##1.

The ratio of the rate constant of a reaction at any temperature T to the rate constant
T is equal to
(A) Energy of activation of the reaction
(B) Fraction of molecules in the activated state
(C) Average life of the reaction
(D) Pre-exponential factor in the Arrhenius equation


##2. The rate constant of a reaction: A B + C at 27C is 3.0 10
5
s
1
at 27C and at
this temperature 1.5 10
4
percent of the reactant molecules are able to cross-over the P.E.
barrier. The maximum rate constant of the reaction is
(A) 4.5 10
9
s
1
(B) 4.5 10
11
s
1

(C) 0.2 s
1
(D) 20 s
1

-
##3. For a first order reaction: A B, whose
concentration vs. time curve is as shown in the figure.
The rate constant is equal to
(A) 41.58 h
1
(B) 4.158 s

1

(C) 1.155 10
3
s
1
(D) 6.93
min
1


B
A
0 10 20 30
Time (min)
C
o
n
c
e
n
t
r
a
t
i
o
n

##4. Rate constant k varies with temperature by equation

( )
1
2000K
logK min 5
T

= . We can conclude
(A) pre-exponential factor A is 5 (B) E
o
is 2000 kcal
(C) pre-exponential factor A is 10
5
(D) E
o
is 9.212 kcal

##5. There is blue colour formation if
(A) Cu electrode is placed inside AgNO
3
solution
(B) Cu electrode is placed inside ZnSO
4
solution
(C) Cu electrode is placed inside dil HNO
3

(D) Cu electrode is placed inside dil H
2
SO
4


##6. The formation of rust on the surface of iron occurs through the reactions
(A) ( ) ( )
2
Fe s Fe aq 2e
+
+ at anode
(B) ( ) ( ) ( )
2 2
O g 4H aq 4e 2H O
+
+ + at cathode
(C) ( ) ( ) ( ) ( )
2
2 2 2 3
4Fe aq O g 4H O 2Fe O s 8H
+ +
+ + +
(D) ( ) ( )
2 3 2 2 3 2
Fe O s xH O Fe O .xH O +

##7. In which case
( )
cell cell
E E

is zero
(A) CuCu
2+
(0.001 M)Ag
+
(0.1 M)Ag
(B) Pt(H
2
)pH = 1Zn
2+
(0.01 M)Zn
(C) Pt(H
2
)pH = 1Zn
2+
(1 M)Zn
(D) Pt(H
2
)H
+
(0.01 M)Zn
2+
(0.01 M)Zn

##8. By passage of 1 F of electricity
(A) 1 mol of Cu is deposited (B) 0.5 mol of Mg is deposited
(C) 9 g of Al is deposited (D) 5.6 L of O
2
gas evolved at anode

##9. In the following electrochemical cell

2+
2
Zn Zn H Pt(H )
+
| |


cell cell
E E

= . This will be when

(A) [Zn
2+
] = [H
+
] = 1 M and pH
2
= 1 atm
(B) [Zn
2+
] = 0.01 M, [H
+
] = 0.1 M and pH
2
= 0.01 atm
(C) [Zn
2+
] = 1 M, [H
+
] = 0.1 M and pH
2
= 0.01 atm
(D) [Zn
2+
] = [H
+
] = 0.1 M and pH
2
= 0.1 atm