DEAN #37261

(McGHP)

RIGHT

INTERACTIVE

4.41

PROPERTIES OF ATOMS, RADICALS, AND BONDS

top of rh
base of rh
cap height
base of text

TABLE 4.11 Bond Dissociation Energies

The bond dissociation energy (enthalpy change) for a bond A 9 B which is broken through the reaction
AB : A B
is dened as the standard-state enthalpy change for the reaction at a specied temperature, here at 298 K.
That is,
Hf298 Hf298(A) Hf298(B) Hf298(AB)
All values refer to the gaseous state and are given at 298 K. Values of 0 K are obtained by subtracting 32RT
from the value at 298 K.
To convert the tabulated values to kcal/mol, divide by 4.184.
Hf298 ,
kJ/mol

Bond
Aluminum
Al 9 Al
Al 9 As
Al 9 Au
Al 9 Br
Al 9 C
Al 9 Cl
AlCl 9 Cl
AlCl 2 9 Cl
AlO 9 Cl
Al 9 Cu
Al 9 D
Al 9 F
AlF 9 F
AlF2 9 F
AlO 9 F
Al 9 H
Al 9 I
Al 9 Li
Al 9 N
Al 9 O
AlCl 9 O
AlF 9 O
Al 9 P
Al 9 Pd
Al 9 S
Al 9 Se
Al 9 Si
Al 9 Te
Al 9 U

Antimony (continued)
186(9)
180
326(6)
439(8)
255
494(13)
402(8)
372(8)
515(84)
216(10)
291
664(6)
546(42)
544(46)
761(42)
285(6)
368(4)
176(15)
297(96)
512(4)
540(41)
582
213(13)
259(12)
374(8)
334(10)
251(3)
268(10)
326(29)

Antimony
Sb 9 Sb
Sb 9 Br
Sb 9 Cl
Sb 9 F
Sb 9 N

Hf298 ,
kJ/mol

Bond

299(6)
314(59)
360(50)
439(96)
301(50)

Sb 9 O
Sb 9 P
Sb 9 S
Sb 9 Te

372(84)
357
379
277.4(38)
Arsenic

As 9 As
As 9 Cl
As 9 Ga
As 9 H
As 9 N
As 9 O
As 9 P
As 9 S
As 9 Se
As 9 Tl

382(11)
448
209.6(12)
272(12)
582(126)
481(8)
534(13)
(478)
96
198(15)
Astatine

At 9 At

(115.9)
Barium

Ba 9 Br
Ba 9 Cl
Ba 9 F
Ba 9 I
Ba 9 O
Ba 9 OH
Ba 9 S

370(8)
444(13)
487(7)
431(4)
563(42)
477(42)
400(19)
Beryllium

Be 9 Be
Be 9 Br
Be 9 Cl

59
381(84)
388(9)

short
standard
long

DEAN #37261

LEFT

(McGHP)

4.42

INTERACTIVE

top of rh
base of rh

SECTION 4

cap height
base of text

TABLE 4.11 Bond Dissociation Energies (Continued)

Hf298 ,
kJ/mol

Bond
Beryllium (continued)
BeCl 9 Cl
Be 9 F
Be 9 H
Be 9 O
Be 9 S

Bromine
540(63)
577(42)
226(21)
448(21)
372(59)

Bismuth
Bi 9 Bi
Bi 9 Br
Bi 9 Cl
Bi 9 D
Bi 9 F
Bi 9 Ga
Bi 9 H
Bi 9 O
Bi 9 P
Bi 9 Pb
Bi 9 S
Bi 9 Sb
Bi 9 Se
Bi 9 Te
Bi 9 Tl

197(4)
267(4)
305(8)
284
259(29)
159(17)
279
343(6)
280(13)
142(15)
316(5)
251(4)
280(6)
232(11)
121(13)
Boron

B9B
H 3 B 9 BH 3
OB 9 BO
B 9 Br
B9C
B 9 Cl
BO 9 Cl
B9D
B9F
BF 9 F
BF2 9 F
B9H
B9I
B9N
B9O
BCl 9 O
B9P
B9S
B 9 Se
B 9 Si
B 9 Te

Hf298 ,
kJ/mol

Bond

297(21)
146
506(84)
435(21)
448(29)
536(29)
460(42)
341(6)
766(13)
523(63)
557(84)
330(4)
384(21)
389(21)
806(5)
715(41)
347(17)
581(9)
462(15)
289(29)
354(20)

Br 9 Br
Br 9 C
Br 9 CH 3
Br 9 CH 2 Br
Br 9 CHBr2
Br 9 CBr3
Br 9 CCl 3
Br 9 CF3
Br 9 CF2CF3
Br 9 CF2CF2CF3
Br 9 CHF2
Br 9 Cl
Br 9 CN
Br 9 CO 9 C6 H 5
Br 9 F
Br 9 N
Br 9 NF2
Br 9 NO
Br 9 O

193.870(4)
280(21)
284(8)
255(13)
259(17)
209(13)
218(13)
285(13)
287.4(63)
278.2(63)
289
218.84(4)
381
268
233.8(2)
276(21)
222
120.1(63)
235.1(4)
Cadmium

Cd 9 Cd
Cd 9 Br
Cd 9 Cl
Cd 9 F
Cd 9 H
Cd 9 I
Cd 9 In
Cd 9 O
Cd 9 S
Cd 9 Se

11.3(8)
159(96)
206.7(34)
305(21)
69.0(4)
138(21)
138
142(42)
196
310
Calcium

Ca 9 Ca
Ca 9 Br
Ca 9 Cl
Ca 9 F
Ca 9 H
Ca 9 I
Ca 9 O
Ca 9 S

14.98(46)
321(23)
398(13)
527(21)
167.8
285(63)
464(84)
314(19)
Carbon

C9C
H 3C 9 CH 3

607(21)
368

short
standard
long

DEAN #37261

(McGHP)

RIGHT

INTERACTIVE

4.43

PROPERTIES OF ATOMS, RADICALS, AND BONDS

cap height
base of text

TABLE 4.11 Bond Dissociation Energies (Continued)

Bond

Hf298 ,
kJ/mol

Hf298 ,
kJ/mol

Bond

Carbon (continued)
(CH 3 )2C 9 CH 3
(CH 3 )2C 9 C(CH 3 )2
CH 3 9 C6 H 5
CH 3 9 CH 2C6H 5
(CH 3 )3C 9 C(C6 H 5 )3
CH 3 9 allyl
CH 3 9 vinyl
CH 3 9 C # CH
CH 2 " CH 9 CH " CH 2
HC # C 9 C # CH
H 2C " CH 2
HC # CH
CH 3 9 CN
CH 3 9 CH 2CN
CH 3 9 CH(CH 3 )CN
CH 3 9 C(C6 H 5 )CN(CH 3 )
CH 3CH 2 9 CH 2CN
NC 9 CN
C6 H 5 9 C6 H 5
CH 3 9 CF3
CH 2 F 9 CH 2 F
CF3 9 CF3
CF2 " CF2
CF3 9 CN
CH 3 9 CHO
CH 3 9 CO
CH 3CO 9 CF3
CH 3CO 9 COCH 3
C6 H 5CO 9 COC6H 5
Aryl 9 CH 2COCH 2 9 aryl
C6 H 5CH 2 9 COOH
(C6 H 5CH 2)2CH 9 COOH
C 9 Cl
C9F
C9H
C9I
C9N
CF3 9 NF2
CH 3 9 NH 2
C6 H 5CH 2 9 NH 2
CH 3 9 NHC6H 5
CH 3 9 N(CH 3 )C6 H 5
C6H 5CH 2 9 NHCH 3
C6H 5CH 2 9 N(CH 3 )2
CH 3 9 (N " NCH 3 )
C2 H 5 9 (N " NC2 H 5)
(CH 3 )3C 9 N " NC(CH 3 )3
Aryl 9 CH 2N " NCH 2 9 aryl

top of rh
base of rh

Carbon (continued)
335
282.4
389
301
63
301
121
490
418
628
682
962
506(21)
305(8)
331(8)
251
321.8(71)
603(21)
418
423.4(46)
368(8)
406(13)
318(13)
501
314
342.7
308.8
280(8)
277.8
273.6
284.9
248.5
397(29)
536(21)
337.2(8)
209(21)
770(4)
272(13)
331(13)
301(4)
285
272
289(4)
255(4)
219.7
209.2
182.0
157

CF3 9 (N " NCF3 )

H 2C " NH
HC # N
CH 3 9 NO
C2 H 5 9 NO
C3 H 7 9 NO
(CH3 )2CH 9 NO
n-C4 H 9 9 NO
C6 H 5 9 NO
Cl 3C 9 NO
F3C 9 NO
C6 F5 9 NO
NC 9 NO
CH 3 9 NO2
C2 H 5 9 NO2
C9O
CH 3 9 OCH 3
CH 3 9 OC6 H 5
CH 3 9 OCH 2C6 H 5
C2 H 5 9 OC6 H 5
C6 H 5CH 2 9 OCOCH 3
C6 H 5CH 2 9 OCOC6 H 5
CH 3CO 9 OCH 3
CH 3 9 OSOCH 3
CH 2 " CHCH 2 9 OSOCH 3
C6 H 5CH 2 9 OSOCH 3
C"O
H 2C " O
OC " O
SC " O
C#O
C9P
C9S
CH 3 9 SH
CH 3 9 SC6 H 5
CH 3 9 SCH 2C6 H 5
OC 9 S
C 9 Se

231.0
644(21)
937
174.9(38)
175.7(54)
167.8(75)
171.5(54)
215.5(42)
215.5(42)
134
130
211.3(42)
121(13)
247(13)
259
1076.5(4)
335
381
280
213
285
289
406
280
209
222
749
732
532.2(4)
628
1075
513(8)
699(8)
305(13)
285(8)
247(8)
310.4
582(96)

Cerium
Ce 9 Ce
Ce 9 F
Ce 9 N
Ce 9 O
Ce 9 S
Ce 9 Se
Ce 9 Te

243(21)
582(42)
519(21)
795(13)
573(13)
495(15)
389(42)

short
standard
long

DEAN #37261

LEFT

(McGHP)

4.44

INTERACTIVE

top of rh
base of rh

SECTION 4

cap height
base of text

TABLE 4.11 Bond Dissociation Energies (Continued)

Hf298 ,
kJ/mol

Bond
Cesium
Cs 9 Cs
Cs 9 Br
Cs 9 Cl
Cs 9 F
Cs 9 H
Cs 9 I
Cs 9 O
Cs 9 OH

Chromium (continued)
41.75(93)
397.5(42)
439(21)
514(8)
178.1(38)
339(4)
297(25)
385(13)

Chlorine
Cl 9 Cl
Cl 9 C
Cl 9 CH 3
Cl 9 CH3
Cl 9 C(CH 3 )3
Cl 9 CH 2Cl
Cl 9 CCl 3
Cl 9 CF3
Cl 9 CCl 2 F
Cl 9 CClF2
Cl 9 CF2CF2
Cl 9 CH " CH 2
Cl 9 CN
Cl 9 COCl
Cl 9 COCH 3
Cl 9 COC6 H 5
Cl 9 Cl
Cl 9 ClO
O3Cl 9 ClO4
Cl 9 F
O3Cl 9 F
Cl 9 N
Cl 9 NCl
Cl 9 NCl 2
Cl 9 NF2
Cl 9 NH 2
Cl 9 NO
Cl 9 NO2
Cl 9 O
OCl 9 O
O2Cl 9 O
Cl 9 P
Cl 9 SiCl 3

242.580(16)
338(42)
339(21)
213
328.4
310(13)
293(21)
360(33)
305(8)
318(8)
346.0(71)
351
439
328
349.4
310(13)
393
143.3(42)
243
250.54(8)
255
389(50)
280
381
ca. 134
251(25)
159(6)
142(4)
272(4)
243(13)
201(4)
289(42)
464
Chromium

Cr 9 Cr
Cr 9 Br
Cr 9 Cl

Hf298 ,
kJ/mol

Bond

155(21)
328(24)
366(24)

Cr 9 Cu
Cr 9 F
Cr 9 Ge
Cr 9 H
Cr 9 I
Cr 9 N
Cr 9 O
OCr 9 O
O2Cr 9 O
Cr 9 S

155(21)
437(20)
170(29)
280(50)
287(24)
378(19)
427(29)
531(63)
477(84)
339(21)
Cobalt

Co 9 Co
Co 9 Br
Co 9 Cl
Co 9 Cu
Co 9 F
Co 9 Ge
Co 9 I
Co 9 O
Co 9 S

167(25)
331(42)
398(8)
162(17)
435(63)
239(25)
235(81)
368(21)
343(21)
Copper

Cu 9 Cu
Cu 9 Br
Cu 9 Cl
Cu 9 F
Cu 9 Ga
Cu 9 Ge
Cu 9 H
Cu 9 I
Cu 9 Ni
Cu 9 O
Cu 9 S
Cu 9 Se
Cu 9 Sn
Cu 9 Te

202(4)
331(25)
383(21)
431(13)
216(15)
209(21)
280(8)
197(21)
206(17)
343(63)
285(17)
293(38)
177(17)
176(38)
Curium

Cm 9 O

736
Dysprosium

Dy 9 F
Dy 9 O
Dy 9 Se
Dy 9 Te

527(21)
611(42)
322(42)
234(42)

short
standard
long

DEAN #37261

(McGHP)

RIGHT

INTERACTIVE

4.45

PROPERTIES OF ATOMS, RADICALS, AND BONDS

cap height
base of text

TABLE 4.11 Bond Dissociation Energies (Continued)

Hf298 ,
kJ/mol

Bond

Hf298 ,
kJ/mol

Bond

Erbium
Er 9 F
Er 9 O
Er 9 S
Er 9 Se
Er 9 Te

top of rh
base of rh

Gallium (continued)
565(17)
611(13)
418(42)
326(42)
239(42)

Ga 9 O
Ga 9 P
Ga 9 Sb
Ga 9 Te

285(63)
230(13)
209(13)
251(25)
Germanium

Europium
Eu 9 Eu
Eu 9 Cl
Eu 9 F
Eu 9 O
Eu 9 S
Eu 9 Se
Eu 9 Te

33.5(165)
ca. 326
528(18)
557(13)
364(15)
301(15)
243(15)
Fluorine

F9F
F 9 F
F 9 CH 3
F 9 C(CH 3 )3
F 9 C6 H 5
F 9 CCl 3
F 9 CCl 2 F
F 9 CClF2
F 9 CF3
F 9 COCH 3
F 9 FO
F 9 FO2
F9N
F 9 NF
F 9 NF2
F 9 NO
F 9 NO2

156.9(96)
251
452(21)
439
485
444(21)
460(25)
490(25)
523(17)
498
272(13)
81.0
301(42)
318(25)
243(8)
235.6(42)
197(25)
Gadolinium

Gd 9 F
Gd 9 O
Gd 9 S
Gd 9 Se

590(27)
716(17)
525(15)
431(15)
Gallium

Ga 9 Ga
Ga 9 Br
(CH 3 )3Ga 9 CH 3
Ga 9 Cl
Ga 9 F
Ga 9 H
Ga 9 I

138(21)
444(17)
253
481(13)
577(15)
274
339(10)

Ge 9 Ge
Ge 9 Br
Ge 9 Cl
Ge 9 F
Ge 9 H
Ge 9 O
Ge 9 S
Ge 9 Se
Ge 9 Si
Ge 9 Te

274(21)
255(29)
431.8(4)
485(21)
321.3(8)
662(13)
551.0(25)
490(21)
301(21)
402(8)
Gold

Au 9 Au
Au 9 B
Au 9 Be
Au 9 Bi
Au 9 Cl
Au 9 Co
Au 9 Cr
Au 9 Cu
Au 9 Fe
Au 9 Ga
Au 9 Ge
Au 9 H
Au 9 La
Au 9 Li
Au 9 Mg
Au 9 Mn
Au 9 Ni
Au 9 Pb
Au 9 Pd
Au 9 Rh
Au 9 S
Au 9 Si
Au 9 Sn
Au 9 Te
Au 9 U

221.3(21)
368(11)
285(8)
293(84)
343(10)
215(13)
215(6)
232(9)
187(17)
294(15)
277(15)
314(10)
80(5)
68.0(16)
243(42)
185(13)
274(21)
130(42)
143(21)
231(29)
418(25)
312(12)
244(17)
247(67)
318(29)
Hafnium

Hf 9 C
Hf 9 N
Hf 9 O

548(63)
534(29)
791(8)

short
standard
long

DEAN #37261

LEFT

(McGHP)

4.46

INTERACTIVE

top of rh
base of rh

SECTION 4

cap height
base of text

TABLE 4.11 Bond Dissociation Energies (Continued)

Hf298 ,
kJ/mol

Bond
Hydrogen

Hydrogen (continued)

H9H
H 9 2 H or H 9 D
2 H 9 2 H or D 9 D
H 9 Br
H9C
H 9 CH
H 9 CH 2
H 9 CH 3
2
H 9 C2 H 3 or D 9 CD3
H 9 C # CH
H 9 CH " CH 2
H 9 CH 2CH 3
H 9 CH 2C # CH
H 9 CH 2CH " CH 2
H 9 cyclopropyl
H 9 CH 2CH 2CH 3
H 9 CH(CH 3 )2
H 9 cyclobutyl
H 9 CH 2CH(CH 3 )2
H 9 CH(CH 3 )CH 2CH 3
H 9 C(CH 3 )3

436.002(4)
439.446(4)
443.546(4)
365.7(21)
337.2(8)
452(33)
473(4)
431(8)
442.75(25)
523(4)
427
410(4)
392.9(50)
356
423(13)
410(8)
395.4
397(13)
360
397(4)
381

H9

339(4)
CH " CH2
335(4)

H 9 CH
CH " CH2

H 9 CH2

CH3
414(4)

C
CH3

H 9 CHCl2
H 9 CCl 3
H 9 CBr3
H 9 CCl2CHCl2
H 9 CH 2 F
H 9 CHF2
H 9 CF3
H 9 CF2Cl
H 9 CH 2CF3
H 9 CF2CH 3
H 9 CF2CF3
H 9 CH 2I
H 9 CHI 2
H 9 CN
H 9 CH 2CN
H 9 CH(CH 3 )CN
H 9 C(CH 3 )2CN
H 9 CH 2 NH 2
H 9 CH 2Si(CH 3 )3
H 9 CH 2COCH 3
H 9 Cl
H 9 CO
H 9 CHO
H 9 COOH
H 9 COCH 3
H 9 COCH 2CH 3
H9

343(4)

H9

Hf298 ,
kJ/mol

Bond

CH3

H 9 C(CH 3 )2CH " CH 2

H 9 cyclopentyl
H 9 CH 2C(CH 3 )3
H 9 C6 H 5
H 9 CH 2C6 H 5
H 9 C(C6 H 5 )3

331
395(42)
418(4)
431
356(4)
314

H9

310

H 9 cyclohexyl
H 9 cycloheptyl
H 9 norbornyl
H 9 CH 2Br
H 9 CHBr2
H 9 CH 2Cl

399.6(42)
387.0(42)
406(13)
410(25)
435
423

O
H 9 COC6 H 5
H 9 COCF3
H9F
H9I
H9N
H 9 NH
H 9 NH 2
H 9 NHCH 3
H 9 N(CH 3 )2
H 9 NHC6 H 5
H 9 N(CH 3 )C6 H 5
HNF2
H 9 N3
H 9 NO
H9O
H 9 OH
H 9 OCH 3
H 9 OCH 2CH 3
H 9 OC(CH 3 )3
H 9 OC6 H 5
H 9 ONO

414.2
377(8)
377(8)
393(8)
423(8)
423(8)
444(13)
435(4)
446(45)
416(4)
431(63)
431(8)
431(8)
540(25)
ca. 389
377(8)
364(8)
397(8)
414(4)
393(75)
431.8(4)
126(8)
364(4)
377
364(4)
364(4)
385
364(4)
381(8)
568.6(13)
298.7(8)
314(17)
377(8)
435(8)
431(8)
397(8)
335(13)
310(13)
318(13)
356
205
428.0(21)
498.7(8)
436.8(42)
436.0
439(4)
368(25)
327.6(25)

short
standard
long

DEAN #37261

(McGHP)

RIGHT

INTERACTIVE

4.47

PROPERTIES OF ATOMS, RADICALS, AND BONDS

cap height
base of text

TABLE 4.11 Bond Dissociation Energies (Continued)

Hf298 ,
kJ/mol

Bond

Iridium

423.4(25)
374(8)
469(17)
460(17)
431(17)
343(29)
344(12)
381(4)
ca. 368
305(2)
298.49(46)
393(13)
377(13)
268(2)

100(8)
418(21)
439(8)
506(15)
360(21)
197.9(85)
289(17)
152(11)
247(17)
218(17)
Iodine

I9I
I 9 Br
I 9 CH 3
I 9 C2 H 5
I 9 CH(CH 3 )2
I 9 C(CH 3 )3
I 9 CH 2CF3
I 9 CF2CH 3
I 9 C3 F7
I 9 CH " CHCH 3
I 9 C6 H 5
I 9 C6 F5
I 9 Cl
I 9 COCH 3
I 9 CN
I9F
I9N
I 9 NO
I 9 NO2
I9O

Ir 9 O
Ir 9 Si

352(21)
463(21)
Iron

Fe 9 Fe
Fe 9 Br
Fe 9 Cl
Fe 9 O
Fe 9 S
Fe 9 Si

100(21)
247(96)
ca. 352
409(13)
339(21)
297(25)
Krypton

Kr 9 Kr
Kr 9 F

Indium
In 9 In
In 9 Br
In 9 Cl
In 9 F
In 9 O
In 9 P
In 9 S
In 9 Sb
In 9 Se
In 9 Te

Hf298 ,
kJ/mol

Bond

Hydrogen (continued)
H 9 ONO2
H 9 OOH
H 9 OOCCH 3
H 9 OOCCH 2CH 3
H 9 OOCC3 H 7
H9P
H9S
H 9 SH
H 9 SCH 3
H 9 Se
H 9 Si
H 9 SiH 3
H 9 Si(CH 3 )3
H 9 Te

top of rh
base of rh

152.549(8)
179.1(4)
232(13)
223.8
222
207.1
234(4)
216(4)
209(4)
172
268(4)
276
213.3(4)
219.7
305(4)
280(4)
159(17)
71(4)
75(4)
184(21)

5.4(8)
54
Lanthanum

La 9 La
La 9 C
La 9 F
La 9 N
La 9 O
La 9 S

247(21)
506(63)
598(42)
519(42)
799(13)
577(25)
Lead

Pb 9 Pb
Pb 9 Br
Pb(CH 3 )3 9 CH 3
Pb 9 Cl
Pb 9 F
Pb 9 H
Pb 9 I
Pb 9 O
Pb 9 S
Pb 9 Se
Pb 9 Te

339(25)
247(38)
207(42)
301(29)
356(8)
176(21)
197(38)
378(4)
346.0(17)
303(4)
251(13)
Lithium

Li 9 Li
Li 9 Br
Li 9 Cl
Li 9 F
Li 9 H
Li 9 I
Li 9 Na
Li 9 O
Li 9 OH

106(4)
423(21)
469(13)
577(21)
247
352(13)
88
341(6)
427(21)

short
standard
long

DEAN #37261

LEFT

(McGHP)

4.48

INTERACTIVE

top of rh
base of rh

SECTION 4

cap height
base of text

TABLE 4.11 Bond Dissociation Energies (Continued)

Hf298 ,
kJ/mol

Bond
Lutetium
Lu 9 Lu
Lu 9 F
Lu 9 O
Lu 9 S
Lu 9 Te

Hf298 ,
kJ/mol

Bond
Molybdenum

142(34)
569(42)
695(13)
507(15)
326(17)

Mo 9 I
Mo 9 O
MoO 9 O
MoO2 9 O

372
607(34)
678(84)
565(84)
Neodymium

Magnesium
Mg 9 Mg
Mg 9 Br
Mg 9 Cl
Mg 9 F
MgF 9 F
Mg 9 H
Mg 9 I
Mg 9 O
Mg 9 OH
Mg 9 S

8.522(4)
297(63)
318(13)
462(21)
569(42)
197(50)
ca. 285
394(35)
238(21)
310(75)

42(29)
314(10)
361(10)
423(15)
283(10)
159(17)
402(34)
301(17)
201(13)
Mercury

Hg 9 Hg
Hg 9 Br
CH 3 9 HgCH 3
C2 H 5 9 HgC2 H 5
C3 H 7 9 HgC3 H 7
Isopropyl 9 Hgisopropyl
C6 H 5 9 HgC6 H 5
Hg 9 Cl
Hg 9 F
Hg 9 H
Hg 9 I
Hg 9 K
Hg 9 Na
Hg 9 S
Hg 9 Se
Hg 9 Te

545(13)
703(34)
474(15)
385(17)
305(17)
Neon

Ne 9 Ne

3.93
Neptunium

Np 9 O

Manganese
Mn 9 Mn
Mn 9 Br
Mn 9 Cl
Mn 9 F
Mn 9 I
Mn 9 Cu
Mn 9 O
Mn 9 S
Mn 9 Se

Nd 9 F
Nd 9 O
Nd 9 S
Nd 9 Se
Nd 9 Te

17.2(21)
72.8(42)
240.6
182.8(42)
197.1
170.3
285
100(8)
130(38)
39.8
38
8.24(21)
6.7
213
(167)
(142)

720(29)
Nickel

Ni 9 Ni
Ni 9 Br
Ni 9 Cl
Ni 9 F
Ni 9 H
Ni 9 I
Ni 9 O
Ni 9 S
Ni 9 Si

261.9(25)
360(13)
372(21)
435
289(13)
293(21)
391.6(38)
360(21)
318(17)
Niobium

Nb 9 O

753(13)
Nitrogen

N9N
N 9 Br
ON 9 Br
N 9 Cl
ON 9 Cl
O2 N 9 Cl
N9F
FN 9 F
F2 F 9 N
ON 9 F
O2 N 9 F

945.33(59)
276(21)
28.7(15)
389(50)
159(6)
142(4)
301(42)
318(21)
243(8)
236(4)
188(21)

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DEAN #37261

(McGHP)

RIGHT

INTERACTIVE

4.49

PROPERTIES OF ATOMS, RADICALS, AND BONDS

cap height
base of text

TABLE 4.11 Bond Dissociation Energies (Continued)

Hf298 ,
kJ/mol

Bond

Oxygen (continued)
159(17)
88(4)
297(8)
271
264
213
38
480.7(42)
39.8(8)
57.3(21)
456(42)
946
630.57(13)
481
167
305
617(21)
464(21)

Osmium
O3Os 9 O

301(21)
Oxygen

O9O
O 9 Br
HO 9 CH 3
HO 9 CH " CH 2
HO 9 CH 2CH " CH 2
HO 9 C6 H 5
HO 9 CH 2C6 H 5
HO 9 CHO
HO 9 COCH 3
HO 9 COC2 H 5
O 9 Cl
HO 9 Cl
O9F
O 9 FO
FO 9 OF
O9I
HO 9 I
O9N
HO 9 NCH 3
HO 9 OC(CH 3 )3
HO 9 OH
O 9 OH
CF3O 9 OCF3
CH 3O 9 OCH 3

Hf298 ,
kJ/mol

Bond

Nitrogen (continued)
N9I
F2 N 9 NF2
H 2 N 9 NH 2
H 2 N 9 NHCH 3
H 2N 9 N(CH 3 )2
H 2N 9 NHC6 H 5
HN 9 N2
ON 9 N
ON 9 NO2
O2 N 9 NO2
HN " NH
N#N
N9O
HN " O
NN 9 O
ON 9 O
N9P
N9S

top of rh
base of rh

498.34(20)
235.1(4)
377(13)
364
456
431
322
402(13)
452(21)
180
272(4)
251(13)
222(17)
467
261(84)
184(21)
234(13)
630.57(13)
209
192(8)
213.8(21)
268(4)
192
157.3(8)

C2 H 5O 9 OC2 H 5
C3 H 7O 9 OC3 H 7

159
155
Palladium

Pd 9 O

234(29)
Phosphorus

P9P
P 9 Br
P9C
P 9 Cl
P9F
P9H
P9N
P9O
Br3 P " O
Cl 3 P " O
F3 P " O
P9S
P"S
P 9 Se
P 9 Te

490(11)
266.5
513(8)
289(42)
439(96)
343(29)
617(21)
596.6
498(21)
510(21)
544(21)
346.0(17)
347
363(10)
298(10)
Platinum

Pt 9 B
Pt 9 H
Pt 9 O
Pt 9 P
Pt 9 Si

478(17)
352(38)
347(34)
417(17)
501(18)
Potassium

K9K
K 9 Br
K 9 Cl
K9F
K9H
K9I
K 9 Na
K9O
K 9 OH

57.3(42)
383(8)
427(8)
497.5(25)
183(15)
331(13)
63.6(29)
239(34)
343(8)
Praseodymium

Pr 9 F
Pr 9 O
Pr 9 S

582(46)
753(17)
492.5(46)

short
standard
long

DEAN #37261

LEFT

(McGHP)

4.50

INTERACTIVE

top of rh
base of rh

SECTION 4

cap height
base of text

TABLE 4.11 Bond Dissociation Energies (Continued)

Hf298 ,
kJ/mol

Bond
Praseodymium (continued)
Pr 9 Se
Pr 9 Te

446(23)
326(42)
Promethium

Pm 9 F
Pm 9 O
Pm 9 S
Pm 9 Se
Pm 9 Te

540(42)
674(63)
423(63)
339(63)
255(63)

Scandium
Sc 9 Sc
Sc 9 Br
Sc 9 C
Sc 9 Cl
Sc 9 F
Sc 9 N
Sc 9 O
Sc 9 S
Sc 9 Se
Sc 9 Te

Radium
Ra 9 Cl
Rhodium
285(21)
476(21)
583.7(63)
377(63)
395(18)
391(15)
Rubidium
Rb 9 Rb
Rb 9 Br
Rb 9 Cl
Rb 9 F
Rb 9 H
Rb 9 I
Rb 9 O
Rb 9 OH

45.6(21)
389(13)
448(21)
494(21)
167(21)
335(13)
255(84)
351(8)
Ruthenium

Ru 9 O
O3 Ru 9 O
Ru 9 Si
Ru 9 Th

481(63)
439
397(21)
592(42)
Samarium

Sm 9 Cl
Sm 9 F
Sm 9 O
Sm 9 S
Sm 9 Se
Sm 9 Te

163(21)
444(63)
393(63)
318
589(13)
469(84)
674(13)
478(13)
385(17)
289(17)
Selenium

343(75)

Rh 9 Rh
Rh 9 B
Rh 9 C
Rh 9 O
Rh 9 Si
Rh 9 Ti

Hf298 ,
kJ/mol

Bond

423(13)
531(18)
619(13)
389
331(15)
272(15)

Se 9 Se
Se 9 Br
Se 9 C
Se 9 Cl
Se 9 F
Se 9 H
Se 9 N
Se 9 O
Se 9 P
Se 9 S
Se 9 Si
Se 9 Te

332.6(4)
297(84)
582(96)
322
339(42)
305(2)
381(63)
423(13)
364(10)
381(21)
531(25)
268(8)
Silicon

Si 9 Si
Si 9 Br
Si 9 C
Si 9 Cl
Si 9 F
Si 9 H
Si 9 I
Si 9 N
Si 9 O
Si 9 S
Si 9 Se
H 3Si 9 SiH 3
(CH 3 )3Si 9 Si(CH 3 )3
(Aryl)3Si 9 Si(aryl)3
Si 9 Te

327(10)
343(50)
435(21)
456(42)
540(13)
298.49(46)
339(84)
439(38)
798(8)
619(13)
531(25)
339(17)
339
368(31)
506(38)
Silver

Ag 9 Ag
Ag 9 Au
Ag 9 Bi

163(8)
203(9)
193(42)

short
standard
long

DEAN #37261

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RIGHT

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4.51

PROPERTIES OF ATOMS, RADICALS, AND BONDS

cap height
base of text

TABLE 4.11 Bond Dissociation Energies (Continued)

Hf298 ,
kJ/mol

Bond

Tantalum
293(29)
341.4
176(8)
354(16)
180(15)
175(21)
226(8)
234(29)
176(17)
213(84)
136(21)
293(96)

Ta 9 N
Ta 9 O

Te 9 B
Te 9 H
Te 9 I
Te 9 O
Te 9 P
Te 9 S
Te 9 Se

Strontium
332(19)
406(13)
542(7)
163(8)
263(42)
454(15)
381(42)
314(21)

Tb 9 F
Tb 9 O
Tb 9 S
Tb 9 Te

561(42)
707(13)
515(42)
339(42)
Thallium

Tl 9 Tl
Tl 9 Br
Tl 9 Cl
Tl 9 F
Tl 9 H
Tl 9 I

63
333.9(17)
372.8(21)
445(19)
188(8)
272(8)
Thorium

Th 9 Th
Th 9 C
Th 9 N
Th 9 O
Th 9 P

289
484(25)
577.4(21)
854(13)
377
Thullium

Sulfur
S9S
S 9 Cl
S9F
O2S 9 F
S9N
S9O
OS 9 O
O2S 9 O
HS 9 SH

354(20)
268(2)
193(42)
391(8)
298(10)
339(21)
268(8)
Terbium

77.0
370(13)
410(8)
481(8)
201(21)
301(8)
63.6(29)
257(17)
381(13)
59(4)

Sr 9 Br
Sr 9 Cl
Sr 9 F
Sr 9 H
Sr 9 I
Sr 9 O
Sr 9 OH
Sr 9 S

611(84)
805(13)
Tellurium

Sodium
Na 9 Na
Na 9 Br
Na 9 Cl
Na 9 F
Na 9 H
Na 9 I
Na 9 K
Na 9 O
Na 9 OH
Na 9 Rb

Hf298 ,
kJ/mol

Bond

Silver (continued)
Ag 9 Br
Ag 9 Cl
Ag 9 Cu
Ag 9 F
Ag 9 Ga
Ag 9 Ge
Ag 9 H
Ag 9 I
Ag 9 In
Ag 9 O
Ag 9 Sn
Ag 9 Te

top of rh
base of rh

429(6)
255
343(5)
71
464(21)
521.70(13)
551.4(84)
348.1(42)
272(21)

Tm 9 F
Tm 9 O
Tm 9 S
Tm 9 Se
Tm 9 Te

569(42)
557(13)
368(42)
276(42)
276(42)
Tin

Sn 9 Sn
Sn 9 Br

195(17)
339(4)

short
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long

DEAN #37261

LEFT

(McGHP)

4.52

INTERACTIVE

top of rh
base of rh

SECTION 4

cap height
base of text

TABLE 4.11 Bond Dissociation Energies (Continued)

Hf298 ,
kJ/mol

Bond
Tin (continued)
BrSn 9 Br
Br3Sn 9 Br
(C2 H 5 )3Sn 9 C2 H 5
Sn 9 Cl
Sn 9 F
Sn 9 H
Sn 9 I
Sn 9 O
Sn 9 S
Sn 9 Se
Sn 9 Te

Hf298 ,
kJ/mol

Bond
Vanadium (continued)

326
272
ca. 238
406(13)
467(13)
267(17)
234(42)
548(21)
464(3)
401.3(59)
319.2(8)

V 9 Cl
V9F
V9N
V9O
V9S
V 9 Se

477(63)
590(63)
477(8)
644(21)
490(16)
347(21)
Xenon

Xe 9 Xe
Xe 9 F
Xe 9 O

6.53(30)
13.0(4)
36.4

Titanium
Ytterbium
Ti 9 Ti
Ti 9 Br
Ti 9 C
Ti 9 Cl
Ti 9 F
Ti 9 H
Ti 9 I
Ti 9 N
Ti 9 O
Ti 9 S
Ti 9 Se
Ti 9 Te

141(21)
439
435(25)
494
569(34)
ca. 159
310(42)
464
662(16)
426(8)
381(42)
289(17)
Tungsten

W 9 Cl
W9F
W9O
OW 9 O
O2W 9 O
W9P

423(42)
548(63)
653(25)
632(84)
598(42)
305(4)
Uranium

U9O
OU 9 O
O2 U 9 O
U9S

761(17)
678(59)
644(88)
523(10)
Vanadium

V9V
V 9 Br
V9C

242(21)
439(42)
469(63)

Yb 9 Cl
Yb 9 F
Yb 9 H
Yb 9 O
Yb 9 S

322
521(10)
159(38)
397.9(63)
167
Yttrium

Y9Y
Y 9 Br
Y9C
Y 9 Cl
Y9F
Y9N
Y9O
Y9S
Y 9 Se
Y 9 Te

159(21)
485(84)
418(63)
527(42)
605(21)
481(63)
715.1(30)
528(11)
435(13)
339(13)
Zinc

Zn 9 Zn
Zn 9 Br
C2 H 5C 9 C2 H 5
Zn 9 Cl
Zn 9 F
Zn 9 H
Zn 9 I
Zn 9 O
Zn 9 S
Zn 9 Se
Zn 9 Te

29
142(29)
ca. 201
229(20)
368(63)
85.8(21)
138(29)
284.1
205(13)
136(13)
205

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long

DEAN #37261

(McGHP)

RIGHT

INTERACTIVE

PROPERTIES OF ATOMS, RADICALS, AND BONDS

4.53

cap height
base of text

TABLE 4.11 Bond Dissociation Energies (Continued)

Hf298 ,
kJ/mol

Bond

Bond

Zirconium
Zr 9 C
Zr 9 F
Zr 9 N

top of rh
base of rh

Hf298 ,
kJ/mol

Zirconium (continued)
561(25)
623(63)
565(25)

Zr 9 O
Zr 9 S

760(8)
575(17)

Source: T. L. Cottrell, The Strengths of Chemical Bonds, 2d ed., Butterworth, London, 1958; B. deB. Darwent, National
Standard Reference Data Series, National Bureau of Standards, no. 31, Washington, 1970; S. W. Benson, J. Chem. Educ.
42:502 (1965); and J. A. Kerr, Chem. Rev. 66:465 (1966).

short
standard