CnLM 26

IIkS1 kC8LLM SL1

Due Date December 2 2011

UNI1S CCNCLN1kA1ICN and S1CICnICML1k

1 uescrlbe Lhe preparaLlon of 100 mL 023 M soluLlon of le(nC
3
)
3
from a sLock soluLlon LhaL ls
42(w/w) le(nC
3
)
3
soluLlon wlLh speclflc gravlLy of 1291 g/mL CalculaLe Lhe molar nC
3

concenLraLlon ln Lhe resulLlng soluLlon Molar mass of le(nC
3
)
3
24186
2 A soluLlon of P
2
SC
4
ls 30 (w/w) acld and lLs speclflc gravlLy ls 00430 g/mL Lxpress Lhe
concenLraLlon of Lhe acld ln Lerms of normallLy and ln ppm Molar mass of P
2
SC
4
9808
3 WhaL volume of 03343 M AgnC
3
wlll be requlred Lo compleLely preclplLaLe Lhe chlorlde lons ln
a 230mL sample of 02000 M 8aCl
2
soluLlon?
4 WhaL should be Lhe normallLy of a sodlum hydroxlde soluLlon lf 2300 mL of Lhe base should be
used Lo compleLely LlLraLe a soluLlon LhaL conLalns 0300 g of a sample LhaL ls 78 (w/w)
P
2
8C
3
P
2
C?
3 Pow many mllllmoles of soluLe are ln 300 mL of a soluLlon LhaL ls 341 ppm CuSC
4
?

kAVIML1k

6 A 7300g sample of a pesLlclde was decomposed wlLh meLalllc sodlum ln alcohol and Lhe
llberaLed chlorlde lon was preclplLaLed as AgCl Lxpress Lhe resulLs of Lhls analysls ln Lerms of
percenL uu1 (C
14
P
9
Cl
3
) based on Lhe recovery of 02100 g of AgCl
7 A 03300g sample conLalnlng chlorlde and lodlde lons gave a sllver hallde preclplLaLe welghlng
03330 g 1hls preclplLaLe was Lhen sLrongly heaLed ln a sLream of Cl
2
gas Lo converL Lhe Agl Lo
AgCl on compleLlon of Lhls LreaLmenL Lhe preclplLaLe welghed 03890g CalculaLe Lhe
percenLage of chlorlde and lodlde ln Lhe sample
8 A 03000g of CC
2
was evolved from a 1300g sample conLalnlng CaCC
3
and k
2
CC
3
only WhaL ls
Lhe percenLage of CaCC
3
and k
2
CC
3
ln Lhe sample?
LUILI8kIA
9 WhaL hydroxlde concenLraLlon ls requlred Lo (a) lnlLlaLe preclplLaLlon of Al
3+
from a 230 x 10
2
M
soluLlon of Al
2
(SC
4
)
3
(b) lower Lhe Al
3+
concenLraLlon ln Lhe foregolng soluLlon Lo 200 x 10
7
M?
ksp30x10
34

10 WhaL LhlocyanaLe concenLraLlon ls requlred Lo (a) lnlLlaLe preclplLaLlon of Ag
+
from a 30 x 10
3

M soluLlon of AgnC
3
(b) lower Lhe Ag
+
concenLraLlon ln Lhe foregolng soluLlon Lo 700 x 10
8
M?
ksp11x10
12