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INDEX

Terms Page No. Terms Page No. 115 115 161 149, 150 34 73, 79 24 237 240, 242 246 12 241 239 151, 156 89 51 22 251, 252 247, 250 7 2, 3, 4 41 64 240 98 149 138 138 28, 220 240 27 23 134, 135 134, 135 256 159 49 74 138 64 63 218, 220 79 83 159 66 26 Absorption 122 Actinoid contraction 231 Actinoids 209, 230 Activated complex 112 Activators 132 Activation energy 113 Adsorption 122 Adsorption isotherm 125 Allotropic forms 175, 187 Ambidentate ligand 240 Amorphous solids 2 Anisotropic 3 Anomalous behaviour of oxygen 182 Antiferromagnetism 28 Aqua regia 199 Arrhenius equation 111, 113 Atomic radii 166, 181, 193, 203 Average rate 95 Avogadro constant 20 Azeotrope 46, 47 Batteries 86 Binary solutions 33, 41, 44 Biochemical catalysis 131 Black phosphorus 176 Blast furnace 154, 156, 157 Blister copper 157 Body-centred unit 7, 11 Bohr magneton 27, 221 Bonding in metal carbonyls 254 Bravais lattices 7 Bredig's arc 137 Brown ring test 175 Brownian movement 140 Calcination 150, 154 Cast iron 156, 162 Catalyst 114, 128 Cell potential 66 Chelate 240 Chemical kinetics 93 Chemisorption 123 Chiral 245 Chromatographic methods 160 Cis - isomer 244, 245 Classification of colloids 134 Close-packed structures 12 Coagulation 142 Colligative properties 47, 56 Collision frequency Collision theory of chemical reactions Column chromatography Concentration of ores Concentration of solutions Conductivity Conductors Coordination compounds Coordination entity Coordination isomerism Coordination number Coordination polyhedron Coordination theory Copper matte Corrosion Cryoscopic constant Crystal defects Crystal field splitting Crystal field theory Crystal lattice Crystalline solids Dalton's law Daniell cell Denticity Dependence on rate of concentration Depressants Dialyser Dialysis Diamagnetism Didentate Diode Dislocation defect Dispersed phase Dispersion medium Dissociation constant Distillation Ebullioscopic constant Electrical conductance Electro dialysis Electrochemical cells Electrochemistry Electrode potential 66, Electrolytes Electrolytic cell Electrolytic refining Electromotive force Electron hole

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Terms Electron vacancy Electronegativity Electronic configuration Electronic defect Electroosmosis Elements Ellingham diagram Eluant Empirical formula Emulsions Enantiomers End-centred unit Enthalpy Enzyme catalysis Equilibrium constant f.- block elements Face centred unit Facial isomer Faraday's law Ferrimagnetism Ferromagnetism First order reaction Froth floatation Fractional distillation Frenkel defect Frequency factor Freundlich isotherm Fuel cells Galvanic cell Gangue Gels Geometric isomerism Giant molecules Gibbs energy Haber's process Half-life Hall heroult process Halogens Henry's law Heterogeneous catalysis Heteroleptic complex Holme's signals Homogeneous catalysis Homoleptic complex Hybridisation Hydrate isomerism Hydration enthalpy Hydraulic washing Hydro metallurgy

Page No. 26 167, 181, 193 210 26 142 147 152 161 238 135, 143 245 8 124 131, 132 71 227 7, 11 245 83 28 28, 221 104, 109 149 169 22, 23 111 125 88 64, 65, 89 147, 148 135 244 5 65, 72, 117 128 108 158 192 40 128, 129 241 176 128 241, 254 248 249 217 148 158

Terms

Page No.

Hydrogen bonded molecular solids 4 Ideal solution 45 Impurity defect 23 Inhibitors 132 Inner transition metals 209, 227 Instability constant 256 Instantaneous rate of a reaction 96, 97 Insulators 25 Inter molecular forces 2 Interstitial compounds 223 Interstitial defect 22 Intrinsic semiconductors 25 Ionic conductance 75 Ionic radii 166, 181, 193 Ionic solids 5 Ionisation enthalpy 166, 181, 193, 203 Ionisation isomerism 246 Isomerism 244 Isotonic solution 54 Kinetic energy 113 Kohlrausch law 81, 82 Kraft temperature 136 Lanthanide contraction 213, 228 Lanthanoids 209, 227 Le Chateliers principle 38 Leaching 150 Lewis acids 240 Ligand field theory 247 Ligands 222, 240 Line defects 22 Linkage isomerism 248 Liquation 161 Long range order 2 Lyophilic colloids 137 Lyophobic colloids 137 Magnetic separation 151 Meridional isomer 247 Metal carbonyls 256 Metal excess defect 23 Metallic solids 5 Metallurgy 149, 153 Micelles 138 Minerals 149 Mischmetall 232 Molal elevation constant 49 Molality 37 Molar conductivity 79 Molarity 36, 53 Mole fraction 35, 48

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279 Index

Terms Molecular orbital theory Molecularity of a reaction Mond process Monoclinic sulphur Mononuclear coordination compounds Nernst equation Noble gases Non-ideal solution Non-polar molecular solids Octahedral voids Optical isomerism Order of a reaction Ores Osmotic pressure Ostwald's process Oxidation number Oxidation state Oxides of nitrogen Oxoacids of halogens Oxoacids of phosphorus Oxoacids of sulphur Ozone Packing efficiency Paper chromatography Paramagnetism p-block elements Peptization Physisorption Pig iron Point defects Polar molecular solids Polydentate Primary battery Primary valence Pseudo first order reaction Pseudo solids Purification of metal Pyrometallurgy Raoult's law Rate law Reaction rate constant Redox couples Red phosphorus Reverberatory furnace Reverse osmosis Rhombic sulphur Roasting

Page No. 249 104 162 189 244 70 204 45 4 15, 17 245 100 148 53 129 241 194 172 199 178, 179 189 185 18 161 27, 220 165 138 123 156 22 4 240 86 237 110 3 147 151, 157 41, 44 98, 99 99 65 175 151, 156 55 187 151, 154

Terms Schottky defect Secondary battery Secondary valence Semi conductors Semipermeable membrane Shape-selective catalysis Short range order Smoke screens Solid state Sols Solubility Solvate isomerism Stereo isomerism Stoichiometric defect Strong field ligands Structural isomerism Super cooled liquids Surface chemistry Temperature dependence of rate Tetrahedral permanganate Tetrahedral voids Thermodynamics Trans isomer Transition metals Tyndall cone Tyndall effect Ultrafiltration Unidentate Unit cells Units of rate constant Units of rate of a reaction Vacancy defect Valence bond theory Van arkel method Vapour phase refining Vapour pressure Voltaic cell Weak field ligands Werner's theory Wheatstone bridge White phosphorus Wrought iron Zeolites Zero order Reaction Zeta potential Zone refining

Page No. 22, 23 87 237, 238 25 53 130 2 176 2 135 37 247 244 22 251 244 3 121 111 226 14, 16 154 244 209, 212 139 139 139 240 7, 10 101 95 22 247, 250 160 160 42, 44 64 251 237, 239 73, 75 175 156, 162 130, 131 103, 109 141 159, 160

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