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i0\sl-480\slmult0 \fs24\cf0\f0\charscalex100\b {GASES IDEALES}\b0 \par\column\pa
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a Iñigo}\b0 \i0 \par\pard\sect\sectd\sbknone\pard\li1173\ri0\sl-213\slmult0 \fs18\
cf0\par\pard\li1173\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li1173\ri0\sl-213\slmu
lt0 \fs18\cf0\par\pard\li1173\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li1173\ri0\s
l-213\slmult0 \fs18\cf0\par\pard\li1173\ri0\sl-266\slmult0 \*\tx6413\fs22\cf0\f1
\charscalex100 {A esta altura de tus estudios seguramente ya sabés}\tab \fs22\cf0\
f1\charscalex100 {que hay muchas sustancias formadas }\par\pard\li466\ri0\sl-266
\slmult0 \fs20\cf0\f1\charscalex100 {por moléculas, qué es una molécula, y que una sus
tancia determinada puede presentarse en tres }\par\pard\li466\ri0\sl-266\slmult0
\fs22\cf0\f1\charscalex100 {distintos estados de agregación.}\par\pard\li1173\ri0
\sl-213\slmult0 \fs18\cf0\par\pard\li1173\ri0\sl-306\slmult0 \fs22\cf0\f1\charsc
alex100 {Si pensamos en una sustancia molecular, en el caso más sencil o, en el ag
ua por ejemplo:}\par\pard\sect\sectd\sbknone\cols2\colno1\colw1173\colsr-0\colno
2\colw9920\pard\li466\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li466\ri0\sl-213\slm
ult0 \fs18\cf0\par\pard\li466\ri0\sl-426\slmult0 \fs24\cf2\f0\charscalex100\b {
1}\b0 \par\column\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-213\
slmult0 \fs18\cf0\par\pard\li0\ri0\sl-333\slmult0 \fs22\cf0\f0\charscalex100\b \
i { ¿Qué diferencia hay a nivel de cómo se encuentran esas moléculas cuando el agua}\b0
\i0 \par\pard\li0\ri0\sl-253\slmult0 \fs22\cf0\f0\charscalex100\b \i { está en est
ado sólido, líquido o gaseoso?}\b0 \i0 \par\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\pa
r\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-373\slmult0 \fs22\cf
0\f1\charscalex100 {Para que un sistema gaseoso quede correctamente determinado
no alcanza simplemente }\par\pard\sect\sectd\sbknone\pard\li466\ri0\sl-266\slmul
t0 \fs22\cf0\f1\charscalex100 {con conocer la masa de gas, o la cantidad de gas
(que se mide en moles). Se deben conocer otras }\par\pard\li466\ri0\sl-266\slmul
t0 \fs20\cf0\f1\charscalex100 {tres variables, que son: temperatura, presión y vol
umen. Un gas no tiene volumen propio, por lo }\par\pard\li466\ri0\sl-266\slmult0
\fs20\cf0\f1\charscalex100 {tanto ocupará todo el volumen del recipiente que lo c
ontenga. Estas cuatro variables no son }\par\pard\li466\ri0\sl-266\slmult0 \fs20
\cf0\f1\charscalex100 {independientes, lo cual significa que a lo sumo se podrán p
oner arbitrariamente tres de el as, y, }\par\pard\li466\ri0\sl-266\slmult0 \fs22
\cf0\f1\charscalex100 {automáticamente la cuarta quedará fijada. La ecuación que relac
iona estas cuatro variables es la:}\par\pard\li3613\ri0\sl-213\slmult0 \fs18\cf0
\par\pard\li3613\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li3613\ri0\sl-373\slmult0
\fs22\cf0\f0\charscalex100\b {Ecuación General del gas ideal}\b0 \par\pard\li4360
\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li4360\ri0\sl-346\slmult0 \fs24\cf0\f0\ch
arscalex100\b {P. V = n . R . T}\b0 \par\pard\li1173\ri0\sl-213\slmult0 \fs18\
cf0\par\pard\li1173\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li1173\ri0\sl-360\slmu
lt0 \fs20\cf0\f1\charscalex100 {La }\fs20\cf0\f0\charscalex100\b {TEORÍA CINÉTICA DE
GASES}\b0 \fs20\cf0\f1\charscalex100 { expresa que las moléculas de un gas están to
talmente }\par\pard\li466\ri0\sl-266\slmult0 \fs18\cf0\f1\charscalex100 {libres,
sin ninguna interacción entre el as. Dichas moléculas se mueven
con un movimiento }\par\pard\li466\ri0\sl-266\slmult0 \fs20\cf0\f1\charscal
ex100 {rectilíneo, chocando entre sí y con las paredes del recipiente con choques elás
ticos. Las moléculas }\par\pard\li466\ri0\sl-266\slmult0 \fs20\cf0\f1\charscalex10
0 {se consideran puntuales, y el volumen que ocupan dichas moléculas es totalmente
despreciable }\par\pard\li466\ri0\sl-266\slmult0 \fs22\cf0\f1\charscalex100 {co
n respecto al volumen del recipiente que se encuentra ocupando dicho gas.}\par\p
ard\sect\sectd\sbknone\cols2\colno1\colw1173\colsr-0\colno2\colw9920\pard\li466\
ri0\sl-213\slmult0 \fs18\cf0\par\pard\li466\ri0\sl-520\slmult0 \fs24\cf2\f0\char
scalex100\b { 2}\b0 \par\column\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\l
i0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-360\slmult0 \fs22\cf0\f0\cha
rscalex100\b \i {¿Que es un choque elástico?}\b0 \i0 \par\pard\li0\ri0\sl-213\slmult
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mult0 \fs22\cf0\f1\charscalex100 {Entonces, un gas ideal es el que cumple con la
teoría cinética de gases y por lo tanto con la }\par\pard\sect\sectd\sbknone\pard\l
i466\ri0\sl-266\slmult0 \fs22\cf0\f1\charscalex100 {ecuación general de un gas ide
al.}\par\pard\li1173\ri0\sl-266\slmult0 \fs22\cf0\f1\charscalex100 {No siempre l
os gases cumplen con esta ecuación, un gas real puede no cumplirla. }\par\pard\sec
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0\ri0\sl-346\slmult0 \fs22\cf0\f0\charscalex100\b \i {¿Por qué, entonces, estamos ut
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quier gas real puede comportarse como ideal dependiendo de las condiciones en qu
e }\par\pard\li466\ri0\sl-266\slmult0 \fs20\cf0\f1\charscalex100 {se encuentre.
Teniendo en cuenta la ecuación general, matemáticamente puede verse qué sucede }\par\p
ard\li466\ri0\sl-266\slmult0 \fs22\cf0\f1\charscalex100 {con el volumen al dismi
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par\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-360\slmult0 \fs22\
cf0\f0\charscalex100\b \i {¿Qué pasará con las moléculas al estar cada vez más juntas?}\b0
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slmult0 \fs22\cf0\f1\charscalex100 {Qué son presiones bajas y temperaturas altas d
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0\f1\charscalex100 {ejemplo el oxígeno a presión atmosférica normal (1 atmósfera) y temp
eratura ambiente (20 \uc1\u8211X 25 }\par\pard\li466\ri0\sl-266\slmult0 \fs20\cf
0\f1\charscalex100 {°C) seguramente se comportará como ideal, en cambio el agua a 1
atm. y 150 °C no se comporta }\par\pard\li466\ri0\sl-266\slmult0 \fs22\cf0\f1\char
scalex100 {como ideal. }\par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\mar
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alex100\b { 6}\b0 \par\column\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0
\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-346\slmult0 \fs22\cf0\f0\chars
calex100\b \i {¿Por qué el agua a 1 atm. y 150 ªC no se comporta como gas ideal?}\b0 \
i0 \par\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-213\slmult0 \f
s18\cf0\par\pard\li0\ri0\sl-373\slmult0 \fs22\cf0\f1\charscalex100 {Cuando se qu
iere estudiar experimentalmente un gas, al existir cuatro variables, no se }\par
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466\ri0\sl-266\slmult0 \fs22\cf0\f1\charscalex100 {pueden cambiar todas juntas,
porque no se l egaría a ninguna conclusión. Lo que se puede hacer }\par\pard\li466\r
i0\sl-266\slmult0 \fs20\cf0\f1\charscalex100 {experimentalmente es dejar fijas d
os de el as, y ver como varía la tercera en función de la cuarta. }\par\pard\li466\r
i0\sl-266\slmult0 \fs20\cf0\f1\charscalex100 {Eso fue lo que hicieron Robert Boy
le (1627 \uc1\u8211X 1691) y Edme Mariotte (1620 \uc1\u8211X 1684) por un lado y
}\par\pard\li466\ri0\sl-266\slmult0 \fs22\cf0\f1\charscalex100 {Jacques A. Char
les (1746 \uc1\u8211X 1823) y Joseph L. Gay Lussac (1778 \uc1\u8211X 1850) por e
l otro.}\par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn666\margrsx
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0\slmult0 \fs22\cf0\f0\charscalex100\b \i {¿Cuáles son las variables que quedan como
constantes en el experimento de Boyle}\b0 \i0 \par\pard\li0\ri0\sl-253\slmult0
\fs22\cf0\f0\charscalex100\b \i { y Mariotte?}\b0 \i0 \par\pard\li0\ri0\sl-213\s
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{Si se coloca un gas en un recipiente herméticamente cerrado, con un émbolo móvil (com
o }\par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn666\margrsxn133\
pard\li466\ri0\sl-266\slmult0 \fs20\cf0\f1\charscalex100 {el que tienen las
jeringas), desde ya, al no poder entrar o salir gas, la can
tidad de gas es }\par\pard\li466\ri0\sl-266\slmult0 \fs18\cf0\f1\charscalex1
00 {constante. Si ese recipiente se mantiene a temperatura const
ante, colocándolo en un baño }\par\pard\li466\ri0\sl-266\slmult0 \fs20\cf0\f
1\charscalex100 {termostático queda constante también la temperatura. Si ahora se co
locan pesas sobre el émbolo }\par\pard\li466\ri0\sl-266\slmult0 \fs20\cf0\f1\chars
calex100 {estamos aumentando la presión, intuitivamente se ve que
el volumen disminuye. }\par\pard\li466\ri0\sl-266\slmult0 \fs20\cf0\f1\chars
calex100 {Experimentalmente, si la presión se aumenta al doble el volumen disminuy
e a la mitad. Este es el }\par\pard\li466\ri0\sl-266\slmult0 \fs20\cf0\f1\charsc
alex100 {experimento de Boyle y Mariotte. Matemáticamente el producto de la presión
por el volumen se }\par\pard\li466\ri0\sl-266\slmult0 \fs20\cf0\f1\charscalex100
{mantiene constante. P . V = cte. Al hacer el gráfico se obtiene una curva deno
minada hipérbola }\par\pard\li466\ri0\sl-266\slmult0 \fs22\cf0\f1\charscalex100 {e
quilátera.}\par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn666\margrs
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par\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-213\slmult0 \fs18\
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0 \fs18\cf0\par\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-213\sl
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i0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-440\slmult0 \fs22\cf0\f0\charsca
lex100\b \i {¿Cuáles son las variables que quedan como constantes en los experimento
s de}\b0 \i0 \par\pard\li0\ri0\sl-253\slmult0 \fs22\cf0\f0\charscalex100\b \i {
Charles y Gay Lussac?}\b0 \i0 \par\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\par
d\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-373\slmult0 \fs22\cf0\f1\
charscalex100 {Si ahora dejamos que nuestro recipiente quede a presión atmosférica (
presión constante) }\par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn6
66\margrsxn133\pard\li466\ri0\sl-266\slmult0 \fs22\cf0\f1\charscalex100 {quedan
constantes la cantidad de gas y la presión. Podemos ver que pasa con el volumen al
variar }\par\pard\li466\ri0\sl-266\slmult0 \fs18\cf0\f1\charscalex100 {la tem
peratura. También intuitivamente se ve que al aumentar la temper
atura el volumen }\par\pard\li466\ri0\sl-266\slmult0 \fs22\cf0\f1\charscalex
100 {aumenta. Este es uno de los experimentos de Charles y Gay Lussac. }\par\par
d\li1173\ri0\sl-266\slmult0 \fs20\cf0\f1\charscalex100 {Si se traba el émbolo de m
anera que no pueda moverse quedan constantes la cantidad de }\par\pard\li466\ri0
\sl-266\slmult0 \fs20\cf0\f1\charscalex100 {gas y el volumen. Nuevamente es fácil
intuir que al aumentar la temperatura la presión aumenta. }\par\pard\li466\ri0\sl-
266\slmult0 \fs20\cf0\f1\charscalex100 {Este es el segundo de los experimentos d
e Charles y Gay Lussac, y también es lo que sucede en }\par\pard\li466\ri0\sl-266\
slmult0 \fs22\cf0\f1\charscalex100 {una ol a a presión para cocinar. }\par\pard\li
1173\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li1173\ri0\sl-333\slmult0 \fs22\cf0\f
1\charscalex100 {Al unir estas tres leyes se l ega a la l amada: }\par\pard\li11
73\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li1173\ri0\sl-213\slmult0 \fs18\cf0\par
\pard\li1173\ri0\sl-373\slmult0 \fs22\cf0\f0\charscalex100\b {
Ecuación de Estado de un gas ideal: P . V / T = cte}\b0 \par\pard\li1173\ri0\sl
-400\slmult0 \fs22\cf0\f0\charscalex100\b { que comúnmente usamos c
omo: P}\b0 \fs14\cf0\f0\charscalex100\b {i}\b0 \fs22\cf0\f0\charscalex100\b {
. V}\b0 \fs14\cf0\f0\charscalex100\b {i}\b0 \fs22\cf0\f0\charscalex100\b { / T}
\b0 \fs14\cf0\f0\charscalex100\b {i}\b0 \fs22\cf0\f0\charscalex100\b { = P}\b0
\fs14\cf0\f0\charscalex100\b {f}\b0 {\super \fs22\up0\cf3\f0\charscalex100\b { .
}\b0 }\fs14\cf0\f0\charscalex100\b {f}\b0 {\super \fs22\up0\cf0\f0\charscalex10
0\b { /T}\b0 }\fs14\cf0\f0\charscalex100\b {f}\b0 \par\pard\li1173\ri0\sl-213\sl
mult0 \fs18\cf0\par\pard\li1173\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li1173\ri0
\sl-213\slmult0 \fs18\cf0\par\pard\li1173\ri0\sl-280\slmult0 \fs20\cf0\f1\charsc
alex100 {Al incorporar como variable la cantidad de gas se l ega a la Ecuación Gen
eral. Fijate que }\par\pard\li466\ri0\sl-266\slmult0 \fs20\cf0\f1\charscalex100
{tanto las leyes de Boyle y Mariotte como las de Charles y Gay Lussac y la ecuac
ión de estado no }\par\pard\li466\ri0\sl-266\slmult0 \fs20\cf0\f1\charscalex100 {s
on más que casos particulares de la ecuación general, en los que algunas de las cuat
ro variables }\par\pard\li466\ri0\sl-266\slmult0 \fs22\cf0\f1\charscalex100 {que
dan constantes. Teniendo en cuenta esto, las preguntas que debés hacerte son: }\pa
r\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn666\margrsxn133\cols2\
colno1\colw1173\colsr-0\colno2\colw9920\pard\li466\ri0\sl-213\slmult0 \fs18\cf0\
par\pard\li466\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li466\ri0\sl-466\slmult0 \f
s24\cf2\f0\charscalex100\b { 9}\b0 \par\column\pard\li0\ri0\sl-213\slmult0 \fs18
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fs22\cf0\f0\charscalex100\b \i {¿Puedo usar cualquier ecuación indistintamente en cu
alquier circunstancia?}\b0 \i0 \par\pard\li0\ri0\sl-253\slmult0 \fs22\cf0\f0\cha
rscalex100\b \i {¿Cuándo es válido usar la ecuación de estado?}\b0 \i0 \par\pard\li0\ri0
\sl-253\slmult0 \fs22\cf0\f0\charscalex100\b \i {¿Cuándo es válido usar la ecuación gene
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t0 \fs22\cf0\f0\charscalex100\b \i {¿Cuáles son las expresiones matemáticas de esas re
ctas?}\b0 \i0 \par\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-213
\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl
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cf0\par\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-213\slmult0 \f
s18\cf0\par\pard\li0\ri0\sl-346\slmult0 \fs22\cf0\f0\charscalex100\b \i {¿Qué sucede
al cambiar la escala de temperaturas a T (temperatura absoluta)?}\b0 \i0 \par\p
ard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\p
ar\pard\li0\ri0\sl-373\slmult0 \fs22\cf0\f1\charscalex100 {Debés asegurarte de con
ocer las unidades de volumen, temperatura y de presión, y el }\par\pard\sect\sectd
\sbknone\pgwsxn11893\pghsxn16840\marglsxn666\margrsxn133\pard\li466\ri0\sl-266\s
lmult0 \fs22\cf0\f1\charscalex100 {pasaje entre unidades de una misma magnitud.}
\par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn666\margrsxn133\col
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pard\li360\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li360\ri0\sl-213\slmult0 \fs18\
cf0\par\pard\li360\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li360\ri0\sl-213\slmult
0 \fs18\cf0\par\pard\li360\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li360\ri0\sl-21
3\slmult0 \fs18\cf0\par\pard\li360\ri0\sl-426\slmult0 \fs22\cf2\f0\charscalex100
\b { 14}\b0 \par\pard\li360\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li360\ri0\sl-2
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ri0\sl-213\slmult0 \fs18\cf0\par\pard\li360\ri0\sl-213\slmult0 \fs18\cf0\par\par
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ar\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-346\slmult0 \fs22\c
f0\f0\charscalex100\b \i {¿Recordás qué es presión? ¿Qué es un Pascal? ¿A qué es igual?}\b
\par\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-213\slmult0 \fs1
8\cf0\par\pard\li0\ri0\sl-373\slmult0 \fs22\cf0\f1\charscalex100 {Las preguntas
que ahora podrías hacerte son: }\par\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\par
d\li0\ri0\sl-306\slmult0 \fs22\cf0\f0\charscalex100\b \i {¿Puedo usar cualquier un
idad en las ecuaciones que utilice?}\b0 \i0 \par\pard\li0\ri0\sl-253\slmult0 \fs
22\cf0\f0\charscalex100\b \i {Por ejemplo, si se está usando la ecuación de estado:
}\b0 \i0 \par\pard\li0\ri0\sl-253\slmult0 \fs22\cf0\f0\charscalex100\b \i {¿Puede
ponerse el volumen en cualquier unidad? ¿y la presión? ¿y la temperatura?}\b0 \i0 \par
\pard\li0\ri0\sl-253\slmult0 \fs22\cf0\f0\charscalex100\b \i {¿Qué sucede si se está u
sando la ecuación general?}\b0 \i0 \par\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\
pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\
par\pard\li0\ri0\sl-413\slmult0 \fs22\cf0\f0\charscalex100\b \i {¿Por qué la tempera
tura debe estar en temperatura absoluta y no en otra unidad,}\b0 \i0 \par\pard\l
i0\ri0\sl-253\slmult0 \fs22\cf0\f0\charscalex100\b \i { Celsius o Fahrenheit, po
r ejemplo?}\b0 \i0 \par\pard\li66\ri0\sl-253\slmult0 \fs20\cf0\f0\charscalex100\
b {Ayuda}\b0 \fs20\cf0\f0\charscalex100 {: }\fs20\cf0\f1\charscalex100 {Volvé a lo
s experimentos de Charles y Gay Lussac y a lo que sucede al cambiar}\par\pard\se
ct\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn666\margrsxn133\pard\li466\ri0\
sl-240\slmult0 \fs20\cf0\f1\charscalex100 { la escala de temperatura
s. Ahí encontrarás la respuesta.}\par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn1684
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de líquidos o sólidos. En los gases el volumen molar varía mucho con }\par\pard\li466\
ri0\sl-266\slmult0 \fs20\cf0\f1\charscalex100 {las condiciones de presión y temper
atura. Observá que la ecuación general nos está diciendo que }\par\pard\li466\ri0\sl-2
66\slmult0 \fs20\cf0\f1\charscalex100 {cualquier gas, siempre que se comporte co
mo ideal, se comporta de la misma manera. Un mol de }\par\pard\li466\ri0\sl-266\
slmult0 \*\tx9640\fs22\cf0\f1\charscalex100 {cualquier gas, medido en las mismas
condiciones de P y T, debe ocupar el mismo volumen,}\tab \fs22\cf0\f1\charscale
x100 {si no }\par\pard\li466\ri0\sl-266\slmult0 \fs22\cf0\f1\charscalex100 {fuer
a así no se cumpliría la igualdad.}\par\pard\li1173\ri0\sl-266\slmult0 \fs22\cf0\f1\
charscalex100 {Esto mismo, pero enunciado al revés, es lo que se conoce como }\fs2
2\cf0\f0\charscalex100\b {Hipótesis de Avogadro: }\b0 \par\pard\li466\ri0\sl-266\s
lmult0 \fs22\cf0\f1\charscalex100 {volúmenes iguales de diferentes gases, medidos
en las mismas condiciones de P y T, tienen el }\par\pard\li466\ri0\sl-266\slmult
0 \fs20\cf0\f1\charscalex100 {mismo número de \uc1\u8220Xpartículas\uc1\u8221X
. La hipótesis de Avogadro habla de partículas porque en el }\pa
r\pard\li466\ri0\sl-266\slmult0 \fs22\cf0\f1\charscalex100 {momento en que fue e
nunciada no se conocía lo que eran las moléculas, hoy sabemos que esas }\par\pard\li
466\ri0\sl-266\slmult0 \fs22\cf0\f1\charscalex100 {\uc1\u8220Xpartículas\uc1\u8221
X son las moléculas del gas.}\par\pard\li1466\ri0\sl-213\slmult0 \fs18\cf0\par\par
d\li1466\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li1466\ri0\sl-213\slmult0 \fs18\c
f0\par\pard\li1466\ri0\sl-426\slmult0 \fs24\cf0\f0\charscalex100\i {Las llamadas
}\i0 \fs24\cf0\f0\charscalex100\b \i {condiciones normales de presión y temperatu
ra (CNPT)}\b0 \i0 \fs24\cf0\f0\charscalex100\i { son }\i0 \fs24\cf0\f0\charscale
x100\b \i {1 atm. y }\b0 \i0 \par\pard\li760\ri0\sl-280\slmult0 \fs24\cf0\f0\cha
rscalex100\b \i {273 K}\b0 \i0 \fs24\cf0\f0\charscalex100\i {. El valor del volu
men molar de cualquier gas ideal en CNPT es }\i0 \fs24\cf0\f0\charscalex100\b \
i {22,4 dm}\b0 \i0 \fs14\cf0\f0\charscalex100\b \i {3}\b0 \i0 \fs24\cf0\f0\chars
calex100\i {, y es el }\i0 \par\pard\li760\ri0\sl-280\slmult0 \fs24\cf0\f0\char
scalex100\i {denominado }\i0 \fs24\cf0\f0\charscalex100\b \i {volumen molar norm
al de un gas ideal.}\b0 \i0 \par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840
\marglsxn666\margrsxn133\cols2\colno1\colw1173\colsr-0\colno2\colw9920\pard\li36
0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li360\ri0\sl-213\slmult0 \fs18\cf0\par\p
ard\li360\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li360\ri0\sl-453\slmult0 \fs24\c
f2\f0\charscalex100\b { 16}\b0 \par\column\pard\li0\ri0\sl-213\slmult0 \fs18\cf0
\par\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-213\slmult0 \fs18
\cf0\par\pard\li0\ri0\sl-426\slmult0 \fs22\cf0\f0\charscalex100\b \i {En condici
ones distintas de las normales pero iguales para cualquier gas}\b0 \i0 \fs22\cf0
\f0\charscalex100\b {:}\b0 \par\pard\li0\ri0\sl-240\slmult0 \fs22\cf0\f0\charsca
lex100\b \i {¿El volumen molar es igual para cualquier gas que sea? ¿Es igual a 22,4
dm}\b0 \i0 \fs14\cf0\f0\charscalex100\b \i {3}\b0 \i0 \fs22\cf0\f0\charscalex10
0\b \i {?}\b0 \i0 \par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn6
66\margrsxn133\pard\li466\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li466\ri0\sl-213
\slmult0 \fs18\cf0\par\pard\li466\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li466\ri
0\sl-213\slmult0 \fs18\cf0\par\pard\li466\ri0\sl-213\slmult0 \fs18\cf0\par\pard\
li466\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li466\ri0\sl-213\slmult0 \fs18\cf0\p
ar\pard\li466\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li466\ri0\sl-466\slmult0 \fs
22\cf0\f0\charscalex100\b {MEZCLA DE GASES}\b0 \fs22\cf0\f0\charscalex100\b { \u
c1\u8211X Ley de Dalton de las presiones parciales}\b0 \par\pard\li1173\ri0\sl-2
13\slmult0 \fs18\cf0\par\pard\li1173\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li117
3\ri0\sl-386\slmult0 \fs22\cf0\f1\charscalex100 {Como todos los gases ideales se
comportan de la misma manera, el volumen que va a }\par\pard\li466\ri0\sl-266\s
lmult0 \fs20\cf0\f1\charscalex100 {ocupar cualquier gas en las mismas condicione
s de P y T depende solamente del número de }\par\pard\li466\ri0\sl-266\slmult0 \fs
20\cf0\f1\charscalex100 {moles, o lo que es lo mismo del número de moléculas. Si se
tiene una mezcla de gas A y gas B, no }\par\pard\li466\ri0\sl-266\slmult0 \fs20\
cf0\f1\charscalex100 {importa de qué gas sean las moléculas, solamente importa el núme
ro total de el as. La ecuación }\par\pard\li466\ri0\sl-266\slmult0 \fs22\cf0\f1\ch
arscalex100 {general se transforma en: }\par\pard\li4000\ri0\sl-213\slmul
t0 \fs18\cf0\par\pard\li4000\ri0\sl-320\slmult0 \fs22\cf0\f0\charscalex100\b {P}
\b0 {\sub \fs14\cf0\f0\charscalex100\b {tot}\b0 }\fs22\cf0\f0\charscalex100\b {
. V = (n}\b0 {\sub \fs14\cf0\f0\charscalex100\b {A}\b0 }\fs22\cf0\f0\charscalex1
00\b { + n}\b0 {\sub \fs14\cf0\f0\charscalex100\b {B}\b0 }\fs22\cf0\f0\charscale
x100\b {). R . T}\b0 \par\pard\li1173\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li11
73\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li1173\ri0\sl-360\slmult0 \fs22\cf0\f1\
charscalex100 {Pasando de término el volumen y aplicando propiedad distributiva se
l ega a:}\par\pard\li3493\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li3493\ri0\sl-2
13\slmult0 \fs18\cf0\par\pard\li3493\ri0\sl-373\slmult0 \fs22\cf0\f0\charscalex1
00\b {P}\b0 \fs14\cf0\f0\charscalex100\b {tot}\b0 \fs22\cf0\f0\charscalex100\b {
= n}\b0 \fs14\cf0\f0\charscalex100\b {A}\b0 \fs22\cf0\f0\charscalex100\b { . R.
T / V + n}\b0 \fs14\cf0\f0\charscalex100\b {B}\b0 \fs22\cf0\f0\charscalex100\
b { . R .T / V}\b0 \par\pard\li1173\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li1173
\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li1173\ri0\sl-373\slmult0 \fs20\cf0\f1\ch
arscalex100 {Esta ecuación es suma de dos términos, que son la presión que tendría el ga
s A si ocupara }\par\pard\li466\ri0\sl-266\slmult0 \fs20\cf0\f1\charscalex100 {sól
o el mismo volumen y a la misma temperatura y lo mismo para el gas B. Estas son
las que se }\par\pard\li466\ri0\sl-266\slmult0 \fs22\cf0\f1\charscalex100 {defin
en como presión parcial del gas A y presión parcial del gas B en la mezcla.}\par\par
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24\cf0\f0\charscalex100\b \i {LA PRESIÓN PARCIAL DE UN GAS EN UNA
MEZCLA es la presión que }\b0 \i0 \par\pard\li760\ri0\sl-280\slmult0 \fs2
4\cf0\f0\charscalex100\b \i {ejercería ese gas si ocupara el mismo volumen que la
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P}\b0 \fs14\cf0\f0\charscalex100\b {A}\b0 \fs22\cf0\f0\charscalex100\b { = n}\b0
\fs14\cf0\f0\charscalex100\b {A}\b0 \fs22\cf0\f0\charscalex100\b { . R. T / V
}\b0 \fs22\cf0\f1\charscalex100 {y}\fs22\cf0\f0\charscalex100\b { P}\b0
\fs14\cf0\f0\charscalex100\b {B}\b0 \fs22\cf0\f0\charscalex100\b { = n}\b0 \fs14
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r\pard\li1173\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li1173\ri0\sl-213\slmult0 \f
s18\cf0\par\pard\li1173\ri0\sl-360\slmult0 \fs22\cf0\f1\charscalex100 {Venos que
la presión total es igual a la suma de las presiones parciales de los gases A y B
.}\par\pard\li4586\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li4586\ri0\sl-213\slmul
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ri0\sl-213\slmult0 \fs18\cf0\par\pard\li1466\ri0\sl-426\slmult0 \fs24\cf0\f0\cha
rscalex100\b \i {LEY DE DALTON DE LAS PRESIONES PARCIALES: la presión total es igu
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i {la suma de las presiones parciales de todos los gases que componen la mezcla.
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\ri0\sl-426\slmult0 \fs24\cf0\f0\charscalex100\b \i {Cuando se resuelve un probl
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i0\sl-280\slmult0 \fs24\cf0\f0\charscalex100\b \i {es utilizar la ecuación P}\b0
\i0 \fs14\cf0\f0\charscalex100\b \i {tot}\b0 \i0 \fs24\cf0\f0\charscalex100\b \i
{ . V = (n}\b0 \i0 \fs14\cf0\f0\charscalex100\b \i {A}\b0 \i0 \fs24\cf0\f0\char
scalex100\b \i { + n}\b0 \i0 \fs14\cf0\f0\charscalex100\b \i {B }\b0 \i0 \fs24\c
f0\f0\charscalex100\b \i {). R . T y el otro es utilizar presiones parciales.}
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lmult0 \fs18\cf0\par\pard\li466\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li466\ri0\
sl-213\slmult0 \fs18\cf0\par\pard\li466\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li
466\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li466\ri0\sl-213\slmult0 \fs18\cf0\par
\pard\li466\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li466\ri0\sl-213\slmult0 \fs18
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t0 \fs22\cf0\f0\charscalex100\b {FRACCIÓN MOLAR }\b0 \par\pard\li1173\ri0\sl-213\s
lmult0 \fs18\cf0\par\pard\li1173\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li1173\ri
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calex100 {La fracción molar es una forma expresar la composición de
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lmult0 \fs22\cf0\f1\charscalex100 {moles de A sobre el nº de moles totales.}\par\p
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sl-386\slmult0 \fs22\cf0\f1\charscalex100 {De la misma forma se puede definir la
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18\cf0\par\pard\li1173\ri0\sl-333\slmult0 \fs22\cf0\f1\charscalex100 {Se deben t
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ex100 {que }\fs22\cf0\f0\charscalex100\b {no tiene unidades}\b0 \fs22\cf0\f1\cha
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lex100 {C. Si se suman todas las fracciones molares vemos que, sacando divisor c
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e el sólido tenga tanto volumen propio como forma propia.}\par\pard\li1173\ri0\sl-
266\slmult0 \fs18\cf0\f1\charscalex100 {En el estado líquido siguen exis
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sl-373\slmult0 \fs22\cf0\f1\charscalex100 {Un gas real se comportará como ideal a
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li1173\ri0\sl-280\slmult0 \fs22\cf0\f1\charscalex100 {Porque el agua en esas con
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tanto habrá interacciones fuertes entre sus moléculas aunque }\par\pard\li466\ri0\sl
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En cambio el oxígeno a presión atmosférica normal y }\par\pard\li466\
ri0\sl-266\slmult0 \fs20\cf0\f1\charscalex100 {temperatura ambiente se encuentr
a muy lejos de su punto de ebul ición y no hay interacciones }\par\pard\li466\ri
0\sl-266\slmult0 \fs22\cf0\f1\charscalex100 {entre sus moléculas.}\par\pard\li1146
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ard\li1146\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li1146\ri0\sl-213\slmult0 \fs18
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}}}}\pgwsxn11893\pghsxn16840\marglsxn666\margrsxn133\margtsxn666\margbsxn666\par
d\li1146\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li1146\ri0\sl-213\slmult0 \fs18\c
f0\par\pard\li1146\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li1146\ri0\sl-213\slmul
t0 \fs18\cf0\par\pard\li1146\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li1146\ri0\sl
-213\slmult0 \fs18\cf0\par\pard\li1146\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li1
146\ri0\sl-413\slmult0 \fs24\cf2\f0\charscalex100\b {14}\b0 \par\pard\li1173\ri0
\sl-213\slmult0 \fs18\cf0\par\pard\li1173\ri0\sl-213\slmult0 \fs18\cf0\par\pard\
li1173\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li1173\ri0\sl-400\slmult0 \fs22\cf0
\f1\charscalex100 {En la ecuación de estado el volumen y la presión pueden ponerse e
n cualquier unidad, }\par\pard\li466\ri0\sl-266\slmult0 \fs20\cf0\f1\charscalex1
00 {siempre que se respete poner la misma unidad en el estado inicial y el final
. No sucede lo mismo }\par\pard\li466\ri0\sl-266\slmult0 \fs20\cf0\f1\charscalex
100 {con la temperatura, que debe estar en temperatura absoluta, tanto en la ecu
ación de estado como }\par\pard\li466\ri0\sl-266\slmult0 \fs20\cf0\f1\charscalex10
0 {en la general, o en cualquiera de las ecuaciones vistas. En la ecuación general
las unidades de }\par\pard\li466\ri0\sl-266\slmult0 \fs20\cf0\f1\charscalex100
{volumen y presión dependen de las unidades de la constante molar de un gas ideal
(R), como }\par\pard\li466\ri0\sl-266\slmult0 \fs20\cf0\f1\charscalex100 {nosotr
os utilizamos R con unidades de dm}\fs12\cf0\f1\charscalex100 {3}\fs20\cf0\f1\ch
arscalex100 { atm. / K mol el volumen deberá estar en dm}\fs12\cf0\f1\charscale
x100 {3}\fs20\cf0\f1\charscalex100 { y la }\par\pard\li466\ri0\sl-266\slmult0 \
fs22\cf0\f1\charscalex100 {presión en atm.}\par\pard\li1200\ri0\sl-213\slmult0 \fs
18\cf0\par\pard\li1200\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li1200\ri0\sl-213\s
lmult0 \fs18\cf0\par\pard\li1200\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li1200\ri
0\sl-213\slmult0 \fs18\cf0\par\pard\li1200\ri0\sl-213\slmult0 \fs18\cf0\par\pard
\li1200\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li1200\ri0\sl-213\slmult0 \fs18\cf
0\par\pard\li1200\ri0\sl-386\slmult0 \fs24\cf2\f0\charscalex100\b {15}\b0 \par\p
ard\li1173\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li1173\ri0\sl-493\slmult0 \fs22
\cf0\f1\charscalex100 {La temperatura debe estar en temperatura abso
luta porque las expresiones }\par\pard\li466\ri0\sl-293\slmult0 \fs22\cf0\
f1\charscalex100 {matemáticas que se usan sólo son válidas si la temperatura está en Kel
vin, al eliminar la }\par\pard\li466\ri0\sl-293\slmult0 \fs22\cf0\f1\charscalex1
00 {ordenada al origen que quedaba con la temperatura en Celsius se obtiene una
expresión }\par\pard\li466\ri0\sl-293\slmult0 \fs22\cf0\f1\charscalex100 {matemática
más sencil a, y tanto V como P son directamente proporcionale
s a la }\par\pard\li466\ri0\sl-293\slmult0 \fs24\cf0\f1\charscalex100 {tempe
ratura en Kelvin, pero no en otra unidad.}\par\pard\li1213\ri0\sl-213\slmult0 \f
s18\cf0\par\pard\li1213\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li1213\ri0\sl-213\
slmult0 \fs18\cf0\par\pard\li1213\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li1213\r
i0\sl-213\slmult0 \fs18\cf0\par\pard\li1213\ri0\sl-213\slmult0 \fs18\cf0\par\par
d\li1213\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li1213\ri0\sl-213\slmult0 \fs18\c
f0\par\pard\li1213\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li1213\ri0\sl-213\slmul
t0 \fs18\cf0\par\pard\li1213\ri0\sl-333\slmult0 \fs24\cf2\f0\charscalex100\b {16
}\b0 \par\pard\li1173\ri0\sl-480\slmult0 \fs20\cf0\f1\charscalex100 {El volumen
molar de cualquier gas ideal será el mismo siempre que se mida en las mismas }\par
\pard\li466\ri0\sl-266\slmult0 \fs22\cf0\f1\charscalex100 {condiciones de P y T,
pero no tiene por qué ser igual a 22,4 dm}\fs14\cf0\f1\charscalex100 {3}\fs22\cf0
\f1\charscalex100 {, salvo por casualidad. }\par\pard\li1173\ri0\sl-266\slmult0
\fs20\cf0\f1\charscalex100 {Es un error muy común que los alumnos pongan el valor
de 22,4 dm}\fs12\cf0\f1\charscalex100 {3}\fs20\cf0\f1\charscalex100 { como volum
en molar }\par\pard\li466\ri0\sl-266\slmult0 \fs22\cf0\f1\charscalex100 {cuando
las condiciones en que está el gas son distintas de las normales.}\par}