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=
2
mv
2
1
V
N
2
3
P
Molecular Interpretation of
Temperature
Temperature is proportional to the average
kinetic energy of the molecules
The total kinetic energy is proportional to the
absolute temperature
T k mv
B
2
3
2
1
2
=
Temperature is proportional to the average
kinetic energy of the molecules
The total kinetic energy is proportional to the
absolute temperature
T k mv
B
2
3
2
1
2
=
nRT KE
total
2
3
=
Internal Energy
In a monatomic gas, the KE is the only type of energy
the molecules can have
U is the internal energy of the gas
In a polyatomic gas, additional possibilities for
contributions to the internal energy are rotational
and vibrational energy in the molecules
nRT U
2
3
=
In a monatomic gas, the KE is the only type of energy
the molecules can have
U is the internal energy of the gas
In a polyatomic gas, additional possibilities for
contributions to the internal energy are rotational
and vibrational energy in the molecules
Speed of the Molecules
Expressed as the root-mean-square (rms) speed
At a given temperature, lighter molecules move
faster, on average, than heavier ones
Lighter molecules can more easily reach escape speed
from the earth
M
T R
m
T k
v
B
rms
3 3
= =
Expressed as the root-mean-square (rms) speed
At a given temperature, lighter molecules move
faster, on average, than heavier ones
Lighter molecules can more easily reach escape speed
from the earth
M
T R
m
T k
v
B
rms
3 3
= =
Energy in Thermal Processes
Internal Energy vs. Heat
Internal Energy, U, is the energy associated with the
microscopic components of the system
Includes kinetic and potential energy associated with the random
translational, rotational and vibrational motion of the atoms or
molecules
Also includes the intermolecular potential energy
Heat is energy transferred between a system and its
environment because of a temperature difference between
them
The systemQ is used to represent the amount of energy transferred
by heat between a system and its environment
Internal Energy, U, is the energy associated with the
microscopic components of the system
Includes kinetic and potential energy associated with the random
translational, rotational and vibrational motion of the atoms or
molecules
Also includes the intermolecular potential energy
Heat is energy transferred between a system and its
environment because of a temperature difference between
them
The systemQ is used to represent the amount of energy transferred
by heat between a system and its environment
Units of Heat
Calorie
An historical unit, before the connection between
thermodynamics and mechanics was recognized
A calorie is the amount of energy necessary to raise the
temperature of 1 g of water from 14.5C to 15.5C .
A Calorie (food calorie) is 1000 cal
Joule 1 cal = 4.186 J
This is called the Mechanical Equivalent of Heat
BTU (US Customary Unit)
BTU stands for British Thermal Unit
A BTU is the amount of energy necessary to raise the temperature
of 1 lb of water from 63F to 64F
Unit s Unit s
SI SI Joule ( J) Joule ( J)
CGS CGS Calorie ( cal) Calorie ( cal)
US Cust omary US Cust omary BTU ( bt u) BTU ( bt u)
Calorie
An historical unit, before the connection between
thermodynamics and mechanics was recognized
A calorie is the amount of energy necessary to raise the
temperature of 1 g of water from 14.5C to 15.5C .
A Calorie (food calorie) is 1000 cal
Joule 1 cal = 4.186 J
This is called the Mechanical Equivalent of Heat
BTU (US Customary Unit)
BTU stands for British Thermal Unit
A BTU is the amount of energy necessary to raise the temperature
of 1 lb of water from 63F to 64F
Specific Heat
Every substance requires a unique amount of energy
per unit mass to change the temperature of that
substance by 1C
directly proportional to mass (thus, per unit mass)
The specific heat, c, of a substance is a measure of this
amount
Every substance requires a unique amount of energy
per unit mass to change the temperature of that
substance by 1C
directly proportional to mass (thus, per unit mass)
The specific heat, c, of a substance is a measure of this
amount
T m
Q
c
A
=
Unit s Unit s
SI SI Joule/ kg Joule/ kg C ( J/ kg C ( J/ kg C) C)
CGS CGS Calorie/ g Calorie/ g C ( cal/ g C ( cal/ g C ) C )
Notes: Heat and Specific Heat
Q = m c T
T is always the final temperature minus the
initial temperature
When the temperature increases, T and Q
are considered to be positive and energy flows
into the system
When the temperature decreases, T and Q
are considered to be negative and energy flows
out of the system
Q = m c T
T is always the final temperature minus the
initial temperature
When the temperature increases, T and Q
are considered to be positive and energy flows
into the system
When the temperature decreases, T and Q
are considered to be negative and energy flows
out of the system
Example1: How much heat is needed to raise temperature of aluminum by 5C?
Given:
Mass: m=0.5 kg
Temp. T= 5
Specific heat:
c
Al
=900 J/kgC
Find:
Q=?
, ), ), ) Joules C C kg J kg
T mc Q
Al
2250 5 900 5 . 0 + = + =
A =
Heat is related to mass and temperature by
Given:
Mass: m=0.5 kg
Temp. T= 5
Specific heat:
c
Al
=900 J/kgC
Find:
Q=?
4186
700
2
=
=
What happens at night?
Question
What happens at night ?
1. same
2. opposit e
3. not hing
4. none of t he above
What happens at night ?
1. same
2. opposit e
3. not hing
4. none of t he above
How t o det ermine specific heat ?
Calorimeter
A technique for determining the specific heat
of a substance is called calorimetry
A calorimeter is a vessel that is a good
insulator that allows a thermal equilibrium to
be achieved between substances without any
energy loss to the environment
A technique for determining the specific heat
of a substance is called calorimetry
A calorimeter is a vessel that is a good
insulator that allows a thermal equilibrium to
be achieved between substances without any
energy loss to the environment
Calorimetry
Analysis performed using a calorimeter
Conservation of energy applies to the isolated system
The energy that leaves the warmer substance equals the
energy that enters the water
Q
cold
= -Q
hot
Negative sign keeps consistency in the sign convention of T
Analysis performed using a calorimeter
Conservation of energy applies to the isolated system
The energy that leaves the warmer substance equals the
energy that enters the water
Q
cold
= -Q
hot
Negative sign keeps consistency in the sign convention of T
Example2: A 0.010-kg piece of unknown metal heated to 100C and dropped into the
bucket containing 0.5 kg of water at 20C. Determine specific heat of
metal if the final temperature of the system is 50C
Given:
Mass: m
1
=0.010 kg
m
2
=0.5 kg
Specific heat (water):
c
W
=4186 J/kgC
Temperatures:
T
1
=100 C
T
2
=20 C
T
f
=50 C
Find:
Specific heat =?
Conservation of energy: heat lost by metal is the
same as heat acquired by water:
Solve this equation:
0 = +
metal water
Q Q
Given:
Mass: m
1
=0.010 kg
m
2
=0.5 kg
Specific heat (water):
c
W
=4186 J/kgC
Temperatures:
T
1
=100 C
T
2
=20 C
T
f
=50 C
Find:
Specific heat =?
, ) , ) , ), ), )
, ) 0 62790 5 . 0
20 50 4186 5 . 0 100 50 01 . 0
0
2 2 2
= + =
+ =
A + A = = +
J c
C C C kg J kg C C c kg
T c m T c m Q Q
metal
metal
O H O H O H metal metal metal metal water
C kg J c
metal
5
10 25 . 1 =
iron
Phase Transitions
ICE ICE WATER WATER STEAM STEAM
Add
heat
Add
heat
Add
heat
Add
heat
These are three states of matter (plasma is another one) These are three states of matter (plasma is another one)
Phase Changes
A phase change occurs when the physical
characteristics of the substance change
from one form to another
Common phases changes are
Solid to liquid melting
Liquid to gas boiling
Phases changes involve a change in the
internal energy, but no change in
temperature
A phase change occurs when the physical
characteristics of the substance change
from one form to another
Common phases changes are
Solid to liquid melting
Liquid to gas boiling
Phases changes involve a change in the
internal energy, but no change in
temperature
Latent Heat
During a phase change, the amount of heat is given as
Q = m L
L is the latent heat of the substance
Latent means hidden or concealed
Choose a positive sign if you are adding energy to the
system and a negative sign if energy is being removed
from the system
Latent heat of fusion is used for melting or freezing
Latent heat of vaporization is used for boiling or
condensing
During a phase change, the amount of heat is given as
Q = m L
L is the latent heat of the substance
Latent means hidden or concealed
Choose a positive sign if you are adding energy to the
system and a negative sign if energy is being removed
from the system
Latent heat of fusion is used for melting or freezing
Latent heat of vaporization is used for boiling or
condensing
Graph of Ice to Steam
Problem-solving hints:
Use consistent units
Transfers in energy are given as Q=mcT for processes
with no phase changes
Use Q = m L
f
or Q = m L
v
if there is a phase change
In Q
cold
= - Q
hot
be careful of sign, T = T
f
- T
i
Use consistent units
Transfers in energy are given as Q=mcT for processes
with no phase changes
Use Q = m L
f
or Q = m L
v
if there is a phase change
In Q
cold
= - Q
hot
be careful of sign, T = T
f
- T
i
Methods of Heat Transfer
Need to know the rate at which energy is
transferred
Need to know the mechanisms responsible for
the transfer
Methods include
Conduction
Convection
Radiation
Need to know the rate at which energy is
transferred
Need to know the mechanisms responsible for
the transfer
Methods include
Conduction
Convection
Radiation
1. Conduction
The transfer can be viewed on an atomic scale
It is an exchange of energy between microscopic
particles by collisions
Less energetic particles gain energy during
collisions with more energetic particles
Rate of conduction depends upon the
characteristics of the substance
The transfer can be viewed on an atomic scale
It is an exchange of energy between microscopic
particles by collisions
Less energetic particles gain energy during
collisions with more energetic particles
Rate of conduction depends upon the
characteristics of the substance
Conduction example
The molecules vibrate about
their equilibrium positions
Particles near the flame
vibrate with larger
amplitudes
These collide with adjacent
molecules and transfer some
energy
Eventually, the energy travels
entirely through the rod
The molecules vibrate about
their equilibrium positions
Particles near the flame
vibrate with larger
amplitudes
These collide with adjacent
molecules and transfer some
energy
Eventually, the energy travels
entirely through the rod
Conduct ion can occur only if t here is a difference Conduct ion can occur only if t here is a difference
in t emperat ure bet ween t wo part s of t he in t emperat ure bet ween t wo part s of t he
conduct ing medium conduct ing medium
Conduction
The slab allows energy to
transfer from the region
of higher temperature to
the region of lower
temperature
The slab allows energy to
transfer from the region
of higher temperature to
the region of lower
temperature
L
T T
kA
t
Q
P
c h
= =
Heat flow
Thermal conductivity
Conduction
A is the cross-sectional area
L = x is the thickness of the slab or the
length of a rod
P is in Watts when Q is in Joules and t is in
seconds
k is the thermal conductivity of the material
Good conductors have high k values and good
insulators have low k values
A is the cross-sectional area
L = x is the thickness of the slab or the
length of a rod
P is in Watts when Q is in Joules and t is in
seconds
k is the thermal conductivity of the material
Good conductors have high k values and good
insulators have low k values
Home Insulation
Substances are rated by their R values
R = L / k
More multiple layers, the total R value is the
sum of the R values of each layer
Wind increases the energy loss by conduction
in a home
Substances are rated by their R values
R = L / k
More multiple layers, the total R value is the
sum of the R values of each layer
Wind increases the energy loss by conduction
in a home
2. Convection
Energy transferred by the movement of a
substance
When the movement results from differences in
density, it is called natural conduction
When the movement is forced by a fan or a pump,
it is called forced convection
Energy transferred by the movement of a
substance
When the movement results from differences in
density, it is called natural conduction
When the movement is forced by a fan or a pump,
it is called forced convection
Convection example
Air directly above the
flame is warmed and
expands
The density of the air
decreases, and it rises
The mass of air warms
the hand as it moves by
Applications:
Radiators
Cooling automobile
engines
Air directly above the
flame is warmed and
expands
The density of the air
decreases, and it rises
The mass of air warms
the hand as it moves by
Applications:
Radiators
Cooling automobile
engines
3. Radiation
Radiation does not require physical contact
All objects radiate energy continuously in the
form of electromagnetic waves due to thermal
vibrations of the molecules
Rate of radiation is given by Stefans Law
Radiation does not require physical contact
All objects radiate energy continuously in the
form of electromagnetic waves due to thermal
vibrations of the molecules
Rate of radiation is given by Stefans Law
Radiation example
The electromagnetic waves carry the energy from
the fire to the hands
No physical contact is necessary
Radiation equation
P = AeT
4
P is the rate of energy transfer, in Watts
= 5.6696 x 10
-8
W/m
2
K
4
A is the surface area of the object
e is a constant called the emissivity
e varies from 0 to 1
T is the temperature in Kelvins
P = AeT
4
P is the rate of energy transfer, in Watts
= 5.6696 x 10
-8
W/m
2
K
4
A is the surface area of the object
e is a constant called the emissivity
e varies from 0 to 1
T is the temperature in Kelvins
Energy Absorption and Emission by
Radiation
With its surroundings, the rate at which the
object at temperature T with surroundings at
T
o
radiates is
P
net
= Ae(T
4
T
4
o
)
When an object is in equilibrium with its
surroundings, it radiates and absorbs at the same
rate
Its temperature will not change
With its surroundings, the rate at which the
object at temperature T with surroundings at
T
o
radiates is
P
net
= Ae(T
4
T
4
o
)
When an object is in equilibrium with its
surroundings, it radiates and absorbs at the same
rate
Its temperature will not change
Example: Determine solar energy over the area of 1 m
2
. Temperature of Suns surface is
6000 K and temperature of surroundings is 300 K.
Given:
Area: A= 1 m
2
Temperatures:
T
1
=6000 K
T
2
=300 K
Find:
Power =?
Use Stefans law:
, )
4
0
4
T T A Power =
Given:
Area: A= 1 m
2
Temperatures:
T
1
=6000 K
T
2
=300 K
Find:
Power =?
, )
, ), ), ), )
s J
K m
K K A Power
7
4 15 2 8
4 4
10 3 . 7
10 3 . 1 1 1 10 67 . 5
300 6000
=
=
=
Temperature of Suns surface Temperature on the Earth
Ideal Absorbers and Reflectors
An ideal absorber is defined as an object that
absorbs all of the energy incident on it
e = 1
This type of object is called a black body
An ideal absorber is also an ideal radiator of energy
An ideal reflector absorbs none of the energy
incident on it
e = 0
An ideal absorber is defined as an object that
absorbs all of the energy incident on it
e = 1
This type of object is called a black body
An ideal absorber is also an ideal radiator of energy
An ideal reflector absorbs none of the energy
incident on it
e = 0
Applications of Radiation
Clothing
Black fabric acts as a good absorber
White fabric is a better reflector
Thermography
The amount of energy radiated by an object can be
measured with a thermograph
Body temperature
Radiation thermometer measures the intensity of the
infrared radiation from the eardrum
Clothing
Black fabric acts as a good absorber
White fabric is a better reflector
Thermography
The amount of energy radiated by an object can be
measured with a thermograph
Body temperature
Radiation thermometer measures the intensity of the
infrared radiation from the eardrum
Question
The use of fiberglass insulat ion in t he out er walls of a building
is int ended t o minimize heat t ransfer t hrough what process?
a. conduct ion
b. radiat ion
c. convect ion
d. vaporizat ion
The use of fiberglass insulat ion in t he out er walls of a building
is int ended t o minimize heat t ransfer t hrough what process?
a. conduct ion
b. radiat ion
c. convect ion
d. vaporizat ion
Resisting Energy Transfer
Dewar flask/thermos bottle
Designed to minimize energy
transfer to surroundings
Space between walls is evacuated
to minimize conduction and
convection
Silvered surface minimizes radiation
Neck size is reduced
Dewar flask/thermos bottle
Designed to minimize energy
transfer to surroundings
Space between walls is evacuated
to minimize conduction and
convection
Silvered surface minimizes radiation
Neck size is reduced
Global Warming
Greenhouse example
Visible light is absorbed and re-emitted as infrared
radiation
Convection currents are inhibited by the glass
Earths atmosphere is also a good transmitter
of visible light and a good absorber of infrared
radiation
Greenhouse example
Visible light is absorbed and re-emitted as infrared
radiation
Convection currents are inhibited by the glass
Earths atmosphere is also a good transmitter
of visible light and a good absorber of infrared
radiation