oot Le WaHO-W-bs. ‘jog wonsanb siyp Jo | a8ed uo parund st ajqny. o1pousg ¥ ‘SPU pg soluseD “> pur g “y suono9g Jo YOR, ‘5jannoadsau syoog samsuy ‘oyp UL uM aq O1 a1 D PUP gq “Y sSUORDEg UF suoHsaNb oF siAMsUY ‘syreur ponb Auzeo suonsonb ity “womnaas yoo wo4y suonsond OAL J2"sUy suonsonb AA aHLLJ0 Sisisuo9 woHIes Yea ‘2 wonsg pup gq wonsag “y uonoag ‘isded sin UL suoNzes FAWHLL 238 exOULL, Usif6ug u potomsue aq snus oded siuL (sinoy €) wid 90'g-wd 007 WW WadWd = =19A97-V AMLSIINSHO ‘Y66L NOLLWNIWYxa 12037 G3NVAGY DNOM ONOH ALIUOHLAY SNOLLYNINYXa ONOX ONOH WW uadvd WaHO W-¥6 st seine waava 40 aNa coum 02) oueraq ty ounanyangs) uszongooroe yoo on so ww pn sacgasoipigsjmucse Jo mos 2 589} apa OTe Prnowe des pore stot pace er Jo suoseas ag soye Ba SHAG MO Finds sunny gy sopiodold eonaageanbon oe woos yn “any poops Ar 30} seayeasap a pu srw jo Keno 990 Ks SHIA L (eum oo nage, ued 9 PEBOR wipro mas x Jo s9pUOID 9 AasAUOAS ay Ameo aN NO} ASD HE AHEM "D copra 02) ayes sey gps pono sone ust we yo aKa! oo sopmaiy2y2soses favors 2 ‘ened seaySouNe 9g FH OSL oo Koes URS “yep sat poo ae 4 90 eg ERIE AL muda ny posite wn md ow ame ns oN soc fag oon mca mem som Sos spo or seq) Key's rot 0 8 soo ansey (QTY #9 9t anewe 2 em po Kuo BeNOR NO ONY 9 NouaasSECTION A ‘Answer any TWO questions in this Section, using the AL(C)1 Answer Book. @ Gas containers A and B each contain an ideal gas at low pressure and 298 K. ‘The volume of container A is twice that of container B, but the number of moles of ideal gas contained in A is only half of that in B. @ If the ideal gas in container A is replaced by an equal number ‘of moles of carbon dioxide, which cannor be considered as fan ideal gas under these conditions, how will the pressure in container A change? Explai containers. «iy (6 marks) ‘A colorimetric method ean be used to provide data for the ‘ctermination of the equilibrium constant of the following reaction. ) Fe"(aq) + NCS'(aq) * FeNCS?*(aq) Outline such # method for the determination of the equilibrium constant K, of the above equilibrium. (4 marks) ‘The table below lists the concentration of the reactant C as a function of time at 298 K for the following reaction. © 300 9 10.2 180 1.6. 120 13.5 60. 16.1 20.0 > Plot two graphs to show that the data fit a second order reaction better than a first order reaction. [C} 10? mol dm? Time /'s 0 at 298 K. ‘The rate constant of the above reaction is found to be doubled when the temperature is raised from 298K 10 Determine the rate constant of the react «i Gi) (7 marks) 306 K. Determine the activation energy of the reaction. (Gas constant R = 8.31] K+ mol) HD] GD GOP GO] UST] GO] CO] Gro oe a | oN wa | sa | a> | ma | wo | my aL sor] zor cor] 66| 6] | 96] _ 36 05 | + ser] ot Eisi [evar | S701 [Sast | eusi | Oest Tort or | ax va om | da | aL ma oy te] oe wo] | 99] 99 © as |= Cm] ee vu | ar fa] us TCO OD] Hoo | Tee FOE | HOO | OUST | USGI] CCH | GT Tet | och wx | ow | oa | at ta fay | | at | so ea | 90. oa] sa] rs] 8 os] | ee] al 9s | “ss ter | ooet fOeer | ect Fat | aor | Foor | ezo1 | Tio Tea8 | 8 [ose ax for | an | as eo |v [ea |r | ma x [as | oH ws] es| es] is sr] | | se] ow | se| ec ower |oeoe [ooe2 | cove Lew [HED [STS | OLBS | EONS | TSE Bere | W.OF | OL GE am | sa [as |v eo | uz | ro | Ww | 00 | a x se| se] we] ee tel oc] oe] we] a] 9% i 6 Seat | sv se | Hee | LH OE woe] an at tia “ai ou wo | s | a W °N sj ui} si} _st ey sear squore ante i Boe | o0'6t [oor] TOF! isor ween 1169 w | a | oO a "1 of 6] 8 s £ wor | vin VIA vi 8007 no H z 1 3 pk sq S000" a 8 ano¥ Sa HVE OOrTad m 94-AL-CHEM II-3 (94-AL-CHEM I-2(yeu 9) ‘ay 405 wunosoy ; (1) Ut pourusorep onqea exp woHy ‘sumyxmut aaoge xp Jo aunssaid snodea om pynod shea 9} ey UI “BupxTU UO suoHNjOs Jwopr MOF 40 Op PUE JL “W867 78 “Ad jo suey ‘uy ‘omssaid smodea syy oumuoyep “p:1 = of 01 g oftes 2four Un J pur J Jo ampxrua ¥ Jo “¥ B67 1 suONInjos oxoge ou 30} Woroeyy ofour snsson ounssoud snodea yo yds © yas SH NaHO-W-¥6 w 0 "dz st g aund Jo yoyp ays Md st g aund Jo amnssaud snodea oun “3 867 a¥. “Bury uo suonnjos yeapt aos 4 pur 3 spinbyy ajqiostut om] (ese 6) vammssasd ‘uy aseasout ue ym sesrarzop sor Jo wod Zunfour oy, “farsoosta uBty w sey "OSH patesiuacud. w 0 + SurMoTIOy em Jo YoeO 404 YUNODOY © wn (opm 9) “amyesadury utoos ye euo ages sou mp 01 adonoqre ages S85] qn MON} 1F0AUOD 70U S50P wogies ym urejdal ; ayqers axou Ajqeonadsous st ‘ommdesd 20 puowerp ‘woqre> Jo adonoqre GomM. Om PI ¥'S6e— 51 31 862 18 puoMp 30 uonsnquo> jo BueyD KAyeryUS a, “as6e We orem Jo vonezuodes Jo aBueys Adjeqrus om oreINo]eD @¥oo + @otnt + Boz + HO swonovas Suvmofjoy ‘y-H WaHO-W-¥6. om roy jour py L10g- st Sy aBueyo Kdpeypus oy (4) “09 + WOHHE + Gor + GHD wwonoeas on 305 “Spry a8ueys Adqeqiue am aremoreD 6'se0- QotH © GFOF + OH s'ese- G09 = Fo + Cmmdu|D osi- GH © Ore + Cute) low py Say Toney “np rronnoqpouny Suyxoyoy 2tp teat @