DWARAKA DOSS GOVERDHAN DOSS VAISHNAV COLLEGE AUTONOMOUS COLLEGE Accredited A Grade College by UGC Affiliated to University of Madras

DEPARTMENT OF CHEMISTRY B.Sc Degree course in chemistry Syllabus CORE I SEMESTER - I General Chemistry 1 (75 Hrs, 5 Credits) Unit 1 ATOMIC STRUCTURE (15 Hrs) Plancks theory equation, importance of black body radiation, photoelectric effect- Compton effect- de-Broglies relationship Heisenbergs uncertainty principleSchrdinger wave equation (elementary treatment-equation only) significance of and 2 quantum number and their significance concept of atomic orbitals, shape of s, p, d and f orbitals. Unit 2 ELECTRONIC CONFIGUARATION AND PERIODIC PROPERTIES (15 Hrs) Paulis exclusion principle- Hunds rule Aufbau principles (n+1) rule stability of half and fully filled orbitals classification of elements as s,p,d and f block elements , variation of atomic volume , atomic and ionic radii, ionization potential ,electron affinity, electronegativity along periods and groups variation of metallic characters- factors influencing the periodic properties. Unit 3 PRINCIPLES OF INORGANIC QUALITATIVE AND VOLUMETRIC ANALYSIS (15Hrs) Solubility product- common ion effect concepts & their application in cation analysis - principle of elimination of interfering anions- complexation reactions in qualitative analysis Reactions of cations and anions in the analysis spot test reagents aluminon cupferon DMG - thiourea Magneson, alizarin and Nesslers reagent. Volumetric analysis molarity, normality, molality and mole fraction primary and secondary standards- Theories of acid- base- redox complexometric, iodometric and iodimetric titrations calculation of equivalent weights theories of acid base- redoxadsorption-metal ion indicators and choice of indicators.

Unit 4 BASIC CONCEPTS OF ORGANIC CHEMISTRY -I (15 Hrs) Hybridization shapes of CH4, C2H4, C2H2, C6H6 bond length bond energy bond polarity dipole moment electron displacement effects- inductive, mesmeric (resonance), Hyper conjugation., Steric Effect. Nomenclature of organic compounds containing upto 10 carbon atomsmonofunctional compounds Bifunctional compounds, mono cyclic and acyclic compounds. Unit 5 BASIC CONCEPTS OF ORGANIC CHEMISTRY II (15 Hrs) Chemsitry of alkanes and cycloalkanes petroleum source of alkanes Methods of preparing alkanes cycloalkanes chemical properties mechanism of free radical substitution in alkanes halogenation uses. Conformational study of ethane and n-butaneSawhorse and Newmann projections relative stability of cyclo alkanes from cyclopropane upto cyclohexane Bayers strain theory limitations cyclohexane and various forms of cyclo hexanes. References 1. Glasstone S., Lewis D., Elements of Physical Chemistry, London, Macmillan & Co., Ltd., 2. Gopalan R, Subramanian P.S, Rangarajan K, Analytical Chemistry. 3. Puri B.R.., Sharma L.R, Pathania Principles of physical Chemistry, Vishal Publishing C0 2006. 4. Puri B.R., Sharma L.R., Kalia K.K Principles of Inorganic chemistry, (23 rd edition), New Delhi, Shoban Lal Nagin Chand * Co 1993. 5. Morrison R.T. and Boyd R.N., Organic chemistry (6th edition) Ny, Allyn & Beecon Ltd (1976). 6. Pillai C. N., Organic chemistry, for undergraduates, 2008, university press.

CORE III SEMESTER - II GENERAL CHEMISTRY - II (75 Hrs, 5 Credits) Unit 1 CHEMICAL BONDING (15 Hrs) Ionic bond Lattice energy Born-Haber cycle Covalent bond bond polaritypauling and Mullikens scales of electronegativity polarizing power and polarisability Fajans rules - VB theory Principles of hybridization shapes of simple inorganic molecules BeCl2, BF3, NH3, XeF4, BrF5, PCl5, SF6, H2O and IF7. MO theory Application of H2, He2, N2, O2, HF and CO comparison of VB and MO theories. Co-ordinate bond Hydrogen bonding types and effects. Unit 2 CHEMISTRY OF S-BLOCK ELEMENTS (15 Hrs) General characteristics of group IA and II A- diagonal relationship- Extraction, properties and uses of Li, Na, K, Be, Mg and Ca. Preparation, properties and uses of NaOH, Na2CO3 KOH, KBr, KI, MgCO3, MgSO4, MgCl2, & Magnesium ammonium phosphate. Position of hydrogen. Unit 3 CHEMISTRY OF ALKENES, ALKYNES AND DIENES (15 Hrs) General methods of preparation and properties of Alkenes and alkyneselectrophillic and radical addition mechanisms-addition reactions with H2, X2 , HX, HOX, H2SO4, H2O, hydroboration, Ozonolysis and peroxide effect. Hydroxylation of alkenes with KMnO4-allylic substitution of alkenes by NBS - acidity of alkynes and formation of acetylides test for alkenes and alkynes. Dienes types stability preparation of 1,3 butadiene, isoprene and chloroprenereactivity 1, 2 and 1, 4 additions in conjugated dienes, Diels Alder reaction. Types of polymerization Mechanisms of ionic and free radical addition polymerization. Unit 4 CHEMISTRY OF BENZENE AND POLYNUCLEAR AROMATIC HYDROCARBONS (15 Hrs) Aromaticity Huckles rule Resonance in benzene Electrophilic substitution in aromatic compounds general mechanism nitration sulphonation halogenation Friedel Crafts alkylation and acylation orientation and reactivity in mono substituted benzenes polynuclear hydrocarbons naphthalene anthracene and phenanthrene preparation, properties and uses. 5

Unit 5 GASEOUS STATE (15 Hrs) Gas laws - kinetic theory of gases collision diameter mean free path collision number transport properties diffusion Maxwells Distribution of molecular velocities (no derivation) mean , root mean square and most probable velocity equipartition of energy molecular basis of heat capacity real gases vander Waals equation of state derivation significance of critical constants Virial equation of State Law of corresponding states Boyle Temperature Coefficient of compressibility Thermal expansion Joule Thompson effect. References: 1 2 3 4 5 6 7 Glasstone S., Lewis D., Elements of Physical Chemistry, London, Macmillan & Co.,Ltd., R.Gopalan, P.S.Subramanian, K.Rangarajan, Analytical Chemistry. Puri B.R.., Sharma L.R, Pathania Principles of physical Chemistry, Vishal Publishing C0 2006. Puri B.R., Sharma L.R., Kalia K.K Principles of Inorganic chemistry, (23 rd edition), New Delhi, Shoban Lal Nagin Chand * Co 1993. Morrison R.T. and Boyd R.N., Organic chemistry (6th edition) Ny, Allyn & Beecon Ltd (1976). C.N.Pillai, Organic chemistry, for undergraduates, 2008, university press. J.D.Lee, Concise Inoganic Chemistry, U.K., Black Well Science (2006)