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c
Introduction
ï The products of substitution reactions of
square-planar complexes [O
O
O
O
have
the same configuration as the reactants,
with direct replacement of the departing
ligand by the new ligand.
!"# ! $!
where:
$!is concentration of the incoming ligand
%## "$
%#$ "%
effect ligands.
Exercise
ï It is possible to prepare different isomers of
Pt(II) complexes with four different ligands.
Predict the products expected if 1 mole of
[PtCl42- is reacted successively with the
following reagent (
G
O
):
a. 2 moles of ammonia
b. 2 moles of pyridine
c. 2 moles of chloride
d. 1 mole of nitrite, NO2-