FA 3 is 2.00 mol dm’ hydrochloric acid, HCL FA 4is 1.00 moldm sodium hydroxide, NaOH FA Sis 1.00mol dm sodium carbonate, Na,CO, You are to determine, by experiment, the enthalpy change, AH, for the reaction NaOH(aq) + HCl(aq) + NaCilaq) + H,0()) ‘and the enthalpy change, AH, for the reaction Na,OO,laq) + 2HClaq) > 2NaClaq) + COQ) + HO) ‘You are then to use the results of your experiments to calculate the enthalpy change, AH, for the reaction 2NaOH{aq) + CO,(g) + Na,CO,(aq) + H,0()) Experiment 1 Place a plastic cup inside a 250 cm® beaker for stability, Using a measuring cylinder, place 40.0cm® of FA 4, aqueous sodium hydroxide, into the plastic cup. Measure and record the temperature of FA 4 in Table 2. Place 50.0 cm’ of FA 3, hydrochloric acid, into a second measuring cylinder. Measure and record the temperature of FA 3 in Table 2.1. Tip the acid from the second measuring cylinder into the plastic cup, stir carefully and measure the maximum temperature obtained. Record this temperature in Table 2.1. Table 2.1 Initial temperature of FA 4 rec Tt Initial temperature of FA 3 1c Average temperature of FA 4 and FA 3 1°C Maximum temperature after reaction 10 ‘Temperature rise during reaction FG. 1) (a) Calculate the heat produced in the cup during the reaction of aqueous sodium hydroxide and hydrochloric acid, [You may assume that 4.3 J are required to raise the temperature of 1 cm of solution by 1°C] AG = (Hors9) >)6T 3 t ar a5 (b) By reference to the volumes used, the concentrations of the solutions and the equation for the reaction, show which of the reagents FA 3 or FA 4 was in excess. ameuntel ef2 > {0-0 X>9°= O-1yo mol 790° =o ote? wel Arreumbof FAY > \oe “00 yl SPAS Ss txeeegs mM | {c) Calculate AH, for the reaction NaOH(aq) + HCl(aq) > NaCl(aq) + H,0()) Give your answer correct to 8 significant figures and include the correct sign and units. ath ; Neot + Hey 4&5 Nell-+ Uy Hy ORI bd mal” *eay 2] [Turn overExperiment 2 Empty and rinse the plastic cup used in Experiment 1. Replace the cup in the 20cm? beaker. Rinse the measuring cylinder used for FA 4 and use it to place 40.0cm® of FA 8, aqueous Sodium carbonate, into the plastic cup. Measure and record the temperature of FA 5 in Table 2.2, Place 60.0cm$ of FA 3, hydrochloric acid, into a second measuring cylinder. Measure and tecord the temperature of FA 3 in Table 2.2. Carefully pour the acid from the second measuring cylinder into the plastic cup, stir carefully and measure the maximum temperature obtained. Record this temperature in Table 2.2. Table 2.2 Initial temperature of FA 5 ic} TA Initial temperature of FA 3 °C iA ‘Average temperature of FA § and FA 3 aCe Maximum temperature after reaction ro}. Th Temperature rise during reaction VC | AGE Ty -Te (6) (@) Calculate the heat produced in the cup during the reaction of aqueous sodium carbonate and hydrochloric acid, (You may assume that 4.3J are required to raise the temperature of 1 cm? of solution by 1°C] BR, > (40S) #48 X 6G (1) (e) By reference to the volumes used, the concentrations of the solutions and the equation for the reaction, show which of the reagents FA 3 or FA 5 was in excess. wp of Fre we x | (a AD ts Opes) (] o>(f) Calculate AH, for the reaction Na,CO,(aq) + 2HCl{aq) > 2NaClfaq) + CO,(a) + H,0() Give your answer correct to 3 significant figures and include the correct sign and units, bu,- Fhe (c) ma(! —- Aca Ar) 4 (g)_Use the equations NaOH(aq) + HCl{aq) > NaCifaq) + H,0() Na,CO,(aq) + 2HCl{aq) > 2NaClaq) + CO,{9) + H,0()) and the calculated values of AH, and AH, to calculate the enthalpy change for the reaction oll 2NaOH(aq) + CO,(g) +°Na,CO,(aq) + H,0() Dat\, J ul 2NGA CV, t U0 es -. GUz 4 SH 26H ou, = 14h Stat ZONK we J @ = 3b ad -- 644 ° Uy 44 Key lo, (4 it (ha Sue Mh For the reaction oh sty 2NaOH(aq) + CO,(g) > Na,CO,(s) + H,0(!) The enthalpy change is... [Total : 32] esanuo0ena [Turn over