1.

The maximum number of electrons which can be accommodated in all the orbitals with principal quantum number 3 and azimuthally quantum number2, is a. 2 b. 8 c. 10 d. 18 2. The statement, All the four quantum numbers for two electrons in an atom can not be the same is known by which of the following? a. Heisenberg uncertainty principle b. Pauli, s exclusion principle c. Hand, s rule d. Aufbau, s principle 3. An atom has 2 electrons in K shell, 8 electrons in L shell and 6 electrons in M shell. The number of s- electrons present in that element is a. 6 b. 5 c. 7 d. 10 4. Principal, azimuthally and magnetic quantum numbers are respectively related to a. Size, orientation and shape b. Size, shape and orientation c. Shape, size and orientation d. Shape, size and spin of electron 5. After filling of 3d orbitals, the new electron will enter in a. 4s b. 4p c. 4d d. None of these 6. Which of the following set of quantum numbers is impossible? a. n = 3, l = 2, m = -2, s = c. n = 5, l = 4, m = 2, s = b. n = 4 ,l = 3, m = 3, s = d. n = 3, l = 3, m = - 3, s =

7. How many unpaired electrons are there in Ni2+ (Z = 28) a. 0 b. 2 c. 4 d. 8 8. Which of the following ions does not have the configuration of Ne? a. Clb. Fc. Na+ d. Mg2+ 9. For which one of the following set of quantum number an electron will have the highest energy a. 3, 2, 1, b. 4, 2, - 1, c. 4, 1, 0 ,-1/2 d. 5, 0, 0 ,1/2 2 2 10. The electronic configuration of an element is 1s 2s 2p23s23p6 3d54s. this represent its a. excited state b. ground state c. cationic from d. anionic from 11. Which of the following will be octahedral? a. SF6 b. BF4c. PSI5 12. Shape of H3O+ is a. Tetrahedral c. Pyramidal 13. Carbon in carbon dioxide molecule is : d. BO33-

b. Angular d. Trigonal planar

a. sp hybridized c. sp3 hybridized 14. The compound 1, 2-butadiene has : a. Only sp hybridized carbon atoms c. Both sp2 and sp3 hybridized carbon atoms d. sp, sp2 and sp3 hybridized carbon atoms 15. In piper dine NH the hybrid state assumed by N is a. sp c. sp3 16. The calculated bond order in H2- ion is a. o c.
2 2 6 1

b. sp2 hybridized d. dsp2 hybridized b. Only sp2 hybridized carbon atoms

b. sp2 d. dsp2 b. d. 1

17. The electronic configuration of metal M is 1s 2s 2p 3s . The formula of its oxide will be a. MO b. M2O c. M2O2 d. MO2 18. Of the following, the substance which has the highest boiling point a. H2S b. H2Se c. H2 Te d. H2O 19. Number of bonds in naphthalene is a. 6 b. 3 c. 4 d. 5 20. The bond order of O2- is a. 1 b. 1.5 c. 2.5 d. 3 21. Which of the following has Intermolecular H-bonding ? a. o-nitro phenol b. p- nitro phenol c. phenol d. Benzene 22. The number of electron that are paired according to MO theory in oxygen molecule is a. 16 b. 12 c. 7 d. 14 + 22+ 23. Consider the iso- electronic series: K , S , CI and Ca . The radii of the ions decrease as: a. Ca2+> K+ > CI- > S2b. CI- > S2- > K+ > Ca2+ c. S2- > CI- > K+ > Ca2+ d. none of these 24. Which of the following is most metallic? a. P b. A s c. Sb c. Bi 25. The energy 349kJ mol-1 evolved in the following chemical reaction CI (g) + e-CI- (g) + 349kJ is called a. Ionization energy b. Electron affinity c. Electro negativity d. Bond energy 26. Diagonal relationship in periodic table is shown by the elements of :

27.

28.

29.

30.

a. First with second period c. Third with fourth period The largest size out of Na+ , Ne, F- is a. Na+ c. FWhich of the following is best oxidizing agent? a. F2 c. O2 Beryllium shows diagonal relationship with : a. Mg c. Li Which of the following is most soluble in water? a. Be(OH)2 c. Ca(OH)2 is a. * + * +

b. Second with third period d. None of these b. Ne All are equal b. CI2 d. Br2 b. AI d. Si b. Mg(OH)2 d. Ba(OH)2 b. [-1, 1] d. *

31. The domain of the function f (x) =

c. none of these 32. The domain of the function f (x) = -1 (

) + [log (3 x )]-1 is

a. [ - 6, 3)\{2} b. [- 6, 2) (2, 3] b. [- 6, 3] d. [-6, 3) 33. The period of the function f (x) = |sin 4x|+ |cos4x|is a. /2 b. /8 c. /4 d. none of these 34. (sin x) is equal to a. 1 b. -1 c. 0 d. none of these 35. If f (x), g(x) be differentiable functions and f (1) = g(1) = 2 then
( ) ( ) ( ) ( ) ( ) ( ) ( ) ( )

is equal to b. 1 d. none of these ( ) b. a = -1, b = 1 d. a = 0, b = -1

a. 0 c. 2 36. The values of constant a and b so that a. a =1, b = - 1 c. a = 0, b = 0 37.

( )

a. exit and it equals c. none of these 38. a. 1

( )

b. exit and it equal - d. does not exist is equal to b. 1

c. 1/3 39. If f(x) = [x 2 ], then a. f(2.5) = and f(5) = 3 b. f(2.5) = 0 and f(5) = 3 40. If y = a. c. 0 41. If (x) = |cos x sin x | then f ( ) a. 1 c. 0 42. If f(x) = log( a. 0 c. 1 43. If 8f (x) + 6f ( ) = x +5 and y = x2 f(x), then a. 0 c. 44. Let f be a function defined for all x then the value of f(27) is a. 15 c. 0 45. If the slope of the curve y = a. 1 ,-2 c. 1 ,2 46. The tangent to the curve a. (1, 2)
( ) ) ( )

d. none of these c. f(2.5.) = 0 and f(5) does not exit d. none of these

b.

d. none of these b. 1 d. none of these m (1) = n (1) = 1 and m(1) n(1) = 2 then f(1) is equal to b. 1 d. none of these at x = - 1 is equal to b. 1/14 b. none of these . If f is differentiable and f (x3) = x5 for all x b. 45 d. none of these b. -1, 2 d. none of these is equally inclined to the axes at the point ( )

at the point (1 ,1) is 2, then the values of a and b are

b. (4, 4) c. (4, -4) d. (- 4, 4) 47. If the line ax + by + c is a tangent to the curve xy = 4, then a. a > 0, b > o b. a > 0, b < 0 c. a < 0 ,b > 0 d. a < 0, b < 0 2 48. The equation of the tangent to the parabola y = 16x inclined at an angle of 60 to x-axis, is a. 3x - c. d. none of these 2 49. The equation of the tangent to the parabola y = 16 perpendicular to the line 2x y + 5 = 0 is a. 2x y +2 = 0 b. 2x + y +2 = 0 c. x + 2y 16 = 0 d. x + 2y + 16 = 0 50. If (0, 4) and (0, 2) are respectively the vertex and focus of a parabola, then the equation is

a. x2 +8y = 32 b. y2 + 8x = 32 c. x2 8y = 32 d. y2 8x = 32 51. If the line 3x 4y + 5 = 0 is a tangent to the parabola y2 = 4ax, then a is equal to a. -5/4 b. -4/3 c. 5/4 d. 15/16 52. Locus of the center of a circle of radius 4 which touches the circle x2 + y2 4x + 2y = 0 externally is a. x2 + y2 4x + 2y 44 = 0 b. x2 + y2 + 4x + 2y 44 = 0 c. x2 + y2 4x 2y 44 = 0 d. none of these 53. The equation of the circle of radius 2 touching the circle x2 + y2 4 |x| = 0 is a. x2 + y2 + 2
2 2

x2 + y 2 +

=0

c. x + y - 4 =0 d. none of these 54. A variable circle passes through the point P(1, 2) and touches the x-axis. The locus of the other end of the diameter through P is a. (x 1)2 = 8y b. (x + 1)2 = 8y c. (y 1)2 = 8x d. none of these 55. The equation of the image of the lines y = |x| by the line x = 2 is a. y = |x 4| b. |y| = x + 4 c. |y|+ 4 = x d. none of these 56. The line (p + 2q) x + (p 3q) y = p q for different values of p and q passes through the fixed point a. ( c. ( ) ) b. ( d. ( ) )

57. On the portion of the straight line x + y = 2 which is intercepted between the axes, a square is constructed away from the origin, with this portion as one of its side. If p denotes the perpendicular distance of a side of this square from the origin, then the maximum value of p is a. 58. c. 3 d. none of these The image of the point (4, - 13 ) in the line 5x + y +6 = 0 is a. (1, 2) b. (-4, 13) c. (-1, -14) d. (3, 4) The new coordinates of a point (4, 5) when the origin is shifted to the point (1, -2) are a. (5, 3) b. (3, 5) c. (3, 7) d. none of these If the sum of distances of a point from two perpendicular lines in a plane is 1 then its locus is a. square b. circle c. straight line d. two intersecting lines If in the circle, power dissipation is 150W, then R is :

59.

60.

61.

62.

63.

64.

65.

66.

67.

68.

69.

70.

71.

72.

a.2 b. 6 c.5 d. 4 If a current is passed through a spring then the spring will: a. expand b. compress c. remain same d. none of these Electromagnetic waves are transverse in nature is evident by: a. polarization b. interference c. reflection d. diffraction By increasing the temperature, the specific resistance of a conductor and a semiconductor a. increases for both b. decreases for both c. increases, decreases respectively d. none of these If an ammeter is to be used in place of a voltmeter, then we must connect with the ammeter a a. low resistance in parallel b. high resistance in parallel c. high resistance in series d. none of these On moving a charge of 20 coulombs by 2 cm, 2 J of work is done, then the potential difference between the points is a. 0.1 V b. 8 V c. 2 V d. 0.5 V If an electron and a proton having same moment enter perpendicularly to a magnetic field, then a. curved path of electron and proton will be same b. they will move undefeated c. path of proton is more curved d. none of these A conducting square loop of side L and resistance R moves in its plane with a uniform velocity perpendicular to one of its sides. A magnetic induction B constant in time and space, pointing perpendicular and in to the loop exist everywhere with half the loop outside the field, as shown in figure. The induced emf is a. zero b. RvB c. vBL/R d. Vbl The time period of a charged particle undergoing a circular motion in a uniform magnetic field is independent of its a. speed b. mass c. charge d. none of these If a charge q is placed at the center of the line joining two equal charges Q such that the system is in equilibrium then the value of q is : a. Q/2 b. Q/2 c. Q/4 d. Q/4 Capacitance of a spherical conductor having radius 1 m, is a. 1.1 x 10-10 b. 10-6 c. 9 x 10-9 d. 10-3 A 3 volts battery with negligible internal resistance is connected in a circuit as shown in the figure. The current I, in the circuit will be

73.

74.

75.

76.

77.

78.

79.

80.

81.

a. 1 A b. 1.5A c. 2 A d. 1/3A A strip of copper and another of germanium are cooled from room temperature to 80 K. The resistance of a. each of these decreases b. copper strip decreases and that of germanium decreases c. copper strip decreases and that of germanium increases d. none of these The difference in the variation of resistance with temperature in a metal and a semiconductor arises essentially due to the difference in the a. crystal structure b. variation of the number of charge carriers with temperature c. type of bonding d. none of these An ammeter reads up to 1 ampere. Its internal resistances is 0.81 ohm. To increase the range to 10 A, the value of the required shunt is of the required shunt is: a. 0.003 b. 0.3 c. 0.9 d. 0.09 A 220 volt, 1000 watt bulb is connected across a 110 volts mains supply. The power consumed will be a. 750 w b. 500 w c. 250w d. 1000 w Alternating current can not be measured by D.C. ammeter because a. A.C. cannot pass through D.C. ammeter b. A.C. changes direction c. average value of current for complete cycle is zero d. none of these The total current supplied to the circuit by the battery is a. 1A b. 2A c. 4A d. 6A The resistance of the series combination of two resistance is S. when they are joined in parallel the total resistance is P. If S = nP, then the minimum possible value of n is a. 4 b. 3 c. 2 d. 1 In a meter bridge experiment, null point is obtained at 20 cm from one end of the wire when resistance X is balanced against another resistance Y. If X< Y, then where will be the new position of the null point from the same end, if one decides to balance a resistance of 4X against Y? a. 50 cm b. 80 cm c. 40 cm d. 70 cm In the circuit, the galvanometer G shows zero deflection. If the batteries A and B have negligible internal resistance, the value of the resistor R will be a. 200 b. 100

c. 500 d. 1000 82. Two sources of equal emf are connected to an external resistance R. Then internal resistances of the two sources are R1 and R2. If the potential difference across the source having internal resistance R2 is zero, then a. R= c. R =
( ( ) )

b. R= R2 R1 d. NONE OF THESE

83. A heater coil is cut into equal parts and only one part is now used in the heater. The heater generated will now be a. doubled b. four times c. one- fourth d. halved 84. A uniform electric field and a uniform magnetic field are acting along the same direction in a certain region. If an electron is projected along the direction of the fields with a certain velocity, then a. its velocity will decrease b. its velocity will increase c. it will turn towards right of direction of motion d. none of these 85. In a potentiometer experiment the balancing with a cell is at length 240 cm. on shunting the cell with a resistance of 2 the balancing length becomes 120 cm.The internal resistance of the cell is a. 1 b. 0.5 c. 4 d. 2 86. The resistance of hot tungsten filament is about 10times the cold resistance. What will be the resistance of 100 and 200 V lamp, when not in use? a. 40 b. 20 c. 400 d. 200 87. An electron dipole is placed at an angle of 30 to a non uniform electric field. The dipole will experience a. a torque only b. a translational force only in the direction on the field c. a torques well as a translational force d. none of these 88. The current I drawn from the 5 volt source will be

a. 0.33A c. 0.67A 89. The flux linked with a coil at any instant t is given by = 3s is

b. 0.5A d. 0.17A 10t2 50t + 250 the induced emf at t

a. -190 V b. -10 V c. 10 V d. 190 V 90. The resistance of a bulb filament is 100 at a temperature of 100 . If its temperature coefficient of resistances be 0.005 per its resistance will become 200 at a temperature of a. 300 b. 400 c. 500 d. 200