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Instructions

PRFUG.XLS
This workbook will fugacities using the Peng-Robinson Equation.

This workbook is related to PREOS.xls and works in a similar fashion.

Worksheets are protected. Values in blue may be changed without unlocking the spreadsheet, which will
permit most common calculations. The worksheets may easily be changed to use a different equation of state.

Copyright 1996-1997, Carl Lira


For use with "An Introduction to Applied Thermodynamics" by J.R. Elliott, C.T. Lira
www.egr.msu.edu/~lira/thermtxt.htm

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Fugacities

Peng-Robinson Equation of State (Mixture) Spreadsheet protected, but no password used.


Fugacities

kij
Component zi Tc (K) Pc (MPa) ω n-pentane n-hexane n-heptane
n-pentane 0.82 469.7 3.37 0.249 - - -
n-hexane 0.15 507.4 3.01 0.305 0 - -
n-heptane 0.03 540.3 2.74 0.349 0 0 -

Current State Roots


T (K) 322.29 Z V fugacity component fugacity coeff component fugacity(MPa) mixture
P (MPa) 0.1 cm3/gmol MPa n-pentane n-hexane n-heptane n-pentane n-hexane n-heptane A 0.04
answers for three 0.96 25449.9 0.1 0.97 0.95 0.94 0.08 0.01 0 B 0
root region 0.03 779.39 R(cm3MPa/molK)
0 121.27 0.12 1.45 0.5 0.19 0.12 0.01 0 8.31
& for 1 root region Err:502 Err:502 Err:502 Err:502 Err:502 Err:502 Err:502 Err:502 Err:502

A
Tr Pr κ α ac a b A B n-pentane n-hexane n-heptane
n-pentane 0.69 0.03 0.74 1.27 2069665.3 2630387.94 90.175 0.04 0 0.04 0.04 0.05
n-hexane 0.64 0.03 0.82 1.36 2701506.2 3675740.07 108.959 0.05 0 0.04 0.05 0.06
n-heptane 0.6 0.04 0.88 1.44 3372204.1 4858785.65 127.728 0.07 0 0.05 0.06 0.07

Solution to Cubic Z3 + a2Z2 + a1Z + a0 =0


R = q2/4 + p3/27 = 0
a2 a1 a0 p q If Negative, three unequal real roots,
-1 0.03 0 -0.3 -0.06 If Positive, one real root

Method 1 - For region with one real root


P Q Root to equation in x Solution methods are summarized
Err:502 Err:502 Err:502 in the appendix of the text.

Method 2 - For region with three real roots


m 3q/pm 3*θ1 θ Roots to equation in x
0.63 1 0.07 0.02 0.63 -0.3 -0.33

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