1.

StateallisomersofC4H10Oanddrawthecondensedstructuralformula.

2.

DrawtheexpandedstructuralformulaofC2H6O.

3.

DrawthecondensedstructuralformulaofC 2H4O2. CH3COOH DrawtheskeletalstructuralformulaofC4H8O2.

4.

5.

Underlinedthetertiarycarboninthefollowingcompound. CH3CH(CH3)CH2CH3 Classifytheunderlinedcarbonatominthefollowingorganicmolecule. CH3CH2COOH Carboxylgroup

6.

7.

ClassifyCH3COOCH3toitshomologousseries. Ester

8.

Whatisthefunctionalgroupofamine? NH2 Whatisthedifferencebetweenalcoholandphenolhomologousseries? AlcoholisaliphaticchainwithOH(hydroxylgroup)whereasphenolisbenzeneringwithOH(hydroxyl group)

9.

10. Writethegeneralformulaofalkane. CnH2n+2 11. Classifythefollowinghaloalkanes. CH3CHBrCH2CH3 Secondaryhaloalkane 12. Howalcoholcanbeclassifiedasprimary,secondaryortertiary?

13. Howmanyprimary,secondary,tertiaryandquaternarycarbonatomscontaininthestructuralformulaof CH3CH2(CH3)3CHO? PRIMARY=3SECONDARY=1TERTIARY=1 14. Namethetypeofaminegroupofthefollowingcompound. C3H9N Primaryamine 15. Defineisomerism. Samemolecularformuladifferentstructuralformula 16. HowmanyisomerscanbemadebyC5H12?

17. WhyitisimpossibletodrawthestructuralformulaC3H5? BECAUSEINCOMPLETESTRUCTURE 18. Drawstereoisomersof1,4dimethylcyclohexane.

19. Whichcarbonsexistsaschiralcarboninthefollowingmolecularformula? CH3CHCH3CH(OH)CH3? CH3CHCH3CH(OH)CH3

20. Definenucleophile. Inchemistry,anucleophile(fromnucleusandtheGreekphile,love)isareagentthatformsachemical bondtoitsreactionpartner(theelectrophile)bydonatingbothbondingelectrons.

21. Namethetypeofreactionofthefollowingreaction. CH3CH2CH2CH2BrCH3CH2CH=CH2+HBr eLIMINATION

22. State how many isomers can be formed with the following molecular formulas. Identify the type of isomerism,anddrawthestructuralformulaoftheisomers. i) C5H10

ii)

C5H10O2

23. CompoundXhasthemolecularformulaofC 3H6O. i) DrawLewisstructurefortwoisomersofX.

ii)

Drawcondensedstructuralformulaforbothisomers.

24. DrawtheLewisstructuresandcondensedstructuralformulaeforthetwoalcoholsofmolecularformula C3H8O.Classifyeachasprimary,secondaryortertiary.

I=PRIMARY II=SECONDARY

25. DrawthecondensedstructuralformulaeforthetwoaldehydesofmolecularformulaC 4H8O. CH3CH2CH2CH=O

26. DrawacondensedstructuralformulaforthesinglecarboxylicacidofmolecularformulaC 3H6O2.

27. Classifythefollowingspeciesaselectrophileornucleophile: AlCl3,NH3,OH,CH3CH=CH2,CH3NH2,(CH3)3C+,CH3OH,BH3,I,HCCH Nucleophile=NH3,OH,CH3OH,I,CH3NH2 electrophile=BH3,AlCl3,HCCH,(CH3)3C+,CH3CH=CH2 28. Whichofthefollowingcompoundsisanorganiccompound?

29. Identifythefunctionalgroupsineachofthefollowingmolecules:

a)

amide b)carboxylgroup c)alkeneanddiols d)hydroxylandalkene

30. DrawstructuresofthefiveisomersofC6H14.

31. Proposestructuresthatmeetthefollowingdescriptions: i) TwoisomericesterswiththeformulaC5H10O2

ii)

TwoisomericnitrileswithformulaC4H7N

32. Drawtheeight5carbonalkylgroups(pentylisomers).

33. Identifythecarbonatomsinthefollowingmoleculesasprimary,secondary,tertiary,orquaternary:

34. Drawstructuresofalkanesthatmeetthefollowingdescriptions: i) Analkanewithtwotertiarycarbons

ii)

Analkanethatcontainsanisopropylgroup

iii) Analkanethathasonequaternaryandonesecondarycarbon

35. WhatistheIUPACnameofthefollowingalkane?

2,6dimethyloctane

36. Drawthestructureof3isopropyl2methylhexane. 37. GiveIUPACnamesforthefollowingcompounds:

38. DrawstructurescorrespondingtothefollowingIUPACnames: i) 3,4dimethylnonane

ii)

3ethyl4,4dimethylheptane

iii)

2,2dimethyl4propyloctane

iv)

Addonemorelineinethyltomakeitpropyl 2,2,4trimethylpentane

39. GiveIUPACnamesforthefollowingcycloalkanes:

A)1,4dimethylcyclohexane b)3methyl1propylcyclopentane c) 40. DrawstructurescorrespondingtothefollowingIUPACnames: i) 1,1dimethylcyclooctane

ii) iii)

3cyclobutylhexane 1,2dichlorocyclopentane

iv)

1,3dibromo5methylcyclohexane

41. Whichofthefollowingspeciesislikelytobeanelectrophile,andwhichanucleophile? i) NO2+electrophile ii) CNnucleophile iii) CH3OHnucleophileohelectrophileCh3 42. Whichofthefollowingspeciesislikelytobeanelectrophile,andwhichanucleophile?

i) ii) iii) iv)

HClnucleophile CH3NH2nucleophile CH3SHnucleophile CH3CHOnucleophile