Beruflich Dokumente
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CHEMISTRY-EXERCISES
Q.3-1: What hydroxide concentration is
required to:
a) Initiate precipitation of Fe3+ from a
1.00x10-3 M solution of Fe2(SO4)3?
b) Lower the Fe3+ concentration in the
foregoing solution to 1.00x10-9 M?
Answer 3-1:
a) Ksp (Fe(OH)3) : 2.00x10-39
1.00x10-3 M Fe2(SO4)3
[Fe3+]= 2x1.00x10-3 M = 2.00x10-3 M
K sp
[OH ] 3
2.10 3
[OH-]= 1.00x10-12 M
b) [Fe3+]= 1.00x10-9 M
K sp
[OH ] 3
1.10 9 [OH-]= 1.00x10-10 M
Q.3-2: The solubility product for a series of iodides
are AgI (Ksp=8.3x10-17) and PbI2 (Ksp=7.1x10-9)
List these two compounds in order of decreasing
Molar solubility in:
a) water b) 0.10 M NaI c) a 0.010 M
solution of the solute cation.
Answer 3.-2: SPbI =? Ksp = 7.1x10-9
2
a) Ag I
K sp 8.3 x1017 9.1x109 M
2
K sp Pb 2 I 4x 3 Pb 1.2 x10
2 3
M
c) For AgI; Pb
2
K sp
7.1x109
7 . 1x10 7
I
2
0.10 2
For PbI2; I Ag
K sp
8.3x10 17
0.010
8.3x10 15 M
I Pb
K
sp
2
I 1
K sp
1 7.1x10 9
4.2 x10 4 M
S PbI 2
2 2 Pb 2
2 0.010
K a 3 x10 8
H 3O OCl
3 x10 8
H O
3
2
[H3O+] =2.4x10-5 M
0.0200
[OH-]=1x10-14 / 2.4x10-5 = 4.1x10-10 M
CH 3COO H 2O CH 3COOH OH
b) 0.0860M CH3COONa?
OH 2
Kb
K w CH 3COOH OH
1x1014
10
Kb
0.0860 Ka
CH 3COO
1.75 x105
5 .71x10
OH 7.01x10
6
c) 0.120M NaOCl?
OCl H 2O HOCl OH
OH HOCl
OCl 0.120 OH
Kb
K w HOCl OH
1x10 14
7
OH
2
Ka
OCl 3.0 x10 8
3.33 x10
Kb
0.120