p-2 IIT 2012 (Final)

1
Test series IIT JEE 2012

Part test 2
Physics
Section-A
Single Correct answer type
This section contains 7 multiple choice questions numbered 1 to 7. Each question has 4 choices (A), (B), (C) and (D), out
of which ONLY ONE is correct Marking Scheme (+ 3, 1)
1. A glass rod with a hemispherical end has a radius 1cm and its material has refractive index
2
3
. It is
immersed in a liquid of refractive index
3
4
and an object is placed in water along the axis of the rod at
a distance of 8cm form the curved edge. The image of the object is formed.
a) at b) 2cm towards object c) 2cm away form the object d) at a distance 8cm form object.
2. Figure shown is a glass paper weight semispherical in shape and of radius 2cm placed in contact with a
mark O on a white paper. When we view the mark verticlally above AB it will appear at a distance (from
AB) of

a) cm
3
4
b) 1.5 cm c) 1 cm d) 2 cm
Impact Coaching S.C.O 380, 2
nd
Floor, Sector 37-D, Chandigarh, Ph. No. 0172-5017711, 09815166849
S P A C E F O R R O U G H W O R K
2
3. If the focal length of the concave mirror is 23cm. What must be the value of x, so that final image is
formed at infinity (given
of transparent slab is 1.5)

a) 4 cm b) 15 cm c) 10 cm d) 25 cm
4. In the figure shown is a glass sphere of radius 10cm and made of a transparent material of refractive index
1.5. The final image of an object O placed at a distance of 2.5cm is

a) At a distance of 10cm away form B b) At a distance 100cm form B
c) At infinity d) At the position of object
5. An optical system consists of two convex lenses of focal lengths f1 = 20cm and f2 = 10cm. The distance
between the lenses is d = 30cm. An object is placed at a distance of a1 = 30cm form the first lens in the
opposite side of the second lens. The distance of image formed form second lens is
a) 7.5cm b) 15 cm c) Infinity d) 30cm
nd
3
6. A point source S is placed midway between two converging mirrors having equal focal length f as shown in
figure. Among the following values of d for which only one image is formed is

a) 2 f b) 4 f c) Both a & b d) 6 f
7.
nd
4
Section-B
Multiple Answer Correct type
This section contains 4 multiple choice questions numbered 8 to 11. Each question has 4 choices (A), (B), (C) and (D),
out of which may have ONE or MORE THAN ONE is correct Marking Scheme (+4, 0)
8. A point object A moves towards a convex mirror with a constant speed v along its optical axis. The speed of
the image
a) Is always < v b) Is > v if its distance is less than focal length
c) Decreases as A goes away from the mirror d) Is may be greater than v for some position of lens.
9. A cube of side
5
f
is placed with one side along the principal axis of concave mirror of focal length f such
that its image will be real, volume will be more than that of object and one face just touches the object then

a) Area of each face of the image is different from that of object
b) Area of one face of image is equal to that of object
c) Length of the side along the principal axis is
4
f
d) Area of the foace which is farthest form the lens and perpendicular to principal axis is
16
2
f
nd
5
10. A thin symmetrical double convex lens of poer p is cut into three parts as shown. Then
a) The power of B is
2
p
b) The power of A is
2
p
c) The power of the configuration given in figure(ii) is 0
d) The power of A and C are half of that of B
11.
nd
6
Section-C
Paragraphs Type
This section contains 2 paragraphs containing a total of 5 multiple choice questions numbered 12 to 16. Each question
has 4 choice (A), (B), (C) and (D) out of which only one correct .
Marking Scheme (+ 3 1)
Passage 1
Read the following Passage and answer the questions. Each question in this section has ONLY one correct answer.
Fermats Principle:
Fermat discovered a remarkable principle which we often express in these terms:
A light ray traveling form one point to another will follow a path such that, compared with nearby paths, the time
required is either a minimum or a maximum or is stationary (or unchanged) (constant)
To prove the law of refraction form Femats principle, consider the diagram, which shows two points A and B in
two different media and a ray APB connecting them.
Optical path length
2 2 1 1
n n +
( )
2 2
2
2 2
1
x d b n x a n + + +
r n i n
dx
d
sin sin 0
2 1

Which is law of refraction
nd
7
12. If t0 is the time taken for the ray APB in the illustration shown and if C is the velocity of light in free space,
then t0 equals
a)
( )
C
n n
2 1
2 2 1 1

+
+
b) ( ) C n n
2 2 1 1
+ c)
C
n n
2 2 1 1
+
d)
2 2 1 1
1
n n +
13. The word near by paths is added in the Fermats principle so that you do not take a far-off path such as
APB as shown in the figure below.

All paths within the hatched region shown can be considered as near by paths.
If t0 is time taken for optical path APB (this is the path with n1 sin i = n2 sin r), and tS, tQ, tR be respective
time value for optical paths through S, Q, R respectively. Then out of tS, tQ, tR
a) tQ will be the minimum b) tR will be the minimum
c) tS will be the minimum d) None of the above
14. Suppose we apply Fermats principle in reflection, as shown below.

nd
8
0
dx
d
Gives condition i = r,
Let the time taken for such a path APB be t1. Compared to other near-by paths, t1 could be either minimum
or maximum or constant. We can work it out of course, but without working it out, we can conclude its
behavior on comparing with the case of refraction in the previous question and say whether t1 will show
same behavior or opposite behavior to t0 (of the refracted ray)
a) Similar to (Either both minimum or both maximum
b) Dissimilar to t0
c) t1 will be constant but t0 is not
c) Cannot conclude unless values of dimensions a and b are known.
Passage 2
15.
16.
nd
9
Section-D
Integer type problems
This section contains 3 integer type questions numbered from 17 to 19 . The answer to each of the question is a single
digit integer, ranging from 0 to 9. Marking Scheme (+4 , 0)
17.
18.
nd
10
19.
Section-E
Matrix Match
This section contains 2 questions. Each question contains statements given in two columns which
have to be matched. Statements (p,q,r,s) in column-I have to be matched with statements (a,b,c,d) in
Column-II. The answers to these questions have to be approximately bubbled as illustrated in the
following example. If the correct matches are p-a,d q-b,c, r-a,b s-d then the correctly bubbled 4 4
matrix should be as shown. Marking Scheme (+ 8, 0)
nd
a b c d
a b c d
a b c d
a b c d
a b c d
p
q
r
s
11
20.
nd
12
21.
nd
13
Mathematics
Section-A
out of which ONLY ONE is correct Marking Scheme (+ 3, 1)
22. The area of the region of the plane bounded by max (|x|, |y|) 1 and x y
2
1
is
(a)
2 ln
2
1
+
(b)
4
31
(c) 1 + 2 ln 2 (d) 3 + ln 2
23. The graphs of f(x) = x
2
and g(x) = cx
3
(c > 0) intersect at the points (a, 0) and
,
_
2
c
1
,
c
1
. If the region which lies
between these graphs and over the interval [0, 1/c] has the area equal to 2/3 then the value of c is :
(a) 1 (b) 1/3 (c) 1/2 (d) 2
24. If l =
+
+
, c ) p ( f dp
1 p
1 p
p 2
1
then f(p) is
(a) ) 1 p p ln(
2
1
2
(b)
,
_
+

p sec
2
1
p cos
2
1
1 1
(c) p sec
2
1
1 p p ln
1 2
+ (d) none
nd
14
25. If
+
+
+
c
x
) 6 bx ( ) x 4 ( a
dx
x
x 4
5
2 2 / 3 2
6
2
(a)
1 b ,
3
40
a
(b)
1 b ,
120
1
a
(c)
3
40
a
, b = 1 (d) a =
1 b ,
120
1
26. If f(x) = f(a x ), g(x) = g(a x) and 3h(x) 4h(a x) = 5 then the value of
a
0
) x ( f
.g(x).h(x).dx = k
a
0
dx ) x ( g ). x ( f
where k is
(a) - 5 (b) 5 (c) 1 (d) none of these
27. Let A =
+
1
0
t
t 1
e
then

a
1 a
t
1 a t
e
has the value :
(a) Ae
-a
(b) -Ae
-a
(c) -ae
-a
(d) Ae
a
28. The differential equation
dx
dy
=
y
y 1
2
determines a family of circles with

(a) variable radii and a fixed centre ( 1 , 0 ).
(b) variable radii and a fixed centre ( 0 , -1 ).
(c) fixed radius 1 and variable centres along the x-axis.

(d)

fixed radius 1 and variable centres along the y-axis.
Section-B
nd
15
29.
b
x
1
ae y
+
is a solution of
2
x
y
dx
dy
when
(a) a = 1, b = 0 (b) a = 2, b = 0 (c) a = 1, b = 1 (d) a = 2, b = 2
30. The equation of curve through point (1, 0) and whose slope is
x x
1 y
2
+
(a) (y 1) (x + 1) + 2x = 0 (c) 2x (y 1) + x + 1 = 0
(b)
x 1
x 1
y
+
(d) none of these

31. If
1
x
2
1
and
t 1
dt
I
I2 =
+
x
1
1
2
t 1
dt
, x > 0; then
(a)
2 1
I I
(b)
2 1
I I >
(c)
1 2
I I >
(d) x tan
4
I
1
2

32.

x 3 tan 3 x tan
x cot x 3 cot 3
dx = Ax + Blog
x tan 3
x tan 3
+
+ C
(a) A = 1 (b) B = 3 (c) B =
3
1
(d) A = 1
Section-C
Paragraphs Type
nd
16
Passage 1
If the integrand is a rational function of x and fractional powers of a linear fractional function of the form ,
d cx
b ax
+
+
then
rationalization of the integral is affected by the substitution
d cx
b ax
+
+
= t
m
where m is .c.m of fractional powers of .
d cx
b ax
+
+
33. If I =
dx
1 ) 3 x 2 (
) 3 x 2 (
3 / 1
2 / 1
= 3
C ) x ( g ) 3 x 2 ( ) 3 x 2 (
3
1
) 3 x 2 (
5
1
) 3 x 2 (
7
1
6 / 1 2 / 1 6 / 5 6 / 7
+
1
]
1
+ +
then g(x) is equal to
(a) tan
1
(2x 3)
1/6
(b) (2x 3)
1/2
(c) 3 tan
1
(2x 3)
1/6
(d) 4(2x 3)
1/6
34. If I =
+
+
+
C
2 x
1 x
A
) 2 x ( ) 1 x (
dx
4 5 3
then A is equal to
(a) 1/3 (b) 2/3 (c) 3/4 (d) 4/3
Passage 2
A rumour spreads through a population of 5000 people at a rate proportional to the product of the number of people who
have heard it and the number who have not. Suppose that 100 people initiate the rumour and that a total of 500 people
known the rumor after two days.
Let y(t) denotes the number of people who know the rumour at time t. Take log9/log 49 = 129/229
35. The time required for half the population to hear rumor is
(a) 4 days (b) 6.2 days (c) 4.58 days (d) 3.32 days
nd
17
36.

1
0
y(t) dt is equal to
(a) 5000 log

,
_
+
49
e 49
k 5000
(b) 5000 log (1 + e
5000 k
)
(c) 5000 log (1 + e
500 k
) (d) 5000 log (1 e
5000 k
)
37. The function y(t) is given by
(a)
kt 5000
e 50 1
5000
+
(b)
kt 5000
e 49 1
5000
+
(c)
kt 5000
e 50 1
5000
(d)
kt 5000
e 49 1
500
+
Section-D
38. If A = 3
( )( )
+ +
0
2 3
cos 1 cos 2 1 sin
d =
39. Suppose y = f(x) satisfies the differential equation ydx +y
2
dy = xdy. If f(x) > 0 x R and f(1) = 1, then f(-3 ) =
40. A curve has slope equals to
( )
1 x
3 y 1 x
2
+
+ +
at point (x , y) and passes through (2 , 0),the area enclosed by the
curve is A, then [A] = , where[ ] denotes greatest integer function is.
Section-E
nd
18
Matrix Match
This section contains 2 questions. Each question contains statements given in two columns which
have to be matched. Statements (p,q,r,s) in column-I have to be matched with statements (a,b,c,d) in
Column-II. The answers to these questions have to be approximately bubbled as illustrated in the
following example. If the correct matches are p-a,d q-b,c, r-a,b s-d then the correctly bubbled 4 4
matrix should be as shown. Marking Scheme (+ 8, 0)
41. Match the following
Column I Column II
(p)
Let

+ +
+
b
a
4 dx
) x b a ( f ) x ( f
) x b a ( f
, if a = 10 then b is equal to
(a) 8
(q)
3
x
0
2 2
0 x
x
dt ) t t 4 (sin
lim
is equal to
(b) 17/3
(r)
Let f : (0, ) R and F(x) =
x
0
) t ( f
dt. If F(x
2
) = x
2
(1 + x),
then f(4) is equal to
(c) 18
(s)
4
0
| x cos |
dx is equal to
(d) 4
42. Let f(x) = max {sin x, cos x, } then area bounded by the curve y = f(x) and x-axis with in the limits
Column I Column II
(p)
0 x < /4
(a)
3 /2
(q)
/4 x < 5/6
(b)
5/12
(r)
5/6 x < 5/3
(c)
2
2 3 +
(s)
5/3 x < 2
(d)
1/ 2
nd
a b c d
a b c d
a b c d
a b c d
a b c d
p
q
r
s
19
Chemistry
Section-A
out of which ONLY ONE is correct Marking Scheme (+ 3, 1)
43. Which of the following statements is not true regarding vapour pressure of solvent (p) and that of the solution
(ps) containing non-volatile solute?
(a) Both p and ps increase on increasing temperature
(b) (pps) increases on increasing temperature
(c) ps = p mole fraction of solvent
(d)

p
) p p (
s
decreases on increasing temperature
44. The pair of compound which can exist together in aqueous solution is
(a) Na2CO3 and NaHCO3 (b) K2Cr2O7 and NaOH
(c) NaHCO3 and NaOH (d) none of these
45. Which of the following sequences represents the correct increasing order of bond angles in the given molecules?
(a) ClO2 < OF2 < OCl2 < H2O (b) OF2 < H2O < OCl2 < CO2
(c) OCl2 < ClO2 < H2O < OF2 (d) H2O < OF2 < OCl2 < ClO2
46. The hybridization of P is
3
4
PO is the same as of
(a) S in SO3 (b) N in N
3 (c) I in ICl
+
2 (d) I in ICl4

nd
+NH
3

20
47. A compound of the molecular formula C10H12O decolorizes bromine in CCl4. On vigorous oxidation, it gives p-
anisic acid (p-methoxybenzoic acid). The compound can exist in how many forms ?
(a) 2 (b) 3 (c) 4 (d) 5
48. When m-chloronitrobenzene is treated with sodamide in presence of liquid ammonia, main product is
(a) o-Nitroaniline (b) p-Nitroaniline (c) m-Nitroaniline (d) All the above
49. A solution of cyclohexane in benzene is stirred at 0C while conc. H2SO4 is added. After the reaction, the acid is
removed and excess of benzene is removed, the product formed would be
(a) 1-cyclohexylcyclohexene (b) cyclohexylbenzene
(c) 1, 1-diphenylcyclohexane (d) no reaction
Section-B
50. Which of the following on reductive Ozonolysis give glyoxal as the exclusive product ?
(a) Ethene (b) Ethyne (c) Benzene (d) Toluene
51. Point out the correct statement(s) amongst the following
(a) Sodium salts are much more soluble than ammonium salts
(b) SnCl2 is ionic but SnCl4 is solvent
(c) NH3 has lesser polar character than BF3
(d) Calcium fluoride is more ionic than calcium iodide.
52. Solid HgI2 is gradually added to KI solution ; which of the following statements is/are correct?
(a) freezing point increases and then becomes constant
(b) freezing point decreases constantly
(c) Boiling point decreases and then becomes constant
nd
+NH
3

21
(d) Vapour pressure increases to a constant value
53. Which of the following statement is false regarding following reaction?
(e) No reaction is possible because Cl is present on benzene ring
(f) A nucleophilic substitution will take place in which both Cl will be replaced by two NH2
groups.
(g) A nucleophilic substitution will take place in which only Cl attached on C1 will be replaced by
NH2.
(h) A nucleophilic substitution will take place in which only Cl attached on C4 will be replaced by
NH2.

Section-C
Paragraphs Type
Passage 1
Four isomeric compounds (A, B, C and D) of the formula C11H13OCl give the following reactions.
nd
Cl
Cl
NO
2
1
2
3
4
5
6
+NH
3

22
A, B or C
X
Ni /
2
H

D
E
Ni /
2
H

A

4
CCl /
2
Br
Meso compound
B
t ) (
4
CCl /
2
Br
Mixture
54. The Compound A is
55. The compound B is
Passage 2
Gypsum when heated to different temperature give different products, various products formed are :
nd
COOH
Cl
OC
2
H
5

oxidation
13 11
OCl H C
Cl
OC
2
H
5
Cl
OC
2
H
5
Cl
OC
2
H
5
Cl
OC
2
H
5
Cl
OC
2
H
5
Cl
OC
2
H
5
Cl
OC
2
H
5
Cl
OC
2
H
5
120C
200C
400C
Gypsum
Plaster of paris
Dead burnt plaster
CaO, SO
2
, O
2
23
When hydrated calcium sulphate is heated to 200C it forms anhydrous salt. The anhydrous salt when heated with coke,
gives out SO2 gas.
56. The anhydrous calcium sulphate is called
(a) gypsum (b) plaster of paris (c) Dead burnt plaster (d) none of these
57. If we subject gypsum to flame test, we will get a flame having a ______ colour.
(a) brick red (b) crimson red (c) golden red (d) none of these
58. The product formed by heating gypsum to 150C will be
(a) CaSO4.2H2O(b) CaSO4.H2O (c) O H
4
3
. CaSO
2 4
(d) O H
2
1
. CaSO
2 4
Section-D
59. Total number of hybrid orbitals on central iodine in tri-iodide ion, are
60. 0.400 g of an acid HA (mol. Mass = 80) was dissolved in 100 of water. The solution showed a depression of
freezing point of 0.12 K. Compute dissociation constant (in multiple 10
3
) of the acid at about 0C, given Kf
(water) = 1.86 K Kg mol
1
. Assume molarity of solution molality
61. How many total monochloro product(s) will be obtained during reaction of 2, 3-dimethyl butane with Cl2 in
presence of sun light?
Section-E
Matrix Match
nd
a b c d
a b c d
a b c d
a b c d
a b c d
p
q
r
s
24
This section contains 2 questions. Each question contains statements given in two columns which have to be matched.
Statements (p,q,r,s) in column-I have to be matched with statements (a,b,c,d) in Column-II. The answers to these
questions have to be approximately bubbled as illustrated in the following example. If the correct matches are p-a,d q-b,c,
r-a,b s-d then the correctly bubbled 4 4 matrix should be as shown. Marking Scheme (+
8, 0)
62. Hf = Molar heat of fusion of ice; Lf = Latent heat of fusion of ice (g
1
)
Hv = Molar heat of vaporization of water; Lv = Latent heat of vaporization of water (g
1
)
Match the following appropriately:
Column I Column II
(p) Molal depression constant of water (a)
v
H 1000
R 373 373 18

(q) Molal elevation constant of water (b)
v
L 1000
R 373 373
(r)
Tf of solution containing 9.0 g of glucose
in 50 g of water
(c)
f
H 1000
R 273 273 18

(s)
Tb of solution containing 3.0 g of urea in
50g of water
(d)
f
L 1000
R 273 273
63. Match the following
Column I Column II
(p) Free radical mechanism (a)
(q) Ionic mechanism (b)
nd
25
(r) Benzyne (c)
(s) Lewis acid (d)
nd

p-2 IIT 2012 (Final)

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1

Test series IIT JEE 2012

of transparent slab is 1.5)

determines a family of circles with

(d) none of these

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