INDIVIDUAL CLASSES FOR CHEMISTRY

ALCHEMY CLASSES
Converting ordinary into extraordinary

2012 From ordinary to extraordinary

ALCHEMY CLASSES

REVIEW TEST-4
CHEMISTRY
Class : XII Time : 90 Min. Date : 11.08.2012 Max. Marks : 132

VERY IMPORTANT : The question paper consists of two sections. Each section contains different types of questions. Please read the instruction carefully which is common for each section.

INSTRUCTIONS
This paper consist total 35 questions. Please ensure that the Question Paper you have received contains ALL THE QUESTIONS in each Section and PAGES. If you find some mistake like missing questions or pages then contact immediately to the Invigilator. 1. In Section-I for Q. 1 to Q. 13; has four choices (A), (B), (C), (D) out of which only one is correct and carry 3 marks each. There is NEGATIVE marking. 1 mark will be deducted for each wrong answer. 2. In Section-II for Q.14 to Q.22, for each question you will be awarded 4 marks and zero marks otherwise. There are no negative marks in this section. 3. In Section-III for Q.23 to Q.25, Comprehension type,each question carries 3 marks and there is no negative marking in this section. 4. In Section-IV is Q.26 , Match the column type question,3 marks will be awarded each if all the bubbles realated to per part of column I are filled correctly .No negative marking. 5. In Section-V for Q.27 to Q.35, are Integer answer type questions and carry 4 marks each. There is NO NEGATIVE marking. Marks will be awarded only if correct bubbles are filled in your OMR sheet. 6. Indicate the correct answer for each question by filling appropriate bubble in your answer sheet. 7. Use of Calculator, Log Table, Slide Rule and Mobile is not allowed. 8. The answer of the questions must be marked by shading the circle against the question by dark By Pen only.

USEFUL DATA
Atomic weights : A1 = 27, Mg = 24, Cu = 63.5, Mn = 55, Cl = 35.5, O = 16, H = 1, P = 31, Ag = 108, N = 14, Li = 7, I = 127, Cr = 52, K = 39, S = 32, Na = 23, C = 12, Br = 80, Fe = 56, Ca = 40, Zn = 65.5, Ti = 48, Ba = 137, U = 238, Co = 59, B = 11, F = 19, He = 4, Ne = 20, Ar = 40, Mo = 96 Take g = 10 m/s2 where ever required.

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REVIEW TEST-4

Er. Shivanand Upadhyay & Neha Joshi Upadhyay

[2] [13 3 = 39]

SECTION-I
ONLY SINGLE CORRECT: Q.1 Select the CH bond marked with an arrow, which has lowest bond energy.

H
H

(A)

(B)

(C)

(D)

H2C H
Q.2

Two elements P and Q have half lives of 20 and 8 minutes respectively. Freshly prepared sample of each isotope initially have same activity. After 40 minutes, the ratio of number of P atoms and Q atoms will be : (A) 16 : 1 (B) 1 : 10 (C) 20 : 1 (D) 1 : 20 Which of the following has highest heat of hydrogenation. (A) (B) (C) (D)

Q.3

Q.4

The half life period of a radioactive element X is same as the mean life of another radioactive element Y. Initially both of them have same number of atoms. Then : (A) X and Y have the same decay rate initially (B) X and Y decay at the same rate always (C) Y will decay at a faster rate than X (D) X will decay at a faster rate than Y The type of delocalisation involving sigma bond orbitals is called (A) inductive effect (B) hyperconjugation (C) electromeric effect (D) mesomeric effect

Q.5

Alchemy Classes : 350, Near Shiv Shakti Mandir, Mahaveer Nagar, Jaipur [Mob.: 9929104019, 9950722060]

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REVIEW TEST-4 Q.6

Er. Shivanand Upadhyay & Neha Joshi Upadhyay

64 29 64 30

[3]

Masses of two isobars Cu and from these data that : (A) both the isobars are stable (B) (C) (D)
64

Zn are 63.9298 u and 63.9292 urespectively. It can be concluded

Zn is radioactive, decaying to Cu is radioactive, decaying to Cu is radioactive, decaying to

64

Cu through -decay Zn through -decay Zn through -decay

64

64

64

64

Q.7

Which of the following has the maximum acidic strength? (A) o-nitrobenzoic acid (B) m-nitrobenzoic acid (C) p-nitrobenzoic acid (D) p-nitrophenol The half life of
131

Q.8

I is 8 days. Given a sample of

131

I at time t = 0, we can assert that :

(A) no nucleus will decay before t = 4 days (B) no nucleus will decay before t = 8 days (C) all nuclei will decay before t = 16 days (D) A given nucleus may decay at any time after t = 0 Q.9 A compound which is not isomeric with diethyl ether is (A) n-propyl methyl ether (B) 1-butanol (C) 2 methyl-2-propanol (D) butanone Which of the following is a correct statement? (A) Beta rays are same as cathode rays (B) Gamma rays are high energy neutrons (C) Alpha particles are single ionized helium atoms (D) Protons and neutrons have exactly the same mass

Q.10

Q.11 The correct order of decreasing acid strength of trichloroacetic acid (A), trifluoroacetic acid (B), acetic acid (C), and formic acid (D) is (A) A > B > C > D (B) A > C > B > D (C) B > A > D > C (D) B > D > C > A

Alchemy Classes : 350, Near Shiv Shakti Mandir, Mahaveer Nagar, Jaipur [Mob.: 9929104019, 9950722060]

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REVIEW TEST-4 Er. Shivanand Upadhyay & Neha Joshi Upadhyay [4] Q.12 Binding energy per nucleon Vs mass number curve for nuclei is shown in the figure. W, X, Y and Z are four nuclei indicated on the curve. The process that would release energy is : (A) Y 2Z (B) W X + Z (C) W 2Y (D) X Y + Z
Binding enegy per nucleon in MeV
Y X W

8.5 8.0 7.5 5 Z 30

60

90

120

Mass number of nuclei

Q.13

Ne nucleus, after absorbing energy, decays into two -particles and an unknown nucleus. The unknown nucleus is : (A) Nitrogen (B) Carbon (C) Boron (D) Oxygen

22

SECTION-II
MORE THAN ONE CORRECT : Q.14 Select the incorrect statement.
NH2 NH2 CH3

[9 4 = 36]

(A)

is more basic than

COOH

(B)

COOH CH3

is less acidic than

NMe2

NMe2

(C)
NO2

CH3

is more basic than

NO2

(D)

CH3

has shorter CN bond length than

Alchemy Classes : 350, Near Shiv Shakti Mandir, Mahaveer Nagar, Jaipur [Mob.: 9929104019, 9950722060]

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REVIEW TEST-4 Er. Shivanand Upadhyay & Neha Joshi Upadhyay [5] Q.15 Which of the following is/are correct regarding the nucleus of an atom : (A) Inside nucleus particles representing neutrons and protons are constantly changing (B) In a stable nucleus the conversion of neutron to proton and proton to neutron are in equilibrium (C) between two protons and between two neutrons neutral II-mesons are exchanged (D) between a neutron and proton there is exchange of charged II-mesons Q.16 Which of the following statement/s is/are true about the following :

O O O

(I)
(A) (I) and (III) are structural isomers (C) (II) and (III) are structural isomers Q.17

(II)

(III)

(B) (I) and (II) are geometrical isomers (D) (I) and (II) are identical

A radioactive nucleus A X undergoes radioactive decay : Z (A) Both A and Z decreases if the decay is -decay (B) Both A and Z change if the decay is -decay (C) A decreases if the decay is + decay (D) Z decreases if the decay is decay Which one of following represents different molecules?

Q.18

(A)

and

(B)

and

Cl

Cl

(C)

and

(D)

and

Alchemy Classes : 350, Near Shiv Shakti Mandir, Mahaveer Nagar, Jaipur [Mob.: 9929104019, 9950722060]

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REVIEW TEST-4 Q.19

Er. Shivanand Upadhyay & Neha Joshi Upadhyay

[6]

A B C D correct statements is/are : (A) A and B are isodiaphers (C) C and D are isobar

(B) B and C are isobar (D) A and D are isotopes

O
Q.20 Correct statement about the molecule Ph C NH is:

(A) This molecule shows geometrical isomerism. (B) One of the resonating structure of this molecule shows geometrical isomerism (C) None of the resonating structure of this molecule shows geometrical isomerism (D) In acidic medium this molecule shows geometrical isomers.

Q.21

n ratio in a radioactive disintegration can be increased by : p (A) -emission (B) -emission (C) positron emission (D) K-electron capture
Select true statement(s) : (A) Resonance effects bond length (B) cis-1-bromo-1,2-difluoro ethene and Z-1-bromo-1,2-difluoro ethene are geometrical isomers

Q.22

O COH
(C) In CH2 most acidic H is connected directly to oxygen not on carbon.

COH O
OH
OH

OH
is less than

(D) Boiling point of

Alchemy Classes : 350, Near Shiv Shakti Mandir, Mahaveer Nagar, Jaipur [Mob.: 9929104019, 9950722060]

REVIEW TEST-5 XII [11-08-12] WA.pmd

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REVIEW TEST-4

Er. Shivanand Upadhyay & Neha Joshi Upadhyay

[7]

SECTION-III
Paragraph for Question No. 23 to 25 [3 3 = 9] Inductive effect is the polarization of shared pair (covalently bonded pair) of electrons towards more electronegative atoms. Let us consider a molecule of ethane.
+ + +

C C C C * Inductive effect operates through bonds. * There occurs partical delocalization (movements) of shared pair of electrons. * This is a very weak effect. * This effect is additive in nature, i.e. two electronegative atoms exert greater induction effect than one atom of greater electronegativity from the same position.

Q.23

Which of the following cation will be more stable : (A)

+

(B)

(C) Q.24

(D)
+

Which of the following carbanion will be highly unstable : (A) CH3CH2 (C) HC
C

(B) CH2=CH (D) O CH2

Q.25

Stability order for radical will be :

(I)

(II)

(III)

(A) I > II > III

(B) II > I > III

(C) III > I > II

(D) I > III > II

Alchemy Classes : 350, Near Shiv Shakti Mandir, Mahaveer Nagar, Jaipur [Mob.: 9929104019, 9950722060]

REVIEW TEST-5 XII [11-08-12] WA.pmd

8/12/2012, 9:50 AM

REVIEW TEST-4

Er. Shivanand Upadhyay & Neha Joshi Upadhyay

[8]

SECTION-IV
MATCH THE COLUMN TYPE QUESTIONS: Q.26 Column-I Mode of decay (A) Alpha decay (B) Electron decay (C) Positron decay (D) K-electron capture Column-II Characteristic properties (P) (Q) [1 12 = 12]

n ratio decreases p

n ratio increases p (R) Neutron is converted into proton

(S) Proton is converted into neutron

SECTION-V
SUBJECTIVE : [9 4 = 36] Q.27 In a nuclear reactor 235U undergoes fission liberating 200 MeV of energy. The reactor has a 10% efficiency and produces 1000 MW power. If the reactor is to function for 16 hrs. The total number of mols of uranium atoms required is ..................... (NA = 6 1023)

Q.28

An unknown atom has 30 neutrons in its nucleus. Ratio of radii of nuclei of this atom and 4 He is 2 (14)1/3. Find the atomic number of unknown atom.

Q.29 Determine how many of the following compounds are cis isomer

(a)

(b)

(c)

Alchemy Classes : 350, Near Shiv Shakti Mandir, Mahaveer Nagar, Jaipur [Mob.: 9929104019, 9950722060]

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REVIEW TEST-4

Er. Shivanand Upadhyay & Neha Joshi Upadhyay

[9]

(d)

(e)

(f)

Q.30

Find the number of chemical species which can act both as Bronsted acids and bases. (1) HCl (5) HS (2) H2O (6) HC2O4 (3) HCO3 (7) HF (4) NH3

Q.31

In a sample pitch blende the atomic ratio of 206Pb : 238U = 24 : 1. The age of the mineral is ....... 108 years. If half life of uranium is taken as 4.2 109 hours. All lead is originated from uranium. [Use ln 5 = 1.6] [ln 2 = 0.7]

Q.32

Number of Bezylic hydrogens in the following compound are :

Q.33

235 If a nuclide 92 U underwent a fission reaction producing two daughter nuclei and two neutrons. If the difference between the mass number and atomic number of two daughter nuclei are 55 and 20 respectively then find x + y. x = Mass number of heavy daughter nuclei y = Atomic number of lighter daughter nuclei

Alchemy Classes : 350, Near Shiv Shakti Mandir, Mahaveer Nagar, Jaipur [Mob.: 9929104019, 9950722060]

REVIEW TEST-5 XII [11-08-12] WA.pmd

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REVIEW TEST-4

Er. Shivanand Upadhyay & Neha Joshi Upadhyay

[10]

Q.34

238 92

U undergoes following sequence

, , , , , , , , , and to obtain A X . Find the value of (Z + A). Z

Q.35

Total No. of contributing structures showing hyperconjugation. (involving C-H bonds) for the
CH3
+

CH2CH3

following carbocation is.

Alchemy Classes : 350, Near Shiv Shakti Mandir, Mahaveer Nagar, Jaipur [Mob.: 9929104019, 9950722060]

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