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1) Sighting along C2-C1 axis, draw the Newman projections of the most
stable conformation for the following compounds:
Et
1
1 1
Br 2 2
2
Cl
HO H Cl
Do the same as the above but sight along C1-C2 axis.
H H Me H Me H
Cl Me OH
For the 2 skeletal structures above, draw the 2 Newman projections of the
2 chair conformations by sighting along both C1-C2 and C5-C4.
School of Physical & Mathematical Sciences
Division of Chemistry & Biological Chemistry
OH OH
Cl
Br
Cl
H Cl
6) Determine the R/S configuration for all the chiral centres present in the
following compounds:
HO OH
OH Br
Cl Br CH3 H 3C H
CH3O CH3
H3C H Ph H CH3
Br
O
Br
Which compound is achiral?
7) List out all the isomers of C4H7Cl. Identify the pairs of enantiomers and
diastereomers.