M1.

(b)

(a)

This part was not marked

1

electrolysis
1

because calcium is more reactive (than aluminium or carbon) accept it is more reactive or very reactive
1

OR in a blast furnace
1

because calcium is less reactive (than carbon or lower)

1

(c)

any equation from 1 mark for correct formulae 1 mark for balancing 2ZnO + C 2Zn + CO2 ZnO + CO Zn + CO2 ZnO + C Zn + CO
1

[5]

M2.

(a)

ammonium nitrate accept NH4NO3 do not accept ammonia nitrate

1

(b)

different reactions need different catalysts

1

(c)

they are used over and over again accept they are reused accept they are not used up accept they are not changed recycling is neutral
1

Page 1 of 7

(d)

any two from they speed up reactions they reduce energy requirements accept allow reactions to take place at a lower temperature they reduce costs accept make process more economic
2

(e)

(high pressure) increases the frequency of collisions accept more collisions move faster is neutral
1

this increases the rate of reaction accept more successful collisions for 2 marks
1

[7]

M3.

(a)

plot correct (2 segments) for 1 mark

1

(b)

nitrogen + hydrogen or N2 H2

ammonia NH3
1

all correct for 1 mark

(c)

largest area labelled nitrogen or shaded for 1 mark

1

(d)

(i)

nitrogen
1

oxygen hydrogen
1

three correct for 2 marks two correct for 1 mark (ii) potassium chloride for 1 mark
1

(e)

(i)

NH4NO3 = 14 + (4 1) + 14 + (3 16) = 80 for one mark

1

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(ii)

ecf (error carried forward from part (i)) look for 28 / 80 for first mark gains 1 mark but 35% (% sign not needed) special case of (14 / 80 100 = 17.5%) gains 1 mark gains 2 marks
2

[9]

M4.

(a) heat

gives out

each for 1 mark

2

(b)

chromium and aluminium oxide

1

(c)

(i) (ii)

chromium oxide
1

oxygen removed/gains electrons

1

[5]

M5.

(i)

160 ignore units

1

(ii)

112 ignore units

1

(iii)

70 do not carry forward errors

1

[3]

M6.

(a)

breakdown / decomposition / splits into elements / not ions

1

separates into elements / produce a chemical reaction using electricity

1

Page 3 of 7

(b)

lead bromide melted / free ions not electrolyte

1

(c)

(+) bromine element must be appropriate to electrode

1

() lead element must be appropriate to electrode

1

(d)

fume cupboard / protective clothing allow safety glasses not safety mat
1

[6]

M7.

(i)

Mg + (H2SO4)
1

MgSO4 +
1

H2 deduct 1 mark if not balanced only if all three correct accept alternative metal of similar reactivity for example Zn or Fe candidate would not then be awarded first mark for Mg then error carried forward deduct 1 mark if not balanced only if all three correct
1

(ii)

to remove the (excess) magnesium accept separate accept insoluble substances or solids or residue do not accept unreactive substances or impurities or remove magnesium from sulphuric acid
1

(iii)

to evaporate (some of the water or solution)

1

to form crystals or crystallise accept to form a saturated solution or concentrated solution do not accept to leave MgSO4
1

[6]

Page 4 of 7

M8.

(a)

(i)

bulb lights up
1

bubbles / fizz / gas or chlorine given off

1

(ii)

in solid, ions
1

are not free to move / (charged) particles cannot move or converse atoms / electrons cannot move worth 0 marks
1

(b)

(i)

breakdown / decomposition / splitting up not separation

1

by using electricity
1

(ii)

gas A = chlorine / oxygen

1

deposit B = copper
1

(c)

any one from: manufacturer of chlorine / sodium hydroxide / hydrogen / sodium electroplating of steel / reference to plating not galvanising extraction of aluminium / metal reactivity series specified purification of copper not making copper
1

[9]

M9.

(a)

(i) calcium carbonate calcium oxide + carbon dioxide

accept CaO3CaO+CO2
1

(ii)

(thermal) decomposition accept endothermic accept reversible

1

(b)

(i)

neutralisation accept exothermic

1

Page 5 of 7

(ii)

sulphuric (acid) H2SO4

2

(c)

(i)

to speed up the reaction accept to increase the rate of reaction or to increase the number or rate of collisions do not accept dissolves copper oxide faster
1

(ii)

all acid reacts accept there will be no acid left or acid used up
1

acid is neutralised (for 2 marks) do not accept to form a concentrated or saturated solution
1

(excess) copper oxide collects in filter paper accept larger particles (of copper oxide) cannot pass through filter paper
1

copper sulphate solution passes through the filter paper accept dissolved copper sulphate passes through filter paper or smaller particles (of copper sulphate) in solution (liquid) pass through filter paper accept (black) solid collects in filter paper and filtrate or soluble solid or (blue) solution (liquid) passes through filter paper for 1 mark only
1

[10]

M10.

use of solvent / solution / water / any named solvent

1

separates / carries colour(s) / dye(s) allow any idea of movement eg runs / moves
1

match against Rf value / known chromatogram / similar pattern or comparison to permitted additive / colour removal of coloured additive from salmon does not gain any marks ignore reasons for separation maximum 2 if technique clearly doesnt work
1

[3]

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Page 7 of 7