1. What is the pH of the solution that is formed when 1 ml of 0.1 M HNO3 solution plus water to 100 ml?

Answer: M1 V1 = V2. M2 1 ml x 0.1 M = 100 ml x M2 1 ml x 0.1 M M2 = 100 ml [HCl] = 0.001 M after dilution and [H +] after dilution = [HCl] = 0.001 M pH = - log [H +] pH = - log 0.001 = 3 2. H2SO4 solution of 500 mL when measured pH with a pH meter shows the number 3. What is the concentration of H2SO4 dissolved in mol dm-3 Answer: [H +] = 10-pH [H +] = 10-3 M and [H +] = 2 [H2SO4] 10-3 M = 2 [H2SO4] [H2SO4] = = 0.001 M

10 3 M = 5 x 10-4 M 2

3. What is the pH of 100 ml solution of formic acid (HCOOH) 0.1 M, if known price equilibrium constant acid = 1.6 x 10-4? Answer: [H +] = [H +] =

Ka.[HCOOH ]

1,6.10 4 x0,1 = 4. 10-3 M

= - Log 4. 10-3 = 2.398

pH = - log [H +]

4. Saturated lime water solution has a concentration of 0.005 mol dm-3. What is the pH of 100 ml aqueous solution of lime {Ca (OH) 2} it? Answer: [OH-] in water lime = 2 [Ca (OH) 2] = 2 x 5. 10-3 mol dm-3 = 10-2 mol dm-3 POH = - log [OH-] = - Log 10-2 = 2 pH = 14-2 = 12 5. 1 liter of solution of weak acid HA with a concentration of 0.1 M containing 0.001 M H + ions. What is the price of weak acid ionization constant of these?

Answer: [H +] 2 K= [HA] Ka =

(0,0001 )( 0,0001 ) = (0,0009 )

1x10 8 9 x10 4

= 1.11 x 10-5

6. Determine the concentration of H + ions in 100 ml of formic acid solution 0.1 mol dm-3. Known Ka = 1.7 x 10-4 Answer: [H +] = [H +] = [H +] =

Ka.[HCOOH ]

1,7.10 4 x10 1
17 x10 6 = 4.123 x 10-3 M.

Determine the concentration of OH-ions in a solution containing: 7. 0.005 M Ba (OH) 2 8. 0.1 M ammonia, if Kb NH3 = 1.8 x 10-5 Answer: 7. Ba (OH) 2 is a strong base and completely ionized in water. [OH-] = 2 [Ca (OH) 2] = 2 x 0.005 M = 0.01 M 8. Ammonia is a weak base, so that: [OH-] =

Kb.[NH 3 ]
5

= 1,8.10 x0,1 = 1.34 x 10-3 M 9. NH3 gas of 0.1 mol dissolved in 1 liter of water. Given Kb NH3 = 10-5, determine the pH of the solution is formed. Answer: moles of solute = 0.1 mol NH3 [NH3] = 0.1 moles per liter = 0.1 M [OH-] =

Kb.[NH 3 ]
5

10 x0,1 = -3 = 10 M POH = - log 10-3 = 3 pH = 14-3 = 11

50 ml HCl solution can be neutralized by 200 ml of 0,1 M NaOH Question: 10. Write the equation for the ion. 11. Determine the concentration of dissolved HCl. Answer: 10. The reaction can be written: NaOH (aq) + HCl (aq) NaCl (aq) + H2O (l) + Na + (aq) + OH (aq) + H (aq) + Cl (aq) Na + (aq) + Cl-(aq) + H2O (l) OH-(aq) + H + (aq) H2O (l)

11. Based on the reaction coefficient, it can be concluded that: mol HCl (aq) = mol NaOH (aq) V. M HCl = V. M NaOH 200 mL x 0.1 mol dm-3 M HCl = 50 ml 12. To neutralize 20 ml of sulfuric acid needed 20ml NaOH 0.2 M. What is the concentration of sulfuric acid? Discussion: Basa concentration [M2] = 0.2 M Volume of sour [V1] = 20 ml Volume bases [V2]= 20 ml Asked: Concentration of acid [M2] N1. V1 = N2.V2 M1.2.20 ml = 0.2 M. 20 ml. 1 M1 = 0.1 M 13. To create a buffer solution with pH = 4, how much volume of 0.05 M CH3COONa into 100 ml of 0.2 M CH3COOH solution [Ka = 10-5]? The number of H + The number of OH=2 =1 = 0.4 mol dm-3

14. Given: Concentration of NaOH = 0.2 M Volume NaOH Volume HCl = 40ml = 60ml Concentration of HCl = 0.05 M H2SO4 concentration = 0.1 M

Asked: volume of H2SO4 is used to neutralize the mixture? Answer:

15. Calculate pH

Answer:

Nurista Rizky Sagita XIA 2/15