Beruflich Dokumente
Kultur Dokumente
Plasma
Reactor
catalyst
GC
1
6000 200
150
4000
100
2000
Voltage (kV)
Current (mA)
50
0 0
- 50
- 2000
- 100
- 4000
voltage - 150
current
- 6000 - 200
- 25 - 15 -5 5 15 25
Time cycle (µs)
2
90
50 W
80 60 W
80 W
70
Conversion (%)
60
50
40
30
20
10
0 10 20 30 40 50
(a)
80
H2
70 C2
C3
60 C4
S elec tivity (% )
50
40
30
20
10
0
10 20 30 40 50
Methane flow rate (mL/min)
(b)
Figure 3. Effects of flow rates on (a) methane conversion and (b) products distribution
3
Intensity (a.u.) γ−Al2 O3
Al2 O 3
3%Fe/Al2 O 3
3%Cu/Al2 O 3
1% Pt/Al2 O 3
3% Pt/Al2 O 3
3% Ni/Al2 O 3
5%Mn/Al2 O 3
3%Ru/Al2 O 3
0 20 40 60 80
o
2 Theta ( )
(a)
ZSM 5x
Intensity (a.u.)
3%Fe/ ZSM 5x
3%Cu/ ZSM 5x
3%Pt /ZSM 5x
3%Ni/ZSM 5x
0 20 40 60 80
o
2 Theta ( )
(b)
Figure 3. XRD spectra of (a) Al2O3 and (b) zeolite (ZSM 5x)- supported catalyst
4
Figure 4. EDS spectra of 3%Ni/γ-Al2O3