Magnetic domain

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Several grains of NdFeB with magnetic domains made visible with a Kerr microscope. The domains are the light and dark stripes visible within each grain.

A magnetic domain is a region within a magnetic material which has uniform magnetization. This means that the individual magnetic moments of the atoms are aligned with one another and they point in the same direction. When cooled below a temperature called the Curie temperature, the magnetization of a piece of ferromagnetic material spontaneously divides into many small regions called magnetic domains. The magnetization within each domain points in a uniform direction, but the magnetization of different domains may point in different directions. Magnetic domain structure is responsible for the magnetic behavior of ferromagnetic materials like iron, nickel, cobalt and their alloys, ferrites etc. such as the formation of permanent magnets. The regions separating magnetic domains are called domain walls, where the magnetization rotates coherently from the direction in one domain to that in the next domain. The study of magnetic domains is called micromagnetics.
Contents
[hide]

1 Development of domain theory 2 Domain structure

o o o o o o

2.1 Why domains form 2.2 Size of domains 2.3 Magnetic anisotropy 2.4 Magnetostriction 2.5 Grain structure 2.6 "Magnetized" states

3 Landau-Lifshitz energy equation

4 Observing domains 5 See also 6 References 7 External links

[edit]Development

of domain theory

Magnetic domain theory was developed by French physicist Pierre-Ernest Weiss[1] who in 1906 suggested existence of magnetic domains in ferromagnets.[2] He suggested that large number of atomic magnetic moments (typically 1012-1018)[citation needed] were aligned parallel. The direction of alignment varies from domain to domain in a more or less random manner although certain crystallographic axis may be preferred by the magnetic moments, called easy axes. Weiss still had to explain the reason for the spontaneous alignment of atomic moments within a ferromagneticmaterial, and he came up with the socalled Weiss mean field : he assumed that a given magnetic moment in a material experienced a very high effective magnetic field due to the magnetization of its neighbors. In the original Weiss theory the mean field was proportional to the bulk magnetization M, so that

where

is the mean field constant. However this is not applicable to ferromagnets due to the variation of

magnetization from domain to domain. In this case, the interaction field is

Where

is the saturation magnetization at 0K.

Later, the quantum theory made it possible to understand the microscopic origin of the Weiss field. The exchange interaction between localized spins favored a parallel (in ferromagnets) or an anti-parallel (in anti-ferromagnets) state of neighboring magnetic moments.

[edit]Domain

structure

How dividing a ferromagnetic material into magnetic domains reduces the magnetostatic energy

[edit]Why

domains form

The reason a piece of magnetic material such as iron spontaneously divides into separate domains, rather than exist in a state with magnetization in the same direction throughout the material, is to minimize its internal energy.[3] A large region of ferromagnetic material with a constant magnetization throughout will create a large magnetic field extending into the space outside itself (diagram a, right). This requires a lot of magnetostatic energy stored in the field. To reduce this energy, the sample can split into two domains, with the magnetization in opposite directions in each domain (diagram b right). The magnetic field lines pass in loops in opposite directions through each domain, reducing the field outside the material. To reduce the field energy further, each of these domains can split also, resulting in smaller parallel domains with magnetization in alternating directions, with smaller amounts of field outside the material. The domain structure of actual magnetic materials does not usually form by the process of large domains splitting into smaller ones as described here. When a sample is cooled below the Curie temperature, for example, the equilibrium domain configuration simply appears. But the description of domains splitting is often used to reveal the energy tradeoffs in domain formation.

[edit]Size

of domains

So a domain which is too big is unstable, and will divide into smaller domains. But a small enough domain will be stable and will not split, and this determines the size of the domains created in a material. This size depends on the balance of several energies within the material.[3] Each time a region of magnetization splits into two domains, it creates a "domain wall" between the domains, where magnetic dipoles (molecules) with magnetization pointing in different directions are adjacent. The exchange interaction which creates the magnetization is a force which tends to align nearby dipoles so they point in the same direction. So forcing adjacent dipoles to point in different directions requires energy. Therefore creating a domain wall requires extra energy, called the "exchange energy", which is proportional to the area of the wall. So the net amount that the energy is reduced when a domain splits is equal to the difference between the magnetic field energy saved, and the additional energy of the domain wall created. The field energy saved is proportional to the cube of the domain size, while the domain wall energy is proportional to the square of the domain size. So as the domains get smaller, the net energy saved by splitting decreases. The domains keep dividing into smaller domains until the energy cost of creating an additional domain wall is just equal to the field energy saved. Then the domains of this size are stable. In most materials the domains are microscopic in size, around 10-4 - 10-6 m.

[edit]Magnetic

anisotropy

An additional way for the material to further reduce its magnetostatic energy is to form domains with magnetization at right angles to the other domains (diagram c, right), instead of just in opposing parallel directions.[3] These domains, called flux closure domains, allow the field lines to turn 180 within the material, forming closed loops entirely within the material, reducing the magnetostatic energy to zero. However, forming these domains incurs two additional energy costs. First, the crystal lattice of most

magnetic materials has magnetic anisotropy, which means it has an "easy" direction of magnetization, parallel to one of the crystal axes. Changing the magnetization of the material to any other direction takes additional energy, called the "magnetocrystalline anisotropy energy".

Micrograph of surface of ferromagnetic material, showing the crystal grains, each divided into several domains parallel to its "easy" axis of magnetization, with the magnetization in alternating directions (red and green areas).

[edit]Magnetostriction
The other energy cost to creating domains with magnetization at an angle to the "easy" direction is caused by the phenomenon called magnetostriction.[3]When the magnetization of a piece of magnetic material is changed to a different direction, it causes a slight change in its shape. The change in magnetic field causes the magnetic dipole molecules to change shape slightly, making the crystal lattice longer in one dimension and shorter in other dimensions. However, since the magnetic domain is "squished in" with its boundaries held rigid by the surrounding material, it cannot actually change shape. So instead, changing the direction of the magnetization induces tiny mechanical stresses in the material, requiring more energy to create the domain. This is called "magnetoelastic anisotropy energy". To form these closure domains with "sideways" magnetization requires additional energy due to the aforementioned two factors. So flux closure domains will only form where the magnetostatic energy saved is greater than the sum of the "exchange energy" to create the domain wall, the magnetocrystalline anisotropy energy, and the magnetoelastic anisotropy energy. Therefore most of the volume of the material is occupied by domains with magnetization either "up" or "down" along the "easy" direction, and the flux closure domains only form in small areas at the edges of the other domains where they are needed to provide a path for magnetic field lines to change direction (diagram c, above).

[edit]Grain

structure

The above describes magnetic domain structure in a perfect crystal lattice, such as would be found in a single crystal of iron. However most magnetic materials are polycrystalline, composed of microscopic crystalline grains. These grains are not the same as domains. Each grain is a little crystal, with the crystal lattices of separate grains oriented in random directions. In most materials, each grain is big enough to

contain several domains. Each crystal has an "easy" axis of magnetization, and is divided into domains with the axis of magnetization parallel to this axis, in alternate directions.

[edit]"Magnetized"

states

It can be seen that, although on a microscopic scale almost all the magnetic dipoles in a piece of ferromagnetic material are lined up parallel to their neighbors in domains, creating strong localmagnetic fields, energy minimization results in a domain structure that minimizes the large-scale magnetic field. The domains point in different directions, confining the field lines to microscopic loops between neighboring domains, so the combined fields cancel at a distance. Therefore a bulk piece of ferromagnetic material in its lowest energy state has little or no external magnetic field. The material is said to be "unmagnetized". However, the domains can also exist in other configurations in which their magnetization mostly points in the same direction, creating an external magnetic field. Although these are not minimum energy configurations, due to a phenomenon where the domain walls become "pinned" to defects in the crystal lattice they can be local minimums of the energy, and therefore can be very stable. This is what happens when a piece of magnetic material is "magnetized" and becomes a permanent magnet.

[edit]Landau-Lifshitz

energy equation

Moving domain walls in a grain of silicon steel caused by an increasing external magnetic field in the "downward" direction, observed in a Kerr microscope. White areas are domains with magnetization directed up, dark areas are domains with magnetization directed down.

The contributions of the different internal energy factors described above is expressed by the free energy equation proposed by Lev Landau and Evgeny Lifshitz in 1935 [1], which forms the basis of the modern theory of magnetic domains. The domain structure of a material is the one which minimizes theGibbs free energy of the material. For a crystal of magnetic material, this is the Landau-Lifshitz free energy, E, which is the sum of these energy terms:[4]

where

Eex is exchange energy: This is the energy due to the exchange interaction between magnetic dipole molecules in ferromagnetic, ferrimagneticand antiferromagnetic materials. It is lowest when the dipoles are all pointed in the same direction, so it is responsible for magnetization of magnetic

materials. When two domains with different directions of magnetization are next to each other, at the domain wall between them magnetic dipoles pointed in different directions lie next to each other, increasing this energy. This additional exchange energy is proportional to the total area of the domain walls.

ED is magnetostatic energy: This is a self-energy, due to the interaction of the magnetic field created by the magnetization in some part of the sample on other parts of the same sample. It is dependent on the volume occupied by the magnetic field extending outside the domain. This energy is reduced by minimizing the length of the loops of magnetic field lines outside the domain. For example, this tends to encourage the magnetization to be parallel to the surfaces of the sample, so the field lines won't pass outside the sample. Reducing this energy is the main reason for the creation of magnetic domains.

E is magnetoelastic anisotropy energy: This energy is due to the effect of magnetostriction, a slight change in the dimensions of the crystal when magnetized. This causes elastic strains in the lattice, and the direction of magnetization that minimizes these strain energies will be favored. This energy tends to be minimized when the axis of magnetization of the domains in a crystal are all parallel.

Ek is magnetocrystalline anisotropy energy: Due to its magnetic anisotropy, the crystal lattice is "easy" to magnetize in one direction, and "hard" to magnetize in others. This energy is minimized when the magnetization is along the "easy" crystal axis, so the magnetization of most of the domains in a crystal grain tend to be in either direction along the "easy" axis. Since the crystal lattice in separate grains of the material is usually oriented in different random directions, this causes the dominant domain magnetization in different grains to be pointed in different directions.

EH is Zeeman energy: This is energy which is added to or subtracted from the magnetostatic energy, due to the interaction between the magnetic material and an externally applied magnetic field. It is proportional to the negative of the cosine of the angle between the field and magnetization vectors. Domains with their magnetic field oriented parallel to the applied field reduce this energy, while domains with their magnetic field oriented opposite to the applied field increase this energy. So applying a magnetic field to a ferromagnetic material generally causes the domain walls to move so as to increase the size of domains lying mostly parallel to the field, at the cost of decreasing the size of domains opposing the field. This is what happens when ferromagnetic materials are "magnetized". With a strong enough external field, the domains opposing the field will be swallowed up and disappear; this is called saturation.

Some sources define a wall energy EW equal to the sum of the exchange energy and the magnetocrystalline anisotropy energy, which replaces Eex and Ek in the above equation.

A stable domain structure is a magnetization function M(X), considered as a continuous vector field, which minimizes the total energy E throughout the material. To find the minimums a variational method is used, resulting in a set of nonlinear differential equations, called Brown's equations after William Fuller Brown Jr. Although in principle these equations can be solved for the stable domain configurations M(X), in practice only the simplest examples can be solved. Analytic solutions do not exist, and numerical solutions calculated by the finite element method are computationally intractable because of the large difference in scale between the domain size and the wall size. Therefore micromagnetics has evolved approximate methods which assume that the magnetization of dipoles in the bulk of the domain, away from the wall, all point in the same direction, and numerical solutions are only used near the domain wall, where the magnetization is changing rapidly.

Rotation of orientation and increase in size of magnetic to an externally applied field (compare Zeeman energy).

[edit]Observing

domains

There are a number of microscopy methods which can make the magnetization at a surface of a magnetic material visible, revealing the magnetic domains. Each method has a different application because not all domains are the same. In magnetic materials, domains can be circular, square, irregular, elongated, and striped, all of which have varied sizes and dimensions. Large domains, within the range of 25-100 micrometers can be easily seen by Kerr microscopy, which uses the magnetooptic Kerr effect, which is the rotation of the polarization of light reflected from a magnetized surface. Smaller domains, down to the scale of a few nanometers, can be viewed by the use of magnetic force microscopy.

Magnetooptical images of different domain structures

Domain structure of a shape-memory alloy(recorded using CMOS-MagView)

Domain structure of a examplary meander domain (recorded using CMOS-MagView)

Domain structure of a examplary magnetic bubble domain (recorded using CMOS-MagView)

[edit]See

also

ferromagnetism Magnetostatic energy Racetrack memory Bloch wall Domain wall Barkhausen effect Coercivity

[edit]References

1.

^ P. Weiss (1906) La variation du ferromagnetisme du temperature, Comptes Rendus, 143, p.1136-1149, cited in Cullity, 2008, p.116

2.

^ Cullity; C. D. Graham. Introduction to Magnetic Materials, 2nd ed.. New York: Wiley-IEte=2008. pp. 116. ISBN 0-471-47741-9.

3.

a b c d

Feynman, Richard P.; Robert B. Leighton, Matthew Sands (1963). The Feynman Lectures

on Physics, Vol. I. USA: California Inst. of Technology. pp. 37.5-37.6. ISBN 0-201-02117-XP. 4. ^ Carey R., Isaac E.D., Magnetic domains and techniques for their observation, The English University Press Ltd, London, (1966).

Jiles, David (1998). Introduction to magnetism and magnetic materials. London: Chapman & Hall. ISBN 0-412-79860-3.

Change of declination in time and space

Magnetic declination varies both from place to place and with the passage of time. As a traveller cruises the east coast of the United States, for example, the declination varies from 20 degrees west (in Maine) to zero (in Florida), to 10 degrees east (in Texas), meaning a compass adjusted at the beginning of the journey would have a true north error of over 30 degrees if not adjusted for the changing declination. In the UK it is one degree 34 minutes west (London), and as the country is quite small that figure is fairly good for the whole of the country. It is reducing, and in about 2050 it will be [1] zero. In most areas, the spatial variation reflects the irregularities of the flows deep in the earth; in some areas, deposits of iron ore or magnetite in the Earth's crust may contribute strongly to the declination. Similarly, secular changes to these flows result in slow changes to the field strength and direction at the same point on the Earth. The magnetic declination in a given area may (most likely will) change slowly over time, possibly as little as 22.5 degrees every hundred years or so, depending upon how far from the magnetic poles it is. For a location closer to the pole like Ivujivik, the declination may change by 1 degree every three years. This may be insignificant to most travellers, but can be important if using magnetic bearings from old charts or metes (directions) in old deeds for locating places with any precision. Simply speaking, true north is the direction in which the north pole is located along the Earth's rotational axis, while magnetic north is the direction toward which the compass needle points.