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LECTURE OBJECTIVES Differentiate acids and bases, strong and weak, based on their properties and based on theories of Arrhenius and Bronsted-Lowry. (CO1) Write and balance acid-base neutralization reactions. (CO1)
+
Have a Cause
BASES
Have bitter Cause
taste
color changes in plant dyes with certain metals to produce H2 with carbonates and bicarbonates to produce CO2 acid solutions conduct electricity
React
Feel
Many
React
Aqueous
Aqueous
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ACIDS
BASES
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Nonelectrolyte does not conduct electricity. No cations (+) and anions (-) in solution C6H12O6 (s) H2O C6H12O6 (aq)
Non-electrolyte
Weak electrolyte
Strong electrolyte
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4.1
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How does electrolytes conduct electricity in solution? Cations (+) and Anions (-)
BASE Strong Electrolyte 100% dissociation/ionization H2O NaCl (s) Na+ (aq) + Cl- (aq) Weak Electrolyte not completely dissociated/ionized CH3COOH CH3COO- (aq) + H+ (aq)
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4.1
Strong Acid
Weak Acid
Hydration is the process in which an ion is surrounded by water molecules arranged in a specific manner.
d-
d+ H2O
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15.4
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4.1
ACID-BASE DEFINITIONS
Svante Arrhenius, 1859-1927 (J.N. Bronsted and T.M. Lowry, 1923)
Arrhenius
ACIDS
Bronsted-Lowry
produce hydronium ion, H3O+ or hydrogen ion, H+ in aqueous solutions produce OH- in aqueous solutions
BASES
BASES
IONIZATION/DISSOCIATION REACTIONS
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4.3
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DISSOCIATION REACTIONS
base
acid
acid
base
4.3
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4.3
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NH4+(aq)
Conjugate acid
Base Acid Conjugate acid Conjugate base Conjugate acid-base pairs: H2O-H3O+; HF-F-
base
acid
H2O is AMPHIPROTIC/AMPHOTERIC Substance that can act either as a proton donor or proton acceptor
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Lewis Definition
Gilbert Newton Lewis (1875-1946)
Acid-Base Definition
Acids yields H3O+ in solution Bases yields OH- in solution proton (H+) acceptor electron pair donor
Definitions Arrhenius
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Dissociation/Ionization reactions
Acids
Strong
Bases
Strong
or weak or
or weak or polybasic
Monoprotic
Monobasic Arrhenius
polyprotic
Arrhenius
or Bronsted-
or Bronsted-
Lowry
Lowry
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15.4
Neutralization/Acid-Base Reaction
During neutralization, an acid reacts with a base, forming water and a salt.
Neutralization/Acid-Base Reaction
The amount of acid (or base) in a solution is determined by careful neutralization.
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ACID-BASE/NEUTRALIZATION REACTION
acid + base HCl (aq) + NaOH (aq) H+ + Cl+ Na+ + OHsalt + water NaCl (aq) + H2O Na+ + Cl- + H2O H2O
H+ + OH-
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