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CLASS TEST - 1 (INORGANIC)
IIT-JEE
CHEMISTRY

P. JOY

Dear student following is an Easy level [ ] test paper. A score of 25 marks in 10 minutes would be a satisfactory performance: Q.No. 1 to 12 (+3, 1). (M.M. 36) Single option correct Q.1 What is the formal charge on chlorine if the compound has this lewis structure?
O

Q.7

In which excited state iodine shows sp3d3 hybridisation state : (A) First (B) Second (D) None (C) Third.

Cl O

(A) 0 Q.2

(B) +3

(C) +5

(D) +7

Q.8

The pair having same steric number : (A) BF3, NF3 (C) BeF2, H2O (B) BF3, AlF3 (D) BCl3, PCl3

Which is the Lewis dot structure of carbon disulfide, CS2 ? In this molecule, the sulfur (S) atom has the same number of valence electrons as an oxygen atom. (A) S C S

Q.9

Keep the odd molecule out with respect to hybridisation of central atom : (A) SiH4 (C) BF4

(B) NCl3 (D) BCl3

(B) S C S

(C) S C S Q.3

(D) None of these

Q.10

The number of shared electrons in x molecules of CS2 is : (A) 2x (B) 4x (C) 6x (D) 8x.

Which of the following types of hybridisation leads to two dimensional arrangement of bonds around the atoms? (A) sp (C) sp3 (B) sp2 (D) None

Q.11

What type of orbital-orbital overlap occurs between O F bonds in OF2 ? (A) sp2 2p (C) sp 2p (B) sp3 2s (D) sp3 2p.

Q.4

In which of the following atoms the number of valency electrons is not three (A) Al (B) B (C) Sc (D) Ge

Q.12

It has been seen that in O 3, the central O atom is bonded to two other oxygen atoms as
1

Q.5

In which of the following central atom has no formal charge ? (A) N3 (B) O3 (C) NH3 (D) NO2

O O
2

O
3

Q.6

Which of the following element show the capacity to form hybrid orbitals by using s, p and d orbital: (A) B (B) N (C) C (D) S

Arrange oxygen atoms marked as 1, 2 and 3 in order of +1, 0, 1 formal charges respectively : (A) 1, 2, 3 (C) 2, 1, 3 (B) 1, 3, 2 (D) 3, 2, 1

&
CHEMISTRY IIT JEE (CLASS TEST - 1) (INORGANIC) ANSWER KEY
Name : .......................................................................................................... A 1. 2. 3. 4. B C D 5. 6. 7. 8. A B C D 9. 10. 11. 12.

&
M.M. 36
Roll No. : .................................. A B C D

CLASS TEST - 1 (INORGANIC)

Que. Ans. 1 B 2 B 3 B 4 D 5 C 6 D

IIT-JEE
CHEMISTRY

P. JOY
8 B 9 D 10 D 11 D 12 A

7 C

Sol.1 (B) Formal charge = Group No. (Lines + dots) Formal charge on Cl = 7 (4 + 0) = 7 4 = + 3 Sol.2 (B) O & S belogs to same group (VI - group) & have 6 valence electrons. In option (B) carbon & sulphur both complete their octet. So it is the correct Lewis dot structure of CS2. In other options, there is incomplete octet. Sol.3 (B) sp hybridisation has linear shape & one dimensional arrangement of bonds and sp2 hybridisation has trigonal planar shape with two dimensional arrangement of bonds and sp3 hybridization has tetrahedral shape with three dimensional arrangement of bonds around the atoms. Sol.4 (D) The outermost electronic configuration of Al is 3s2 3p1 (3e) The outermost electronic configuration of B is 2s2 2p1 (3e) The outermost electronic configuration of Sc is 3d1 4s2 (3e) The outermost electronic configuration of Ge is 4s2 4p2 (4e). Sol.5 (C) (A) N3 O3
.. .. :N = N = N:
-1 +1 -1

Sol.7 (C) I 5s2 5p5 5d0

sp d

3 3

Sol.8 (B) (A) BF3, NF3 Steric No. 3 Steric No. Sol.9 (D) (A) SiH4
sp
3

..

(B) BF3, AlF3 3 3 3 4

.. (D) BCl3, PCl3

4 4

.. (C) BeF 2, H3O:

(B) NCl3
sp
3

..

(C) BF4
sp
3

(D) BCl3
sp
2

Sol.10 (D)
.. .. :S : : C : : S:

In 1 molecule of CS2, the number of showed electrons is = 8. So in x molecule of CS2, the number of showed electrons is = 8x. Sol.11 (D) In OF2 molecule, O is sp3 hybridised. So half filled sp3 hybridised orbital of O overlap with half-filled 2p-orbital of F to form OF bond. Sol.12 (A) Formal charge on 1-oxygen atom is = 6 (3 + 2) = 6 5 = +1 Formal charge on 2-oxygen atom = 6 (2 + 4) = 6 6 = 0 Formal charge on 3-oxygen atom = 6 (1 + 6) = 6 7 = 1 So correct order is 1, 2, 3.

(B)

:O ..
0

.. +1 S .. O: ..
1

(C)

NH3

.. N0 H H H 0 0
0

(D)

NO2

.. N +1 O
0

Sol.6 (D) Boron, Nitrogen & Carbon doesn't have empty d-orbital in their valence shell, but sulphur has empty d-orbital in its valence shell which can be used in hybridisation to form hybrid orbitals.