121.50333
1
8861.43177222
1
11538.88

425
20.265

425
20.265

After Cooler

After separator (Recycle)

Stream 20
Stream 21
Mol Fraction
Mole (kmol/h)
Mass fraction
Mass (kg/h)Mol FractionMole (kmol/h)
Mass fraction
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0.556332 432.708
0.075
865.416 0.556332 432.7080234
0.75
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0.013237 10.29522
0.025
288.472 0.013237 10.29521826
0.25
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0.430431 334.7838
0.9
10384.99 0.430431 334.7837705
0
1
777.787
1
11538.88
1
777.7870121
1

100
18.265

100
18.265

Stream 22

fter separator (Recycle)

After separator (Product)

Stream 22
Mass (kg/h)Mol Fraction
Mole (kmol/h)
Mass
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
865.416 0.97676 432.708
0
0
0
0
0
0
0
0
0
288.472 0.02324 10.29522
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1153.888
1
443.0032

Stream 23
fraction
Mass (kg/h)Mol Fraction
Mole (kmol/h)
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1
10384.99
1
334.7838
1
10384.99
1
334.7838

100
18.265

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