F. Foods &amp Flavours

Name : Ethyl Alcohol Std. Mix. Name : Ethyl Alcohol Std. Mix.
Instrumen : Chemito GC with FID Instrument : Chemito GC with FID

5
Analytical Conditions Analytical Conditions
Col : Porapak Q, 8 ft. Col : 4% Carbowax 20M on 7 10
Inj : 200° C Carbopak B, 2 mtr. Glass
Det : 225° C Inj : 200° C
Oven : 135° C (5min.) 5° c/min. Det : 200° C
220° C (Temp.Prog.) Oven : 55° C (5min) 6° c/min 100° C
Sample : 1 ul (5 min.) 8° C/min 160° C
(100 ppm each impurity in Ethyl Alcohol) (Temp.Prog.) 9
3 Sample : 1 ul 6 8
1. Methanol
1
2. Acetaldehyde 1. Acetaldehyde
3. Ethanol 8 2. Methyl Acetate
4. iso Propanol 5 9 10
4 3. Methanol 4
5. n Propanol 4. Ethy Acetate 3
6. Di Acetyl 5. Ethanol
7. Ethyl Acetate 2
7 11 6. n-Propanol
8. iso Butanol 12 7. iso-Butanol
2 6
9. n Butanol 8. n-Butyl Acetate
10. iso Amyl Alcohol 1
9. iso-Amyl Acetate
11. Butyl Acetate 10. iso-Amyl Alcohol 0 2 4 6 8 10 12
12. Amyl Acetate
0 2 4 6 8 10 12 14 16 18 20
Code No.: F_2501 Code No.: F_2502
Name : Alcohol Beverage Std. Mixture Name : Acetaldehyde

Instrument : Chemito Capillary GC with FID Instrument : Chemito GC with TCD
Analytical Conditions Analytical Conditions 3

Col : 60 mtr. BP 20 Col : Porapak Q, 6 ft. 2
Capillary Column Inj : 150° C
Inj : 200° C Det : 150° C
Det : 250° C Oven : 120° C
Oven : 50° C (5min) 6° c/min 180° C
(Temp.Prog.)
Sample : 0.5 ul 14 1. Water
Split : 1 : 60 5 2. Formaldehyde
3. Acetaldehyde
1. Acetaldehyde 12. isobutanol 16 18
4. Methanol
2. Ethyl Acetate 13. iso Amyl Acetate
19
3. Ethanol 14. N Butanol 20
3 15 17
4. Methanol 15. iso Amyl Alcohol 6 21
2
5. Ethyl Propionate 16. Ethyl Caprylate 1 7 9 12
6. n Propyl Acetate 17. Furfural 4 8 10 11 13
7. Diacetyl 18. Ethyl Caprate 1 4
8. t Amyl Alcohol 19. Ethyl Lauratc 22
9. Ethyl Butyrate 20. Phenethyl Acetate
10. n Propanol 21. Phenethyl Alcohol 0 2 4 6 8 10
11. n Butyl Acetate 22. Ethyl Palmitate 0 2 4 6 8 10 12 14 16 18 20
Name : Volatile Fatty Acids Name : Fatty Acid Methyl Esters

Instrument : Chemito GC with FID Instrument : Chemito GC with FID
Analytical Conditions 5 Analytical Conditions

Col : 10% FFAP + 2% H3PO4, 10 ft. 6 7 Col : 15% DEGS, 20 ft.
Inj : 250° C Inj : 240° C 1
Det : 250° C Det : 240° C
Oven : 140° C 4 Oven : 200° C
Sample : 1 ul (200 mg each in Water)
2 3 1. C12
1. Acetic Acid 2. C14
2. Propionic 3. C16
3. iso Butyric 1 4. C18:0
4. n Butyric 5. C18:1
5. iso Valeric 6. C20 3
6. n Valeric 5
7. Caproic 2 4
6
0 2 4 6 8 10 0 2 4 6 8 10

Name : Fatty Acid Methyl Esters Name : Fatty Acid Methyl Esters C16-C22
Instrument : Chemito Capillary GC with FID Instrument : Chemito Capillary GC with FID

Col : BP X 70 Capillary Column Col : 25 mtr. BP X 70, Capillary Column
Inj : 240° C Inj : 240° C
Det : 240° C 1 5 Det : 240° C
Oven : 170° C Oven : 170° C
Sample : 0.2 ul
Split : 1 : 80
10
4 5
6 1
1. Solvent 2 6
4 1. Solvent
2. C16 2. C16
3. C18 3. C18
4. C18:1 4. C18:1
5. C18:2 5. C18:2
6. C18:3 2 8
6. C18:3
3 7. C20
3 7
8. C20:1 9
9. C22:1
10. C22
0 4 6 8 10 12 14 16 18 20 22 0 5 10 15 20 25
Name : Butyl Acetate Name : Benzyl Acetate

Instrument : Chemito GC with TCD Instrument : Chemito GC with FID
1
4
Col : Porapak Q, 6 ft. Col : 10% Carbowax 20M, 8 ft.
Inj : 220° C 3 Inj : 160° C
Det : 225° C Det : 200° C
Oven : 180° C Oven : 120° C
1. Water 1. Benzyl Acetate

2. Acetic Acid
3. n Butanol
4. Butyl Acetate 1
0 1 2 3 4 5 0 4 8 12
Name : Peppermint Oil Name : Spearmint Oil


Col : 10% Carbowax 20M Col : 10% Carbowax 20M
4
Inj : 270° C Inj : 270° C
Det : 270° C Det : 270° C
Oven : 80° C 3° c/min 210° C Oven : 80° C 3° c/min 210° C 3
(Temp.Prog.) 3 (Temp.Prog.)
Sample : 0.4 ul 1 Sample : 0.4 ul
2
2
1. Ketone 1. Pimene 1
2. isomenthol 2. Neo Menthol
3. i Menthol 3. Menthol
4 4. Carvone
4. isomenthol
0 5 10 15 20 25 30 35 0 5 10 15 20 25 30 35 40 45

Name : Anise Oil Name : Cinnamon Oil

Inj : 270° C Inj : 270° C
Det : 270° C Det : 270° C
Oven : 80° C 3° c/min 210° C Oven : 80° C 3° c/min 210° C
(Temp.Prog.) (Temp.Prog.)
Sample : 0.4 ul 2 Sample : 0.4 ul 1
1. Pimine 3
2. Anethol
3. Anis Aldehyde 1. Cinnamic Aldehyde
0 5 10 15 20 25 30 35 40 45 50 0 5 10 15 20 25 30 35 40 45 50 55
Name : Clove Oil Name : Citranellal Oil


Inj : 270° C Inj : 270° C
Det : 270° C Det : 270° C
Oven : 80° C 3° c/min 210° C Oven : 80° C 3° c/min 210° C 1 2 3
Sample : 0.4 ul 1 Sample : 0.4 ul
2
1. Eugenol
2. isoeugenol
1. Citranellal
2. Citranellol
3. Geraniol
0 5 10 15 20 25 30 35 40 45 50 0 5 10 15 20 25 30 35 40 45 50
Name : Lemon Grass Oil Name : Vetiver Oil


Inj : 270° C Inj : 270° C
Det : 270° C Det : 270° C
Sample : 0.4 ul Sample : 0.4 ul
1 2
3
1. Citral B
4
2. Citral A
3. Citronellol
4. Geraniol
0 5 10 15 20 25 30 35 40 45 50 55
0 5 10 15 20 25 30 35 40 45 50 55

Name : Geranium Oil Name : Eucalyptus Oil

Inj : 270° C Inj : 270° C
Det : 270° C Det : 270° C
1 2 1
1. Cineol
1. Citronellol
2. Geraniol
0 5 10 15 20 25 30 35 40 45 50 0 5 10 15 20 25 30 35 40 45
Name : Red Rose Oil Name : Terpineol

2 34
Inj : 270° C Inj : 200° C
Det : 270° C Det : 250° C
Oven : 80° C 3° c/min 210° C 1 2 Oven : 100° C 5° c/min 200° C
(Temp.Prog.) 3 (Temp.Prog.)
Sample : 0.4 ul
1. Menthadiene
1. Citranellol 2. Terpine-1 Alcohol
2. Geraniol 3. Terpin-4 Alcohol
3. Phenyl Ethyl Alcohol 4. cis Beta terpinol
1
0 5 10 15 20 25 30 35 40 45 50 0 5 10 15 20 25 30 35 40 45 50
Name : L - Menthol Name : Perfumary Grade Terpinol


Col : 25 mtr. BP 20, Capillary Column Col : 25 mtr. BP 20, Capillary Column
Inj : 230° C Inj : 230° C
Det : 250° C Det : 250° C
Oven : 80° C (2 min.) 4° c/min 200° C Oven : 80° C (2 min.) 4° c/min
(Temp.Prog.) 200° C (Temp.Prog.)
Split : 1 : 80 Split : 1 : 80
0 2 4 6 8 10 12 0 2 4 6 8 10 12 14 16

Name : Mentha Piperita Name : Metha Spicata

Inj : 230° C Inj : 230° C
Det : 250° C Det : 250° C
Split : 1 : 80 Split : 1 : 80
0 2 4 6 8 10 12
0 5 10 15 20
Name : Lavender Oil Name : Essential Oils in Tobacco


Inj : 230° C Inj : 230° C
Det : 250° C Det : 250° C
Split : 1 : 80 Split : 1 : 80
0 5 10 15 20 0 5 10 15 20
Name : Menthol in Cosmetics Name : Molasses

Instrument : Chemito Capillary GC with FID Instrument : Chemito GC with FID
3
Col : 25 mtr. BP 20, Capillary Column Col : Porapak Q
Inj : 200° C Inj : 160° C
Det : 250° C Det : 220° C
Oven : 120° C Oven : 140° C (5 min.) 5° c/min
Sample : 0.2 ul (10% Soln in Acetone) 200° C (Temp.Prog.)
Split : 1 : 60 Sample : 1 ul (100 ppm Each in Water)
1. Methanol 1 2 6
2. Acetaldehyde 4
1 3. Ethanol
1. Menthol 4. isopropanol 7
5. Acetic Acid
5
6. n-Butanol
7. Butyric Acid 8
8. Furfural
0 2 3 4 5
0 5 10 15 20 25

Name : Peppermint Oil Name : Spearmint Oil

Inj : 240° C Inj : 240° C
Det : 260° C Det : 260° C
Oven : 80° C (2 min.) 4° c/min 200° C Oven : 80° C (2 min.) 4° c/min 200° C
Split : 1 : 100 Split : 1 : 100
0 5 10 15 20 25 30
0 5 10 15 20 25
Name : Sandal Wood Oil Name : Clove Oil


Inj : 240° C Inj : 240° C
Det : 260° C Det : 260° C
Split :1 : 100 Split : 1 : 100
0 5 10 15 20 25 30 35 40 0 5 10 15 20 25
Name : Eucalyptus Oil Name : Lemon Grass Oil


Inj : 240° C Inj : 240° C
Det : 260° C Det : 260° C
Oven : 60° C (2 min.) 4° c/min Oven : 80° C (2 min.) 4° c/min
200° C (Temp.Prog.) 200° C (Temp.Prog.)
Split : 1 : 100 Split : 1 : 100
0 5 10 15 20 25 30 35 40
0 5 10 15 20 25 30

Name : Bergamot Oil Name : Orange Flavour

Inj : 240° C Inj : 240° C
Det : 260° C Det : 260° C
Oven : 80° C (2 min.) 4° c/min Oven : 80° C (2 min.) 4° c/min
200° C (Temp.Prog.) 200° C
Sample : 0.1 ul (Temp.Prog.)
Split : 1 : 100 Sample : 0.1 ul
Split : 1 : 100
0 5 10 15 20 25 30 0 5 10 15 20 25 30
Name : Red Rose Oil Name : Satin Rose


Inj : 240° C Inj : 240° C
Det : 260° C Det : 260° C
Oven : 120° C (2 min.) 4° c/min Oven : 120° C (2 min.) 4° c/min 200° C
200° C (Temp.Prog.) (Temp.Prog.)
Split : 1 : 100 Split : 1 : 100
0 5 10 15 20 25 30 35 0 5 10 15 20 25
Name : Floral (Mix Flower Flavour) Name : Jasmine Oil


Inj : 240° C Inj : 240° C
Det : 260° C Det : 260° C
Oven : 80° C (2 min.) 4° c/min Oven : 120° C (2 min.) 4° c/min 200° C
200° C (Temp.Prog.)
(Temp.Prog.) Sample : 0.1 ul
Sample : 0.1 ul Split : 1 : 100
Split : 1 : 100
0 5 10 15 20 25 30 35 40 45 0 5 10 15 20 25 30 33

Name : Citronella Oil Name : Geranium Oil (China)

Inj : 230° C Inj : 230° C
Det : 250° C Det : 250° C
Split : 1 : 60 Split : 1 : 60
0 5 10 15 20 25 30 35 40 0 5 10 15 20 25 30 35 40
Name : Geranium Oil (Africa) Name : Geranium Oil (P. Chauvet)


Inj : 230° C Inj : 230° C
Det : 250° C Det : 250° C
Split : 1 : 60 Split : 1 : 60
0 5 10 15 20 25 30 35
0 5 10 15 20 25 30 35
Name : Lemon Oil Name : Orange Oil


Inj : 230° C Inj : 230° C
Det : 250° C Det : 250° C
Split : 1 : 60 Split : 1 : 60
0 5 10 15 20 25 30 0 5 10 15 20 25 30

Name : Cumin Oil Name : Ajowan Oil
Instrument Chemito GC with FID Instrument : Chemito GC with FID

Col : 5% Apiezon L, 8 ft. Col : 5% Apiezon L, 8 ft.
Inj : 240° C Inj : 250° C
Det : 250° C Det : 270° C
Oven : 80° C(1 min.) 8° c/min Oven : 90° C(1 min.) 8° c/min
220° C (Temp.Prog.) 220° C (Temp.Prog.)
Sample : 0.2 ul Sample : 0.2 ul 1 3
2 4
5
3
2
1
1 Limonene
1 Terpinene
2 Terpinene
6 2 P Cymene
3 P Cymene
3 Thymol
4 Cumin Aldehyde
5 Perilla Aldehyde
6 Anise Aldehyde
0 5 10 15 20 25 0 5 10 15 20 25
Name : Phenyl Ethyl Acetate Name : Coumarin

Instrument : Chemito GC with FID Instrument : Chemito Capillary GC with FID

Col : 10% SE 30, 8 ft. Col : 25 mtr. BP 1, Cap. Col.
Inj : 250° C Inj : 270° C 1 2
Det : 270° C Det : 280° C
Oven : 90° C(2 min.) 16° c/min 250° C 1 Oven : 70° C(1 min.) 12° c/min 230° C
Sample : 1 ul Sample : 0.2 ul (1% Soln)
Split : 1 : 30
1 Solvent
2 Coumarin
1 Phenyl Ethyl Acetate
0 2 4 6 8 10 12
0 2 4 6 8 10
Name : Butyl Carbinol Name : Amyl Salicylate


Col : 10% Carbowax 20 M, 8 ft. Col : 10% SE 30, 8 ft.
Inj : 200° C Inj : 250° C
Det : 200° C Det : 270° C
Oven : 160° C Oven : 90° C(2 min.) 16° c/min 250° C
Sample : 1 ul 1 (Temp.Prog.)
1
Sample : 1 ul
1 Butyl Carbinol
1 Amyl Salicylate
0 5 10 15 20 25 30 0 2 4 6 8 10 12 14

Name : Rice Aroma Extract Name : Ethyl Cinnamate
Analytical Conditions : Analytical Conditions :

Col : 30 mtr BP X 5 Cap. Column Col : 30 mtr BP 20 Cap. Column
Inj : 280° C Inj : 240° C
Det : 300° C Det : 250° C
Oven : 60°C (2 min) 6°C/min 300°C Oven : 240° C
(Temp.Prog.) Sample : 0.5 ul neat
Sample : 1 ul Split : 4.5 ml/min
Split : 20 ml/min
1
1. Ethyl Cinnamate
0 5 10 15 20 25 30 35 40 0 5 10 15 20 25
Name : Ethyl Palmitate Name : Extract of Kanthika Pills.


Col : 30 mtr BP 20 Cap. Column. Col : 30 mtr BP 20
Inj : 220° C Inj : 230° C
Det : 250° C Det : 250° C
Oven : 150°C 5°C/min 220°C (20min) Oven : 60°C 3°C/min 210°C (20 min)
(Temp.Prog.) (Temp. Prog.)
Sample : 0.2 ul (Neat) Sample : 1 ul
Split : 4.5 ml/min Split : 1:80
10 gm of sample extracted in methanal

1
1. Pepper mint oil
1. Ethyl Palmitate 2. Camphor
3. Clove Oil 2 3
4. Thymol
1 4
0 5 10 15 20 25 30 35 40 0 10 20 30 40 50 60
Name : Fatty Acid Methyl Esters. Name : Fatty Acid Methyl Esters. Of Palm Oil

Col : 30 mtr BP X 70 Col : 30 mtr BP X 70
Inj : 240° C Inj : 240° C
Det : 250° C Det : 250° C 3 5
Oven : 140°C 5°C/min 210°C 3 Oven : 140°C 5°C/min 210°C
10 min (Temp. Prog.) 1 4 10 min
Split : 1:40 Split : 1:40
1. C16 1. C12
6
2. C18:0 2. C14
3. C18:1 3. C16
4. C18:2 4. C18:0
5. C20 5. C18:1
6. C20:1 6. C18:2
7. C22 7 4
2 5 2
6 1
0 5 10 15 20 0 2 4 6 8 10 12 14

Name : Fatty Acid Methyl Esters of Sunflower Oil Name : Fatty Acid Methyl Esters of Soyabean oil

Col : 30 mtr BP X 70 Col : 30 mtr BP X 70
Inj : 240° C Inj : 240° C 4
Det : 250° C Det : 250° C
Oven : 140°C 5°C/min 210°C 4 Oven : 140°C 5°C/min 210°C
10 min 10 min
Split : 1:40 Split : 1:40 3
1. C16 3 1. C16 1
2. C18:0 2. C18:0
3. C18:1 3. C18:1
4. C18:2 4. C18:2 5
5. C18:3 5. C18:3
1
2
2 5
0 2 4 6 8 10 12 0 5 10 15 20
Code No.: F_2562

Code No.: F_2561
Name : Std Alcohol Mix Name : Fatty Acid Methyl Esters. STD Mix

Col : 60 mtr BP 20 Col : 30 mtr BP X 70
Inj : 230° C Inj : 240° C
Det : 250° C Det : 250° C 1
Oven : 45°C (8min) 6°C/min Oven : 140°C 5°C/min 210°C
220°C/min 10 min
Spit : 1:60 Split : 1:40
4
1. C14
1. Acetaldehyde 9. Ethyl Caprilate 2. C16
2. EtAc 10. Furfural 3. C18
3. MeOH 11. Ethyl caprate 14 4. C18:0 2
7 10
4. EtOH 12. Ethyl laurate 56 13 5. C18:1 7
5. n-propanol 13. Phenytyl acetate 8 4 5
6. C20
6. n-butanol 14. Phenytyl alcohol 2 3 9 12 6
7. C22
7. iso butanol 15. Ethyl myristate 1 11 15 16 3
8. iso amyl Alcohol 16. Ethyl palmitate
0 10 20 30 40 50 60 0 5 10 15 20

Name : FAME Methyl Esters of 18. Linolelaidic acid (C18:2m6t)
Instrument : Chemito GC with FID 1. Caproic acid (C6 : 0) 19. Linoleic acid (C18:2n6c)
2. Caprylic acid (C8 : 0) 20. Arachidic acid (C20:0)
Analytical Conditions : 3. Capric acid (C10 : 0) 21. V-Linolenic acid (C18:3n3)
Col : 100 mtr SP 2560 4. Undecanoic acid (C11:0) 22. Cis-11-Eicosenoic acid (C20:1)
Inj : 240° C 5. Lauric acid (C12:0) 23. Linolenic acid (C20:2)
Det : 250° C 6. Tri decanoic acid (C13:0) 24. Heneicosanoic acid (C21:0)
Oven : 140°C (5min) 4°C/min 240°C (30 min) 7. Myristic Acid (C14:0) 25. Cis-11, 14, Eicosadienoic acid (C20:2)
Sample : 0.2 ul 8. Myristoleic Acid (C14:1) 26. Behenic acid (C22:0)
Split : 1:50 9. Penta decanoic Acid (C15:0) 27. Cis-8,11,14 Eicosotrienoic acid (C20:3n6)
10. Cis-10-Pentadecanoic Acid (C15:1) 28. Erucoc acid (C22:1n9)
11. Palmitic Acid (C16:0) 29. Cis-11, 14,17, Eicosatrienoic acid (C20:3n3)
12. Palmitoleic Acid (C16:1) 30. Arachidonic acid (C20:4n6)
13. Heptadecanoic Acid (C17:0) 31. Tricosanoic acid (C23:0)
14. Cis-10- Hepiadecanoic Acid (C17:1) 32. Cis 13,16 Docosadienoic acid (C22:2)
15. Stearic acid (C18:0) 33. Lignoceric acid (C24:0)
16. Elaidic acid (C18:1n9t) 34. Cis-5,8,11, 14,17 Eicosapentaenoic acid (C20:5n3)
17. Oleic acid (C18:1n9c ) 35. Nervonic acid (C24: 1)
36. Cis 4,7,10,13, 16, 19 Docosahexanoic acid (C22:6n3)
11
7
3 5
2 15 17
1 21
6 10 25 27 34
4 9 12 13 14 16 33
8 23 24 30
18 20 29 31 36
19 22 26 32
28 35
0 5 10 15 20 25 30 35 40 45 50 55 60
Code No.: F_2565

F. Foods &amp Flavours

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Verfügbare Formate

Name : Ethyl Alcohol Std. Mix. Name : Ethyl Alcohol Std. Mix.

Instrumen : Chemito GC with FID Instrument : Chemito GC with FID

Name : Alcohol Beverage Std. Mixture Name : Acetaldehyde

Analytical Conditions Analytical Conditions 3

Code No.: F_2503 Code No.: F_2504

Name : Volatile Fatty Acids Name : Fatty Acid Methyl Esters

Analytical Conditions 5 Analytical Conditions

Code No.: F_2505 Code No.: F_2506

Analytical Conditions Analytical Conditions

Code No.: F_2507 Code No.: F_2508

Name : Butyl Acetate Name : Benzyl Acetate

1. Water 1. Benzyl Acetate

Code No.: F_2509 Code No.: F_2510

Name : Peppermint Oil Name : Spearmint Oil

Analytical Conditions Analytical Conditions

Code No.: F_2511 Code No.: F_2512

Analytical Conditions Analytical Conditions

Code No.: F_2513 Code No.: F_2514

Name : Clove Oil Name : Citranellal Oil

Analytical Conditions Analytical Conditions

Code No.: F_2515 Code No.: F_2516

Name : Lemon Grass Oil Name : Vetiver Oil

Analytical Conditions Analytical Conditions

Code No.: F_2517 Code No.: F_2518

Analytical Conditions Analytical Conditions

Code No.: F_2519 Code No.: F_2520

Name : Red Rose Oil Name : Terpineol

Code No.: F_2521 Code No.: F_2522

Name : L - Menthol Name : Perfumary Grade Terpinol

Analytical Conditions Analytical Conditions

Code No.: F_2523 Code No.: F_2524

Analytical Conditions Analytical Conditions

Code No.: F_2525 Code No.: F_2526

Name : Lavender Oil Name : Essential Oils in Tobacco

Analytical Conditions Analytical Conditions

Code No.: F_2527 Code No.: F_2528

Name : Menthol in Cosmetics Name : Molasses

Code No.: F_2529 Code No.: F_2530

Analytical Conditions Analytical Conditions

Name : Sandal Wood Oil Name : Clove Oil

Analytical Conditions Analytical Conditions

Code No.: F_2533 Code No.: F_2534

Name : Eucalyptus Oil Name : Lemon Grass Oil

Analytical Conditions Analytical Conditions

Code No.: F_2535 Code No.: F_2536

Analytical Conditions Analytical Conditions

Code No.: F_2537 Code No.: F_2538

Name : Red Rose Oil Name : Satin Rose

Analytical Conditions Analytical Conditions

Code No.: F_2539 Code No.: F_2540

Name : Floral (Mix Flower Flavour) Name : Jasmine Oil

Analytical Conditions Analytical Conditions

Code No.: F_2541 Code No.: F_2542

Analytical Conditions Analytical Conditions

Code No.: F_2543 Code No.: F_2544

Name : Geranium Oil (Africa) Name : Geranium Oil (P. Chauvet)

Analytical Conditions Analytical Conditions

Code No.: F_2545 Code No.: F_2546

Name : Lemon Oil Name : Orange Oil

Analytical Conditions Analytical Conditions

Code No.: F_2547 Code No.: F_2548

Analytical Conditions Analytical Conditions