CALCULO DE LAS ENTROPIAS ABSOLUTAS DEL ACIDO CLORHIDRICO

1.-Calculando la constante de contribución de traslación del acido clorhídrico a 298.15 - 600ºK

M 36 . 46×10−3 Kg×mol−1
m= = 23
=6 . 05442×10−26 Kg
N A 6 . 022045×10 mol −1

E=6. 05442×10−26
3
5 2 π mkT 2 kT
{ [
S Tº = +Ln 2
2 h ] } Pº

{[ }
−26 −23 −1 −23 −1
5 2 π (6 . 05442×10 Kg)(1 .380662×10 JK )(298 .15 ) (1380662×10 JK )(298 . 15 K )
S Tº = +
2 (6 . 626176×10−34 JS )
×
101325 Nm−1 ]
E=(8 .311441 JK−1 mol−1 )(2. 5+Ln(8653196 . 796)
S Tº =156 . 595 JK −1 mol−1

Tº/K Stº JK-1mol-1

298.15 153.595
308.15 154.2715
318.15 154.935
328.15 155.579
338.15 156.203
348.15 156.809
358.15 157.398
368.15 157.971
378.15 158.528
388.15 159.0710
398.15 159.599
408.15 160.167
418.15 160.619
428.15 161.110
438.15 161.590
448.15 162.059
458.15 162.698
468.15 162.967
478.15 163.4075
488.15 163.837
498.15 164.259
508.15 164.672
518.15 165.077
528.15 165.475
538.15 166.865
548.15 166247
558.15 166.623
568.15 166.992
578.15 167.355
588.15 167.712
600.00 168.062

CONTRIBUCIONES ROTACIONALES PARA EL ACIDO CLORHIDRICO A DIFERENTE

TEMPERATURA SE OBTIENE

Ur
S Rº=KLnQ +
T (σθℓT )
=
r
σ HCL=1
θrHCL=15 . 2344
CALCULANDO=298 . 15−600 ºK
ℓT (2. 7183 )(298 . 15 K )
S rº =RLn
( )
σθr
=(8 . 31441 K −1 mol−1 ) Ln
[
(1)(15 .2344 ) ]
S rº =33. 0420 JK −1 mol−1

Tº/K Srº JK-1mol-1

298.15 33.042
308.15 33.312
318.15 33.577
328.15 33.835
338.15 34.084
348.15 34.327
358.15 34.562
368.15 34.791
378.15 35.014
388.15 35.231
398.15 35.443
408.15 35.649
418.15 35.851
428.15 36.047
438.15 36.239
448.15 36.427
458.15 36.611
468.15 36.790
478.15 36.966
488.15 37.138
498.15 37.307
508.15 37.472
518.15 37.634
528.15 37.793
538.15 37.949
548.15 38.102
558.15 38.253
568.15 38.400
578.15 38.548
588.15 38.688
600.00 38.828

CONTRIBUCIONES ROTACIONALES PARA EL ACIDO CLORIDRICO Y A DIFERENTE TEMPERATURA

SE OBTIENE

θvº

S vº =
[ T
θv

ℓ T −1
−Ln(1−ℓ
−θ
T
v

)
]
(4301 .34 )
S vº =(8 .31441 K mol ) −1 −1

[ (298. 15 )

(ℓ
S vº =(8 .31441 K−1 mol−1 )(8. 370591566×10−6 )
4301. 38
298.15
−1 )
−Ln(1−ℓ
−4301 .38
298.15

]
S vº =6. 9596×10−5 K −1 mol−1

Tº/K SVº JK-1mol-11.

298.15 6.9596*10-5
308.15 1.070996*10-4
318.15 1.612755178*10-4
328.15 2.3667878*10-4
338.15 3.392771637*10-4
348.15 4.76041082*10-4
358.15 6.549659724*10-4
368.15 8.850771384*10-4
378.15 1.176414129*10-3
388.15 1.539995529*10-3
398.15 1.987765701*10-3
408.15 2.532525455*10-3
418.15 3.187848999*10-3
428.15 3.967989707*10-3
438.15 4.887777306*10-3
448.15 5.962509044*10-3
458.15 7.20783734*10-1
468.15 8.63965615*10-3
478.15 0.01027398721
488.15 0.01212687455
498.15 0.01421356804
508.15 0.01655193694
518.15 0.019115536165
528.15 0.02203965713
538.15 0.02521948905
548.15 0.02870959234
558.15 0.03252176583
568.15 0.03667070321
578.15 0.04116806148
588.15 0.04602536551
600.00 0.05125338879