AP CHEMISTRY TEST CHAPTERS 1-4 MULTIPLE CHOICE - Place your answers on the sheet provided. 1.

Which pair consists of equalities? a. -117oC, -179oF b. -117oC, 390 K c. -32oC, 0oF d. 0oF, 243 K 2. Which number contains exactly four significant digits? a. 1240 b. 124.0 c. 0.0124 d. 0.124 3. How many liters will 1760 g of benzene occupy at 20oC if d20oC= 0.88g/mL? a. 0.25 L b. 0.50 L c. 1.0 L d. 2.0 L 4. How many grams of sugar are contained in 1.00 L of a sugar solution that has a density of 1.15 g/mL and contains 52.0 percent sugar? a. 1150 g b. 598 g c. 552 g d. 115 g 5. What is the mass in grams of a 5.0 grain aspirin tablet, given the following Apothecaries Weight System: 60 grains = 1 dram and 96 drams = 1 lb? ( 454 g = 1 lb ) a. 43 g b. 38 g c. 1.4 g d. 0.39 g 6. What is the correct sum for the following measurements: 3.65 x 101 cm, 4.26 x 102 cm, 1.32 x 102 cm? a. 9.23 x 101 cm b. 9.23 x 102 cm c. 5.95 x 102 cm d. 5.945 x 102 cm 7. How many significant digits should the answer to the following calculation possess? (2.65)(3.002)(38.26-1.2) = a. 1

b. 2 c. 3 d. 4 8. Which of the following statements is true, given the following information? Density of A = 2.0 g/mL; Density of B = 3.5 g/mL; Density of C = 0.10 g/mL; All densities are at 20oc a. 1 mL of A weighs more than 1 mL of B. b. 10 g of C has a smaller volume than 10 g of B. c. A, B, and C all have densities greater than water at 20oC. d. One liter of B has a greater mass than 1 liter of C. 9. Which of the following is incorrectly named? a. H3PO4 - phosphoric acid b. PO33- - phosphate ion c. HCl - hydrochloric acid d. Cl- - chloride ion 10. Which of the following is incorrectly named? a. CO - carbon monoxide b. SO2 - sulfur dioxide c. PCl3 - phosphorus trichloride d. N2O - nitrogen oxide 11. Which of the following is incorrectly named? a. CaCl2 - calcium chloride b. Na3PO4 - sodium phosphate c. KClO4 - potassium chlorate d. Mg(NO2)2 - magnesium nitrite 12. Which of the following is true about Daltons Atomic Theory? a. Atoms were viewed as indivisible. b. It was the first statement on the atomic characteristics of matter. c. It was immediately and widely accepted. d. All of his postulates are still true based on todays information.

13. Which of the following is the atomic mass of silver given the following distribution and masses of naturally occurring isotopes of silver: amu; and
109 47 107 47

Ag : 51.88%, 106.906

Ag :48.12%, 108.905 amu.

a. b. c. d.

107.868 amu 106.926 amu 108.235 amu 108.642 amu

14. Which of the following is not an empirical formula? a. N2O b. N2O4 c. NO2 d. HNO3 15. Which of the following is an ionic compound? a. CO2 b. PCl3 c. NO2 d. BaCl2 16. Which of the following is true about a. 63 protons b. 29 electrons c. 29 neutrons d. 63 neutrons 17. How many electrons does a. 10 b. 12 c. 14 d. 24
24 12 63 29

Cu ? It has

Mg 2+ possess?

18. Which of the following reactions represents a decomposition reaction? a. P4O10 + 6H2O 4H3PO4 b. 2NaN3 2Na + 3N2 c. 2H2O + O2 2H2O2 d. HCl + NaOH NaCl + H2O 19. What is the coefficient in front of MnO2 when the following equation is balanced? MnO2 + Al Mn + Al2O3 a. 1 b. 2 c. 3 d. 4 20. Which of the following contains 6.00 x 1016 atoms? a. 6.00 x 1016 H2O molecules b. 3.00 x 1016 Cl2 molecules c. 2.00 x 1016 P4 molecules

d. 1.50 x 106 CaSO4 empirical units 21. How many atoms are there in 36.20 g of P4 ( mass of one mole P=30.97 g) a. 1.746 x 1022 atoms b. 1.746 x 1023 atoms c. 7.040 x 1022 atoms d. 7.040 x 1023 atoms 22. What is the mass percentage of Ca in one mole of Ca3(PO4)2? a. 9.9% b. 20.0% c. 12.9% d. 38.8% 23. What is the empirical formula of caffeine if it contains 5.19% H, 28.85% N, 16.48% O, and 49.48% C by weight? a. C4H5NO2 b. C2H6NO2 c. C3H5NO d. C4H5N2O 24. What is the mass of Cu produced if 10.0 g of Cu2S reacts with 16.0 g of O2 as follows: Cu2S + O2 2Cu + SO2 a. 31.8 g b. 63.5 g c. 3.99 g d. 7.98 g 25. What is the percent yield if 25.0 g of I2 is formed when 130.0 g of HNO3 reacts with 285.0 g of HI as follows: 2HNO3 + 6HI 2NO + 3I2 + 4H2O a. 27.2% b. 17.6% c. 8.84% d. 4.42% 26. How many milliliters of 1.00 M NaOH are required to completely neutralize 100.0 mL of 0.500 M H3PO4? a. 50.0 mL b. 100.0 mL c. 150.0 mL d. 200.0 mL 27. What is the molarity of a NaNO3 solution if 25.0 mL of a 0.200 M NaNO3 solution is diluted to 100.0 mL? a. 0.0500 M b. 0.100 M c. 0.150 M d. 0.200 M

28. What is the molarity of a solution that contains 32.0 g of HCl in 2.50 L of solution? a. 0.00351 M b. 0.0128 M c. 0.351 M d. 12.8 M 29. How many moles of H2SO4 are present in 250 mL of a 3.00 M H2SO4 solution? a. 0.150 moles b. 0.750 moles c. 1.50 moles d. 750 moles For questions 30 through 37, identify each substance as a (a) strong electrolyte, (b) weak electrolyte, or (c) nonelectrolyte in water. 30. HCl 31. HF 32. HCN 33. NH3 34. sugar 35. I2 36. HClO4 37. MgCl2 38. Which of the following is not a strong base? a. NaOH b. Ca(OH)2 c. LiOH d. NH3 39. When HBr is neutralized with KOH, what salt is produced? a. H2O b. KH c. KBr d. K2O

40. What are the spectator ions in the reaction BaCl2(aq) + Na2SO4(aq) 2NaCl(aq) + BaSO4(s) a. Ba2+, Clb. Na+, Clc. Ba2+, SO42d. Na+, SO4241. Which of the following is the net ionic equation for the reaction Fe(NO3)3(aq) + K3PO4(aq) FePO4(s) 3KNO3(aq)

a. b. c. d.

K+(aq) + NO3-(aq) KNO3(aq) Fe3+(aq) + PO43-(aq) FePO4(aq) 3K+(aq) + PO43-(aq) K3PO4(aq) Fe3+(aq) + PO43-(aq) FePO4(s)

For questions 42 through 47, identify each species as (a) soluble or (b) insoluble in water. 42. Na3PO4 43. AgBr 44. NH4NO3 45. Ni(OH)2 46. CaCO3 47. BaCl2 48. Which of the following is most easily oxidized? a. Na b. Cl2 c. Au d. S 49. When a strong acid reacts with an active metal, which of the following is formed? a. H2(g) b. H2O(l) c. An element of the acid d. Another acid 50. Magnesium is more active than cobalt and hydrogen lies below both of them in the activity series. This means that a. cobalt is the most easily oxidized. b. magnesium is the most easily oxidized. c. neither metal reacts with acids. d. water is produced when the metals react with hydrogen ion.

PROBLEMS - Place your answers on looseleaf. 1. Read the following description of the element zinc, and indicate which are physical properties and which are chemical properties. Zinc is a silver-gray- colored metal that melts at 420oC. When zinc granules are added to dilute sulphuric acid, hydrogen is given off and the metal dissolves. Zinc has a hardness on the Mohs scale of 2.5 and a density of 7.13 g/mL at 25oC. It reacts slowly with oxygen gas at elevated temperatures to form zinc oxide, ZnO. 2. A match is lit and held under a cold piece of metal. The following observations are made: (a) The match burns. (b) The metal gets warmer. (c) Water condenses

on the metal. (d) Soot (carbon) is deposited on the metal. Which of these occurrences are due to physical changes, and which are due to chemical changes? 3. A cube of osmium metal 1.500 cm on a side has a mass of 76.31 g at 25oC. What is its density in g/cm3 at this temperature? 4. The speed of light in a vacuum is 2.998 x 108 m/s. What is its speed in km/hr? 5. What is the symbol for an ion with 63 protons, 60 electrons, and 88 neutrons? 6. Compute the mass in grams of a sample of americium containing six atoms. 7. Calculate the mass of a sample of cobalt containing 5.00 x 1030 atoms. 8. Compute the mass percent of each element in carvone, C10H14O. 9. A white powder is analyzed and found to contain 43.64% phophorus and 56.36% oxygen by mass. The compound has a molecular mass of 283.88 g/mol. What are the compounds empirical and molecular formulas? 10. If a sample containing 18.2 g of NH3 is reacted with 90.4 g of CuO, which is the limiting reactant? How many grams of N2 will be formed? The other products of the reaction are solid copper and water vapor. 11. Methanol, CH3OH, can be produced by the reaction of gaseous carbon monoxide and hydrogen. Suppose 68. 5 kg of CO(g) is reacted with 8.60 kg of H2(g). Calculate the theoretical yield of methanol. If 3.57 x 104 g is actually produced, what is the percent yield of methanol? 12. Calculate the number of moles of Cl- ions in 1.75 L of 1.0 x10-3 M ZnCl2. 13. What volume of 16 M sulfuric acid must be used to prepare 1.5 L of a 0.1 M H2SO4 solution? 14. Using the activity series, write balanced chemical equations for the following reactions. If no reaction occurs, simply write NR. (a) Iron metal is added to a solution of copper(II) nitrate; (b) zinc metal is added to a solution of magnesium sulfate; (c) hydrobromic acid is added to tin metal; (d) hydrogen gas is bubbled through an aqueous solution of nickel(II) chloride; (e) aluminum metal is added to a solution of cobalt(II) sulfate. 15. Which of the following are redox reactions? For those that are, indicate which element is oxidized and which is reduced. For those that are not, indicate whether they are precipitation or acid-base reactions. a. Cu(OH)2(s) + 2HNO3(aq) Cu(NO3)2(aq) + 2H2O(l) b. Fe2O3(s) + 3CO(g) 2Fe(s) + 3CO2(g) c. Sr(NO3)2(aq) + H2SO4(aq) SrSO4(s) + 2HNO3(aq) d. 4Zn(s) + 10H+(aq) + 2NO3-(aq) 4Zn2+(aq) + N2O(g) + 5H2O(l) e.