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pH and its Importance

The pH (hydrogen ion potential) of a solution is defined as


pH = - log10 (H+) , where (H+) is the hydrogen ion concentration. pH
scale (from potential of Hydrogen) is the logarithm of the reciprocal of
hydrogen- ion concentration in gram atoms per litre and provides a
measure on a scale from 0 to 14 of the acidity or alkalinity of a solution
(where 7 is neutral and greater than 7 is more basic and less than 7 is
more acidic). When pH goes off microbes in the blood can change
shape, mutate, become pathogenic, constructive enzymes turn
destructive, oxygen delivery to cells suffer, mineral assimilation can get
thrown off and organs of your body can become compromised, like your
heart or brain. The pH balance of the human bloodstream is recognized
by all medical physiology texts as one of the most important biochemical
balances in all of human body chemistry. All biochemical reactions and
electrical (life) energy are under pH control. The higher (more alkaline)
the pH of a substance or solution, the more electrical resistance that
substance or solution holds. Therefore, electricity travels slower with
higher pH.

Ideally, the pH of the blood should be


maintained at 7.4. If the pH drops below 6.8 or rises above 7.8, death
may occur. Buffers in the blood to protect against large changes in
pH. If, for instance, the pH of the blood and external fluid is too
low (too many H+ ions), then an excess of H+ ions will enter the cell.
In order to maintain the proper chemical composition inside the
cells, the chemical composition of the fluids outside the cells must be
kept relatively constant (homeostasis). The most important way that
the pH of the blood is kept relatively constant is by buffers dissolved
in the blood. By far the most important buffer for maintaining acid-
base balance in the blood is the carbonic-acid-bicarbonate buffer. It
is the kidneys that ultimately remove (from the body) H+ ions and
other components of the pH buffers that build up in excess. The
increased-breathing response to exercise helps to counteract the pH-
lowering effects of exercise by removing CO2, a component of the
principal pH buffer in the blood.
pH Measurement – Conventional methods :

Conventional techniques of pH measurement include


measurement using pH strips and pH electrodes. With pH strips, pH
is measured as a change in the colour of the strip. However, pH strips
suffer from poor resolution and poor sensitivity. Again, real time
measurement is not possible with pH strips. pH electrodes uses
Ag/AgCl electrodes, offer better resolution and are more reliable.
However, pH electrodes are made of glass and are fragile. They have
a comparatievely larger size and suffer from less sensitivity .
Substance pH – A Comparision
MATERIAL pH Value
Lemon juice 2.4
Cola 2.5
Vinegar 2.9
Orange 3.5
Beer 4.5
Acid Rain <5.0
Coffee 5.0
Tea 5.5
Milk 6.5
Pure Water 7.0
Blood  7.34 – 7.45
Seawater 7.7 – 8.3
Hand soap 9.0 – 10.0
Bleach 12.5

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