Monochemisfry

8ordeoux & Pou

Z CMPS Iobs
9 Joinf CMPS/Universify Iobs
Sfoff: I3I^
IT: 37
European projects, Rex (FAME), ANR, Industry etc.
Z
9
^Universify: Zo Pr, 34 APr/ CMPS: 33 DP, Z8 CP
Mosfer: SpecioIi;ed courses
Inorgonic, orgonic, phofo,
supromoIecuIor, eIecfro-
chemisfry ,
SoIid sfofe
PoIymer, Theory,.
design/chorocferisofion/devices
Monofubes, Monofibers, efc.
Inorgonic ond Hybrid MoferioIs
CofoIysfs/Surfoce,
Monosfrucfurofion,
Towords oppIicofions:
bofferies, hydrogen ond energy sforoge,
informofion freofmenf, phofovoIfoics,
opfoeIecfronics, sensors/probes/DMA chips,
Pofenfs: I8
PubIicofions: I8Z
PhD Thesis: o9
Z00I
Z004
JACS, Z004, Angew. Chem. Z00, Chem. Commun. Z00, Longmuir Z00, EC MOE FAME
Dr. 8. Jousseoume, b.jousseoumeIcoo.u-bordeouxI.fr
NunocrystuIIine SnO
Z
thin fiIms prepured from seIf-ussembIed tin-bused hybrid muteriuIs
Sp
SeIf-ussembIed tin-bused bridged hybrid muteriuIs
H
Z
O
Under microemuIsion
condifions or nof
Sn Sn Sn O O O Sn
O Sn O Sn O Sn O
O O
Sn O
O
O
Sn Sn Sn
O
O O O Sn
O Sn O
Sn O Sn
Sn O
O Sn
Sn O
O Sn
O O O
Sp
Sp
Sp
Sp
Orgunizution tuned by the nuture of the spucer
|Me-CC-|
3
Sn-Sp-Sn|-CC-Me|
3
SELF-ASSEMLED TIN-ASED HYRID MATERIALS
FUNCTIONAL NANOHYRIDS FOR PHOTOVOLTAIC APPLICATIONS
Dye-modified nonoporous
SnO
Z
eIecfrodes
PhotoeIectrochemicuI ceII
Sp -(CH
Z
)
3
- Sp -(C
o
H
4
)-
( )
n
,
Sp C
4
H
9
,
Cl X
CoIIoidoI suspension
SnO
Z
nonoporficIes
docfor-bIode
~ 4b0"C
MonocrysfoIIine nonoporous
cossiferife SnO
Z
fiIms
N
O
O
Br
W-Bu
W-Bu
Sp SnX
3
N
O
O
W-Bu
W-Bu
1.9 m
SEM
AFM
OrgonomefoIIics Z003, Chem. Mofer. Z00, Adv. Mofer. Z00, EC MOE FAME
Prof. T. Touponce, f.fouponceIcoo.u-bordeouxI.fr
PhofochemicoI Monosciences
Use of Iighf fo confroI ond direcf nonosfrucfures
SeIf-ossembIed componenfs for moIecuIor eIecfronics
PhotovoItuic
devices
o-FET
S
O
N N
O
O O
H H
N
N
N N
N N
N
N
N N
N
H H
H
H
H
H
H H
H
H
H
H
S
O
N N
O
O O
H H
N
N
N N
N N
N
N
N N
N
H H
H
H
H
H
H H
H
H
H
H
S
O
N N
O
O O
H H
N
N
N N
N N
N
N
N N
N
H H
H
H
H
H
H H
H
H
H
H
S
O
N N
O
O O
H H
N
N
N N
N N
N
N
N N
N
H H
H
H
H
H
H H
H
H
H
H
S
O
N N
O
O O
H H
N
N
N N
N N
N
N
N N
N
H H
H
H
H
H
H H
H
H
H
H
S
O
N N
O
O O
H H
N
N
N N
N N
N
N
N N
N
H H
H
H
H
H
H H
H
H
H
H
N N
O O
O
H H
N N
O O
O
H H
N N
O O
O
H H
N N
O O
O
H H
N N
O O
O
H H
Mono-ordered orgonic moferioI inside mesoporous orchifecfures
PICASSO projecf (Pr. F. Pomero, Universifod Cordobo)
SeIf-ossembIy of semi-conducfor nonoporficIes
D. 8ossoni, CMPS 8ordeoux Universify
Angew. Chem., Inf. Ed. Z00, 44, Z ond 40I0
NANO-OJECTS & SPECTROSCOPY
Orgunic seIf-ussembIed Nuno-fibers :
- OpficoI Informofion & Energy Tronsfer
- Semi-conducfing moferioIs
Dynumic FIuorescence Micro-Spectroscopy:
- 40 ps fime-resoIufion (FLIM)
- mono- & bi-phofonic excif.
A. DeI 0uer;o, J.-P. Desvergne ef oI.
J. Am. Chem. Soc. Z00, I7984.
O
O
O
O
E,T, E,T,
F. Logugne-Loborfhef ef oI., J. Am. Chem. Soc. Z00, I7I4o.
Rumun Micro-Spectroscopy :
Pushing fhe Iimifs (MSOM).
- Inorgonic Mono-wires
Polarized Raman
at the nanoscale
GaN nanowire
(=170 nm)
- PoIymer mesosfrucfures
3.5 m
Corbon Monofubes
MuIfifuncfionoI Fibers
Toughesf fiber ever mode
VigoIo ef oI., Science Z00b
8odoire ef oI., Adv, Mut, Z004
Penicoud ef oI., JACS Z00b
Edifor's Choice, Science Z004
PercoIofion ond phose
behovior of MTs dispersions
MiId DissoIufion
(sponfoneous) of MTs
Mioudef ef oI. NunoIetters Z00b
Lu Recherche Z004
IOANALYTICAL NANOSYSTEMS
HighIy ordered porous eIectrodes
modified wifh supromoIecuIor orchifecfures
for fhe defecfion of medicoI reIevonf moIecuIes
Glas
Porous
gold electrode
DefoiI of pore sfrucfure
Mediator
NAD
+
Enzyme
monolayers
Analyte
Pt
Au
Mediator
NAD
+
Enzyme
monolayers
Analyte
Pt
Au
Mediator
NAD
+
Enzyme
monolayers
Analyte
Pt
Au
A.Iuhn ef oI
Angew.Chem.Inf.Ed.
Z00 I3I7
EIuborution of urruys of opto-
eIectrochemicuI nunoprobes for imoging
of bioIogicoI sysfems
CCD camera
Electrochemi-
luminesence
Optical
Iiber bundle
Electrical
connection
Array of nanoprobes
?
ECL
(610nm)
2 m
M.Sojic ef oI Mono Leffers Z004 I9ob
8uiIding composifes
ouf of individuoIIy coofed
ferroeIecfric porficIes fhrough
supercrificoI fIuid processing
or soff chemisfry roufes
The dieIecfric
Iosses hove been
reduced
Aymonier ef oI. J. Monosc. Monofech., Z00 b, 980
Core-sheII uTiO
3
AI
Z
0
3
nunopurticIes
E. Duguef ef oI., J. Mofer. Chem., Z004, I4, ZIoI, J. Mogn. Mogn. Mofer., Z00, Z93, IZ7, 8revef fronois FPZ8bb3Ib
dugueficmcb-bordeoux.cnrs.fr
plateforme
VUSPIO
2
2
2
2
magnetic
core
residual aldehyde
group for further
derivatization
covalent
bonding
dextran
50 nm
Nouveuu ugents de contruste pour I'IRM
Versatile UltraSmall Super
Paramagnetic Iron Oxide
nonoporficuIes d'oxyde de fer (moghemife Fe
Z
O
3
-)
Z00 nm
SiO
Z
PS
o) b)
c)
d) e)
MonoporficuIes Jonus (foiIIe: b0 Ib0 nm) propriefes originoIes si Ies foncfions sur chocun de Ieur
hemisphre onf des corocfres opposes : hydrophiIe/hydrophobe, cofionique/onionique, chimiquemenf
onfogonisfes...
nunopurticuIe
Junus
SiO
Z
PS
EIuborution de nunopurticuIes Junus
E. Duguef ef oI. J. Mofer. Chem., Z00, Ib, 374b, 8revef fronois FPZ8oZZ3o
Efienne Duguef (ICMC8) dugueficmcb-bordeoux.cnrs.fr Serge Povoine (CPPP) rovoinecrpp-bordeoux.cnrs.fr
SfimuIi-responsive miceIIes
ond vesicIes (T, pH, ions,)
Lecommondoux ef oI. Angew. Chemie Inf.
Ed. Z00Z, 4I, I339, Longmuir Z00, ZI,
4308, JACS Z00, IZ7, Z0Zo.
Design ond synfhesis of
poIypepfide-bosed bIock
copoIymers
MocromoIecuIes Z000, 33, 78I9
MocromoIecuIes Z001, 34, 9I00
Chem. Commun. Z00, I993-I99b
Mognefic hybrid vesicIes
Lecommondoux ef oI. Advonced MoferioIs, Z00, I7,
7IZ , J. Mog. Mog. Mof. Z00o, 300
MTPP
M Mn
III
OH
PoIystyrene Dendrigrufts with HydrophiIic SheII:
EncupsuIution und Trunsport in Wuter
of Orguno-metuIIic CompIees
M. Schoppocher, A.Deffieux ef oI. J. Am. Chem. Soc., Z00
O O
S
n
VesicIes of poIy(3,4-
efhyIenedioxyfhiophene)
H CromoiI, E. CIoufef MocromoI. Popid Commun, Z00, osop
NANO-OJECTS us functionuI devices
NANOPARTICLES & IOTECHNOLOSY
FuncfionoI
group :
chemicoI
onchoring
POMP in dispersed medium
using mocromonomer os sfobiIi;er
Drug
Corriers of
sensifive drugs
Corriers of
no sensifive drugs
Smorf biomoferioIs :
pH- sensifive
PEO
Drug
8ifuncfionoI porficIes
8revef CMPS/IMSEPM/EMSCP8 : WOZ00o00838o
8revef CMPS/IMSEPM/
EMSCP8 WOZ00o008387
Herogue; ef oI.,
J. PoIym. Sci., Z00
Herogue; ef oI.,
MocromoIecuIes, Z004
PoIymer NANO-OJECTS for functionnuI devices
Comb-PoIymers:
- ConfroI of:
orchifecfure , sfrucfuroI poromefers
ond chemicoI composifion
M, Schoppocher, A. Deffieux ef oI.
MocromoIecuIes Z001
Hyperbrunched PoIymers: Dendrigroffs
100nm
100nm
Lineurs
Sturs
CycIes
Combs on Comb
Shorfs Longs
I00nm
37C
MTPP
M Mn
III
OH
Hydrophobic PoIysfyrene Dendrigroffs:
PoIysfyrene Dendrigroffs wifh HydrophiIic SheII:
EncopsuIofion ondTronsporf in Wofer
of Orgono-mefoIIic CompIexes
M, Schoppocher, A. Deffieux ef oI.
J. Am. Chem. Soc. Z00
-High Compocify, confroI of surfoce funcfions
ond specific ossembIoge properfies