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PROPERTIES
OF CERAMIC
Concept of . Stress-Strain
Behavior
Stress the resistance of a material when subjected to
external loading.
Stress F/A
Different types of forces or stresses that are encountered in
dealing with mechanical properties of materials
can be tensile, compressive, shear or torsional.
stronger the material the greater the load it can withstand.
Strain the change of length per unit length
Stress as a cause; strain as the effect
Mechanical Properties
Mechanical behavior are generally
dened as the modes of deformation
and modes of failure
The degree to which a structure
deforms or strains depends on the
magnitude of an imposed stress
Mode of deformation elastic and
plastic deformation
Mode of failure ductile and brittle
Elastic deformation
Deformation in which stress and
strain are proportional is called
elastic deformation
a plot of stress (ordinate) versus
strain (abscissa) results in a
linear relationship;
The slope of this linear
relationship E is the modulus
of elasticity, or Youngs modulus.
This modulus may be thought of
as stiffness, or a materials
resistance to elastic
deformation.
The greater the modulus, the
stiffer the material, or the
Elastic deformation
nonpermanent
when the applied load is released, the
piece returns to its original shape.
Application of the load corresponds to
moving from the origin up and along the
straight line. Upon release of the load, the
line is traversed in the opposite direction,
back to the origin
On an atomic scale, macroscopic elastic
strain is manifested as small changes in
the interatomic spacing and the
stretching of interatomic bonds.
As a consequence, the magnitude of the
modulus of elasticity is a measure of the
resistance to separation of adjacent
atoms, that is, the interatomic bonding
forces
Elastic Deformation
1. Initial
2. Small load
3. Unload
bonds
stretch
return to
initial
Linearelastic
Non-Linearelastic
Plastic deformation
For some materials, elastic
deformation persists only to
certain value of strains
As the material is deformed
beyond this point, the stress
is no longer proportional to
strain and permanent,
nonrecoverable, or plastic
deformation occurs
Plastic deformation
From an atomic perspective, plastic deformation corresponds to
the breaking of bonds with original atom neighbors and then
reforming bonds with new neighbors
large numbers of atoms or molecules move relative to one
Plastic deformation corresponds to the motion of large numbers of
dislocations.
net movement of large numbers of atoms in response to an
applied stress
During this process, interatomic bonds must be ruptured and then
reformed.
After removal of the stress, the large number of atoms that have
relocated, do not return to original position.
Plastic Deformation
1. Initial
2. Small load
3. Unload
bonds
stretch
& planes
shear
planes
still
sheared
elastic + plastic
plastic
F
F
Plastic means permanent.
linear
elastic
linear
elastic
plastic
10
Elasticity of ceramic
From ambient temperature
(or below) and up to
relatively high temperatures
(T < 1,000C), ceramics are
elastic materials par
excellence
their behavior under load is
most often linear with a
nearly full reversibility of
the deformation on removal
of the load
the fracture takes place
during elastic loading (no
plasticity), for a deformation
less than 1%.
Failure
Ceramic materials are somewhat limited in applicability by their
mechanical properties, which in many respects are inferior to those
of metals.
Simple fracture is the separation of a body into two or more pieces
in response to an imposed stress that is static (i.e., constant or
slowly changing with time) and at temperatures that are low
relative to the melting temperature of the material.
The applied stress may be tensile, compressive, shear, or torsional;
Based on the ability of a material to experience plastic deformation,
two fracture modes : ductile and brittle.
Ductile
It is a measure of the degree of plastic deformation that has
been sustained at fracture
exhibit substantial plastic deformation with high energy
absorption before fracture
the process proceeds relatively slowly as the crack length is
extended. Such a crack is often said to be stable.
That is, it resists any further extension unless there is an
increase in the applied stress.
Brittle
a material that experiences very little or no
plastic deformation with low energy absorption
upon fracture
Such cracks may be said to be unstable, and
crack propagation, once started, will continue
spontaneously without an increase in
magnitude of the applied stress
Brittle fracture takes place without any
appreciable deformation, and the cracks may
spread extremely rapid crack propagation.
The direction of crack motion is very nearly
perpendicular to the direction of the applied
tensile stress and yields a relatively flat
fracture surface
A brittle material should not be considered as
lacking in strength. It only shows the lack of
plasticity
POROSITY
the precursor material is in the
form of a powder.
Subsequent to compaction or
forming of these powder particles
into the desired shape, pores or
void spaces will exist between the
powder particles.
During the ensuing heat
treatment, much of this porosity
will be eliminated; however, it is
often the case that this pore
elimination
process is incomplete and some
residual porosity will remain
HARDNESS
how much energy it takes to deform
(stretch, compress, bend, etc.) a
material.
If the material takes a lot of energy to
change only a little, it is said to be hard.
Conversely, if only a little amount of
energy is needed to make a lot of shape
change, then the material is soft.
One benecial mechanical property of
ceramics is their hardness, which is
often utilized when an abrasive or
grinding action is required; in fact, the
hardest known materials are ceramics
High degree of hardness means:
--resistance to plastic deformation or
cracking in compression.
--better wear properties
TOUGHNESS
the ability of a material to absorb energy up to fracture
material's resistance to brittle fracture when a crack is
present
If the material takes a lot of energy (it may change shape)
before breaking, then it is a tough material. If only a little
energy is needed to break the material it is weak or brittle
For a material to be tough, it must display both strength
and ductility, should withstand both high stresses and high
strain
often, ductile materials are tougher than brittle ones
ceramics have poor toughness
c07f13
Toughness
Lower toughness: ceramics
Higher toughness:
metals
25
creep
Materials are often placed in service at elevated temperatures and
exposed to static mechanical stresses (e.g., turbine rotors in jet
engines and steam generators that experience centrifugal stresses).
Deformation under such circumstances is termed creep
creep the evolution undergone by the geometry of a body over a
length of time, under the effect of stresses
subjected to a constant load or stress, creep is normally an
undesirable phenomenon and is often the limiting factor in the
lifetime of a part.
Often ceramic materials experience creep deformation as a result of
exposure to stresses (usually compressive) at elevated temperatures
The speed of deformation or creep rate increases quickly when the
temperature approaches the softening temperature of the material
(case of glass), or the least
Ceramics are therefore not very deformable until a relatively high
temperature is reached.