2007 Exposure Limits for Air Contaminants (PELs, TLVs & STELs)

Document Number: 232 Definitions: TLV - Threshold Limit Value. An estimate of the average safe airborne concentration of a substance in representative conditions under which it is believed that nearly all workers may be repeatedly exposed day after day without adverse effect. TLVs are published annually by the ACGIH (American Conference of Governmental Industrial Hygienists). PEL - Permissible Exposure Limit. The OSHA limits of employee exposure to chemicals; found primarily in 29 CFR 1910.1000, Table Z-1. STEL - Short Term Exposure Limit, the maximum concentration for a continuous 15-minute exposure period. Ceiling - The maximum allowable concentration to which an employee may be exposed. IDLH - Immediately Dangerous to Life and Health, is the concentration of an airborne chemical which may cause irreversible health effects or death. NIOSH

Chemical Name Acetaldehyde Acetic Acid Acetic Anhydride Acetone Acetonitrile Acetylene tetrabromide (1,1,2,2 Tetrabromoethane) Acrolein Acrylamide Aldrin Allyl alcohol Allyl chloride Allyl glycidyl ether Allyl propyl disulfide alpha-Alumina (td)

TLV ppm 10 5 500 40 0.1 0.03 0.05 0.5 1 1 0.5 10 mg/m3

PEL ppm 200 10 5 1000 40 1 0.1 0.3 mg/m3 0.25 mg/m3 2 1 10 + 2 15 mg/m3

STEL/Ceiling ppm 25 ACGIH 15 ACGIH 750 ACGIH 0.1 ACGIH 4 NIOSH 2 ACGIH / NIOSH 10 NIOSH 3 NIOSH -

IDLH ppm 2000 ++ 50 200 2500 500 8 2 60 mg/m3++ 25 mg/m3++ 20 250 50 -

alpha-Alumina (rf) Aluminum, metal (td) Aluminum metal (rf) 2-Aminopyridine Ammonia Ammonium sulfamate (td) Ammonium sulfamate (rf) n-Amyl acetate (1-Pentyl acetate) sec-Amyl acetate (2-Pentyl acetate) Aniline and homologs Anisidine o-, p-isomers Antimony & compounds ANTU Arsenic, org. comp. Arsine Azinphos-methyl

10 mg/m3 0.5 25 10 mg/m3 50 50 2 0.1 0.5 mg/m3 0.3 mg/m3 0.01 mg/m3 0.005 0.2 mg/m3

5 mg/m3 15 mg/m3 5 mg/m3 0.5 50 15 mg/m3 5 mg/m3 100 125 5 0.5 mg/m3 0.5 mg/m3 0.3 mg/m3 0.5 mg/m3 0.05 0.2 mg/m3

35 ACGIH / NIOSH 100 ACGIH 100 ACGIH 0.002 mg/m3 NIOSH -

5 300 1500 mg/m3 1000 1000 100 ++ 50 mg/m3 ++ 50 mg/m3 100 mg/m3 3 ++ 10 mg/m3

" + " indicates a Ceiling Value " ++ " indicates that the chemical is believed, by NIOSH, to be a potential Carcinogen.

Chemical Name Barium, sol. comp. Barium sulfate (td) Barium sulfate (rf) Benomyl (td) Benomyl (rf) Benzene *See 29 CFR 1910.1028 Benzoyl peroxide Benzyl chloride

TLV ppm 0.5 mg/m3 10 mg/m3 10 mg/m3 0.5

PEL ppm 0.5 mg/m3 15 mg/m3 5 mg/m3 15 mg/m3 5 mg/m3 1*

STEL/Ceiling ppm 5* OSHA 2.5 ACGIH 1 NIOSH 1 / 15min NIOSH

IDLH ppm 50 mg/m3 500 ++

5 mg/m3 1

5 mg/m3 1

1500 mg/m3 10

Beryllium

0.002 mg/m3 10 mg/m3 10 mg/m3 1+ 0.1 0.5 2 200 20 150 200 200 20 100 100 5+ 0.1 mg/m3+ 3 0.5 1

0.002 mg/m3 15 mg/m3 5 mg/m3 15 mg/m3 1+ 0.1 0.5 1 200 50 150 200 200 100 150 100 5+ 0.1 mg/m3+ 50 10 10

Bismuth telluride undoped (td) Bismuth telluride undoped (rf) Boron oxide (td) Boron trifluoride Bromine Bromoform 1,3 Butadiene 2-Butanone (MEK) 2-Butoxyethanol n-Butyl-acetate sec-Butyl acetate tert-Butyl acetate n-Butyl alcohol (n-Butanol) sec-Butyl alcohol (secButanol) tert-Butyl alcohol (tertButanol) Butylamine tert-Butyl chromate See 29 CFR 1910.1026 n-Butyl glycidyl ether Butyl mercaptan p-tert-Butyl-1-toluene " + " indicates a Ceiling Value

0.005 ; 0.025 30 min peak/8hr shift OSHA 0.0005 mg/m3 NIOSH 1 NIOSH 0.2 ACGIH 0.3 NIOSH 5 OSHA 300 ACGIH / NIOSH 200 ACGIH / NIOSH 50 NIOSH 150 NIOSH 150 NIOSH 5 NIOSH 5.6 /15min NIOSH 0.5 /15min NIOSH 20 NIOSH

4 mg/m3 ++ 2000 mg/m3 25 3 850 2000 ++ (LEL) 3000 700 1700 (LEL) 1700 (LEL) 1500 (LEL) 1400 (LEL) 2000 1600 300 15 mg/m3 ++ 250 500 100

" ++ " indicates that the chemical is believed, by NIOSH, to be a potential Carcinogen.

Chemical Name Cadmium fume See 29 CFR 1910.1027 Cadmium dust See 29 CFR

TLV ppm -

PEL ppm 0.3 mg/m3 0.3

STEL/Ceiling ppm

IDLH ppm 9 mg/m3 ++ 9 mg/m3 ++

1910.1027 Calcium carbonate (td) (Limestone) Calcium carbonate (rf) Calcium hydroxide (td) Calcium hydroxide (rf) Calcium oxide Calcium silicate (td) Calcium silicate (rf) Calcium sulfate (td) Calcium sulfate (rf) Camphor, synthetic Carbaryl Carbon black Carbon dioxide Carbon disulfide Carbon monoxide Carbon tetrachloride Cellulose (td) Cellulose (rf) Chlorodane Chlorinated camphene Chlorinated diphenyl oxide Chlorine Chlorine dioxide

5 mg/m3 2 mg/m3 10 mg/m3 10 mg/m3 12 mg/m3 5 mg/m3 3.5 mg/m3 5000 1 25 5 10 mg/m3 0.5 mg/m3 0.5 mg/m3 0.5 mg/m3 0.5 0.1

mg/m3 15 mg/m3 5 mg/m3 15 mg/m3 5 mg/m3 5 mg/m3 15 mg/m3 5 mg/m3 15 mg/m3 5 mg/m3 2 mg/m3 5 mg/m3 3.5 mg/m3 5000 2 mg/m3 50 2 mg/m3 15 mg/m3 5 mg/m3 0.5 mg/m3 0.5 mg/m3 0.5 mg/m3 1+ 0.1

19 mg/m3 ACGIH 30,000 ACGIH / NIOSH 10 NIOSH 200 NIOSH 10 ACGIH 2 / 60 min NIOSH 1 ACGIH 0.5 NIOSH 0.3 ACGIH / NIOSH

25 mg/m3 200 mg/m3 100 mg/m3 1750 mg/m3 ++ 40,000 500 1200 200 ++ 100 mg/m3++ 200 mg/m3++ 5 mg/m3 10 5

Chlorine trifluoride Chloroacetaldehyde a-chloroacetophenone Chlorobenzene o-Chlorobenzylidene malononitrile Chlorobromomethane Chlorodiphenyl (42% Cl) Chlorobiphenyl (54% Cl) Chloroform 1-Chloro-1-nitro- propane Chloropicrin beta-Chloroprene 2-Chloro-6-trichloro- methyl) pyridine (td) 2-Chloro-6-(trichloro methyl) pyridine (rf) Chromic acids and Chromate Chromium (II) compounds Chromium (III) compounds Chromium metal and insoluble salts Clopidol (td) Clopidol (rf) Coal dust (less than 5% SiO (2) anthracite Coal dust (greater or equal to 5% SiO(2) bituminous Coal tar pitch volatiles Cobalt metal, dust, and fume Copper fume Copper dusts and mists Cotton dust Crag herbicide (td) (Sesone)

0.1 + 1+ 0.05 10 0.05+ 200 1 mg/m3 0.5 mg/m3 10 2 0.1 10 10 mg/m3 0.05 mg/m3 0.5 mg/m3 0.5 mg/m3 10 mg/m3 0.4 mg/m3 0.9 mg/m3 0.2 mg/m3 0.02 mg/m3 0.2 mg/m3 1 mg/m3 0.2 mg/m3 10 mg/m3

0.1 + 1+ 0.05 75 0.05 200 1 mg/m3 0.5 mg/m3 50+ 20 0.1 25 15 mg/m3 5 mg/m3 4 0.5 mg/m3 0.5 mg/m3 1 mg/m3 15 mg/m3 5 mg/m3 3 mg/m3 3 mg/m3 0.2 mg/m3 0.1 mg/m3 0.1 mg/m3 1 mg/m3 1 mg/m3 15 mg/m3

0.1 NIOSH 1 NIOSH 0.05 NIOSH 2 /60min NIOSH 1 / 15min NIOSH 20 mg/m3 0.1 mg/m3 ACGIH -

20 45 15 mg/m3 1000 2 mg/m3 2000 5 mg/m3++ 5 mg/m3++ 500 ++ 100 2 300 15 mg/m3 ++ 250 mg/m3 25 mg/m3 250 mg/m3 80 mg/m3++ 20 mg/m3 100 mg/m3 100 mg/m3 100 mg/m3 500 mg/m3

Crag herbicide (rf) Cresol, all isomers Crotonaldehyde Cumene Cyanides Cyclohexane Cyclohexanol Cyclohexanone Cyclohexene Cyclopentadiene " + " indicates a Ceiling Value

5 0.3 + 50 100 50 20 300 75

5 mg/m3 5 2 50 5 mg/m3 300 50 50 300 75

250 50 900 (LEL) 25 mg/m3 1300 (LEL) 400 700 2000 750

" ++ " indicates that the chemical is believed, by NIOSH, to be a potential Carcinogen.

Chemical Name 2,4-D (Dichlorophenoxyacetic acid) Decaborane Demeton Diacetone alcohol Diazomethane Diborane Dibutyl phosphate Dibutyl phthalate o-Dichlorobenzene p-Dichlorobenzene Dichlorodifluoromethane 1,3 Dichloro 5,5 dimethyl hydantoin Dichlorodiphenyltri-chloroethane (DDT) 1,1 Dichloroethane 1,2-Dichloroethylene Dichloroethyl ether

TLV ppm 10 mg/m3 0.05 0.05 mg/m3 50 0.2 0.1 1 5 mg/m3 25 10 1000 0.2 mg/m3 1 mg/m3 100 200 5

PEL ppm 10 mg/m3 0.05 0.1 mg/m3 50 0.2 0.1 1 5 mg/m3 50+ 75 1000 0.2 mg/m3 1 mg/m3 100 200 15 +

STEL/Ceiling ppm 0.15 ACGIH / NIOSH 2 ACGIH / NIOSH 50 ACGIH / NIOSH 10 ACGIH / NIOSH

IDLH ppm 100 mg/m3 15 mg/m3 10 mg/m3 1800 (LEL) 2 15 30 4000 mg/m3 200 150 ++ 15,000 5 mg/m3 500 mg/m3 ++ 3000 1000 100 ++

Dichloromono- fluomethane (Dichlorofluoromethane) 1,1 Dichloro-1- nitroethane Dichlorotetra- fluoroethane Dichlorvos (DDVP) Dicyclopentadienyl iron (td) Dicyclopentadienyl iron (rf) Dieldrin Diethylamine 2-Diethylaminoethanol Difluorodibromomethane Diglycidyl ether (DGE) Diisobutyl ketone Diisopropylamine Dimethyl acetamide Dimethylamine Dimethylaniline (N,N-Dimethylaniline) Dimethyl-1,2-dibromo- 2,2-dichloroethyl phosphate (NALED) Dimethylformamide 1,1-Dimethylhydrazine Dimethylphthalate Dimethyl sulfate Dinitrobenzene (all isomers) Dinitro-o-cresol Dinitrotoluene Dioxane (Diethylene dioxide) Diphenyl (Biphenyl) Dipropylene glycol methyl ether DPGME [2-(Methoxymethylethoxy)propanol] Di-sec octyl phthalate (Di-(2-ethylhexyl) phthalate) DEHP

10 2 1000 0.1 mg/m3 10 mg/m3 0.25 mg/m3 5 2 100 0.01 25 5 10 5 5 0.1 mg/m3 10 0.01 5 mg/m3 0.1 0.15 0.2 mg/m3 0.2 mg/m3 20 0.2 100 5 mg/m3

1000 10 + 1000 1 mg/m3 15 mg/m3 5 mg/m3 0.25 mg/m3 25 10 100 0.5 + 50 5 10 10 5 3 mg/m3 10 0.5 5 mg/m3 1 1 mg/m3 0.2 mg/m3 1.5 mg/m3 100 0.2 100 5 mg/m3

15 ACGIH 12 NIOSH 15 ACGIH 10 ACGIH / NIOSH 0.06 / 120min NIOSH 1 / 30min NIOSH 150 ACGIH / NIOSH -

5000 25 15,000 100 mg/m3 50 mg/m3++ 200 100 2000 10 ++ 500 200 300 500 100 200 mg/m3 500 15++ 2000 mg/m3 7++ 50 mg/m3 5 mg/m3 50 mg/m3++ 500 ++ 100 mg/m3 600 5000 mg/m3

" + " indicates a Ceiling Value " ++ " indicates that the chemical is believed, by NIOSH, to be a potential Carcinogen.

Chemical Name Emery (td) Emery (rf) Endosulfan Endrin Epichlorohydrin EPN Ethanolamine 2-Ethoxyethanol (Cellosolve) 2-Ethoxyethyl acetate (cellosolve acetate) Ethyl acetate Ethyl acrylate Ethyl alcohol (Ethanol) Ethylamine Ethyl amyl ketone (5- Methyl-3heptanone) Ethyl benzene Ethyl bromide Ethyl butyl ketone (3- Heptanone) Ethyl chloride Ethyl ether Ethyl formate Ethyl mercaptan Ethyl silicate Ethylene chlorohydrin Ethylenediamine Ethylene dibromide

TLV ppm 10 mg/m3 0.1 mg/m3 0.1 mg/m3 0.5 0.1 mg/m3 3 5 5 400 5 1000 5 10 100 5 50 100 400 100 0.5 10 1+ 10 -

PEL ppm 15 mg/m3 5 mg/m3 0.1 mg/m3 5 0.5 mg/m3 3 200 100 400 25 1000 10 25 100 200 50 1000 400 100 10 + 100 5 10 2 mg/m3

STEL/Ceiling ppm 6 ACGIH / NIOSH 15 ACGIH 15 ACGIH 125 ACGIH / NIOSH 75 ACGIH 500 ACGIH 0.5 / 15min NIOSH 1 NIOSH 30;50/5 min peak 8hr OSHA 0.13 /15 min NIOSH 2 NIOSH -

IDLH ppm 2 mg/m3 75++ 5 mg/m3 30 500 500 2000 (LEL) 300 ++ 3300 (LEL) 600 800 (LEL) 2000 1000 3800 (LEL) 1900 1500 500 700 7 1000 100 ++

Ethylene dichloride Ethylene glycol dinitrate

10 0.05

2 mg/m3 0.2 +

50 ++ 75 mg/m3

N-Ethylmorpholine " + " indicates a Ceiling Value

20

100

" ++ " indicates that the chemical is believed, by NIOSH, to be a potential Carcinogen.

Chemical Name Ferbam (td) Ferrovanadium dust Fluorides (as F) Fluorine Fluorotrichloromethane (Trichlorofluoromethane) Formaldehyde See 29 CFR 1910.1048 Formic acid Furfural Furfuryl alcohol " + " indicates a Ceiling Value

TLV PEL ppm ppm 10 15 mg/m3 mg/m3 1 mg/m3 1 mg/m3 2.5 mg/m3 1 1000 + 0.3 + 5 2 10 2.5 mg/m3 0.1 1000 0.75 5 5 50

STEL/Ceiling ppm 3 mg/m3 ACGIH / NIOSH 2 ACGIH 1000 NIOSH 0.1 / 15min NIOSH 10 ACGIH 15 ACGIH / NIOSH

IDLH ppm 800 mg/m3 500 mg/m3 250 mg/m3 25 2000 20 ++ 30 100 75

" ++ " indicates that the chemical is believed, by NIOSH, to be a potential Carcinogen.

Chemical Name Glycerin (td) Glycerin (rf) Glycidol Grain dust (oat, wheat, barley) Graphite, natural Graphite, synthetic (td) Graphite, synthetic (rf) Gypsum (td) Gypsum (rf) " + " indicates a Ceiling Value

TLV ppm 10 mg/m3 2 4 mg/m3 2 mg/m3 2 mg/m3 10 mg/m3 -

PEL ppm 15 mg/m3 5 mg/m3 50 10 mg/m3 3 mg/m3 15 mg/m3 5 mg/m3 15 mg/m3 5 mg/m3

STEL/Ceiling ppm -

IDLH ppm 150 1250 mg/m3 -

" ++ " indicates that the chemical is believed, by NIOSH, to be a potential Carcinogen.

Chemical Name

TLV

PEL

STEL/Ceiling

IDLH

Hafnium Heptachlor Heptane (n-Heptane) Hexachloroethane Hexachloronaph- thalene n-Hexane 2-Hexanone (Methyl n-butyl ketone) Hexone (Methyl isobutyl ketone) sec-Hexyl acetate Hydrazine Hydrogen bromide Hydrogen chloride Hydrogen cyanide Hydrogen fluoride Hydrogen peroxide Hydrogen selenide (as Se) Hydrogen sulfide Hydroquinone

ppm 0.5 mg/m3 0.05 mg/m3 400 1 0.2 mg/m3 50 5 50 50 0.01 2+ 2+ 4.7+ 0.5 1 0.05 10 2 mg/m3

ppm 0.5 mg/m3 0.5 mg/m3 500 1 0.2 mg/m3 500 100 100 50 1 3 5+ 10 2 mg/m3 1 0.05 2 mg/m3 2 mg/m3

ppm 500 ACGIH 440 / 15min NIOSH 10 ACGIH 75 ACGIH / NIOSH 3 NIOSH 5 NIOSH 4.7 NIOSH 2 ACGIH 6 / 15min NIOSH 15 ACGIH 10 NIOSH 2 mg/m3 / 15min NIOSH

ppm 50 mg/m3 35 mg/m3 ++ 750 300++ 2 mg/m3 1100 (LEL) 1600 500 500 50 ++ 30 50 50 30 75 1 100 50 mg/m3

" + " indicates a Ceiling Value " ++ " indicates that the chemical is believed, by NIOSH, to be a potential Carcinogen.

Chemical Name Iodine Iron oxide fume Isoamyl acetate (Isopentyl acetate) Isoamyl alcohol (primary and secondary) Isobutyl acetate Isobutyl alcohol Isophorone Isopropyl acetate

TLV ppm 0.1 + 5 mg/m3 50 100 150 50 5+ 100

PEL ppm 0.1 + 10 mg/m3 100 100 150 100 25 250

STEL/Ceiling ppm 0.1 NIOSH 100 ACGIH 125 ACGIH / NIOSH 200 ACGIH

IDLH ppm 2 2500 mg/m3 1000 500 1300 (LEL) 1600 200 1800

Isopropyl alcohol (2-Propanol) Isopropylamine Isopropyl ether Isopropyl glycidyl ether (IGE)

200 5 250 50

400 5 500 50

400 ACGIH 500 NIOSH 10 ACGIH 310 ACGIH 75 ACGIH 50 / 15min NIOSH

2000 (LEL) 750 1400 (LEL) 400

" + " indicates a Ceiling Value " ++ " indicates that the chemical is believed, by NIOSH, to be a potential Carcinogen.

Chemical Name Kaolin (td) Kaolin (rf) Ketene Limestone (td) Limestone (rf) Lindane Lithium hydride L.P.G. (Liquefied petroleum gas) " + " indicates a Ceiling Value

TLV ppm 2 mg/m3 0.5 0.5 mg/m3 0.025 mg/m3 1000

PEL ppm 15 mg/m3 5 mg/m3 0.5 15 mg/m3 5 mg/m3 0.5 mg/m3 0.025 mg/m3 1000

STEL/Ceiling ppm 1.5 ACGIH / NIOSH -

IDLH ppm 5 50 mg/m3 0.5 mg/m3 2000 (LEL)

" ++ " indicates that the chemical is believed, by NIOSH, to be a potential Carcinogen.

Chemical Name Magnesite (td) Magnesite (rf) Magnesium oxide fume (total particulate) Malathion (td) Maleic anhydride Manganese compounds (as Mn) Manganese fume (as Mn) Marble (td)

TLV ppm 10 mg/m3 1 mg/m3 0.1 0.2 mg/m3 0.2 mg/m3 -

PEL ppm 15 mg/m3 5 mg/m3 15 mg/m3 15 mg/m3 0.25 5 mg/m3+ 5 mg/m3+ 15

STEL/Ceiling ppm 3 mg/m3 NIOSH 3 mg/m3 NIOSH -

IDLH ppm 750 mg/m3 250 mg/m3 10 mg/m3 500 mg/m3 500 mg/m3 -

Marble (rf) Mercury (aryl and inorganic) Mercury (organo) alkyl compounds Mercury (vapor) Mesityl oxide Methoxychlor (td) 2-Methoxyethanol (Methyl cellosolve) 2-Methoxyethyl acetate (Methyl cellosolve acetate) Methyl acetate Methyl acetylene (propyne) Methyl acetylene- propadiene mixture (MAPP) Methyl acrylate Methylal (Dimetoxy- methane) Methyl alcohol Methylamine Methyl n-amyl ketone Methyl bromide Methyl chloride Methyl chloroform (1,1,1Trichloroethane) Methylcyclohexane Methylcyclohexanol o-Methylcyclohexanone Methylene chloride (Dichloromethane) See 29 CFR 1910.1003 Methylene bisphenyl isocyanate (MDI) Methyl formate Methyl hydrazine (Mono- methyl hydrazine) Methyl iodide Methyl isoamyl ketone Methyl isobutyl carbinol

0.025 mg/m3 0.025 mg/m3 0.025 mg/m3 15 10 mg/m3 0.1 0.1 200 1000 1000 2 1000 200 5 50 1 50 350 400 50 50 50

mg/m3 5 mg/m3 2 mg/m3 2 mg/m3 2 mg/m3 25 15 mg/m3 25 25 200 1000 1000 10 1000 200 10 100 20 + 2 mg/m3 350 500 100 100 2 mg/m3

0.1 mg/m3 OSHA/ NIOSH 0.1 mg/m3 OSHA/ NIOSH 0.1 mg/m3 OSHA/ NIOSH 25 250 ACGIH / NIOSH 1250 ACGIH / NIOSH 250 ACGIH / NIOSH 15 ACGIH 100 ACGIH 450 ACGIH 350 NIOSH 75 ACGIH / NIOSH -

10 mg/m3 2 mg/m3 1400 (LEL) 5000 mg/m3++ 200 200 3100 (LEL) 1700 (LEL) 3400 (LEL) 250 2200 (LEL) 6000 100 800 250++ 2000 ++ 700 1200 (LEL) 500 600 2300

0.005 100 0.01 2 50 25

0.02+ 100 0.2+ 5 100 25

0.02 NIOSH 150 ACGIH / NIOSH 0.4 NIOSH 40 ACGIH /

75 mg/m3 4500 20++ 100++ 400

Methyl isocyanate Methyl mercaptan Methyl methacrylate alpha-Methyl styrene Molybdenum (as Mo) Soluble compounds Molybdenum (as Mo) Insoluble compounds (td)

0.02 0.5 50 50 0.5 mg/m3 10 mg/m3 I 3 mg/m3 R 0.5 20

0.02 10 + 100 100 + 5 mg/m3 15 mg/m3

NIOSH 0.5 / 15min NIOSH 100 ACGIH 100 ACGIH / NIOSH -

3 150 1000 700 1000 mg/m3 5000 mg/m3

Monomethyl aniline (N-Methyl aniline) Morpholine " + " indicates a Ceiling Value

2 20

30 NIOSH

100 1400 (LEL)

" ++ " indicates that the chemical is believed, by NIOSH, to be a potential Carcinogen.

Chemical Name Naphtha (Coal tar) Naphthalene Nickel carbonyl (as Ni) Nickel, metal and insoluble compounds (as Ni) Nickel, soluble compounds (as Ni) Nicotine Nitric acid Nitric oxide p-Nitroaniline Nitrobenzene p-Nitrochlorobenzene

TLV ppm 400 10 0.05 0.2 mg/m3 0.1 mg/m3 0.5 mg/m3 2 25 3 mg/m3 1 0.1

PEL ppm 100 10 0.001 1 mg/m3 1 mg/m3 0.5 mg/m3 2 25 1 1 1 mg/m3

STEL/Ceiling ppm 15 ACGIH / NIOSH 4 ACGIH / NIOSH -

IDLH ppm 1000 (LEL) 250 2++ 10 mg/m3++ ++ 5 mg/m3 25 100 300 mg/m3 200 100 mg/m3 ++ 1000 20 1000

Nitroethane Nitrogen dioxide Nitrogen trifluoride

100 3 10

100 5+ 10

5 ACGIH 1 NIOSH -

Nitroglycerin Nitromethane 1-Nitropropane 2-Nitropropane Nitrotoluene (all isomers) Octachloronaphthalene Octane Oil mist, mineral Osmium tetroxide (as Os) Oxalic acid Oxygen difluoride Ozone

0.05 20 25 10 2 0.1 mg/m3 300 5 mg/m3 0.0002 1 mg/m3 0.05+ 0.1 light work

0.2+ 100 25 25 5 0.1 mg/m3 500 5 mg/m3 0.002 mg/m3 1 mg/m3 0.05 0.1

0.1 mg/m3 NIOSH 0.3 mg/m3+ 385 / 15min NIOSH 10 mg/m3 ACGIH/ NIOSH 0.0006 ACGIH / NIOSH 2 mg/m3 0.05 ACGIH / NIOSH 0.1 NIOSH

75 mg/m3 750 1000 100 ++ 200 Unknown 1000 2500 mg/m3 1 mg/m3 500 mg/m3 0.5 5

" + " indicates a Ceiling Value " ++ " indicates that the chemical is believed, by NIOSH, to be a potential Carcinogen.

Chemical Name Paraquat (rd) Parathion Particulates not other- wise regulated (PNOR) (td) Particulates not other- wise regulated (PNOR) (rf) Pentaborane Pentachloronaphthalene Pentachlorophenol Pentaerythritol (td) Pentaerythritol (rf) Pentane 2-Pentanone (Methyl propyl

TLV ppm 0.5 mg/m3 0.05 mg/m3 10 mg/m3 3 mg/m3 0.005 0.5 mg/m3 0.5 mg/m3 10 mg/m3 600 150+

PEL ppm 0.5 mg/m3 0.1 mg/m3 15 mg/m3 5 mg/m3 0.005 0.5 mg/m3 0.5 mg/m3 15 mg/m3 5 mg/m3 1000 200

STEL/Ceiling ppm 0.015 ACGIH / NIOSH 610 / 15min NIOSH 250

IDLH ppm 1 mg/m3 10 mg/m3 1 Unknown 2.5 mg/m3 1500 (LEL) 1500

ketone) Perchloroethylene (Tetrachloroethylene) Perchloromethyl mercaptan Perchloryl fluoride Perlite (td) Perlite (rf) Petroleum distillates (Naphtha) (Rubber Solvent) Phenol p-Phenylene diamine Phenyl ether, vapor Phenyl ether-biphenyl mixture, vapor Phenyl glycidyl ether (PGE) Phenylhydrazine Phosdrin (mevinphos) Phosgene (Carbonyl chloride) Phosphine Phosphoric acid Phosphorus (yellow) Phosphorus pentachloride Phosphorus pentasulfide Phosphorus trichloride Phthalic anhydride Picloram (td) Picloram (rf) Picric acid Pindone (2-Pivalyl-1, 3-indandione) Plaster of Paris (td) Plaster of Paris (rf) Platinum (as Pt) Soluble salts Portland cement (td)

10 0.1 3 See Specific 5 0.1 mg/m3 1 0.1 0.1 0.01 mg/m3 0.1 0.3 1 mg/m3 0.02 0.1 1 mg/m3 0.2 1 10 mg/m3 0.1 mg/m3 0.1 mg/m3 0.002 mg/m3 10 mg/m3

2 mg/m3 0.1 3 15 mg/m3 5 mg/m3 500 5 0.1 mg/m3 1 1 10 5 0.1 mg/m3 0.1 0.3 1 mg/m3 0.1 mg/m3 1 mg/m3 1 mg/m3 0.5 2 15 mg/m3 5 mg/m3 0.1 mg/m3 0.1 mg/m3 15 mg/m3 5 mg/m3 0.002 mg/m3 15 mg/m3

25 ACGIH 6 ACGIH / NIOSH 1800 mg/m3 NIOSH 15.6 /15min NIOSH 2 ACGIH 1 /15min NIOSH 0.14 /120min NIOSH 0.03 NIOSH 0.2 / 15min NIOSH 1 ACGIH / NIOSH 3 mg/m3 ACGIH / NIOSH 3 mg/m3 0.5 -

150 ++ 10 100 1100 (LEL) 250 25 mg/m3 100 10 100++ 15++ 4 2 50 1000 mg/m3 5 mg/m3 70 mg/m3 250 mg/m3 25 60 mg/m3 75 mg/m3 100 mg/m3 4 mg/m3 5000 mg/m3

Portland cement (rf) Propane (Aliphatic hydrocarbon gases) n-Propyl acetate n-Propyl alcohol (n-Propanol) Propylene dichloride Propylene imine Propylene oxide n-Propyl nitrate Pyrethrum Pyridine " + " indicates a Ceiling Value

1000 200 100 10 2 20 25 5 mg/m3 1

5 mg/m3 1000 200 200 75 2 100 25 5 mg/m3 5

250 ACGIH / NIOSH 250 NIOSH 40 ACGIH / NIOSH -

2100 (LEL) 1700 800 400++ 100++ 400++ 500 5000 mg/m3 1000

" ++ " indicates that the chemical is believed, by NIOSH, to be a potential Carcinogen.

Chemical Name Quinone Rhodium, metal fume and insoluble compounds Rhodium, soluble compounds Ronnel Rotenone Rouge (td) Rouge (rf) " + " indicates a Ceiling Value

TLV ppm 0.1 1 mg/m3 0.01 mg/m3 5 mg/m3 5 mg/m3 -

PEL ppm 0.1 0.1 mg/m3 0.001 mg/m3 15 mg/m3 5 mg/m3 15 mg/m3 5 mg/m3

STEL/Ceiling ppm -

IDLH ppm 100 mg/m3 100 mg/m3 2 mg/m3 300 mg/m3 2500 mg/m3 -

" ++ " indicates that the chemical is believed, by NIOSH, to be a potential Carcinogen.

Chemical Name Selenium compounds (as Se) Selenium hexafluoride (as Se) Silica, amorphous, precipitated and

TLV ppm 0.2 mg/m3 0.05 -

PEL ppm 0.2 mg/m3 0.05 3 mg/m3

STEL/Ceiling ppm -

IDLH ppm 1 mg/m3 2 3000

gel Silica, amorphous, diatomaceous earth Silica, crystalline cristobalite Silica, crystalline quartz Silica, crystalline tripoli Silica, crystalline tridymite Silica, fused Silicates (lees than 1% crystalline silica) mica Soapstone (td) Soapstone (rf) Silicon (td) Silicon (rf) Silicon carbide (td) Silicon carbide (rf) Silver, metal and soluble compounds (as Ag) Sodium fluoro- acetate Sodium hydroxide Starch (td) Starch (rf) Stibine (Antimony hydride) Stoddard solvent

0.025 mg/m3 0.025 mg/m3 3 mg/m3 6 mg/m3 3 mg/m3 3 mg/m3 10 mg/m3 0.1 mg/m3 0.05 mg/m3 2 mg/m3+ 10 mg/m3 0.1 100

3 mg/m3 3 mg/m3 3 mg/m3 3 mg/m3 3 mg/m3 3 mg/m3 3 mg/m3 3 mg/m3 3 mg/m3 15 mg/m3 5 mg/m3 15 mg/m3 5 mg/m3 0.01 mg/m3 0.05 mg/m3 2 mg/m3 15 mg/m3 5 mg/m3 0.1 500

2 mg/m3 NIOSH 1800 mg/m3 /15min NIOSH 40 ACGIH 100 NIOSH 5 ACGIH / NIOSH 3 mg/m3+ 1 NIOSH 0.01 NIOSH 10 ACGIH / NIOSH

mg/m3 3000 mg/m3 25 mg/m3 ++ 50 mg/m3 ++ 50 mg/m3 ++ 25 mg/m3 1500 3000 mg/m3 3000 mg/m3 10 mg/m3 2.5 mg/m3 10 mg/m3 5 20,000 mg/m3 3 mg/m3 700 100 15 mg/m3 5 1 200

Strychnine Styrene Sucrose (td) Sucrose (rf) Sulfur dioxide Sulfur hexafluoride Sulfuric acid Sulfur monochloride Sulfur pentafluoride Sulfuryl fluoride

0.15 mg/m3 20 10 mg/m3 2 1000 0.2 mg/m3 1+ 0.01+ 5

0.15 mg/m3 2 mg/m3 15 mg/m3 5 mg/m3 5 1000 1 mg/m3 1 0.025 5

" + " indicates a Ceiling Value " ++ " indicates that the chemical is believed, by NIOSH, to be a potential Carcinogen.

Chemical Name 2,4,5-T (2,4,5-trichlorophenoxyacetic acid) Talc (containing asbestos) See 29 CFR 1910.1001 Talc (containing no asbestos) Tantalum, metal and oxide dust TEDP (Sulfotep) Tellurium and compounds (as Te) Tellurium hexafluoride (as Te) Temephos (td) Temephos (rf) TEPP (Tetraethyl pyrophosphate) Terphenyls 1,1,1,2-Tetrachloro-2, 2difluoroethane 1,1,2,2-Tetrachloro-1, 2difluoroethane 1,1,2,2-Tetrachloroethane Tetrachloronaphthalene Tetraethyl lead (as Pb) Tetrahydrofuran Tetramethyl lead (as Pb) Tetramethyl succinonitrile Tetranitromethane Tetryl (2,4,6-Trinitrophenylmethylnitramine) Thallium, soluble compounds (as Tl) 4,4'-Thiobis (6-tert, Butyl-m-cresol) (td) 4,4'-Thiobis (6-tert, Butyl-m-cresol) (rf)

TLV ppm 10 mg/m3 0.1 f/cc (F) 2 mg/m3 5 mg/m3 0.1 mg/m3 0.1 mg/m3 0.02 1 mg/m3 0.01 mg/m3 0.53 + 500 500 1 2 mg/m3 0.1 mg/m3 50 0.15 mg/m3 0.5 0.005 1.5 mg/m3 0.1 mg/m3 10 mg/m3 -

PEL ppm 10 mg/m3 3 mg/m3 3 mg/m3 5 mg/m3 0.2 mg/m3 0.1 mg/m3 0.02 15 mg/m3 5 mg/m3 0.05 mg/m3 1+ 500 500 5 2 mg/m3 0.075 mg/m3 200 0.075 mg/m3 0.5 1 1.5 mg/m3 0.1 mg/m3 15 mg/m3 5 mg/m3

STEL/Ceiling ppm 0.5 NIOSH 100 ACGIH 250 NIOSH -

IDLH ppm 250 mg/m3 1000 mg/m3 ++ 1000 mg/m3 2500 mg/m3 10 mg/m3 25 mg/m3 1 5 mg/m3 500 mg/m3 2000 2000 100++ Unknown 40 mg/m3 2000 (LEL) 40 mg/m3 5 4 750 mg/m3 15 mg/m3 -

Thiram Tin, inorganic compounds (except oxides) (as Sn) Tin, organic compounds (as Sn) Titanium dioxide (td) Toluene

1 mg/m3 2 mg/m3 0.1 mg/m3 10 mg/m3 20

5 mg/m3 2 mg/m3 0.1 mg/m3 15 mg/m3 200

300 OSHA 500 /10min peak 150 NIOSH 25 ACGIH 1250 ACGIH / NIOSH 3 ACGIH -

100 mg/m3 100 mg/m3 25 mg/m3 5000 mg/m3 ++ 500

Toluene-2,4-diisocyanate (TDI) o-Toluidine Tributyl phosphate 1,1,2-Trichloroethane Trichloroethylene Trichloronaphthalene 1,2,3-Trichloropropane 1,1,2-Trichloro-1,2,2trifluoroethane Triethylamine Trifluorobromo- methane 2,4,6-Trinitrotoluene (TNT) Triorthocresyl phosphate Triphenyl phosphate Turpentine " + " indicates a Ceiling Value

0.005 2 0.2 10 10 5 mg/m3 10 1000 1 1000 0.1 mg/m3 0.1 mg/m3 3 mg/m3 20

0.02+ 5 5 mg/m3 10 2 mg/m3 5 mg/m3 50 1000 25 1000 1.5 mg/m3 0.1 mg/m3 3 mg/m3 100

2.5++ 50++ 30 100++ 1000 ++ Unknown 100++ 2000 200 40,000 500 mg/m3 40 mg/m3 1000 mg/m3 800

" ++ " indicates that the chemical is believed, by NIOSH, to be a potential Carcinogen.

Chemical Name Uranium (as U) Soluble compounds Uranium (as U) Insoluble compounds Vanadium (rd) (as V2O5) Vanadium (fume) (as V2O5) Vegetable oil mist (td) Vegetable oil mist (rf) Vinyl toluene

TLV ppm 0.2 mg/m3 0.2 mg/m3 0.05 mg/m3 0.05 mg/m3 50

PEL ppm 0.05 mg/m3 0.25 mg/m3 0.5 mg/m3 + 0.1 mg/m3 + 15 mg/m3 5 mg/m3 100

STEL/Ceiling ppm 0.5 mg/m3 0.1 mg/m3 100 ACGIH

IDLH ppm 10 mg/m3++ 10 mg/m3++ 35 mg/m3 35 mg/m3 400

Warfarin " + " indicates a Ceiling Value

0.1 mg/m3

0.1 mg/m3

100 mg/m3

" ++ " indicates that the chemical is believed, by NIOSH, to be a potential Carcinogen.

Chemical Name Xylenes (o-, m-, p-isomers) Xylidine Yttrium Zinc chloride fume Zinc oxide fume Zinc oxide (td) Zinc oxide (rf) Zinc stearate (td) Zinc stearate (rf) Zirconium compounds (as Zr) " + " indicates a Ceiling Value

TLV ppm 100 0.5 1 mg/m3 1 mg/m3 2 mg/m3 10 mg/m3 5 mg/m3

PEL ppm 100 5 1 mg/m3 1 mg/m3 5 mg/m3 15 mg/m3 5 mg/m3 15 mg/m3 5 mg/m3 5 mg/m3

STEL/Ceiling ppm 150 ACGIH / NIOSH 2 mg/m3 ACGIH / NIOSH 10 mg/m3

IDLH ppm 900 50 500 mg/m3 50 mg/m3 500 mg/m3 500 mg/m3 500 mg/m3 25 mg/m3

" ++ " indicates that the chemical is believed, by NIOSH, to be a potential Carcinogen.
Sumber : http://www.labsafety.com/refinfo/ezfacts/ezf232.htm