The Gas Technology Institute (GTI), Sampling and Analysis of Water Streams Associated with the Development of Marcellus Shale Gas, Final report, prepared for: Marcellus Shale Coalition (Formerly the Marcellus Shale Committee), December 31, 2009.

Sampling and Analysis of Water Streams
Associated with the Development of Marcellus

Shale Gas
Final Report
Prepared for
Marcellus Shale Coalition
(Formerly the Marcellus Shale Committee)
Prepared By
Thomas Hayes, Principal Investigator
Gas Technology Institute
1700 S. Mount Prospect Road
Des Plaines, IL 60018
December 31, 2009
List of Acronyms and Abbreviations
Acronym
Definition
Acronym
Definition
ASWCMC Appalachian Shale Water

Conservation and
Management Coalition
MSC
Marcellus Shale Coalition
BBL/bbl
Barrel (42 gallons)
PADEP
Pennsylvania Department of
Environmental Protection
BCF
Billion Cubic Feet
ug/L
Micrograms per liter (ppb)
BTEX
Benzene, Toluene,
Ethylbenzene, Xylenes
QAPP
Quality Assurance Project Plan
Flowback
Water
The water stream that

flows from a well in the
weeks following hydraulic
fracturing completion
TCF
Trillion Cubic Feet
Frac
Hydraulic Fracture
TDS
Total Dissolved Solids
Frac Job
Well completion event

involving hydraulic
fracturing
TPH
Total Petroleum Hydrocarbons
FSAP
Field Sampling and

Analysis Plan
PCB
Polychlorinated Biphenyl
Compound
mg/l
Milligrams per liter (ppm)
POTW
Publicly Owned Treatment

Works (a Sewage Treatment
Facility)
WVDEP West Virginia Department of

Environmental Protection
Table of Contents
List of Acronyms and Abbreviations .............................................................................. 2
Executive Summary ...................................................................................................... 6
1.0
Introduction ........................................................................ 9
2.0
Methods and Procedures ................................................. 10
3.0
Results and Discussion .................................................... 19
3.1
Flowback Water Collection Characteristics ...................... 22
4.0
Implications for Fate and Transport.................................. 37
5.0
Conclusions...................................................................... 40
6.0
References Cited.............................................................. 42
Appendix ..................................................................................................................... 45
Appendix A Field Sampling and Analysis Plan (FSAP) ........................................ 45
Appendix B Quality Assurance Project Plan (QAPP)............................................ 45
Appendix C Tabulated Data Obtained from Locations A - S................................. 45
Appendix D Summary of Detected VOC, SVOC, Pesticides and PCBs ............... 45
List of Figures
Figure 1. Sampling Locations in Pennsylvania
Figure 2. Sampling Locations in West Virginia.
Figure 3. Salt Concentration and Flowback Water Flow Versus Time from Location B
List of Tables
Table 1.
Measurements and Determinations
Table 2.
Summary of Methods
Table 3.
Water Use and Flowback Water Collection Associated with Hydraulic

Fracturing Completion of Shale Gas Wells
Table 4.
Concentration of Total Dissolved Solids in Flowback Water at 19

Locations, mg/L
Table 5.
Summary of Chemical Characteristics of Influent Water(1) Used for

Hydraulic Fracturing after Additives(2) Were Blended
Table 6.
Summary of Chemical Characteristics of Water Supplies(1) used for

Hydraulic Fracturing before Additives were Blended
Table 7.
Summary of Chemical Characteristics of Flowback Water Sampled 5

Days Following the Hydraulic Fracturing Event(1)
Table 8.
Summary of Chemical Characteristics of Flowback Water Sampled at 14

Days Following the Hydraulic Fracturing Event (1)
Table 9.
Total Metals Concentrations in the Influent Water and 5-day Flowback

Water Obtained from 19 Locations
Table 10.
Comparisons of Metals Levels in Shale Gas Waters with Municipal

Biosolids (Sewage Sludge)
Executive Summary
At current estimates of recoverable natural gas of more than 489 tcf, the Marcellus
Shale is considered to be among the largest natural gas reserves in the world. The
development of this resource is technology driven, involving the use of hydraulic
fracturing technology as one of the necessary initial steps to releasing natural gas from
shale rock. Sustainable development of shale gas in the Marcellus Play requires the
management of volumes of water in a manner that is protective of human health and
the environment. Typically, 1 - 4 million gallons of an aqueous influent stream bearing
very low concentrations of additives are introduced downhole during each well
completion. These additives may include friction reducers, corrosion inhibitors,
oxygen scavengers, scale inhibitors and biocides that can be blended into the water
and sand mixture, but make up less than 0.5 percent of the total frac fluid that is
injected into a drilled well at high pressures to achieve and maintain the fracture of the
shale rock. Following fracturing, flowback water is collected from the well and placed
into frac tanks and/or flowback impoundments.
Effective management of flowback water requires some level of knowledge of the
characteristics of the water. Flowback water contains salts, metals and organic
compounds from the formation and the compounds that were introduced as additives
to the influent stream. Discussions between the industry and regulatory agencies of
Pennsylvania and West Virginia have pointed to the need for an information base on
the composition and properties of flowback water and on the influent water streams
that are used to perform frac jobs. The objective of this effort was to conduct the initial
sampling and analysis of water streams associated with shale gas development in the
Marcellus Shale.
In recognition of the importance of this effort, 17 member companies of the Marcellus
Shale Coalition (MSC) volunteered 19 locations where shale gas wells were scheduled
to be hydraulically fractured. The Field Sampling and Analysis Plan and the Quality
Assurance Project Plan were developed, reviewed, and finalized for the effort by the
6
companies of the Appalachian Shale Water Conservation and Management

Committee (ASWCMC), Pennsylvania Department of Environmental Protection
(PADEP) and West Virginia Department of Environmental Protection (WVDEP). At
each of the host sites, samples of influent water streams at Day 0 and the flowback
water streams at 1, 5, 14, and 90 days following the frac job event were collected by a
single engineering subcontractor, URS. All samples were sent to Test America (a
PADEP and WVDEP certified environmental testing laboratory) for analyses. The list
of constituents recommended for the characterization study was developed from
comments received from the PADEP, the WVDEP and members of the ASWCMC.
Categories of determinations that were conducted included: 1) General Chemistry, 2)
Organic Compounds, and 3) Metals. Once reviewed and qualified, data from these
analyses were organized and tabulated in a source blind manner into an Excel
spreadsheet that currently represents the information base.
Results from this effort indicates that values for pH, alkalinity, total dissolved solids
(TDS), total organic carbon (TOC), oils and greases and other parameters from
general water characterization are within the normal ranges reported for conventional
produced waters by the USGS. Flowback water concentrations of TDS ranged from
680 to 345,000 mg/l; typical profiles show an increase in TDS in flowback water with
time following a frac job event. As with conventional produced water, shale gas
flowback water cations are dominated by sodium and calcium; the main anion is
chloride. Metals normally seen in conventional produced waters, such as iron,
calcium, magnesium, and boron, are at levels in flowback waters that are well within
known ranges for normal produced waters. Heavy metals that are of concern in urban
industrial wastewaters and POTW sludges --- such as chromium, copper, nickel, zinc,
cadmium, lead, arsenic and mercury --- are at very low levels. Among volatile organic
constituents (VOCs), approximately 96% of the constituent determinations were at
non-detectable levels and less than 0.5% were detected above 1 ppm. VOCs that are
measurable are those that are normally found in conventional produced waters.
Regarding semi-volatile organic constituents (SVOCs), more than 98% of the
determinations were at non-detectable levels and less than 0.03% of all the
constituents were above 1 ppm; and several constituents were at low trace levels
7
usually below 10 ppb.
Pesticide concentrations measured in the samples were
extremely low (all results were less than 1 ug/L) and extremely random with results
occurring in some supply water, Day 0, Day 14 and Day 90 samples. It is possible that
these low level concentrations are not representative of actual conditions and may be
attributed to laboratory contamination or instrument noise.
In conclusion, the results of this shale gas water characterization effort indicate that all
pesticides, PCBs, and a large fraction of the VOC and SVOC should be considered to
be unnecessary for the sampling and analysis of flowback waters in the future.
1.0 Introduction
The Marcellus Shale formation is the largest known shale deposit in the world. It
overlies much of the Appalachian Basin from West Virginia in the south, to Upstate
New York in the north, and Ohio to the west. The recoverable reserves of natural gas
in the Marcellus shale have been estimated at more than 489 trillion cubic feet
(Engelder, 2008).
Recent advances in horizontal drilling and multi-stage hydraulic fracturing technologies
have made sustainable natural gas production viable from otherwise uneconomical,
unconventional shale reservoirs such as the Barnett, Haynesville, Fayetteville,
Woodford, et al. These tools and technologies have been successfully applied and
currently enable the ongoing development of the Marcellus Shale. This development
is currently underway in both West Virginia and Pennsylvania with the majority of the
wells drilled and completed in southwest and northeast Pennsylvania.
Many of the logistical challenges associated with the development of shale gas stem
from the amounts of water associated with the completion and operation of shale gas
wells that must be transported, stored and disposed of in a manner that is protective of
human health and the environment. In the course of developing shale gas in the
Appalachian Basin, thousands of wells will be drilled and completed. Hydraulic
fracturing (fracing) is a necessary step for the completion of each of these wells in
order to achieve economic well performance in terms of natural gas production. This
step requires between 1 and 4 million gallons (23,800 and 95,200 bbl) of water for
successful completion of each well; vertical wells require approximately 1 million
gallons (23,800 bbl) and horizontal wells require 3-4 million gallons (71,400 to 95,200
bbl) (Gaudlip, et al., 2008).
During a typical frac job, water is pumped downhole while additives such as friction
reducers and various grades of sand are introduced to ensure a successful fracture
and completion of the shale. Following hydraulic fracturing, a fraction of the water
9
(approximately 25%) that was injected is collected over several days resulting in the
collection of a flowback water stream that contains salts, oils and greases, and
soluble organics (volatile and semi-volatile) that accumulated in the water downhole.
Flowback water also contains low concentrations of additives that are introduced
during the frac job which normally include friction reducing polymers, corrosion
inhibitors, scale inhibitors, and biocides. These additives facilitate the hydraulic
fracturing process and prevent problems with well operation.
The first steps in identifying effective water management alternatives include an
effective analysis of the characteristics of the water streams involved in shale gas
development. The overall objective of this project is to develop an information base on
the nature and composition of influent water and flowback waters associated with
completions of shale gas wells in the Marcellus Shale.
2.0 Methods and Procedures

17 member companies of the MSC volunteered 19 locations for the sampling of
influent and effluent water streams. At each location, a well completion was
conducted using hydraulic fracturing procedures that involved the injection of an
influent stream of water and the subsequent collection of flowback water. Standard
procedures were used to conduct sampling and analysis needed for the development
of water characterization data. All sampling was performed by the GTI subcontractor,
URS, following the same standard procedures. All sample analyses were performed
by a single laboratory, Test America of Pittsburgh, PA. Test America, an independent
analytical laboratory, provided the appropriate sample containers, preservatives and
completed the analytical analyses. Test America is certified in West Virginia and
Pennsylvania. Data tabulation, analysis and information base development was
provided by the Gas Technology Institute for this effort.
Details of the methods and procedures used for the collection and analysis of samples
obtained from each of the 19 locations are found in the Field Sampling and Analysis
Plan (FSAP) which is located in Appendix A. The Field Sampling and Analysis Plan
10
(FSAP) was developed to ensure that the data and information gathered for the
flowback characterization study was properly collected and documented.
A major aim of the characterization study was to generate technically sound data. To
meet this objective a Quality Assurance Project Plan (QAPP) was used to generate
accurate, precise, representative and complete data; this document is provided in
Appendix B. The QAPP provided the specific quality assurance/quality control
(QA/QC) procedures executed during the flowback Characterization Study.
Together the FSAP and QAPP comprise the Sampling and Analysis Plan (SAP). The
SAP was designed to meet the following informational goals:
Identify the specific constituents of interest (COI) associated with flow back
water;
Determine whether hydraulic fracturing additives are a source of COI in the

management of water associated with shale gas development; and,
Provide sufficient information for the selection of proper water management and
disposal techniques.
Prior to initiating the characterization study, the SAP was reviewed by regulatory
officials from the Pennsylvania Department of Environmental Protection (PADEP) and
the West Virginia Department of Environmental Protection (WVDEP).
The original SAP proposed that four (4) grab samples be taken from six (6) vertical or
horizontal well locations throughout West Virginia and Pennsylvania. The following
grab samples were proposed:
One baseline fracturing water sample that includes the fracturing additives,
excluding the sand;
Flowback water samples collected on days 1, 5 and 14 following the fracturing

process; and
11
Water from an existing producing well at 90 days following hydraulic fracturing.
The list of constituents recommended for the characterization study was developed
from comments received from the PADEP, the WVDEP and members of the
Appalachian Shale Water Conservation and Management Committee (ASWCMC).
Because the recommended list of constituents was extremely extensive, it was
decided that one sample from each site would be completed for the full list of
recommended constituents. All other samples were collected and analyzed for a
subset of these constituents, which was designed based on generator knowledge.
Following the first few rounds of sampling, industry identified a data gap with respect
to characterizing the supply water used for fracturing. Supply water is identified as the
water used for fracturing prior to introducing the fracing additives.
The updated protocol characterization study called for the collection of five (5) grab
samples from the each of the volunteered locations and expanded the sampling effort
to encompass 19 well locations volunteered by 17 member companies of the
Marcellus Shale Coalition. Table1 presents the list of all of the constituents of interest
(by category) that formed the basis for sample analysis. Analytical methods used to
perform the various determinations are listed in Table 2.
Under the updated sampling plan, the following grab samples were collected at each
of the volunteered locations:
A supply water sample (before the blending of additives);
One influent water sample following blending with fracturing additives, excluding
sand;
Flowback water samples collected on 1, 5 and 14 days after hydraulic

fracturing; and
Water from the producing well at 90 days after completion.
To address this data gap, it was decided to update the sampling/analysis protocol.
12
Following the collection of the samples and the performance of all of the
determinations, the data was organized, qualified and tabulated by GTI using an Excel
spreadsheet.
Table 1. Measurements and Determinations

General Chemistry
pH
Acidity
Total Alkalinity
Hardness as CaCO3
Total Suspended Solids
Turbidity
Chloride
Specific Conductance
Total Kjeldahl Nitrogen

Ammonia Nitrogen
Nitrate-Nitrite
Nitrite as N
Biochemical Oxygen
Demand
Chemical Oxygen
Demand
Total Organic Carbon
(TOC)
Dissolved Organic
Carbon
Oil & Grease (HEM)

Cyanide, Total
Amenable Cyanide
Bromide
Fluoride
Total Sulfide
Sulfate
Total Phosphorus
Total Recoverable
Phenolics
Volatile Organic Compounds

1, 4 - Dichlorobenzene
1, 3 Dichloropropane
2, 2 Dichloropropane
1, 1 Dichloropropene
p Isopropyltoluene
Naphthalene
n Propylbenzene
1, 2, 3 - Trichlorobenzene
1, 2, 4 - Trichlorobenzene
1, 2, 4 - Trimethylbenzene
1, 3, 5 - Trimethylbenzene
Benzyl chloride
Isopropylbenzene
2 Butanone
Methyl tert - butyl ether
(MTBE)
Xylenes (total)
2 - Chloroethyl vinyl ether
Cis - 1, 2 - Dichloroethene
Acetone
Acrolein
Acrylonitrile
Benzene
Bromodichloromethane
Bromoform
Bromomethane
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
Dibromochloromethane
1, 2 - Dibromo - 3
chloropropane
1, 2 - Dibromoethane (EDB)
Dibromomethane
Dichlorodifluoromethane
13
1, 4 Dioxane
Ethylbenzene
Ethylene Glycol
2 Hexanone
Methylene chloride
4 - Methyl - 2 - pentanone
(MIBK)
Styrene
1, 1, 1, 2
Tetrachloroethane
1, 1, 2, 2
Tetrachloroethane
Tetrachloroethene
Toluene
1, 1, 1 Trichloroethane
1, 1, 2 Trichloroethane
Trichloroethene
Trichlorofluoromethane
1, 2, 3 Trichloropropane
Vinyl acetate
Bromobenzene
n Butylbenzene
sec Butylbenzene
tert Butylbenzene
4 Chlorotoluene
1, 2 - Dichlorobenzene
1, 3 Dichlorobenzene
1, 1 Dichloroethane
1, 2 Dichloroethane
1, 1 Dichloroethene
trans - 1, 2 - Dichloroethene
1, 2 - Dichloropropane
cis - 1, 3 - Dichloropropene
trans-1, 3 - Dichloropropene
Vinyl chloride
Tert - butyl acetate
Tetrahydrofuran
1 - chloro - 4
trifluoromethylbenz
Semivolatile Organic Compounds

Diphenylamine
Benzidine
bis (2 - Chloroisopropyl)
ether
1, 4 Dioxane
1, 2 Diphenylhydrazine
Acenaphthene
Acenaphthylene
Acetophenone
2 Acetylaminofluorene
4 Aminobiphenyl
Aniline
Benzo (a) anthracene
Benzo (a) pyrene
Benzo (b) fluoranthene
Benzo (ghi) perylene
Benzo (k) fluoranthene
Benzyl alcohol
bis (2 - Chloroethoxy)
methane
bis (2 - Chloroethyl)
ether
bis (2 - Ethylhexyl)
phthalate
4 - Bromophenyl phenyl
ether
Butyl benzyl phthalate
4 Chloroaniline
4 - Chloro - 3
methylphenol
2 Chloronaphthalene
2 Chlorophenol
4 - Chlorophenyl phenyl
ether
Chrysene
Diallate
Diethyl phthalate
Dimethoate
pDimethylaminoazobenzene
7, 12 - Dimethylbenz (a)
anthracene
2, 4 Dimethylphenol
Dimethyl phthalate
Di - n - octyl phthalate
1, 3 Dinitrobenzene
4, 6 - Dinitro - 2
methylphenol
2, 4 Dinitrophenol
2, 4 Dinitrotoluene
2, 6 Dinitrotoluene
Dinoseb
Disulfoton
Ethyl methanesulfonate
Fluoranthene
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hexachlorocyclopentadiene
Hexachloroethane
Hexachloropropene
Indeno (1, 2, 3 - cd) pyrene
Isodrin
Isophorone
Isosafrole
3 - Methylcholanthrene
Methyl methanesulfonate
2 - Methylnaphthalene
2 Methylphenol
3 - Methylphenol & 4
Methylphenol
14
Nitrobenzene
2 Nitrophenol
4 Nitrophenol
N - Nitrosodi - n
butylamine
N Nitrosodiethylamine
N Nitrosodimethylamine
N - Nitrosodi - n
propylamine
N Nitrosodiphenylamine
N
Nitrosomethylethylamine
N Nitrosomorpholine
N Nitrosopiperidine
N Nitrosopyrrolidine
5 - Nitro - o Toluidine
Parathion
Pentachlorobenzene
Pentachloroethane
Pentachloronitrobenzene
Pentachlorophenol
Phenanthrene
Phenol
Phorate
2 Picoline
Pronamide
Pyrene
Pyridine
Safrole
1, 2, 4, 5
Tetrachlorobenzene
2, 3, 4, 6 Tetrachlorophenol
Thionazin
o Toluidine
1, 2, 4 Trichlorobenzene
Dibenz (a, h) anthracene

Dibenzofuran
Di - n butyl phthalate
3, 3' Dichlorobenzidine
2, 4 Dichlorophenol
2, 6 Dichlorophenol
Naphthalene
1, 4 - Naphthoquinone
1 Naphthylamine
2 Naphthylamine
2 Nitroaniline
3 Nitroaniline
4 Nitroaniline
2, 4, 5 Trichlorophenol
2, 4, 6 Trichlorophenol
O, O, O
Triethylphosphorothioate
Chlorobenzilate
Aramite
Chromium
Trivalent Chromium
Copper
Iron
Lead
Lithium
Magnesiium
Manganese
Molybdenum
Nickel
Potassium
Sodium
Selenium
Tin
Strontium
Titanium
Thallium
Zinc
Endosulfan I
Dieldrin
4, 4' DDE
Endrin
Endrin ketone
Endrin aldehyde
Endosulfan II
4, 4' DDD
Endosulfan sulfate
4, 4' DDT
Methoxychlor
Toxaphene
Metals
Aluminum
Antimony
Arsenic
Barium
Beryllium
Boron
Calcium
Cadmium
Cobalt
Pesticides
Chlordane (Technical)
alpha BHC
beta BHC
delta BHC
gamma - BHC (Lindane)
Heptachlor
Aldrin
Heptachlor epoxide
Organophosphorus Pesticides
Thionazin
Ethyl parathion
Tetraethyldithiopyrophosphate
Polychlorinated Biphenyls (PCBs)

15
Aroclor 1016
Aroclor 1221
Aroclor 1232
Aroclor 1242
Aroclor 1248
Aroclor 1254
Aroclor 1260
16
Table 2. Summary of Methods

Parameter
Analytical Method
Preparation Method
pH
SW846 9040
Acidity (Titrimetric)
SM20 2310 B (4a)
Alkalinity, Total
SM18 2320 B
SM18 2320 B
Amenable Cyanide
SM18 4500-CN E
SM18 4500-CN E
Biochemical Oxygen Demand
SM18 5210 B
SM18 5210 B
Bromide
MCAWW 300.1A
MCAWW 300.1A
Chemical Oxygen Demand
MCAWW 410.4
MCAWW 410.4
Chloride
MCAWW 300.1A
MCAWW 300.1A
Cyanide, Total
SW846 9012A
SW846 9012A
Dissolved Organic Carbon
SW846 7196A
SW846 7196A
Fluoride
MCAWW 300.1A
MCAWW 300.1A
Hexavalent Chromium
EPA 901.1 MOD
Hardness, Total
SM20 2340C
Mercury in Liquid Waste
SW846 7470A
SW846 7470A
N-Hexane Extractable Material
CFR136A 1664A H
EPA 1664A
Nitrate as N
MCAWW 300.1A
MCAWW 300.1A
Nitrite-Nitrate
MCAWW 353.2
MCAWW 353.2
Nitrite as N
MCAWW 300.1A
MCAWW 300.1A
Nitrogen, Ammonia
MCAWW 350.1
MCAWW 350.1
Organochlorine Pesticide
SW846 8081A
SW846 3510C
Organophosphorus Compounds
SW846 8141A
SW846 3510
Phenolics
SW846 9066
SW846 9066
Polychlorinated Biphenyls
SW846 8082
SW846 3510C
SW846 8270C
SW846 3520C
MCAWW 120.1
MCAWW 120.1
Sulfate
MCAWW 300.0A
MCAWW 300.0A
Sulfides, Total
SW846 9030B/903
SW846 9030B/903
17
SW846 9040
Table 2. Summary of Methods

Parameter
Analytical Method
Preparation Method
Total Phosphorus
MCAWW 365.2
SM18 2540 C
MCAWW 351.3
SM20 5310B
SM20 2540D
Trace Inductively Coupled

Plasma Metals
SW846 6010B
SW846 3005A
SW846 6010B
SW846 3010A
Trivalent Chromium
SW846 6010B
Wet None
Turbidity (Nephelometric)
MCAWW 180.1
MCAWW 180.1
Volatile Organics by GC/MS
SW846 8260B
SW846 5030B
Ethylene Glycol
SW846 8015
SW846 8015
Methylene Blue Activated

Substances (MBAS)
SM5540C
SM5540C
18
MCAWW 365.2
MCAWW 351.3
3.0 Results and Discussion

Throughout the performance of the flowback water sampling program, natural gas
development companies of the Marcellus Shale provided third party access to each of
the sampled well sites. This access was necessary to obtain the critical flowback
water samples at the standardized times of 0, 1, 5, and 14 days following the hydraulic
fracturing event. About a third of the companies assisted with the collection of a 90
day sampling of the flowback water, as well.
In total, 17 shale gas companies enabled the sampling of 19 locations within the
Marcellus Shale Region, including 3 locations in West Virginia and 16 locations in
Pennsylvania, as shown in the maps of Figures 1 and 2. The approximate positions of
all of the sampling locations (Locations A through S) are indicated on the maps.
Locations in West Virginia included 2 well completion sites in Lewis County and 1
completion site in Taylor County; both counties are in the northern half of the state, as
seen in Figure 2.
Host sites in Pennsylvania were well-distributed across the Commonwealth, involving
sampling in the Southwestern, Central, Northern and Northeastern regions of the state
representing the locations where most of the shale gas development is occurring. Half
of the sites sampled (a total of 8) were located in the Southwestern area of the state
as indicated on the map of Figure 1. Two sites were located in the Central portion and
two sites were located on the Northeastern side of the state. The remaining four
locations are positioned in the northern tier of Pennsylvania as shown in Figure 1.
19
Figure 1. Sampling Locations in Pennsylvania.
20
Host sites in West Virginia, on the other hand, were located in three counties of the
northern section of the state.
Figure 2. Sampling Locations in West Virginia.
Results from the analysis of all samples taken from Locations A through S have been
tabulated. Measurements and determinations included the following: 1) General
Chemistry; 2) Organic Compounds; and, 3) Metals. Tables of these results are
presented in Appendix C.
21
3.1
Flowback Water Collection Characteristics
As previously mentioned, the completion of each shale gas well examined in this
project required the introduction of a substantial volume of influent water (bearing
additives and sand) over a period of hours to achieve hydraulic fracturing. Following
successful fracturing, a water stream emerges from the well under pressure; this
stream is collected in frac tanks or in impoundments. The initial volume of water that
is collected shortly after well completion is called flowback water. Beyond the
completion period, water from the formation is co-produced with natural gas over time.
Water volumes associated with 14 of the 19 wells sampled in this project are shown in
Table 3. Of the 14 wells reporting water volume information, six wells were vertical
wells and eight wells were of horizontal configuration. Of the vertical wells, an average
of approximately 40,000 bbls of influent water were used to achieve fracturing, and
about 16,000 bbls on average were collected within a 90 day period. Of the horizontal
wells, an average of approximately 90,000 bbls of influent water were used to achieve
fracturing, followed by a collection of about 18,000 bbls of effluent water (flowback).
Cumulative volumes of water collected over time for these 14 completed wells are
tabulated in Table 3.
Salt concentrations in influent water and in flowback water generated over time from
the 19 sampling locations are tabulated in Table 4. As shown in Table 4, influent
water usually contains moderate to low concentrations of salts. Following the use of
this water for hydraulic fracturing, a flowback water stream that is collected from the
well exhibits increasing concentrations of salts with time. Evidently, the water
introduced down-hole picks up soluble inorganic constituents from the formation
(consisting mostly of sodium and calcium chloride); as this water resides down hole, it
picks up increasing concentrations of total dissolved solids.
22
Table 3. Water Use and Flowback Water Collection Associated with Hydraulic
Fracturing Completion of Shale Gas Wells
Location
Well Type
Total Vol.
Frac Fluid
Used,
bbls
Vertical
Cumulative Volume of Flowback Water, bbls
90 Days
Percent
Collected
1 Day*
5 Days
14 Days
40,046
3,950
10,456
15,023
Vertical
94,216
1,095
10,782
13,718
Horizontal
146,226
3,308
9,652
15,991
Horizontal
21,144
2,854
8,077
9,938
11,185
52.9
Horizontal
53,500
8,560
20,330
24,610
25,680
48.0
Horizontal
77,995
3,272
10,830
12,331
17,413
22.3
Horizontal
123,921
1,219
7,493
12,471
18,677
15.1
Vertical
36,035
3,988
16,369
21,282
31,735
88.0
Horizontal
70,774
5,751
8,016
9,473
13.4
Horizontal
99,195
16,419
17,935
19,723
19.9
Vertical
11,435
2,432
2,759
3,043
Horizontal
96,706
5,131
19,202
Vertical
23,593
1,315
3,577
5,090
Vertical
16,460
2,094
7,832
9,345
37.5
17,890
19.0
10.9
3,535
30.9
19.8
21.6
10,723
Weighted Average % Collected
65.1
24.3
* Days from the hydraulic fracturing event.
A typical profile of salt concentrations measured in flowback water with time is shown
in Figure 3. In this figure, data from Location B is plotted. As seen in this diagram,
early flowback water emerging soon after the frac job is relatively low in TDS content;
following the initial day, the concentration of total dissolved solids increases with time
from low salt concentrations to a plateau of elevated salt levels as measured at 14 and
90 days. Also shown in this diagram is the marked concomitant decrease in flowback
brine flow with time, exhibiting a high initial flow rate of over 2,400 bbls/day, then
decreasing to a minimal flow rate of less than 55 bbls/day after the initial few weeks
following completion, a 98% reduction of daily flow. It should be mentioned that the
lowest flow rate bar shown on the chart in Figure 3 was calculated from cumulative
water data between 14 and 90 days; actual flows in the 60 to 90 day period are
23
significantly less than 55 bbls/day. The diagram, however, demonstrates that although
the TDS levels in the flowback water emerging between 14 and 90 days almost
doubles to nearly reach 200,000 mg/l, the daily brine volumes produced by the well
decrease to a deminimus level that can be easily managed as a normal produced
water stream.
Table 4. Concentration of Total Dissolved Solids in Flowback Water at 19

Locations, mg/L
Location
Day 0*
Day 1
Day 5
Day 14
Day 90
990
15,400
54,800
105,000
216,000
27,800
22,400
87,800
112,000
194,000
719
24,700
61,900
110,000
267,000
1,410
9,020
40,700
5,910
28,900
55,100
124,000
462
61,200
116,000
157,000
1,920
74,600
125,000
169,000
7,080
19,200
150,000
206,000
265
122,000
238,000
261,000
4,840
5,090
48,700
19,100
804
18,600
39,400
3,010
221
20,400
72,700
109,000
371
735
31,800
116,000
2,670
17,400
125,000
186,000
401
11,600
78,600
63,900
311
16,600
38,500
120,000
481
15,100
46,900
20,900
280
680
58,300
124,000
155,000
228,000
* Day 0 sample was taken of the influent water plus additives without sand.
24
345,000
Figure 3. Salt Concentration and Flowback Water Flow Versus Time from
Location B
3.1.1 General Chemistry

A summary of the general chemical characteristics of the water influent streams and
the flowback water effluents associated with the completion and operation of wells of
the 19 sampling locations are presented in Tables 5-8. Characteristics of influent
water, identified as Day 0 samples, after the blending of additives (not including sand)
at each of the locations are shown in Table 5. The pH of these streams ranging from
5.2 to 8.9 is generally representative of surface waters; however, the wide range of
total dissolved solids (221 to 27,800 mg/l) reflects the implementation of water reuse
25
Table 5. Summary of Chemical Characteristics of Influent Water(1) Used for

Hydraulic Fracturing after Additives(2) Were Blended
Parameter
pH
Acidity
Total Alkalinity
Hardness as CaCO3
Turbidity
Chloride
Ammonia Nitrogen
Nitrate-Nitrite
Nitrite as N
Total Organic Carbon (TOC)
Oil & Grease (HEM)
Cyanide, Total
Amenable Cyanide
Bromide
Fluoride
Total Sulfide
Sulfate
Total Phosphorus
Total Recoverable Phenolics
Sulfite
Methylene Blue Active Substances
(MBAS)
Range
Median
Units
5.2 - 8.9
< 5 1,230
5 308
26 - 9,500
4 - 5,290
2.7 715
18 - 10,700
221 - 27,800(3)
177 34,600
2.3 400
0.28 441
0.1 3.1
< 0.05 - 5
< 2.0 2,220
35.3 47,400
5.6 - 1,260
7.2
NC
NC
No Units
mg/L
mg/L
mg/L
mg/L
NTU
mg/L
mg/L
Umhos/cm
mg/L
mg/L
1,730
226
mg/L
g/L
mg/L
mg/L
5 - 1,270
301
mg/L
4.6 255
3.5 954
< 0.01- 0.87
< 0.2 107
< 0.05 - 58.3
< 3 8.8
2.9 2,920
< 0.1 16
< 0.01 - 0.77
< 5 61.6
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
mg/L
ug/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
< 0.03 0.506
NC
mg/L
130
NC
249
90.2
735
726
33.5
5.9
NC
NC
NC
(1) Influent water samples are identified as Day 0; samples at 19 locations, Locations A S.
(2) Additives included corrosion inhibitors, scale inhibitors, friction reducers, biocides, and oxygen
scavengers. Blended water samples were taken before the addition of sand.
(3) Upper end concentrations in the TDS range may be due to implementation of flowback water reuse
and blending into the influent stream.
NC - indicates the median concentration was not calculated due to undetected results.
26
Table 6. Summary of Chemical Characteristics of Water Supplies(1) used for

Hydraulic Fracturing before Additives were Blended
Range
Median
Units
6.7 - 7.4
< 5 5.5
6.2 88.8
18 - 1,080
7.2
NC
52.5
132
No Units
mg/L
mg/L
mg/L

Turbidity
Chloride
Ammonia Nitrogen
Nitrate-Nitrite
Nitrite as N
<2 24
1.3 33.7
4.1 3,000
35 5,510(2)
55 10,100
< 3 56.4
0.017 20.8
< 0.1 3.0
< 0.05 4.9
< 2.0 110
< 10 924
1.8 202
1.4 222
NC
3.7
35.2
334
423
NC
0.41
NC
NC
NC
NC
3.4
3.2
mg/L
NTU
mg/L
mg/L
umhos/cm
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
Oil & Grease (HEM)

Cyanide, Total
Amenable Cyanide
Bromide
Fluoride
Not Detected
< 10 625
< 0.01 - 0.27
< 0.2 31.9
< 0.05 - 1.2
NC
NC
NC
NC
NC
mg/L
ug/L
mg/L
mg/L
mg/L
Total Sulfide
1.6 - 5.6
NC
mg/L
Sulfate
3.8 139
26
mg/L
< 0.1 0.14

0.01 - 0.031
NC
NC
mg/L
mg/L
6 21.6
10.8
mg/L
< 0.05 - 0.962
NC
mg/L
Parameter
pH
Acidity
Total Alkalinity
Hardness as CaCO3
Total Phosphorus
Sulfite
Methylene Blue Active
Substances (MBAS)
(1) Water Supplies at 8 Locations: F, H, I, J, L, M, N, S.

(2) Upper end concentrations in the TDS range may be due to implementation of flowback water reuse
and blending into the influent stream.
27
Table 7. Summary of Chemical Characteristics of Flowback Water Sampled 5

Days Following the Hydraulic Fracturing Event(1)
Parameter
Range
Median
Units
pH
5.8 - 7.2
6.6
No Units
Acidity
< 5 447
NC
mg/L
Total Alkalinity
48.8 327
138
mg/L
5,100 - 55,000
17,700
mg/L
10.8 - 3,220
99
mg/L
Turbidity
2.3 1540
80
NTU
Chloride
26,400 - 148,000
41,850
mg/L
38,500 238,000
67,300
mg/L
79,500 470,000
167,500
umhos/cm
38 204
86.1
mg/L
Ammonia Nitrogen
29.4 199
71.2
mg/L
Nitrate-Nitrite
< 0.1 1.2
NC
mg/L
Nitrite as N
Biochemical Oxygen
Demand
Oil & Grease (HEM)
Cyanide, Total
Amenable Cyanide
Bromide
Fluoride
Total Sulfide
1.2 29.3
NC
mg/L
37.1 - 1,950
195 - 17,700
3.7 388
30.7 501
4.6 655
< 10 - 72.1
< 0.01 - 0.032
185 - 1,190
< 0.05 17.3
< 3 5.6
144
4,870
62.8
114
6.3
NC
NC
445
NC
NC
mg/L
mg/L
mg/L
mg/L
mg/L
ug/L
mg/L
mg/L
mg/L
mg/L
2.4 106
NC
mg/L
< 0.01 2.5

< 0.01 0.31
2.5 38
NC
NC
NC
mg/L
mg/L
mg/L
<0.012 1.52
0.133
mg/L
Hardness as CaCO3
Sulfate
Total Phosphorus
Sulfite
Substances (MBAS)
(1) Median values at 19 locations: Locations A S.

NC indicates the median concentration was not calculated due to undetected results.
28
Table 8. Summary of Chemical Characteristics of Flowback Water Sampled at

14 Days Following the Hydraulic Fracturing Event (1)
Range
Median
Units
4.9 6.8
< 5 473
6.2
NC
No Units
mg/L
Total Alkalinity
Hardness as CaCO3
26.1 121
630 95,000
85.2
34,000
mg/L
mg/L

Turbidity
17 1,150
10.5 1,090
209
233
78,100
mg/L
NTU
Parameter
pH
Acidity
Chloride
1,670 181,000
3,010 261,000
6,800 710,000
5.6 261
Ammonia Nitrogen
Nitrate-Nitrite
Nitrite as N
Nitrate as N
Oil & Grease (HEM)
Cyanide, Total
Amenable Cyanide
Bromide
Fluoride
3.7 359
< 0.1 0.92
< 2.5 77.4
< 0.5 - < 5
2.8 2070
228 21,900
1.2 509
5 695
< 4.6 103
< 10
<0.01
15.8- 1,600
< 0.05 < 50
Total Sulfide
(2)
Sulfite
Sulfate
Total Phosphorus
Sulfite
Substances (MBAS) (2)
< 3.0 - 3.2

7.2 73.6
<10 - 89.3
< 0.1 2.2
120,000
256,000
116
124.5
NC
NC
NC
39.8
8530
38.7
43
NC
NC
NC
704
NC
NC
13.8
mg/L
mg/L
Umhos/cm
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
ug/L
mg/L
mg/L
mg/L
mg/L
Mg/l
mg/L
mg/L
< 0.01 0.31
NC
NC
NC
7.2 73.6
13.8
mg/L
<0.05 - 4.6
NC
mg/L
mg/L
(1) Samples were collected from 17 locations. Day 14 samples were not collected at locations D and N.
(2) Sulfite and MBAS were not sampled at locations B and C.
NC indicates the median concentration was not calculated due to undetected results.
29
(i.e. the use of a portion of the flowback water from the completion of one well to
blend with the freshwater influent stream for the next well completion) at a minority of
the locations. Dissolved solids measurements for the influent waters used for
hydraulic fracturing (with additives) had a median value of 735 mg/l, which is
considered in the range of fresh surface water supplies. Interestingly, oil and grease
measurements had a range of 4.6 to 255 mg/l while total organic carbon
concentrations ranged from 5.6 to 1,260 mg/l. Elevated values in these
measurements may be due to various degrees of blending of reused waters into frac
job influent water supplies.
A summary of the same characteristics is tabulated for water supplies from 8 locations
(F, H, I, J, L, M, N, S) in Table 6; information in this table provides an indication of the
quality of influent water before the blending of additives. The data in this table
indicates that the water supply samples varied widely in quality. Total dissolved solids
ranged from 35 to 5510 mg/l, with a median value of 334. Total organic carbon content
ranged from 1.8 to 202 mg/l while biochemical oxygen demand ranged between
undetected to 110 mg/l. These widely varying results reflect the fact that, in some
cases, water used for hydraulic fracturing a prior well was re-used for a subsequent
well, with the addition of previously unused water. Oils and greases were not detected
in any of these samples, and many characteristic parameters are representative of
typical surface water quality
Characteristics of flowback water sampled at 5 and 14 days following the hydraulic
fracturing event are presented in Tables 7 and 8, respectively. Consistent with the
profile of Figure 3, the median value of total dissolved solids for 14-day samples
(120,000 mg/l) was almost twice the median concentration value measured in the 5day samples (67,300 mg/l). However, the bulk of the water collected within the first 5
days had the lowest concentrations of TDS, also consistent with Figure 3. The water
is of relatively modest alkalinity, ranging between about 50 and 327 mg/l with a median
value of 138 mg/l, reflecting low carbonate concentrations which allow for very high
levels of soluble calcium which confers a very high hardness on the water as
evidenced by median hardness values of 17,700 and 34,000 mg/l for the 5-day and
30
14-day sample sets, respectively. Cations are dominated by sodium and calcium in
this water; anions are dominated by chloride. Levels of total organic carbon (TOC) in
the flowback water samples at 5 and 14 days (with median values of 63 and 39 mg/l,
respectively) are substantially lower (by about 75%) than the TOC of the blended
influent water with additives; a possible reason for this is that the polyacrylamide
friction reducers exert a TOC in the influent stream and are removed as water resides
in the down-hole environment. The same observation is made, though less
consistently, in comparing biochemical oxygen demand (BOD) values in flowback
water with the BOD of the influent water streams; in general, the BOD levels of the 14day flowback waters are less than half the influent and Day 5 BOD concentrations.
The widely varying BOD levels in the water supply and influent samples is, as stated
previously, probably reflective of flowback water re-use. The moderate levels of BOD
in the influent waters may have resulted from carbonaceous algae growth in the
source water or resulted from the biodegradable nature of the additives (e.g.
polyacrylamide friction reducing compounds). The loss of friction reducing compounds
due to adherence to surfaces downhole may be responsible for the lower BOD
concentrations in flowback waters.
General characteristics of the samples tested in this project appear very consistent
with the ranges of values reported in the literature for normal produced waters (USGS,
2004). The large database collected by the USGS indicates that salinities for
produced waters generated among all basins can vary widely from approximately
5,000 to greater than 350,000 mg/l of total dissolved solids. Chloride is the dominant
anion in nearly all formation waters associated with petroleum and with most
conventional natural gas (Kharaka and Rice, 2004). Sodium is the most dominant
cation in most producing fields and constitutes 70 to more than 90% of total cations
(USGS, 2004). General characterization data from the waters tested at the 19
locations of this project appear consistent with much of the available compositional
information available from the USGS database. The USGS database containing
produced water characterization data from more than 60,000 wells is accessible from
the Internet at: http://energy.cr.usgs.gov/prov/prodwat/intro.htm .
31
3.1.2 Organic Compounds

The organic compounds included in the characterization of water samples included the
categories of VOC, SVOC, chlorinated pesticides, organophosphorus pesticides, and
polychlorinated biphenyls. Most of the compounds in the first two categories and all
compounds in the last three categories were included on the list of analyses in
response to recommendations from PADEP and WVDEP. The following sections
summarize the results among all five of the categories of analysis.
As presented in Table 1, samples collected from Locations A through S were analyzed
for 70 volatile compounds of highly varied chemical characteristics, including the
volatile hydrocarbon constituents that are normally found in produced water (such as
benzene, toluene, ethylbenzene, and xylenes or BTEX, and naphthalene) as well as
constituents not known to be associated with conventional produced water such as
chlorinated solvents and halogenated aromatics. A summary of the detected results
for volatile compound determinations performed is shown in Appendix D. Many of the
constituent determinations, on average, were at non-detectable levels.
Appendix C
provides a summary of all of the VOC results.

Constituents that exceeded 100 ppb included components that are commonly present
in conventional produced water, such as naphthalene, BTEX, several methylated
benzene compounds and an alkylated toluene (p-isopropyltoluene). Few
determinations of these compounds exceeded 2 ppm. In the locations where BTEX
was measured at levels above 100 ppb, BTEX levels in the 5-day and 14-day flowback
waters that were in contact with the natural gas producing formation were generally
higher than BTEX concentrations in the influent water streams, indicating that these
compounds are naturally occurring and not the result of additives. Levels of BTEX
and methylated aromatics vary from location to location. Determination of factors that
control levels of these compounds could potentially be determined through a
correlation of the composition of volatiles and other flowback water characteristics with
the key shale gas development parameters of geographic area, depth of wells,
completion methods, etc.
32
Very few volatile organic compounds exceeded 2 ppm among the total of the
locations. Several locations exhibited one or more of the volatile compounds that
exceeded 1 ppm.
Two ketones were measured in a very limited number of samples;
acetone and 2-butanone (also known as methyl ethyl ketone or MEK), were found at
measurable concentrations. These compounds are well known solvents in industry
that are used for cleaning purposes. In a few samples, carbon disulfide was
measured. In the manufacture of some types of polymers, carbon disulfide is useful in
the promotion of nucleophilic attack in polymer synthesis; this compound may be a
residual reactant from the manufacture of polymers used as friction reducers.
However, carbon disulfide was only measured in a few samples examined at a limited
number of locations.
A total of 112 semi-volatile organic compounds (as listed in Table 1) were included in
the analysis of influent water and in flowback water samples. A summary of the
detected results of semivolatile determinations in these samples is presented in
Appendix D. More than 98% of the constituent determinations, on average, were at
non-detectable levels and less than 0.03 percent of all the constituents were above 1
ppm. Several constituents were measured in any of the samples at levels exceeding
10 ppb. Acetophenone and aniline are commonly associated with fossil fuels, as are
the methylated phenols. Only two compounds, bis (2-chloroethyl) ether and pyridine,
were measured at levels greater than 1 ppm. The only compound that was measured
at a level above 1 ppm more than once was pyridine. Pyridine is a nucleophile that is
used widely in the manufacture of certain types of chemicals and pharmaceuticals and
its presence may be due to its use as a precursor in the manufacture of one of the
hydraulic fracturing additives.
In general, nearly all of the SVOC determinations were either non-detect or at low
trace levels. Detected SVOC constituents are summarized in Appendix D. Appendix
C provides all the SVOC reported results.
33
Pesticides
Determinations of the 20 chlorinated and three organophosphorus pesticides listed in
Table 1 were conducted on the influent, 14-day and 90-day flowback water samples.
Results from the measurements of pesticides in all samples are summarized in
Appendix C. Pesticide concentrations measured in samples were extremely low (all
samples were less than 1 ug/l.) and random with results occurring in some of the water
supply, Day 0, Day 14 or Day 90 samples collected. It is possible that these low level
concentrations are not representative of actual conditions and are attributed to
laboratory contamination or instrument noise. Appendix C summarizes the pesticides
results. Appendix D provides a summary of the detected pesticide results.
Polychlorinated Biphenyls (PCBs)
Determinations of the 7 polychlorinated biphenyl compounds (Aroclors) listed in Table
1 were conducted on the influent, 14-day and 90-day flowback water streams.
Aroclors were not detected in any sample, except for Aroclor 1248 that was detected
at 8 ug/L in the Day 14 sample at Location R. The detected PCB result is summarized
in Appendix D. Appendix C summarizes the all of the PCB results.
3.1.4 Metals
A summary of metal concentrations in the influent water stream (with additives) and
the 5-Day Flowback water samples across all 19 locations is presented in Table 9; all
concentrations in this table are reported in units of g/l (ppb). As seen in this table,
sodium is the major cation in all of the samples, followed by concentrations in some
samples of calcium, magnesium and barium that will need to be monitored for
purposes of scale control in some locations. Since strontium is present in flowback
waters at concentrations between 345 to 4,830 mg/l in the 5-day flowback samples, it
will be important for operators to implement procedures to prevent the formation of
strontium-bearing scale. Iron levels in the range of 21 to 180 mg/l may also need to be
watched and mitigated in order to prevent operational difficulties at a number of well
completion locations.
Heavy metals of toxicological concern that are often associated with urban industrial
activity (including chromium, copper, nickel, zinc, lead, cadmium, mercury and arsenic)
34
are at very low levels in all of the shale gas water samples compared to levels
reported for municipal wastewaters. Table 10 presents range values from the 5-Day
Flowback samples which are compared to median heavy metals concentrations
measured in sewage sludges (biosolids) generated by Penn State for the State of
Pennsylvania (Stehouwer, 2000); note that concentrations in this table are reported in
mg/l. The comparison shows that the levels of heavy metals of concern are 100 to
10,000 times higher in municipal biosolids (sewage sludges that are routinely
transported across communities to disposal sites) than the levels measured in shale
gas waters.
35
Table 9. Total Metals Concentrations in the Influent Water and 5-day Flowback
Water Obtained from 19 Locations
Parameter
-- Influent Water -Range

Median
-- 5-Day Flowback -Range

Median
Units
Aluminum
ND 1,030 B
NC
ND - 47,200 J
NC
ug/L
Antimony
ND - 21.6 BJ
NC
ND - 47.2 B
NC
ug/L
Arsenic
ND - 9.1 B
NC
ND 124
NC
ug/L
Barium
63.1 BJ - 87,100
410
21,400 J - 13,900,000
686,000
ug/L
ND 3 B
NC
ND
NC
ug/L
ND - 40,700 J
NC
3,140 J - 97,900
12,200
ug/L
ND - 10.5
NC
ND - 9.6 B
NC
ug/L
6,690 BJ - 2,990,000
32,900
1,440,000 J - 23,500,000 J
4,950,000
ug/L
Beryllium
Boron
Cadmium
Calcium
Chromium
ND - 704
NC
ND - 152
NC
ug/L
Chromium
+3
ND 4.8 B
NC
ND 67.4
NC
ug/L
Chromium
+6
ND
ND
ND
NC
ug/L
Cobalt
ND - 11.9 B
NC
ND
NC
ug/L
Copper
ND 120 B
NC
ND - 4,150
NC
ug/L
Iron
137 B - 14,300
1,180
21,400 - 180,000
39,000
ug/L
Lead
ND - 111
NC
ND - 606
NC
ug/L
ND - 14,900 JE
NC
10,600 - 153,000
43,700
ug/L
Magnesium
1,250 B - 235,000
6,740
135,000 - 1,550,000
559,000
ug/L
Manganese
ND - 3,640
NC
881 - 7,040
2,630
ug/L
Mercury
ND - 0.66 BJ
NC
ND - 0.24 J
NC
ug/L
Molybdenum
ND - 91.8 B
NC
ND 147 B
33.1
ug/L
ND - 457
NC
ND 187 B
NC
ug/L
Potassium
2250 B - 229,000 E
42,600
48,900 B - 2,430,000
301,000
ug/L
Selenium
ND - 35.3 B
NC
ND
NC
ug/L
Sodium
25,700 B - 6,190,000
67,800
10,700,000 - 65,100,000
18,000,000
ug/L
Strontium
58.5 BJE - 439,000 E
768
345,000 4,830,000
1,080,000
ug/L
Thallium
ND -19.8 B
NC
ND 24.6 B
NC
ug/L
Tin
ND - 6.9 B
NC
ND - 25.7 B
NC
ug/L
Titanium
ND - 39.1 B
NC
ND 313 B
NC
ug/L
ND - 1,610 E
NC
67.6 BJ 2,930 J
172
ug/L
Lithium
Nickel
Zinc
* Influent Water is the supply water containing hydraulic fracturing additives, but without sand. Influent samples are
identified as Day 0 samples.
ND Not detected
NC Indicates the median concentration was not calculated due to undetected results.
B Analyte was also detected in the method blank for that sample
J Estimated concentration for analyte detected between the method detection level and the reporting limit
G Analyzed at a diluted concentration due to matrix effects
E The concentration exceeds the linear range of the instrument. The result is considered estimated.
36
Table 10. Comparisons of Metals Levels in Shale Gas Waters with Municipal
Biosolids (Sewage Sludge)
Metal
5-day Flowback
Range
Sewage Sludge*
Units
Chromium
ND 0.152
35
mg/L
Copper
ND 4.150
511
mg/L
Nickel
ND 0.187 B
22.6
mg/L
Zinc
0.068 2.93 J
705
mg/L
Lead
ND 0.606
65
mg/L
Cadmium
ND 0.096 B
2.3
mg/L
Mercury
ND 0.00024 J
1.5
mg/L
Arsenic
ND 0.124
3.6
mg/L
* Penn State study reporting median heavy metal content values for Pennsylvania publicly owned treatment works
(POTW) biosolids (Stehauwer, et al., 2000).
ND Not detected
4.0 Implications for Fate and Transport

As seen in Table 1, the list of measurements and determinations that were pursued in
this study were very exhaustive but highly useful in establishing an information base to
define a chemical fingerprint associated with flowback waters from this geologic
formation. Much of the expense and time required for water characterization has
arisen from the extensive effort to analyze the samples for large numbers of volatile
and semivolatile organic compounds suggested by PADEP and WVDEP (including
chlorinated pesticides, organophosphorus pesticides and polychlorinated biphenyls);
the information base developed in this project strongly suggests that this level of water
characterization in the future is not necessary and that monitoring should be focused
on measuring constituents that are likely to be present. A number of observations
that are relevant to fingerprinting and to the fate and transport of constituents can be
made from consideration of the information base assembled from the first 19 locations.
37
First, there is clear indication that halogenated hydrocarbon compounds (among

volatile, semivolatile, pesticides and PCB categories) and nearly all of the polynuclear
aromatic hydrocarbons (of 3 rings and above) are not a part of typical components in
flowback waters. Volatile and semivolatile organic constituents that are normally found
at low levels in conventional produced waters, such as BTEX, methylated benzenes,
naphthalene, naphthenic acids, volatile acids, simple alkanes, etc., are also found in
flowback waters and in influent waters for frac jobs that utilize flowback water reuse.
However, in terms of fate and transport in the environment, many volatile and
semivolatile organics present in shale gas waters are at modest concentrations (most
compounds are below 1 ppm). The challenge, therefore, is to choose an alternate
parameter that can be used to quickly detect any small release of flowback water that
may occur in the course of storage or handling.
A more practical approach might be to use chloride analyses of samples to monitor
fate and transport of flowback/produced waters. Chloride has been used as a
conservative tracer in hydrogeochemical studies for decades and is well documented
in the literature (Clement et al., 2000; Farrell et al., 1994; Lamontagne et al., 2005;
Negrel and Lachassagne, 2000; Nelson et al., 2001; Paine, 2003; van Breukelen et al.,
1998). A general overview of the processes controlling the movement of solutes in the
subsurface is provided below.
Fate and transport of constituents in the soil/rock/water system is governed by four
fundamental processes: advection, dispersion, retardation, and decay. Advection is
simply the mass movement of a solute along with groundwater and is modeled by
Darcys Law. Dispersion is a mathematical description of diffusion and mechanical
mixing of a solute in a system. Diffusion is modeled using Ficks first and second law.
Dispersion is an empirical correction factor controlled by the physical properties of the
soil/rock matrix (porosity, grain size, sorting, etc) and scale of the system. Retardation
is the process by which non conservative solutes interact with the soil/rock and their
movement downgradient is subsequently slowed. It is modeled by a linear equation
that is a function of porosity, moisture content, bulk density, and the humic organic
matter content. Examples of retardation reactions are adsorption-desorption, ion
38
exchange, precipitation-dissolution, and oxidation-reduction reactions. Decay is the

process by which a solute is removed from the system due to chemical reactions,
biological reactions, and/or radioactive decay and is modeled using the appropriate
equation for the reaction occurring in the system.
Conservative solutes are ones that can be modeled using only advection and
dispersion. Common examples are chloride and bromide, but bromide levels in the
samples collected as part of this study were several orders of magnitude lower than
chloride levels. Non-conservative solutes can only be modeled using advection,
dispersion, retardation, and/or decay. Examples of non-conservative solutes are
volatile/semivolatile organics (e.g. benzene, toluene, PAHs, PCBs, etc.), sulfate, iron,
and many others. Non-conservative species subsequently migrate slower throughout
the subsurface than do conservative tracers and therefore are inappropriate to use as
indicators of Marcellus Shale flowback water impact to a system. Nearly all classes of
volatile and semivolatile organics discussed in this report have been shown to be
sequestered to various types of soils, thereby significantly retarding their mobility in the
environment (Linz and Nakles, 1997).
Chloride, on the other hand, is more mobile and has considerable potential as an early
sentinel indicator of flowback water impacts due to a number of advantages. In
addition to being conservative (by virtue of its non-volatile, non-sequestering, nonreactive property), chloride is usually present in relatively high concentrations ranging
from 10,000 to 200,000 mg/l, ten to a hundred times the concentration of most
inorganics and more than a million times the levels of most volatile and semivolatile
organic constituents. Chloride is also easily measured with field kits that can
determine the presence of this anion with small samples, and verified in its presence
with simple conductivity instruments. Due to its high concentration and its ubiquitous
presence in flowback waters, chloride anion is an excellent monitoring tool for even the
smallest leaks of flowback water into the environment.
39
5.0 Conclusions
With the completion of this sampling and analysis effort, the following conclusions can
be drawn from the results:
1. General chemistry characterization of flowback water indicates that values for
pH, alkalinity, total dissolved solids, total organic carbon, oils and greases and
other parameters from general water characterization are well within the normal
ranges reported for conventional produced waters. Flowback water appears
similar in composition to conventional produced water, even in the presence of
additives employed for performing hydraulic fracturing.
2. Shale gas flowback water cations are dominated by sodium and calcium;
anions are dominated by chloride.
3. Metals in flowback water are well within the ranges for normal produced waters.
Industrial heavy metals (e.g. chromium, copper, nickel, zinc, lead, cadmium,
arsenic and mercury) are a small fraction (less than 1 percent) of the heavy
metals content in municipal biosolids generated from POTWs.
4. Among volatile organic constituents, approximately 96% of these constituents
were found at non-detectable levels and 0.5% were above 1 ppm for any of the
5 sampling events among 19 locations. The data indicate that the constituents
above 1 ppm are those that are a normal part of produced waters associated
with natural gas operations (such as xylenes, toluene and naphthalene).
5. Among SVOC, more than 98% of all determinations were at nondetectable
levels and 0.03% of these constituents were above 1 ppm.
6. Low levels (less than 1 ug/l) and the random distribution of chlorinated and
organophosphorus pesticides suggest that these compounds are laboratory
artifacts and are not contained in flowback water.
40
7. Only one PCB (Aroclor 1248) was detected in all the samples analyzed. This
result should be considered an anomaly.
8. Virtually, all halogenated organic compounds were at non-detect levels. This
strongly suggests that additives that are blended with influent waters do not
contain concentrations of organic chemicals of concern.
9. The results of this shale gas water characterization effort indicate that
pesticides, PCBs, and a large fraction of the volatile and semivolatile
constituents should be considered to be unnecessary for the sampling and
analysis of flowback waters in the future.
10. Determination of factors that affect levels of organic and inorganic compounds
could potentially be determined through a correlation of flowback water
composition with the key shale gas development parameters of geographic
area, depth of wells, completion methods, etc.
41
6.0 References Cited

APHA. 1992. Standard Methods for the Examination of Water and Wastewater, 18th
Edition (SM18).
APHA. 1999. Standard Methods for the Examination of Water and Wastewater, 20th
Edition (SM20).
Clark, C.E. and J.A. Veil. 2009. Produced Water Volumes and Management
Practices in the U.S. USDOE/Argonne Laboratories Report No. ANL/EVS/R-09/1.
Clement, T.P., Johnson, C.D., Sun, Y., Klecka, G.M., and Bartlett, C., 2000, Natural
attenuation of chlorinated ethene compounds; model development and field-scale
application at the Dover site: Journal of Contaminant Hydrology, v. 42, p. 113-140.
Engelder, T., and G.G. Lash. 2008. Marcellus Shale Plays Vast Resource Potential
Creating a Stir in Appalachia. The American Oil & Gas Reporter, May.
Farrell, D.A., Woodbury, A.D., and Sudicky, E.A., 1994, The 1978 Borden tracer
experiment; analysis of the spatial moments: Water Resources Research, v. 30, p.
3213-3223.
Gaudlip, A.W., L.O. Paugh, and T.D. Hayes. 2008. Marcellus Shale Water
Management Challenges in Pennsylvania. SPE Paper No. SPE119898-PP, Society
of Petroleum Engineers.
Kharaka, Y.K. and C.A. Rice. 2004. Organic and Inorganic Species in Produced
Water: Implications for Water Reuse, Proceedings of the Natural Gas Technologies
Conference, Phoenix, Feb 8-10. Available from the Gas Technology Institute,
Lamontagne, S., Leaney, F.W., and Herczeg, A.L., 2005, Groundwater-surface water
interactions in a large semi-arid floodplain; implications for salinity management:
Hydrological Processes, v. 19, p. 3063-3080.
Linz, D.G. and D.V. Nakles. 1997. Environmentally Acceptable Endpoints in Soil.
American Academy of Environmental Engineers, United Book Press, Inc., Baltimore,
MD.
Negrel, P., and Lachassagne, P., 2000, Geochemistry of the Maroni River (French
Guiana) during the low water stage; implications for water-rock interaction and
groundwater characteristics: Journal of Hydrology, v. 237, p. 212-233.
Nelson, M.D., Parker, B.L., Al, T.A., Cherry, J.A., and Loomer, D., 2001, Geochemical
reactions resulting from in situ oxidation of PCE-DNAPL by KMnO (sub 4) in a sandy
aquifer: Environmental Science & Technology, v. 35, p. 1266-1275.
Paine, J., 2003, Determining salinization extent, identifying salinity sources, and
estimating chloride mass using surface, borehole, and airborne electromagnetic
induction methods: Water Resources Research, v. 39, p. 10.
42
Stehouwer, R.C., A.M. Wolf, and W.T. Doty. 2000. Chemical Monitoring of Sewage
Sludge in Pennsylvania: Variability and Application Uncertainty. J. Environ. Qual. 29:
1686 1695.
USEPA. 1984. Methods for Organic Chemical Analysis of Municipal and Industrial
Wastewater, 40CFR, Part 136, Appendix A, October 26.
USEPA. 1983. Methods for Chemical Analysis of Water and Wastes, EPA-600/4-79020, March.
USEPA. 1986. Test Methods for Evaluating Solid Waste, Physical/Chemical
Methods, Third Edition, November (SW846).
USGS. 2009. USGS Produced Water Database. Available at:
http://energy.cr.usgs.gov/prov/prodwat/intro.htm .
van Breukelen, B.M., Appelo, C.A.J., and Olsthoorn, T.N., 1998, Hydrogeochemical
transport modelling of 24 years of Rhine water infiltration in the dunes of the
Amsterdam water supply: Journal of Hydrology, v. 209, p. 281-296.
43
Disclaimer
This report was prepared by the Gas Technology Institute (GTI) as an account of work
funded by the Marcellus Shale Coalition (MSC). Neither GTI nor any person acting on
behalf of GTI:
1. Makes any warranty or representation, express or implied with respect to the
accuracy, completeness, or usefulness of the information contained in this
report, or that the use of any information or method disclosed in this report may
not infringe privately-owned rights, or
2. Assumes any liability with respect to the use of, or for any and all damages,
resulting from the use of, any information or method in this report.
44
Appendix

45
Appendix A
Field Sampling and Analysis Plan (FSAP)
FIELD SAMPLING AND ANALYSIS PLAN

DEVONIAN SHALE FLOW BACK WATER
CHARACTERIZATION STUDY
Prepared by
Appalachian Shale Water Conservation and Management Committee
December 2008
TABLE OF CONTENTS
1.0
INTRODUCTION ................................................................................................... 3
1.1
PURPOSE ............................................................................................................ 3
1.2
DATA OBJECTIVES .......................................................................................... 3
1.3
BACKGROUND.................................................................................................. 3
2.0
CHARACTERIZATION STUDY OF FLOW BACK WATER ............................. 5
2.1
Sampling and Analyses ........................................................................................ 5
3.0
SAMPLING PROTOCOLS ..................................................................................... 7
3.1
PROJECT INITIATION ...................................................................................... 7
3.2
DOCUMENTATION ........................................................................................... 7
3.2.1
Field Logbook ............................................................................................... 7
3.2.2
Chain-of-Custody Form ................................................................................ 8
3.3 SAMPLE DESIGNATION AND IDENTIFICATION ....................................... 8
3.4 SAMPLE MANAGEMENT AND SHIPMENT ................................................. 9
4.0
SAMPLING EQUIPMENT AND PROCEDURES .............................................. 10
5.0 INVESTIGATION DERIVED WASTE ............................................................... 11

5.1 MANAGEMENT OF HAZARDOUS IDW ...................................................... 11
6.0
REFERENCES ...................................................................................................... 12
Tables
1
Summary of Extensive List of Constituents of Interest, EPA Methods, Reporting

Limits and Holding Times.
Summary of List of Constituents Based on Generator Knowledge, EPA Methods,

Reporting Limits and Holding Times
1.0
INTRODUCTION
This Field Sampling and Analysis Plan (SAP) details the procedures for sampling and
field documentation to be utilized for the characterization study of the fracturing and flow
back fluids associated with the Devonian shale. The FSAP has been prepared to ensure
that all data and information gathered are properly sampled, documented, and technically
sound. The FSAP and Quality Assurance Project Plan (QAPP) together comprise the
Sampling and Analysis Plan (SAP).
1.1
PURPOSE
The FSAP includes a detailed description of field sampling procedures to be conducted.
The procedures described are consistent with the RCRA Technical Enforcement
Guidance Document (TEGD), U.S. EPA, 1989; RCRA Facility Investigation Guidance
Document (U.S. EPA, May 1989); RCRA Ground Water Monitoring; Draft technical
Guidance (U.S. EPA, 1992); Data Quality Objectives for Remedial Response Activities
(U.S. EPA, 1987).
The SAP consists of 5 sections. Section 1.0 includes a brief description of the data
objectives and a brief discussion of the project. 2.0 provides information regarding
documentation, quality assurance/quality control (QA/QC) requirements, and reporting.
Section 3.0 addresses the sampling procedures. Section 4.0 describes the proper handling
requirements of any investigative derived waste generated. Reference documents are
provided in Section 5.0
1.2
DATA OBJECTIVES
The data objectives will address characterization of the fracturing and flow back fluids
associated with the development of the Devonian shale. This characterization study will:
Identify the specific constituents of interest (COI) associated with flow back
water;
Reduce/eliminate the allegations that the chemicals used for fracturing will
contaminate groundwater; and
Provide sufficient information for the selection of proper disposal techniques.
Achieving these data objectives will require obtaining data of acceptable levels of
certainty. Therefore, it is essential that the field and sampling procedures be completed
under stringent and appropriate methods.
1.3
BACKGROUND
The process of developing Devonian Shale wells requires increasing the number of
fractures and extending the existing fractures. Fracturing is necessary to obtain a greater
volume of natural gas from the Devonian Shale at in a cost-efficient manner. Fracturing
uses high volumes and high-pressure chemically treated water or a gel to induce fractures
in the shale surrounding the well bore. Most applications require between 500 and 10,000
psi.
Fracturing is done by isolating off a portion of the well and injecting chemically treated
water or gel and sand with cement, perforating, under very high pressure into the isolated
portion of the well bore. Generally, 1.5 to 5 million gallons of water is pumped into the
formation of a vertical or horizontal well, respectively. The high pressure fractures the
shale and sand keeps the fractures open. A drop in pressure indicates that the formation
has accepted water.
To prevent the fractures from closing when the pressure is reduced several hundred tons
of sand or other propant is pumped down the well and into the pressurized portion of the
well. When the fracturing occurs the sand is forced into the fractures. If enough sand is
trapped in the fractures it will prop the fractures open when the pressure is reduced. The
propped fractures provide an increase in the permeability for gas flow.
Approximately 25 to 30 percent of the water used in fracturing is recovered. This flow
back water is currently a concern because there is a limited amount data. The ASMCWC
is conducting this study in an effort to characterize the flow back water associated with
the Devonian Shale.
The flow back water will be collected in either an on-site off-stream temporary
impoundment or a series of frac tanks.
2.0
CHARACTERIZATION STUDY OF FLOW BACK WATER
Fracturing is completed over several days depending on the geological formation.
Because the flow back water is under pressure, initially the flowback water is recovered
at a faster rate in the beginning of fracturing and significantly declines as facturing
continues and the well is released to production. The initial concentrations at the start of
fracturing (high yields of flow back water) should yield lower concentrations of
constituents of interest (COI). It is assumed that the concentration of the fracturing
chemicals remain constant throughout the flow back regardless of the rate of return.
However, the increase concentration of in the COI is due to a longer residence time in the
applicable formation and not associated to the additives of the fracing fluids.
Therefore, to obtain representative samples of the flow back water samples will be
collected on three separate days (i.e., days 1, 5 and 14). The data obtained from day 14
should represent the chemical characteristics of the natural formation fluid.
Additionally, a baseline sample of the fracturing fluid will be collected prior to injection.
The baseline sample will contain the materials (e.g., water and chemicals) used in the
fracturing process. A sample will also be collected from a well in Devonian shale that
has been in production for a period of time (i.e., a well that has been in production for
more than 3 months). The data obtained from this well should represent the chemical
characteristics of the natural formation fluid. The analytical results associated with these
samples will assist in the data interpretation.
2.1
Sampling and Analyses
In general, several frac tanks are connected in-line and filled simultaneously with the
flow back water. This is completed to avoid back pressure when shutting one frac tank
and opening another tank for additional capacity. This filling process will provide a
composite sample of the flow back water over time. To minimize volatilization, a
representative composite sample of the flow back water samples will be collected from
the top of a frac tank or flow back impoundment.
The flow back water is either pumped into the frac tanks for storage until the water is
disposed of properly. If a project does have an impoundment that stores flow back water
on site in an impoundment, a grab sample will be collected from the impoundment
following day 1, 5 and 14 of fracturing.
The base fracturing fluid will be collected prior to going down hole. The base fracturing
fluid will be collected from either the sampling lines built into the blenders or as a grab
sample from the blending containers. In either case a representative sample of the fluid
will be collected.
Numerous flow back water samples will be collected from several unique locations.
Phase one of this characterization study will include the sampling of six flow back water
samples from six unique locations.
The list of constituents recommended for the characterization study was developed from
comments received from the Pennsylvania Department of Environmental Protection
(PADEP), the West Virginia Department of Environmental Protection (WVDEP) and
members of the ASWCMC. Because the recommended list of constituents is extremely
extensive, it was decided that one sample from each site will be completed for the full list
of recommended constituents (Table 1). All other samples will be sampled for a subset
of these constituents (Table 2), which are based on generator knowledge and Group 1 and
Group 2. The analytical results of phase one of the characterization study will determine
the list of constituents of subsequent sampling events.
3.0
SAMPLING PROTOCOLS
This section identifies the protocols to be implemented during field sampling.
Specifically this section describes the preparation, documentation, and reporting
procedures to be used that will assure quality assurance and quality control.
3.1
PROJECT INITIATION
Following acceptance of this plan by the ASWCMC and the state agencies, Gas
Technology Institute (GTI) will authorize Test America an independent a credited
analytical laboratory to provide the appropriate sample containers and preservatives; and
URS, an independent environmental consulting company has been retained to collect the
flow back water. Furthermore, Test America will complete the analytical analyses. Test
America is certified by WVDEP and PADEP.
The regulatory agencies are invited to collect split samples. The samples will be
collected at the discretion of the agency. All agency sampling must be approved and
coordinated with the appropriate gas company.
3.2
DOCUMENTATION
A field logbook and chain-of-custody form will be utilized during the field activities.
3.2.1 Field Logbook
During field activities, a site-specific logbook will be used for documentation of all notes.
It is recommended that each page of the logbook be numbered and dated. The entries
should be legible and contain accurate and inclusive documentation of the project
activities. Once completed, the logbook becomes an accountable document and is
maintained as part of the project file. The logbook should include, at a minimum, the
following information:
Identification of logbook ownership and telephone number on the inside front
cover;
Well location and identifying number;
Names of field personnel at the site;
Weather information (general);
Sample locations and activities;
Sample collection equipment;
Date and time of monitoring of sampling;
Water quality measurements (field pH, specific conductance, water temperature);
Field instrument calibration information;
Visual observations;
Collection of field quality assurance samples (i.e., blanks or duplicates);
Regulatory agency personnel observing sampling;
Enter agency, collectors name, samples splits, etc., if a regulatory agency splits
samples; and
Documentation of sample shipment dates, time, and carrier tracking (air bill)
number, if necessary.
Copies of the field book pages will become part of the sample data package.
3.2.2 Chain-of-Custody Form
The chain-of-custody form is used to record the custody of all samples collected. This
chain-of-custody form documents transfer of the custody from the sampling personnel to
another person, to the laboratory, or to another party, such as a courier delivery service.
The chain-of-custody form also serves as a sample logging mechanism for the laboratory
sample custodian.
When the field personnel sends samples to the analytical laboratory, each cooler chest
containing samples must be accompanied by a chain-of-custody form. These forms
contain the following information pertaining to the samples:
Project Name
Name(s) and signature(s) of the individual(s) collection the samples;
Sample location;
Date and time of sample collection;
Total number of sample containers per sample location;
Type of sample preservation used (e.g., HNO3, HCl, etc.)
Analytical parameters of interest for each sample and number of containers per
analytical parameter;
Remarks or observations;
Signature(s) of all individual(s) relinquishing and receiving custody of the
samples;
Name of the carrier shipping the samples; and
Air bill number under which sample containers(s) was sent, if applicable;
The chain-of-custody forms are multi-colored carbon copy forms. The original copy
(white) is submitted to the laboratory with the samples, the second copy (pink) is sent to
GTI, and the third (yellow) is kept for the project files.
3.3
SAMPLE DESIGNATION AND IDENTIFICATION
Each sample collected for this characterization study will be assigned a unique sample
tracking number. The identification of the well location and participating gas company
will not be identified. All well locations will be blind. GTI will assign each well a
project identifier. The project identifier will be a unique single alphanumeric letter that
will identify the Devonian Shale well location and company. This unique alphanumeric
letter will be provided to the third party environmental consultants to be used in the
sample designation.
3.4
SAMPLE MANAGEMENT AND SHIPMENT
The possession of samples or other physical evidence shall be traceable from the time the
samples are obtained until they have been submitted to the analytical laboratory. To
simplify the documentation of possession that is maintained on the chain-of-custody
form, the number of people who handle the sample during the investigation should be
minimized. All samples will be documented in the field logbook, on the chain-ofcustody form and on the sample container labels. Field documentation procedures are
provided above in Section 2.3 and the in the QAPP.
Sample labels shall be completed for each sample using waterproof non-erasable ink. All
samples are to be sealed immediately upon collection and are to be immediately place on
ice in a cooler.
Samples are to be properly packaged for shipment and delivery to the laboratory. To
ensure that the samples are kept cold for preservation requirements, the samples are to be
shipped in iced coolers for overnight delivery. Samples collected during the
characterization study are to be classified as environmental samples.
Shipping containers are to be secured with tape and use of security seal method to ensure
that the cooler may not be opened without evidence of the seal being tampered.
Ice used to keep the samples cooled must be secured in plastic bags (e.g., Zip-Lock
plastic bags) to ensure that melted ice does not cross contaminate the samples pr leak
from the coolers.
Samples will be either hand delivered to the laboratory or shipped via priority service to
the laboratory or the air bill retained for the project file.
4.0
SAMPLING EQUIPMENT AND PROCEDURES
Grab samples will be conducted using a new PVC bailer from the top of the frac tank.
The order, in which the grab samples are collected, as prioritized to the sensitivity to
volatilization, is as follows:
Volatile Organics
Purgeable Organics
Purgeable Organic Halogens
Total Organic Halogens
Extractable Organics
Total Metals
Dissolved Metals
Phenols
Cyanide
Sulfate and Chloride
Turbidity
Nitrate and Ammonia
There is not an order of preference for the collection of the remaining conventional
parameters.
Temperature, pH, dissolve oxygen, and specific conductance measurements will be
completed in the field
5.0
INVESTIGATION DERIVED WASTE
Materials which may be investigation derived waste (IDW) are:

Personnel protective equipment (PPE), including disposable gloves, coveralls,
booties, etc.;
Disposable equipment, including plastic ground and equipment covers, aluminum
foil, Composite liquid waste samplers (COLIWASAs), used sample containers,
tape, etc.;
5.1
MANAGEMENT OF HAZARDOUS IDW
If wastes are suspected to be hazardous, appropriate analysis must be performed to make
that determination. The analytical testing should meet the requirements of the potential
disposal characterization requirements. If the IDW is determined to be hazardous wastes
either through testing of characteristics or as a listed waste, they must be properly
container and labeled. They may be stored on site for a maximum of 90 days before they
must be manifested and shipped to a permitted treatment of disposal facility.
Care should be taken to keep non-hazardous materials segregated from hazardous wastecontaminated materials.
6.0
REFERENCES
Kitrell, F.W. 1990. A Practical Guide to Water Quality Studies.
U.S. EPA, 1986. Test Methods for Evaluating Solid Waste, Volume II; Field Manual,
Physical/Chemical Methods. Office of Solid Waste and Emergency Response, SW-846,
November 1986
U.S. EPA 1987. Data Quality Objectives for Remedial response Activities. Oswer
Directive 935507B, Office of Emergency and Remedial Response, Washington DC.
EPA/5406/6=87/100 and 004.
U.S. EPA, 1986. RCRA Ground-Water Technical Enforcement Guidance Document.
Office of Waste Programs Enforcement, Washington DC, Oswer Directive 99501.
U.S. EPA, 1992. RCRA Groundwater Monitoring: Draft Technical Guidance. Office of
Solid Waste, Washington DC. EPA/530/R-93/001.
U.S. EPA, 1998. Environmental Investigations Standard Operating Procedures and
Quality Assurance Manual. U.S. EPA Region 4, Athens, GA, May 1996.
Appendix B
Quality Assurance Project Plan (QAPP)
QUALITY ASSURANCE PROJECT PLAN

DEVONIAN SHALE FLOWBACK WATER
CHARACTERIZATION STUDY
Prepared by
Appalachian Shale Water Conservation and Management Committee
November 2008
TABLE CONTENTS
1.0 PURPOSE
2.0 PROJECT DESCRIPTION

2.1
SCOPE OF WORK
4
4
3.0 QUALITY ASSURANCE OBJECTIVES FOR MEASUREMENT DATA

3.1
DATA QUALITY LEVELS
3.2
QUALITY CONTROL PARAMETERS
5
5
6
4.0 SAMPLING PROCEDURES

4.1
SAMPLE IDENTIFICATION
4.2
SAMPLE CONTAINERS
4.3
FIELD QA/QC SAMPLES
4.3.1 Trip Blanks
4.3.2 Equipment Blanks
4.4
DOCUMENTATION
8
8
9
9
9
10
10
5.0 SAMPLE CUSTODY
11
6.0 ANALYTICAL PROCEDURES
12
7.0 CALIBRATION PROCEDURES AND FREQUENCY

7.1
PREPARATION OF STANDARDS
7.2
CORRECTIVE ACTION
13
13
13
8.0
15
15
15
16
16
17
17
17
DATA EVALUATION/VALIDATION
8.1
FIELD DATA VALIDATION
8.2
LABORATORY DATA VALIDATION
8.3
INDEPENDENT DATA VALIDATION
8.4
DATA REPORTING
8.4.1 LEVEL I REPORTING
8.4.2 LEVEL II REPORTING
8.4.3 LEVEL III REPORTING
9.0 QUALITY CONTROL PROCEDURES

9.1
FIELD QC CHECKS
9.1.1 EQUIPMENT BLANKS
9.1.2 TRIP BLANKS
19
19
19
19
9.2
9.2.2
9.2.3
9.2.4
9.2.5
INTERNAL LABORATORY QC CHECKS

Preparation/Method Blanks
Matrix Spike And Duplicate (Or Matrix Spike Duplicate) Analysis
Surrogate Spike Standard Performance Evaluation
Calibration Check Compounds And Reagent Blanks
20
20
21
21
21
10.0 PERFORMANCE AND SYSTEM AUDITS

10.1 PERFORMANCE AUDITS
10.1.1
Laboratory Performance Audits
10.2 SYSTEM AUDITS
10.2.1
Laboratory System Audits
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22
22
22
22
11.0 ASSESSMENT PROCEDURES FOR DATA ACCEPTABILITY

11.1 PRECISION
11.2 ACCURACY
11.3 COMPLETENESS
11.4 QUALITY CONTROL CHARTS
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23
23
23
24
12.0 PREVENTIVE MAINTENANCE

12.1 FIELD
12.2 LABORATORY
25
25
25
13.0 CORRECTIVE ACTION
26
14.0 QA REPORTS TO MANAGEMENT
27
FIGURE
1
Chain of Custody Record
TABLES
1 Summary of Extensive List of Constituents of Interest, Reporting Limits, and Holding
Times
2 Summary of List of Constituents Based on Generator Knowledge, Reporting Limits, and
Holding Times
This document is the Quality Assurance Project Plan (QAPP), which provides specific quality
assurance/quality control (QA/QC) procedures to be executed and supported for the
Characterization Study of the flow back water associated with the well fracturing of the
Devonian Shale.
Data generated for environmental purposes must be technically sound and legally defensible, and
supported by defined and verified limits of confidence. Therefore, the objective of this QAPP is
to ensure the generation of accurate, precise, representative and complete data. The QAPP sets
forth the data collection procedures and data evaluation processes, which will ensure that
appropriate levels of data quality are obtained.
Analyses must meet the QA/QC requirements associated with this QAPP and the following
documents:
SW-846, Third Edition (September 1986), as amended by updates 1 (July 1992), II (September
1994), IIA (August 1993), and IIB (January 1995), or the most current SW-846 update;
EPA's "Handbook for Analytical Quality Control in Water and Wastewater Laboratories" (EPA
600/1-79-019);
Standard Methods for the Examination of Water and Wastewater.
Only U.S. EPA-approved methods will be used for chemical analyses. Any omission in this
QAPP of relevant requirements, tasks and other items found in the referenced methods does not
constitute a waiver of the omitted requirement, task, or item. It is the responsibility of all
personnel involved in the various site investigation activities to perform and document the
required procedures designated herein.
The Appalachian Shale Water Conservation and Management Committee (ASWCMC) is

conducting a study to characterize the fracturing and flow back water generated from
development of Devonian Shale wells.
Samples will be collected from both vertical and horizontal Devonian Shall gas wells. Numerous
samples will be collected from several locations. Phase one of the characterization study will
include 4 grab samples from 6 well sites. A sample will also be collected from a well that has
been in production for at least three months. The following grab samples will be collected from
each site:
One baseline fracturing water sample that includes the fracturing chemicals, excluding
the sand;
Flowback water samples will be collected on days 1, 5 and 14 of the following the
fracturing process; and
Water from an existing producing well.
The list of constituents recommended for the characterization study was developed from
comments received from the Pennsylvania Department of Environmental Protection (PADEP),
the West Virginia Department of Environmental Protection (WVDEP) and members of the
ASWCMC. Because the recommended list of constituents is extremely extensive, it was decided
that one sample from each site will be completed for the full list of recommended constituents
(Table 2). All other samples will be sampled for a subset of these constituents (Table 3), which
are based on generator knowledge. The analytical results of phase one of the characterization
study will determine the list of constituents of subsequent sampling events.
In addition, field measurements of pH, specific conductance, temperature, dissolved oxygen, and
turbidity will be taken of flow back aqueous samples.
Data Quality Objectives (DQOs) are qualitative and quantitative statements to ensure that data of
known and appropriate quality are obtained during the characterization study (sampling and
analysis).
The data objectives will address characterization of the flow back fluids associated with well
fracturing generated from Devonian shale. This characterization study will:
Identify the specific constituents of interest (COI) associated with flow back water;
Reduce/eliminate the allegations that the chemicals used for fracturing will contaminate
groundwater; and
Provide sufficient information for the selection of proper disposal techniques.
Achieving these data objectives will require obtaining data of acceptable levels of
certainty. Therefore, it is essential that the field and sampling procedures be completed
under stringent and appropriate methods
There are typically five analytical levels of data quality available to accomplish the objectives of
investigations of this type. These levels are typically designated as follows:
Level I:
field screening or analysis using portable instruments, calibrated to noncompound specific standards;
Level II:
field analysis using portable instruments, calibrated to specific compounds;
Level III:
non-Contract Laboratory Program (non-CLP) laboratory methods;
Level IV:
CLP Routine Analytical Services (RAS) methods; and
Level V:
non-standard analytical methods.
DQO Levels I and III will be used to characterize the Devonian Shale Fracturing Flowback
sampling activities. The following sections describe the use of the analytical procedural levels
that will be used during the project.
Field Screening Methods - Level I

Field determinations of pH, specific conductance, temperature, dissolved oxygen, and turbidity
will be made during characteristic sampling as part of a field screening procedure. These
analytical methods are used to determine stability of the well and they are typically designated as
Level I data quality.
In addition, as part of the health and safety program, worker safety may be monitored via one or
more of a variety of field screening tests such as a photoionization detector (PID) or flame
ionization detector (FID) to test for volatile organic vapors, or a combustible gas indicator to test
for explosivity potential. These tests, which are semi-quantitative, are classified as field
screening evaluations, even though they typically are not used for site characterization purposes.
Non-CLP Laboratory Methods - Level III
Level III analytical procedures provide precise, accurate and defensible data for the intended data
uses, with a less formal documentation and reporting nomenclature at reduced analytical costs
over Level IV data quality procedures. Data Quality Level III will be used during this
characterization study. Table 1, summarizes analyses that will be conducted to characterize and
quantify constituent concentrations.
The exact quantitative criteria used to evaluate data quality from the laboratory's precision and
accuracy perspective for the aqueous and solid sampling media will be presented in the selected
laboratory Quality Assurance Manual(s) (Appendix QAPP-1 and following). The following is a
description of terms that appear in the QAM.
Reference:
procedure.
The reference of the U.S. EPA standard analytical methodology used for each
Precision:
A measure of the mutual agreement among individual measurements of the same
property under prescribed similar conditions. Precision is evaluated based on the relative percent
difference (RPD) between duplicate matrix spike results or duplicate sample results, as
appropriate. The matrix spike duplicate RPD limits are parameter and method-specific,
MS/MSD RPD QC limits will be presented in the laboratory QAMs. Laboratory duplicate
sample RPD limits are typically 20 percent for aqueous media and 35 percent for solid media
(exceptions may apply for solid media whose samples may be nonhomogeneous). Field
duplicates are also evaluated by calculating the RPDs between field duplicate sample results.
However, evaluations of field duplicate RPDs are used as advisory determinations since
numerous factors in sampling and analysis may cause variances between field duplicate results.
Accuracy:
The degree of agreement of a measurement with an accepted reference or true
value. Accuracy is evaluated based on the percent recovery of spiked samples. The matrix spike
recoveries for organic analyses are method and parameter specific and are typically used as an
advisory QA/QC measure due to the difficulty associated with recovering spiked organic
parameters. Organic parameter percent recovery QC limits will be presented in the laboratorys
QAM. The matrix spike recoveries for inorganic and most conventional parameters are typically
a range of 25 percent.
Completeness: A measure of the amount of valid data obtained from a measurement system
compared to the amount expected to be obtained under normal conditions. The method of
calculation for percent completeness is defined in Section 12.3. Completeness can be evaluated
in two ways: 1) by comparing the number of samples actually collected to the expected number
of samples to be collected; and 2) by comparing the number of valid analyses received from the
laboratory to the number of actual samples collected. The results of any Level III analyses to be
performed is typically used for characterization studies and as such will have a minimum
completeness of 95 percent for both evaluations of completeness.
Exact QA/QC criteria the laboratory will use to evaluate its data's precision and accuracy will be
provided following selection of the analytical laboratory, if the criteria are not method-specific.
Table 1 summarizes the individual parameters and associated reporting limits.
There are also qualitative criteria that are adhered to ensure that data of known and appropriate
quality are obtained during investigation activities. These criteria include representativeness and
comparability.
The sampling and analysis programs are designed to ensure that analytical data obtained during
the characterization study represent current conditions found at the site and produce data of
comparable quality. The sampling frequency was selected to ensure data are suitable for their
intended use and adequately characterize the flow back water. Additionally, standard recognized
analytical methodologies will be utilized to ensure comparability. These designs are instituted to
ensure appropriate sample representativeness and data comparability.
This section outlines the procedures to be used for the preparation of sampling equipment and
containers and for sample preservation. It also provides some of the quality control and
operating procedures to be followed for sampling. Detailed field sampling details including the
number of samples to be collected, the rationale for sampling, and QC requirements are
described in the Field Sampling and Analysis Plan.
Each sample collected for this characterization study will be assigned a unique sample tracking
number. The identification of the well location and participating gas company will not be
identified. All well locations will be blind. GTI will assign each well a project identifier. The
project identifier will be a unique single alphanumeric letter that will identify the Devonian Shale
well location and company. This unique alphanumeric letter will be provided to the third party
environmental consultants to be used in the sample designation.
Flow back Sampling

Fracturing is completed over several days depending on the geological formation. The flow back
water is initially removed at a faster rate at the start of production and significantly declines as
production continues. It is believed that the volume of water is relative to the concentration. It is
assumed that the concentration of the fracturing chemicals remain constant throughout the flow
back regardless of the rate of return. However, the increase of in the COI is due to a longer
residence time in the applicable formation and not associated to the additives of the fracturing
fluids. Therefore, to obtain representative samples of the flow back water samples will be
collected on three separate days (i.e., days 1, 5 and 14).
Additionally, a baseline sample of the fracturing fluid will be collected prior to injection. The
baseline sample will contain the materials (e.g., water and chemicals) used in the fracturing
process. A sample will also be collected from a well in Devonian shale that has been in
production for a period of time (i.e., I production fro more than 3 months). The analytical results
associated with these samples will assist in the data interpretation.
Quality Assurance
The quality assurance field will only be used to indicate a sample collected for quality assurance
purposes.
Quality Assurance/Quality Control Samples will be identified as follows:
EB
TB
Equipment Blank
Trip Blank
The following are sample identification samples.

A05V
Sample collected from company X on day 5 from a vertical well.
CEH
Sample collected from company Y from an existing horizontal well.
TB
Trip Blank.
Each sample container will be marked with a label identifying the specific parameters of interest.
The label will record the date of sample collection, alphanumeric identification, parameters to be
analyzed, and preservatives, if applicable. Sample bottles should be prelabeled by the laboratory
to avoid unnecessary delays.
The specific information for each sample will be documented in the field logbook and on a
chain-of-custody form. The sample identification will be correlated in the logbook and chain-ofcustody by sample designation, sampling date, time, and location. The analytical parameters for
which the sample is to be analyzed and the respective number of sample bottles will be provided
on the chain-of-custody sheet.
All new pre-cleaned sample bottles with screw-type Teflon-lined lids will be used for holding
and shipping samples. These sample bottles will be supplied by the analytical laboratory, and
pre-preserved by the laboratory as necessary.
Two types of field QA/QC samples will be collected (i.e., trip blanks and equipment blanks).
The following provides a description of the essential field QA/QC samples.
Trip blanks are collected only for volatile organic samples. The trip blank is prepared by the
laboratory by filling a batch of pre-cleaned 40-ml vials with laboratory-grade water. The vials
are transported to the site and returned to the laboratory in the same manner as the environmental
sample containers. Any constituents found in the trip blank could be attributed to: a) interaction
between the sample and the container, b) contaminated laboratory-grade water, or c) a storage or
handling procedure which alters the sample. One trip blank should accompany VOC samples for
each sampling event. The trip blank is placed in the cooler that contains samples for volatile
organics. At no time after the preparation are trip blanks to be opened before they are returned to
the laboratory.
To verify that no constituents are introduced from sampling equipment, equipment blanks are
collected by pouring distilled water through the representative sampling device and analyzing for
all constituents of interest. One equipment blank will be collected during the characterization
study.
A number of documents will be used during the characterization study. These documents
include: chain-of-custody forms and field data sheets.
Chain-of-custody Forms
The field chain-of-custody form is used to record the custody of all samples collected. This
chain-of-custody form documents the transfer of the custody from the sampling personnel to
another person, to the laboratory, or another party, such as a courier delivery service.
When the field team sends samples to an analytical laboratory, each shipping cooler containing
samples, which are sent under one shipping document, must be accompanied by a chain-ofcustody form (Figure 1). These forms document information regarding the origination of
samples and those parties having subsequent possession of samples. They also contain
information pertaining to these samples, such as project name, name of the individuals collecting
the samples, sample identification number, the date and time of collection, the number of sample
containers for each parameter of interest for each sample, remarks or observations of samples, if
appropriate, the signature of the person relinquishing control of the samples and the person
receiving the samples, and the name of the overnight carrier shipping the samples to the
laboratory. The original chain-of-custody sheet is sent with the samples. One copy will be
submitted to Gas Technology Institute (GTI), and the other copy is stored in the field team files.
The primary objective of sample custody is to create an accurate written verified record, which
can be used to trace the possession and handling of the samples from the moment of collection
through data analysis and reporting.
The field sampler will be personally responsible for the care and custody of the samples collected
until they are properly transferred. Samples will be accompanied by a Chain-of-Custody Record.
Upon arrival at the laboratory, samples will be checked in using laboratory custody procedures
outlined in the laboratory QAM. The laboratory is required to verify that all samples were
received and in good condition. The laboratory should assign a laboratory-specific sample
identification. This unique identification guarantees sample anonymity to the analyst of the
sample's site.
Once samples have been logged-in and transferred to the proper storage areas, the laboratory
department manager is responsible for their proper storage and condition. Copies of the
completed Chain-of-Custody Records and an analysis narrative presenting laboratory sample
identifications and their correlating field assigned sample identifications should be included in
the data package for delivery to the data user.
All analyses will be performed using U.S. EPA analytical methods procedures from the
following:
Third Edition (September 1986), as amended by updates 1 (July 1992), II (September
1994), IIA (August 1993), and IIB (January 1995), or the most current SW-846 update;
EPA's "Handbook for Analytical Quality Control in Water and Wastewater Laboratories"
(EPA 600/1-79-019);
Standard Methods for the Examination of Water and Wastewater.
Table 1 and Table 2, summarize the list the constituents of interest (COIs) associated with the
characterization study for the flow back water from the wells of the Devonian shale and the
required reporting limits to be reported by the laboratory. Method selection was based on the
following factors: reliability in identification and quantifications, and comparability of sample
results and best achievability of the lower of federal Maximum Contaminant Levels (MCLs).
All procedures for environmental sample handling, storage, and documentation while in the
laboratory's custody and deliverable requirements upon delivery of the data to the user are stated
in the laboratory QAMs.
All field and laboratory equipment are calibrated before use to ensure proper operating
conditions. Laboratory instrument calibration procedures are presented in the laboratory QAMs.
Field calibration procedures and frequencies should be followed in accordance with the
manufactures specifications. Field calibrations must be completed each day at a minimum. pH
meters are required to be calibrated or verified every two hours at a minimum.
All analytical methods must be validated at some point by the use of calibration standards. A
calibration standard is made by the appropriate dilution of a pure substance, the purity of which
is traceable to an NBS or U.S. EPA standard. Because of the high sensitivity of many analytical
instruments, the calibration standard is an extremely dilute version of the pure compound.
Because of the high dilution required to be within the linear range of the instrument, the
preparation of the calibration standard is frequently made by serial dilution rather than in a single
step. In order to provide standard solutions at sufficiently low concentrations, a minuscule
amount of the pure substance will be required, the measurement of which is subject to extreme
error. Thus, it is preferable to deal with potential dilution errors, rather than with the large error
associated with the measurement of a very small amount of the pure substance.
The initial standard is usually obtained either as a pure material or as a prepared certified solution
of a given concentration of the pure compound or compounds. In preparing the stock solution of
the calibration standard, great care must be exercised in measuring weights and volumes as
accurately as possible, since all of the analyses following the calibration will be based on the
accuracy of the calibration, and the accuracy of the analytical data is dependent on the calibration
curve. It is the analyst's responsibility to assure that all standards used are within the standard
solution holding time, and to prepare fresh standard solutions whenever necessary. In preparing
working solutions, or using working solutions, the analyst must check for signs of deterioration
of the standard, such as cloudiness, precipitation, or discoloration. The standard must also be
periodically compared with previous runs of standards, and with independently prepared
standards to assure that response factors fall within a historically accepted range.
There are many laboratory functions that may require corrective action. The decision to
undertake corrective action, and the ensuing action must be documented so that traceability can
be maintained. The point of originating the corrective action varies, depending upon the mode of
detection that such action is necessary. It is generally the role of either the Laboratory QA
Officer or the Laboratory Department Manager to initiate such action. Those actions that affect
the quality of the data will be recorded and the record maintained by the Laboratory QA Officer.
The general procedures for appropriate laboratory corrective actions and identification of
potential problems are presented in the analytical laboratory QAM.
Data are typically validated by the laboratory and field personnel. First, during the field
operations, field measures will be validated at the time of collection by the field sampler by
verifying the use of standard operating procedures for the sampling effort and using field QC
checks. Second, laboratory analytical results will be validated by the Laboratory Department
Manager or the analyst who is the specific analytical task leader.
Validation of field obtained data, as well as ongoing QA/QC checks of environmental samples
being taken, is performed on field data. All field data are reviewed during the time of collection
and second, all data are reviewed by secondary field personnel if multiple personnel are present.
Corrections in the field logbooks will be removed by placing a single line through the entry,
initialing and dating the correction. If information is added without a correction being necessary
that entry will be initialed and dated to indicate that it was not entered at the original time of data
entry. Entries should never be whited out or made in pencil.
The individual Laboratory Department Managers should validate all laboratory data, prior to
reporting. Some of the following QA/QC measures are reviewed or procedures are typically
used:
A standard curve is prepared prior to sample analysis;
The standard regression coefficient is within the acceptable range;
Standard reference materials are analyzed at the proper frequencies and acceptable results
are obtained;
The reagent blanks are analyzed at the proper frequency;
Precision requirements of this plan are met;
Accuracy requirements of this plan are met;
Completeness requirements of this plan are met;
Samples are analyzed within the proper sample holding times;
All calculations are verified as correct;
Proper units are reported; and
The proper methodologies were used.
Besides this review of analytical results and project specific precision, accuracy, and
completeness requirements, the Laboratory Department Manager should perform unannounced
audits of report forms and other data sheets as well as regular reviews of instrument logs,
performance test results, and analysts performance. Any review of analytical results or internal
QA/QC checks that indicate problems, immediate corrective actions should be taken and all data
collected since the previous approved QC audits should be reviewed for validity. Specific
laboratory procedures for validation of the analytical data generated are described in the
laboratory QAMs.
The laboratory will provide DQO Level 3 (i.e., CLP Like) data packages. However, the data
packages will not be validated at this time. Data validation procedures following the applicable
guidance from the current U. S. EPA's Contract Laboratory Program, National Functional
Guidelines for Organic Data Review and the U. S. EPA's Contract Laboratory Program,
National Functional Guidelines for Inorganic Data Review will be performed, if required.
Analytical Laboratory
Once the data have been validated internally by the laboratory, all of the results are electronically
or automatically entered into the laboratory's data management system where they are stored
prior to reporting. When all analyses are completed for data storage, the Laboratory Director (or
his/her designee) will issue a final data report including a descriptive case narrative. He or she
will then issue the report to the data user. All applicable QC data should be included with the
final report.
The data reports generated for this project should contain all pertinent information for the data
user to determine the applicability and usability of the data for its intended purposes. For this
reason, a specified and uniform data reporting format should be implemented. For this project,
DQO levels III data packages will be reported as a Level IV (CLP-like) deliverable to facilitate
data validation, if needed. The following criteria and information should be supplied, at a
minimum, for data reports generated for this project:
1. A descriptive case narrative identifying any problems encountered during internal data
validation (as described above);
2. Completed and legible chain-of-custodies for all analyses contained within each
submitted data package;
3. A lab sample chronicle indicating which analyses were requested and performed for the
samples contained in the data package;
4. A summary of the laboratory sample identifications and the correlating field sample
identifications;
5. A summary of all applicable analytical results reported in the correct number of
significant figures, reporting units; and
6. Included in the individual sample reporting results should be the complete sample
identifications, the sample dilutions (if necessary), and the individual sample analysis
dates.
Summary reporting only will be provided. Bulleted items above are required under this DQL.
Summary reporting only will be provided. The data package reporting requirements are the same
as Level I except legible and calculated QA/QC summaries for laboratory blanks, surrogate
recoveries (if applicable), laboratory control sample recoveries, and matrix spike/matrix spike
duplicate recoveries (or matrix spike recovery and laboratory duplicate results) must also be
supplied under this DQL.
The following summary forms and raw data deliverable requirements will apply for Data Quality
Level III.
The following forms are required for all analyses using Gas Chromatography/Mass Spectroscopy
methods.
Narrative and sample identification cross reference;
Copies of Chain-of-Custody documentation;
Laboratory chronicle;
Method summaries and references;
Organic analysis data sheet for samples and blanks (with TICs as required);
System monitoring compound/surrogate recoveries summary;
Matrix spike/Matrix spike duplicate summary or any lab duplicate;
QC Check Sample summary;
Method blank summary and results;
Instrument performance check summary;
Initial calibration summary for all constituents of interest;
Continuing calibration check summary for all constituents of interest;
Internal standard area and RT summary;
Extraction/preparation logs;
The handwritten calculation for at least one positive result in one sample at a rate of one
calculation per twenty samples or per data package (whichever is greater) per fraction
(e.g., VOC or SVOC); and
Raw data including run logs, mass spectra, quantitation reports and chromatograms for
samples, as well as any raw data used to complete the hand written calculation.
The following forms are required for all total metal analyses.
Inorganic analysis data sheets;
Initial and continuing calibration verification;
Initial and continuing calibration blanks and preparation blank summary;
ICP interference check sample summary;
Spike sample recovery;
Duplicate results summary;
Laboratory Control Sample summary;
Standard addition results summary, when applicable;
ICP serial dilutions;
Instrument detection limits;
ICP inter-element correction factors summary;
Preparation log;
Analysis run log;
The hand-written calculation for at least one positive result in one sample at a rate of one
calculation per twenty samples or per data package (whichever is greater) per method
(e.g., GFAA/ICP/CU); and
Raw data.
The following data and summary forms will be submitted by the laboratory for inorganic nonmetals analyses or other analyses not discussed above:
Analysis data sheets;
Calibration summaries; and
Calibration equation and curve plot;
Blank results summary;
Sample spike recovery, where applicable;
Duplicate sample results, where applicable; and
Laboratory control sample summary where applicable.
Quality control (QC) procedures and checks are used to verify the accuracy of investigation data.
Field QC checks are used to identify potential problems with sampling procedures such as the
inconsistent use of sampling standard operating procedures or field introduced sample or water
supply contamination and/or problems with sample homogeneity or representativeness.
Laboratory QC checks are used to identify potential problems with analytical procedures such as
the misapplication of required analytical methodologies or other laboratory related problems
which could result in inaccurate or imprecise data reported. The laboratory QC checks and
procedures presented in this section are required for most of the applicable methods, but the
frequency of the QC checks should follow procedures outlined in the laboratory QAMs.
To check the quality of data from field sampling efforts, field blanks and field duplicate samples
will be collected for analysis. These samples will be treated as separate samples for
identification, logging, and shipping. Analytical results on blanks and duplicates will be reported
with the appropriate field sample data. The number of these samples, when required, and their
use was described in Section 5.0.
The equipment blank provides a check on possible sources of sample contamination. The
equipment blanks should be collected in the worst-case scenario. The reason for performing
equipment blanks in the most impacted area is to attempt to simulate a worst-case scenario
regarding contributions from site condition or from improperly cleaned sampling equipment to
sample contamination. One equipment blank will be for this project. Equipment blanks should
be handled, transported, and analyzed in the same manner as the samples with which they are
associated.
The equipment blank water must be maintained at 4 (2) C following collection and during
shipment. Holding times for individual parameters are dictated by the specific analytical method
being used. The holding-time clock begins at the time of sample collection of the equipment
blank.
Trip blanks are used to check for sample contamination introduced by the sample containers, by
the sampling equipment, or by the sampling environment. Trip blanks travel to the site with the
empty sample bottles and return from the site with the collected samples in an effort to simulate
sample handling conditions. Trip blanks are collected in association with samples that are to be
analyzed for volatile organic compounds. Potential sources of sample contamination are from
the laboratory-grade reagent water, sample containers, field or laboratory ambient air, laboratory
reagents, or cross contamination during shipping, handling, preparation or analysis. A trip blank
should accompany VOC samples for each sampling event.
The trip blank water must be maintained at 4 (2) C through sample collection activities and
during shipment. Holding times for individual parameters are dictated by the specific analytical
method being used. The holding-time clock begins at the time of sample collection of the oldest
sample in the sampling container.
The QC check frequencies and requirements specified in the following sections is a general
description only. The laboratory will follow the internal QC checks specified in its QAM for
each analysis type employed. However, these QC checks must meet, at a minimum, the
requirements specified in the respective U.S. EPA analytical methods.
The following internal laboratory QC checks are performed for most analyses, whenever
applicable, to ensure the measurement systems are under control:
Initial and continuing calibrations;
Preparation/method blanks;
Matrix spike and matrix spike duplicate or matrix spike and laboratory duplicate analysis,
as appropriate;
Surrogate spike standard performance evaluation (for organic analyses only); and
Calibration check compounds and reagent blanks (for organic analyses only).
Additional internal laboratory QC checks are typically performed for most analyses, as required
by the associated analytical method. Only the most common QC checks are generally described
below.
9.2.1 INITIAL AND CONTINUING CALIBRATION
Each measurement system must be calibrated immediately prior to use and be shown to maintain
the calibration throughout the course of the analysis. For the organic parameter methods, all
target compounds will be checked during initial and continuing calibrations. Calibration
procedures and frequencies is discussed for the various analysis types in the laboratory QAMs.
An initial calibration will be performed prior to WSC sample analyses. Continuing calibrations
will be typically analyzed at a minimum frequency of one every ten samples. For CLP GC/MS
analysis, calibration checks are only required once every 12 hours of analysis.
A preparation or method blank is run with each batch of samples received for analysis.
Compound or analyte responses observed in the blank at levels above the reportable detection
limit are reviewed for possible laboratory contamination. If high blank values are observed,
laboratory glassware and reagents may need to be checked for contamination and the analysis of
future samples halted until the system can be brought under control. A high blank value is
typically defined as a value greater than the method detection limit. A preparation and/or method
blank will be prepared at a frequency of one per 20 samples or one per day, whichever is greater.
For all analyses where matrix spiking is possible, 1 in 20 samples is analyzed as matrix spikes
and matrix spike duplicates or 1 in 20 samples is analyzed as matrix spikes and duplicates. Field
personnel must provide additional volume for the laboratory to complete a MS/MSD. The
percent recovery for spiked samples is calculated using the equations given in Section 12.0 and
compared to the accuracy criteria specified in the QAM for the associated analytical method.
The relative percent difference of replicate spikes or replicate analytical results are calculated
using the equations given in Section 12.0 and compared to the precision criteria specified in the
laboratory QAMs (Appendix QAPP-1 and following) for the associated analytical method.
Surrogate standards are defined as nonpriority pollutant compounds used to monitor the percent
recovery efficiencies of the analytical procedures on a sample-by-sample basis. Surrogate
standard determinations are performed on all samples and blanks for organic analyses. All
samples are fortified with surrogate spiking compounds before purging or extraction to monitor
the preparation and analysis of samples.
Surrogate compounds and recovery levels for the associated analyses are presented in the
laboratory QAM (surrogate recovery limits are method- and media-specific and are either
specified in the method or are calculated annually by the analytical laboratory as described in the
analytical method). When the surrogate recovery level is outside of the control limits on the
initial analysis, the laboratory must take the following actions for all organic analyses for
p
samples:
Check calculations to assure there are no errors, check internal standard and surrogate
spiking solutions for degradation or contamination and check instrument performance;
and
Recalculate or reinject/repurge the sample or re-extract and reanalyze the sample.
These calibration check compounds and reagent blanks are analyzed periodically throughout the
course of the analysis, depending on the required analysis. The exact frequencies and methods of
use are presented in the laboratory QAM.
Two types of audit procedures may be conducted during any environmental investigation:
performance audits and system audits. These audits may be performed on the laboratory as well
as field activities. A description of the laboratory's specific guidance for Performance and
System Audits will be presented in laboratory QAMs. General procedures for laboratory
performance and system audits are presented below.
Laboratory performance audits are typically conducted by the Laboratory QA Officer on a regular
basis. Each laboratory analyst is given a performance evaluation sample containing analytes for
the parameters which he/she usually performs. These audit samples are used to identify
problems in sample preparation or analysis techniques or methodologies which could lead to
future analytical problems.
Additionally, the laboratory performance audits include verification of each analyst's record
keeping, proper use and understanding of procedures, and performance documentation.
Corrective action will be taken for any deficiencies noted during the audit.
Laboratory system audits are typically conducted by the Laboratory QA Officer. These audits are
used to ensure that all aspects of the Laboratory's QAM are operative. This involves a thorough
review of all laboratory methods performed and documentation to confirm that work is
performed according to project specifications.
In some cases, outside certification agencies conduct performance and system audits to verify
contract compliance or the laboratories' ability to meet certification requirements on methods of
analysis and documentation. Results of these outside certification audits may be reviewed at any
time as a check on the laboratorys internal auditing procedures.
The following discussion describes the procedures that will be employed to evaluate the
precision, accuracy, and completeness of the generated data.
Precision is a measure of agreement among individual measurements of the same property under
prescribed similar conditions. Precision is assessed by calculating the relative percent difference
(RPD) of replicate spike samples or replicate sample analyses according to, the following
equation:
RPD
=
(R1 + R2)/2
R1 - R2
x 100
R2 = result 2
where
R1 = result 1
Accuracy is a measure of the closeness of an individual measurement to the true value. Accuracy
is measured by calculating the percent recovery (%R) of known levels of spike compounds as
follows:
concentration of spike sample - concentration of unspiked
sample
%R = _____________________________________________________ x 100
concentration of spike added
Completeness is a measure of the amount of valid data obtained from a measurement system,
expressed as a percentage of the number of valid measurements that should have been collected.
As is specified in Section 4.2, more than one completeness check can be evaluated. It is
calculated as follows:
number of valid samples reported
_______________________________
Completeness (%) =
total number of samples analyzed
100
Quality control charts can be prepared after every 20 analytical determinations to graphically
evaluate precision and accuracy criteria. The charts are prepared by calculating the mean value
of the determinations and setting control limits at + 3 standard deviations from that mean. The
following equations are used:
The control limits should be within acceptance limits or ranges presented in the as yet unselected
laboratory's QAM. If the values are found to be outside these limits or ranges, the measurement
system is examined to determine if possible problems exist.
Periodic preventive maintenance is required for equipment whose performance can affect results.
Instrument manuals are kept on file for reference if equipment needs repair. Troubleshooting
sections of manuals are often useful in assisting personnel in performing maintenance tasks.
Field sampling personnel will be responsible for preventive maintenance of all field instruments.
The field sampling personnel will protect the instruments by placing them in portable boxes
and/or protective cases.
All field equipment will be subject to a routine maintenance program, prior to and after each use.
The routine maintenance program for each piece of equipment will be in accordance with the
manufacturer's operations and maintenance manual. All equipment will be cleaned and checked
for integrity before and after each use. Necessary repairs will be performed immediately after
any defects are observed, and before the item of equipment is used again.
Equipment parts with a limited life (such as batteries, membranes and some electronic
components) will be periodically checked and replaced or recharged as necessary according to
the manufacturer's specifications.
Preventive maintenance is important since it provides for a longer useful life of the equipment
and helps to ensure a successful field sampling and testing program. Each piece of field
equipment will have its own log sheet which contains the equipment identification and the type
of maintenance performed. Since most equipment is used on an irregular basis, all equipment
will be properly stored when not in use.
All major laboratory instruments should normally be under service contract so that trained
professionals are available on call to minimize instrument downtime. Other preventive
maintenance schedules and/or procedures for laboratory equipment is presented in the laboratory
QAMs (Appendix QAPP-1 and following).
Corrective action procedures are divided into two subgroups: methods corrective action and
systems corrective action. These corrective actions are implemented whenever system or
performance audits note deficiencies or when QC procedures indicate a potential analytical
problem. The laboratory guidance on Corrective Action procedures is presented in the laboratory
QAMs.
This QAPP provides a documentable mechanism for the assurance of quality work performed at
for the characterization study. Audit reports will be provided by the Laboratory Director (or
his/her designee) as a means of tracking program performance, as applicable, or if needed.
Additionally, periodic assessments of measurement data accuracy, precision, and completeness
and significant QA/QC problems will be performed and reported to laboratory and/or project
management, if needed.
Field QA reports will not be necessary considering the expected size and length of any individual
sample collection activities. Any problems noted during sampling will be immediately
communicated to GTI, so GTI can take whatever corrective actions necessary.
Upon completion of the project-specific Work Plans, a final QA/QC report will be issued,
assessing the overall degree of project conformance to specifications and the impact of any nonconformances that may affect management decisions.
The final storage location of the files will be maintained at GTIs office in Chicago. The files
will be maintained for a period of at least three years.
Appendix C
Tabulated Data Obtained from Locations A - S
Key to Abbreviations
g/l
Micrograms per liter.
ND
Method blank contamination.

The associated method blank
contains the target analyte at a
reportable level.
Estimated result. Result

concentration exceeds the
calibration range.
MDL
Estimated result. Result

concentration exceeds the
calibration range.
RL
48
Non-detect. Result is less than

the method detection limit.
Result was measured against
nearest internal standard
assuming a response factor of 1.
Method detection limit.
Reporting limit.
PARAMETER
Conventional Analyses
Acidity
Amenable cyanide
Ammonia Nitrogen
Bromide
Chemical Oxygen Demand (COD)
Chloride
Fluoride
Hardness, as CaCO3
Nitrate as N
Nitrate-Nitrite
Nitrite as N
Oil & Grease (HEM)
Sulfate
TOC
Total Alkalinity
Total phosphorus
Turbidity
Cyanide, Total
Total Sulfide
pH
Sulfite
MBAS (mol.wt 320)
Total and Dissolved Metals
Aluminum
Aluminum-DISS
Antimony
Antimony-DISS
Arsenic
Arsenic-DISS
Barium
Barium-DISS
Beryllium
Beryllium-DISS
Boron
Boron-DISS
Cadmium
Cadmium-DISS
Calcium
Calcium-DISS
Chromium
Chromium-DISS
Cobalt
Cobalt-DISS
Copper
Copper-DISS
Iron
Iron-DISS
Lead
Lead-DISS
Lithium
Lithium-DISS
Magnesium
Magnesium-DISS
Manganese
Manganese-DISS
Molybdenum
Molybdenum-DISS
Nickel
Nickel-DISS
Potassium
Potassium-DISS
Selenium
Selenium-DISS
Silver
Silver-DISS
Location A
Lewis County, WV
Day 5
Day 0
Day 1
2/7/2009
2/8/2009
SM20 2310B (4a)

SM18 4500-CN E
MCAWW 350.1
SM18 5210 B
MCAWW 300.0A
MCAWW 410.4
MCAWW 300.0A
SM20 5310B
MCAWW 300.0A
SM20 2340C
MCAWW 300.0A
MCAWW 353.2
MCAWW 300.0A
CFR136A 1664A HEM
MCAWW 120.1
MCAWW 300.0A
SM20 5310B
SM18 2320 B
SM18 2540 C
MCAWW 351.3
MCAWW 365.2
SM20 2540D
MCAWW 180.1
SW846 9012A
SW846 9030B/9034
SW846 9040
SW846 9066
SM4500-SO3 B
SM5540 C
5
0.01
3.6
794
0.2
3120
74.6
247
0.05
80
0.45
1
0.059
NA
498
51.5
350
76.7
990
39.2
0.15
190
321
10
2.4
7.2
0.051
NA
NA
5
0.01
19.6
353
82.9
1670
9510
253
0.5
3600
0.5
0.36
5
4.8
31900
46.3
260
308
15400
56
0.04
82
13.1
10
1.6
7.2
0.027
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
358
154
10
10
10
10
276
104
4
4
43.8
49.6
5
5
21100
20200
5
5
50
50
39.1
24.5
926
362
12.1
7.6
40.4
44.5
3690
3500
91
73.3
1.2
4.8
9.5
2.6
2300
2590
3.2
3
5
5
UNITS
PQL
US EPA Method
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
umhos/cm
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
NTU
ug/L
mg/L
No Units
mg/L
mg/L
mg/L
5
0.01
0.1
2
1
10
1
-1
5
0.05
0.1
0.05
5
-1
1
5
10
3
0.1
4
-10
3
-0.01
1
0.05
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
200
200
10
10
10
10
200
200
4
4
2000
2000
5
5
5000
5000
5
5
500
500
25
25
100
100
3
3
500
500
5000
5000
150
150
400
400
40
40
5000
5000
5
5
5
5
U
U
J
U
J
J
U
J
J
J
U
B
NA
NA
J
BJ
U
U
U
U
B
U
U
B
B
U
U
U
U
U
U
B
B
B
B
B
BJ
B
B
B
B
B
B
B
U
U
223
47.7
17.6
18.3
13.3
12.8
70200
30200
4
4
8720
9000
0.21
5
828000
827000
21.1
6.6
50
50
9.6
25
2680
1830
1.7
3
9530
9480
72800
75300
697
704
35.6
34.8
68.3
61.5
183000
188000
5
5
5
5
2/11/2009
U
U
J
5
0.01
67.1
374
274
9090
J
29800
J
114
GU
2.5
12000
GU
2.5
J
0.33
GU
29.3
U
4.8
J
137000
J
39.6
110
J
149
54800
76.2
B
0.074
71
2.3
U
10
B
3.2
NA
0.011
NA
NA
J
U
U
J
J
B
U
J
J
U
U
B
U
J
B
U
JE
JE
J
BJ
BJ
E
E
U
U
U
U
125
166
10
9.5
17.4
21.5
157000
163000
20
20
33700
34200
25
25
3400000
3460000
25
25
250
250
125
125
10800
10300
15
15
24000
23300
314000
319000
960
991
30.6
13.3
33.2
29.5
921000
934000
25
25
25
25
U
U
J
J
J
GU
GU
J
U
J
BJG
J
Day 14
Day 90
2/20/2009
5/8/2009
5
0.01
121
2.8
604
3280
67100
65
5
26000
5
0.18
17.6
5
248000
20.5
38.7
93.3
105000
124
0.1
197
20.1
10
3
6.5
0.011
U
U
J
GU
GU
J
U
J
BJ
J
J
U
U
NA
NA
BJ
BJ
B
B
B
B
U
U
J
U
U
U
U
U
U
U
U
U
U
E
B
B
B
B
E
U
U
U
U
925
0.01
293
12.5
1260
28300
125000
5960
2.5
59000
2.5
0.1
2.5
62.6
385000
50
5680
26.2
216000
202
0.1
201
175
10
2.4
5.7
0.23
GU
GU
U
GU
J
GU
J
U
B
NA
NA
174
133
50
10.2
24.8
19.4
569000
583000
20
0.9
56900
58000
1.9
1.2
7820000
8070000
31
10.7
1250
1250
23
125
41200
40600
15
15
51800
51600
725000
738000
1760
1760
18.8
22.6
33.3
21.2
1880000
1940000
25
25
25
25
BJ
BJ
U
B
B
B
J
U
BJ
J
B
B
J
J
B
U
U
B
U
J
U
U
J
BJ
B
B
B
U
U
U
U
370
348
100
100
46.2
106
639000
787000
40
40
67300
85200
2.5
2.5
11400000
14400000
17.7
7.6
2500
2500
51.5
51.9
103000
102000
970
647
67100
84900
1090000
1330000
2130
2590
17
400
2000
2000
1770000
2190000
50
50
50
50
B
B
U
U
B
J
U
U
J
J
B
B
J
J
B
B
U
U
B
B
B
U
U
U
U
U
U
U
PARAMETER
Sodium
Sodium-DISS
Strontium
Strontium-DISS
Thallium
Thallium-DISS
Tin
Tin-DISS
Titanium
Titanium-DISS
Trivalent Chrom
Zinc
Zinc-DISS
Diss Hexavalent Cr-DISS
Hexavalent Chromium
Mercury
Mercury-DISS
1,1,1,2-Tetrachloroethane
1,1,1-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,1-Dichloropropene
1,2,3-Trichlorobenzene
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,2-Dibromo-3-chloropropane
1,2-Dibromoethane (EDB)
1,2-Dichlorobenzene
1,2-Dichloroethane
1,2-Dichloropropane
1,3-Dichlorobenzene
1,3-Dichloropropane
1,4-Dichlorobenzene
1,4-Dioxane
1-chloro-4-trifluoromethylbenzene
2,2-Dichloropropane
2-Butanone
2-Chloroethyl vinyl ether
2-Hexanone
4-Chlorotoluene
4-Methyl-2-pentanone (MIBK)
Acetone
Acrolein
Acrylonitrile
Benzene
Benzyl chloride
Bromobenzene
Bromoform
Bromomethane
Carbon disulfide
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
cis-1,2-Dichloroethene
cis-1,3-Dichloropropene
Dibromomethane
Ethylbenzene
Isopropylbenzene
Methyl tert-butyl ether (MTBE)
Methylene chloride
Naphthalene
n-Butylbenzene
n-Propylbenzene
p-Isopropyltoluene
sec-Butylbenzene
Styrene
UNITS
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
mg/L
mg/L
ug/L
ug/L
PQL
5000
5000
50
50
10
10
1000
1000
500
500
50
20
20
0.01
0.01
0.2
0.2
US EPA Method
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 7196A
SW846 7196A
SW846 7470A
SW846 7470A
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
1000
-5
5
10
5
5
5
20
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
Location A
Lewis County, WV
Day 5
Day 0
Day 1
2/7/2009
88400
96100
726 E
711 E
19.8 B
23.6 B
6.3 B
5.2 B
4B
50 U
5U
36.6
35.5
0.01 U
0.02 U
0.036 B J
0.037 B J
2/8/2009
4490000 J E
4750000
137000 J E
144000 J E
4.9 B J
6.2 B J
3.8 B
100 U
50 U
50 U
6.6
107
89.9
0.05 U
0.05 U
0.042 B J
0.08 B J
2/11/2009
15000000
15000000
872000 J
870000 J E
50 U
28.5 B J
500 U
500 U
250 U
250 U
25 U
119
115 J
0.1 G U
0.1 G U
0.027 B
0.032 B J
2/20/2009
31500000
32600000
2080000
2080000 J
50 U
17.4 B
500 U
16.8 B
250 U
250 U
25 U
179 J
160 J
0.1 G U
0.1 G U
0.029 B J
0.028 B J
5/8/2009
39700000
49300000
3480000
4370000 J
500 U
500 U
1000 U
1000 U
190 B J
196 B J
50 U
372 J
382 J
0.5 G U
0.5 G U
0.2 U
0.2 U
5
5
5
5
5
5
5
5
5
5
4.7
5
5
5
5
5
3.1
5
5
5
1000
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
J
U
U
U
U
5
5
5
5
5
5
5
5
5
5
1.1
5
5
5
5
5
5
5
5
5
1000
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
10
10
10
10
10
10
10
10
10
10
1.9
10
10
10
10
10
10
10
10
10
2000
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
5
5
5
5
5
5
5
5
5
5
0.82
5
5
5
5
5
5
5
5
5
1000
5
5
10
5
5
5
17
100
100
7.7
5
5
5
5
5
5
5
5
5
28
5
5
5
5
5
5
0.98
5
5
1.6
2.1
2
5
2.1
5
5
U
U
U
U
U
U
J
U
U
5
2
10
5
5
5
76
100
100
8
5
5
5
5
5
5
5
5
5
2.2
5
5
5
5
5
5
5
5
5
1.4
0.51
5
5
5
5
5
U
J
U
U
U
U
10
10
20
10
10
10
40
200
200
8.5
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
5
5
5
5
5
5
5
5
5
5
16
5
5
5
5
5
6
5
5
5
1000
NA
5
5
10
5
5
5
20
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
2.3
5
5
5
2.2
5
2
5
3.2
5
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
NA
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
J
U
J
U
J
U
NA
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
J
J
J
U
J
U
U
Day 14
Day 90
NA
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
J
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
NA
5
5
10
5
5
5
15
100
100
1.5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
U
U
U
U
U
U
JB
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
PARAMETER
tert-butyl acetate
tert-Butylbenzene
Tetrachloroethene
tetrahydrofuran
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Vinyl acetate
Vinyl chloride
Xylenes (total)
Semi-Volatile Organics
1,2,4,5-Tetrachlorobenzene
1,2-Diphenylhydrazine
1,3-Dinitrobenzene
1,4-Naphthoquinone
1-Naphthylamine
2,3,4,6-Tetrachlorophenol
2,3,7,8-TCDD
2,4,5-Trichlorophenol
2,4-Dimethylphenol
2,4-Dinitrophenol
2,4-Dinitrotoluene
2,6-Dichlorophenol
2,6-Dinitrotoluene
2-Acetylaminofluorene
2-Chloronaphthalene
2-Chlorophenol
2-Methylnaphthalene
2-Methylphenol
2-Naphthylamine
2-Nitroaniline
2-Nitrophenol
2-Picoline
3,3'-Dichlorobenzidine
3-Methylcholanthrene
3-Methylphenol & 4-Methylphenol
3-Nitroaniline
4,6-Dinitro-2-methylphenol
4-Aminobiphenyl
4-Bromophenyl phenyl ether
4-Chloro-3-methylphenol
4-Chloroaniline
4-Chlorophenyl phenyl ether
4-Nitroaniline
4-Nitrophenol
5-Nitro-o-toluidine
7,12-Dimethylbenz(a)anthracene
Acenaphthene
Acenaphthylene
Acetophenone
Aniline
Aramite
Benzidine
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(ghi)perylene
Benzo(k)fluoranthene
Benzyl alcohol
bis(2-Chloroethoxy)methane
bis(2-Chloroethyl) ether
bis(2-Chloroisopropyl) ether
bis(2-Ethylhexyl) phthalate
Chlorobenzilate
Chrysene
Diallate
Dibenz(a,h)anthracene
Dibenzofuran
Diethyl phthalate
Dimethoate
Dimethyl phthalate
Di-n-butyl phthalate
Location A
Lewis County, WV
Day 5
Day 0
Day 1
2/8/2009
UNITS
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
PQL
-5
5
-5
5
5
5
5
5
5
15
US EPA Method
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
2/7/2009
NA
5U
5U
NA
3.1 J
5U
5U
5U
5U
5U
5U
18
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
10
2
10
10
10
10
-10
10
10
40
10
2
10
10
2
10
2
10
10
50
10
10
10
10
10
50
50
10
10
10
10
10
50
50
100
10
2
2
10
10
10
200
10
5
2
2
2
10
10
2
2
10
10
10
2
10
2
10
10
10
10
10
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
9.7
1.9
9.7
9.7
9.7
9.7
NA
9.7
9.7
9.7
48
9.7
2
9.7
9.7
1.9
9.7
1.9
9.7
9.7
48
9.7
9.7
9.7
9.7
9.7
48
48
9.7
9.7
9.7
9.7
9.7
48
48
97
9.7
1.9
1.9
9.7
9.7
9.7
190
1.9
1.9
1.9
1.9
1.9
9.7
9.7
1.9
1.9
9.7
9.7
9.7
1.9
9.7
1.9
9.7
9.7
9.7
9.7
9.7
NA
NA
5U
5U
NA
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Day 14
Day 90
2/20/2009
5/8/2009
NA
5U
5U
NA
NA
10 U
10 U
NA
5U
5U
NA
5.1
5
5
5
5
5
5
10
U
U
U
U
U
U
J
2
5
5
5
5
5
5
15
J
U
U
U
U
U
U
U
3.4
10
10
10
10
10
10
30
J
U
U
U
U
U
U
U
1.6
5
5
5
5
5
5
15
J
U
U
U
U
U
U
U
97
19
97
97
97
97
U
U
U
U
U
U
190
38
190
190
190
190
U
U
U
U
U
U
96
19
96
96
96
96
U
U
U
U
U
U
95
19
95
95
95
95
U
U
U
U
U
U
97
97
97
480
97
19
97
97
19
97
19
97
97
480
97
97
97
97
97
480
480
97
97
97
97
97
480
480
970
97
19
19
97
97
97
1900
19
19
19
19
19
97
97
19
19
97
97
97
19
97
19
97
97
97
97
97
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
190
190
190
940
190
38
190
190
38
190
38
190
190
940
190
190
190
190
190
940
940
190
190
190
190
190
940
940
1900
190
38
38
190
190
190
3800
38
38
38
38
38
190
190
38
38
190
190
190
38
190
38
190
35
190
190
190
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
96
96
96
480
96
19
96
96
19
96
19
96
96
480
96
96
96
96
96
480
480
96
96
96
96
96
480
480
960
96
19
19
96
96
96
1900
19
19
19
19
19
96
96
19
19
96
96
96
19
96
19
96
96
96
96
96
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
95
95
95
480
95
19
95
95
19
95
19
95
95
480
95
95
95
95
95
480
480
95
95
95
95
95
480
480
950
95
19
19
95
95
95
1900
19
19
19
19
19
95
95
19
19
95
95
95
19
95
19
95
95
95
95
95
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
NA
U
U
U
U
U
2/11/2009
NA
NA
NA
Day 1
Day 0
PARAMETER
Di-n-octyl phthalate
Dinoseb
Diphenylamine
Disulfoton
Fluoranthene
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hexachloroethane
Hexachloropropene
Indeno(1,2,3-cd)pyrene
Isodrin
Isophorone
Isosafrole
Nitrobenzene
N-Nitrosodiethylamine
N-Nitrosodimethylamine
N-Nitrosodi-n-butylamine
N-Nitrosodi-n-propylamine
N-Nitrosodiphenylamine
N-Nitrosomethylethylamine
N-Nitrosomorpholine
N-Nitrosopiperidine
N-Nitrosopyrrolidine
O,O,O-Triethyl phosphorothioate
o-Toluidine
Parathion
p-Dimethylaminoazobenzene
Pentachlorobenzene
Pentachloroethane
Pentachlorophenol
Phenanthrene
Phenol
Phorate
Pronamide
Pyrene
Pyridine
Safrole
Thionazin
UNITS
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
PQL
10
10
2
10
10
2
2
0.05
2
2
10
10
2
10
10
10
10
2
10
10
10
2
2
10
10
10
10
10
10
10
10
10
20
10
10
2
2
10
10
2
10
10
10
10
US EPA Method
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
Organochlorine Pesticides
4,4'-DDD
4,4'-DDE
4,4'-DDT
Aldrin
alpha-BHC
beta-BHC
Chlordane (technical)
delta-BHC
Dieldrin
Endosulfan I
Endosulfan II
Endosulfan sulfate
Endrin
Endrin aldehyde
Endrin ketone
gamma-BHC (Lindane)
Heptachlor
Heptachlor epoxide
Methoxychlor
Toxaphene
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.1
2
PCBs
Aroclor 1016
Aroclor 1221
Aroclor 1232
Aroclor 1242
Aroclor 1248
Aroclor 1254
Aroclor 1260
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
0.4
0.4
0.4
0.4
0.4
0.4
0.4
Location A
Lewis County, WV
Day 5
Day 14
Day 90
2/7/2009
9.7 U
9.7 U
1.9 U
9.7 U
9.7 U
1.9 U
1.9 U
1.9 U
1.9 U
9.7 U
9.7 U
9.7 U
1.9 U
9.7 U
9.7 U
9.7 U
9.7 U
1.9 U
9.7 U
9.7 U
9.7 U
1.9 U
1.9 U
9.7 U
9.7 U
9.7 U
9.7 U
9.7 U
9.7 U
9.7 U
9.7 U
9.7 U
19 U
9.7 U
9.7 U
2.7
1.9 U
9.7 U
9.7 U
0.54 J B
86
9.7 U
0.97 U
NA
NA
2/11/2009
190 U
190 U
38 U
190 U
190 U
38 U
38 U
38 U
38 U
190 U
190 U
190 U
38 U
190 U
190 U
190 U
190 U
38 U
190 U
190 U
190 U
38 U
38 U
190 U
190 U
190 U
190 U
190 U
190 U
190 U
190 U
190 U
380 U
190 U
190 U
38 U
38 U
190 U
190 U
38 U
1800
190 U
190 U
NA
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
0.048
0.048
0.048
0.048
0.048
0.048
0.48
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.096
1.9
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.048
0.048
0.048
0.048
0.048
0.048
0.48
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.095
1.9
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
0.048
0.048
0.048
0.048
0.048
0.048
0.48
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.095
1.9
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
SW846 8082
SW846 8082
SW846 8082
SW846 8082
SW846 8082
SW846 8082
SW846 8082
0.38
0.38
0.38
0.38
0.38
0.38
0.38
U
U
U
U
U
U
U
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.38
0.38
0.38
0.38
0.38
0.38
0.38
U
U
U
U
U
U
U
0.41
0.41
0.41
0.41
0.41
0.41
0.41
U
U
U
U
U
U
U
2/8/2009
97 U
97 U
19 U
97 U
97 U
19 U
19 U
19 U
19 U
97 U
97 U
97 U
19 U
97 U
97 U
97 U
97 U
19 U
97 U
97 U
97 U
19 U
19 U
97 U
97 U
97 U
97 U
97 U
97 U
97 U
97 U
97 U
190 U
97 U
97 U
19 U
19 U
97 U
97 U
19 U
2600
97 U
97 U
2/20/2009
96 U
96 U
19 U
96 U
96 U
19 U
19 U
19 U
19 U
96 U
96 U
96 U
19 U
96 U
96 U
96 U
96 U
19 U
96 U
96 U
96 U
19 U
19 U
96 U
96 U
96 U
96 U
96 U
96 U
96 U
96 U
96 U
190 U
96 U
96 U
19 U
19 U
96 U
96 U
19 U
860
96 U
96 U
NA
5/8/2009
95 U
95 U
19 U
95 U
95 U
19 U
19 U
19 U
19 U
95 U
95 U
95 U
19 U
95 U
95 U
95 U
95 U
19 U
95 U
95 U
95 U
19 U
19 U
95 U
95 U
95 U
95 U
95 U
95 U
95 U
95 U
95 U
190 U
95 U
95 U
19 U
19 U
95 U
95 U
19 U
490
95 U
95 U
NA
PARAMETER
Day 0
Day 1
2/7/2009
2/8/2009
Location A
Lewis County, WV
Day 5
2/11/2009
Day 14
Day 90
2/20/2009
5/8/2009
UNITS
PQL
US EPA Method
Ethyl parathion
ug/L
0.4
SW846 8141A
0.97 U
NA
NA
Alcohols
2-Propanol
Butyl alcohol
Ethanol
Methanol
n-Propanol
mg/L
mg/L
mg/L
mg/L
mg/L
10
10
10
10
10
SW846 8015
SW846 8015
SW846 8015
SW846 8015
SW846 8015
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
Glycols
Ethylene Glycol
Propylene glycol
mg/L
mg/L
50
50
SW846 8015
SW846 8015
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
Acids
Acetic Acid
Butyric Acid
Propionic Acid
Volatile Acids
mg/L
mg/L
mg/L
mg/L
10
10
10
10
SW846 8015
SW846 8015
SW846 8015
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.98 U
0.97 U
PARAMETER
Acidity
Amenable cyanide
Ammonia Nitrogen
Bromide
Chloride
Fluoride
Hardness, as CaCO3
Nitrate as N
Nitrate-Nitrite
Nitrite as N
Oil & Grease (HEM)
Sulfate
TOC
Total Alkalinity
Total phosphorus
Turbidity
Cyanide, Total
Total Sulfide
pH
Sulfite
MBAS (mol.wt 320)
Aluminum
Aluminum-DISS
Antimony
Antimony-DISS
Arsenic
Arsenic-DISS
Barium
Barium-DISS
Beryllium
Beryllium-DISS
Boron
Boron-DISS
Cadmium
Cadmium-DISS
Calcium
Calcium-DISS
Chromium
Chromium-DISS
Cobalt
Cobalt-DISS
Copper
Copper-DISS
Iron
Iron-DISS
Lead
Lead-DISS
Lithium
Lithium-DISS
Magnesium
Magnesium-DISS
Manganese
Manganese-DISS
Molybdenum
Molybdenum-DISS
Nickel
Nickel-DISS
Potassium
Potassium-DISS
Selenium
Selenium-DISS
Silver
Silver-DISS
UNITS
PQL
US EPA Method
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
umhos/cm
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
NTU
ug/L
mg/L
No Units
mg/L
mg/L
mg/L
5
0.01
0.1
2
1
10
1
-1
5
0.05
0.1
0.05
5
-1
1
5
10
3
0.1
4
-10
3
-0.01
1
0.05
SM20 2310B (4a)

SM18 4500-CN E
MCAWW 350.1
SM18 5210 B
MCAWW 300.0A
MCAWW 410.4
MCAWW 300.0A
SM20 5310B
MCAWW 300.0A
SM20 2340C
MCAWW 300.0A
MCAWW 353.2
MCAWW 300.0A
CFR136A 1664A HEM
MCAWW 120.1
MCAWW 300.0A
SM20 5310B
SM18 2320 B
SM18 2540 C
MCAWW 351.3
MCAWW 365.2
SM20 2540D
MCAWW 180.1
SW846 9012A
SW846 9030B/9034
SW846 9040
SW846 9066
SM4500-SO3 B
SM5540 C
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
200
200
10
10
10
10
200
200
4
4
2000
2000
5
5
5000
5000
5
5
500
500
25
25
100
100
3
3
500
500
5000
5000
150
150
400
400
40
40
5000
5000
5
5
5
5
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
Day 0
Day 1
1/26/2009
1/29/2009
5
0.01
9.3
2
107
1730
10700
153
0.25
9500
0.25
0.15
5
19.4
34600
198
168
121
27800
23
0.36
790
338
5.4
2.4
7.6
0.082
25.0
0.500
481
200
2.4
3
9.1
10
9810
11700
4
4
2140
2400
10.5
3.9
2990000
3260000
4.8
1.5
50
50
21
25
11600
441
111
6.9
14900
16400
235000
266000
3640
3930
8.9
5.4
10.4
6.6
229000
257000
5
5
0.82
1.6
U
U
J
U
J
J
GU
GU
GU
J
J
J
B
B
U
U
U
B
B
B
U
U
U
J
J
B
J
B
B
U
U
B
U
E
JE
JE
BJ
B
B
B
E
E
U
U
B
BJ
5
0.01
32
132
120
1340
10500
204
0.65
4700
0.25
0.27
5
5.7
48800
222
207
226
22400
51
0.19
81
130
10
3
7.8
0.064
5.20
0.0691
328
39.9
37.8
37.4
13.5
11.3
3570
4680
4
4
9260
9320
5
5
1370000
1390000
11.1
8.6
50
50
25
25
6030
4440
3.8
3
13900
14400
153000
154000
1060
1050
28.8
29.1
18.6
16.9
109000
110000
5
5
0.73
5
Location B
Washington, PA
Day 5
2/2/2009
U
U
J
J
J
GU
J
GU
J
J
J
U
U
J
U
U
J
J
U
U
J
J
U
U
U
U
U
E
JE
J
BJ
B
BJ
B
E
E
U
U
B
U
107
0.01
82.4
1950
544
6120
50000
50
1.2
26400
1.2
0.15
12.5
4.8
175000
106
50.6
97.6
87800
71.7
0.45
35.6
20.9
10
3
6.6
0.01
10.0
0.131
166
1000
18
12.2
50
50
21400
37300
20
20
14300
14800
25
25
7630000
8040000
7.5
7.2
250
250
125
125
20400
18900
15
15
49100
49300
817000
843000
4220
4360
9.6
27.6
11
8.6
300000
316000
25
25
2.8
25
U
J
J
GU
GU
J
GU
U
J
U
U
U
B
U
B
B
U
U
J
U
U
J
J
U
U
J
J
B
B
U
U
U
U
J
J
U
U
JE
J
BJ
BJ
B
B
E
U
U
B
U
Day 14
Day 90
2/10/2009
4/29/2009
106
0.01
107
149
849
4340
78600
36.9
1.2
43500
1.2
0.089
77.4
30.8
284000
60.1
34.2
53.2
112000
112
0.088
17
25.6
10
2.4
5.5
0.015
8.40
0.0857
1000
1000
9.2
12.6
12.6
10
74200
58200
2.2
20
16200
16100
1.4
25
12500000
12800000
8.4
25
250
250
125
125
54200
39800
15
15
73700
71400
1330000
1310000
7090
7000
6.8
10.6
7
200
415000
451000
25
25
5.5
25
U
J
J
J
GU
GU
BJ
J
J
J
U
B
U
U
B
B
B
B
J
JE
B
U
J
J
B
U
J
JE
B
U
U
U
U
U
U
U
J
JE
J
BJ
BJ
B
U
E
U
U
B
U
185
0.01
259
33.6
1380
36600
122000
15.4
2.5
85000
2.5
NA
2.5
14.7
440000
83.8
12.6
43.1
194000
136
0.1
150
116
10
3.2
6.1
0.039
30.8
0.138
811
536
100
100
114
151
133000
179000
40
40
13500
18600
7.7
8.6
18300000
23000000
20.9
17.5
2500
2500
27.2
250
69700
74300
68
150
88600
115000
1710000
2160000
8830
11300
400
400
2000
2000
335000
422000
44
64.7
50
10.4
J
GU
GU
GU
J
J
J
BJ
B
U
U
J
U
U
J
B
B
J
B
B
U
U
B
U
B
U
U
U
U
U
B
U
B
PARAMETER
Sodium
Sodium-DISS
Strontium
Strontium-DISS
Thallium
Thallium-DISS
Tin
Tin-DISS
Titanium
Titanium-DISS
Trivalent Chrom
Zinc
Zinc-DISS
Hexavalent Chromium
Mercury
Mercury-DISS
1,1-Dichloroethane
1,1-Dichloroethene
1,1-Dichloropropene
1,2-Dichlorobenzene
1,2-Dichloroethane
1,2-Dichloropropane
1,3-Dichlorobenzene
1,3-Dichloropropane
1,4-Dichlorobenzene
1,4-Dioxane
2,2-Dichloropropane
2-Butanone
2-Hexanone
4-Chlorotoluene
Acetone
Acrolein
Acrylonitrile
Benzene
Benzyl chloride
Bromobenzene
Bromoform
Bromomethane
Carbon disulfide
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
Dibromomethane
Ethylbenzene
Isopropylbenzene
Methylene chloride
Naphthalene
n-Butylbenzene
n-Propylbenzene
p-Isopropyltoluene
sec-Butylbenzene
Styrene
UNITS
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
mg/L
mg/L
ug/L
ug/L
PQL
5000
5000
50
50
10
10
1000
1000
500
500
50
20
20
0.01
0.01
0.2
0.2
US EPA Method
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 7196A
SW846 7196A
SW846 7470A
SW846 7470A
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
1000
-5
5
10
5
5
5
20
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
Day 0
Day 1
1/26/2009
6190000
6790000
439000
478000
6
7.1
6.9
9.4
50
50
4.8
117
51.9
0.01
0.05
0.55
0.054
1/29/2009
6370000
6310000
167000
166000
5.4
5.5
5.1
7.4
50
50
11.1
86.9
68.1
0.01
0.01
0.05
0.022
150
150
150
150
150
150
150
150
150
150
140
150
150
150
150
150
100
150
150
150
30000
NA
150
150
300
150
150
150
600
3000
3000
150
150
150
150
150
150
1500
150
150
150
150
150
150
150
150
150
150
19
150
150
150
24
150
150
150
84
150
E
JE
B
B
B
B
U
U
B
J
J
U
GU
J
BJ
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
J
U
U
U
J
U
25
25
25
25
25
25
25
25
25
25
82
25
25
25
25
25
33
25
25
25
5000
NA
25
25
50
25
25
25
100
500
500
240
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
14
3.2
25
25
18
25
25
25
25
25
Location B
Washington, PA
Day 5
E
JE
B
BJ
B
B
U
U
J
J
U
U
B
B
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
J
U
U
J
U
U
U
U
U
2/2/2009
22000000
22400000
1080000
1190000
50
50
500
500
250
250
5
84.9
120
0.042
0.01
0.023
0.037
120
120
120
120
120
120
120
120
120
120
110
120
120
120
120
120
120
120
120
120
25000
NA
120
120
250
120
120
120
500
2500
2500
1200
120
120
120
120
120
120
120
120
120
120
120
120
120
120
120
120
85
120
120
120
120
120
120
54
68
120
J
JE
J
U
U
U
U
U
U
U
BJ
U
B
B
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
J
J
U
Day 14
2/10/2009
32500000
31500000
1850000
1990000
50
50
500
500
250
250
8.4
66.8
62.2
0.05
0.05
0.049
0.028
50
50
50
50
50
50
50
50
50
50
74
50
50
50
50
50
65
50
50
50
10000
NA
50
50
100
50
50
50
200
1000
1000
420
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
42
50
50
50
50
50
50
22
50
50
Day 90
J
J
J
JE
U
U
U
U
U
U
B
B
GU
GU
BJ
BJ
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
J
U
U
4/29/2009
34200000
44600000
2520000
3350000
500
500
1000
1000
156
195
17.5
73.8
67.1
0.5
0.25
0.2
0.2
50
50
50
50
50
50
50
16
50
50
23
50
50
50
50
50
19
50
50
50
10000
NA
50
50
100
50
50
50
75
1000
1000
360
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
21
50
50
50
50
50
50
50
50
50
J
U
U
U
U
B
B
B
BJ
B
GU
GU
U
U
U
U
U
U
U
U
U
J
U
U
J
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
JB
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
PARAMETER
tert-butyl acetate
tert-Butylbenzene
Tetrachloroethene
tetrahydrofuran
Toluene
Trichloroethene
Vinyl acetate
Vinyl chloride
Xylenes (total)
1,3-Dinitrobenzene
1,4-Naphthoquinone
1-Naphthylamine
2,3,7,8-TCDD
2,4-Dimethylphenol
2,4-Dinitrophenol
2,4-Dinitrotoluene
2,6-Dichlorophenol
2,6-Dinitrotoluene
2-Chloronaphthalene
2-Chlorophenol
2-Methylnaphthalene
2-Methylphenol
2-Naphthylamine
2-Nitroaniline
2-Nitrophenol
2-Picoline
3-Nitroaniline
4-Aminobiphenyl
4-Chloroaniline
4-Nitroaniline
4-Nitrophenol
5-Nitro-o-toluidine
Acenaphthene
Acenaphthylene
Acetophenone
Aniline
Aramite
Benzidine
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(ghi)perylene
Benzyl alcohol
Chlorobenzilate
Chrysene
Diallate
Dibenzofuran
Diethyl phthalate
Dimethoate
Dimethyl phthalate
UNITS
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
PQL
-5
5
-5
5
5
5
5
5
5
15
US EPA Method
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
10
2
10
10
10
10
-10
10
10
40
10
2
10
10
2
10
2
10
10
50
10
10
10
10
10
50
50
10
10
10
10
10
50
50
100
10
2
2
10
10
10
200
10
5
2
2
2
10
10
2
2
10
10
10
2
10
2
10
10
10
10
10
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
Day 0
Day 1
1/26/2009
NA
150
150
NA
81
150
150
150
150
150
150
210
1/29/2009
NA
25
25
NA
340
25
25
25
25
25
25
180
190
38
190
190
190
190
NA
190
190
190
940
190
38
190
190
38
190
120
190
41
940
190
190
190
190
3.5
940
940
190
190
190
190
190
940
940
1900
190
38
38
190
190
190
3800
38
38
38
38
38
190
190
38
38
190
190
190
38
190
38
190
190
190
190
190
U
U
J
U
U
U
U
U
U
JB
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
95
19
95
95
95
95
NA
95
95
7.7
480
95
19
95
95
19
95
94
7.7
95
480
95
95
95
95
8.7
480
480
95
95
95
95
95
480
480
950
95
19
19
95
95
95
1900
19
19
19
19
19
95
95
19
19
95
95
95
19
95
19
95
95
95
95
95
Location B
Washington, PA
Day 5
U
U
U
U
U
U
U
U
B
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
J
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
2/2/2009
NA
120
120
NA
2300
120
120
120
120
120
120
1100
9.4
1.9
9.4
9.4
9.4
9.4
NA
9.4
9.4
9.4
47
9.4
1.9
9.4
9.4
1.9
9.4
1.9
9.8
9.4
47
9.4
9.4
9.4
9.4
14
47
47
9.4
9.4
9.4
9.4
9.4
47
47
94
9.4
1.9
0.75
9.4
9.4
9.4
190
1.4
1
1.1
1.1
1
9.4
9.4
1.9
1.9
1.8
9.4
9.4
1.2
9.4
3.2
9.4
1.5
9.4
9.4
1.8
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
JB
J
JB
J
JB
U
U
U
U
J
U
U
JB
U
U
J
U
U
J
Day 14
2/10/2009
NA
50
50
NA
820
50
50
50
50
50
50
520
9.5
1.9
9.5
9.5
9.5
9.5
NA
9.5
9.5
9.5
48
9.5
1.9
9.5
9.5
1.9
9.5
1.9
9.5
9.5
48
9.5
9.5
9.5
9.5
11
48
48
9.5
9.5
9.5
9.5
9.5
48
48
95
9.5
1.9
1.9
9.5
9.5
9.5
190
1.9
1.9
1.9
1.9
1.9
9.5
9.5
1.9
1.9
1.8
9.5
9.5
1.9
9.5
1.9
9.5
1.6
9.5
9.5
9.5
Day 90
U
U
U
U
U
U
U
U
B
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
JB
U
U
U
4/29/2009
NA
50
50
NA
660
50
50
50
50
50
50
300
9.5
1.9
9.5
9.5
9.5
9.5
NA
9.5
9.5
8.3
48
9.5
1.9
9.5
9.5
1.9
9.5
1.9
11
9.5
48
9.5
9.5
9.5
9.5
14
48
48
9.5
9.5
9.5
9.5
9.5
48
48
95
9.5
1.9
1.9
9.5
9.5
9.5
190
1.9
1.9
1.9
1.9
1.9
9.5
9.5
1.9
1.9
9.8
9.5
9.5
1.9
9.5
1.9
9.5
9.5
9.5
9.5
9.5
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
PARAMETER
Dinoseb
Diphenylamine
Disulfoton
Fluoranthene
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hexachloroethane
Hexachloropropene
Isodrin
Isophorone
Isosafrole
Nitrobenzene
N-Nitrosomorpholine
N-Nitrosopiperidine
o-Toluidine
Parathion
Pentachlorobenzene
Pentachloroethane
Pentachlorophenol
Phenanthrene
Phenol
Phorate
Pronamide
Pyrene
Pyridine
Safrole
Thionazin
Day 0
Day 1
1/26/2009
190
190
38
190
190
38
11
38
38
190
190
190
38
190
190
190
190
38
190
190
190
38
38
190
190
190
190
190
190
190
190
190
380
190
190
22
38
190
190
38
310
190
190
NA
1/29/2009
95
95
19
95
95
19
8.4
19
19
95
95
95
19
95
95
95
95
19
95
95
95
19
19
95
95
95
95
95
95
95
95
95
190
95
95
16
11
95
95
19
350
95
95
NA
Location B
Washington, PA
Day 5
Day 14
Day 90
UNITS
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
PQL
10
10
2
10
10
2
2
0.05
2
2
10
10
2
10
10
10
10
2
10
10
10
2
2
10
10
10
10
10
10
10
10
10
20
10
10
2
2
10
10
2
10
10
10
10
US EPA Method
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
4,4'-DDD
4,4'-DDE
4,4'-DDT
Aldrin
alpha-BHC
beta-BHC
delta-BHC
Dieldrin
Endosulfan I
Endosulfan II
Endosulfan sulfate
Endrin
Endrin aldehyde
Endrin ketone
gamma-BHC (Lindane)
Heptachlor
Heptachlor epoxide
Methoxychlor
Toxaphene
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.1
2
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
0.048
0.048
0.048
0.048
0.048
0.048
0.48
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.095
1.9
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.05
0.05
0.05
0.05
0.05
0.05
0.5
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.099
2
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
0.049
0.049
0.049
0.049
0.049
0.049
0.49
0.049
0.049
0.049
0.049
0.049
0.049
0.049
0.049
0.049
0.049
0.049
0.098
2
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
PCBs
Aroclor 1016
Aroclor 1221
Aroclor 1232
Aroclor 1242
Aroclor 1248
Aroclor 1254
Aroclor 1260
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
0.4
0.4
0.4
0.4
0.4
0.4
0.4
SW846 8082
SW846 8082
SW846 8082
SW846 8082
SW846 8082
SW846 8082
SW846 8082
0.38
0.38
0.38
0.38
0.38
0.38
0.38
U
U
U
U
U
U
U
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.4
0.4
0.4
0.4
0.4
0.4
0.4
U
U
U
U
U
U
U
0.39
0.39
0.39
0.39
0.39
0.39
0.39
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
J
U
U
U
U
U
2/2/2009
4.4
9.4
1.9
9.4
9.4
1.3
1.9
0.99
1.9
9.4
9.4
9.4
3.1
9.4
9.4
9.4
9.4
1.9
9.4
9.4
9.4
1.9
1.9
9.4
9.4
9.4
9.4
9.4
9.4
9.4
9.4
9.4
19
9.4
9.4
1.8
1.9
9.4
9.4
1.1
250
9.4
9.4
NA
J
U
U
U
U
JB
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
JB
U
U
2/10/2009
9.5
9.5
1.9
9.5
9.5
1.9
1.9
1.9
1.9
9.5
9.5
9.5
1.9
9.5
9.5
9.5
9.5
1.9
9.5
9.5
9.5
1.9
1.9
9.5
9.5
9.5
9.5
9.5
9.5
9.5
9.5
9.5
19
9.5
9.5
1.9
1.9
9.5
9.5
1.9
77
9.5
0.98
NA
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
4/29/2009
9.5
9.5
1.9
9.5
9.5
1.9
1.9
1.9
1.9
9.5
9.5
9.5
1.9
9.5
9.5
9.5
9.5
1.9
9.5
9.5
9.5
1.9
1.9
9.5
9.5
9.5
9.5
9.5
9.5
9.5
9.5
9.5
19
9.5
9.5
0.3
1.9
9.5
9.5
1.9
260
9.5
0.98
NA
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
PARAMETER
Location B
Washington, PA
Day 5
Day 0
Day 1
1/26/2009
1/29/2009
2/2/2009
NA
NA
UNITS
PQL
US EPA Method
Ethyl parathion
ug/L
0.4
SW846 8141A
0.96 U
Alcohols
2-Propanol
Butyl alcohol
Ethanol
Methanol
n-Propanol
mg/L
mg/L
mg/L
mg/L
mg/L
10
10
10
10
10
SW846 8015
SW846 8015
SW846 8015
SW846 8015
SW846 8015
4
4
4
88
4
Glycols
Ethylene Glycol
Propylene glycol
mg/L
mg/L
50
50
SW846 8015
SW846 8015
20.1
10 U
20.6
10 U
20.8
10 U
Acids
Acetic Acid
Butyric Acid
Propionic Acid
Volatile Acids
mg/L
mg/L
mg/L
mg/L
10
10
10
10
SW846 8015
SW846 8015
SW846 8015
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
U
U
U
U
1
1
1
8
1
U
U
U
U
1
1
1
3.2
1
U
U
U
U
Day 14
Day 90
2/10/2009
4/29/2009
0.98 U
0.98 U
1
1
1
4.7
1
10
10
10
10
10
U
U
U
U
11
10 U
21.5
NA
NA
NA
UJ
UJ
UJ
UJ
UJ
100 UJ
100 UJ
10 UJ
10 UJ
10 UJ
6300
PARAMETER
Acidity
Amenable cyanide
Ammonia Nitrogen
Bromide
Chloride
Fluoride
Hardness, as CaCO3
Nitrate as N
Nitrate-Nitrite
Nitrite as N
Oil & Grease (HEM)
Sulfate
TOC
Total Alkalinity
Total phosphorus
Turbidity
Cyanide, Total
Total Sulfide
pH
Sulfite
MBAS (mol.wt 320)
Aluminum
Aluminum-DISS
Antimony
Antimony-DISS
Arsenic
Arsenic-DISS
Barium
Barium-DISS
Beryllium
Beryllium-DISS
Boron
Boron-DISS
Cadmium
Cadmium-DISS
Calcium
Calcium-DISS
Chromium
Chromium-DISS
Cobalt
Cobalt-DISS
Copper
Copper-DISS
Iron
Iron-DISS
Lead
Lead-DISS
Lithium
Lithium-DISS
Magnesium
Magnesium-DISS
Manganese
Manganese-DISS
Molybdenum
Molybdenum-DISS
Nickel
Nickel-DISS
Potassium
Potassium-DISS
Selenium
Selenium-DISS
Silver
Silver-DISS
UNITS
PQL
US EPA Method
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
umhos/cm
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
NTU
ug/L
mg/L
No Units
mg/L
mg/L
mg/L
5
0.01
0.1
2
1
10
1
-1
5
0.05
0.1
0.05
5
-1
1
5
10
3
0.1
4
-10
3
-0.01
1
0.05
SM20 2310B (4a)

SM18 4500-CN E
MCAWW 350.1
SM18 5210 B
MCAWW 300.0A
MCAWW 410.4
MCAWW 300.0A
SM20 5310B
MCAWW 300.0A
SM20 2340C
MCAWW 300.0A
MCAWW 353.2
MCAWW 300.0A
CFR136A 1664A HEM
MCAWW 120.1
MCAWW 300.0A
SM20 5310B
SM18 2320 B
SM18 2540 C
MCAWW 351.3
MCAWW 365.2
SM20 2540D
MCAWW 180.1
SW846 9012A
SW846 9030B/9034
SW846 9040
SW846 9066
SM4500-SO3 B
SM5540 C
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
200
200
10
10
10
10
200
200
4
4
2000
2000
5
5
5000
5000
5
5
500
500
25
25
100
100
3
3
500
500
5000
5000
150
150
400
400
40
40
5000
5000
5
5
5
5
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
Day 0
Day 1
Location C
Lewis County, WV
Day 5
2/11/2009
2/17/2009
2/20/2009
5
0.01
88.7
4.9
0.2
578
39.7
121
0.036
36
0.86
1.1
0.05
U
U
J
5
0.01
83.8
132
151
2980
15100
109
0.5
4800
0.98
0.88
3.1
13.9
64500
71.5
82.5
249
24700
132
8.5
522
164
38.5
3
7.2
0.0083
U
J
J
B
J
U
NA
1190
269
167
233
719
146
16
110
9.1
10
8
8.9
0.0079
J
J
J
BJ
NA
NA
U
NR U
J
J
GU
J
B
J
J
J
J
U
B
NA
NA
217
68.7
10
10
10
10
63.1
57.2
0.21
0.32
2430
3460
5
5
14300
16400
1.2
1.1
50
50
7.7
10.5
439
250
3.3
205
7.7
9.2
2830
3200
58.7
64.8
6.6
6.1
1.3
1
42600
45100
5
5
5
5
J
BJ
U
U
U
U
BJ
B
BJ
BJ
J
J
U
U
J
B
B
U
U
B
B
J
BJ
BJ
B
B
B
B
B
B
U
U
U
U
705
244
8.9
50
15.8
50
102000
15000
20
20
13100
14000
25
25
1220000
1330000
49.1
9.4
250
250
28.4
125
29000
10500
11.8
15
16400
18000
122000
134000
1040
1020
37.2
17.8
10.9
200
151000
171000
25
25
25
25
BJ
BJ
B
U
B
U
J
U
U
J
J
U
U
J
B
U
U
B
U
J
B
U
JE
J
B
B
B
U
U
U
U
U
5
0.01
98.9
63.7
331
5500
39800
46.9
5
15000
5
0.8
7.1
5
192000
36.4
32.9
147
61900
120
1.3
102
14
8.8
3
6.7
0.012
NA
NA
206
176
50
50
13.8
17.9
787000
755000
20
20
18800
18500
25
25
4390000
4340000
20.8
14.6
500
500
125
125
21200
18400
15
15
43700
41900
432000
426000
2440
2390
31.7
45.1
200
200
349000
343000
25
25
25
25
U
U
J
GU
GU
J
U
J
BJ
J
J
BJ
U
BJ
BJ
U
U
B
B
J
U
U
J
U
U
J
J
B
B
U
U
U
U
J
U
U
E
J
BJ
B
U
U
E
U
U
U
U
Day 14
Day 90
2/27/2009
5/15/09
5
0.01
149
39.8
637
4560
78100
22.8
1.2
33000
1.2
0.5
20.3
4.7
239000
22.3
14.4
71.4
110000
136
0.55
475
72
10
3
6.1
0.01
NA
NA
235
149
50
50
12
50
2160000
2130000
20
20
19900
19900
2.2
25
9520000
9500000
21.8
25
1250
1250
125
125
33200
13800
15
15
71800
71200
872000
875000
4430
4420
18.8
20.7
200
200
533000
533000
25
25
25
25
U
U
J
J
J
GU
GU
J
U
J
BJ
J
J
U
U
U
BJ
BJ
U
U
B
U
J
J
U
U
B
U
J
B
U
U
U
U
U
U
U
E
JE
B
B
U
U
E
E
U
U
U
U
220
0.01
182
242
1080
16200
107000
117
2.5
77000
2.5
0.029
2.5
5
384000
50
117
41.4
267000
134
0.1
446
277
42.6
3
5.9
0.01
NA
NA
1040
910
200
200
91.2
117
4220000
4370000
80
80
25300
25600
2.6
100
18600000
19400000
100
100
2500
2500
500
500
93000
59100
150
150
122000
125000
1790000
1830000
9770
9900
800
800
2000
2000
548000
564000
100
100
100
100
NR U
J
GU
GU
B
GU
U
J
GU
J
U
U
BJ
BJ
U
U
B
B
J
U
U
J
B
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Day 0
PARAMETER
Sodium
Sodium-DISS
Strontium
Strontium-DISS
Thallium
Thallium-DISS
Tin
Tin-DISS
Titanium
Titanium-DISS
Trivalent Chrom
Zinc
Zinc-DISS
Hexavalent Chromium
Mercury
Mercury-DISS
1,1-Dichloroethane
1,1-Dichloroethene
1,1-Dichloropropene
1,2-Dichlorobenzene
1,2-Dichloroethane
1,2-Dichloropropane
1,3-Dichlorobenzene
1,3-Dichloropropane
1,4-Dichlorobenzene
1,4-Dioxane
2,2-Dichloropropane
2-Butanone
2-Hexanone
4-Chlorotoluene
Acetone
Acrolein
Acrylonitrile
Benzene
Benzyl chloride
Bromobenzene
Bromoform
Bromomethane
Carbon disulfide
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
Dibromomethane
Ethylbenzene
Isopropylbenzene
Methylene chloride
Naphthalene
n-Butylbenzene
n-Propylbenzene
p-Isopropyltoluene
sec-Butylbenzene
Styrene
UNITS
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
mg/L
mg/L
ug/L
ug/L
PQL
5000
5000
50
50
10
10
1000
1000
500
500
50
20
20
0.01
0.01
0.2
0.2
US EPA Method
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 7196A
SW846 7196A
SW846 7470A
SW846 7470A
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
1000
-5
5
10
5
5
5
20
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
2/11/2009
70700
86100
103 J
168 J E
10 U
4.2 B
3.9 B
3.7 B
50 U
50 U
1.2 B
11.7 B J
78.6 J
0.01 U
0.01 U
0.2 U
0.025 B J
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
100000
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
500
500
1000
500
500
500
2000
10000
10000
500
500
500
500
500
500
23000
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
NA
Day 1
2/17/2009
7690000
8430000
244000 J E
236000 J
50 U
50 U
500 U
500 U
250 U
250 U
9.4 B
504 J
92.4 B J
0.1 G U
0.1 G U
0.052 B J
0.056 B J
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
20000
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
100
100
200
100
100
100
400
2000
2000
100
100
100
100
100
100
1400
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
NA
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Location C
Lewis County, WV
Day 5
Day 90
2/27/2009
29100000
29200000
1820000 J E
1800000 J E
15.9 B
18 B
17.8 B
500 U
250 U
250 U
25 U
116
100
0.5 U
0.07 B
0.054 B J
0.2 U
5/15/09
52800000
54100000
3620000 J
3710000 J
500 U
162 B
2000 U
2000 U
242 B
264 B
100 U
178 B
196 B
1 GU
0.1 G U
0.2 U
0.2 U
15
15
15
15
15
15
15
15
15
15
15
15
15
15
15
15
15
15
15
15
3000
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
1000
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
1000
15
15
30
15
15
15
60
300
300
8
15
15
15
15
15
260
15
15
15
15
15
15
15
15
15
15
15
15
15
15
15
15
15
15
15
15
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
NA
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Day 14
2/20/2009
18200000
18000000
893000 E
891000 J
19.4 B
20.7 B
500 U
21.8 B
250 U
250 U
14.6 B
83.6 B J
67.1 B J
0.1 G U
0.1 G U
0.04 B J
0.038 B J
NA
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
5
5
10
5
5
5
8.1
100
100
3
5
5
5
5
5
19
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
ND U
U
U
U
U
U
U
J
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
NA
5
5
10
5
5
5
11
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
ND U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
PARAMETER
tert-butyl acetate
tert-Butylbenzene
Tetrachloroethene
tetrahydrofuran
Toluene
Trichloroethene
Vinyl acetate
Vinyl chloride
Xylenes (total)
1,3-Dinitrobenzene
1,4-Naphthoquinone
1-Naphthylamine
2,3,7,8-TCDD
2,4-Dimethylphenol
2,4-Dinitrophenol
2,4-Dinitrotoluene
2,6-Dichlorophenol
2,6-Dinitrotoluene
2-Chloronaphthalene
2-Chlorophenol
2-Methylnaphthalene
2-Methylphenol
2-Naphthylamine
2-Nitroaniline
2-Nitrophenol
2-Picoline
3-Nitroaniline
4-Aminobiphenyl
4-Chloroaniline
4-Nitroaniline
4-Nitrophenol
5-Nitro-o-toluidine
Acenaphthene
Acenaphthylene
Acetophenone
Aniline
Aramite
Benzidine
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(ghi)perylene
Benzyl alcohol
Chlorobenzilate
Chrysene
Diallate
Dibenzofuran
Diethyl phthalate
Dimethoate
Dimethyl phthalate
UNITS
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
PQL
-5
5
-5
5
5
5
5
5
5
15
US EPA Method
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
10
2
10
10
10
10
-10
10
10
40
10
2
10
10
2
10
2
10
10
50
10
10
10
10
10
50
50
10
10
10
10
10
50
50
100
10
2
2
10
10
10
200
10
5
2
2
2
10
10
2
2
10
10
10
2
10
2
10
10
10
10
10
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
Day 0
Day 1
Location C
Lewis County, WV
Day 5
Day 14
Day 90
2/11/2009
2/17/2009
2/20/2009
2/27/2009
5/15/09
NA
NA
500 U
500 U
NA
NA
100 U
100 U
NA
NA
15 U
15 U
NA
NA
5U
5U
5U
5U
NA
NA
500
500
500
500
500
500
500
1500
U
U
U
U
U
U
U
U
100
100
100
100
100
100
100
300
U
U
U
U
U
U
U
U
15
15
15
15
15
15
15
45
U
U
U
U
U
U
U
U
1.6
5
5
5
5
5
5
15
J
U
U
U
U
U
U
U
5
5
5
5
5
5
5
15
U
U
U
U
U
U
U
U
9.6
1.9
9.6
9.6
9.6
9.6
U
U
U
U
U
U
9.7
1.9
9.7
9.7
9.7
9.7
U
U
U
U
U
U
9.8
2
9.8
9.8
9.8
9.8
U
U
U
U
U
U
U
U
U
U
U
U
9.5
1.9
9.5
9.5
9.5
9.5
9.6
9.6
9.6
48
9.6
1.9
9.6
9.6
1.9
9.6
1.3
9.6
9.6
48
9.6
9.6
9.6
9.6
9.6
48
48
9.6
9.6
9.6
9.6
9.6
48
48
96
9.6
1.9
1.9
9.6
9.6
9.6
190
1.9
1.9
1.9
1.9
1.9
9.6
9.6
1.9
1.9
9.4
9.6
9.6
1.9
9.6
1.9
9.6
9.6
9.6
9.6
9.6
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
9.7
9.7
9.7
48
9.7
1.9
9.7
9.7
1.9
9.7
2.1
9.7
9.7
48
9.7
9.7
9.7
9.7
0.28
48
48
9.7
9.7
9.7
9.7
9.7
48
48
97
9.7
1.9
1.9
2.9
9.7
9.7
190
1.9
1.9
1.9
1.9
1.9
9.7
9.7
1.9
1.9
9.7
9.7
9.7
1.9
9.7
1.9
9.7
9.7
9.7
9.7
0.68
U
U
U
U
U
U
U
U
U
U
9.8
9.8
9.8
49
9.8
2
9.8
9.8
2
9.8
0.34
9.8
9.8
49
9.8
9.8
9.8
9.8
0.21
49
49
9.8
9.8
9.8
9.8
9.8
49
49
98
9.8
2
2
9.8
9.8
9.8
200
2
2
2
2
2
9.8
9.8
2
2
9.8
9.8
9.8
2
9.8
2
9.8
0.73
9.8
9.8
9.8
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
9.4
1.9
9.4
9.4
9.4
9.4
#N/A
9.4
9.4
9.4
47
9.4
1.9
9.4
9.4
1.9
9.4
1.9
9.4
9.4
47
9.4
9.4
9.4
9.4
9.4
47
47
9.4
9.4
9.4
9.4
9.4
47
47
94
9.4
1.9
1.9
9.4
9.4
9.4
190
1.9
1.9
1.9
1.9
1.9
9.4
9.4
1.9
1.9
9.4
9.4
9.4
1.9
9.4
1.9
9.4
9.4
9.4
9.4
9.4
U
U
U
U
U
U
ND U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
NA
NA
NA
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
#N/A
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
NA
9.5
9.5
9.5
48
9.5
1.9
9.5
9.5
1.9
9.5
1.9
9.5
9.5
48
9.5
9.5
9.5
9.5
9.5
48
48
9.5
9.5
9.5
9.5
9.5
48
48
95
9.5
1.9
1.9
9.5
9.5
9.5
190
1.9
1.9
1.9
1.9
1.9
9.5
9.5
1.9
1.9
9.5
9.5
9.5
1.9
9.5
1.9
9.5
9.5
9.5
9.5
9.5
PARAMETER
Dinoseb
Diphenylamine
Disulfoton
Fluoranthene
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hexachloroethane
Hexachloropropene
Isodrin
Isophorone
Isosafrole
Nitrobenzene
N-Nitrosomorpholine
N-Nitrosopiperidine
o-Toluidine
Parathion
Pentachlorobenzene
Pentachloroethane
Pentachlorophenol
Phenanthrene
Phenol
Phorate
Pronamide
Pyrene
Pyridine
Safrole
Thionazin
Day 0
Day 1
Location C
Lewis County, WV
Day 5
Day 14
Day 90
2/11/2009
9.6 U
9.6 U
1.9 U
9.6 U
9.6 U
1.9 U
1.9 U
1.9 U
1.9 U
9.6 U
9.6 U
9.6 U
1.9 U
9.6 U
9.6 U
9.6 U
9.6 U
1.9 U
9.6 U
9.6 U
9.6 U
1.9 U
1.9 U
9.6 U
9.6 U
9.6 U
9.6 U
9.6 U
9.6 U
9.6 U
9.6 U
9.6 U
19 U
9.6 U
9.6 U
0.28 J
1.9 U
9.6 U
9.6 U
1.9 U
0.91 J
9.6 U
0.96 U
2/17/2009
9.7 U
9.7 U
1.9 U
9.7 U
9.7 U
1.9 U
1.9 U
1.9 U
1.9 U
9.7 U
9.7 U
9.7 U
1.9 U
9.7 U
9.7 U
9.7 U
9.7 U
1.9 U
9.7 U
9.7 U
9.7 U
1.9 U
1.9 U
9.7 U
9.7 U
9.7 U
9.7 U
9.7 U
9.7 U
9.7 U
9.7 U
9.7 U
19 U
9.7 U
9.7 U
0.39 J
1.9 U
9.7 U
9.7 U
1.9 U
6.4 J
9.7 U
9.7 U
2/20/2009
4.1 J
9.8 U
2U
9.8 U
9.8 U
2U
2U
2U
2U
9.8 U
9.8 U
9.8 U
2U
9.8 U
9.8 U
9.8 U
9.8 U
2U
9.8 U
9.8 U
9.8 U
2U
2U
9.8 U
9.8 U
9.8 U
9.8 U
9.8 U
9.8 U
9.8 U
9.8 U
9.8 U
20 U
9.8 U
9.8 U
2U
2U
9.8 U
9.8 U
2U
4.1 J
9.8 U
9.8 U
2/27/2009
9.4 U
9.4 U
1.9 U
9.4 U
9.4 U
1.9 U
1.9 U
1.9 U
1.9 U
9.4 U
9.4 U
9.4 U
1.9 U
9.4 U
9.4 U
9.4 U
9.4 U
1.9 U
9.4 U
9.4 U
9.4 U
1.9 U
1.9 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
19 U
9.4 U
9.4 U
1.9 U
1.9 U
9.4 U
9.4 U
1.9 U
3J
9.4 U
9.4 U
5/15/09
9.5 U
9.5 U
1.9 U
9.5 U
9.5 U
1.9 U
1.9 U
1.9 U
1.9 U
9.5 U
9.5 U
9.5 U
1.9 U
9.5 U
9.5 U
9.5 U
9.5 U
1.9 U
9.5 U
9.5 U
9.5 U
1.9 U
1.9 U
9.5 U
9.5 U
9.5 U
9.5 U
9.5 U
9.5 U
9.5 U
9.5 U
9.5 U
19 U
9.5 U
9.5 U
1.9 U
1.6 J
9.5 U
9.5 U
1.9 U
9.5 U
9.5 U
9.5 U
UNITS
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
PQL
10
10
2
10
10
2
2
0.05
2
2
10
10
2
10
10
10
10
2
10
10
10
2
2
10
10
10
10
10
10
10
10
10
20
10
10
2
2
10
10
2
10
10
10
10
US EPA Method
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
4,4'-DDD
4,4'-DDE
4,4'-DDT
Aldrin
alpha-BHC
beta-BHC
delta-BHC
Dieldrin
Endosulfan I
Endosulfan II
Endosulfan sulfate
Endrin
Endrin aldehyde
Endrin ketone
gamma-BHC (Lindane)
Heptachlor
Heptachlor epoxide
Methoxychlor
Toxaphene
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.1
2
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
0.049
0.049
0.049
0.049
0.049
0.049
0.49
0.049
0.049
0.049
0.049
0.049
0.049
0.049
0.049
0.049
0.049
0.049
0.098
2
PCBs
Aroclor 1016
Aroclor 1221
Aroclor 1232
Aroclor 1242
Aroclor 1248
Aroclor 1254
Aroclor 1260
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
0.4
0.4
0.4
0.4
0.4
0.4
0.4
SW846 8082
SW846 8082
SW846 8082
SW846 8082
SW846 8082
SW846 8082
SW846 8082
0.39
0.39
0.39
0.39
0.39
0.39
0.39
NA
NA
NA
NA
NA
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.048
0.048
0.048
0.048
0.048
0.048
0.48
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.096
0.096
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
0.097
0.097
0.097
0.097
0.097
0.097
0.97
0.097
0.097
0.097
0.097
0.097
0.097
0.097
0.097
0.097
0.24
0.097
0.19
3.9
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.38
0.38
0.38
0.38
0.38
0.38
0.38
U
U
U
U
U
U
U
0.39
0.39
0.39
0.39
0.39
0.39
0.39
U
U
U
U
U
U
U
U
U
U
PARAMETER
Day 0
Day 1
Location C
Lewis County, WV
Day 5
Day 14
Day 90
2/11/2009
2/17/2009
2/20/2009
2/27/2009
5/15/09
UNITS
PQL
US EPA Method
Ethyl parathion
ug/L
0.4
SW846 8141A
0.96 U
NA
NA
Alcohols
2-Propanol
Butyl alcohol
Ethanol
Methanol
n-Propanol
mg/L
mg/L
mg/L
mg/L
mg/L
10
10
10
10
10
SW846 8015
SW846 8015
SW846 8015
SW846 8015
SW846 8015
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
Glycols
Ethylene Glycol
Propylene glycol
mg/L
mg/L
50
50
SW846 8015
SW846 8015
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
Acids
Acetic Acid
Butyric Acid
Propionic Acid
Volatile Acids
mg/L
mg/L
mg/L
mg/L
10
10
10
10
SW846 8015
SW846 8015
SW846 8015
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.95 U
0.97 U
Location D
Greene County, PA
Day 1
Day 5
Day 0
PARAMETER
Acidity
Amenable cyanide
Ammonia Nitrogen
Bromide
Chloride
Fluoride
Hardness, as CaCO3
Nitrate as N
Nitrate-Nitrite
Nitrite as N
Oil & Grease (HEM)
Sulfate
TOC
Total Alkalinity
Total phosphorus
Turbidity
Cyanide, Total
Total Sulfide
pH
Sulfite
MBAS (mol.wt 320)
Aluminum
Aluminum-DISS
Antimony
Antimony-DISS
Arsenic
Arsenic-DISS
Barium
Barium-DISS
Beryllium
Beryllium-DISS
Boron
Boron-DISS
Cadmium
Cadmium-DISS
Calcium
Calcium-DISS
Chromium
Chromium-DISS
Cobalt
Cobalt-DISS
Copper
Copper-DISS
Iron
Iron-DISS
Lead
Lead-DISS
Lithium
Lithium-DISS
Magnesium
Magnesium-DISS
Manganese
Manganese-DISS
Molybdenum
Molybdenum-DISS
Nickel
Nickel-DISS
Potassium
Potassium-DISS
Selenium
Selenium-DISS
Silver
Silver-DISS
2/12/2009
UNITS
PQL
US EPA Method
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
umhos/cm
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
NTU
ug/L
mg/L
No Units
mg/L
mg/L
mg/L
5
0.01
0.1
2
1
10
1
-1
5
0.05
0.1
0.05
5
-1
1
5
10
3
0.1
4
-10
3
-0.01
1
0.05
SM20 2310B (4a)

SM18 4500-CN E
MCAWW 350.1
SM18 5210 B
MCAWW 300.0A
MCAWW 410.4
MCAWW 300.0A
SM20 5310B
MCAWW 300.0A
SM20 2340C
MCAWW 300.0A
MCAWW 353.2
MCAWW 300.0A
CFR136A 1664A HEM
MCAWW 120.1
MCAWW 300.0A
SM20 5310B
SM18 2320 B
SM18 2540 C
MCAWW 351.3
MCAWW 365.2
SM20 2540D
MCAWW 180.1
SW846 9012A
SW846 9030B/9034
SW846 9040
SW846 9066
SM4500-SO3 B
SM5540 C
5
0.01
1.8
438
1
3450
234
857
0.15
230
0.46
0.73
0.32
NA
1970
374
741
120
1410
25.8
0.054
16
385
10
8
7.1
0.065
NA
NA
U
U
J
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
200
200
10
10
10
10
200
200
4
4
2000
2000
5
5
5000
5000
5
5
500
500
25
25
100
100
3
3
500
500
5000
5000
150
150
400
400
40
40
5000
5000
5
5
5
5
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
298
67.6
10
10
10
10
111
75.4
4
4
109
103
5
5
52700
56400
4.3
2.6
1.1
0.7
28.6
25
1720
810
4.7
2.6
17.5
28.4
16700
18000
146
149
40
40
6.2
2.1
3280
3540
5
5
5
5
J
BJ
U
U
U
U
B
B
U
U
BE
BJ
U
U
J
J
J
B
B
B
B
U
B
B
B
U
U
B
B
B
B
U
U
U
U
2/13/2009
5
0.01
5.4
656
35.5
1290
4900
435
0.75
1500
0.5
0.61
4.7
4.8
19200
348
342
577
9020
21.8
0.42
23.2
31.4
10
1.6
7.7
0.01
10.8
3.38
U
U
J
887
681
9.3
9.8
17.5
16
7620
4170
4
4
5420
5750
5
5
297000
300000
32.6
20
50
50
22.5
25
14700
10700
3
3
4350
4620
40800
42100
1150
1120
10.5
4.2
17.6
4.1
38000
38200
4.3
5
5
5
J
J
B
B
J
J
GU
J
U
J
J
J
U
B
U
U
U
J
U
U
U
U
B
U
B
B
B
B
B
U
U
U
Day 90
2/17/2009
5
0.01
34.1
721
242
6970
26800
161
0.5
8400
0.5
0.52
6
350
122000
25.9
161
266
40700
46.5
0.91
3220
786
10
2.4
6.6
0.028
9.60
0.210
47200
670
33.8
13.6
92.9
17
165000
226000
20
20
12200
13000
7.4
25
2260000
2420000
130
15
250
250
2280
125
140000
28400
349
15
21400
22700
291000
296000
3290
2540
50.5
12
187
13.3
144000
146000
25
25
25
25
5/13/09
U
U
J
J
GU
GU
J
J
J
J
J
U
B
J
BJ
B
B
B
J
U
U
J
B
U
J
J
B
U
U
U
J
U
JE
BJ
B
B
B
U
U
U
U
162
0.01
96
1080
766
8590
78300
305
2.5
40000
2.5
0.1
2.5
21.3
249000
50
302
75.2
155000
92.8
0.1
153
174
10
3.2
6.2
0.0091
9.60
4.54
358
195
100
100
54
50.7
1440000
1500000
40
40
13000
14000
2.5
1.4
8500000
8930000
50
6.8
1000
1000
250
250
87800
78700
45.6
60
44500
48000
933000
1000000
4720
5040
400
400
800
800
191000
202000
50
50
50
50
J
GU
GU
U
GU
J
GU
J
B
B
U
U
B
B
J
U
U
J
J
B
B
J
J
U
B
U
U
U
U
B
U
U
U
U
U
U
U
U
U
Location D
Greene County, PA
Day 1
Day 5
Day 0
PARAMETER
Sodium
Sodium-DISS
Strontium
Strontium-DISS
Thallium
Thallium-DISS
Tin
Tin-DISS
Titanium
Titanium-DISS
Trivalent Chrom
Zinc
Zinc-DISS
Hexavalent Chromium
Mercury
Mercury-DISS
1,1-Dichloroethane
1,1-Dichloroethene
1,1-Dichloropropene
1,2-Dichlorobenzene
1,2-Dichloroethane
1,2-Dichloropropane
1,3-Dichlorobenzene
1,3-Dichloropropane
1,4-Dichlorobenzene
1,4-Dioxane
2,2-Dichloropropane
2-Butanone
2-Hexanone
4-Chlorotoluene
Acetone
Acrolein
Acrylonitrile
Benzene
Benzyl chloride
Bromobenzene
Bromoform
Bromomethane
Carbon disulfide
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
Dibromomethane
Ethylbenzene
Isopropylbenzene
Methylene chloride
Naphthalene
n-Butylbenzene
n-Propylbenzene
p-Isopropyltoluene
sec-Butylbenzene
Styrene
UNITS
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
mg/L
mg/L
ug/L
ug/L
PQL
5000
5000
50
50
10
10
1000
1000
500
500
50
20
20
0.01
0.01
0.2
0.2
US EPA Method
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 7196A
SW846 7196A
SW846 7470A
SW846 7470A
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
1000
-5
5
10
5
5
5
20
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
2/12/2009
321000
345000
789 J E
911 J
10 U
10 U
6.7 B
5.5 B
3.2 B
50 U
4.3 B
43.6
36 J
0.1 G U
0.1 G U
0.025 B
0.056 B J
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
400000
NA
2000
2000
4000
2000
2000
2000
8000
40000
40000
2000
2000
2000
2000
2000
2000
54000
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
2/13/2009
2860000
2950000
24100 J
24200 J
10 U
10 U
7B
6.3 B
15.1 B
9.5 B
32.6
248
108 J
0.1 G U
0.1 G U
0.05 B J
0.053 B J
250
250
250
250
250
250
250
250
250
250
250
250
250
250
250
250
250
250
250
250
50000
NA
250
250
500
250
250
250
1000
5000
5000
250
250
250
250
250
250
7300
250
250
250
250
250
250
250
250
250
250
250
250
250
250
250
250
250
250
250
250
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Day 90
2/17/2009
12900000
14100000
345000
378000 J E
50 U
50 U
25.7 B
500 U
195 B
250 U
15 B
2930 J
283 J
0.1 G U
0.1 G U
0.24 J
0.064 B J
100
100
100
100
100
100
100
100
100
100
15
100
100
100
100
100
100
100
100
100
20000
NA
100
100
200
100
100
100
140
2000
2000
100
100
100
100
100
100
400
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
5/13/09
26900000
28700000
1220000
1300000
200
200
1000
1000
130
124
50
29.3
130
0.5
0.5
0.2
0.068
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
BJ
BJ
U
BJ
BJ
GU
GU
U
BJ
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
1000
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
5
5
10
5
5
5
20
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
U
U
U
U
U
U
NA
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Location D
Greene County, PA
Day 1
Day 5
Day 0
PARAMETER
tert-butyl acetate
tert-Butylbenzene
Tetrachloroethene
tetrahydrofuran
Toluene
Trichloroethene
Vinyl acetate
Vinyl chloride
Xylenes (total)
1,3-Dinitrobenzene
1,4-Naphthoquinone
1-Naphthylamine
2,3,7,8-TCDD
2,4-Dimethylphenol
2,4-Dinitrophenol
2,4-Dinitrotoluene
2,6-Dichlorophenol
2,6-Dinitrotoluene
2-Chloronaphthalene
2-Chlorophenol
2-Methylnaphthalene
2-Methylphenol
2-Naphthylamine
2-Nitroaniline
2-Nitrophenol
2-Picoline
3-Nitroaniline
4-Aminobiphenyl
4-Chloroaniline
4-Nitroaniline
4-Nitrophenol
5-Nitro-o-toluidine
Acenaphthene
Acenaphthylene
Acetophenone
Aniline
Aramite
Benzidine
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(ghi)perylene
Benzyl alcohol
Chlorobenzilate
Chrysene
Diallate
Dibenzofuran
Diethyl phthalate
Dimethoate
Dimethyl phthalate
UNITS
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
PQL
-5
5
-5
5
5
5
5
5
5
15
US EPA Method
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
10
2
10
10
10
10
-10
10
10
40
10
2
10
10
2
10
2
10
10
50
10
10
10
10
10
50
50
10
10
10
10
10
50
50
100
10
2
2
10
10
10
200
10
5
2
2
2
10
10
2
2
10
10
10
2
10
2
10
10
10
10
10
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
2/12/2009
NA
2000 U
2000 U
NA
2000 U
2000 U
2000 U
2000 U
2000 U
2000 U
2000 U
6000 U
11
2.2
11
11
11
11
NA
11
11
11
56
11
2.2
11
11
2.2
11
7.5
11
11
56
11
11
11
11
11
56
56
11
11
11
11
11
56
56
110
11
2.2
2.2
0.97
11
11
220
2.2
2.2
2.2
2.2
2.2
11
11
2.2
2.2
11
11
11
2.2
11
2.2
11
11
11
11
11
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
2/13/2009
NA
250 U
250 U
NA
250 U
250 U
250 U
250 U
250 U
250 U
250 U
750 U
9.8
2
9.8
9.8
9.8
9.8
NA
9.8
9.8
9.8
49
9.8
2
9.8
9.8
2
9.8
3.7
9.8
9.8
49
9.8
9.8
9.8
9.8
0.35
49
49
9.8
9.8
9.8
9.8
9.8
49
49
98
9.8
2
2
5
9.8
9.8
200
2
2
2
2
2
9.8
9.8
2
2
3.9
9.8
9.8
2
9.8
2
9.8
0.84
9.8
9.8
9.8
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
J
U
U
U
Day 90
2/17/2009
NA
100 U
100 U
NA
100 U
100 U
100 U
100 U
100 U
100 U
100 U
300 U
9.7
1.9
9.7
9.7
9.7
9.7
NA
9.7
9.7
9.7
48
9.7
1.9
9.7
9.7
1.9
9.7
1.9
9.7
9.7
48
9.7
9.7
9.7
9.7
9.7
48
48
9.7
9.7
9.7
9.7
9.7
48
48
97
9.7
1.9
1.9
9.7
9.7
9.7
190
1.9
1.9
1.9
1.9
1.9
9.7
9.7
1.9
1.9
30
5.6
9.7
1.9
9.7
1.9
9.7
9.7
9.7
9.7
0.53
5/13/09
NA
5U
5U
NA
U
U
U
U
U
U
5
5
5
5
5
5
5
15
U
U
U
U
U
U
U
U
9.4
1.9
9.4
9.4
9.4
9.4
U
U
U
U
U
U
9.4
9.4
9.4
47
9.4
1.9
9.4
9.4
1.9
9.4
1.9
9.4
9.4
47
9.4
9.4
9.4
9.4
1.1
47
47
9.4
9.4
9.4
9.4
9.4
47
47
94
9.5
1.9
1.9
2.1
9.4
9.4
190
1.9
1.9
1.9
1.9
1.9
9.4
9.4
1.9
1.9
9.4
9.4
9.4
1.9
9.4
1.9
9.4
9.4
9.4
9.4
5.4
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
NA
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
J
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
Location D
Greene County, PA
Day 1
Day 5
Day 0
PARAMETER
Dinoseb
Diphenylamine
Disulfoton
Fluoranthene
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hexachloroethane
Hexachloropropene
Isodrin
Isophorone
Isosafrole
Nitrobenzene
N-Nitrosomorpholine
N-Nitrosopiperidine
o-Toluidine
Parathion
Pentachlorobenzene
Pentachloroethane
Pentachlorophenol
Phenanthrene
Phenol
Phorate
Pronamide
Pyrene
Pyridine
Safrole
Thionazin
UNITS
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
PQL
10
10
2
10
10
2
2
0.05
2
2
10
10
2
10
10
10
10
2
10
10
10
2
2
10
10
10
10
10
10
10
10
10
20
10
10
2
2
10
10
2
10
10
10
10
US EPA Method
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
2/12/2009
11 U
11 U
2.2 U
11 U
11 U
2.2 U
2.2 U
2.2 U
2.2 U
11 U
11 U
11 U
2.2 U
11 U
11 U
11 U
11 U
2.2 U
11 U
11 U
11 U
2.2 U
2.2 U
11 U
11 U
11 U
11 U
11 U
11 U
11 U
11 U
11 U
22 U
11 U
11 U
1.1 J
2.2 U
11 U
11 U
0.19 J
17
11 U
0.96 U
NA
4,4'-DDD
4,4'-DDE
4,4'-DDT
Aldrin
alpha-BHC
beta-BHC
delta-BHC
Dieldrin
Endosulfan I
Endosulfan II
Endosulfan sulfate
Endrin
Endrin aldehyde
Endrin ketone
gamma-BHC (Lindane)
Heptachlor
Heptachlor epoxide
Methoxychlor
Toxaphene
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.1
2
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
0.05
0.11
0.05
0.05
0.05
0.05
0.5
0.05
0.05
0.0093
0.05
0.067
0.018
0.05
0.05
0.05
0.053
0.05
0.1
2
PCBs
Aroclor 1016
Aroclor 1221
Aroclor 1232
Aroclor 1242
Aroclor 1248
Aroclor 1254
Aroclor 1260
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
0.4
0.4
0.4
0.4
0.4
0.4
0.4
SW846 8082
SW846 8082
SW846 8082
SW846 8082
SW846 8082
SW846 8082
SW846 8082
0.4
0.4
0.4
0.4
0.4
0.4
0.4
2/13/2009
9.8 U
9.8 U
2U
9.8 U
9.8 U
2U
0.31 J
2U
2U
9.8 U
9.8 U
9.8 U
2U
9.8 U
9.8 U
9.8 U
9.8 U
2U
9.8 U
9.8 U
9.8 U
2U
2U
9.8 U
9.8 U
9.8 U
9.8 U
9.8 U
9.8 U
9.8 U
9.8 U
9.8 U
20 U
9.8 U
9.8 U
2U
2U
9.8 U
9.8 U
2U
5.9 J
9.8 U
9.8 U
NA
2/17/2009
9.7 U
9.7 U
1.9 U
9.7 U
9.7 U
1.9 U
1.9 U
1.9 U
1.9 U
9.7 U
9.7 U
9.7 U
1.9 U
9.7 U
9.7 U
9.7 U
9.7 U
1.9 U
9.7 U
9.7 U
9.7 U
1.9 U
1.9 U
9.7 U
9.7 U
9.7 U
9.7 U
9.7 U
9.7 U
9.7 U
9.7 U
9.7 U
19 U
9.7 U
9.7 U
0.64 J
1.9 U
9.7 U
9.7 U
0.19 J
3.7 J
9.7 U
9.7 U
NA
Day 90
5/13/09
9.4
9.4
1.9
9.4
9.4
1.9
1.9
1.9
1.9
9.4
9.4
9.4
1.9
9.4
9.4
9.4
3.2
1.9
9.4
9.4
9.4
1.9
1.9
9.4
9.4
9.4
9.4
9.4
9.4
9.4
9.4
9.4
19
9.4
9.4
1.9
2.4
9.4
9.4
1.9
9.4
9.4
0.97
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
NA
U
U
U
U
U
U
U
J PG
U
PG
J PG
U
U
U
PG
U
U
U
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.049
0.049
0.049
0.049
0.049
0.049
0.49
0.049
0.049
0.049
0.049
0.049
0.049
0.049
0.049
0.049
0.049
0.049
0.098
2
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.39
0.39
0.39
0.39
0.39
0.39
0.39
U
U
U
U
U
U
U
Day 0
PARAMETER
2/12/2009
Location D
Greene County, PA
Day 1
Day 5
2/13/2009
Day 90
2/17/2009
5/13/09
UNITS
PQL
US EPA Method
Ethyl parathion
ug/L
0.4
SW846 8141A
0.96 U
NA
NA
0.97 U
Alcohols
2-Propanol
Butyl alcohol
Ethanol
Methanol
n-Propanol
mg/L
mg/L
mg/L
mg/L
mg/L
10
10
10
10
10
SW846 8015
SW846 8015
SW846 8015
SW846 8015
SW846 8015
420
10 U
10 U
26
10 U
200
10 U
10 U
39
10 U
170
20 U
20 U
110
20 U
63
47
28
410
10
Glycols
Ethylene Glycol
Propylene glycol
mg/L
mg/L
50
50
SW846 8015
SW846 8015
50 U
260
50 U
160
52
160
100 UJ
100 UJ
Acids
Acetic Acid
Butyric Acid
Propionic Acid
Volatile Acids
mg/L
mg/L
mg/L
mg/L
10
10
10
10
SW846 8015
SW846 8015
SW846 8015
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
6.3 J
1.6 UJ
1.7 UJ
NA
J
J
J
J
YJ
PARAMETER
Acidity
Amenable cyanide
Ammonia Nitrogen
Bromide
Chloride
Fluoride
Hardness, as CaCO3
Nitrate as N
Nitrate-Nitrite
Nitrite as N
Oil & Grease (HEM)
Sulfate
TOC
Total Alkalinity
Total phosphorus
Turbidity
Cyanide, Total
Total Sulfide
pH
Sulfite
MBAS (mol.wt 320)
Aluminum
Aluminum-DISS
Antimony
Antimony-DISS
Arsenic
Arsenic-DISS
Barium
Barium-DISS
Beryllium
Beryllium-DISS
Boron
Boron-DISS
Cadmium
Cadmium-DISS
Calcium
Calcium-DISS
Chromium
Chromium-DISS
Cobalt
Cobalt-DISS
Copper
Copper-DISS
Iron
Iron-DISS
Lead
Lead-DISS
Lithium
Lithium-DISS
Magnesium
Magnesium-DISS
Manganese
Manganese-DISS
Molybdenum
Molybdenum-DISS
Nickel
Nickel-DISS
Potassium
Potassium-DISS
Selenium
Selenium-DISS
Silver
Silver-DISS
UNITS
PQL
US EPA Method
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
umhos/cm
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
NTU
ug/L
mg/L
No Units
mg/L
mg/L
mg/L
5
0.01
0.1
2
1
10
1
-1
5
0.05
0.1
0.05
5
-1
1
5
10
3
0.1
4
-10
3
-0.01
1
0.05
SM20 2310B (4a)

SM18 4500-CN E
MCAWW 350.1
SM18 5210 B
MCAWW 300.0A
MCAWW 410.4
MCAWW 300.0A
SM20 5310B
MCAWW 300.0A
SM20 2340C
MCAWW 300.0A
MCAWW 353.2
MCAWW 300.0A
CFR136A 1664A HEM
MCAWW 120.1
MCAWW 300.0A
SM20 5310B
SM18 2320 B
SM18 2540 C
MCAWW 351.3
MCAWW 365.2
SM20 2540D
MCAWW 180.1
SW846 9012A
SW846 9030B/9034
SW846 9040
SW846 9066
SM4500-SO3 B
SM5540 C
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
200
200
10
10
10
10
200
200
4
4
2000
2000
5
5
5000
5000
5
5
500
500
25
25
100
100
3
3
500
500
5000
5000
150
150
400
400
40
40
5000
5000
5
5
5
5
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
Day 0
Day 1
4/1/2009
4/3/2009
5
0.027
15.6
788
32.8
996
3560
663
3.9
1060
0.31
1.1
0.14
6.6
4980
50.3
226
308
5910
7.8
0.14
1040
715
69
3
7
0.14
10.4
0.05
166
2000
100
100
100
100
2210
2560
40
40
414
502
50
50
227000
265000
50
50
500
500
250
250
1180
1230
30
30
808
1000
49400
56100
189
227
400
400
400
400
13200
16600
50
50
50
50
U
J
B
J
B
U
J
U
J
U
B
U
U
U
U
U
U
U
BJ
BJ
U
U
U
U
U
U
U
U
U
U
U
U
U
U
B
B
U
U
U
U
5
0.01
36.3
158
172
1330
16900
167
1.2
4700
1.3
0.38
1.2
5
68400
10.7
108
278
28900
42.5
0.11
7
42.6
35.5
3
6.9
0.057
36.8
0.0621
176
2000
100
100
100
27.4
26700
45700
40
40
8360
10900
50
50
1030000
1270000
50
50
500
500
250
250
12400
13600
30
30
11800
15300
131000
160000
782
967
19.7
30
10.6
17.9
63800
80500
50
50
50
50
Location E
Greene County
Day 5
4/7/2009
U
NR U
J
J
GU
U
J
BJ
J
U
J
B
U
U
U
U
B
U
U
J
J
U
U
U
U
U
U
U
U
U
U
B
B
B
B
U
U
U
U
5
0.01
70.3
106
536
17700
48900
59.4
0.045
20000
1.5
0.38
2.5
5.1
183000
40.2
46.2
135
55100
86.1
0.097
47
32.5
10
3
6.5
0.0076
18.8
0.258
571
230
100
100
35.4
54.4
434000
489000
40
40
14400
16000
50
50
4950000
5430000
50
50
1000
1000
250
250
28200
29700
60
34.4
34600
39400
559000
602000
2630
2880
8.7
13.8
800
800
173000
194000
50
50
50
50
U
U
J
J
B
BJ
J
GU
J
BJ
J
U
U
B
B
B
U
U
B
B
U
U
J
J
U
U
U
U
U
U
U
U
U
B
B
B
U
U
U
U
U
U
Day 14
Day 90
4/17/2009
4/17/2009
40.8
0.01
NA
32.4
880
4670
76800
7.5
2.5
39200
2.9
0.91
2.5
4.9
256000
39.8
5.9
87.9
124000
95.5
2.5
1100
74.8
10
3
6
0.011
18.8
0.05
539
467
100
100
50.8
81.6
1010000
1000000
40
40
16800
17200
4.4
2.1
9600000
10500000
14
50
1000
2500
250
250
74800
49800
38.2
150
56100
58500
1000000
1120000
5170
5590
400
400
800
2000
299000
281000
30.1
50
50
8.9
J
GU
U
J
BJ
J
GU
U
U
BJ
BJ
U
U
B
B
J
U
U
BJ
B
J
J
BJ
U
U
U
U
U
J
BJ
U
J
J
U
U
U
U
B
U
U
B
345
0.01
214
26
1430
8570
121000
57.6
5
106000
15.9
0.085
5
6.1
468000
42.4
207
40.3
199000
146
0.2
237
159
1.9
3
5.9
0.0089
18.8
0.05
1020
285
100
100
100
100
2110000
2640000
40
40
18600
23700
50
50
19400000
23700000
50
50
5000
5000
250
250
144000
155000
30
30
112000
5610
1810000
2260000
10400
12800
400
400
400
400
592000
782000
50
50
50
50
U
J
J
GU
B
GU
BJ
J
GU
BJ
U
B
U
BJ
BJ
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
Day 0
PARAMETER
Sodium
Sodium-DISS
Strontium
Strontium-DISS
Thallium
Thallium-DISS
Tin
Tin-DISS
Titanium
Titanium-DISS
Trivalent Chrom
Zinc
Zinc-DISS
Hexavalent Chromium
Mercury
Mercury-DISS
1,1-Dichloroethane
1,1-Dichloroethene
1,1-Dichloropropene
1,2-Dichlorobenzene
1,2-Dichloroethane
1,2-Dichloropropane
1,3-Dichlorobenzene
1,3-Dichloropropane
1,4-Dichlorobenzene
1,4-Dioxane
2,2-Dichloropropane
2-Butanone
2-Hexanone
4-Chlorotoluene
Acetone
Acrolein
Acrylonitrile
Benzene
Benzyl chloride
Bromobenzene
Bromoform
Bromomethane
Carbon disulfide
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
Dibromomethane
Ethylbenzene
Isopropylbenzene
Methylene chloride
Naphthalene
n-Butylbenzene
n-Propylbenzene
p-Isopropyltoluene
sec-Butylbenzene
Styrene
UNITS
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
mg/L
mg/L
ug/L
ug/L
PQL
5000
5000
50
50
10
10
1000
1000
500
500
50
20
20
0.01
0.01
0.2
0.2
US EPA Method
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 7196A
SW846 7196A
SW846 7470A
SW846 7470A
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
1000
-5
5
10
5
5
5
20
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
4/1/2009
1460000
1770000
23200
28000
100
100
1000
1000
500
500
50
200
200
0.05
0.1
0.2
0.2
5
5
5
5
5
5
5
5
5
5
0.72
5
5
5
5
5
5
5
5
5
1000
NA
5
5
10
5
5
5
6.4
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
Location E
Greene County
Day 5
Day 1
U
U
U
U
U
U
U
U
U
GU
GU
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
4/3/2009
7540000
9760000
139000
178000
100 U
100 U
1000 U
1000 U
500 U
39.5 B
50 U
406
471
0.0086 B
0.01 U
0.2 U
0.044 B J
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
1000
NA
5
5
10
5
5
5
7.9
100
100
7.8
5
5
5
5
5
5
5
5
5
5
2
5
5
5
5
5
5
5
5
5
0.73
5
5
5
5
5
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
4/7/2009
21300000
23400000
650000
721000
200
200
1000
1000
90
102
50
264
295
0.5
0.5
0.2
0.2
5
5
5
5
5
5
5
5
5
5
1.1
5
5
5
5
5
0.64
5
5
5
1000
NA
5
5
10
5
5
5
17
100
100
5.8
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
0.67
5
5
5
5
5
5
5
5
5
U
U
U
U
B
B
U
GU
GU
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
Day 14
Day 90
4/17/2009
32600000
31600000
1370000
1380000
200
500
1000
1000
121
134
50
200
66.1
0.5
0.5
0.2
0.2
4/17/2009
47700000
60100000
2870000
3640000
100
27.1
1000
1000
500
500
50
147
173
0.19
0.55
0.2
0.2
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
1000
NA
5
5
10
5
5
5
12
100
100
17
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
J
J
U
U
U
U
B
B
U
U
B
GU
GU
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
1000
NA
5
5
10
5
5
5
20
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
J
J
J
U
B
U
U
U
U
U
BJ
BJ
B
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Day 0
PARAMETER
tert-butyl acetate
tert-Butylbenzene
Tetrachloroethene
tetrahydrofuran
Toluene
Trichloroethene
Vinyl acetate
Vinyl chloride
Xylenes (total)
1,3-Dinitrobenzene
1,4-Naphthoquinone
1-Naphthylamine
2,3,7,8-TCDD
2,4-Dimethylphenol
2,4-Dinitrophenol
2,4-Dinitrotoluene
2,6-Dichlorophenol
2,6-Dinitrotoluene
2-Chloronaphthalene
2-Chlorophenol
2-Methylnaphthalene
2-Methylphenol
2-Naphthylamine
2-Nitroaniline
2-Nitrophenol
2-Picoline
3-Nitroaniline
4-Aminobiphenyl
4-Chloroaniline
4-Nitroaniline
4-Nitrophenol
5-Nitro-o-toluidine
Acenaphthene
Acenaphthylene
Acetophenone
Aniline
Aramite
Benzidine
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(ghi)perylene
Benzyl alcohol
Chlorobenzilate
Chrysene
Diallate
Dibenzofuran
Diethyl phthalate
Dimethoate
Dimethyl phthalate
UNITS
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
PQL
-5
5
-5
5
5
5
5
5
5
15
US EPA Method
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
10
2
10
10
10
10
-10
10
10
40
10
2
10
10
2
10
2
10
10
50
10
10
10
10
10
50
50
10
10
10
10
10
50
50
100
10
2
2
10
10
10
200
10
5
2
2
2
10
10
2
2
10
10
10
2
10
2
10
10
10
10
10
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
4/1/2009
NA
5
5
NA
5.6
5
5
5
5
5
5
15
10
2
10
10
10
10
NA
10
10
10
50
10
2
10
10
2
10
2
10
10
50
10
10
10
10
10
50
50
10
10
10
10
10
50
50
100
10
2
2
10
10
10
200
2
2
2
2
2
10
10
2
2
4.1
10
10
2
10
2
10
10
10
10
0.36
Location E
Greene County
Day 5
Day 1
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
J
4/3/2009
NA
5U
5U
NA
3.8 J
5U
5U
5U
5U
5U
5U
15 U
21
4.2
21
21
21
21
NA
21
21
21
100
21
4.2
21
21
4.2
21
4.2
0.32
21
100
21
21
21
21
21
100
100
21
21
21
21
21
100
100
210
21
4.2
4.2
9
21
21
420
4.2
4.2
4.2
4.2
4.2
21
21
4.2
4.2
21
21
21
4.2
21
4.2
21
21
21
21
21
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
4/7/2009
NA
5
5
NA
7.7
5
5
5
5
5
5
5.1
9.4
1.9
9.4
9.4
9.4
9.4
NA
9.4
9.4
9.4
47
9.4
1.9
9.4
9.4
1.9
9.4
1.9
9.4
9.4
47
9.4
9.4
9.4
9.4
0.87
47
47
9.4
9.4
9.4
9.4
9.4
47
47
94
9.4
1.9
1.9
10
9.4
9.4
190
1.9
1.9
1.9
1.9
1.9
9.4
9.4
1.9
1.9
1.6
9.4
9.4
1.9
9.4
1.9
9.4
0.43
9.4
9.4
0.32
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
J
U
U
J
Day 14
Day 90
4/17/2009
NA
5
5
NA
13
5
5
5
5
5
5
3.2
4/17/2009
NA
5
5
NA
5
5
5
5
5
5
5
15
9.6
1.9
9.6
9.6
9.6
9.6
NA
9.6
9.6
9.6
48
9.6
1.9
9.6
9.6
1.9
9.6
1.9
9.6
9.6
48
9.6
9.6
9.6
9.6
0.38
48
48
9.6
9.6
9.6
9.6
9.6
48
48
96
9.6
1.9
1.9
6.4
9.6
9.6
190
1.9
1.9
1.9
1.9
1.9
9.6
9.6
1.9
1.9
9.6
9.6
9.6
1.9
9.6
1.9
9.6
9.6
9.6
9.6
9.6
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
9.5
1.9
9.5
9.5
9.5
9.5
NA
9.5
9.5
9.5
48
9.5
1.9
9.5
9.5
1.9
9.5
1.9
9.5
9.5
48
9.5
9.5
9.5
9.5
9.5
48
48
9.5
9.5
9.5
9.5
9.5
48
48
95
9.5
1.9
1.9
1.3
9.5
9.5
190
1.9
1.9
1.9
1.9
1.9
9.5
9.5
1.9
1.9
9.5
9.5
9.5
1.9
9.5
1.9
9.5
9.5
9.5
9.5
9.5
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Day 0
PARAMETER
Dinoseb
Diphenylamine
Disulfoton
Fluoranthene
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hexachloroethane
Hexachloropropene
Isodrin
Isophorone
Isosafrole
Nitrobenzene
N-Nitrosomorpholine
N-Nitrosopiperidine
o-Toluidine
Parathion
Pentachlorobenzene
Pentachloroethane
Pentachlorophenol
Phenanthrene
Phenol
Phorate
Pronamide
Pyrene
Pyridine
Safrole
Thionazin
Day 1
Location E
Greene County
Day 5
Day 14
Day 90
4/17/2009
9.6
9.6
1.9
9.6
9.6
1.9
1.9
1.9
1.9
9.6
9.6
9.6
1.9
9.6
9.6
9.6
9.6
1.9
9.6
9.6
9.6
1.9
1.9
9.6
9.6
9.6
9.6
9.6
9.6
9.6
9.6
9.6
19
9.6
9.6
1.9
1.9
9.6
9.6
1.9
200
9.6
9.6
NA
4/17/2009
9.5
9.5
1.9
9.5
9.5
1.9
1.9
1.9
1.9
9.5
9.5
9.5
1.9
9.5
9.5
9.5
9.5
1.9
9.5
9.5
9.5
1.9
1.9
9.5
9.5
9.5
9.5
9.5
9.5
9.5
9.5
9.5
19
9.5
9.5
1.9
1
9.5
9.5
1.9
57
9.5
9.5
NA
UNITS
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
PQL
10
10
2
10
10
2
2
0.05
2
2
10
10
2
10
10
10
10
2
10
10
10
2
2
10
10
10
10
10
10
10
10
10
20
10
10
2
2
10
10
2
10
10
10
10
US EPA Method
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
4,4'-DDD
4,4'-DDE
4,4'-DDT
Aldrin
alpha-BHC
beta-BHC
delta-BHC
Dieldrin
Endosulfan I
Endosulfan II
Endosulfan sulfate
Endrin
Endrin aldehyde
Endrin ketone
gamma-BHC (Lindane)
Heptachlor
Heptachlor epoxide
Methoxychlor
Toxaphene
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.1
2
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
0.049
0.049
0.049
0.049
0.049
0.049
0.49
0.049
0.049
0.049
0.049
0.049
0.049
0.049
0.049
0.049
0.049
0.049
0.098
2
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.048
0.048
0.048
0.048
0.048
0.048
0.48
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.096
1.9
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
0.05
0.05
0.05
0.05
0.05
0.062
0.5
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.043
0.05
0.1
2
PCBs
Aroclor 1016
Aroclor 1221
Aroclor 1232
Aroclor 1242
Aroclor 1248
Aroclor 1254
Aroclor 1260
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
0.4
0.4
0.4
0.4
0.4
0.4
0.4
SW846 8082
SW846 8082
SW846 8082
SW846 8082
SW846 8082
SW846 8082
SW846 8082
0.39
0.39
0.39
0.39
0.39
0.39
0.39
U
U
U
U
U
U
U
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.38
0.38
0.38
0.38
0.38
0.38
0.38
U
U
U
U
U
U
U
0.4
0.4
0.4
0.4
0.4
0.4
0.4
4/1/2009
10
10
2
10
10
2
2
2
2
10
10
10
2
10
10
10
10
2
10
10
10
2
2
10
10
10
10
10
10
10
10
10
20
10
10
1.3
2
10
10
2
35
10
10
NA
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
4/3/2009
21 U
21 U
4.2 U
21 U
21 U
4.2 U
4.2 U
4.2 U
4.2 U
21 U
21 U
21 U
4.2 U
21 U
21 U
21 U
21 U
4.2 U
21 U
21 U
21 U
4.2 U
4.2 U
21 U
21 U
21 U
21 U
21 U
21 U
21 U
21 U
21 U
42 U
21 U
21 U
4.2 U
2.6 J
21 U
21 U
4.2 U
430
21 U
21 U
NA
4/7/2009
9.4
9.4
1.9
9.4
9.4
1.9
0.27
1.9
1.9
9.4
9.4
9.4
1.9
9.4
9.4
9.4
9.4
1.9
9.4
9.4
9.4
1.9
1.9
9.4
9.4
9.4
9.4
9.4
9.4
9.4
9.4
9.4
19
9.4
9.4
1.9
3.2
9.4
9.4
1.9
310
9.4
9.4
NA
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
PG
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
PARAMETER
Location E
Greene County
Day 5
Day 0
Day 1
4/1/2009
4/3/2009
4/7/2009
NA
Day 14
Day 90
4/17/2009
4/17/2009
UNITS
PQL
US EPA Method
Ethyl parathion
ug/L
0.4
SW846 8141A
0.95 U
NA
Alcohols
2-Propanol
Butyl alcohol
Ethanol
Methanol
n-Propanol
mg/L
mg/L
mg/L
mg/L
mg/L
10
10
10
10
10
SW846 8015
SW846 8015
SW846 8015
SW846 8015
SW846 8015
10
10
10
10
10
5
20
5
5
5
Glycols
Ethylene Glycol
Propylene glycol
mg/L
mg/L
50
50
SW846 8015
SW846 8015
1000 UJ
1000 UJ
100 UJ
100 UJ
100 UJ
100 UJ
50 UJ
50 UJ
50 UJ
50 UJ
Acids
Acetic Acid
Butyric Acid
Propionic Acid
Volatile Acids
mg/L
mg/L
mg/L
mg/L
10
10
10
10
SW846 8015
SW846 8015
SW846 8015
100 UJ
100 UJ
100 UJ
230
10 UJ
10 UJ
10 UJ
290
50 UJ
50 UJ
50 UJ
260
500 UJ
500 UJ
500 UJ
380
500 UJ
500 UJ
500 UJ
380
UJ
UJ
UJ
UJ
UJ
UJ
J
UJ
UJ
UJ
5
10
5
5
5
UJ
J
UJ
UJ
UJ
0.96 U
0.99 U
10
10
10
10
10
10
10
10
10
10
UJ
UJ
UJ
UJ
UJ
UJ
UJ
UJ
UJ
UJ
PARAMETER
Acidity
Amenable cyanide
Ammonia Nitrogen
Bromide
Chloride
Fluoride
Hardness, as CaCO3
Nitrate as N
Nitrate-Nitrite
Nitrite as N
Oil & Grease (HEM)
Sulfate
TOC
Total Alkalinity
Total phosphorus
Turbidity
Cyanide, Total
Total Sulfide
pH
Sulfite
MBAS (mol.wt 320)
Aluminum
Aluminum-DISS
Antimony
Antimony-DISS
Arsenic
Arsenic-DISS
Barium
Barium-DISS
Beryllium
Beryllium-DISS
Boron
Boron-DISS
Cadmium
Cadmium-DISS
Calcium
Calcium-DISS
Chromium
Chromium-DISS
Cobalt
Cobalt-DISS
Copper
Copper-DISS
Iron
Iron-DISS
Lead
Lead-DISS
Lithium
Lithium-DISS
Magnesium
Magnesium-DISS
Manganese
Manganese-DISS
Molybdenum
Molybdenum-DISS
Nickel
Nickel-DISS
Potassium
Potassium-DISS
Selenium
Selenium-DISS
Silver
Silver-DISS
Supply Water
Day 0
3/24/2009
3/24/2009
UNITS
PQL
US EPA Method
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
umhos/cm
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
NTU
ug/L
mg/L
No Units
mg/L
mg/L
mg/L
5
0.01
0.1
2
1
10
1
-1
5
0.05
0.1
0.05
5
-1
1
5
10
3
0.1
4
-10
3
-0.01
1
0.05
SM20 2310B (4a)

SM18 4500-CN E
MCAWW 350.1
SM18 5210 B
MCAWW 300.0A
MCAWW 410.4
MCAWW 300.0A
SM20 5310B
MCAWW 300.0A
SM20 2340C
MCAWW 300.0A
MCAWW 353.2
MCAWW 300.0A
CFR136A 1664A HEM
MCAWW 120.1
MCAWW 300.0A
SM20 5310B
SM18 2320 B
SM18 2540 C
MCAWW 351.3
MCAWW 365.2
SM20 2540D
MCAWW 180.1
SW846 9012A
SW846 9030B/9034
SW846 9040
SW846 9066
SM4500-SO3 B
SM5540 C
5
0.01
20.8
2.7
0.2
13.2
18.5
3.6
NA
182
0.39
0.51
0.05
4.7
575
139
3.8
80.9
215
56.4
0.043
16.8
15.7
10
5.6
6.7
0.01
9.20
0.0613
U
U
J
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
200
200
10
10
10
10
200
200
4
4
2000
2000
5
5
5000
5000
5
5
500
500
25
25
100
100
3
3
500
500
5000
5000
150
150
400
400
40
40
5000
5000
5
5
5
5
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
2000
2000
19
100
100
100
74.7
91.6
40
40
65.9
22.2
50
50
49800
63400
50
50
500
500
250
250
882
1000
30
30
500
500
6700
8690
116
136
400
400
400
400
50000
50000
50
50
50
50
U
U
B
U
U
U
B
BJ
U
U
BJ
B
U
U
B
J
U
U
U
U
U
U
B
U
U
U
U
U
B
B
B
B
U
U
U
U
U
U
U
U
U
U
U
J
J
U
U
J
J
J
Location F
Washington, PA
Day 1
3/27/2009
5
0.01
12.9
154
0.2
851
30.7
288
0.1
190
0.41
0.47
0.05
7.3
476
59.2
205
126
462
33.5
0.44
90
145
10
8.8
7
0.085
61.6
0.112
U
U
J
2000
189
100
100
100
100
91.4
95.2
40
40
122
39.6
50
50
59500
61800
50
50
500
500
49.3
250
2440
2310
30
30
30.1
29.4
7910
8410
140
128
400
400
25.1
400
50000
50000
50
50
50
50
U
B
U
U
U
U
B
BJ
U
U
BJ
B
U
U
U
J
J
U
J
B
U
J
U
U
U
U
B
U
U
U
B
B
B
B
B
B
U
U
B
U
U
U
U
U
U
U
5
0.01
60.3
75.4
376
2470
31500
40.2
1.2
12300
1.4
0.45
1.2
4.9
124000
102
43.5
157
61200
77.7
0.22
6.8
14.8
10
2.4
6.4
0.058
5
0.0641
510
282
100
100
36.9
23
19200
16600
40
40
12600
12400
50
50
3980000
3850000
11.4
50
10.5
9.5
62.1
50.3
12200
10600
25.2
19
33900
33000
394000
386000
2390
2300
11.5
11.2
15.3
9.3
157000
160000
50
50
50
50
U
U
J
J
J
GU
J
GU
U
J
U
B
B
B
U
U
B
B
J
U
U
J
U
U
J
B
U
B
B
B
B
B
B
B
B
B
B
U
U
U
U
Day 5
Day 14
Day 90
4/1/2009
4/9/2009
6/29/2009
5
0.01
115
64.8
826
5170
72000
47.3
5
34000
5
0.34
5
20.4
233000
60.7
62.8
54
116000
55.9
0.16
204
45.6
10
3
6.4
0.016
13.6
0.05
950
363
100
100
78.4
91.2
77100
55200
40
40
12200
16900
2.2
3
8880000
12000000
39.3
12.1
1000
1000
116
250
49600
45700
61
63.8
55900
78800
881000
1180000
4680
6120
30.8
20.2
26.4
800
246000
336000
50
50
50
50
U
U
J
J
GU
GU
J
GU
J
B
J
U
U
J
U
B
B
U
U
B
B
U
U
J
J
B
B
B
B
U
U
B
U
B
B
B
U
U
U
U
U
122
0.01
135
120
1040
8370
100000
10.8
2
53000
2.5
0.25
2.5
9.9
288000
89.3
44
60.2
157000
127
0.09
209
254
10
3
6.2
0.01
18.8
0.465
1450
395
100
100
82.8
63.2
83100
75700
40
40
14700
15400
4.7
3.8
14000000
14300000
32.8
11.6
2500
2500
73.3
250
75200
47300
106
150
86000
94500
1380000
1370000
7320
7740
400
400
2000
2000
368000
394000
50
50
50
5.6
U
J
J
B
GU
J
GU
J
J
J
J
U
U
U
B
B
U
U
B
B
U
U
J
J
B
B
B
B
U
U
B
U
B
U
U
U
U
U
U
U
U
B
388
0.01
168
12400
1600
18400
138000
1480
2.5
77000
2.5
0.1
2.5
802
480000
32.8
1530
11.5
200000
87.7
0.1
83
134
10
4.8
5.9
0.23
8.80
0.699
2570
2000
38.3
100
109
99
87200
104000
40
40
12700
15900
3.2
2.8
19800000
24600000
15.8
16
5000
46
250
32.4
68700
74200
300
300
105000
127000
1830000
2320000
8990
11000
400
400
4000
4000
366000
461000
49.9
50
50
50
U
J
J
GU
GU
U
GU
J
BJ
J
U
B
U
B
U
U
B
B
J
J
B
B
U
B
U
B
J
U
U
J
U
U
U
U
B
U
U
U
PARAMETER
Sodium
Sodium-DISS
Strontium
Strontium-DISS
Thallium
Thallium-DISS
Tin
Tin-DISS
Titanium
Titanium-DISS
Trivalent Chrom
Zinc
Zinc-DISS
Hexavalent Chromium
Mercury
Mercury-DISS
1,1-Dichloroethane
1,1-Dichloroethene
1,1-Dichloropropene
1,2-Dichlorobenzene
1,2-Dichloroethane
1,2-Dichloropropane
1,3-Dichlorobenzene
1,3-Dichloropropane
1,4-Dichlorobenzene
1,4-Dioxane
2,2-Dichloropropane
2-Butanone
2-Hexanone
4-Chlorotoluene
Acetone
Acrolein
Acrylonitrile
Benzene
Benzyl chloride
Bromobenzene
Bromoform
Bromomethane
Carbon disulfide
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
Dibromomethane
Ethylbenzene
Isopropylbenzene
Methylene chloride
Naphthalene
n-Butylbenzene
n-Propylbenzene
p-Isopropyltoluene
sec-Butylbenzene
Styrene
UNITS
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
mg/L
mg/L
ug/L
ug/L
PQL
5000
5000
50
50
10
10
1000
1000
500
500
50
20
20
0.01
0.01
0.2
0.2
US EPA Method
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 7196A
SW846 7196A
SW846 7470A
SW846 7470A
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
1000
-5
5
10
5
5
5
20
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
Supply Water
Day 0
3/24/2009
3/24/2009
25700
27400
303
312
100
100
1000
1000
500
500
50
59.5
38.8
0.01
0.02
0.66
0.93
7980
9540
220
274
100
100
1000
1000
500
500
50
200
200
0.01
0.01
0.61
0.66
B
B
B
B
U
U
U
U
U
U
U
U
U
U
U
BJ
BJ
5
5
5
5
5
5
5
5
5
5
0.61
5
5
5
5
5
5
5
5
5
1000
NA
5
5
10
5
5
5
20
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
1.1
5
5
5
5
5
5
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
1000
NA
5
5
10
5
5
5
6
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
Location F
Washington, PA
Day 1
B
B
B
B
U
U
U
U
U
U
U
BJ
B
U
GU
BJ
BJ
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
3/27/2009
14700000
14700000
539000
531000
100
100
1000
1000
39.9
55.3
50
132
42
0.011
0.014
0.065
0.064
10
10
10
10
10
10
10
10
10
10
11
10
10
10
10
10
5.2
10
10
10
2000
NA
10
10
20
10
10
10
14
200
200
280
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
7.6
10
10
10
10
10
10
10
10
10
U
U
U
U
B
B
U
BJ
B
BJ
BJ
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
Day 5
Day 14
Day 90
4/1/2009
23700000
31600000
1350000
1880000
200
200
1000
1000
126
170
11.8
106
84.6
0.01
0.05
0.2
0.2
4/9/2009
34000000
36400000
2100000
2330000
500
500
1000
1000
192
187
11.6
123
92.8
0.25
0.25
0.2
0.2
6/29/2009
39000000
47800000
3410000
4140000
1000
1000
1000
1000
260
264
15.8
218
250
0.25
0.25
0.2
0.2
50
50
50
50
50
50
50
50
50
50
52
50
50
50
50
50
33
50
50
50
10000
NA
50
50
100
50
50
50
200
1000
1000
880
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
29
50
50
50
50
50
50
50
50
50
U
U
U
U
B
B
B
B
B
U
GU
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
25
25
25
25
25
25
25
25
25
25
33
25
25
25
25
25
21
25
25
25
5000
NA
25
25
50
25
25
25
98
500
500
400
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
23
25
25
25
25
25
25
25
25
25
U
U
U
U
B
B
B
B
B
GU
GU
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
250
250
250
250
250
250
250
170
250
66
980
250
250
250
250
250
820
250
250
250
50000
NA
250
250
500
250
250
250
1000
5000
5000
290
250
250
250
250
250
250
250
250
250
250
250
250
250
250
250
250
270
250
250
250
130
250
250
250
250
250
J
J
U
U
U
U
B
B
B
J
GU
GU
U
U
U
U
U
U
U
U
U
J
U
J
U
U
U
U
U
U
U
U
U
ND U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
PARAMETER
tert-butyl acetate
tert-Butylbenzene
Tetrachloroethene
tetrahydrofuran
Toluene
Trichloroethene
Vinyl acetate
Vinyl chloride
Xylenes (total)
1,3-Dinitrobenzene
1,4-Naphthoquinone
1-Naphthylamine
2,3,7,8-TCDD
2,4-Dimethylphenol
2,4-Dinitrophenol
2,4-Dinitrotoluene
2,6-Dichlorophenol
2,6-Dinitrotoluene
2-Chloronaphthalene
2-Chlorophenol
2-Methylnaphthalene
2-Methylphenol
2-Naphthylamine
2-Nitroaniline
2-Nitrophenol
2-Picoline
3-Nitroaniline
4-Aminobiphenyl
4-Chloroaniline
4-Nitroaniline
4-Nitrophenol
5-Nitro-o-toluidine
Acenaphthene
Acenaphthylene
Acetophenone
Aniline
Aramite
Benzidine
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(ghi)perylene
Benzyl alcohol
Chlorobenzilate
Chrysene
Diallate
Dibenzofuran
Diethyl phthalate
Dimethoate
Dimethyl phthalate
UNITS
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
PQL
-5
5
-5
5
5
5
5
5
5
15
US EPA Method
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
10
2
10
10
10
10
-10
10
10
40
10
2
10
10
2
10
2
10
10
50
10
10
10
10
10
50
50
10
10
10
10
10
50
50
100
10
2
2
10
10
10
200
10
5
2
2
2
10
10
2
2
10
10
10
2
10
2
10
10
10
10
10
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
Supply Water
Day 0
3/24/2009
3/24/2009
NA
5
5
NA
5
5
5
5
5
5
5
15
NA
5
5
NA
1.1
5
5
5
5
5
5
15
9.8
2
9.8
9.8
9.8
9.8
NA
9.8
9.8
9.8
49
9.8
2
9.8
9.8
2
9.8
0.85
9.8
9.8
49
9.8
9.8
9.8
9.8
9.8
49
49
9.8
9.8
9.8
9.8
9.8
49
49
98
9.8
2
2
0.46
9.8
9.8
200
2
2
2
2
2
9.8
9.8
2
2
2.2
9.8
9.8
2
9.8
2
9.8
2.3
9.8
9.8
9.8
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
JB
U
U
U
9.4
1.9
9.4
9.4
9.4
9.4
NA
9.4
9.4
9.4
47
9.4
1.9
9.4
9.4
1.9
9.4
1.9
9.4
9.4
47
9.4
9.4
9.4
9.4
9.4
47
47
9.4
9.4
9.4
9.4
9.4
47
47
94
9.4
1.9
1.9
9.4
9.4
9.4
190
1.9
1.9
1.9
1.9
1.9
9.4
9.4
1.9
1.9
9.4
9.4
9.4
1.9
9.4
1.9
9.4
1.8
9.4
9.4
0.29
Location F
Washington, PA
Day 1
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
JB
U
U
J
3/27/2009
NA
10
10
NA
300
10
10
10
10
10
10
120
19
3.8
19
19
19
19
NA
19
19
9.8
94
19
3.8
19
19
3.8
19
3.8
9
19
94
19
19
19
19
14
94
94
19
19
19
19
19
94
94
190
19
3.8
3.8
19
19
19
380
3.8
3.8
3.8
3.8
3.8
19
19
3.8
3.8
19
19
19
3.8
19
3.8
19
19
19
19
19
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Day 5
Day 14
Day 90
4/1/2009
NA
50
50
NA
920
50
50
50
50
50
50
340
4/9/2009
NA
25
25
NA
540
25
25
25
25
25
25
280
6/29/2009
NA
250
250
NA
1600
250
250
250
250
250
250
3300
10
2
10
10
10
10
NA
10
10
7.1
50
10
2
10
10
2
10
2
7.9
10
50
10
10
10
10
11
50
50
10
10
10
10
10
50
50
100
10
2
2
11
10
10
200
2
2
2
2
2
10
10
2
2
33
10
10
2
10
2
10
10
10
10
14
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
47
9.4
47
47
47
47
NA
47
47
8.3
240
47
9.4
47
47
9.4
47
9.4
7.5
47
240
47
47
47
47
12
240
240
47
47
47
47
47
240
240
470
47
9.4
9.4
47
47
47
940
9.4
9.4
9.4
9.4
9.4
47
47
9.4
9.4
870
47
47
9.4
47
9.4
47
47
47
47
47
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
94
19
94
94
94
94
NA
94
94
94
470
94
19
94
94
19
94
19
94
94
470
94
94
94
94
94
470
470
94
94
94
94
94
470
470
940
94
19
19
94
94
94
1900
19
19
19
19
19
94
94
19
19
94
94
94
19
94
19
9
94
94
94
94
U
U
ND U
U
U
U
U
U
U
U
U
U
U
U
U
ND U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
PARAMETER
Dinoseb
Diphenylamine
Disulfoton
Fluoranthene
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hexachloroethane
Hexachloropropene
Isodrin
Isophorone
Isosafrole
Nitrobenzene
N-Nitrosomorpholine
N-Nitrosopiperidine
o-Toluidine
Parathion
Pentachlorobenzene
Pentachloroethane
Pentachlorophenol
Phenanthrene
Phenol
Phorate
Pronamide
Pyrene
Pyridine
Safrole
Thionazin
UNITS
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
PQL
10
10
2
10
10
2
2
0.05
2
2
10
10
2
10
10
10
10
2
10
10
10
2
2
10
10
10
10
10
10
10
10
10
20
10
10
2
2
10
10
2
10
10
10
10
US EPA Method
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
4,4'-DDD
4,4'-DDE
4,4'-DDT
Aldrin
alpha-BHC
beta-BHC
delta-BHC
Dieldrin
Endosulfan I
Endosulfan II
Endosulfan sulfate
Endrin
Endrin aldehyde
Endrin ketone
gamma-BHC (Lindane)
Heptachlor
Heptachlor epoxide
Methoxychlor
Toxaphene
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.1
2
PCBs
Aroclor 1016
Aroclor 1221
Aroclor 1232
Aroclor 1242
Aroclor 1248
Aroclor 1254
Aroclor 1260
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
0.4
0.4
0.4
0.4
0.4
0.4
0.4
Supply Water
Day 0
3/24/2009
Location F
Washington, PA
Day 1
Day 5
Day 14
Day 90
4/9/2009
47
47
9.4
47
47
9.4
9.4
9.4
9.4
47
47
47
9.4
47
47
47
47
9.4
47
47
47
9.4
9.4
47
47
47
47
47
47
47
47
47
94
47
47
9.4
16
47
47
9.4
220
47
0.95
NA
6/29/2009
94
94
19
94
94
19
19
19
19
94
94
94
19
94
94
94
94
19
94
94
94
19
19
94
94
94
94
94
94
94
94
94
190
94
94
3
19
94
94
19
140
94
4.8
NA
9.8
9.8
2
9.8
9.8
2
2
2
2
9.8
9.8
9.8
2
9.8
1.3
9.8
9.8
2
9.8
9.8
9.8
2
2
9.8
9.8
9.8
9.8
9.8
9.8
9.8
9.8
9.8
20
9.8
9.8
0.6
2
9.8
9.8
2
9.8
9.8
0.95
NA
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
0.048
0.048
0.048
0.048
0.048
0.048
0.48
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.095
1.9
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
0.047
0.047
0.047
0.047
0.047
0.047
0.47
0.047
0.047
0.047
0.047
0.047
0.047
0.047
0.047
0.047
0.047
0.047
0.094
1.9
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.048
0.048
0.048
0.048
0.048
0.048
0.48
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.097
1.9
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
0.049
0.049
0.049
0.12
0.049
0.049
0.49
0.049
0.049
0.049
0.049
0.049
0.049
0.049
0.049
0.049
0.093
0.049
0.098
2
SW846 8082
SW846 8082
SW846 8082
SW846 8082
SW846 8082
SW846 8082
SW846 8082
0.38
0.38
0.38
0.38
0.38
0.38
0.38
U
U
U
U
U
U
U
0.38
0.38
0.38
0.38
0.38
0.38
0.38
U
U
U
U
U
U
U
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.39
0.39
0.39
0.39
0.39
0.39
0.39
U
U
U
U
U
U
U
0.39
0.39
0.39
0.39
0.39
0.39
0.39
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
3/27/2009
19
19
3.8
19
19
3.8
3.8
3.8
3.8
19
19
19
3.8
19
19
19
19
3.8
19
19
19
3.8
3.8
19
19
19
19
19
19
19
19
19
38
19
19
3.8
16
19
19
3.8
520
19
19
NA
4/1/2009
10
10
2
10
10
2
2
2
2
10
10
10
2
10
10
10
10
2
10
10
10
2
2
10
10
10
10
10
10
10
10
10
20
10
10
0.29
15
10
10
2
250
10
10
NA
3/24/2009
9.4
9.4
1.9
9.4
9.4
1.9
1.9
1.9
1.9
9.4
9.4
9.4
1.9
9.4
9.4
9.4
9.4
1.9
9.4
9.4
9.4
1.9
1.9
9.4
9.4
9.4
9.4
9.4
9.4
9.4
9.4
9.4
19
9.4
9.4
1.9
1.9
9.4
9.4
1.9
370
9.4
0.95
NA
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
PG
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
PARAMETER
Location F
Washington, PA
Day 1
Supply Water
Day 0
3/24/2009
3/24/2009
UNITS
PQL
US EPA Method
Ethyl parathion
ug/L
0.4
SW846 8141A
0.95 U
0.95 U
NA
Alcohols
2-Propanol
Butyl alcohol
Ethanol
Methanol
n-Propanol
mg/L
mg/L
mg/L
mg/L
mg/L
10
10
10
10
10
SW846 8015
SW846 8015
SW846 8015
SW846 8015
SW846 8015
1
1
1
1
1
1
1
1
1.2
1
1
1
1
3.4
1
Glycols
Ethylene Glycol
Propylene glycol
mg/L
mg/L
50
50
SW846 8015
SW846 8015
10 U
10 U
44
10 U
Acids
Acetic Acid
Butyric Acid
Propionic Acid
Volatile Acids
mg/L
mg/L
mg/L
mg/L
10
10
10
10
SW846 8015
SW846 8015
SW846 8015
NA
NA
NA
NA
NA
NA
NA
75
U
U
U
U
U
3/27/2009
U
U
U
U
Day 5
Day 14
Day 90
4/1/2009
4/9/2009
6/29/2009
NA
U
U
U
U
10 U
31 B
10 UJ
10 UJ
10 UJ
1000
5
5
5
5
5
0.95 U
UJ
UJ
UJ
UJ
UJ
10
10
10
10
10
UJ
UJ
UJ
UJ
UJ
4.8 U
200
200
200
4500
200
UJ
UJ
UJ
J
UJ
100 UJ
100 UJ
100 UJ
100 UJ
290 J
250 UJ
10 UJ
10 UJ
10 UJ
230
100 UJ
100 UJ
100 UJ
51000
50 UJ
50 UJ
50 UJ
100000
PARAMETER
Acidity
Amenable cyanide
Ammonia Nitrogen
Bromide
Chloride
Fluoride
Hardness, as CaCO3
Nitrate as N
Nitrate-Nitrite
Nitrite as N
Oil & Grease (HEM)
Sulfate
TOC
Total Alkalinity
Total phosphorus
Turbidity
Cyanide, Total
Total Sulfide
pH
Sulfite
MBAS (mol.wt 320)
Aluminum
Aluminum-DISS
Antimony
Antimony-DISS
Arsenic
Arsenic-DISS
Barium
Barium-DISS
Beryllium
Beryllium-DISS
Boron
Boron-DISS
Cadmium
Cadmium-DISS
Calcium
Calcium-DISS
Chromium
Chromium-DISS
Cobalt
Cobalt-DISS
Copper
Copper-DISS
Iron
Iron-DISS
Lead
Lead-DISS
Lithium
Lithium-DISS
Magnesium
Magnesium-DISS
Manganese
Manganese-DISS
Molybdenum
Molybdenum-DISS
Nickel
Nickel-DISS
Potassium
Potassium-DISS
Selenium
Selenium-DISS
Silver
Silver-DISS
Day 0
Day 1
Location G
Lycoming County, PA
Day 5
3/31/2009
4/8/2009
4/13/2009
UNITS
PQL
US EPA Method
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
umhos/cm
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
NTU
ug/L
mg/L
No Units
mg/L
mg/L
mg/L
5
0.01
0.1
2
1
10
1
-1
5
0.05
0.1
0.05
5
-1
1
5
10
3
0.1
4
-10
3
-0.01
1
0.05
SM20 2310B (4a)

SM18 4500-CN E
MCAWW 350.1
SM18 5210 B
MCAWW 300.0A
MCAWW 410.4
MCAWW 300.0A
SM20 5310B
MCAWW 300.0A
SM20 2340C
MCAWW 300.0A
MCAWW 353.2
MCAWW 300.0A
CFR136A 1664A HEM
MCAWW 120.1
MCAWW 300.0A
SM20 5310B
SM18 2320 B
SM18 2540 C
MCAWW 351.3
MCAWW 365.2
SM20 2540D
MCAWW 180.1
SW846 9012A
SW846 9030B/9034
SW846 9040
SW846 9066
SM4500-SO3 B
SM5540 C
1230
0.01
441
189
0.2
502
86
11.6
0.19
130
3.4
2.4
2.5
4.7
6720
2920
11.4
5
1920
400
0.26
4
4.7
10
3
6
0.017
5
0.0933
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
200
200
10
10
10
10
200
200
4
4
2000
2000
5
5
5000
5000
5
5
500
500
25
25
100
100
3
3
500
500
5000
5000
150
150
400
400
40
40
5000
5000
5
5
5
5
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
2000
2000
100
100
100
100
339
348
40
40
59.3
68.7
50
50
32900
31800
50
50
7.9
14.2
120
85.3
14300
13100
30
30
34.1
38.7
6190
6240
67.2
73.7
400
400
457
452
50000
50000
50
50
50
50
U
J
U
J
GU
U
J
J
U
U
U
J
U
U
U
U
U
U
U
B
B
U
U
BJ
BJ
U
U
B
B
U
U
B
B
B
B
U
U
B
B
B
B
B
B
U
U
U
U
U
U
U
U
5
0.01
71.4
302
261
2100
43300
124
2.2
15000
1.6
1.9
2.5
4.6
147000
19
123
124
74600
69.9
0.19
68
126
10
3
7
0.01
5.60
2.94
505
358
100
100
28.2
37.4
1160000
1340000
40
40
3030
3470
50
50
4070000
4360000
50
50
2500
2500
250
250
15700
3690
30
30
80300
93000
271000
293000
1680
1930
8.9
12.1
14.9
20.1
127000
144000
50
50
50
50
U
U
J
J
B
B
J
GU
U
J
BJ
J
U
U
U
B
B
U
U
B
B
U
U
J
J
U
U
U
U
U
U
U
U
U
U
B
B
B
B
U
U
U
U
5
0.01
NA
144
553
4470
77200
58.4
2.4
44000
2
0.63
2.5
10.8
278000
39.2
60.8
72.4
125000
94.9
2.5
260
92
10
3
6.3
0.0084
23.2
0.736
927
508
100
100
54.2
70.5
3220000
3260000
40
40
3840
3890
3
50
9270000
9700000
20.8
50
1000
5000
73.3
250
33500
16700
40.4
150
153000
155000
608000
647000
3440
3550
12.4
400
800
2000
210000
235000
50
50
9.3
50
B
B
J
GU
J
BJ
J
GU
U
U
B
BJ
BJ
U
U
B
B
J
U
U
BJ
U
J
J
BJ
U
U
U
B
U
J
BJ
U
J
J
B
U
U
U
U
U
B
U
Day 15
Day 90
4/22/2009
10/21/2009
19.4
0.01
359
7.3
697
12800
102000
43
2.5
55000
2.5
0.16
2.5
4.6
360000
49.4
42.2
47.7
169000
130
2.5
162
32.9
10
1.6
6.4
0.011
13.6
1.06
835
562
100
100
77.3
82.3
5150000
5070000
40
40
3880
3820
3.8
3.2
13100000
14800000
12.7
6.6
5000
5000
250
250
39200
31500
78
150
201000
202000
781000
875000
4780
5170
400
400
2000
2000
312000
274000
39.4
49.5
8.4
8.1
U
J
J
GU
GU
J
GU
U
J
BJ
J
GU
U
B
J
BJ
BJ
U
U
B
B
J
U
U
BJ
B
J
J
BJ
B
U
U
U
U
J
BJ
U
J
J
U
U
U
U
B
B
B
B
149
0.01
220
2
171
12700
166000
16.4
5
96000
5
0.051
146
4.8
742000
100
63.3
25
298000
157
1
71.5
94.5
10
3
5.8
0.01
NA
NA
173
167
100
100
100
100
8450000
7530000
40
40
2990
2680
50
50
22900000
20500000
50
50
5000
5000
250
250
58700
41700
30
30
262000
230000
1280000
1170000
9740
8760
400
54.4
400
400
547000
477000
50
50
50
50
U
J
U
J
J
GU
GU
B
U
GU
J
J
GU
U
U
U
BJ
BJ
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
J
U
B
U
U
U
U
U
U
Day 0
PARAMETER
Sodium
Sodium-DISS
Strontium
Strontium-DISS
Thallium
Thallium-DISS
Tin
Tin-DISS
Titanium
Titanium-DISS
Trivalent Chrom
Zinc
Zinc-DISS
Hexavalent Chromium
Mercury
Mercury-DISS
1,1-Dichloroethane
1,1-Dichloroethene
1,1-Dichloropropene
1,2-Dichlorobenzene
1,2-Dichloroethane
1,2-Dichloropropane
1,3-Dichlorobenzene
1,3-Dichloropropane
1,4-Dichlorobenzene
1,4-Dioxane
2,2-Dichloropropane
2-Butanone
2-Hexanone
4-Chlorotoluene
Acetone
Acrolein
Acrylonitrile
Benzene
Benzyl chloride
Bromobenzene
Bromoform
Bromomethane
Carbon disulfide
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
Dibromomethane
Ethylbenzene
Isopropylbenzene
Methylene chloride
Naphthalene
n-Butylbenzene
n-Propylbenzene
p-Isopropyltoluene
sec-Butylbenzene
Styrene
UNITS
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
mg/L
mg/L
ug/L
ug/L
PQL
5000
5000
50
50
10
10
1000
1000
500
500
50
20
20
0.01
0.01
0.2
0.2
US EPA Method
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 7196A
SW846 7196A
SW846 7470A
SW846 7470A
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
1000
-5
5
10
5
5
5
20
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
3/31/2009
45000
44700
691
686
100
100
1000
1000
500
500
50
40.7
46.9
0.01
0.01
0.2
0.2
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
1000
NA
5
5
10
5
5
5
20
100
100
2.2
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
Day 1
B
B
U
U
U
U
U
U
U
B
B
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
4/8/2009
18100000
20900000
947000
1090000
100
100
1000
1000
55.9
105
50
200
200
0.5
0.5
0.2
0.2
5
5
5
5
5
5
5
5
5
5
1.3
5
5
5
5
5
5
5
5
5
1000
NA
5
5
10
5
5
5
13
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
1.7
5
5
5
5
5
U
U
U
U
B
B
U
U
U
GU
GU
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
Location G
Lycoming County, PA
Day 5
Day 15
Day 90
4/13/2009
30800000
31400000
2350000
2530000
200
500
1000
1000
133
121
50
67.6
41.6
1
1
0.2
0.2
4/22/2009
40300000
41100000
3650000
3710000
500
500
1000
1000
148
138
50
52.2
49.8
2.5
2.5
0.2
0.2
10/21/2009
58600000
50700000
6390000
5710000
26.4
53.8
1000
29.8
500
500
50
48
42.3
2
2
0.2
0.2
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
1000
NA
5
5
10
5
5
5
16
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
J
J
U
U
U
U
B
B
U
BJ
B
GU
GU
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
1000
NA
5
5
10
5
5
5
26
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
J
J
U
U
U
U
B
B
U
BJ
B
GU
GU
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
1000
NA
5
5
10
5
5
5
12
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
J
J
J
B
B
U
B
U
U
U
BJ
BJ
GU
GU
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Day 0
PARAMETER
tert-butyl acetate
tert-Butylbenzene
Tetrachloroethene
tetrahydrofuran
Toluene
Trichloroethene
Vinyl acetate
Vinyl chloride
Xylenes (total)
1,3-Dinitrobenzene
1,4-Naphthoquinone
1-Naphthylamine
2,3,7,8-TCDD
2,4-Dimethylphenol
2,4-Dinitrophenol
2,4-Dinitrotoluene
2,6-Dichlorophenol
2,6-Dinitrotoluene
2-Chloronaphthalene
2-Chlorophenol
2-Methylnaphthalene
2-Methylphenol
2-Naphthylamine
2-Nitroaniline
2-Nitrophenol
2-Picoline
3-Nitroaniline
4-Aminobiphenyl
4-Chloroaniline
4-Nitroaniline
4-Nitrophenol
5-Nitro-o-toluidine
Acenaphthene
Acenaphthylene
Acetophenone
Aniline
Aramite
Benzidine
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(ghi)perylene
Benzyl alcohol
Chlorobenzilate
Chrysene
Diallate
Dibenzofuran
Diethyl phthalate
Dimethoate
Dimethyl phthalate
UNITS
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
PQL
-5
5
-5
5
5
5
5
5
5
15
US EPA Method
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
10
2
10
10
10
10
-10
10
10
40
10
2
10
10
2
10
2
10
10
50
10
10
10
10
10
50
50
10
10
10
10
10
50
50
100
10
2
2
10
10
10
200
10
5
2
2
2
10
10
2
2
10
10
10
2
10
2
10
10
10
10
10
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
3/31/2009
NA
5
5
NA
5
5
5
5
5
5
5
15
9.4
1.9
9.4
9.4
9.4
9.4
NA
9.4
9.4
9.4
47
9.4
1.9
9.4
9.4
1.9
9.4
1.9
9.4
9.4
47
9.4
9.4
9.4
9.4
9.4
47
47
9.4
9.4
9.4
9.4
9.4
47
47
94
9.4
1.9
1.9
0.21
9.4
9.4
190
1.9
1.9
1.9
1.9
1.9
9.4
9.4
1.9
1.9
9.4
9.4
9.4
1.9
9.4
1.9
9.4
9.4
9.4
9.4
9.4
Day 1
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
4/8/2009
NA
5
5
NA
5
5
5
5
5
5
5
15
9.2
1.8
9.2
9.2
9.2
9.2
NA
9.2
9.2
9.2
46
9.2
1.8
9.2
9.2
1.8
9.2
2.7
9.2
9.2
46
9.2
9.2
9.2
9.2
9.2
46
46
9.2
9.2
9.2
9.2
9.2
46
46
92
9.2
0.22
1.8
0.98
9.2
9.2
180
1.8
1.8
1.8
1.8
1.8
9.2
9.2
1.8
1.8
9.2
9.2
9.2
1.8
9.2
1.8
9.2
9.2
9.2
9.2
9.2
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Location G
Lycoming County, PA
Day 5
Day 15
Day 90
4/13/2009
NA
5
5
NA
5
5
5
5
5
5
5
15
4/22/2009
NA
5
5
NA
5
5
5
5
5
5
5
15
10/21/2009
NA
5
5
NA
5
5
5
5
5
5
5
15
9.4
1.9
9.4
9.4
9.4
9.4
NA
9.4
9.4
9.4
47
9.4
1.9
9.4
9.4
1.9
9.4
1.9
9.4
9.4
47
9.4
9.4
9.4
9.4
9.4
47
47
9.4
9.4
9.4
9.4
9.4
47
47
94
9.4
1.9
1.9
0.81
9.4
9.4
190
1.9
1.9
1.9
1.9
1.9
9.4
9.4
1.9
1.9
9.4
9.4
9.4
1.9
9.4
1.9
9.4
1.1
9.4
9.4
9.4
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
9.5
1.9
9.5
9.5
9.5
9.5
NA
9.5
9.5
9.5
48
9.5
1.9
9.5
9.5
1.9
9.5
1.9
9.5
9.5
48
9.5
9.5
9.5
9.5
9.5
48
48
9.5
9.5
9.5
9.5
9.5
2.6
48
95
9.5
1.9
1.9
0.38
9.5
9.5
190
1.9
1.9
1.9
1.9
1.9
9.5
9.5
1.9
1.9
9.5
9.5
9.5
1.9
9.5
1.9
9.5
9.5
9.5
9.5
9.5
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
10
2
10
10
10
10
NA
10
10
10
50
10
2
10
10
2
10
2
10
10
50
10
10
10
10
10
50
50
10
10
10
10
10
50
50
100
10
2
2
10
10
10
200
2
2
2
2
2
10
10
2
2
10
10
10
2
10
2
10
10
10
10
10
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Day 0
PARAMETER
Dinoseb
Diphenylamine
Disulfoton
Fluoranthene
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hexachloroethane
Hexachloropropene
Isodrin
Isophorone
Isosafrole
Nitrobenzene
N-Nitrosomorpholine
N-Nitrosopiperidine
o-Toluidine
Parathion
Pentachlorobenzene
Pentachloroethane
Pentachlorophenol
Phenanthrene
Phenol
Phorate
Pronamide
Pyrene
Pyridine
Safrole
Thionazin
UNITS
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
PQL
10
10
2
10
10
2
2
0.05
2
2
10
10
2
10
10
10
10
2
10
10
10
2
2
10
10
10
10
10
10
10
10
10
20
10
10
2
2
10
10
2
10
10
10
10
US EPA Method
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
4,4'-DDD
4,4'-DDE
4,4'-DDT
Aldrin
alpha-BHC
beta-BHC
delta-BHC
Dieldrin
Endosulfan I
Endosulfan II
Endosulfan sulfate
Endrin
Endrin aldehyde
Endrin ketone
gamma-BHC (Lindane)
Heptachlor
Heptachlor epoxide
Methoxychlor
Toxaphene
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.1
2
PCBs
Aroclor 1016
Aroclor 1221
Aroclor 1232
Aroclor 1242
Aroclor 1248
Aroclor 1254
Aroclor 1260
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
0.4
0.4
0.4
0.4
0.4
0.4
0.4
Day 1
Location G
Lycoming County, PA
Day 5
Day 15
Day 90
4/13/2009
9.4
9.4
1.9
9.4
9.4
1.9
1.9
1.9
1.9
9.4
9.4
9.4
1.9
9.4
9.4
9.4
9.4
1.9
9.4
9.4
9.4
1.9
1.9
9.4
9.4
9.4
9.4
9.4
9.4
9.4
9.4
9.4
19
9.4
9.4
1.9
1.9
9.4
9.4
1.9
30
9.4
9.4
NA
4/22/2009
9.5
9.5
1.9
9.5
9.5
1.9
1.9
1.9
1.9
9.5
9.5
9.5
1.9
9.5
9.5
9.5
9.5
1.9
9.5
9.5
9.5
1.9
1.9
9.5
9.5
9.5
9.5
9.5
9.5
9.5
9.5
9.5
19
9.5
9.5
1.9
1.9
9.5
9.5
1.9
14
9.5
9.5
NA
10/21/2009
10
10
2
10
10
2
2
2
2
10
10
10
2
10
10
10
10
2
10
10
10
2
2
10
10
10
10
10
10
10
10
10
20
10
10
2
2
10
10
2
10
10
10
NA
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
3/31/2009
9.4
9.4
1.9
9.4
9.4
1.9
1.9
1.9
1.9
9.4
9.4
9.4
1.9
9.4
9.4
9.4
9.4
1.9
9.4
9.4
9.4
1.9
1.9
9.4
9.4
9.4
9.4
9.4
9.4
9.4
9.4
9.4
19
9.4
9.4
1.9
1.9
9.4
9.4
1.9
9.4
9.4
9.4
NA
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
4/8/2009
9.2
9.2
1.8
9.2
9.2
1.8
0.22
1.8
1.8
9.2
9.2
9.2
1.8
9.2
9.2
9.2
9.2
1.8
9.2
9.2
9.2
1.8
1.8
9.2
9.2
9.2
9.2
9.2
9.2
9.2
9.2
9.2
18
9.2
9.2
1.8
1.8
9.2
9.2
1.8
55
9.2
9.2
NA
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
0.048
0.048
0.048
0.048
0.048
0.048
0.48
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.095
1.9
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.047
0.047
0.047
0.047
0.047
0.047
0.47
0.047
0.047
0.047
0.047
0.047
0.047
0.047
0.047
0.047
0.047
0.047
0.094
1.9
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
0.072
0.072
0.072
0.072
0.072
0.072
0.72
0.072
0.072
0.072
0.072
0.072
0.072
0.072
0.072
0.072
0.072
0.072
0.14
2.9
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
SW846 8082
SW846 8082
SW846 8082
SW846 8082
SW846 8082
SW846 8082
SW846 8082
0.38
0.38
0.38
0.38
0.38
0.38
0.38
U
U
U
U
U
U
U
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.38
0.38
0.38
0.38
0.38
0.38
0.38
U
U
U
U
U
U
U
0.4
0.4
0.4
0.4
0.4
0.4
0.4
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
PARAMETER
Day 0
Day 1
Location G
Lycoming County, PA
Day 5
Day 15
Day 90
3/31/2009
4/8/2009
4/13/2009
4/22/2009
10/21/2009
UNITS
PQL
US EPA Method
Ethyl parathion
ug/L
0.4
SW846 8141A
0.94 U
NA
NA
Alcohols
2-Propanol
Butyl alcohol
Ethanol
Methanol
n-Propanol
mg/L
mg/L
mg/L
mg/L
mg/L
10
10
10
10
10
SW846 8015
SW846 8015
SW846 8015
SW846 8015
SW846 8015
5
5
5
8.3
5
UJ
UJ
UJ
J
UJ
NA
NA
NA
NA
NA
10
10
10
58
10
Glycols
Ethylene Glycol
Propylene glycol
mg/L
mg/L
50
50
SW846 8015
SW846 8015
100 UJ
100 UJ
NA
NA
100 UJ
100 UJ
Acids
Acetic Acid
Butyric Acid
Propionic Acid
Volatile Acids
mg/L
mg/L
mg/L
mg/L
10
10
10
10
SW846 8015
SW846 8015
SW846 8015
10 UJ
10 UJ
10 UJ
250
NA
NA
NA
NA
100 U
100 U
100 U
430
0.94 U
UJ
UJ
UJ
J
UJ
10
10
10
39
10
1U
UJ
UJ
UJ
J
UJ
NA
NA
NA
NA
NA
100 UJ
100 UJ
NA
NA
10
18
10
10
J
J
UJ
UJ
NA
NA
NA
NA
PARAMETER
Acidity
Amenable cyanide
Ammonia Nitrogen
Bromide
Chloride
Fluoride
Hardness, as CaCO3
Nitrate as N
Nitrate-Nitrite
Nitrite as N
Oil & Grease (HEM)
Sulfate
TOC
Total Alkalinity
Total phosphorus
Turbidity
Cyanide, Total
Total Sulfide
pH
Sulfite
MBAS (mol.wt 320)
Aluminum
Aluminum-DISS
Antimony
Antimony-DISS
Arsenic
Arsenic-DISS
Barium
Barium-DISS
Beryllium
Beryllium-DISS
Boron
Boron-DISS
Cadmium
Cadmium-DISS
Calcium
Calcium-DISS
Chromium
Chromium-DISS
Cobalt
Cobalt-DISS
Copper
Copper-DISS
Iron
Iron-DISS
Lead
Lead-DISS
Lithium
Lithium-DISS
Magnesium
Magnesium-DISS
Manganese
Manganese-DISS
Molybdenum
Molybdenum-DISS
Nickel
Nickel-DISS
Potassium
Potassium-DISS
Selenium
Selenium-DISS
Silver
Silver-DISS
Supply Water
Day 0
4/7/2009
4/7/2009
UNITS
PQL
US EPA Method
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
umhos/cm
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
NTU
ug/L
mg/L
No Units
mg/L
mg/L
mg/L
5
0.01
0.1
2
1
10
1
-1
5
0.05
0.1
0.05
5
-1
1
5
10
3
0.1
4
-10
3
-0.01
1
0.05
SM20 2310B (4a)

SM18 4500-CN E
MCAWW 350.1
SM18 5210 B
MCAWW 300.0A
MCAWW 410.4
MCAWW 300.0A
SM20 5310B
MCAWW 300.0A
SM20 2340C
MCAWW 300.0A
MCAWW 353.2
MCAWW 300.0A
CFR136A 1664A HEM
MCAWW 120.1
MCAWW 300.0A
SM20 5310B
SM18 2320 B
SM18 2540 C
MCAWW 351.3
MCAWW 365.2
SM20 2540D
MCAWW 180.1
SW846 9012A
SW846 9030B/9034
SW846 9040
SW846 9066
SM4500-SO3 B
SM5540 C
5
0.01
18.1
110
31.9
924
3000
79.7
1.2
1080
0.5
0.036
4.9
4.8
10100
53.3
78.3
75.8
5510
16.7
0.14
24
33.7
20.2
3
7.3
0.031
15.2
0.05
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
200
200
10
10
10
10
200
200
4
4
2000
2000
5
5
5000
5000
5
5
500
500
25
25
100
100
3
3
500
500
5000
5000
150
150
400
400
40
40
5000
5000
5
5
5
5
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
264
2000
100
100
100
100
5480
6120
40
40
2450
2680
50
50
315000
325000
50
50
500
500
250
250
4310
4010
30
30
2240
2450
30600
31200
237
242
400
400
11.1
400
53600
56900
50
50
50
50
U
NR U
J
GU
BJ
U
J
J
J
BE
U
U
U
U
U
U
U
J
J
U
U
U
U
U
U
U
U
U
U
B
B
E
U
U
B
U
U
U
U
U
87.5
0.01
64.8
1740
41.7
6410
2810
1270
58.3
1010
0.5
0.15
0.5
64.1
9980
58.5
1260
81.8
7080
73.9
0.16
230
305
680
3
5.2
0.072
18.8
0.0506
425
223
100
100
100
100
6280
6320
40
40
2580
2470
50
50
329000
301000
50
50
500
500
250
250
3560
3920
30
30
2340
2290
32300
29200
253
235
400
400
400
7.8
57400
54600
35.3
50
50
50
Location H
Westmoreland County, PA
Day 1
Day 5
4/8/2009
GU
J
GU
J
J
J
B
B
U
U
U
U
U
U
J
J
U
U
U
U
U
U
U
U
U
U
B
B
U
U
U
B
B
U
U
U
5
0.01
50.2
737
176
2470
14500
612
32.9
5200
0.99
0.5
2.5
4.8
49400
68
443
253
19200
52.9
0.083
27.5
53.8
75.6
3
7.5
0.055
16.8
0.05
666
466
100
100
100
100
11700
18900
40
40
12200
14600
50
50
1180000
1340000
13.5
13.8
500
500
246
199
8140
7920
33
34.3
8460
10300
102000
115000
489
558
38.9
51.5
71
77.6
187000
224000
50
50
50
50
4/13/2009
U
NR U
J
B
J
GU
U
J
J
J
J
B
B
U
U
U
U
U
U
J
J
U
U
B
B
U
U
B
B
B
B
B
B
U
U
U
U
447
0.01
NA
138
1190
6710
110000
140
17.3
55000
0.081
0.22
5
16.2
398000
47.1
119
54.5
150000
204
2.5
246
198
10
3
5.9
0.31
8.00
0.737
2460
731
20
100
124
107
1550000
1320000
40
40
97900
91300
8.6
5.7
13600000
13900000
92.4
23.8
2500
2500
102
250
180000
107000
104
150
96800
95000
1080000
1090000
2650
2260
60.1
400
2000
2000
2430000
2270000
50
50
8.1
12.2
B
J
GU
J
BJ
J
J
GU
U
U
J
BJ
B
U
J
U
U
BJ
B
J
J
J
B
U
U
B
U
J
BJ
U
J
J
B
U
U
U
U
U
B
B
Day 14
Day 90
4/22/2009
7/22/2009
90.5
0.01
291
2070
1600
17600
143000
73.2
5
63000
5
0.091
5
75.4
482000
61.6
89.2
38.1
206000
261
2.5
439
238
10
1.6
5.9
0.31
17.2
1.4
2630
785
200
200
135
140
1800000
1860000
80
80
114000
115000
12.4
9
16400000
19100000
94.2
37.8
2500
2500
241
68
242000
135000
596
148
115000
123000
1290000
1460000
3470
3400
32.4
800
2000
2000
2820000
2920000
95.6
100
100
100
U
J
GU
GU
BJ
GU
J
BJ
J
J
GU
U
B
J
BJ
BJ
U
U
B
B
J
U
U
BJ
B
J
J
BJ
B
U
U
B
B
J
J
B
J
J
B
U
U
U
B
U
U
U
720
0.01
416
4.1
1990
2630
185000
3.3
5
78000
5
0.1
42.8
4.6
600000
100
4
7.5
345000
312
0.1
436
106
10
4
5.2
0.02
11.2
0.469
173
2000
100
100
100
100
2160000
2370000
40
2.7
145000
155000
50
50
24000000
24800000
13.5
7.3
5000
5000
250
250
158000
151000
30
30
137000
148000
1740000
1830000
3040
3230
400
400
400
18
3950000
4080000
50
50
50
50
J
GU
GU
U
U
J
GU
J
B
U
U
U
U
U
U
B
U
U
J
J
B
B
U
U
U
U
U
U
U
U
U
B
U
U
U
U
PARAMETER
Sodium
Sodium-DISS
Strontium
Strontium-DISS
Thallium
Thallium-DISS
Tin
Tin-DISS
Titanium
Titanium-DISS
Trivalent Chrom
Zinc
Zinc-DISS
Hexavalent Chromium
Mercury
Mercury-DISS
1,1-Dichloroethane
1,1-Dichloroethene
1,1-Dichloropropene
1,2-Dichlorobenzene
1,2-Dichloroethane
1,2-Dichloropropane
1,3-Dichlorobenzene
1,3-Dichloropropane
1,4-Dichlorobenzene
1,4-Dioxane
2,2-Dichloropropane
2-Butanone
2-Hexanone
4-Chlorotoluene
Acetone
Acrolein
Acrylonitrile
Benzene
Benzyl chloride
Bromobenzene
Bromoform
Bromomethane
Carbon disulfide
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
Dibromomethane
Ethylbenzene
Isopropylbenzene
Methylene chloride
Naphthalene
n-Butylbenzene
n-Propylbenzene
p-Isopropyltoluene
sec-Butylbenzene
Styrene
UNITS
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
mg/L
mg/L
ug/L
ug/L
PQL
5000
5000
50
50
10
10
1000
1000
500
500
50
20
20
0.01
0.01
0.2
0.2
US EPA Method
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 7196A
SW846 7196A
SW846 7470A
SW846 7470A
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
1000
-5
5
10
5
5
5
20
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
Supply Water
Day 0
4/7/2009
1380000
1490000
76200
81100
100
100
1000
1000
500
28
50
40.5
44.1
0.01
0.019
0.2
0.071
4/7/2009
1460000
1410000
78500
74300
100
100
1000
1000
500
27.8
50
176
169
0.05
0.05
0.2
0.093
4000
4000
4000
4000
4000
4000
4000
4000
4000
4000
24000
4000
4000
4000
4000
4000
11000
4000
4000
4000
800000
NA
4000
4000
8000
4000
4000
4000
66000
80000
80000
4000
4000
4000
4000
4000
4000
4000
4000
4000
4000
4000
4000
4000
4000
4000
4000
4000
4000
4000
4000
4000
10000
4000
4000
4000
4000
4000
U
U
U
U
U
B
U
BE
B
U
U
BJ
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
1000
NA
5
5
10
5
5
5
23
100
100
6.7
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
Location H
Day 1
Day 5
U
U
U
U
U
B
U
B
B
GU
GU
U
BJ
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
4/8/2009
5160000
6130000
281000
330000
100
100
1000
1000
92
136
13.8
82.7
89.1
0.02
0.019
0.051
0.046
500
500
500
500
500
500
500
500
500
500
4000
500
500
500
500
500
1900
500
500
500
100000
NA
500
500
1000
500
500
500
5800
10000
10000
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
1400
500
500
500
500
500
U
U
U
U
B
B
B
B
B
GU
B
B
BJ
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
4/13/2009
48100000
46100000
4440000
4290000
500
500
1000
1000
313
153
23.8
1230
753
0.25
0.25
0.2
0.27
100
100
100
100
100
100
100
100
100
100
630
100
100
100
100
100
280
100
100
100
20000
NA
100
100
200
100
100
100
1600
2000
2000
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
260
100
100
100
100
100
Day 14
J
J
U
U
U
U
B
B
B
J
GU
GU
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
4/22/2009
64900000
62600000
5410000
6280000
151
172
2000
2000
247
207
37.8
2290
1790
1
0.5
0.2
0.2
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
1000
NA
5
5
10
5
5
5
20
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
Day 90
J
J
B
B
U
U
B
B
B
J
GU
GU
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
7/22/2009
75800000
82500000
8020000
8460000
168
196
1000
24.2
500
500
13.5
811
840
0.25
0.5
0.2
0.2
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
1000
NA
5
5
10
5
5
5
13
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
J
J
U
B
U
U
B
GU
GU
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
PARAMETER
tert-butyl acetate
tert-Butylbenzene
Tetrachloroethene
tetrahydrofuran
Toluene
Trichloroethene
Vinyl acetate
Vinyl chloride
Xylenes (total)
1,3-Dinitrobenzene
1,4-Naphthoquinone
1-Naphthylamine
2,3,7,8-TCDD
2,4-Dimethylphenol
2,4-Dinitrophenol
2,4-Dinitrotoluene
2,6-Dichlorophenol
2,6-Dinitrotoluene
2-Chloronaphthalene
2-Chlorophenol
2-Methylnaphthalene
2-Methylphenol
2-Naphthylamine
2-Nitroaniline
2-Nitrophenol
2-Picoline
3-Nitroaniline
4-Aminobiphenyl
4-Chloroaniline
4-Nitroaniline
4-Nitrophenol
5-Nitro-o-toluidine
Acenaphthene
Acenaphthylene
Acetophenone
Aniline
Aramite
Benzidine
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(ghi)perylene
Benzyl alcohol
Chlorobenzilate
Chrysene
Diallate
Dibenzofuran
Diethyl phthalate
Dimethoate
Dimethyl phthalate
UNITS
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
PQL
-5
5
-5
5
5
5
5
5
5
15
US EPA Method
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
10
2
10
10
10
10
-10
10
10
40
10
2
10
10
2
10
2
10
10
50
10
10
10
10
10
50
50
10
10
10
10
10
50
50
100
10
2
2
10
10
10
200
10
5
2
2
2
10
10
2
2
10
10
10
2
10
2
10
10
10
10
10
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
Supply Water
Day 0
4/7/2009
NA
4000
4000
NA
4000
4000
4000
4000
4000
4000
4000
5200
4/7/2009
NA
5
5
NA
3
5
5
5
5
5
5
15
9.7
1.9
9.7
9.7
9.7
9.7
NA
9.7
9.7
9.7
48
9.7
1.9
9.7
9.7
1.9
9.7
0.72
9.7
9.7
48
9.7
9.7
9.7
9.7
0.19
48
48
9.7
9.7
9.7
9.7
9.7
48
48
97
9.7
1.9
1.9
9.7
9.7
9.7
190
1.9
1.9
1.9
1.9
1.9
9.7
9.7
1.9
1.9
9.7
9.7
9.7
1.9
9.7
1.9
9.7
9.7
9.7
9.7
9.7
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
9.8
2
9.8
9.8
9.8
9.8
NA
9.8
9.8
9.8
49
9.8
2
9.8
9.8
2
9.8
2
9.8
9.8
49
9.8
9.8
9.8
9.8
9.8
49
49
9.8
9.8
9.8
9.8
9.8
49
49
98
9.8
2
2
9.8
9.8
9.8
200
2
2
2
2
2
9.8
9.8
2
2
16
9.8
9.8
2
9.8
2
9.8
9.8
9.8
9.8
9.8
Location H
Day 1
Day 5
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
4/8/2009
NA
500
500
NA
500
500
500
500
500
500
500
860
9.4
1.9
9.4
9.4
9.4
9.4
NA
9.4
9.4
9.4
47
9.4
1.9
9.4
9.4
1.9
9.4
1.9
9.4
9.4
47
9.4
9.4
9.4
9.4
9.4
47
47
9.4
9.4
9.4
9.4
9.4
47
47
94
9.4
1.9
1.9
9.4
9.4
9.4
190
1.9
1.9
1.9
1.9
1.9
9.4
9.4
1.9
1.9
9.4
9.4
9.4
1.9
9.4
1.9
9.4
9.4
9.4
9.4
1.3
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
4/13/2009
NA
100
100
NA
100
100
100
100
100
100
100
130
9.4
1.9
9.4
9.4
9.4
9.4
NA
9.4
9.4
9.4
47
9.4
1.9
9.4
9.4
1.9
9.4
1.9
9.4
9.4
47
9.4
9.4
9.4
9.4
9.4
47
47
9.4
9.4
9.4
9.4
9.4
47
47
94
9.4
1.9
1.9
9.4
9.4
9.4
190
1.9
1.9
1.9
1.9
1.9
9.4
9.4
1.9
1.9
10
9.4
9.4
1.9
9.4
1.9
9.4
9.4
9.4
9.4
1.3
Day 14
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
4/22/2009
NA
5
5
NA
5
5
5
5
5
5
5
15
9.5
1.9
9.5
9.5
9.5
9.5
NA
9.5
9.5
9.5
48
9.5
1.9
9.5
9.5
1.9
9.5
1.9
9.5
9.5
48
9.5
9.5
9.5
9.5
9.5
48
48
9.5
9.5
9.5
9.5
9.5
48
48
95
9.5
1.9
1.9
9.5
9.5
9.5
190
1.9
1.9
1.9
1.9
1.9
9.5
9.5
1.9
1.9
20
9.5
9.5
1.9
9.5
1.9
9.5
1.7
9.5
9.5
11
Day 90
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
7/22/2009
NA
5
5
NA
5
5
5
5
5
5
5
15
9.4
1.9
9.4
9.4
9.4
9.4
NA
9.4
9.4
9.4
47
9.4
1.9
9.4
9.4
1.9
9.4
1.9
9.4
9.4
47
9.4
9.4
9.4
9.4
0.28
47
47
9.4
9.4
9.4
9.4
9.4
47
47
94
9.4
1.9
1.9
9.4
9.4
9.4
190
1.9
1.9
1.9
1.9
1.9
9.4
9.4
1.9
1.9
5
9.4
9.4
1.9
9.4
1.9
9.4
9.4
9.4
9.4
0.39
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
J
PARAMETER
Dinoseb
Diphenylamine
Disulfoton
Fluoranthene
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hexachloroethane
Hexachloropropene
Isodrin
Isophorone
Isosafrole
Nitrobenzene
N-Nitrosomorpholine
N-Nitrosopiperidine
o-Toluidine
Parathion
Pentachlorobenzene
Pentachloroethane
Pentachlorophenol
Phenanthrene
Phenol
Phorate
Pronamide
Pyrene
Pyridine
Safrole
Thionazin
Supply Water
Day 0
4/7/2009
9.7
9.7
1.9
9.7
9.7
1.9
0.13
1.9
1.9
9.7
9.7
9.7
1.9
9.7
9.7
9.7
9.7
1.9
9.7
9.7
9.7
1.9
1.9
9.7
9.7
9.7
9.7
9.7
9.7
9.7
9.7
9.7
19
9.7
9.7
1.9
1.9
9.7
9.7
1.9
9.7
9.7
9.7
NA
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
4/7/2009
9.8
9.8
2
9.8
9.8
2
2
2
2
9.8
9.8
9.8
2
9.8
9.8
9.8
9.8
2
9.8
9.8
9.8
2
2
9.8
9.8
9.8
9.8
9.8
9.8
9.8
9.8
9.8
20
9.8
9.8
2
2
9.8
9.8
2
9.8
9.8
9.8
NA
UNITS
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
PQL
10
10
2
10
10
2
2
0.05
2
2
10
10
2
10
10
10
10
2
10
10
10
2
2
10
10
10
10
10
10
10
10
10
20
10
10
2
2
10
10
2
10
10
10
10
US EPA Method
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
4,4'-DDD
4,4'-DDE
4,4'-DDT
Aldrin
alpha-BHC
beta-BHC
delta-BHC
Dieldrin
Endosulfan I
Endosulfan II
Endosulfan sulfate
Endrin
Endrin aldehyde
Endrin ketone
gamma-BHC (Lindane)
Heptachlor
Heptachlor epoxide
Methoxychlor
Toxaphene
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.1
2
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
0.048
0.048
0.048
0.048
0.048
0.048
0.48
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.096
1.9
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
0.048
0.048
0.048
0.048
0.048
0.048
0.48
0.048
0.048
0.22
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.096
1.9
PCBs
Aroclor 1016
Aroclor 1221
Aroclor 1232
Aroclor 1242
Aroclor 1248
Aroclor 1254
Aroclor 1260
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
0.4
0.4
0.4
0.4
0.4
0.4
0.4
SW846 8082
SW846 8082
SW846 8082
SW846 8082
SW846 8082
SW846 8082
SW846 8082
0.38
0.38
0.38
0.38
0.38
0.38
0.38
U
U
U
U
U
U
U
0.38
0.38
0.38
0.38
0.38
0.38
0.38
Location H
Day 1
Day 5
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
4/8/2009
9.4
9.4
1.9
9.4
9.4
1.9
1.9
1.9
1.9
9.4
9.4
9.4
1.9
9.4
9.4
9.4
9.4
1.9
9.4
9.4
9.4
1.9
1.9
9.4
9.4
9.4
9.4
9.4
9.4
9.4
9.4
9.4
19
9.4
9.4
0.8
1.9
9.4
9.4
1.9
9.4
9.4
9.4
NA
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
4/13/2009
9.4
9.4
1.9
9.4
9.4
1.9
1.9
1.9
1.9
9.4
9.4
9.4
1.9
9.4
9.4
9.4
9.4
1.9
9.4
9.4
9.4
1.9
1.9
9.4
9.4
9.4
9.4
9.4
9.4
9.4
9.4
9.4
19
9.4
9.4
1.9
1.9
9.4
9.4
1.9
9.4
9.4
9.4
NA
Day 14
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
4/22/2009
9.5
9.5
1.9
9.5
9.5
1.9
1.9
1.9
1.9
9.5
9.5
9.5
1.9
9.5
9.5
9.5
9.5
1.9
9.5
9.5
9.5
1.9
1.9
9.5
9.5
9.5
9.5
9.5
9.5
9.5
9.5
9.5
19
9.5
9.5
1.9
1.9
9.5
9.5
1.9
9.5
9.5
9.5
NA
U
U
U
U
U
U
U
U
U
PG
U
U
U
U
U
U
U
U
U
U
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.048
0.048
0.048
0.048
0.048
0.048
0.48
0.048
0.048
0.048
0.42
0.27
0.07
0.064
0.057
0.048
0.017
0.048
0.095
1.9
U
U
U
U
U
U
U
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.38
0.38
0.38
0.38
0.38
0.38
0.38
Day 90
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
PG
PG
PG
PG
U
J PG
U
U
U
U
U
U
U
U
U
U
7/22/2009
7.2
9.4
1.9
9.4
9.4
1.9
1.9
1.9
1.9
9.4
9.4
9.4
1.9
9.4
9.4
9.4
9.4
1.9
9.4
9.4
9.4
1.9
1.9
9.4
9.4
9.4
9.4
9.4
9.4
9.4
9.4
9.4
19
9.4
9.4
1.9
1.9
9.4
9.4
1.9
9.4
9.4
9.4
#N/A
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
0.048
0.048
0.048
0.35
0.048
0.048
0.48
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.095
1.9
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
0.38
0.38
0.38
0.38
0.38
0.38
0.38
U
U
U
U
U
U
U
PARAMETER
Supply Water
Day 0
4/7/2009
4/7/2009
UNITS
PQL
US EPA Method
Ethyl parathion
ug/L
0.4
SW846 8141A
0.96 U
Alcohols
2-Propanol
Butyl alcohol
Ethanol
Methanol
n-Propanol
mg/L
mg/L
mg/L
mg/L
mg/L
10
10
10
10
10
SW846 8015
SW846 8015
SW846 8015
SW846 8015
SW846 8015
31
5
5
5
5
Glycols
Ethylene Glycol
Propylene glycol
mg/L
mg/L
50
50
SW846 8015
SW846 8015
100 UJ
100 UJ
Acids
Acetic Acid
Butyric Acid
Propionic Acid
Volatile Acids
mg/L
mg/L
mg/L
mg/L
10
10
10
10
SW846 8015
SW846 8015
SW846 8015
50 UJ
50 UJ
50 UJ
57
J
UJ
UJ
UJ
UJ
Location H
Day 1
Day 5
Day 14
Day 90
4/22/2009
7/22/2009
4/8/2009
4/13/2009
0.95 U
NA
NA
0.95 U
0.95 U
450
10
10
10
10
280
10
10
10
10
J
UJ
UJ
UJ
UJ
NA
NA
NA
NA
NA
66
10
10
10
10
10
10
10
10
10
1000 UJ
1000 UJ
100 UJ
300 J
NA
NA
100 UJ
100 UJ
100 UJ
100 UJ
50 UJ
50 UJ
50 UJ
170
50 UJ
50 UJ
50 UJ
260
NA
NA
NA
NA
50 UJ
50 UJ
50 UJ
1600
100 UJ
100 UJ
100 UJ
700
J
UJ
UJ
UJ
UJ
J
UJ
UJ
UJ
UJ
J
UJ
UJ
UJ
UJ
PARAMETER
Acidity
Amenable cyanide
Ammonia Nitrogen
Bromide
Chloride
Fluoride
Hardness, as CaCO3
Nitrate as N
Nitrate-Nitrite
Nitrite as N
Oil & Grease (HEM)
Sulfate
TOC
Total Alkalinity
Total phosphorus
Turbidity
Cyanide, Total
Total Sulfide
pH
Sulfite
MBAS (mol.wt 320)
Aluminum
Aluminum-DISS
Antimony
Antimony-DISS
Arsenic
Arsenic-DISS
Barium
Barium-DISS
Beryllium
Beryllium-DISS
Boron
Boron-DISS
Cadmium
Cadmium-DISS
Calcium
Calcium-DISS
Chromium
Chromium-DISS
Cobalt
Cobalt-DISS
Copper
Copper-DISS
Iron
Iron-DISS
Lead
Lead-DISS
Lithium
Lithium-DISS
Magnesium
Magnesium-DISS
Manganese
Manganese-DISS
Molybdenum
Molybdenum-DISS
Nickel
Nickel-DISS
Potassium
Potassium-DISS
Selenium
Selenium-DISS
Silver
Silver-DISS
Supply Water
Day 0
5/9/2009
5/9/2009
UNITS
PQL
US EPA Method
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
umhos/cm
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
NTU
ug/L
mg/L
No Units
mg/L
mg/L
mg/L
5
0.01
0.1
2
1
10
1
-1
5
0.05
0.1
0.05
5
-1
1
5
10
3
0.1
4
-10
3
-0.01
1
0.05
SM20 2310B (4a)

SM18 4500-CN E
MCAWW 350.1
SM18 5210 B
MCAWW 300.0A
MCAWW 410.4
MCAWW 300.0A
SM20 5310B
MCAWW 300.0A
SM20 2340C
MCAWW 300.0A
MCAWW 353.2
MCAWW 300.0A
CFR136A 1664A HEM
MCAWW 120.1
MCAWW 300.0A
SM20 5310B
SM18 2320 B
SM18 2540 C
MCAWW 351.3
MCAWW 365.2
SM20 2540D
MCAWW 180.1
SW846 9012A
SW846 9030B/9034
SW846 9040
SW846 9066
SM4500-SO3 B
SM5540 C
5
0.01
0.064
2
0.22
18.7
49.9
3.2
0.05
38
0.05
0.1
0.05
4.8
247
8.3
4.7
9.3
400
3
0.14
2
3.1
10
1.6
7.3
0.01
21.6
0.240
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
200
200
10
10
10
10
200
200
4
4
2000
2000
5
5
5000
5000
5
5
500
500
25
25
100
100
3
3
500
500
5000
5000
150
150
400
400
40
40
5000
5000
5
5
5
5
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
2000
2000
100
100
100
100
1640
1580
40
40
34.3
44.2
50
50
11600
12000
50
50
500
500
250
250
192
1000
30
30
42.2
32.7
1840
1830
13.9
150
400
400
400
400
50000
2240
50
50
50
50
U
U
B
U
J
U
U
U
U
U
J
J
J
J
U
B
U
B
U
U
U
U
U
U
U
B
BJ
U
U
BJ
BJ
U
U
BJ
BJ
U
U
U
U
U
U
B
U
U
U
B
B
B
B
B
U
U
U
U
U
U
B
U
U
U
U
5
0.01
5.9
578
1
2560
90.2
577
0.05
42
0.02
0.59
0.034
62.2
362
8.4
607
33.4
265
65.4
0.062
192
75.2
4.1
3
7.6
0.028
27.6
0.05
2000
227
100
100
100
100
1170
1500
40
40
33.9
49.9
50
50
9900
13000
50
50
500
500
250
250
198
175
30
30
29.7
51.7
1360
1720
150
11.5
400
400
400
400
50000
3790
50
50
50
50
Location I
Cameron County, PA
Day 1
Day 5
5/15/2009
U
U
U
B
B
J
J
J
B
U
U
B
U
U
U
U
B
BJ
U
U
BJ
BJ
U
U
BJ
BJ
U
U
U
U
U
U
B
B
U
U
B
B
B
B
U
B
U
U
U
U
U
B
U
U
U
U
5
0.01
127
399
238
8790
58700
600
2.5
8600
2.5
1.1
2.5
53.9
200000
36.6
610
175
122000
150
0.084
308
461
10
3
6.6
0.015
NA
NA
1750
286
31.5
18.9
42.9
29.9
516000
532000
40
40
5930
6240
2.9
2.6
2950000
3060000
50.4
18.7
1000
1000
68.3
35
58700
21000
60
60
34600
36500
177000
185000
2840
2870
90
84.2
66.8
66.8
378000
410000
50
50
50
50
5/19/2009
U
U
GU
GU
GU
J
BJ
J
U
U
BJ
BJ
B
B
B
B
J
U
U
J
B
B
B
U
U
B
B
U
U
B
B
B
B
U
U
U
U
123
0.01
199
99.4
901
195
148000
59.6
2.5
42000
2.5
0.1
2.5
4.8
470000
50
48
48.8
238000
160
0.45
696
203
10
3
5.8
0.022
6.80
1.31
418
596
47.2
200
59.6
62.6
1400000
1740000
80
80
11900
15400
9.6
11.4
9400000
11700000
12.2
100
2500
2500
500
500
49700
39100
150
150
97600
125000
604000
765000
5520
6810
27.6
29.2
2000
2000
811000
1040000
100
100
100
100
U
J
GU
GU
U
GU
U
J
GU
J
U
U
BJ
BJ
B
U
B
B
U
U
B
B
J
B
U
U
U
U
U
J
U
U
B
B
U
U
U
U
U
U
Day 14
Day 90
5/28/2009
10/20/2009
216
0.01
229
10.4
1010
12100
181000
26.5
5
50800
5
0.1
52
4.8
570000
100
12.8
37.3
261000
131
0.1
65.2
180
10
3
5.6
0.017
31.2
0.191
846
983
27.2
200
89.2
75.6
2460000
2500000
80
80
16400
16800
11.8
12.2
17300000
17600000
28.8
24.4
2500
2500
79
500
76600
53900
150
150
170000
172000
1100000
1110000
9560
9630
34.4
31.8
2000
2000
1300000
1320000
100
100
100
100
GU
GU
U
U
J
GU
J
U
U
B
B
B
U
B
B
U
U
BJ
B
J
J
B
B
U
U
B
U
U
U
B
B
U
U
U
U
U
U
336
0.01
278
3.4
1510
20200
196000
13.2
5
104000
7.4
0.58
5
4.7
763000
44.2
14
25.3
271000
218
0.08
82
67.2
3.6
3
5.1
0.01
NA
NA
904
130
100
100
100
100
4670000
5810000
3.4
6.8
18700
24300
3.5
3
33000000
41000000
9.7
8
5000
5000
48.1
28.6
131000
152000
13.2
30
323000
323000
2020000
2550000
16900
21200
400
400
400
400
2860000
3850000
50
50
50
50
U
J
GU
GU
BJ
J
B
U
U
BJ
BJ
U
U
U
U
B
B
J
BJ
B
B
B
U
U
B
B
B
U
J
U
U
U
U
U
U
U
U
Supply Water
PARAMETER
Sodium
Sodium-DISS
Strontium
Strontium-DISS
Thallium
Thallium-DISS
Tin
Tin-DISS
Titanium
Titanium-DISS
Trivalent Chrom
Zinc
Zinc-DISS
Hexavalent Chromium
Mercury
Mercury-DISS
1,1-Dichloroethane
1,1-Dichloroethene
1,1-Dichloropropene
1,2-Dichlorobenzene
1,2-Dichloroethane
1,2-Dichloropropane
1,3-Dichlorobenzene
1,3-Dichloropropane
1,4-Dichlorobenzene
1,4-Dioxane
2,2-Dichloropropane
2-Butanone
2-Hexanone
4-Chlorotoluene
Acetone
Acrolein
Acrylonitrile
Benzene
Benzyl chloride
Bromobenzene
Bromoform
Bromomethane
Carbon disulfide
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
Dibromomethane
Ethylbenzene
Isopropylbenzene
Methylene chloride
Naphthalene
n-Butylbenzene
n-Propylbenzene
p-Isopropyltoluene
sec-Butylbenzene
Styrene
UNITS
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
mg/L
mg/L
ug/L
ug/L
PQL
5000
5000
50
50
10
10
1000
1000
500
500
50
20
20
0.01
0.01
0.2
0.2
US EPA Method
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 7196A
SW846 7196A
SW846 7470A
SW846 7470A
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
1000
-5
5
10
5
5
5
20
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
Day 0
5/9/2009
24400
24900
1500
1460
100
100
1000
1000
29.9
29.6
50
25.7
61.5
0.25
0.25
0.053
0.05
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
1000
NA
5
5
10
5
5
5
6.3
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
B
B
J
U
U
U
U
BJ
BJ
U
BJ
BJ
GU
GU
BJ
BJ
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
JB
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
5/9/2009
54200
70800
1070
1340
100
100
1000
1000
27.1
24.4
50
45.7
79.4
0.25
0.25
0.044
0.47
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
1000
NA
5
7.5
10
5
5
5
20
100
100
5
5
5
5
5
5
1.6
5
5
5
5
5
5
5
5
5
5
5
5
5
13
0.95
5
5
5
5
5
Day 1
J
U
U
U
U
BJ
BJ
U
BJ
BJ
GU
GU
BJ
BJ
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
B
J
U
U
U
U
U
Location I
Cameron County, PA
Day 5
5/15/2009
34700000
35000000
492000
500000
200
200
1000
1000
69.9
44.3
50
314
187
0.5
0.27
0.2
0.2
25
25
25
25
25
25
25
25
25
25
3.1
25
25
25
25
25
25
25
25
25
5000
NA
25
25
50
25
25
25
390
500
500
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
J
J
U
U
U
U
B
B
U
B
U
B
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Day 14
5/19/2009
65100000
83400000
1800000
2210000
500
500
2000
2000
143
211
100
269
195
0.25
0.25
0.2
0.2
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
1000
NA
5
5
10
5
5
5
130
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
J
U
U
U
U
B
B
U
BJ
B
GU
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
5/28/2009
85600000
88000000
3120000
3210000
500
500
2000
2000
197
230
24.4
591
566
0.5
0.25
0.2
0.2
5
5
5
5
5
5
5
5
5
5
2.4
5
5
5
5
5
2.3
5
5
5
1000
NA
5
5
10
5
5
5
25
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
Day 90
J
U
U
U
U
B
B
B
J
GU
GU
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
10/20/2009
95500000
117000000
6290000
7820000
26.8
100
1000
1000
500
500
50
810
992
0.5
0.5
0.2
0.2
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
1000
NA
5
5
10
5
5
5
20
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
J
J
J
B
U
U
U
U
U
U
J
J
GU
GU
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Supply Water
PARAMETER
tert-butyl acetate
tert-Butylbenzene
Tetrachloroethene
tetrahydrofuran
Toluene
Trichloroethene
Vinyl acetate
Vinyl chloride
Xylenes (total)
1,3-Dinitrobenzene
1,4-Naphthoquinone
1-Naphthylamine
2,3,7,8-TCDD
2,4-Dimethylphenol
2,4-Dinitrophenol
2,4-Dinitrotoluene
2,6-Dichlorophenol
2,6-Dinitrotoluene
2-Chloronaphthalene
2-Chlorophenol
2-Methylnaphthalene
2-Methylphenol
2-Naphthylamine
2-Nitroaniline
2-Nitrophenol
2-Picoline
3-Nitroaniline
4-Aminobiphenyl
4-Chloroaniline
4-Nitroaniline
4-Nitrophenol
5-Nitro-o-toluidine
Acenaphthene
Acenaphthylene
Acetophenone
Aniline
Aramite
Benzidine
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(ghi)perylene
Benzyl alcohol
Chlorobenzilate
Chrysene
Diallate
Dibenzofuran
Diethyl phthalate
Dimethoate
Dimethyl phthalate
UNITS
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
PQL
-5
5
-5
5
5
5
5
5
5
15
US EPA Method
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
10
2
10
10
10
10
-10
10
10
40
10
2
10
10
2
10
2
10
10
50
10
10
10
10
10
50
50
10
10
10
10
10
50
50
100
10
2
2
10
10
10
200
10
5
2
2
2
10
10
2
2
10
10
10
2
10
2
10
10
10
10
10
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
Day 0
5/9/2009
NA
5
5
NA
5
5
5
5
5
5
5
15
9.4
1.9
9.4
9.4
9.4
9.4
NA
9.4
9.4
9.4
47
9.4
1.9
9.4
9.4
1.9
9.4
1.9
9.4
9.4
47
9.4
9.4
9.4
9.4
9.4
47
47
9.4
9.4
9.4
9.4
9.4
47
47
94
9.4
1.9
1.9
9.4
9.4
9.4
190
1.9
1.9
1.9
1.9
1.9
9.4
9.4
1.9
1.9
9.4
9.4
9.4
1.9
9.4
1.9
9.4
9.4
9.4
9.4
9.4
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
5/9/2009
NA
5
1.3
NA
6.7
5
5
0.81
5
5
5
2.6
9.5
1.9
9.5
9.5
9.5
9.5
NA
9.5
9.5
9.5
48
9.5
1.9
9.5
9.5
1.9
9.5
1.9
9.5
9.5
48
9.5
9.5
9.5
9.5
9.5
48
48
9.5
9.5
9.5
9.5
9.5
48
48
95
9.5
1.9
1.9
9.5
9.5
9.5
190
1.9
1.9
1.9
1.9
1.9
9.5
9.5
1.9
1.9
9.5
9.5
9.5
1.9
9.5
1.9
9.5
9.5
9.5
9.5
9.5
Day 1
U
J
U
U
J
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Location I
Cameron County, PA
Day 5
5/15/2009
NA
25
8.9
NA
25
25
25
25
25
25
25
75
94
19
94
94
94
94
NA
94
94
94
470
94
19
94
94
19
94
19
94
94
470
94
94
94
94
94
470
470
94
94
94
94
94
470
470
940
94
19
19
94
94
94
1900
19
19
19
19
19
41
94
19
19
94
94
94
19
94
19
94
94
94
94
94
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Day 14
5/19/2009
NA
5
5
NA
5
5
5
5
5
5
5
15
9.4
1.9
9.4
9.4
9.4
9.4
NA
9.4
9.4
9.4
47
9.4
1.9
9.4
9.4
1.9
9.4
0.67
0.53
9.4
1.3
9.4
9.4
9.4
9.4
1.2
47
47
9.4
9.4
9.4
9.4
0.75
47
47
94
9.4
0.9
0.84
9.4
9.4
9.4
190
0.97
6.7
10
6.9
5.9
17
9.4
1.9
1.9
6.9
9.4
9.4
0.85
9.4
11
0.87
1.3
9.4
0.87
5.3
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
J
U
J
U
U
U
U
J
U
U
U
U
U
U
J
U
U
U
U
J
J
U
U
U
U
J
U
U
U
J
U
U
J
U
J
J
U
J
J
5/28/2009
NA
5
5
NA
3
5
5
5
5
5
5
6.9
9.7
1.9
9.7
9.7
9.7
9.7
NA
9.7
9.7
9.7
48
9.7
1.9
9.7
9.7
1.9
9.7
1.9
9.7
9.7
48
9.7
9.7
9.7
9.7
8.1
48
48
9.7
9.7
9.7
9.7
9.7
48
48
97
9.7
1.9
1.9
9.7
9.7
9.7
190
1.9
1.9
1.9
1.9
1.9
9.7
9.7
1.9
1.9
4
9.7
9.7
1.9
9.7
1.9
9.7
9.7
9.7
9.7
9.7
Day 90
U
U
J
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
10/20/2009
NA
5
5
NA
5
5
5
5
5
5
5
15
20
4
20
20
20
20
NA
20
20
20
100
20
4
20
20
4
20
4
20
20
100
20
20
20
20
20
100
100
20
20
20
20
20
100
100
200
20
4
4
20
20
20
400
4
4
4
4
4
20
20
4
4
1.4
20
20
0.29
20
4
20
20
20
20
20
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
JB
U
U
U
U
U
U
U
Supply Water
PARAMETER
Dinoseb
Diphenylamine
Disulfoton
Fluoranthene
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hexachloroethane
Hexachloropropene
Isodrin
Isophorone
Isosafrole
Nitrobenzene
N-Nitrosomorpholine
N-Nitrosopiperidine
o-Toluidine
Parathion
Pentachlorobenzene
Pentachloroethane
Pentachlorophenol
Phenanthrene
Phenol
Phorate
Pronamide
Pyrene
Pyridine
Safrole
Thionazin
UNITS
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
PQL
10
10
2
10
10
2
2
0.05
2
2
10
10
2
10
10
10
10
2
10
10
10
2
2
10
10
10
10
10
10
10
10
10
20
10
10
2
2
10
10
2
10
10
10
10
US EPA Method
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
4,4'-DDD
4,4'-DDE
4,4'-DDT
Aldrin
alpha-BHC
beta-BHC
delta-BHC
Dieldrin
Endosulfan I
Endosulfan II
Endosulfan sulfate
Endrin
Endrin aldehyde
Endrin ketone
gamma-BHC (Lindane)
Heptachlor
Heptachlor epoxide
Methoxychlor
Toxaphene
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.1
2
PCBs
Aroclor 1016
Aroclor 1221
Aroclor 1232
Aroclor 1242
Aroclor 1248
Aroclor 1254
Aroclor 1260
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
0.4
0.4
0.4
0.4
0.4
0.4
0.4
Day 0
5/9/2009
Day 1
Location I
Cameron County, PA
Day 5
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
0.048
0.048
0.048
0.048
0.048
0.048
0.48
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.095
1.9
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
0.047
0.047
0.047
0.047
0.047
0.047
0.47
0.047
0.047
0.047
0.047
0.047
0.047
0.047
0.047
0.047
0.047
0.047
0.094
1.9
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.048
0.048
0.048
0.048
0.048
0.37
0.48
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.095
1.9
U
U
U
U
U
SW846 8082
SW846 8082
SW846 8082
SW846 8082
SW846 8082
SW846 8082
SW846 8082
0.38
0.38
0.38
0.38
0.38
0.38
0.38
U
U
U
U
U
U
U
0.38
0.38
0.38
0.38
0.38
0.38
0.38
U
U
U
U
U
U
U
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.38
0.38
0.38
0.38
0.38
0.38
0.38
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
5/19/2009
9.4
9.4
1
9.4
9.4
6.1
0.82
1.9
1.9
9.4
9.4
9.4
9.5
9.4
9.4
9.4
9.4
1.9
9.4
9.4
9.4
1.9
1
9.4
9.4
9.4
9.4
9.4
9.4
9.4
9.4
9.4
19
9.4
9.4
0.89
0.7
9.4
9.4
0.89
310
9.4
9.4
NA
U
U
J
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
J
J
U
U
J
U
U
5/28/2009
9.7
9.7
1.9
9.7
9.7
1.9
1.9
1.9
1.9
9.7
9.7
9.7
1.9
9.7
9.7
9.7
9.7
1.9
9.7
9.7
9.7
1.9
1.9
9.7
9.7
9.7
9.7
9.7
9.7
9.7
9.7
9.7
19
9.7
9.7
1.9
1.9
9.7
9.7
1.9
9.7
9.7
9.7
NA
Day 90
9.4
9.4
1.9
9.4
9.4
1.9
1.9
1.9
1.9
9.4
9.4
9.4
1.9
9.4
9.4
9.4
9.4
1.9
9.4
9.4
9.4
1.9
1.9
9.4
9.4
9.4
9.4
9.4
9.4
9.4
9.4
9.4
19
9.4
9.4
1.9
1.9
9.4
9.4
1.9
9.4
9.4
9.4
NA
U
U
U
U
U
5/15/2009
94
94
19
94
94
19
19
19
19
94
94
94
19
94
94
94
94
19
94
94
94
19
19
94
94
94
94
94
94
94
94
94
190
94
94
19
19
94
94
19
640
94
94
NA
Day 14
5/9/2009
9.5
9.5
1.9
9.5
9.5
5.5
1.9
1.9
1.9
9.5
9.5
9.5
1.9
9.5
9.5
9.5
9.5
1.9
9.5
9.5
9.5
1.9
1.9
9.5
9.5
9.5
9.5
9.5
9.5
9.5
9.5
9.5
19
9.5
9.5
1.9
1.9
9.5
9.5
1.9
4.5
9.5
9.5
NA
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
10/20/2009
20
20
4
20
20
4
4
4
4
20
20
20
4
20
20
20
20
4
20
20
20
4
4
20
20
20
20
20
20
20
20
20
40
20
20
4
4
20
20
4
42
20
20
NA
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
0.05
0.05
0.05
0.05
0.05
0.05
0.5
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.1
2
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
0.4
0.4
0.4
0.4
0.4
0.4
0.4
U
U
U
U
U
U
U
PARAMETER
Location I
Cameron County, PA
Day 5
Supply Water
Day 0
Day 1
5/9/2009
5/9/2009
5/15/2009
UNITS
PQL
US EPA Method
Ethyl parathion
ug/L
0.4
SW846 8141A
0.95 U
Alcohols
2-Propanol
Butyl alcohol
Ethanol
Methanol
n-Propanol
mg/L
mg/L
mg/L
mg/L
mg/L
10
10
10
10
10
SW846 8015
SW846 8015
SW846 8015
SW846 8015
SW846 8015
10
10
10
10
10
Glycols
Ethylene Glycol
Propylene glycol
mg/L
mg/L
50
50
SW846 8015
SW846 8015
100 UJ
100 UJ
200 UJ
200 UJ
100 UJ
100 UJ
Acids
Acetic Acid
Butyric Acid
Propionic Acid
Volatile Acids
mg/L
mg/L
mg/L
mg/L
10
10
10
10
SW846 8015
SW846 8015
SW846 8015
1U
1U
1U
NA
50 UJ
50 UJ
50 UJ
NA
10 UJ
10 UJ
10 UJ
NA
UJ
UJ
UJ
UJ
UJ
0.97 U
NA
20
20
20
130
20
10
10
10
52
10
UJ
UJ
UJ
J
UJ
5/19/2009
NA
UJ
UJ
UJ
J
UJ
10
10
10
59
10
Day 14
Day 90
5/28/2009
10/20/2009
0.95 U
UJ
UJ
UJ
J
UJ
10
10
10
48
10
1U
UJ
UJ
UJ
J
UJ
UJ
UJ
UJ
J
UJ
100 UJ
100 UJ
100 UJ
100 UJ
UJ
UJ
10 UJ
10 UJ
10 UJ
57
100 UJ
100 UJ
100 UJ
460
UJ
UJ
UJ
PARAMETER
Acidity
Amenable cyanide
Ammonia Nitrogen
Bromide
Chloride
Fluoride
Hardness, as CaCO3
Nitrate as N
Nitrate-Nitrite
Nitrite as N
Oil & Grease (HEM)
Sulfate
TOC
Total Alkalinity
Total phosphorus
Turbidity
Cyanide, Total
Total Sulfide
pH
Sulfite
MBAS (mol.wt 320)
Aluminum
Aluminum-DISS
Antimony
Antimony-DISS
Arsenic
Arsenic-DISS
Barium
Barium-DISS
Beryllium
Beryllium-DISS
Boron
Boron-DISS
Cadmium
Cadmium-DISS
Calcium
Calcium-DISS
Chromium
Chromium-DISS
Cobalt
Cobalt-DISS
Copper
Copper-DISS
Iron
Iron-DISS
Lead
Lead-DISS
Lithium
Lithium-DISS
Magnesium
Magnesium-DISS
Manganese
Manganese-DISS
Molybdenum
Molybdenum-DISS
Nickel
Nickel-DISS
Potassium
Potassium-DISS
Selenium
Selenium-DISS
Silver
Silver-DISS
Supply Water
Day 0
5/1/2009
5/1/2009
UNITS
PQL
US EPA Method
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
umhos/cm
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
NTU
ug/L
mg/L
No Units
mg/L
mg/L
mg/L
5
0.01
0.1
2
1
10
1
-1
5
0.05
0.1
0.05
5
-1
1
5
10
3
0.1
4
-10
3
-0.01
1
0.05
SM20 2310B (4a)

SM18 4500-CN E
MCAWW 350.1
SM18 5210 B
MCAWW 300.0A
MCAWW 410.4
MCAWW 300.0A
SM20 5310B
MCAWW 300.0A
SM20 2340C
MCAWW 300.0A
MCAWW 353.2
MCAWW 300.0A
CFR136A 1664A HEM
MCAWW 120.1
MCAWW 300.0A
SM20 5310B
SM18 2320 B
SM18 2540 C
MCAWW 351.3
MCAWW 365.2
SM20 2540D
MCAWW 180.1
SW846 9012A
SW846 9030B/9034
SW846 9040
SW846 9066
SM4500-SO3 B
SM5540 C
5
0.01
0.017
2
0.14
10
42.3
3.2
0.033
140
1.7
1.8
0.05
4.8
380
43.7
2.2
71.4
746
3
0.044
9.6
1.3
10
2.4
7.2
0.01
10.0
0.962
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
200
200
10
10
10
10
200
200
4
4
2000
2000
5
5
5000
5000
5
5
500
500
25
25
100
100
3
3
500
500
5000
5000
150
150
400
400
40
40
5000
5000
5
5
5
5
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
249
2000
100
100
100
100
338
241
40
40
29.8
39.2
50
50
37500
43200
50
50
500
500
250
250
273
1000
30
30
33.8
40.7
5160
6160
145
129
400
400
400
400
2850
2260
50
50
50
50
U
U
BJ
U
B
U
J
B
U
U
J
J
U
B
U
B
J
BJ
U
U
U
U
U
B
BJ
U
U
BJ
B
U
U
BJ
B
U
U
U
U
U
U
B
U
U
U
B
B
B
B
B
B
U
U
U
U
B
B
U
U
U
U
Location J
Tioga County, PA
Day 1
5/4/2009
5
0.01
5.6
47.1
36.6
47400
2180
168
0.05
1300
1.6
2
0.05
29.2
9280
27.7
569
191
4840
17.1
0.072
230
101
4.6
3
7.2
0.027
20.4
0.05
400
2000
100
100
100
100
87100
84400
40
40
156
202
50
50
241000
293000
50
50
500
500
250
250
3080
1510
30
30
2050
2590
21000
25300
395
430
400
400
400
400
11600
13000
50
50
50
50
U
U
J
J
U
U
J
B
U
BJ
U
U
U
U
U
J
U
U
BJ
B
U
U
J
U
U
U
U
U
U
U
U
B
B
U
U
U
U
B
B
U
U
U
U
5
0.01
13.2
36.7
39.1
397
2460
207
0.5
1060
0.83
0.94
0.39
7.3
8740
17.4
56.6
107
5090
14.2
0.14
330
330
15.2
3
7.4
0.03
13.2
0.134
4030
212
100
100
34.3
100
121000
64400
40
40
1120
1180
2.5
50
305000
318000
359
5.8
500
500
41.3
250
55200
14200
26.4
30
4060
3790
25900
25900
1290
1190
372
185
203
24.1
26700
21600
50
50
50
50
U
NR U
J
GU
B
J
J
J
J
B
U
U
B
U
J
U
U
BJ
B
B
U
J
B
U
U
B
U
B
U
B
B
B
B
B
B
B
B
U
U
U
U
Day 5
Day 14
5/8/2009
5/18/2009
5
0.01
36.9
47.5
233
4870
26400
30.7
1.2
7800
2.3
0.89
1.2
4.8
90500
17.6
27.5
187
48700
96.1
0.088
68.8
30.2
10
3
6.6
0.01
6.00
0.0761
111
2000
35.8
29.9
32.1
55.3
1210000
1290000
40
40
3140
3500
50
50
1790000
1950000
15.1
50
500
500
250
250
39000
38200
30
30
37000
40000
154000
167000
1100
1200
400
14.9
400
400
48900
53100
50
50
50
50
U
U
J
GU
GU
U
J
BJ
J
U
U
U
B
U
B
B
B
B
J
U
U
J
J
U
U
J
J
B
U
U
U
U
U
U
U
U
B
U
U
B
U
U
U
U
5
0.01
17.8
20.3
65
8530
8060
82.8
0.5
3100
0.5
0.92
1.8
4.8
32000
10
23.6
119
19100
17.9
0.3
1150
524
10
3
6.8
0.009
9.6
0.137
4680
266
25.7
100
60.4
100
589000
496000
40
40
885
901
1.5
50
847000
928000
460
5.7
500
500
253
250
223000
45800
453
34.7
12200
13300
77600
83800
2810
1710
188
25.6
216
33.3
98900
106000
50
50
50
50
U
U
J
J
GU
GU
U
J
GU
J
U
U
B
J
BJ
B
U
B
U
J
U
U
BJ
B
B
U
B
U
U
U
B
B
B
B
U
U
U
U
PARAMETER
Sodium
Sodium-DISS
Strontium
Strontium-DISS
Thallium
Thallium-DISS
Tin
Tin-DISS
Titanium
Titanium-DISS
Trivalent Chrom
Zinc
Zinc-DISS
Hexavalent Chromium
Mercury
Mercury-DISS
1,1-Dichloroethane
1,1-Dichloroethene
1,1-Dichloropropene
1,2-Dichlorobenzene
1,2-Dichloroethane
1,2-Dichloropropane
1,3-Dichlorobenzene
1,3-Dichloropropane
1,4-Dichlorobenzene
1,4-Dioxane
2,2-Dichloropropane
2-Butanone
2-Hexanone
4-Chlorotoluene
Acetone
Acrolein
Acrylonitrile
Benzene
Benzyl chloride
Bromobenzene
Bromoform
Bromomethane
Carbon disulfide
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
Dibromomethane
Ethylbenzene
Isopropylbenzene
Methylene chloride
Naphthalene
n-Butylbenzene
n-Propylbenzene
p-Isopropyltoluene
sec-Butylbenzene
Styrene
UNITS
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
mg/L
mg/L
ug/L
ug/L
PQL
5000
5000
50
50
10
10
1000
1000
500
500
50
20
20
0.01
0.01
0.2
0.2
US EPA Method
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 7196A
SW846 7196A
SW846 7470A
SW846 7470A
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
1000
-5
5
10
5
5
5
20
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
Location J
Tioga County, PA
Day 1
Supply Water
Day 0
5/1/2009
5/1/2009
17800
21300
588
685
100
100
1000
1000
500
500
50
73.9
52.8
0.01
0.01
0.2
0.2
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
1000
NA
5
5
10
5
5
5
20
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
B
B
J
U
U
U
U
U
U
U
BJ
B
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
884000
1120000
47900
58200
100
100
1000
1000
500
500
50
76.8
45.5
0.05
0.05
0.056
0.051
5
5
5
5
5
5
5
5
5
5
5
5
5
5
2.6
5
5
5
5
5
1000
NA
5
5
10
5
5
5
10
100
100
5
5
5
5
7.8
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
J
U
U
U
U
U
U
U
BJ
B
GU
GU
B
B
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
JB
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Day 5
5/4/2009
1090000
1160000
56700
58600 J
100 U
100 U
1000 U
1000 U
23.5 B
500 U
209
665 J
378
0.086
0.15
0.2 U
0.2 U
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
1000
NA
5
5
10
5
5
5
10
100
100
5
5
5
5
5.8
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
3.7
5
5
5
5
5
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
JB
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
5/8/2009
10700000
11700000
443000
477000
100
100
1000
1000
50.3
62.5
50
91
97.5
0.5
0.5
0.043
0.2
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
1000
NA
5
5
10
5
5
5
22
100
100
0.99
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
Day 14
J
U
U
U
U
BJ
BJ
U
BJ
BJ
GU
GU
BJ
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
B
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
5/18/2009
3940000
4120000
197000
210000
100
100
1000
1000
63.6
500
50
1330
178
0.52
0.5
0.2
0.2
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
2000
NA
10
10
20
10
10
10
330
200
200
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
J
J
U
U
U
U
B
U
U
B
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
PARAMETER
tert-butyl acetate
tert-Butylbenzene
Tetrachloroethene
tetrahydrofuran
Toluene
Trichloroethene
Vinyl acetate
Vinyl chloride
Xylenes (total)
1,3-Dinitrobenzene
1,4-Naphthoquinone
1-Naphthylamine
2,3,7,8-TCDD
2,4-Dimethylphenol
2,4-Dinitrophenol
2,4-Dinitrotoluene
2,6-Dichlorophenol
2,6-Dinitrotoluene
2-Chloronaphthalene
2-Chlorophenol
2-Methylnaphthalene
2-Methylphenol
2-Naphthylamine
2-Nitroaniline
2-Nitrophenol
2-Picoline
3-Nitroaniline
4-Aminobiphenyl
4-Chloroaniline
4-Nitroaniline
4-Nitrophenol
5-Nitro-o-toluidine
Acenaphthene
Acenaphthylene
Acetophenone
Aniline
Aramite
Benzidine
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(ghi)perylene
Benzyl alcohol
Chlorobenzilate
Chrysene
Diallate
Dibenzofuran
Diethyl phthalate
Dimethoate
Dimethyl phthalate
UNITS
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
PQL
-5
5
-5
5
5
5
5
5
5
15
US EPA Method
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
10
2
10
10
10
10
-10
10
10
40
10
2
10
10
2
10
2
10
10
50
10
10
10
10
10
50
50
10
10
10
10
10
50
50
100
10
2
2
10
10
10
200
10
5
2
2
2
10
10
2
2
10
10
10
2
10
2
10
10
10
10
10
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
Supply Water
Day 0
5/1/2009
5/1/2009
NA
5
5
NA
5
5
5
5
5
5
5
15
9.8
2
9.8
9.8
9.8
9.8
NA
9.8
9.8
9.8
49
9.8
2
9.8
9.8
2
9.8
2
9.8
9.8
49
9.8
9.8
9.8
9.8
9.8
49
49
9.8
9.8
9.8
9.8
9.8
49
49
98
9.8
2
2
9.8
9.8
9.8
200
2
2
2
2
2
9.8
9.8
2
2
9.8
9.8
9.8
2
9.8
2
9.8
9.8
9.8
9.8
9.8
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Location J
Tioga County, PA
Day 1
NA
5
5
NA
1.3
5
5
5
5
5
5
2.6
200
40
200
200
200
200
NA
200
200
200
1000
200
40
200
200
40
200
40
200
200
1000
200
200
200
200
200
1000
1000
200
200
200
200
200
1000
1000
2000
200
40
40
200
200
200
4000
40
40
40
40
40
200
200
4300
40
200
200
200
40
200
40
200
200
200
200
200
U
U
J
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Day 5
5/4/2009
NA
5U
5U
NA
5U
5U
5U
5U
5U
5U
5U
15 U
9.6
1.9
9.6
9.6
9.6
9.6
NA
9.6
9.6
25
48
9.6
1.9
9.6
9.6
1.9
9.6
0.82
7.3
9.6
48
9.6
9.6
9.6
9.6
4.5
48
48
9.6
9.6
9.6
9.6
9.6
48
48
96
9.6
1.9
1.9
13
9.6
9.6
190
1.9
1.9
1.9
1.9
1.9
9.6
9.6
18
1.9
1.2
9.6
9.6
1.9
9.6
1.9
9.6
1.6
9.6
9.6
0.3
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
J
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
J
U
U
J
Day 14
5/8/2009
NA
5
5
NA
5
5
5
5
5
5
5
15
9.4
1.9
9.4
9.4
9.4
9.4
NA
9.4
9.4
9.4
47
9.4
1.9
9.4
9.4
1.9
9.4
1.9
9.4
9.4
47
9.4
9.4
9.4
9.4
9.4
47
47
9.4
9.4
9.4
9.4
9.4
47
47
94
9.4
1.9
1.9
1.1
9.4
9.4
190
1.9
1.9
1.9
1.9
1.9
9.4
9.4
17
1.9
1.6
9.4
9.4
1.9
9.4
1.9
9.4
9.4
9.4
9.4
5.3
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
JB
U
U
U
U
U
U
U
U
U
J
5/18/2009
NA
10
10
NA
2.5
10
10
10
10
10
10
30
9.5
1.9
9.5
9.5
9.5
9.5
NA
9.5
9.5
9.5
48
9.5
1.9
9.5
9.5
1.9
9.5
2
0.19
9.5
48
9.5
9.5
9.5
9.5
0.61
48
48
9.5
9.5
9.5
9.5
9.5
48
48
95
9.5
0.67
1.9
1
9.5
9.5
190
1.9
1.9
1.9
1.9
1.9
9.5
9.5
1.9
1.9
9.6
9.5
9.5
1.9
9.5
1.9
9.5
9.5
9.5
9.5
130
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
J
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
PARAMETER
Dinoseb
Diphenylamine
Disulfoton
Fluoranthene
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hexachloroethane
Hexachloropropene
Isodrin
Isophorone
Isosafrole
Nitrobenzene
N-Nitrosomorpholine
N-Nitrosopiperidine
o-Toluidine
Parathion
Pentachlorobenzene
Pentachloroethane
Pentachlorophenol
Phenanthrene
Phenol
Phorate
Pronamide
Pyrene
Pyridine
Safrole
Thionazin
UNITS
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
PQL
10
10
2
10
10
2
2
0.05
2
2
10
10
2
10
10
10
10
2
10
10
10
2
2
10
10
10
10
10
10
10
10
10
20
10
10
2
2
10
10
2
10
10
10
10
US EPA Method
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
4,4'-DDD
4,4'-DDE
4,4'-DDT
Aldrin
alpha-BHC
beta-BHC
delta-BHC
Dieldrin
Endosulfan I
Endosulfan II
Endosulfan sulfate
Endrin
Endrin aldehyde
Endrin ketone
gamma-BHC (Lindane)
Heptachlor
Heptachlor epoxide
Methoxychlor
Toxaphene
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.1
2
PCBs
Aroclor 1016
Aroclor 1221
Aroclor 1232
Aroclor 1242
Aroclor 1248
Aroclor 1254
Aroclor 1260
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
0.4
0.4
0.4
0.4
0.4
0.4
0.4
Supply Water
Day 0
5/1/2009
5/1/2009
Location J
Tioga County, PA
Day 1
9.8
9.8
2
9.8
9.8
2
2
2
2
9.8
9.8
9.8
2
9.8
9.8
9.8
9.8
2
9.8
9.8
9.8
2
2
9.8
9.8
9.8
9.8
9.8
9.8
9.8
9.8
9.8
20
9.8
9.8
2
2
9.8
9.8
2
9.8
9.8
9.8
NA
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
200
200
40
200
200
40
40
40
40
200
200
200
40
200
200
200
200
40
200
200
200
40
40
200
200
200
200
200
200
200
200
200
400
200
200
40
40
200
200
40
200
200
200
NA
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
0.048
0.048
0.048
0.048
0.048
0.048
0.48
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.096
1.9
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
0.049
0.049
0.049
0.049
0.038
0.049
0.49
0.049
0.049
0.049
0.049
0.049
0.049
0.049
0.049
0.049
0.049
0.049
0.098
2
SW846 8082
SW846 8082
SW846 8082
SW846 8082
SW846 8082
SW846 8082
SW846 8082
0.38
0.38
0.38
0.38
0.38
0.38
0.38
U
U
U
U
U
U
U
0.39
0.39
0.39
0.39
0.39
0.39
0.39
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
5/4/2009
9.6 U
9.6 U
1.9 U
9.6 U
9.6 U
1.9 U
1.9 U
1.9 U
1.9 U
9.6 U
9.6 U
9.6 U
1.9 U
9.6 U
9.6 U
9.6 U
9.6 U
1.9 U
9.6 U
9.6 U
9.6 U
1.9 U
1.9 U
9.6 U
9.6 U
9.6 U
9.6 U
9.6 U
9.6 U
9.6 U
9.6 U
9.6 U
19 U
9.6 U
9.6 U
1.9 U
1.9 U
9.6 U
9.6 U
1.9 U
3.2 J
9.6 U
9.6 U
NA
Day 5
Day 14
5/8/2009
9.4
9.4
1.9
9.4
9.4
1.9
1.9
1.9
1.9
9.4
9.4
9.4
1.9
9.4
9.4
9.4
9.4
1.9
9.4
9.4
9.4
1.9
1.9
9.4
9.4
9.4
9.4
9.4
9.4
9.4
9.4
9.4
19
9.4
9.4
1.9
0.76
9.4
9.4
1.9
9.4
9.4
9.4
NA
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
5/18/2009
9.5
9.5
2.7
9.5
9.5
1.9
0.78
1.9
1.9
9.5
9.5
9.5
1.9
9.5
9.5
9.5
9.5
1.9
9.5
9.5
9.5
1.9
2.7
9.5
9.5
9.5
9.5
9.5
9.5
9.5
9.5
9.5
19
9.5
9.5
1
1.9
9.5
9.5
1.9
3.5
9.5
9.5
NA
U
U
U
U
J PG
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.048
0.048
0.048
0.083
0.048
0.048
0.48
0.048
0.048
0.048
0.044
0.048
0.048
0.048
0.048
0.27
0.36
0.052
0.095
1.9
U
U
U
U
U
U
U
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.38
0.38
0.38
0.38
0.38
0.38
0.38
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
J PG
U
U
U
U
PG
PG
U
U
U
U
U
U
U
U
U
PARAMETER
Supply Water
Day 0
5/1/2009
5/1/2009
UNITS
PQL
US EPA Method
Ethyl parathion
ug/L
0.4
SW846 8141A
0.95 U
Alcohols
2-Propanol
Butyl alcohol
Ethanol
Methanol
n-Propanol
mg/L
mg/L
mg/L
mg/L
mg/L
10
10
10
10
10
SW846 8015
SW846 8015
SW846 8015
SW846 8015
SW846 8015
10
10
10
10
10
Glycols
Ethylene Glycol
Propylene glycol
mg/L
mg/L
50
50
Acids
Acetic Acid
Butyric Acid
Propionic Acid
Volatile Acids
mg/L
mg/L
mg/L
mg/L
10
10
10
10
Location J
Tioga County, PA
Day 1
5/4/2009
1U
NA
10
10
10
10
10
Day 5
Day 14
5/8/2009
5/18/2009
NA
UJ
UJ
UJ
UJ
UJ
13
10
10
10
10
0.95 U
UJ
UJ
UJ
UJ
UJ
NA
NA
NA
NA
NA
J
UJ
UJ
UJ
UJ
10
10
10
10
10
UJ
UJ
UJ
UJ
UJ
SW846 8015
SW846 8015
100 UJ
100 UJ
NA
NA
100 UJ
100 UJ
100 UJ
100 UJ
100 UJ
100 UJ
SW846 8015
SW846 8015
SW846 8015
0.15 U
0.16 U
0.17 U
NA
NA
NA
NA
NA
0.15 U
0.16 U
0.17 U
NA
10 UJ
10 UJ
10 UJ
NA
1.5 UJ
1.6 UJ
1.7 JU
110
Location K
Bradford County, PA
Day 1
Day 5
Day 0
PARAMETER
Acidity
Amenable cyanide
Ammonia Nitrogen
Bromide
Chloride
Fluoride
Hardness, as CaCO3
Nitrate as N
Nitrate-Nitrite
Nitrite as N
Oil & Grease (HEM)
Sulfate
TOC
Total Alkalinity
Total phosphorus
Turbidity
Cyanide, Total
Total Sulfide
pH
Sulfite
MBAS (mol.wt 320)
Aluminum
Aluminum-DISS
Antimony
Antimony-DISS
Arsenic
Arsenic-DISS
Barium
Barium-DISS
Beryllium
Beryllium-DISS
Boron
Boron-DISS
Cadmium
Cadmium-DISS
Calcium
Calcium-DISS
Chromium
Chromium-DISS
Cobalt
Cobalt-DISS
Copper
Copper-DISS
Iron
Iron-DISS
Lead
Lead-DISS
Lithium
Lithium-DISS
Magnesium
Magnesium-DISS
Manganese
Manganese-DISS
Molybdenum
Molybdenum-DISS
Nickel
Nickel-DISS
Potassium
Potassium-DISS
Selenium
Selenium-DISS
Silver
Silver-DISS
05/07/2009
UNITS
PQL
US EPA Method
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
umhos/cm
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
NTU
ug/L
mg/L
No Units
mg/L
mg/L
mg/L
5
0.01
0.1
2
1
10
1
-1
5
0.05
0.1
0.05
5
-1
1
5
10
3
0.1
4
-10
3
-0.01
1
0.05
SM20 2310B (4a)

SM18 4500-CN E
MCAWW 350.1
SM18 5210 B
MCAWW 300.0A
MCAWW 410.4
MCAWW 300.0A
SM20 5310B
MCAWW 300.0A
SM20 2340C
MCAWW 300.0A
MCAWW 353.2
MCAWW 300.0A
CFR136A 1664A HEM
MCAWW 120.1
MCAWW 300.0A
SM20 5310B
SM18 2320 B
SM18 2540 C
MCAWW 351.3
MCAWW 365.2
SM20 2540D
MCAWW 180.1
SW846 9012A
SW846 9030B/9034
SW846 9040
SW846 9066
SM4500-SO3 B
SM5540 C
66.7
0.01
14
430
18.9
1260
82
301
0.05
104
1.6
0.37
0.056
4.9
507
21.5
949
116
804
47.2
0.097
26
249
320
1.6
6.3
0.011
10.4
0.05
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
200
200
10
10
10
10
200
200
4
4
2000
2000
5
5
5000
5000
5
5
500
500
25
25
100
100
3
3
500
500
5000
5000
150
150
400
400
40
40
5000
5000
5
5
5
5
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
311
2000
16.7
100
100
100
1220
1360
40
40
71.4
76.4
50
50
26600
22900
50
50
500
500
250
250
745
567
30
21.2
42
56.3
4320
3760
33.2
27.5
400
400
400
400
2750
2790
50
50
50
50
NR U
J
U
U
J
J
J
J
B
U
B
U
U
U
B
BJ
U
U
BJ
BJ
U
U
BJ
BJ
U
U
U
U
U
U
B
B
U
B
B
B
B
B
B
B
U
U
U
U
B
B
U
U
U
U
5/20/2009
5
0.01
16.8
650
117
855
10200
197
0.38
2100
2.4
0.32
1.1
4.8
35700
21.6
124
311
18600
25.2
0.14
172
63.8
16.7
1.6
7.4
0.01
8.8
0.575
420
166
34.9
36.5
32.3
100
251000
224000
40
40
2850
2590
50
50
577000
493000
48.1
50
500
500
250
250
18000
11700
70.9
35.7
23600
20200
52000
44800
519
440
54.4
42.7
176
33.4
35800
31900
50
50
50
50
Day 14
5/22/2009
U
NR U
J
U
J
J
J
B
U
BJ
B
B
B
B
U
U
U
U
U
J
B
U
U
U
U
U
B
B
B
B
B
B
U
U
U
U
6/2/2009
5
0.01
29.4
214
185
1720
34000
158
1.2
5100
1.2
0.2
4.8
4.9
79500
6.6
103
245
39400
38
0.12
61
140
7.4
1.6
6.9
0.052
5
0.012
U
U
J
2000
205
33.7
21.7
28.8
32.6
893000
1010000
40
40
3550
4170
50
50
1440000
1590000
14.6
6.6
500
500
250
250
33600
34400
30
30
41800
47800
135000
150000
881
1020
33.1
34
400
400
54600
64000
50
50
50
50
U
B
B
B
B
B
J
GU
GU
U
J
BJ
J
BJ
B
U
U
U
U
J
B
B
U
U
U
U
U
U
B
B
U
U
U
U
U
U
5
0.01
3.7
30.5
15.8
228
1670
5.2
0.05
630
0.65
0.68
1.7
9.4
6800
0.78
7.2
91.3
3010
5.6
0.17
561
548
10
3
6.6
0.0097
14
0.0733
3990
2000
14.1
100
79.8
100
105000
102000
40
40
464
313
50
50
173000
204000
567
50
10.9
500
493
250
166000
26800
138
30
3410
4000
18500
21900
2170
1230
149
400
769
62.1
8230
8140
50
50
50
50
U
U
J
U
J
BJ
J
U
U
B
U
B
U
B
U
U
U
B
B
U
U
J
J
U
B
U
U
B
B
B
U
B
B
B
U
U
U
U
Location K
Bradford County, PA
Day 1
Day 5
Day 0
PARAMETER
Sodium
Sodium-DISS
Strontium
Strontium-DISS
Thallium
Thallium-DISS
Tin
Tin-DISS
Titanium
Titanium-DISS
Trivalent Chrom
Zinc
Zinc-DISS
Hexavalent Chromium
Mercury
Mercury-DISS
1,1-Dichloroethane
1,1-Dichloroethene
1,1-Dichloropropene
1,2-Dichlorobenzene
1,2-Dichloroethane
1,2-Dichloropropane
1,3-Dichlorobenzene
1,3-Dichloropropane
1,4-Dichlorobenzene
1,4-Dioxane
2,2-Dichloropropane
2-Butanone
2-Hexanone
4-Chlorotoluene
Acetone
Acrolein
Acrylonitrile
Benzene
Benzyl chloride
Bromobenzene
Bromoform
Bromomethane
Carbon disulfide
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
Dibromomethane
Ethylbenzene
Isopropylbenzene
Methylene chloride
Naphthalene
n-Butylbenzene
n-Propylbenzene
p-Isopropyltoluene
sec-Butylbenzene
Styrene
UNITS
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
mg/L
mg/L
ug/L
ug/L
PQL
5000
5000
50
50
10
10
1000
1000
500
500
50
20
20
0.01
0.01
0.2
0.2
US EPA Method
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 7196A
SW846 7196A
SW846 7470A
SW846 7470A
05/07/2009
67800
80700
1310
899 J E
100 U
100 U
1000 U
1000 U
22.3 B J
21.2 B J
50 U
99.7 B J
76.1 B J
0.5 G U
0.5 G U
0.052 B J
0.46 B J
5/20/2009
6630000
5830000 J
117000
99700 J
100 U
100 U
1000 U
1000 U
38.5 B
39.4 B
50 U
198 B J
109 B J
0.1 G U
0.1 G U
0.2 U
0.2 U
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
1000
-5
5
10
5
5
5
20
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
5
5
5
5
5
5
5
5
5
5
42
5
5
5
5
5
20
5
5
5
1000
NA
5
5
10
5
5
5
6.7
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
1.7
5
5
5
3.9
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
14
5
5
5
5
5
7.7
5
5
5
1000
NA
5
5
10
5
5
5
5.9
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
JB
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
5/22/2009
11700000
13200000
357000
390000
100
100
1000
1000
23.9
39.2
50
147
172
0.17
0.17
0.2
0.2
5
5
5
5
5
5
5
5
5
5
7.7
5
5
5
5
5
5.3
5
5
5
1000
NA
5
5
10
5
5
5
6.9
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
Day 14
J
J
U
U
U
U
B
B
U
BJ
BJ
B
B
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
6/2/2009
922000
1100000
39000
46100
100
100
23
1000
119
500
50
517
75.7
0.05
0.047
0.2
0.2
5
5
5
5
5
5
5
5
5
5
3.9
5
5
5
5
5
2.8
5
5
5
1000
NA
5
5
10
5
5
5
20
100
100
1.5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
2.3
J
U
U
B
U
B
U
U
J
B
GU
B
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
Location K
Bradford County, PA
Day 1
Day 5
Day 0
PARAMETER
tert-butyl acetate
tert-Butylbenzene
Tetrachloroethene
tetrahydrofuran
Toluene
Trichloroethene
Vinyl acetate
Vinyl chloride
Xylenes (total)
1,3-Dinitrobenzene
1,4-Naphthoquinone
1-Naphthylamine
2,3,7,8-TCDD
2,4-Dimethylphenol
2,4-Dinitrophenol
2,4-Dinitrotoluene
2,6-Dichlorophenol
2,6-Dinitrotoluene
2-Chloronaphthalene
2-Chlorophenol
2-Methylnaphthalene
2-Methylphenol
2-Naphthylamine
2-Nitroaniline
2-Nitrophenol
2-Picoline
3-Nitroaniline
4-Aminobiphenyl
4-Chloroaniline
4-Nitroaniline
4-Nitrophenol
5-Nitro-o-toluidine
Acenaphthene
Acenaphthylene
Acetophenone
Aniline
Aramite
Benzidine
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(ghi)perylene
Benzyl alcohol
Chlorobenzilate
Chrysene
Diallate
Dibenzofuran
Diethyl phthalate
Dimethoate
Dimethyl phthalate
UNITS
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
PQL
-5
5
-5
5
5
5
5
5
5
15
US EPA Method
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
10
2
10
10
10
10
-10
10
10
40
10
2
10
10
2
10
2
10
10
50
10
10
10
10
10
50
50
10
10
10
10
10
50
50
100
10
2
2
10
10
10
200
10
5
2
2
2
10
10
2
2
10
10
10
2
10
2
10
10
10
10
10
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
05/07/2009
NA
5U
5U
NA
5U
5U
5U
5U
5U
5U
5U
35
9.9
2
9.9
9.9
9.9
9.9
NA
9.9
9.9
9.9
50
9.9
2
9.9
9.9
2
9.9
2
9.9
9.9
50
9.9
9.9
9.9
9.9
9.9
50
50
9.9
9.9
9.9
9.9
9.9
50
50
99
9.9
2
2
9.9
9.9
9.9
200
1.1
6.9
11
7.4
6.7
9.9
9.9
2
2
15
9.9
9.9
1.7
9.9
12
9.9
9.9
9.9
9.9
9.9
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
B
U
U
J
U
U
U
U
U
U
5/20/2009
NA
5U
5U
NA
5U
5U
5U
5U
5U
5U
5U
4.8 J
9.5
1.9
9.5
9.5
9.5
9.5
NA
9.5
9.5
9.5
48
9.5
1.9
9.5
9.5
1.9
9.5
1.9
9.5
9.5
48
9.5
9.5
9.5
9.5
9.5
48
48
9.5
9.5
9.5
9.5
9.5
48
48
95
9.5
1.9
1.9
9.5
9.5
9.5
190
1.9
1.9
1.9
1.9
1.9
9.5
9.5
1.9
1.9
1.8
9.5
9.5
1.9
9.5
1.9
9.5
9.5
9.5
9.5
5
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
J
5/22/2009
NA
5
5
NA
5
5
5
5
5
5
5
3
9.4
1.9
9.4
9.4
9.4
9.4
NA
9.4
9.4
9.4
47
9.4
1.9
9.4
9.4
1.9
9.4
1.9
9.4
9.4
47
9.4
9.4
9.4
9.4
9.4
47
47
9.4
9.4
9.4
9.4
9.4
47
47
94
9.4
1.9
1.9
9.4
9.4
9.4
190
1.9
1.9
1.9
1.9
1.9
9.4
9.4
1.9
1.9
9.4
9.4
9.4
1.9
9.4
1.9
9.4
9.4
9.4
9.4
9.4
Day 14
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
6/2/2009
NA
5
5
NA
1.6
5
5
5
5
5
5
3.7
10
2
10
10
10
10
NA
10
10
10
50
10
2
10
10
2
10
2
10
10
50
10
10
10
10
0.41
50
50
10
10
10
10
10
50
50
100
10
2
2
10
10
10
200
2
2
2
2
2
9.1
10
2
2
10
10
10
2
10
2
10
0.73
10
10
10
U
U
J
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
J
U
U
U
Location K
Bradford County, PA
Day 1
Day 5
Day 0
PARAMETER
Dinoseb
Diphenylamine
Disulfoton
Fluoranthene
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hexachloroethane
Hexachloropropene
Isodrin
Isophorone
Isosafrole
Nitrobenzene
N-Nitrosomorpholine
N-Nitrosopiperidine
o-Toluidine
Parathion
Pentachlorobenzene
Pentachloroethane
Pentachlorophenol
Phenanthrene
Phenol
Phorate
Pronamide
Pyrene
Pyridine
Safrole
Thionazin
Day 14
UNITS
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
PQL
10
10
2
10
10
2
2
0.05
2
2
10
10
2
10
10
10
10
2
10
10
10
2
2
10
10
10
10
10
10
10
10
10
20
10
10
2
2
10
10
2
10
10
10
10
US EPA Method
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
4,4'-DDD
4,4'-DDE
4,4'-DDT
Aldrin
alpha-BHC
beta-BHC
delta-BHC
Dieldrin
Endosulfan I
Endosulfan II
Endosulfan sulfate
Endrin
Endrin aldehyde
Endrin ketone
gamma-BHC (Lindane)
Heptachlor
Heptachlor epoxide
Methoxychlor
Toxaphene
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.1
2
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
0.049
0.049
0.049
0.049
0.049
0.049
0.49
0.049
0.049
0.049
0.049
0.049
0.049
0.049
0.049
0.049
0.049
0.049
0.098
2
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.048
0.048
0.048
0.048
0.048
0.048
0.48
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.036
0.1
0.048
0.097
1.9
PCBs
Aroclor 1016
Aroclor 1221
Aroclor 1232
Aroclor 1242
Aroclor 1248
Aroclor 1254
Aroclor 1260
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
0.4
0.4
0.4
0.4
0.4
0.4
0.4
SW846 8082
SW846 8082
SW846 8082
SW846 8082
SW846 8082
SW846 8082
SW846 8082
0.39
0.39
0.39
0.39
0.39
0.39
0.39
U
U
U
U
U
U
U
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.39
0.39
0.39
0.39
0.39
0.39
0.39
05/07/2009
9.9 U
9.9 U
2U
9.9 U
9.9 U
2U
2U
2U
2U
9.9 U
9.9 U
9.9 U
10
9.9 U
9.9 U
9.9 U
9.9 U
2U
9.9 U
9.9 U
9.9 U
2U
2U
9.9 U
9.9 U
9.9 U
9.9 U
9.9 U
9.9 U
9.9 U
9.9 U
9.9 U
20 U
9.9 U
9.9 U
2U
2U
9.9 U
9.9 U
2U
9.9 U
9.9 U
9.9 U
NA
5/20/2009
9.5 U
9.5 U
1.9 U
9.5 U
9.5 U
1.9 U
1.9 U
1.9 U
1.9 U
9.5 U
9.5 U
9.5 U
1.9 U
9.5 U
9.5 U
9.5 U
9.5 U
1.9 U
9.5 U
9.5 U
9.5 U
1.9 U
1.9 U
9.5 U
9.5 U
9.5 U
9.5 U
9.5 U
9.5 U
9.5 U
9.5 U
9.5 U
19 U
9.5 U
9.5 U
1.9 U
1.9 U
9.5 U
9.5 U
1.9 U
9.5 U
9.5 U
9.5 U
NA
5/22/2009
9.4
9.4
1.9
9.4
9.4
1.9
1.9
1.9
1.9
9.4
9.4
9.4
1.9
9.4
9.4
9.4
9.4
1.9
9.4
9.4
9.4
1.9
1.9
9.4
9.4
9.4
9.4
9.4
9.4
9.4
9.4
9.4
19
9.4
9.4
1.9
1.9
9.4
9.4
1.9
9.4
9.4
9.4
NA
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
6/2/2009
10
10
2
10
10
2
2
2
2
10
10
10
2
10
10
10
10
2
10
10
10
2
2
10
10
10
10
10
10
10
10
10
20
10
10
2
2
10
10
2
150
10
10
NA
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J PG
U
U
U
U
U
U
U
U
U
U
Location K
Bradford County, PA
Day 1
Day 5
Day 0
PARAMETER
Day 14
UNITS
PQL
US EPA Method
Ethyl parathion
ug/L
0.4
SW846 8141A
0.95 U
NA
Alcohols
2-Propanol
Butyl alcohol
Ethanol
Methanol
n-Propanol
mg/L
mg/L
mg/L
mg/L
mg/L
10
10
10
10
10
SW846 8015
SW846 8015
SW846 8015
SW846 8015
SW846 8015
10
10
10
10
10
10
10
10
10
10
Glycols
Ethylene Glycol
Propylene glycol
mg/L
mg/L
50
50
SW846 8015
SW846 8015
100 UJ
220 J
100 UJ
130 J
100 UJ
100 UJ
100 UJ
100 UJ
Acids
Acetic Acid
Butyric Acid
Propionic Acid
Volatile Acids
mg/L
mg/L
mg/L
mg/L
10
10
10
10
SW846 8015
SW846 8015
SW846 8015
50 UJ
50 UJ
50 UJ
2300
42 J
20 UJ
20 UJ
170
39 J
10 UJ
10 UJ
400
10 UJ
10 UJ
10 UJ
110
05/07/2009
UJ
UJ
UJ
UJ
UJ
5/20/2009
5/22/2009
6/2/2009
NA
UJ
UJ
UJ
UJ
UJ
10
10
10
10
10
0.95 U
UJ
UJ
UJ
UJ
UJ
10
10
10
10
10
UJ
UJ
UJ
UJ
UJ
Day 0
Supply Water
PARAMETER
Acidity
Amenable cyanide
Ammonia Nitrogen
Bromide
Chloride
Fluoride
Hardness, as CaCO3
Nitrate as N
Nitrate-Nitrite
Nitrite as N
Oil & Grease (HEM)
Sulfate
TOC
Total Alkalinity
Total phosphorus
Turbidity
Cyanide, Total
Total Sulfide
pH
Sulfite
MBAS (mol.wt 320)
Aluminum
Aluminum-DISS
Antimony
Antimony-DISS
Arsenic
Arsenic-DISS
Barium
Barium-DISS
Beryllium
Beryllium-DISS
Boron
Boron-DISS
Cadmium
Cadmium-DISS
Calcium
Calcium-DISS
Chromium
Chromium-DISS
Cobalt
Cobalt-DISS
Copper
Copper-DISS
Iron
Iron-DISS
Lead
Lead-DISS
Lithium
Lithium-DISS
Magnesium
Magnesium-DISS
Manganese
Manganese-DISS
Molybdenum
Molybdenum-DISS
Nickel
Nickel-DISS
Potassium
Potassium-DISS
Selenium
Selenium-DISS
Silver
Silver-DISS
Location L
Butler County, PA
Day 1
5/12/2009
5/14/2009
UNITS
PQL
US EPA Method
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
umhos/cm
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
NTU
ug/L
mg/L
No Units
mg/L
mg/L
mg/L
5
0.01
0.1
2
1
10
1
-1
5
0.05
0.1
0.05
5
-1
1
5
10
3
0.1
4
-10
3
-0.01
1
0.05
SM20 2310B (4a)

SM18 4500-CN E
MCAWW 350.1
SM18 5210 B
MCAWW 300.0A
MCAWW 410.4
MCAWW 300.0A
SM20 5310B
MCAWW 300.0A
SM20 2340C
MCAWW 300.0A
MCAWW 353.2
MCAWW 300.0A
CFR136A 1664A HEM
MCAWW 120.1
MCAWW 300.0A
SM20 5310B
SM18 2320 B
SM18 2540 C
MCAWW 351.3
MCAWW 365.2
SM20 2540D
MCAWW 180.1
SW846 9012A
SW846 9030B/9034
SW846 9040
SW846 9066
SM4500-SO3 B
SM5540 C
5.5
0.27
3.9
2
30.6
594
101
222
0.05
124
0.59
0.61
0.3
4.6
519
48.3
202
33.6
390
17.9
0.088
14
9.1
625
3
6.8
0.011
10.8
0.317
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
200
200
10
10
10
10
200
200
4
4
2000
2000
5
5
5000
5000
5
5
500
500
25
25
100
100
3
3
500
500
5000
5000
150
150
400
400
40
40
5000
5000
5
5
5
5
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
2000
2000
100
100
100
100
243
222
40
40
47.9
54.1
50
50
32000
33900
50
50
500
500
250
250
1810
968
30
30
500
500
6530
7090
29.3
27.8
400
400
400
400
2360
3250
50
50
50
50
5
0.87
2.9
2
9.2
511
115
361
0.05
114
0.91
1
0.34
20
599
40
155
62
221
24
0.063
4
2.7
954
3
7.8
0.01
J
U
U
J
J
J
J
B
B
J
U
U
J
J
J
J
B
U
NA
NA
U
U
U
U
U
U
B
BJ
U
U
BJ
BJ
U
U
BJ
BJ
U
U
U
U
U
U
B
U
U
U
U
B
B
B
B
U
U
U
U
B
B
U
U
U
U
2000
2000
100
21.1
100
100
108
91.2
40
40
43.3
54.5
50
50
31500
33800
50
50
500
500
250
250
137
1000
30
30
500
500
6740
7170
7.5
150
400
400
400
400
2250
4220
50
50
50
50
U
U
U
B
U
U
B
BJ
U
U
BJ
BJ
U
U
BJ
BJ
U
U
U
U
U
U
B
U
U
U
U
U
B
B
B
U
U
U
U
U
B
B
U
U
U
U
5
0.14
31.6
27.6
162
1010
9580
313
0.5
2200
1.7
0.74
0.5
5.2
33800
58.9
115
186
20400
46.4
0.1
71
16.2
177
3
7.8
0.022
9.60
0.301
290
223
17.9
19.8
100
100
7110
6520
40
40
7290
6690
50
50
833000
757000
10.4
50
4.5
500
57.2
47.2
5570
4950
26.1
30
17400
15900
89000
81300
682
608
151
135
41.7
32.7
126000
118000
50
50
50
50
GU
GU
U
J
J
J
BJ
BJ
B
B
U
U
J
U
U
J
U
U
B
U
B
U
B
B
B
U
B
B
B
B
U
U
U
U
Day 5
Day 14
5/18/2009
5/27/2009
5
0.032
71.2
37.1
413
4250
35100
117
1.2
12600
1.2
0.54
1.2
8.4
118000
51.4
80.5
109
72700
67.6
1
23.2
20.9
46.1
2.4
6.7
0.026
12.4
0.234
350
310
100
100
40.7
100
34700
60700
40
40
14100
14400
50
50
3890000
3970000
10.5
50
500
500
250
250
21500
20200
51.1
30
49700
52100
424000
440000
2110
2160
47.2
48.6
400
400
308000
322000
50
50
50
50
J
GU
GU
GU
U
J
J
J
GU
BJ
BJ
U
U
B
U
J
U
U
J
U
U
B
U
U
U
U
U
B
B
U
U
U
U
U
U
252
0.01
114
426
704
12000
49000
57.2
2.5
27000
2.5
0.33
13.4
103
181000
28.8
83.2
99.8
109000
110
0.039
865
1090
2.7
3.2
6.1
0.04
7.20
0.126
728
418
100
100
110
43.5
82300
75600
40
40
17800
18300
4.4
1.8
7300000
7570000
167
50
27.8
15.6
212
250
574000
135000
171
60
78500
78700
792000
813000
18600
16700
69.4
400
82.6
35.8
496000
508000
50
50
50
50
U
J
GU
GU
J
B
J
B
B
U
U
B
U
U
BJ
B
J
J
U
B
B
B
U
B
U
B
B
U
U
U
U
Supply Water
PARAMETER
Sodium
Sodium-DISS
Strontium
Strontium-DISS
Thallium
Thallium-DISS
Tin
Tin-DISS
Titanium
Titanium-DISS
Trivalent Chrom
Zinc
Zinc-DISS
Hexavalent Chromium
Mercury
Mercury-DISS
1,1-Dichloroethane
1,1-Dichloroethene
1,1-Dichloropropene
1,2-Dichlorobenzene
1,2-Dichloroethane
1,2-Dichloropropane
1,3-Dichlorobenzene
1,3-Dichloropropane
1,4-Dichlorobenzene
1,4-Dioxane
2,2-Dichloropropane
2-Butanone
2-Hexanone
4-Chlorotoluene
Acetone
Acrolein
Acrylonitrile
Benzene
Benzyl chloride
Bromobenzene
Bromoform
Bromomethane
Carbon disulfide
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
Dibromomethane
Ethylbenzene
Isopropylbenzene
Methylene chloride
Naphthalene
n-Butylbenzene
n-Propylbenzene
p-Isopropyltoluene
sec-Butylbenzene
Styrene
UNITS
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
mg/L
mg/L
ug/L
ug/L
PQL
5000
5000
50
50
10
10
1000
1000
500
500
50
20
20
0.01
0.01
0.2
0.2
US EPA Method
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 7196A
SW846 7196A
SW846 7470A
SW846 7470A
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
1000
-5
5
10
5
5
5
20
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
Location L
Butler County, PA
Day 1
Day 0
5/12/2009
46900
49400
634
580
100
100
1000
1000
500
26.9
50
35.8
75.9
0.25
0.25
0.054
0.53
5
5
5
5
5
5
5
5
5
5
27
5
5
5
5
5
14
5
5
5
1000
NA
5
5
10
5
5
5
9.8
100
100
5
5
5
5
50
5
5
5
1.3
5
5
5
5
5
5
5
5
0.65
5
5
5
4.6
5
5
5
5
5
B
B
J
U
U
U
U
U
BJ
U
BJ
BJ
GU
GU
BJ
BJ
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
J
U
U
U
J
U
U
U
U
U
64800
72000
206
158
100
100
1000
1000
19.4
500
50
34.8
138
0.25
0.25
0.05
0.57
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
1000
NA
5
5
10
5
5
5
20
100
100
5
5
5
5
9.3
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
3.8
5
5
5
5
5
B
BJ
U
U
U
U
BJ
U
U
BJ
BJ
GU
U
BJ
BJ
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
5/14/2009
6290000
5630000
169000
151000
100
100
1000
1000
500
500
50
95.6
79.5
0.01
0.01
0.2
0.2
5
5
5
5
5
5
5
5
5
5
0.81
5
5
5
5
5
0.78
5
5
5
1000
NA
5
5
10
5
5
5
6
100
100
39
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
1.3
5
5
5
5
5
5
5
5
5
Day 5
J
J
U
U
U
U
U
U
U
B
B
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
5/18/2009
17900000
18600000
738000
763000
100
26.9
1000
1000
53.7
42.8
50
172
147
0.25
0.25
0.2
0.2
10
10
10
10
10
10
10
10
10
10
38
10
10
10
10
10
32
10
10
10
2000
NA
10
10
20
10
10
10
17
200
200
99
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
17
10
10
10
10
10
10
10
10
10
Day 14
J
J
U
B
U
U
B
B
U
B
B
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
5/27/2009
26600000
26400000
1620000
1650000
200
200
1000
1000
175
105
50
330
74.5
0.1
0.1
0.2
0.2
50
50
50
50
50
50
50
50
50
50
770
50
50
50
50
50
670
50
50
50
10000
NA
50
50
100
50
50
50
200
1000
1000
260
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
220
86
50
50
50
50
50
50
50
50
J
U
U
U
U
B
B
U
J
B
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Supply Water
PARAMETER
tert-butyl acetate
tert-Butylbenzene
Tetrachloroethene
tetrahydrofuran
Toluene
Trichloroethene
Vinyl acetate
Vinyl chloride
Xylenes (total)
1,3-Dinitrobenzene
1,4-Naphthoquinone
1-Naphthylamine
2,3,7,8-TCDD
2,4-Dimethylphenol
2,4-Dinitrophenol
2,4-Dinitrotoluene
2,6-Dichlorophenol
2,6-Dinitrotoluene
2-Chloronaphthalene
2-Chlorophenol
2-Methylnaphthalene
2-Methylphenol
2-Naphthylamine
2-Nitroaniline
2-Nitrophenol
2-Picoline
3-Nitroaniline
4-Aminobiphenyl
4-Chloroaniline
4-Nitroaniline
4-Nitrophenol
5-Nitro-o-toluidine
Acenaphthene
Acenaphthylene
Acetophenone
Aniline
Aramite
Benzidine
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(ghi)perylene
Benzyl alcohol
Chlorobenzilate
Chrysene
Diallate
Dibenzofuran
Diethyl phthalate
Dimethoate
Dimethyl phthalate
UNITS
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
PQL
-5
5
-5
5
5
5
5
5
5
15
US EPA Method
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
10
2
10
10
10
10
-10
10
10
40
10
2
10
10
2
10
2
10
10
50
10
10
10
10
10
50
50
10
10
10
10
10
50
50
100
10
2
2
10
10
10
200
10
5
2
2
2
10
10
2
2
10
10
10
2
10
2
10
10
10
10
10
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
Location L
Butler County, PA
Day 1
Day 0
5/12/2009
NA
5
2.2
NA
5
5
5
5
5
5
5
2
12
2.3
12
12
12
12
NA
12
12
12
58
12
2.3
12
12
2.3
12
2.3
12
12
58
12
12
12
12
12
58
58
12
12
12
12
12
58
58
120
12
2.3
2.3
12
12
12
230
2.3
2.3
2.3
2.3
2.3
12
12
6.7
2.3
12
12
12
2.3
12
2.3
12
12
12
12
6.3
U
J
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
NA
5
5
NA
5
5
5
5
5
5
5
15
9.7
1.9
9.7
9.7
0.81
9.7
NA
9.7
9.7
9.7
48
9.7
1.9
9.7
9.7
1.9
9.7
1.9
9.7
9.7
48
9.7
9.7
9.7
9.7
9.7
48
48
9.7
9.7
9.7
9.7
9.7
48
48
97
9.7
1.9
1.9
1.2
9.7
9.7
190
1.9
1.9
1.9
1.9
1.9
16
9.7
1.9
1.9
9.7
9.7
9.7
1.9
9.7
1.9
9.7
9.7
9.7
9.7
5.5
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
5/14/2009
NA
5
5
NA
46
5
5
5
5
5
5
15
9.6
1.9
9.6
9.6
9.6
9.6
NA
9.6
9.6
1.5
48
9.6
1.9
9.6
9.6
1.9
9.6
1.9
2.7
9.6
48
9.6
9.6
9.6
9.6
3
48
48
9.6
9.6
9.6
9.6
9.6
48
48
96
9.6
1.9
1.9
9.6
9.6
9.6
190
1.9
1.9
1.9
1.9
1.9
9.6
9.6
1.9
1.9
9.6
9.6
9.6
1.9
9.6
1.9
9.6
9.6
9.6
9.6
9.6
Day 5
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
5/18/2009
NA
10
10
NA
260
10
10
10
10
10
10
220
9.4
1.9
9.4
9.4
9.4
9.4
NA
9.4
9.4
9.4
47
9.4
1.9
9.4
9.4
1.9
9.4
1.9
4
9.4
47
9.4
9.4
9.4
9.4
5.2
47
47
9.4
9.4
9.4
9.4
9.4
47
47
94
9.4
1.9
1.9
9.4
9.4
9.4
190
1.9
1.9
1.9
1.9
1.9
7.1
9.4
1.9
1.9
9.4
9.4
9.4
1.9
9.4
1.9
9.4
3
9.4
9.4
9.4
Day 14
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
J
U
U
U
5/27/2009
NA
50
50
NA
1500
50
50
50
50
50
50
2700
9.4
1.9
9.4
9.4
9.4
9.4
NA
9.4
9.4
9.4
47
9.4
1.9
9.4
9.4
1.9
9.4
1.9
9.4
9.4
47
9.4
9.4
9.4
9.4
9.4
47
47
9.4
9.4
9.4
9.4
9.4
47
47
94
9.4
1.9
1.9
9.4
9.4
9.4
190
1.9
1.9
1.9
1.9
1.9
9.4
9.4
1.9
1.9
6.4
9.4
9.4
1.9
9.4
1.9
9.4
9.4
9.4
9.4
9.4
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
Supply Water
PARAMETER
Dinoseb
Diphenylamine
Disulfoton
Fluoranthene
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hexachloroethane
Hexachloropropene
Isodrin
Isophorone
Isosafrole
Nitrobenzene
N-Nitrosomorpholine
N-Nitrosopiperidine
o-Toluidine
Parathion
Pentachlorobenzene
Pentachloroethane
Pentachlorophenol
Phenanthrene
Phenol
Phorate
Pronamide
Pyrene
Pyridine
Safrole
Thionazin
UNITS
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
PQL
10
10
2
10
10
2
2
0.05
2
2
10
10
2
10
10
10
10
2
10
10
10
2
2
10
10
10
10
10
10
10
10
10
20
10
10
2
2
10
10
2
10
10
10
10
US EPA Method
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
4,4'-DDD
4,4'-DDE
4,4'-DDT
Aldrin
alpha-BHC
beta-BHC
delta-BHC
Dieldrin
Endosulfan I
Endosulfan II
Endosulfan sulfate
Endrin
Endrin aldehyde
Endrin ketone
gamma-BHC (Lindane)
Heptachlor
Heptachlor epoxide
Methoxychlor
Toxaphene
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.1
2
PCBs
Aroclor 1016
Aroclor 1221
Aroclor 1232
Aroclor 1242
Aroclor 1248
Aroclor 1254
Aroclor 1260
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
0.4
0.4
0.4
0.4
0.4
0.4
0.4
Location L
Butler County, PA
Day 1
Day 0
5/12/2009
Day 5
Day 14
12
12
2.3
12
12
2.3
2.3
2.3
2.3
12
12
12
2.3
12
12
12
12
2.3
12
12
12
2.3
2.3
12
12
12
12
12
12
12
12
12
23
12
12
2.3
2.3
12
12
2.3
12
12
12
NA
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
9.7
9.7
1.9
9.7
9.7
1.9
1.9
1.9
1.9
9.7
9.7
9.7
1.9
9.7
9.7
9.7
9.7
1.9
9.7
9.7
9.7
1.9
1.9
9.7
9.7
9.7
9.7
9.7
9.7
9.7
9.7
9.7
19
9.7
9.7
1.9
1.9
9.7
9.7
1.9
9.7
9.7
9.7
NA
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
5/14/2009
9.6
9.6
1.9
9.6
9.6
1.9
1.9
1.9
1.9
9.6
9.6
9.6
1.9
9.6
9.6
9.6
9.6
1.9
9.6
9.6
9.6
1.9
1.9
9.6
9.6
9.6
9.6
9.6
9.6
9.6
9.6
9.6
19
9.6
9.6
1.9
5.5
9.6
9.6
1.9
9.6
9.6
9.6
NA
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
0.047
0.047
0.047
0.047
0.047
0.047
0.47
0.047
0.047
0.047
0.047
0.047
0.047
0.047
0.047
0.047
0.047
0.047
0.094
1.9
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
0.048
0.048
0.048
0.048
0.048
0.048
0.48
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.096
1.9
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.048
0.048
0.048
0.048
0.037
0.069
0.48
0.048
0.048
0.048
0.048
0.048
0.046
0.048
0.048
0.38
0.048
0.048
0.095
1.9
SW846 8082
SW846 8082
SW846 8082
SW846 8082
SW846 8082
SW846 8082
SW846 8082
0.38
0.38
0.38
0.38
0.38
0.38
0.38
U
U
U
U
U
U
U
0.38
0.38
0.38
0.38
0.38
0.38
0.38
U
U
U
U
U
U
U
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.38
0.38
0.38
0.38
0.38
0.38
0.38
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
5/18/2009
9.4
9.4
1.9
9.4
9.4
1.9
1.9
1.9
1.9
9.4
9.4
9.4
1.9
9.4
9.4
9.4
9.4
1.9
9.4
9.4
9.4
1.9
1.9
9.4
9.4
9.4
9.4
9.4
9.4
9.4
9.4
9.4
19
9.4
9.4
1.9
10
9.4
9.4
1.9
9.4
9.4
9.4
NA
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
5/27/2009
9.4
9.4
1.9
9.4
9.4
1.9
1.9
1.9
1.9
9.4
9.4
9.4
1.9
9.4
9.4
9.4
9.4
1.9
9.4
9.4
9.4
1.9
1.9
9.4
9.4
9.4
9.4
9.4
9.4
9.4
9.4
9.4
19
9.4
9.4
0.62
1.9
9.4
9.4
1.9
9.4
9.4
9.4
NA
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
J PG
PG
U
U
U
U
U
U
J PG
U
U
U
U
U
U
U
U
U
U
U
U
U
Supply Water
PARAMETER
Location L
Butler County, PA
Day 1
Day 0
Day 5
Day 14
5/18/2009
5/27/2009
UNITS
PQL
US EPA Method
Ethyl parathion
ug/L
0.4
SW846 8141A
0.99 U
0.98 U
NA
Alcohols
2-Propanol
Butyl alcohol
Ethanol
Methanol
n-Propanol
mg/L
mg/L
mg/L
mg/L
mg/L
10
10
10
10
10
SW846 8015
SW846 8015
SW846 8015
SW846 8015
SW846 8015
10
10
10
10
10
UJ
UJ
UJ
UJ
UJ
NA
NA
NA
NA
NA
10
10
10
10
10
Glycols
Ethylene Glycol
Propylene glycol
mg/L
mg/L
50
50
SW846 8015
SW846 8015
100 UJ
100 UJ
NA
NA
100 UJ
100 UJ
100 UJ
100 UJ
100 UJ
100 UJ
Acids
Acetic Acid
Butyric Acid
Propionic Acid
Volatile Acids
mg/L
mg/L
mg/L
mg/L
10
10
10
10
SW846 8015
SW846 8015
SW846 8015
1.5 UJ
1.6 UJ
1.7 UJ
NA
NA
NA
NA
NA
7.5 UJ
8 UJ
8.5 UJ
NA
7.5 UJ
8 UJ
8.5 UJ
NA
7.5 UJ
8 UJ
8.5 UJ
290
5/12/2009
5/14/2009
NA
UJ
UJ
UJ
UJ
UJ
10
10
10
10
10
0.95 U
UJ
UJ
UJ
UJ
UJ
10
13
10
10
10
UJ
J
UJ
UJ
UJ
PARAMETER
Acidity
Amenable cyanide
Ammonia Nitrogen
Bromide
Chloride
Fluoride
Hardness, as CaCO3
Nitrate as N
Nitrate-Nitrite
Nitrite as N
Oil & Grease (HEM)
Sulfate
TOC
Total Alkalinity
Total phosphorus
Turbidity
Cyanide, Total
Total Sulfide
pH
Sulfite
MBAS (mol.wt 320)
Aluminum
Aluminum-DISS
Antimony
Antimony-DISS
Arsenic
Arsenic-DISS
Barium
Barium-DISS
Beryllium
Beryllium-DISS
Boron
Boron-DISS
Cadmium
Cadmium-DISS
Calcium
Calcium-DISS
Chromium
Chromium-DISS
Cobalt
Cobalt-DISS
Copper
Copper-DISS
Iron
Iron-DISS
Lead
Lead-DISS
Lithium
Lithium-DISS
Magnesium
Magnesium-DISS
Manganese
Manganese-DISS
Molybdenum
Molybdenum-DISS
Nickel
Nickel-DISS
Potassium
Potassium-DISS
Selenium
Selenium-DISS
Silver
Silver-DISS
UNITS
PQL
US EPA Method
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
umhos/cm
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
NTU
ug/L
mg/L
No Units
mg/L
mg/L
mg/L
5
0.01
0.1
2
1
10
1
-1
5
0.05
0.1
0.05
5
-1
1
5
10
3
0.1
4
-10
3
-0.01
1
0.05
SM20 2310B (4a)

SM18 4500-CN E
MCAWW 350.1
SM18 5210 B
MCAWW 300.0A
MCAWW 410.4
MCAWW 300.0A
SM20 5310B
MCAWW 300.0A
SM20 2340C
MCAWW 300.0A
MCAWW 353.2
MCAWW 300.0A
CFR136A 1664A HEM
MCAWW 120.1
MCAWW 300.0A
SM20 5310B
SM18 2320 B
SM18 2540 C
MCAWW 351.3
MCAWW 365.2
SM20 2540D
MCAWW 180.1
SW846 9012A
SW846 9030B/9034
SW846 9040
SW846 9066
SM4500-SO3 B
SM5540 C
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
200
200
10
10
10
10
200
200
4
4
2000
2000
5
5
5000
5000
5
5
500
500
25
25
100
100
3
3
500
500
5000
5000
150
150
400
400
40
40
5000
5000
5
5
5
5
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
Supply Water
Day 0
5/19/2009
5/19/2009
5
0.01
0.25
2
2
10
4.1
1.4
0.05
18
0.24
0.24
0.21
4.6
54.8
3.8
1.8
6.2
51
2.2
0.1
4
4.3
10
1.6
7.1
0.01
6
0.05
122
160
14.6
100
100
100
271
274
40
40
2000
2000
50
50
4880
3690
50
50
500
500
250
250
605
543
30
30
500
500
1080
1440
134
127
400
400
400
400
50000
50000
50
50
50
50
U
U
J
U
GU
U
B
11.4
0.0097
1.5
137
10
490
29.9
84.3
0.009
26
2.5
0.24
2.5
33.2
177
2.9
86.6
9.6
371
31.3
0.096
110
254
12.5
3
6.2
0.0069
12
0.05
BJ
B
B
U
U
U
B
B
U
U
U
U
U
U
BJ
B
U
U
U
U
U
U
B
B
U
U
U
U
B
B
B
B
U
U
U
U
U
U
U
U
U
U
180
239
100
100
100
100
579
621
40
40
2000
2000
50
50
6690
6080
50
50
500
500
44.5
250
497
460
30
30
500
28.1
1250
1460
127
130
400
400
19.5
400
50000
50000
50
50
50
50
U
B
B
U
J
B
J
B
U
U
U
B
U
Location M
McKean County, PA
Day 1
6/6/2009
B
J
GU
B
B
U
GU
J
B
J
U
B
BJ
B
U
U
U
U
B
B
U
U
U
U
U
U
BJ
B
U
U
U
U
B
U
B
B
U
U
U
B
B
B
B
B
U
U
B
U
U
U
U
U
U
U
NA
0.01
173
36.3
NA
10700
NA
77
2.5
NA
2.5
0.01
NA
NA
NA
50
2.2
NA
NA
158
1.4
NA
NA
10
3
5.9
0.007
24.4
0.241
165
289
13.9
16.9
100
100
1450000
1430000
40
40
12000
11800
50
50
19700000
19700000
15.7
50
5000
5000
255
81.1
67200
37600
30
30
129000
126000
1320000
1310000
5960
5850
48.2
34.7
400
400
923000
1000000
50
50
50
50
GU
GU
B
GU
U
U
B
B
BJ
B
B
U
U
U
U
U
U
J
J
B
U
U
U
B
U
U
J
B
BJ
U
U
U
U
U
U
Day 5
Day 14
6/10/2009
6/19/2009
NA
0.01
192
103
NA
7600
NA
33.1
2.5
NA
2.5
0.049
25.9
NA
NA
50
3.7
NA
NA
178
0.1
NA
NA
10
3
7.2
0.29
11.6
0.291
131
188
17.3
20.9
100
100
1730000
1760000
40
40
10500
11000
50
1.5
23500000
23800000
50
50
5000
5000
78.9
57.7
53100
44800
30
30
137000
154000
1550000
1600000
7040
7170
400
400
400
400
849000
1010000
50
50
50
50
GU
GU
BJ
GU
U
U
B
BJ
B
B
U
U
U
U
U
B
J
J
U
U
U
U
B
B
U
U
J
U
U
U
U
U
U
U
U
200
0.01
268
10.2
1190
9180
151000
5
2.5
95000
2.5
0.11
55.8
7.4
710000
50
1.2
26.1
228000
199
2.2
40.8
67.8
10
3
5.8
0.006
10.4
0.198
158
210
100
15.7
100
100
1970000
1990000
40
40
10000
9740
50
1.5
26400000
26200000
50
50
5000
5000
250
250
61000
53300
30
30
155000
158000
1800000
1740000
8560
8420
400
400
400
400
972000
1010000
50
50
50
50
U
J
GU
GU
J
GU
J
U
U
B
B
BJ
U
B
U
U
U
U
U
B
J
J
U
U
U
U
U
U
U
U
J
U
U
U
U
E
E
U
U
U
U
Supply Water
PARAMETER
Sodium
Sodium-DISS
Strontium
Strontium-DISS
Thallium
Thallium-DISS
Tin
Tin-DISS
Titanium
Titanium-DISS
Trivalent Chrom
Zinc
Zinc-DISS
Hexavalent Chromium
Mercury
Mercury-DISS
1,1-Dichloroethane
1,1-Dichloroethene
1,1-Dichloropropene
1,2-Dichlorobenzene
1,2-Dichloroethane
1,2-Dichloropropane
1,3-Dichlorobenzene
1,3-Dichloropropane
1,4-Dichlorobenzene
1,4-Dioxane
2,2-Dichloropropane
2-Butanone
2-Hexanone
4-Chlorotoluene
Acetone
Acrolein
Acrylonitrile
Benzene
Benzyl chloride
Bromobenzene
Bromoform
Bromomethane
Carbon disulfide
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
Dibromomethane
Ethylbenzene
Isopropylbenzene
Methylene chloride
Naphthalene
n-Butylbenzene
n-Propylbenzene
p-Isopropyltoluene
sec-Butylbenzene
Styrene
UNITS
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
mg/L
mg/L
ug/L
ug/L
PQL
5000
5000
50
50
10
10
1000
1000
500
500
50
20
20
0.01
0.01
0.2
0.2
US EPA Method
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 7196A
SW846 7196A
SW846 7470A
SW846 7470A
5/19/2009
4200 B
3600 B J
352 B
340 B J
100 U
100 U
1000 U
1000 U
500 U
500 U
50 U
56.7 B J
41.1 B J
0.01 U
0.01 U
0.2 U
0.2 U
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
1000
-5
5
10
5
5
5
20
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
1000
NA
5
5
10
5
5
5
20
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Day 0
5/19/2009
32600
34200
768
816
100
100
1000
1000
500
29.8
50
50.2
40.6
0.01
0.05
0.2
0.2
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
1000
NA
5
3.6
10
5
5
5
20
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
Location M
McKean County, PA
Day 1
B
BJ
J
U
U
U
U
U
B
U
BJ
BJ
GU
GU
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Day 5
6/6/2009
6/10/2009
20600000
17200000
31500000
31300000
4330000
4830000
4280000 J
4920000 J
27.2 B
100 U
100 U
100 U
1000 U
1000 U
1000 U
1000 U
500 U
500 U
500 U
500 U
50 U
50 U
391 J
270 J
314 J
240 J
0.5 G U
0.5 G U
0.5 G U
0.5 G U
0.2 U
0.2 U
0.2 U
0.2 U
5
5
5
5
5
5
5
5
5
5
1.6
5
5
5
5
5
1.2
5
5
5
1000
NA
5
5
10
5
5
5
21
100
100
3.5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
5
5
5
5
5
5
5
5
5
5
4
5
5
5
5
5
3.3
5
5
5
1000
NA
5
5
10
5
5
5
18
100
100
3.2
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
0.63
0.53
5
5
5
5
5
5
5
5
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
J
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
J
U
U
U
U
U
U
U
U
Day 14
6/19/2009
23200000
30400000
5570000 E
5350000 J E
100 U
100 U
1000 U
1000 U
500 U
500 U
50 U
223 J
143 B J
1 GU
1 GU
0.2 U
0.2 U
5
5
5
5
5
5
5
5
5
5
0.98
5
5
5
5
5
5
5
5
5
1000
NA
5
5
10
5
5
5
18
100
100
6.2
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Supply Water
PARAMETER
tert-butyl acetate
tert-Butylbenzene
Tetrachloroethene
tetrahydrofuran
Toluene
Trichloroethene
Vinyl acetate
Vinyl chloride
Xylenes (total)
1,3-Dinitrobenzene
1,4-Naphthoquinone
1-Naphthylamine
2,3,7,8-TCDD
2,4-Dimethylphenol
2,4-Dinitrophenol
2,4-Dinitrotoluene
2,6-Dichlorophenol
2,6-Dinitrotoluene
2-Chloronaphthalene
2-Chlorophenol
2-Methylnaphthalene
2-Methylphenol
2-Naphthylamine
2-Nitroaniline
2-Nitrophenol
2-Picoline
3-Nitroaniline
4-Aminobiphenyl
4-Chloroaniline
4-Nitroaniline
4-Nitrophenol
5-Nitro-o-toluidine
Acenaphthene
Acenaphthylene
Acetophenone
Aniline
Aramite
Benzidine
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(ghi)perylene
Benzyl alcohol
Chlorobenzilate
Chrysene
Diallate
Dibenzofuran
Diethyl phthalate
Dimethoate
Dimethyl phthalate
UNITS
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
PQL
-5
5
-5
5
5
5
5
5
5
15
US EPA Method
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
10
2
10
10
10
10
-10
10
10
40
10
2
10
10
2
10
2
10
10
50
10
10
10
10
10
50
50
10
10
10
10
10
50
50
100
10
2
2
10
10
10
200
10
5
2
2
2
10
10
2
2
10
10
10
2
10
2
10
10
10
10
10
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
5/19/2009
NA
5U
5U
NA
5U
5U
5U
5U
5U
5U
5U
15 U
9.6
1.9
9.6
9.6
9.6
9.6
NA
9.6
9.6
9.6
48
9.6
1.9
9.6
9.6
1.9
9.6
1.9
9.6
9.6
48
9.6
9.6
9.6
9.6
9.6
48
48
9.6
9.6
9.6
9.6
9.6
48
48
96
9.6
1.9
1.9
9.6
9.6
9.6
190
1.9
1.9
1.9
1.9
1.9
9.6
9.6
1.9
1.9
6
9.6
9.6
1.9
9.6
1.9
9.6
9.6
9.6
9.6
9.6
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
Day 0
5/19/2009
NA
5
5
NA
5
5
5
5
5
5
5
15
10
2
10
10
10
10
NA
10
10
10
50
10
2
10
10
2
10
2
10
10
50
10
10
10
10
10
50
50
10
10
10
10
10
50
50
100
10
2
2
10
10
10
200
2
2
2
2
2
10
10
2
2
10
10
10
2
10
2
10
10
10
10
10
Location M
McKean County, PA
Day 1
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Day 5
Day 14
6/6/2009
NA
5U
5U
NA
3.8 J
5U
5U
5U
5U
5U
5U
3.2 J
6/10/2009
NA
5U
5U
NA
4.8 J
5U
5U
5U
5U
5U
5U
6J
6/19/2009
NA
5U
5U
NA
3.4 J
5U
5U
5U
5U
5U
5U
6.2 J
9.5
1.9
9.5
9.5
9.5
9.5
NA
9.5
9.5
9.5
48
9.5
1.9
9.5
9.5
1.9
9.5
1.9
0.28
9.5
48
9.5
9.5
9.5
9.5
9.5
48
48
9.5
9.5
9.5
9.5
9.5
48
48
95
9.5
1.9
1.9
9.5
2.2
9.5
190
1.9
1.9
1.9
1.9
1.9
9.5
9.5
1.9
1.9
2.8
9.5
9.5
1.9
9.5
1.9
9.5
2.4
9.5
9.5
1.3
9.4
1.9
9.4
9.4
9.4
9.4
NA
9.4
9.4
9.4
47
9.4
1.9
9.4
9.4
1.9
9.4
1.9
0.26
9.4
47
9.4
9.4
9.4
9.4
0.69
47
47
9.4
9.4
9.4
9.4
9.4
47
47
94
9.4
1.9
1.9
0.8
2.1
9.4
190
1.9
1.9
1.9
1.9
1.9
9.4
9.4
1.9
1.9
9.4
9.4
9.4
1.9
9.4
1.9
9.4
9.4
9.4
9.4
9.4
9.6
1.9
9.6
9.6
9.6
9.6
NA
9.6
9.6
9.6
48
9.6
1.9
9.6
9.6
1.9
9.6
1.9
9.6
9.6
48
9.6
9.6
9.6
9.6
9.6
48
48
9.6
9.6
9.6
9.6
9.6
48
48
96
9.6
1.9
1.9
9.6
2
9.6
190
1.9
1.9
1.9
1.9
1.9
9.6
9.6
1.9
1.9
2.5
9.6
9.6
1.9
9.6
1.9
9.6
9.6
9.6
9.6
9.6
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
JB
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
J
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
Supply Water
PARAMETER
Dinoseb
Diphenylamine
Disulfoton
Fluoranthene
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hexachloroethane
Hexachloropropene
Isodrin
Isophorone
Isosafrole
Nitrobenzene
N-Nitrosomorpholine
N-Nitrosopiperidine
o-Toluidine
Parathion
Pentachlorobenzene
Pentachloroethane
Pentachlorophenol
Phenanthrene
Phenol
Phorate
Pronamide
Pyrene
Pyridine
Safrole
Thionazin
UNITS
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
PQL
10
10
2
10
10
2
2
0.05
2
2
10
10
2
10
10
10
10
2
10
10
10
2
2
10
10
10
10
10
10
10
10
10
20
10
10
2
2
10
10
2
10
10
10
10
US EPA Method
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
4,4'-DDD
4,4'-DDE
4,4'-DDT
Aldrin
alpha-BHC
beta-BHC
delta-BHC
Dieldrin
Endosulfan I
Endosulfan II
Endosulfan sulfate
Endrin
Endrin aldehyde
Endrin ketone
gamma-BHC (Lindane)
Heptachlor
Heptachlor epoxide
Methoxychlor
Toxaphene
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.1
2
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
0.048
0.048
0.048
0.048
0.048
0.048
0.48
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.8
0.048
0.095
1.9
PCBs
Aroclor 1016
Aroclor 1221
Aroclor 1232
Aroclor 1242
Aroclor 1248
Aroclor 1254
Aroclor 1260
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
0.4
0.4
0.4
0.4
0.4
0.4
0.4
SW846 8082
SW846 8082
SW846 8082
SW846 8082
SW846 8082
SW846 8082
SW846 8082
0.38
0.38
0.38
0.38
0.38
0.38
0.38
5/19/2009
9.6 U
9.6 U
1.9 U
9.6 U
9.6 U
1.9 U
1.9 U
1.9 U
1.9 U
9.6 U
9.6 U
9.6 U
1.9 U
9.6 U
2.2 J
9.6 U
9.6 U
1.9 U
9.6 U
9.6 U
9.6 U
1.9 U
1.9 U
9.6 U
9.6 U
9.6 U
9.6 U
9.6 U
9.6 U
9.6 U
9.6 U
9.6 U
19 U
9.6 U
9.6 U
1.9 U
1.9 U
9.6 U
9.6 U
1.9 U
2.6 J
9.6 U
9.6 U
NA
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
PG
U
U
U
U
U
U
U
U
U
U
Day 0
5/19/2009
10
10
2
10
10
2
2
2
2
10
10
10
2
10
10
10
10
2
10
10
10
2
2
10
10
10
10
10
10
10
10
10
20
10
10
2
2
10
10
2
2
10
10
NA
0.049
0.049
0.049
0.049
0.049
0.049
0.49
0.049
0.049
0.049
0.049
0.049
0.049
0.05
0.049
0.049
0.84
0.049
0.098
2
0.39
0.39
0.39
0.39
0.39
0.39
0.39
Location M
McKean County, PA
Day 1
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
6/6/2009
9.5 U
9.5 U
1.9 U
9.5 U
9.5 U
1.9 U
1.9 U
1.9 U
1.9 U
9.5 U
9.5 U
9.5 U
1.9 U
9.5 U
9.5 U
9.5 U
9.5 U
1.9 U
9.5 U
9.5 U
9.5 U
1.9 U
1.9 U
9.5 U
9.5 U
9.5 U
9.5 U
9.5 U
9.5 U
9.5 U
9.5 U
9.5 U
19 U
9.5 U
9.5 U
1.9 U
1.9 U
9.5 U
9.5 U
1.9 U
140
9.5 U
9.5 U
NA
Day 5
Day 14
6/10/2009
9.4 U
9.4 U
1.9 U
9.4 U
9.4 U
1.9 U
1.9 U
1.9 U
1.9 U
9.4 U
9.4 U
9.4 U
1.9 U
9.4 U
9.4 U
9.4 U
9.4 U
1.9 U
9.4 U
9.4 U
9.4 U
1.9 U
1.9 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
19 U
9.4 U
9.4 U
1.9 U
1.9 U
9.4 U
9.4 U
1.9 U
100
9.4 U
9.4 U
NA
6/19/2009
9.6 U
9.6 U
1.9 U
9.6 U
9.6 U
1.9 U
1.9 U
1.9 U
1.9 U
9.6 U
9.6 U
9.6 U
1.9 U
9.6 U
9.6 U
9.6 U
9.6 U
1.9 U
9.6 U
9.6 U
9.6 U
1.9 U
1.9 U
9.6 U
9.6 U
9.6 U
9.6 U
9.6 U
9.6 U
9.6 U
9.6 U
9.6 U
19 U
9.6 U
9.6 U
1.9 U
1.9 U
9.6 U
9.6 U
1.9 U
94
9.6 U
9.6 U
NA
U
U
PG
U
U
U
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.048
0.048
0.048
0.048
0.048
0.048
0.48
0.026
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.096
1.9
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.38
0.38
0.38
0.38
0.38
0.38
0.38
U
U
U
U
U
U
U
PARAMETER
Supply Water
Day 0
5/19/2009
5/19/2009
Location M
McKean County, PA
Day 1
Day 5
Day 14
6/10/2009
6/19/2009
UNITS
PQL
US EPA Method
Ethyl parathion
ug/L
0.4
SW846 8141A
0.95 U
0.97 U
NA
Alcohols
2-Propanol
Butyl alcohol
Ethanol
Methanol
n-Propanol
mg/L
mg/L
mg/L
mg/L
mg/L
10
10
10
10
10
SW846 8015
SW846 8015
SW846 8015
SW846 8015
SW846 8015
10
10
10
10
10
20
20
20
20
20
10
10
10
23
10
Glycols
Ethylene Glycol
Propylene glycol
mg/L
mg/L
50
50
SW846 8015
SW846 8015
100 UJ
100 UJ
200 UJ
200 UJ
100 UJ
100 UJ
100 UJ
100 UJ
Acids
Acetic Acid
Butyric Acid
Propionic Acid
Volatile Acids
mg/L
mg/L
mg/L
mg/L
10
10
10
10
SW846 8015
SW846 8015
SW846 8015
1U
1U
1U
57
100 UJ
100 UJ
100 UJ
2300
10 UJ
10 UJ
10 UJ
1100
500 UJ
500 UJ
500 UJ
1200
UJ
UJ
UJ
UJ
UJ
6/6/2009
UJ
UJ
UJ
UJ
UJ
NA
UJ
UJ
UJ
J
UJ
10
10
10
21
10
1U
UJ
UJ
UJ
J
UJ
10
10
10
16
10
UJ
UJ
UJ
J
UJ
100 U
100 U
10 UJ
10 UJ
10 UJ
52000
Supply Water
PARAMETER
Acidity
Amenable cyanide
Ammonia Nitrogen
Bromide
Chloride
Fluoride
Hardness, as CaCO3
Nitrate as N
Nitrate-Nitrite
Nitrite as N
Oil & Grease (HEM)
Sulfate
TOC
Total Alkalinity
Total phosphorus
Turbidity
Cyanide, Total
Total Sulfide
pH
Sulfite
MBAS (mol.wt 320)
Aluminum
Aluminum-DISS
Antimony
Antimony-DISS
Arsenic
Arsenic-DISS
Barium
Barium-DISS
Beryllium
Beryllium-DISS
Boron
Boron-DISS
Cadmium
Cadmium-DISS
Calcium
Calcium-DISS
Chromium
Chromium-DISS
Cobalt
Cobalt-DISS
Copper
Copper-DISS
Iron
Iron-DISS
Lead
Lead-DISS
Lithium
Lithium-DISS
Magnesium
Magnesium-DISS
Manganese
Manganese-DISS
Molybdenum
Molybdenum-DISS
Nickel
Nickel-DISS
Potassium
Potassium-DISS
Selenium
Selenium-DISS
Silver
Silver-DISS
UNITS
PQL
US EPA Method
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
umhos/cm
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
NTU
ug/L
mg/L
No Units
mg/L
mg/L
mg/L
5
0.01
0.1
2
1
10
1
-1
5
0.05
0.1
0.05
5
-1
1
5
10
3
0.1
4
-10
3
-0.01
1
0.05
SM20 2310B (4a)

SM18 4500-CN E
MCAWW 350.1
SM18 5210 B
MCAWW 300.0A
MCAWW 410.4
MCAWW 300.0A
SM20 5310B
MCAWW 300.0A
SM20 2340C
MCAWW 300.0A
MCAWW 353.2
MCAWW 300.0A
CFR136A 1664A HEM
MCAWW 120.1
MCAWW 300.0A
SM20 5310B
SM18 2320 B
SM18 2540 C
MCAWW 351.3
MCAWW 365.2
SM20 2540D
MCAWW 180.1
SW846 9012A
SW846 9030B/9034
SW846 9040
SW846 9066
SM4500-SO3 B
SM5540 C
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
200
200
10
10
10
10
200
200
4
4
2000
2000
5
5
5000
5000
5
5
500
500
25
25
100
100
3
3
500
500
5000
5000
150
150
400
400
40
40
5000
5000
5
5
5
5
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
07/14/09
5
0.08
0.3
2
0.2
11.6
8.3
2.5
0.05
26
0.17
0.14
0.05
4.6
91.6
6.9
3
16.2
35
3
0.1
2
2.9
85.9
3
7.4
0.01
07/14/09
U
J
U
U
J
U
U
J
J
J
J
U
U
B
U
U
NA
NA
2000
2000
14.2
17.2
100
100
309
290
40
40
36.4
28.2
50
50
7450
6730
50
50
500
500
250
250
1000
1000
30
30
500
500
1100
1070
26.9
150
400
400
400
400
2660
50000
50
50
50
50
Location N
Potter County, PA
Day 1
Day 0
U
U
BJ
BJ
U
U
BJ
B
U
U
BJ
BJ
U
U
B
B
U
U
U
U
U
U
U
U
U
U
U
U
B
B
B
U
U
U
U
U
B
U
U
U
U
U
5
0.01
83.3
166
0.9
734
132
218
0.05
50
0.12
0.23
0.22
4.6
1350
165
208
154
735
142
15.4
14.4
8.8
5.4
3
8.2
0.01
6.80
0.0809
2000
2000
21.6
100
100
100
1420
3400
40
40
40700
44700
50
50
15600
16100
50
50
500
500
71.3
87.2
834
688
30
30
180
196
1740
1790
18.3
17
400
400
400
400
48300
50700
50
50
50
50
Day 5
7/15/2009
U
U
J
U
J
J
J
J
B
U
U
U
U
BJ
U
U
U
BJ
U
U
J
J
U
U
B
B
U
U
U
U
B
B
B
B
U
U
BJ
B
B
B
B
B
U
U
U
U
B
U
U
U
U
5
0.01
83.6
73.2
165
1760
17500
20.2
0.5
5100
0.5
0.45
4.7
4.8
73600
110
28.1
254
31800
101
4.1
112
50.4
10
3
7.4
0.014
6.80
0.0969
2000
2000
34.9
41.5
46
48.8
271000
272000
40
40
6680
6540
50
50
1400000
1340000
36.8
29.4
500
500
57.1
36.6
13900
10900
55.2
48.8
26000
24600
112000
108000
725
683
36.6
34.3
42.9
35
115000
110000
50
50
50
50
7/19/2009
U
U
J
GU
GU
U
J
J
J
J
U
U
U
U
BJ
BJ
B
B
J
U
U
J
J
U
U
B
B
U
U
B
B
B
B
B
B
U
U
U
U
5
0.01
182
70.9
608
3200
67200
32
1.2
30000
1.2
0.14
13.2
5.1
273000
7.3
37.8
145
116000
137
0.71
171
328
10
3
6.6
0.017
12.8
0.0657
360
208
19.4
18.5
100
100
3530000
3170000
40
40
8360
7710
50
50
8520000
7930000
44.7
27.2
5000
5000
64.8
250
46900
6490
20.6
30
106000
97200
678000
629000
2590
2360
16.6
400
19.1
400
339000
304000
50
50
50
50
U
U
GU
GU
J
BJ
J
U
U
BJ
BJ
B
B
U
U
U
U
U
U
J
J
B
B
U
U
B
U
B
U
J
BJ
U
B
U
U
U
U
U
Supply Water
PARAMETER
Sodium
Sodium-DISS
Strontium
Strontium-DISS
Thallium
Thallium-DISS
Tin
Tin-DISS
Titanium
Titanium-DISS
Trivalent Chrom
Zinc
Zinc-DISS
Hexavalent Chromium
Mercury
Mercury-DISS
1,1-Dichloroethane
1,1-Dichloroethene
1,1-Dichloropropene
1,2-Dichlorobenzene
1,2-Dichloroethane
1,2-Dichloropropane
1,3-Dichlorobenzene
1,3-Dichloropropane
1,4-Dichlorobenzene
1,4-Dioxane
2,2-Dichloropropane
2-Butanone
2-Hexanone
4-Chlorotoluene
Acetone
Acrolein
Acrylonitrile
Benzene
Benzyl chloride
Bromobenzene
Bromoform
Bromomethane
Carbon disulfide
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
Dibromomethane
Ethylbenzene
Isopropylbenzene
Methylene chloride
Naphthalene
n-Butylbenzene
n-Propylbenzene
p-Isopropyltoluene
sec-Butylbenzene
Styrene
UNITS
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
mg/L
mg/L
ug/L
ug/L
PQL
5000
5000
50
50
10
10
1000
1000
500
500
50
20
20
0.01
0.01
0.2
0.2
US EPA Method
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 7196A
SW846 7196A
SW846 7470A
SW846 7470A
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
1000
-5
5
10
5
5
5
20
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
07/14/09
8930
8100
204
187
100
100
1000
1000
500
500
50
54.6
27.2
0.01
0.01
0.2
0.2
BJ
B
BJ
BJ
U
U
U
U
U
U
U
BJ
BJ
U
U
U
U
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
1000
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
5
5
10
5
5
5
20
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
NA
Day 0
Location N
Potter County, PA
Day 1
07/14/09
74400
80000
3020
3150
100
100
1000
1000
500
500
50
75.5
80.7
0.01
0.0062
0.2
0.2
25
25
25
25
25
25
25
25
25
25
4.2
25
25
25
25
25
3.4
25
25
25
5000
NA
25
25
50
25
25
25
170
500
500
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
J
J
J
U
U
U
U
U
U
U
BJ
BJ
U
B
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
7/15/2009
8210000
7800000
388000
368000
100
28.3
1000
1000
37.8
23.4
29.3
617
538
0.5
0.37
0.2
0.2
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
5000
NA
25
25
50
25
25
25
90
500
500
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
5.5
25
25
25
25
25
25
Day 5
J
J
J
U
B
U
U
B
B
B
J
J
U
B
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
7/19/2009
31100000
29000000
2980000
2690000
100
100
1000
1000
500
500
44.7
241
262
0.5
0.5
0.2
0.2
5
5
5
5
5
5
5
5
5
5
0.54
5
5
5
5
5
5
5
5
5
1000
NA
5
3.4
10
5
5
0.65
210
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
J
J
U
U
U
U
U
U
B
J
J
GU
GU
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Supply Water
PARAMETER
tert-butyl acetate
tert-Butylbenzene
Tetrachloroethene
tetrahydrofuran
Toluene
Trichloroethene
Vinyl acetate
Vinyl chloride
Xylenes (total)
1,3-Dinitrobenzene
1,4-Naphthoquinone
1-Naphthylamine
2,3,7,8-TCDD
2,4-Dimethylphenol
2,4-Dinitrophenol
2,4-Dinitrotoluene
2,6-Dichlorophenol
2,6-Dinitrotoluene
2-Chloronaphthalene
2-Chlorophenol
2-Methylnaphthalene
2-Methylphenol
2-Naphthylamine
2-Nitroaniline
2-Nitrophenol
2-Picoline
3-Nitroaniline
4-Aminobiphenyl
4-Chloroaniline
4-Nitroaniline
4-Nitrophenol
5-Nitro-o-toluidine
Acenaphthene
Acenaphthylene
Acetophenone
Aniline
Aramite
Benzidine
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(ghi)perylene
Benzyl alcohol
Chlorobenzilate
Chrysene
Diallate
Dibenzofuran
Diethyl phthalate
Dimethoate
Dimethyl phthalate
UNITS
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
PQL
-5
5
-5
5
5
5
5
5
5
15
US EPA Method
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
10
2
10
10
10
10
-10
10
10
40
10
2
10
10
2
10
2
10
10
50
10
10
10
10
10
50
50
10
10
10
10
10
50
50
100
10
2
2
10
10
10
200
10
5
2
2
2
10
10
2
2
10
10
10
2
10
2
10
10
10
10
10
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
07/14/09
NA
5U
5U
NA
5
5
5
5
5
5
5
15
U
U
U
U
U
U
U
U
9.5
1.9
9.5
9.5
9.5
9.5
U
U
U
U
U
U
9.5
9.5
9.5
48
9.5
1.9
9.5
9.5
1.9
9.5
1.9
9.5
9.5
48
9.5
9.5
9.5
9.5
9.5
48
48
9.5
9.5
9.5
9.5
9.5
48
48
95
9.5
1.9
1.9
9.5
9.5
9.5
190
1.9
1.9
1.9
1.9
1.9
9.5
9.5
1.9
1.9
9.7
9.5
9.5
1.9
9.5
1.9
9.5
9.5
9.5
9.5
9.5
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
NA
U
U
U
U
U
U
U
U
U
U
Day 0
Location N
Potter County, PA
Day 1
07/14/09
NA
25
25
NA
25
25
25
25
25
25
25
25
9.5
1.9
9.5
9.5
9.5
9.5
NA
9.5
9.5
0.39
48
9.5
1.9
9.5
9.5
1.9
9.5
1.9
9.5
9.5
48
9.5
9.5
9.5
9.5
9.5
48
48
9.5
9.5
9.5
9.5
9.5
48
48
95
9.5
1.9
1.9
9.5
9.5
9.5
190
1.9
1.9
1.9
1.9
1.9
9.5
9.5
1.9
1.9
9.1
9.5
9.5
1.9
9.5
1.9
9.5
9.5
9.5
9.5
0.29
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
J
7/15/2009
NA
25
25
NA
25
25
25
25
25
25
25
75
9.4
1.9
9.4
9.4
9.4
9.4
NA
9.4
9.4
9.4
47
9.4
1.9
9.4
9.4
1.9
9.4
2.5
0.2
9.4
47
9.4
9.4
9.4
9.4
0.33
47
47
9.4
9.4
9.4
9.4
9.4
47
47
94
9.4
0.29
1.9
0.82
9.4
9.4
190
1.9
1.9
1.9
1.9
1.9
9.4
9.4
1.9
1.9
6.5
9.4
9.4
1.9
9.4
1.9
9.4
1.2
9.4
9.4
0.54
Day 5
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
J
U
J
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
J
U
U
J
7/19/2009
NA
5
5
NA
0.91
5
5
5
5
5
5
4.7
9.4
1.9
9.4
9.4
9.4
9.4
NA
9.4
9.4
9.4
47
9.4
1.9
9.4
9.4
1.9
9.4
0.41
9.4
9.4
47
9.4
9.4
9.4
9.4
9.4
47
47
9.4
9.4
9.4
9.4
9.4
47
47
94
9.4
1.9
1.9
9.4
9.4
9.4
190
1.9
1.9
1.9
1.9
1.9
9.4
9.4
1.9
1.9
5.8
9.4
9.4
1.9
9.4
1.9
9.4
9.4
9.4
9.4
0.61
U
U
J
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
J
Supply Water
PARAMETER
Dinoseb
Diphenylamine
Disulfoton
Fluoranthene
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hexachloroethane
Hexachloropropene
Isodrin
Isophorone
Isosafrole
Nitrobenzene
N-Nitrosomorpholine
N-Nitrosopiperidine
o-Toluidine
Parathion
Pentachlorobenzene
Pentachloroethane
Pentachlorophenol
Phenanthrene
Phenol
Phorate
Pronamide
Pyrene
Pyridine
Safrole
Thionazin
UNITS
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
PQL
10
10
2
10
10
2
2
0.05
2
2
10
10
2
10
10
10
10
2
10
10
10
2
2
10
10
10
10
10
10
10
10
10
20
10
10
2
2
10
10
2
10
10
10
10
US EPA Method
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
4,4'-DDD
4,4'-DDE
4,4'-DDT
Aldrin
alpha-BHC
beta-BHC
delta-BHC
Dieldrin
Endosulfan I
Endosulfan II
Endosulfan sulfate
Endrin
Endrin aldehyde
Endrin ketone
gamma-BHC (Lindane)
Heptachlor
Heptachlor epoxide
Methoxychlor
Toxaphene
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.1
2
PCBs
Aroclor 1016
Aroclor 1221
Aroclor 1232
Aroclor 1242
Aroclor 1248
Aroclor 1254
Aroclor 1260
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
0.4
0.4
0.4
0.4
0.4
0.4
0.4
07/14/09
9.5
9.5
1.9
9.5
9.5
1.9
1.9
1.9
1.9
9.5
9.5
9.5
1.9
9.5
9.5
9.5
9.5
1.9
9.5
9.5
9.5
1.9
1.9
9.5
9.5
9.5
9.5
9.5
9.5
9.5
9.5
9.5
19
9.5
9.5
1.9
1.9
9.5
9.5
1.9
9.5
9.5
9.5
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8082
SW846 8082
SW846 8082
SW846 8082
SW846 8082
SW846 8082
SW846 8082
Day 0
Location N
Potter County, PA
Day 1
Day 5
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
07/14/09
9.5
9.5
1.9
9.5
9.5
1.9
1.9
1.9
1.9
9.5
9.5
9.5
1.9
9.5
9.5
9.5
9.5
1.9
9.5
9.5
9.5
1.9
1.9
9.5
9.5
9.5
9.5
9.5
9.5
9.5
9.5
9.5
19
9.5
9.5
1.9
1.9
9.5
9.5
1.9
9.5
9.5
9.5
NA
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
7/15/2009
9.4
9.4
1.9
9.4
9.4
1.9
0.45
1.9
1.9
9.4
9.4
9.4
1.9
9.4
9.4
9.4
9.4
1.9
9.4
9.4
9.4
1.9
1.9
9.4
9.4
9.4
9.4
9.4
9.4
9.4
9.4
9.4
19
9.4
9.4
0.89
1.9
9.4
9.4
0.18
9.4
9.4
9.4
NA
0.048
0.048
0.048
0.048
0.048
0.048
0.48
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.095
1.9
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
0.048
0.048
0.048
0.048
0.048
0.048
0.48
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.095
1.9
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.38
0.38
0.38
0.38
0.38
0.38
0.38
U
U
U
U
U
U
U
0.38
0.38
0.38
0.38
0.38
0.38
0.38
U
U
U
U
U
U
U
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
J
U
U
U
7/19/2009
9.4
9.4
1.9
9.4
9.4
1.9
0.097
1.9
1.9
9.4
9.4
9.4
1.9
9.4
9.4
9.4
9.4
1.9
9.4
9.4
9.4
1.9
1.9
9.4
9.4
9.4
9.4
9.4
9.4
9.4
9.4
9.4
19
9.4
9.4
1.9
1.9
9.4
9.4
1.9
9.4
9.4
9.4
NA
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
PARAMETER
Location N
Potter County, PA
Day 1
Supply Water
Day 0
07/14/09
07/14/09
Day 5
UNITS
PQL
US EPA Method
Ethyl parathion
ug/L
0.4
SW846 8141A
0.95 U
0.95 U
NA
Alcohols
2-Propanol
Butyl alcohol
Ethanol
Methanol
n-Propanol
mg/L
mg/L
mg/L
mg/L
mg/L
10
10
10
10
10
SW846 8015
SW846 8015
SW846 8015
SW846 8015
SW846 8015
NA
NA
NA
NA
NA
10
10
10
10
10
10
10
10
10
10
Glycols
Ethylene Glycol
Propylene glycol
mg/L
mg/L
50
50
SW846 8015
SW846 8015
NA
NA
500 UJ
500 UJ
100 UJ
100 UJ
100 UJ
100 UJ
Acids
Acetic Acid
Butyric Acid
Propionic Acid
Volatile Acids
mg/L
mg/L
mg/L
mg/L
10
10
10
10
SW846 8015
SW846 8015
SW846 8015
NA
NA
NA
NA
15
1U
1U
20
22 J
2 UJ
2 UJ
200
23
1U
1U
350
7/15/2009
UJ
UJ
UJ
UJ
UJ
7/19/2009
NA
UJ
UJ
UJ
UJ
UJ
10
10
10
10
10
UJ
UJ
UJ
UJ
UJ
Location O
Susquehanna County
Day 1
Day 5
Day 0
PARAMETER
Acidity
Amenable cyanide
Ammonia Nitrogen
Bromide
Chloride
Fluoride
Hardness, as CaCO3
Nitrate as N
Nitrate-Nitrite
Nitrite as N
Oil & Grease (HEM)
Sulfate
TOC
Total Alkalinity
Total phosphorus
Turbidity
Cyanide, Total
Total Sulfide
pH
Sulfite
MBAS (mol.wt 320)
Aluminum
Aluminum-DISS
Antimony
Antimony-DISS
Arsenic
Arsenic-DISS
Barium
Barium-DISS
Beryllium
Beryllium-DISS
Boron
Boron-DISS
Cadmium
Cadmium-DISS
Calcium
Calcium-DISS
Chromium
Chromium-DISS
Cobalt
Cobalt-DISS
Copper
Copper-DISS
Iron
Iron-DISS
Lead
Lead-DISS
Lithium
Lithium-DISS
Magnesium
Magnesium-DISS
Manganese
Manganese-DISS
Molybdenum
Molybdenum-DISS
Nickel
Nickel-DISS
Potassium
Potassium-DISS
Selenium
Selenium-DISS
Silver
Silver-DISS
UNITS
PQL
US EPA Method
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
umhos/cm
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
NTU
ug/L
mg/L
No Units
mg/L
mg/L
mg/L
5
0.01
0.1
2
1
10
1
-1
5
0.05
0.1
0.05
5
-1
1
5
10
3
0.1
4
-10
3
-0.01
1
0.05
SM20 2310B (4a)

SM18 4500-CN E
MCAWW 350.1
SM18 5210 B
MCAWW 300.0A
MCAWW 410.4
MCAWW 300.0A
SM20 5310B
MCAWW 300.0A
SM20 2340C
MCAWW 300.0A
MCAWW 353.2
MCAWW 300.0A
CFR136A 1664A HEM
MCAWW 120.1
MCAWW 300.0A
SM20 5310B
SM18 2320 B
SM18 2540 C
MCAWW 351.3
MCAWW 365.2
SM20 2540D
MCAWW 180.1
SW846 9012A
SW846 9030B/9034
SW846 9040
SW846 9066
SM4500-SO3 B
SM5540 C
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
200
200
10
10
10
10
200
200
4
4
2000
2000
5
5
5000
5000
5
5
500
500
25
25
100
100
3
3
500
500
5000
5000
150
150
400
400
40
40
5000
5000
5
5
5
5
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
7/1/2009
7/1/2009
5
0.01
10
924
20
2420
1060
558
5
570
5
0.1
5
255
4000
100
575
66.1
2670
89.9
0.5
5290
505
10
3
7.2
0.77
47.2
0.05
1030
162
100
100
100
100
72200
62300
40
40
1190
1310
50
50
123000
120000
17.3
50
500
500
79.4
34.1
7400
954
19.4
30
1800
1930
14700
14800
288
196
50.6
58.4
400
400
7840
6850
50
50
50
50
U
U
GU
J
GU
GU
GU
J
GU
J
J
U
U
J
U
B
BJ
U
U
U
U
U
U
B
B
U
U
J
J
B
U
U
U
B
B
B
B
U
B
B
BJ
B
U
U
B
B
U
U
U
U
5
0.01
52
606
69.8
1480
7860
271
2.5
25000
2.5
0.18
6.7
4.6
30700
50
308
114
17400
88.8
21.8
4
152
21.5
3
6.5
0.036
26.8
0.198
1120
274
15.8
15
48
28
387000
447000
40
40
808
944
50
50
676000
800000
37.5
12.9
500
500
250
250
20900
18000
30
30
14200
17300
65700
76400
760
823
25.9
24.1
48.3
39.5
33500
39900
50
50
50
50
Day 14
7/6/2009
U
NR U
GU
GU
U
J
GU
J
U
J
B
B
B
B
B
B
U
U
B
B
U
U
J
J
B
B
U
U
U
U
J
U
U
J
B
B
B
B
B
B
U
U
U
U
48.7
0.01
135
1520
885
7390
86800
240
2.5
36000
2.5
0.1
19.9
40.7
261000
50
237
94.2
125000
147
2.3
302
54.6
5.2
3.2
6.5
0.15
16.8
0.0897
536
172
100
100
100
100
13900000
12700000
40
40
3570
3200
50
50
9250000
8200000
33.4
27.7
25000
25000
250
250
43500
38400
30
30
132000
125000
691000
610000
5550
4960
400
400
400
400
353000
284000
50
50
50
50
07/15/2009
GU
GU
U
J
J
GU
J
B
BJ
U
U
U
U
U
U
U
U
J
J
B
B
U
U
U
U
U
U
U
U
U
U
U
U
U
U
473
0.01
237
725
872
10000
98300
695
2.5
54000
2.5
0.1
25.9
17.5
428000
50
509
95.1
186000
180
0.038
324
244
1.9
3
6.6
0.13
73.6
4.60
845
912
48.8
45
76.6
86.5
12500000
13600000
40
40
2520
2760
3.1
3.3
10300000
11200000
31.2
19.4
5000
5000
54.8
250
77500
58700
60
60
147000
162000
794000
858000
7100
7630
400
400
800
800
233000
253000
34
50
50
50
U
J
J
J
GU
GU
U
J
GU
J
J
B
U
B
B
BJ
BJ
B
B
J
U
U
J
J
B
B
B
B
U
U
B
U
U
U
J
U
U
U
U
B
U
U
U
Location O
Susquehanna County
Day 1
Day 5
Day 0
PARAMETER
Sodium
Sodium-DISS
Strontium
Strontium-DISS
Thallium
Thallium-DISS
Tin
Tin-DISS
Titanium
Titanium-DISS
Trivalent Chrom
Zinc
Zinc-DISS
Hexavalent Chromium
Mercury
Mercury-DISS
1,1-Dichloroethane
1,1-Dichloroethene
1,1-Dichloropropene
1,2-Dichlorobenzene
1,2-Dichloroethane
1,2-Dichloropropane
1,3-Dichlorobenzene
1,3-Dichloropropane
1,4-Dichlorobenzene
1,4-Dioxane
2,2-Dichloropropane
2-Butanone
2-Hexanone
4-Chlorotoluene
Acetone
Acrolein
Acrylonitrile
Benzene
Benzyl chloride
Bromobenzene
Bromoform
Bromomethane
Carbon disulfide
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
Dibromomethane
Ethylbenzene
Isopropylbenzene
Methylene chloride
Naphthalene
n-Butylbenzene
n-Propylbenzene
p-Isopropyltoluene
sec-Butylbenzene
Styrene
UNITS
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
mg/L
mg/L
ug/L
ug/L
PQL
5000
5000
50
50
10
10
1000
1000
500
500
50
20
20
0.01
0.01
0.2
0.2
US EPA Method
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 7196A
SW846 7196A
SW846 7470A
SW846 7470A
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
1000
-5
5
10
5
5
5
20
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
7/1/2009
589000
658000
27000
28200
100
29.5
1000
1000
500
500
50
1610
924
0.1
0.05
0.2
0.17
50
50
50
50
50
50
50
50
50
50
67
50
50
50
50
50
7.7
50
50
50
10000
NA
50
50
100
50
50
50
130
1000
1000
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
820
50
50
50
50
50
JE
JE
U
B
U
U
U
U
U
E
U
U
U
B
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
7/1/2009
3920000
4670000
196000
233000
100
100
1000
1000
33.8
48.6
50
244
287
0.1
0.1
0.2
0.2
25
25
25
25
25
25
25
25
25
25
59
25
25
25
25
25
6.7
25
25
25
5000
NA
25
17
50
25
25
25
69
500
500
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
720
25
25
25
25
25
J
J
U
U
U
U
B
B
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
J
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Day 14
7/6/2009
34100000
30900000
2960000
2660000
100
38
1000
1000
500
500
33.4
211
183
2
2
0.2
0.2
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
1000
NA
5
5
10
5
5
5
20
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
0.5
5
5
5
5
5
J
J
U
B
U
U
U
U
B
B
GU
GU
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
07/15/2009
36800000
39100000
3520000
3580000
200
200
1000
1000
126
152
50
229
127
13.2
2
0.2
0.2
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
1000
NA
5
5
10
5
5
5
20
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
J
J
J
U
U
U
U
B
B
U
J
BJ
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Location O
Susquehanna County
Day 1
Day 5
Day 0
PARAMETER
tert-butyl acetate
tert-Butylbenzene
Tetrachloroethene
tetrahydrofuran
Toluene
Trichloroethene
Vinyl acetate
Vinyl chloride
Xylenes (total)
1,3-Dinitrobenzene
1,4-Naphthoquinone
1-Naphthylamine
2,3,7,8-TCDD
2,4-Dimethylphenol
2,4-Dinitrophenol
2,4-Dinitrotoluene
2,6-Dichlorophenol
2,6-Dinitrotoluene
2-Chloronaphthalene
2-Chlorophenol
2-Methylnaphthalene
2-Methylphenol
2-Naphthylamine
2-Nitroaniline
2-Nitrophenol
2-Picoline
3-Nitroaniline
4-Aminobiphenyl
4-Chloroaniline
4-Nitroaniline
4-Nitrophenol
5-Nitro-o-toluidine
Acenaphthene
Acenaphthylene
Acetophenone
Aniline
Aramite
Benzidine
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(ghi)perylene
Benzyl alcohol
Chlorobenzilate
Chrysene
Diallate
Dibenzofuran
Diethyl phthalate
Dimethoate
Dimethyl phthalate
UNITS
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
PQL
-5
5
-5
5
5
5
5
5
5
15
US EPA Method
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
10
2
10
10
10
10
-10
10
10
40
10
2
10
10
2
10
2
10
10
50
10
10
10
10
10
50
50
10
10
10
10
10
50
50
100
10
2
2
10
10
10
200
10
5
2
2
2
10
10
2
2
10
10
10
2
10
2
10
10
10
10
10
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
7/1/2009
NA
50
50
NA
19
50
50
50
50
50
50
46
190
38
190
190
190
190
NA
190
190
190
940
190
38
190
190
38
190
260
190
190
940
190
190
190
190
190
940
940
190
190
190
190
190
940
940
1900
190
38
38
190
190
190
3800
38
38
38
38
38
190
190
38
38
190
190
190
38
190
38
190
190
190
190
190
U
U
J
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
7/1/2009
NA
25
25
NA
25
25
25
25
25
25
25
26
94
19
94
94
94
94
NA
94
94
94
470
94
19
94
94
19
94
52
94
94
470
94
94
94
94
94
470
470
94
94
94
94
94
470
470
940
94
19
19
94
94
94
1900
19
19
19
19
19
94
94
19
19
94
94
94
19
94
19
94
94
94
94
94
Day 14
7/6/2009
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
07/15/2009
NA
5
5
NA
0.94
5
5
5
5
5
5
15
9.8
2
9.8
9.8
9.8
9.8
NA
9.8
9.8
9.8
49
9.8
2
9.8
9.8
2
9.8
2
9.8
9.8
49
9.8
9.8
9.8
9.8
9.8
49
49
9.8
9.8
9.8
9.8
9.8
49
49
98
9.8
2
2
9.8
9.8
9.8
200
2
2
2
2
2
9.8
9.8
2
2
2.5
9.8
9.8
2
9.8
2
9.8
9.8
9.8
9.8
9.8
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
NA
5
5
NA
5
5
5
5
5
5
5
15
940
190
940
940
940
940
NA
940
940
940
4700
940
190
940
940
190
940
190
940
940
4700
940
940
940
940
940
4700
4700
940
940
940
940
940
4700
4700
9400
940
190
190
940
940
940
19000
190
190
190
190
190
940
940
190
190
940
940
940
190
940
190
940
940
940
940
940
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Location O
Susquehanna County
Day 1
Day 5
Day 0
PARAMETER
Dinoseb
Diphenylamine
Disulfoton
Fluoranthene
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hexachloroethane
Hexachloropropene
Isodrin
Isophorone
Isosafrole
Nitrobenzene
N-Nitrosomorpholine
N-Nitrosopiperidine
o-Toluidine
Parathion
Pentachlorobenzene
Pentachloroethane
Pentachlorophenol
Phenanthrene
Phenol
Phorate
Pronamide
Pyrene
Pyridine
Safrole
Thionazin
UNITS
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
PQL
10
10
2
10
10
2
2
0.05
2
2
10
10
2
10
10
10
10
2
10
10
10
2
2
10
10
10
10
10
10
10
10
10
20
10
10
2
2
10
10
2
10
10
10
10
US EPA Method
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
4,4'-DDD
4,4'-DDE
4,4'-DDT
Aldrin
alpha-BHC
beta-BHC
delta-BHC
Dieldrin
Endosulfan I
Endosulfan II
Endosulfan sulfate
Endrin
Endrin aldehyde
Endrin ketone
gamma-BHC (Lindane)
Heptachlor
Heptachlor epoxide
Methoxychlor
Toxaphene
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.1
2
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
0.051
0.051
0.051
0.11
0.051
0.051
0.51
0.051
0.051
0.051
0.051
0.051
0.051
0.051
0.051
0.051
0.065
0.051
0.1
2
PCBs
Aroclor 1016
Aroclor 1221
Aroclor 1232
Aroclor 1242
Aroclor 1248
Aroclor 1254
Aroclor 1260
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
0.4
0.4
0.4
0.4
0.4
0.4
0.4
SW846 8082
SW846 8082
SW846 8082
SW846 8082
SW846 8082
SW846 8082
SW846 8082
0.41
0.41
0.41
0.41
0.41
0.41
0.41
7/1/2009
190
190
38
190
190
38
38
38
38
190
190
190
38
190
190
190
190
38
190
190
190
38
38
190
190
190
190
190
190
190
190
190
380
190
190
38
38
190
190
38
190
190
190
NA
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
7/1/2009
94
94
19
94
94
19
19
19
19
94
94
94
19
94
94
94
94
19
94
94
94
19
19
94
94
94
94
94
94
94
94
94
190
94
94
19
3.5
94
94
19
94
94
94
NA
Day 14
7/6/2009
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
9.8
9.8
2
9.8
9.8
2
2
2
2
9.8
9.8
9.8
2
9.8
9.8
9.8
9.8
2
9.8
9.8
9.8
2
2
9.8
9.8
9.8
9.8
9.8
9.8
9.8
9.8
9.8
20
9.8
9.8
2
2
9.8
9.8
2
1.1
9.8
9.8
NA
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
07/15/2009
940
940
190
940
940
190
190
190
190
940
940
940
190
940
940
940
940
190
940
940
940
190
190
940
940
940
940
940
940
940
940
940
1900
940
940
190
190
940
940
190
940
940
940
NA
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
PG
U
U
U
U
U
U
U
U
U
U
U
U
PG
U
U
U
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.048
0.048
0.048
0.048
0.048
0.048
0.48
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.095
1.9
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.38
0.38
0.38
0.38
0.38
0.38
0.38
U
U
U
U
U
U
U
Location O
Susquehanna County
Day 1
Day 5
Day 0
PARAMETER
Day 14
UNITS
PQL
US EPA Method
Ethyl parathion
ug/L
0.4
SW846 8141A
Alcohols
2-Propanol
Butyl alcohol
Ethanol
Methanol
n-Propanol
mg/L
mg/L
mg/L
mg/L
mg/L
10
10
10
10
10
SW846 8015
SW846 8015
SW846 8015
SW846 8015
SW846 8015
20
20
120
20
20
Glycols
Ethylene Glycol
Propylene glycol
mg/L
mg/L
50
50
SW846 8015
SW846 8015
200 UJ
200 UJ
200 UJ
200 UJ
100 UJ
100 UJ
100 UJ
100 UJ
Acids
Acetic Acid
Butyric Acid
Propionic Acid
Volatile Acids
mg/L
mg/L
mg/L
mg/L
10
10
10
10
SW846 8015
SW846 8015
SW846 8015
50 UJ
50 UJ
50 UJ
200
1U
1U
1U
200
1U
1U
1U
300
20 UJ
20 UJ
20 UJ
800
7/1/2009
7/1/2009
1U
UJ
UJ
J
UJ
UJ
7/6/2009
NA
10
10
230
10
10
07/15/2009
NA
UJ
UJ
J
UJ
UJ
10
10
110
10
10
4.8 U
UJ
UJ
J
UJ
UJ
10
10
39
10
10
UJ
UJ
J
UJ
UJ
PARAMETER
Acidity
Amenable cyanide
Ammonia Nitrogen
Bromide
Chloride
Fluoride
Hardness, as CaCO3
Nitrate as N
Nitrate-Nitrite
Nitrite as N
Oil & Grease (HEM)
Sulfate
TOC
Total Alkalinity
Total phosphorus
Turbidity
Cyanide, Total
Total Sulfide
pH
Sulfite
MBAS (mol.wt 320)
Aluminum
Aluminum-DISS
Antimony
Antimony-DISS
Arsenic
Arsenic-DISS
Barium
Barium-DISS
Beryllium
Beryllium-DISS
Boron
Boron-DISS
Cadmium
Cadmium-DISS
Calcium
Calcium-DISS
Chromium
Chromium-DISS
Cobalt
Cobalt-DISS
Copper
Copper-DISS
Iron
Iron-DISS
Lead
Lead-DISS
Lithium
Lithium-DISS
Magnesium
Magnesium-DISS
Manganese
Manganese-DISS
Molybdenum
Molybdenum-DISS
Nickel
Nickel-DISS
Potassium
Potassium-DISS
Selenium
Selenium-DISS
Silver
Silver-DISS
UNITS
PQL
US EPA Method
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
umhos/cm
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
NTU
ug/L
mg/L
No Units
mg/L
mg/L
mg/L
5
0.01
0.1
2
1
10
1
-1
5
0.05
0.1
0.05
5
-1
1
5
10
3
0.1
4
-10
3
-0.01
1
0.05
SM20 2310B (4a)

SM18 4500-CN E
MCAWW 350.1
SM18 5210 B
MCAWW 300.0A
MCAWW 410.4
MCAWW 300.0A
SM20 5310B
MCAWW 300.0A
SM20 2340C
MCAWW 300.0A
MCAWW 353.2
MCAWW 300.0A
CFR136A 1664A HEM
MCAWW 120.1
MCAWW 300.0A
SM20 5310B
SM18 2320 B
SM18 2540 C
MCAWW 351.3
MCAWW 365.2
SM20 2540D
MCAWW 180.1
SW846 9012A
SW846 9030B/9034
SW846 9040
SW846 9066
SM4500-SO3 B
SM5540 C
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
200
200
10
10
10
10
200
200
4
4
2000
2000
5
5
5000
5000
5
5
500
500
25
25
100
100
3
3
500
500
5000
5000
150
150
400
400
40
40
5000
5000
5
5
5
5
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
Day 0
Day 1
Location P
Butler County, PA
Day 5
7/14/2009
7/15/2009
7/20/2009
5
0.01
0.28
4.2
0.2
35.3
152
5
0.27
194
0.52
0.47
0.11
5
726
73.7
5.6
38.6
401
2.3
0.1
10
3.4
10
3
7.3
0.01
10
0.05
2000
2000
100
100
100
100
173
187
40
40
80.8
90.2
50
50
63200
69900
50
50
500
500
250
32.1
1000
1000
30
30
500
500
9410
10400
23.7
15.4
400
400
21.1
16.6
4590
4010
50
50
50
50
U
U
J
U
J
J
U
J
J
J
J
B
U
U
U
U
U
U
U
U
U
U
U
BJ
B
U
U
BJ
BJ
U
U
U
U
U
U
U
B
U
U
U
U
U
U
B
B
B
B
U
U
B
B
B
B
U
U
U
U
5
0.01
17.4
391
60
1180
6450
302
1.3
2200
0.75
0.56
2.9
4.9
24600
65.6
292
255
11600
61.6
0.17
18
15.7
9.8
3
7.6
0.027
8.40
0.178
2000
227
25.3
19.3
100
100
2590
2690
40
40
6510
7200
50
50
616000
655000
33.2
26.4
500
5.3
250
250
5240
5120
30
30
7900
8300
65500
70100
369
397
72.4
75.4
28.6
30.8
99500
105000
50
50
50
50
U
U
J
U
J
J
J
J
B
U
U
B
BJ
BJ
U
U
J
U
U
J
J
U
U
B
B
U
B
U
U
U
U
J
B
B
B
B
U
U
U
U
28.8
0.01
107
1260
477
4820
43900
240
1.2
24000
1.2
0.46
11.8
57.7
160000
53.1
287
93.2
78600
92.9
0.11
10.8
486
10
3
6.3
0.037
2.5
0.0777
378
435
100
15.2
100
100
28900
41000
40
40
21000
22900
50
50
6160000
6450000
44.2
45
500
500
250
250
28800
30300
30
30
40200
43000
658000
715000
1300
1390
44.4
47
400
400
656000
723000
50
50
50
50
U
J
GU
GU
J
J
J
U
U
BJ
BJ
U
B
U
U
U
U
U
U
J
J
B
B
U
U
U
U
U
U
J
BJ
B
U
U
E
E
U
U
U
U
Day 14
Day 90
7/29/2009
10/29/2009
5
0.01
78
752
487
3170
45600
237
1.2
21000
1.2
0.83
9.4
5
175000
48.7
226
121
63900
42.2
0.14
79.2
708
10
3
6.6
0.02
7.20
0.125
529
301
14.9
100
100
100
43900
72000
40
40
20600
21100
50
1.6
5700000
5780000
98.3
75.5
500
500
250
250
67300
21600
30
30
56500
57400
613000
632000
2240
2240
87.8
93.2
25.2
400
614000
628000
50
50
50
50
U
U
J
GU
GU
U
J
U
U
BJ
BJ
B
U
U
U
U
U
U
B
J
J
U
U
U
U
U
U
J
BJ
B
B
U
U
U
U
U
253
0.01
134
525
678
4440
66300
121
5
53000
5
0.031
5
4.6
231000
64
297
80.5
117000
121
0.2
112
416
10
3
6.2
0.04
NA
NA
225
208
100
100
100
100
56000
63200
40
40
24400
27800
50
50
8370000
9390000
52.2
48.1
500
500
104
81.9
140000
111000
105
30
62900
71000
908000
1030000
3150
3540
400
400
30.9
27.4
821000
952000
50
50
50
50
U
J
J
U
GU
B
GU
U
BJ
J
GU
U
U
BJ
BJ
U
U
U
U
U
U
J
U
U
B
U
U
B
B
U
J
U
U
B
B
E
E
U
U
U
U
Day 0
PARAMETER
Sodium
Sodium-DISS
Strontium
Strontium-DISS
Thallium
Thallium-DISS
Tin
Tin-DISS
Titanium
Titanium-DISS
Trivalent Chrom
Zinc
Zinc-DISS
Hexavalent Chromium
Mercury
Mercury-DISS
1,1-Dichloroethane
1,1-Dichloroethene
1,1-Dichloropropene
1,2-Dichlorobenzene
1,2-Dichloroethane
1,2-Dichloropropane
1,3-Dichlorobenzene
1,3-Dichloropropane
1,4-Dichlorobenzene
1,4-Dioxane
2,2-Dichloropropane
2-Butanone
2-Hexanone
4-Chlorotoluene
Acetone
Acrolein
Acrylonitrile
Benzene
Benzyl chloride
Bromobenzene
Bromoform
Bromomethane
Carbon disulfide
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
Dibromomethane
Ethylbenzene
Isopropylbenzene
Methylene chloride
Naphthalene
n-Butylbenzene
n-Propylbenzene
p-Isopropyltoluene
sec-Butylbenzene
Styrene
UNITS
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
mg/L
mg/L
ug/L
ug/L
PQL
5000
5000
50
50
10
10
1000
1000
500
500
50
20
20
0.01
0.01
0.2
0.2
US EPA Method
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 7196A
SW846 7196A
SW846 7470A
SW846 7470A
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
1000
-5
5
10
5
5
5
20
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
Location P
Butler County, PA
Day 5
Day 1
7/14/2009
56700
62000
417
464
100
100
1000
1000
500
500
50
72.3
45.3
0.01
0.01
0.2
0.2
5
5
5
5
5
5
5
5
5
5
0.79
5
5
5
5
5
5
5
5
5
1000
NA
5
5
10
5
5
5
12
100
100
5
5
5
2.2
5
5
5
5
5
5
2.4
5
5
5
2.1
5
5
5
5
5
5
0.55
5
5
5
5
5
J
BJ
BJ
U
U
U
U
U
U
U
BJ
BJ
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
J
U
U
U
U
U
U
J
U
U
U
J
U
U
U
U
U
U
J
U
U
U
U
U
7/15/2009
3040000
3230000
93100
98300
100
100
1000
1000
500
500
26.4
184
154
0.01
0.0068
0.2
0.2
10
10
10
10
10
10
10
10
10
10
1.4
10
10
10
10
10
10
10
10
10
2000
NA
10
10
20
10
10
10
320
200
200
140
10
10
10
10
10
10
10
10
10
10
5.9
10
10
10
10
10
2.5
10
10
10
10
10
10
10
10
10
J
J
J
U
U
U
U
U
U
B
BJ
BJ
U
B
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
7/20/2009
18000000
18700000
1240000
1320000
100
23.6
1000
1000
500
500
44.2
150
245
0.25
0.25
0.2
0.2
500
500
500
500
500
500
500
500
500
500
840
500
500
500
500
500
940
500
500
500
100000
NA
500
500
1000
500
500
500
5200
10000
10000
2000
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
650
160
500
500
500
500
500
500
500
500
JE
JE
U
B
U
U
U
U
B
BJ
J
GU
GU
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
Day 14
7/29/2009
21100000
21000000
1210000
1240000
33.9
41
1000
21.4
500
500
98.3
90.3
105
0.1
0.1
0.2
0.2
500
500
500
500
500
500
500
500
500
500
710
500
500
500
500
500
770
500
500
500
100000
NA
500
500
1000
500
500
500
2000
10000
10000
1100
500
500
500
500
230
500
500
500
500
500
500
500
500
500
500
500
470
120
500
500
500
500
90
500
500
500
Day 90
J
J
B
B
U
B
U
U
BJ
BJ
GU
GU
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
J
J
U
U
U
U
J
U
U
U
10/29/2009
25100000
28200000
1790000
2020000
100
100
1000
1000
500
500
48.1
424
236
0.25
0.25
0.2
0.2
25
25
25
25
25
25
25
25
25
25
84
25
25
25
25
25
79
25
25
25
5000
NA
25
25
50
25
25
25
190
500
500
200
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
46
25
25
25
25
25
25
25
25
25
J
JE
JE
U
U
U
U
U
U
B
J
J
GU
GU
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
PARAMETER
tert-butyl acetate
tert-Butylbenzene
Tetrachloroethene
tetrahydrofuran
Toluene
Trichloroethene
Vinyl acetate
Vinyl chloride
Xylenes (total)
1,3-Dinitrobenzene
1,4-Naphthoquinone
1-Naphthylamine
2,3,7,8-TCDD
2,4-Dimethylphenol
2,4-Dinitrophenol
2,4-Dinitrotoluene
2,6-Dichlorophenol
2,6-Dinitrotoluene
2-Chloronaphthalene
2-Chlorophenol
2-Methylnaphthalene
2-Methylphenol
2-Naphthylamine
2-Nitroaniline
2-Nitrophenol
2-Picoline
3-Nitroaniline
4-Aminobiphenyl
4-Chloroaniline
4-Nitroaniline
4-Nitrophenol
5-Nitro-o-toluidine
Acenaphthene
Acenaphthylene
Acetophenone
Aniline
Aramite
Benzidine
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(ghi)perylene
Benzyl alcohol
Chlorobenzilate
Chrysene
Diallate
Dibenzofuran
Diethyl phthalate
Dimethoate
Dimethyl phthalate
UNITS
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
PQL
-5
5
-5
5
5
5
5
5
5
15
US EPA Method
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
10
2
10
10
10
10
-10
10
10
40
10
2
10
10
2
10
2
10
10
50
10
10
10
10
10
50
50
10
10
10
10
10
50
50
100
10
2
2
10
10
10
200
10
5
2
2
2
10
10
2
2
10
10
10
2
10
2
10
10
10
10
10
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
Day 0
Day 1
Location P
Butler County, PA
Day 5
Day 14
7/14/2009
7/15/2009
7/20/2009
7/29/2009
NA
5
5
NA
0.93
5
5
5
5
5
5
5.1
9.4
1.9
9.4
9.4
9.4
9.4
NA
9.4
9.4
9.4
47
9.4
1.9
9.4
9.4
1.9
9.4
1.9
9.4
9.4
47
9.4
9.4
9.4
9.4
9.4
47
47
9.4
9.4
9.4
9.4
9.4
47
47
94
9.4
1.9
1.9
9.4
9.4
9.4
190
1.9
1.9
1.9
1.9
1.9
9.4
9.4
1.9
1.9
4.2
9.4
9.4
1.9
9.4
1.9
9.4
0.49
9.4
9.4
0.6
U
U
J
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
J
U
U
J
NA
10
10
NA
92
10
10
10
10
10
10
32
9.7
1.9
9.7
9.7
9.7
9.7
NA
9.7
9.7
9.7
48
9.7
1.9
9.7
9.7
1.9
9.7
1.9
9.7
9.7
48
9.7
9.7
9.7
9.7
2.5
48
48
9.7
9.7
9.7
9.7
9.7
48
48
97
9.7
1.9
1.9
0.95
9.7
9.7
190
1.9
1.9
1.9
1.9
1.9
9.7
9.7
1.9
1.9
5.9
9.7
9.7
1.9
9.7
1.9
9.7
0.51
9.7
9.7
0.46
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
J
U
U
J
NA
500
500
NA
6200
500
500
500
500
500
500
6500
20
3.9
20
20
20
20
NA
20
20
20
98
20
3.9
20
20
3.9
20
3.9
20
20
98
20
20
20
20
20
98
98
20
20
20
20
20
98
98
200
20
3.9
3.9
20
20
20
390
3.9
3.9
3.9
3.9
3.9
20
20
3.9
3.9
16
20
20
3.9
20
3.9
20
20
20
20
0.84
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
J
Day 90
NA
500
500
NA
5200
500
500
500
500
500
500
5400
9.4
1.9
9.4
9.4
9.4
9.4
NA
9.4
9.4
9.4
47
9.4
1.9
9.4
9.4
1.9
9.4
1.9
9.4
9.4
47
9.4
9.4
9.4
9.4
9.4
47
47
9.4
9.4
9.4
9.4
9.4
47
47
94
9.4
1.9
1.9
9.4
9.4
9.4
190
1.9
1.9
1.9
1.9
1.9
9.4
9.4
1.9
1.9
4.6
9.4
9.4
1.9
9.4
1.9
9.4
9.4
9.4
9.4
9.4
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
10/29/2009
NA
25
25
NA
580
25
25
25
25
25
25
530
9.4
1.9
9.4
9.4
9.4
9.4
NA
9.4
9.4
12
47
9.4
1.9
9.4
9.4
1.9
9.4
1.9
15
9.4
47
9.4
9.4
9.4
9.4
16
47
47
9.4
9.4
9.4
9.4
9.4
47
47
94
9.4
1.9
1.9
16
9.4
9.4
190
1.9
1.9
1.9
1.9
1.9
9.4
9.4
1.9
1.9
9.4
9.4
9.4
1.9
9.4
1.9
9.4
9.4
9.4
9.4
9.4
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
PARAMETER
Dinoseb
Diphenylamine
Disulfoton
Fluoranthene
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hexachloroethane
Hexachloropropene
Isodrin
Isophorone
Isosafrole
Nitrobenzene
N-Nitrosomorpholine
N-Nitrosopiperidine
o-Toluidine
Parathion
Pentachlorobenzene
Pentachloroethane
Pentachlorophenol
Phenanthrene
Phenol
Phorate
Pronamide
Pyrene
Pyridine
Safrole
Thionazin
UNITS
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
PQL
10
10
2
10
10
2
2
0.05
2
2
10
10
2
10
10
10
10
2
10
10
10
2
2
10
10
10
10
10
10
10
10
10
20
10
10
2
2
10
10
2
10
10
10
10
US EPA Method
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
4,4'-DDD
4,4'-DDE
4,4'-DDT
Aldrin
alpha-BHC
beta-BHC
delta-BHC
Dieldrin
Endosulfan I
Endosulfan II
Endosulfan sulfate
Endrin
Endrin aldehyde
Endrin ketone
gamma-BHC (Lindane)
Heptachlor
Heptachlor epoxide
Methoxychlor
Toxaphene
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.1
2
PCBs
Aroclor 1016
Aroclor 1221
Aroclor 1232
Aroclor 1242
Aroclor 1248
Aroclor 1254
Aroclor 1260
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
0.4
0.4
0.4
0.4
0.4
0.4
0.4
Day 0
Day 1
Location P
Butler County, PA
Day 5
Day 14
7/14/2009
7/15/2009
7/20/2009
7/29/2009
9.4
9.4
1.9
9.4
9.4
1.9
1.9
1.9
1.9
9.4
9.4
9.4
1.9
9.4
9.4
9.4
9.4
1.9
9.4
9.4
9.4
1.9
1.9
9.4
9.4
9.4
9.4
9.4
9.4
9.4
9.4
9.4
19
9.4
9.4
1.9
1.9
9.4
9.4
1.9
9.4
9.4
9.4
NA
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
9.7
9.7
1.9
9.7
9.7
1.9
1.9
1.9
1.9
9.7
9.7
9.7
1.9
9.7
9.7
9.7
9.7
1.9
9.7
9.7
9.7
1.9
1.9
9.7
9.7
9.7
9.7
9.7
9.7
9.7
9.7
9.7
19
9.7
9.7
1.9
1.9
9.7
9.7
0.28
360
9.7
9.7
NA
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
0.047
0.047
0.047
0.047
0.047
0.047
0.47
0.047
0.047
0.047
0.047
0.047
0.047
0.047
0.047
0.047
0.047
0.047
0.094
1.9
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
SW846 8082
SW846 8082
SW846 8082
SW846 8082
SW846 8082
SW846 8082
SW846 8082
0.38
0.38
0.38
0.38
0.38
0.38
0.38
U
U
U
U
U
U
U
NA
NA
NA
NA
NA
NA
NA
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
15
20
3.9
20
20
3.9
3.9
3.9
3.9
20
20
20
3.9
20
20
20
20
3.9
20
20
20
3.9
3.9
20
20
20
20
20
20
20
20
20
39
20
20
3.9
3.9
20
20
3.9
470
20
20
NA
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Day 90
10/29/2009
9.4
9.4
1.9
9.4
9.4
1.9
1.9
1.9
1.9
9.4
9.4
9.4
1.9
9.4
9.4
9.4
9.4
1.9
9.4
9.4
9.4
1.9
1.9
9.4
9.4
9.4
9.4
9.4
9.4
9.4
9.4
9.4
19
9.4
9.4
1.9
21
9.4
9.4
1.9
340
9.4
9.4
NA
9.4
9.4
1.9
9.4
9.4
1.9
1.9
1.9
1.9
9.4
9.4
9.4
1.9
9.4
9.4
9.4
9.4
1.9
9.4
9.4
9.4
1.9
1.9
9.4
9.4
9.4
9.4
9.4
9.4
9.4
9.4
9.4
19
9.4
9.4
1.9
1.9
9.4
9.4
1.9
220
9.4
9.4
NA
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.05
0.05
0.05
0.05
0.05
0.05
0.5
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.1
2
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
0.047
0.047
0.047
0.047
0.047
0.047
0.47
0.047
0.047
0.047
0.047
0.047
0.047
0.047
0.047
0.047
0.047
0.047
0.094
1.9
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
NA
NA
NA
NA
NA
NA
NA
0.4
0.4
0.4
0.4
0.4
0.4
0.4
U
U
U
U
U
U
U
0.38
0.38
0.38
0.38
0.38
0.38
0.38
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
PARAMETER
Day 0
Day 1
Location P
Butler County, PA
Day 5
Day 14
Day 90
7/14/2009
7/15/2009
7/20/2009
7/29/2009
10/29/2009
UNITS
PQL
US EPA Method
Ethyl parathion
ug/L
0.4
SW846 8141A
0.97 U
NA
Alcohols
2-Propanol
Butyl alcohol
Ethanol
Methanol
n-Propanol
mg/L
mg/L
mg/L
mg/L
mg/L
10
10
10
10
10
SW846 8015
SW846 8015
SW846 8015
SW846 8015
SW846 8015
10
10
10
10
10
10
10
10
190
10
Glycols
Ethylene Glycol
Propylene glycol
mg/L
mg/L
50
50
SW846 8015
SW846 8015
100 UJ
100 UJ
100 UJ
100 UJ
Acids
Acetic Acid
Butyric Acid
Propionic Acid
Volatile Acids
mg/L
mg/L
mg/L
mg/L
10
10
10
10
SW846 8015
SW846 8015
SW846 8015
1U
1U
1U
20
1U
1U
1U
80
UJ
UJ
UJ
UJ
UJ
NA
UJ
UJ
UJ
J
UJ
10
10
10
160
10
0.95 U
UJ
UJ
UJ
J
UJ
10
10
10
140
10
0.95 U
UJ
UJ
UJ
J
UJ
NA
NA
NA
NA
NA
100 UJ
100 UJ
100 UJ
100 UJ
NA
NA
20 UJ
20 UJ
20 UJ
250
10 UJ
10 UJ
10 UJ
150
NA
NA
NA
NA
Location Q
Day 1
Day 5
Day 14
Day 0
PARAMETER
Acidity
Amenable cyanide
Ammonia Nitrogen
Bromide
Chloride
Fluoride
Hardness, as CaCO3
Nitrate as N
Nitrate-Nitrite
Nitrite as N
Oil & Grease (HEM)
Sulfate
TOC
Total Alkalinity
Total phosphorus
Turbidity
Cyanide, Total
Total Sulfide
pH
Sulfite
MBAS (mol.wt 320)
Aluminum
Aluminum-DISS
Antimony
Antimony-DISS
Arsenic
Arsenic-DISS
Barium
Barium-DISS
Beryllium
Beryllium-DISS
Boron
Boron-DISS
Cadmium
Cadmium-DISS
Calcium
Calcium-DISS
Chromium
Chromium-DISS
Cobalt
Cobalt-DISS
Copper
Copper-DISS
Iron
Iron-DISS
Lead
Lead-DISS
Lithium
Lithium-DISS
Magnesium
Magnesium-DISS
Manganese
Manganese-DISS
Molybdenum
Molybdenum-DISS
Nickel
Nickel-DISS
Potassium
Potassium-DISS
Selenium
Selenium-DISS
Silver
Silver-DISS
6/30/2009
UNITS
PQL
US EPA Method
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
umhos/cm
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
NTU
ug/L
mg/L
No Units
mg/L
mg/L
mg/L
5
0.01
0.1
2
1
10
1
-1
5
0.05
0.1
0.05
5
-1
1
5
10
3
0.1
4
-10
3
-0.01
1
0.05
SM20 2310B (4a)

SM18 4500-CN E
MCAWW 350.1
SM18 5210 B
MCAWW 300.0A
MCAWW 410.4
MCAWW 300.0A
SM20 5310B
MCAWW 300.0A
SM20 2340C
MCAWW 300.0A
MCAWW 353.2
MCAWW 300.0A
CFR136A 1664A HEM
MCAWW 120.1
MCAWW 300.0A
SM20 5310B
SM18 2320 B
SM18 2540 C
MCAWW 351.3
MCAWW 365.2
SM20 2540D
MCAWW 180.1
SW846 9012A
SW846 9030B/9034
SW846 9040
SW846 9066
SM4500-SO3 B
SM5540 C
5
0.01
1.8
121
4.5
1770
78.1
467
0.25
88
0.25
0.33
0.25
5
426
45.3
410
49
311
11.9
0.034
120
20.7
92.4
4.8
6.9
0.033
12.0
0.501
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
200
200
10
10
10
10
200
200
4
4
2000
2000
5
5
5000
5000
5
5
500
500
25
25
100
100
3
3
500
500
5000
5000
150
150
400
400
40
40
5000
5000
5
5
5
5
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
2000
2000
100
100
100
100
227
294
40
40
2000
33.5
50
50
27800
26800
50
50
500
500
39.7
35.6
429
1000
30
30
500
500
6400
6090
8.2
150
400
400
400
400
50000
4110
50
50
50
50
7/1/2009
U
NR U
J
GU
GU
GU
U
J
J
J
J
U
U
U
U
U
U
B
B
U
U
U
B
U
U
BJ
BJ
U
U
U
U
B
B
BJ
U
U
U
U
U
B
B
BJ
U
U
U
U
U
U
B
U
U
U
U
5
0.01
16.1
184
87.9
1080
8960
341
2.5
2200
2.5
0.51
6.5
4.8
39800
31.8
142
338
16600
24.3
0.16
9.2
11.7
21.2
3.2
7.5
0.0087
12.4
0.05
395
190
24.7
25.2
100
100
37600
43800
40
40
5110
5840
50
50
641000
728000
50
50
500
500
250
250
5830
5000
14.5
14.5
12300
14300
59800
67100
752
826
21.1
24.1
400
400
45400
53500
50
50
50
50
U
NR U
J
J
GU
GU
U
J
BJ
J
J
BJ
U
B
B
B
B
U
U
U
U
U
U
J
J
U
U
U
U
U
U
J
B
B
J
B
B
U
U
B
U
U
U
U
7/6/2009
5
0.01
65.4
144
310
1850
33500
160
2.5
9100
2.5
0.055
13.2
4.6
130000
50
46.5
140
38500
61.7
0.097
95
68.2
72.1
2.4
6.6
0.018
6.4
0.133
246
173
100
100
100
100
415000
401000
40
40
9070
8500
50
50
3120000
2890000
50
50
500
500
28.9
250
37500
30400
30
30
29300
27000
331000
307000
2300
2130
20.6
400
400
400
187000
163000
50
50
50
50
U
NR U
GU
GU
BJ
U
J
GU
J
J
B
J
B
BJ
U
U
U
U
U
U
U
U
J
J
U
U
U
U
B
U
U
U
BJ
U
U
U
U
U
U
U
Day 90
7/15/2009
63.2
0.01
102
98.1
720
14000
71500
25.8
2.5
32000
2.5
0.025
19.9
4.8
249000
50
24
113
120000
83.1
0.055
62
10.5
10
3
6.2
0.01
14.8
0.836
640
737
37.2
38.5
46.4
65
1700000
1730000
40
40
10400
10800
1.4
1.9
8790000
8730000
50
50
1000
1000
250
250
72700
72900
60
60
68700
69100
938000
963000
4790
4890
14.8
400
800
800
265000
267000
50
44.2
50
50
10/27/2009
U
J
GU
GU
B
U
J
GU
J
J
BJ
U
U
U
B
B
BJ
BJ
B
B
J
U
U
J
J
B
B
U
U
U
U
U
U
U
U
J
B
U
U
U
U
B
U
U
698
0.01
215
121
1090
7080
131000
18.4
2.5
90000
2.5
0.069
84.5
6.4
464000
50
34.1
52.9
207000
128
1
534
264
10
3
5.9
0.01
14.8
0.836
271
181
100
100
100
100
3440000
2560000
40
40
13600
10200
2.6
50
18000000
13400000
14.8
50
5000
5000
56.6
250
321000
220000
50
15.7
100000
74500
1690000
1290000
10200
7700
17.5
400
49.9
36.5
858000
611000
50
50
50
50
U
J
GU
GU
B
GU
J
GU
U
U
U
BJ
BJ
U
U
U
U
U
U
J
BJ
U
B
U
U
U
B
U
B
J
B
U
B
B
U
U
U
U
Day 0
PARAMETER
Sodium
Sodium-DISS
Strontium
Strontium-DISS
Thallium
Thallium-DISS
Tin
Tin-DISS
Titanium
Titanium-DISS
Trivalent Chrom
Zinc
Zinc-DISS
Hexavalent Chromium
Mercury
Mercury-DISS
1,1-Dichloroethane
1,1-Dichloroethene
1,1-Dichloropropene
1,2-Dichlorobenzene
1,2-Dichloroethane
1,2-Dichloropropane
1,3-Dichlorobenzene
1,3-Dichloropropane
1,4-Dichlorobenzene
1,4-Dioxane
2,2-Dichloropropane
2-Butanone
2-Hexanone
4-Chlorotoluene
Acetone
Acrolein
Acrylonitrile
Benzene
Benzyl chloride
Bromobenzene
Bromoform
Bromomethane
Carbon disulfide
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
Dibromomethane
Ethylbenzene
Isopropylbenzene
Methylene chloride
Naphthalene
n-Butylbenzene
n-Propylbenzene
p-Isopropyltoluene
sec-Butylbenzene
Styrene
Day 1
Location Q
Day 5
Day 14
UNITS
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
mg/L
mg/L
ug/L
ug/L
PQL
5000
5000
50
50
10
10
1000
1000
500
500
50
20
20
0.01
0.01
0.2
0.2
US EPA Method
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 7196A
SW846 7196A
SW846 7470A
SW846 7470A
6/30/2009
63200
67900
292 B J
254 B J
100 U
100 U
1000 U
1000 U
500 U
500 U
50 U
37.7 B
69 B J
0.5 G U
0.5 G U
0.2 U
0.095 B
7/1/2009
5400000
5960000
86200 J
98800 J
100 U
100 U
1000 U
1000 U
44.5 B
35.4 B
50 U
78.6 B
100 B J
0.5 G U
0.5 G U
0.2 U
0.2 U
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
1000
-5
5
10
5
5
5
20
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
1000
NA
5
5
10
5
5
5
28
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
1000
NA
5
5
10
5
5
5
16
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
7/6/2009
1.7E+07
1.6E+07
422000 J
396000 J
100 U
100 U
1000 U
22.4 B
500 U
500 U
50 U
156 B
159 B
0.1 G U
0.1 G U
0.2 U
0.2 U
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
1000
NA
5
5
10
5
5
5
42
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
4
5
5
5
5
5
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
Day 90
7/15/2009
30800000 J
31300000
1310000 J
1300000 J
200 U
200 U
1000 U
1000 U
139 B
113 B
50 U
144 B J
137 B J
0.25 G U
0.25 U
0.2 U
0.2 U
10/27/2009
49700000
36800000 J
2860000 J
2100000 J
100 U
100 U
1000 U
1000 U
500 U
500 U
50 U
247000 J
182000 J
1 GU
1 GU
0.2 U
0.2 U
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
10000
NA
50
50
100
50
50
50
520
1000
1000
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
5
5
5
5
5
5
5
4.9
5
5
5
5
5
5
5
5
5
5
5
5
1000
NA
5
5
10
5
5
5
20
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Day 0
PARAMETER
tert-butyl acetate
tert-Butylbenzene
Tetrachloroethene
tetrahydrofuran
Toluene
Trichloroethene
Vinyl acetate
Vinyl chloride
Xylenes (total)
1,3-Dinitrobenzene
1,4-Naphthoquinone
1-Naphthylamine
2,3,7,8-TCDD
2,4-Dimethylphenol
2,4-Dinitrophenol
2,4-Dinitrotoluene
2,6-Dichlorophenol
2,6-Dinitrotoluene
2-Chloronaphthalene
2-Chlorophenol
2-Methylnaphthalene
2-Methylphenol
2-Naphthylamine
2-Nitroaniline
2-Nitrophenol
2-Picoline
3-Nitroaniline
4-Aminobiphenyl
4-Chloroaniline
4-Nitroaniline
4-Nitrophenol
5-Nitro-o-toluidine
Acenaphthene
Acenaphthylene
Acetophenone
Aniline
Aramite
Benzidine
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(ghi)perylene
Benzyl alcohol
Chlorobenzilate
Chrysene
Diallate
Dibenzofuran
Diethyl phthalate
Dimethoate
Dimethyl phthalate
UNITS
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
PQL
-5
5
-5
5
5
5
5
5
5
15
US EPA Method
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
10
2
10
10
10
10
-10
10
10
40
10
2
10
10
2
10
2
10
10
50
10
10
10
10
10
50
50
10
10
10
10
10
50
50
100
10
2
2
10
10
10
200
10
5
2
2
2
10
10
2
2
10
10
10
2
10
2
10
10
10
10
10
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
Day 1
6/30/2009
NA
5U
5U
NA
5U
5U
5U
5U
5U
5U
5U
15 U
9.5
1.9
9.5
9.5
9.5
9.5
NA
9.5
9.5
9.5
48
9.5
1.9
9.5
9.5
1.9
9.5
1.9
9.5
9.5
48
9.5
9.5
9.5
9.5
9.5
48
48
9.5
9.5
9.5
9.5
9.5
48
48
95
9.5
1.9
1.9
9.5
9.5
9.5
190
1.9
1.9
1.9
1.9
1.9
9.5
9.5
1.9
1.9
10
9.5
9.5
1.9
9.5
1.9
9.5
9.5
9.5
9.5
1.1
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
7/1/2009
NA
5U
5U
NA
5U
5U
5U
5U
5U
5U
5U
15 U
9.5
1.9
9.5
9.5
9.5
9.5
NA
9.5
9.5
9.5
48
9.5
1.9
9.5
9.5
1.9
9.5
1.9
9.5
9.5
48
9.5
9.5
9.5
9.5
9.5
48
48
9.5
9.5
9.5
9.5
9.5
48
48
95
9.5
1.9
1.9
1.2
9.5
9.5
190
1.9
1.9
1.9
1.9
1.9
9.5
9.5
1.9
1.9
9.5
9.5
9.5
1.9
9.5
1.9
9.5
9.5
9.5
9.5
9.5
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Location Q
Day 5
Day 14
7/6/2009
NA
5U
5U
NA
1.2 J
5U
5U
5U
5U
5U
5U
4.4 J
9.4
1.9
9.4
9.4
9.4
9.4
NA
9.4
9.4
9.4
47
9.4
1.9
9.4
9.4
1.9
9.4
1.9
9.4
9.4
47
9.4
9.4
9.4
9.4
0.2
47
47
9.4
9.4
9.4
9.4
9.4
47
47
94
9.4
1.9
1.9
0.34
9.4
9.4
190
1.9
1.9
1.9
1.9
1.9
9.4
9.4
1.9
1.9
9.4
9.4
9.4
1.9
9.4
1.9
9.4
9.4
9.4
9.4
9.4
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Day 90
7/15/2009
NA
50 U
50 U
NA
50 U
50 U
50 U
50 U
50 U
50 U
50 U
150 U
9.4
1.9
9.4
9.4
9.4
9.4
NA
9.4
9.4
9.4
47
9.4
1.9
9.4
9.4
1.9
9.4
1.9
9.4
9.4
47
9.4
9.4
9.4
9.4
9.4
47
47
9.4
9.4
9.4
9.4
9.4
47
47
94
9.4
1.9
1.9
0.33
9.4
9.4
190
1.9
1.9
1.9
1.9
1.9
4.4
9.4
1.9
1.9
3.7
9.4
9.4
1.9
9.4
1.9
9.4
9.4
9.4
9.4
9.4
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
J
U
U
U
J
U
U
U
U
U
U
U
U
U
U
10/27/2009
NA
5U
5U
NA
5U
5U
5U
5U
5U
5U
5U
15 U
9.4
1.9
9.4
9.4
9.4
9.4
NA
9.4
9.4
9.4
47
9.4
1.9
9.4
9.4
1.9
9.4
1.9
9.4
9.4
47
9.4
9.4
9.4
9.4
9.4
47
47
9.4
9.4
9.4
9.4
9.4
47
47
94
9.4
1.9
1.9
9.4
9.4
9.4
190
1.9
1.9
1.9
1.9
1.9
9.4
9.4
1.9
1.9
2
9.4
9.4
1.9
9.4
1.9
9.4
9.4
9.4
9.4
9.4
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
Day 0
PARAMETER
Dinoseb
Diphenylamine
Disulfoton
Fluoranthene
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hexachloroethane
Hexachloropropene
Isodrin
Isophorone
Isosafrole
Nitrobenzene
N-Nitrosomorpholine
N-Nitrosopiperidine
o-Toluidine
Parathion
Pentachlorobenzene
Pentachloroethane
Pentachlorophenol
Phenanthrene
Phenol
Phorate
Pronamide
Pyrene
Pyridine
Safrole
Thionazin
Day 1
Location Q
Day 5
Day 14
Day 90
UNITS
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
PQL
10
10
2
10
10
2
2
0.05
2
2
10
10
2
10
10
10
10
2
10
10
10
2
2
10
10
10
10
10
10
10
10
10
20
10
10
2
2
10
10
2
10
10
10
10
US EPA Method
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
6/30/2009
9.5 U
9.5 U
1.9 U
9.5 U
9.5 U
1.9 U
1.9 U
1.9 U
1.9 U
9.5 U
9.5 U
9.5 U
1.9 U
9.5 U
9.5 U
9.5 U
9.5 U
1.9 U
9.5 U
9.5 U
9.5 U
1.9 U
1.9 U
9.5 U
9.5 U
9.5 U
9.5 U
9.5 U
9.5 U
9.5 U
9.5 U
9.5 U
19 U
9.5 U
9.5 U
1.9 U
1.9 U
9.5 U
9.5 U
1.9 U
9.5 U
9.5 U
9.5 U
NA
7/1/2009
9.5 U
9.5 U
1.9 U
9.5 U
9.5 U
1.9 U
1.9 U
1.9 U
1.9 U
9.5 U
9.5 U
9.5 U
1.9 U
9.5 U
9.5 U
9.5 U
9.5 U
1.9 U
9.5 U
9.5 U
9.5 U
1.9 U
1.9 U
9.5 U
9.5 U
9.5 U
9.5 U
9.5 U
9.5 U
9.5 U
9.5 U
9.5 U
19 U
9.5 U
9.5 U
1.9 U
1.9 U
9.5 U
9.5 U
1.9 U
9.5 U
9.5 U
9.5 U
NA
7/6/2009
9.4 U
9.4 U
1.9 U
9.4 U
9.4 U
1.9 U
1.9 U
1.9 U
1.9 U
9.4 U
9.4 U
9.4 U
1.9 U
9.4 U
9.4 U
9.4 U
9.4 U
1.9 U
9.4 U
9.4 U
9.4 U
1.9 U
1.9 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
19 U
9.4 U
9.4 U
1.9 U
1.9 U
9.4 U
9.4 U
1.9 U
9.4 U
9.4 U
9.4 U
NA
4,4'-DDD
4,4'-DDE
4,4'-DDT
Aldrin
alpha-BHC
beta-BHC
delta-BHC
Dieldrin
Endosulfan I
Endosulfan II
Endosulfan sulfate
Endrin
Endrin aldehyde
Endrin ketone
gamma-BHC (Lindane)
Heptachlor
Heptachlor epoxide
Methoxychlor
Toxaphene
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.1
2
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
0.048
0.048
0.048
0.17
0.048
0.26
0.48
0.072
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.12
0.26
0.095
1.9
PG
U
U
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.047
0.047
0.047
0.047
0.047
0.047
0.47
0.047
0.047
0.047
0.047
0.047
0.047
0.047
0.047
0.047
0.047
0.047
0.094
1.9
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
0.048
0.048
0.048
0.048
0.048
0.048
0.48
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.096
1.9
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
PCBs
Aroclor 1016
Aroclor 1221
Aroclor 1232
Aroclor 1242
Aroclor 1248
Aroclor 1254
Aroclor 1260
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
0.4
0.4
0.4
0.4
0.4
0.4
0.4
SW846 8082
SW846 8082
SW846 8082
SW846 8082
SW846 8082
SW846 8082
SW846 8082
0.38
0.38
0.38
0.38
0.38
0.38
0.38
U
U
U
U
U
U
U
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.38
0.38
0.38
0.38
0.38
0.38
0.38
U
U
U
U
U
U
U
0.4
0.4
0.4
0.4
0.4
0.4
0.4
U
U
U
U
U
U
U
U
U
U
PG
U
U
PG
U
U
U
U
U
U
U
U
7/15/2009
9.4 U
9.4 U
1.9 U
9.4 U
9.4 U
1.9 U
1.9 U
1.9 U
1.9 U
9.4 U
9.4 U
9.4 U
1.9 U
9.4 U
9.4 U
9.4 U
9.4 U
1.9 U
9.4 U
9.4 U
9.4 U
1.9 U
1.9 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
19 U
9.4 U
9.4 U
1.9 U
1.9 U
9.4 U
9.4 U
1.9 U
9.4 U
9.4 U
9.4 U
NA
10/27/2009
9.4 U
9.4 U
1.9 U
9.4 U
9.4 U
1.9 U
1.9 U
1.9 U
1.9 U
9.4 U
9.4 U
9.4 U
1.9 U
9.4 U
9.4 U
9.4 U
9.4 U
1.9 U
9.4 U
9.4 U
9.4 U
1.9 U
1.9 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
19 U
9.4 U
9.4 U
1.9 U
1.9 U
9.4 U
9.4 U
1.9 U
9.4 U
9.4 U
9.4 U
NA
PARAMETER
Location Q
Day 5
Day 14
Day 0
Day 1
6/30/2009
7/1/2009
7/6/2009
0.95 U
NA
NA
38
5
5
5
5
Day 90
UNITS
PQL
US EPA Method
Ethyl parathion
ug/L
0.4
SW846 8141A
Alcohols
2-Propanol
Butyl alcohol
Ethanol
Methanol
n-Propanol
mg/L
mg/L
mg/L
mg/L
mg/L
10
10
10
10
10
SW846 8015
SW846 8015
SW846 8015
SW846 8015
SW846 8015
110
20
20
20
20
Glycols
Ethylene Glycol
Propylene glycol
mg/L
mg/L
50
50
SW846 8015
SW846 8015
200 UJ
200 UJ
100 UJ
100 UJ
100 UJ
100 UJ
100 UJ
100 UJ
100 UJ
100 UJ
Acids
Acetic Acid
Butyric Acid
Propionic Acid
Volatile Acids
mg/L
mg/L
mg/L
mg/L
10
10
10
10
SW846 8015
SW846 8015
SW846 8015
20 UJ
20 UJ
20 UJ
300
1U
5 UJ
1U
100
33
1U
1U
120
33 J
10 UJ
10 UJ
600
33 J
10 UJ
10 UJ
600
J
UJJ
UJJ
UJ
UJ
J
UJ
UJ
UJ
UJ
28
10
10
10
10
J
UJ
UJ
UJ
UJ
7/15/2009
10/27/2009
0.95 U
0.98 U
20
10
10
10
10
20
10
10
10
10
J
UJ
UJ
UJ
UJ
J
UJ
UJ
UJ
UJ
PARAMETER
Acidity
Amenable cyanide
Ammonia Nitrogen
Bromide
Chloride
Fluoride
Hardness, as CaCO3
Nitrate as N
Nitrate-Nitrite
Nitrite as N
Oil & Grease (HEM)
Sulfate
TOC
Total Alkalinity
Total phosphorus
Turbidity
Cyanide, Total
Total Sulfide
pH
Sulfite
MBAS (mol.wt 320)
Aluminum
Aluminum-DISS
Antimony
Antimony-DISS
Arsenic
Arsenic-DISS
Barium
Barium-DISS
Beryllium
Beryllium-DISS
Boron
Boron-DISS
Cadmium
Cadmium-DISS
Calcium
Calcium-DISS
Chromium
Chromium-DISS
Cobalt
Cobalt-DISS
Copper
Copper-DISS
Iron
Iron-DISS
Lead
Lead-DISS
Lithium
Lithium-DISS
Magnesium
Magnesium-DISS
Manganese
Manganese-DISS
Molybdenum
Molybdenum-DISS
Nickel
Nickel-DISS
Potassium
Potassium-DISS
Selenium
Selenium-DISS
Silver
Silver-DISS
Day 0
Day 1
6/22/2009
6/23/2009
UNITS
PQL
US EPA Method
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
umhos/cm
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
NTU
ug/L
mg/L
No Units
mg/L
mg/L
mg/L
5
0.01
0.1
2
1
10
1
-1
5
0.05
0.1
0.05
5
-1
1
5
10
3
0.1
4
-10
3
-0.01
1
0.05
SM20 2310B (4a)

SM18 4500-CN E
MCAWW 350.1
SM18 5210 B
MCAWW 300.0A
MCAWW 410.4
MCAWW 300.0A
SM20 5310B
MCAWW 300.0A
SM20 2340C
MCAWW 300.0A
MCAWW 353.2
MCAWW 300.0A
CFR136A 1664A HEM
MCAWW 120.1
MCAWW 300.0A
SM20 5310B
SM18 2320 B
SM18 2540 C
MCAWW 351.3
MCAWW 365.2
SM20 2540D
MCAWW 180.1
SW846 9012A
SW846 9030B/9034
SW846 9040
SW846 9066
SM4500-SO3 B
SM5540 C
5
0.01
0.58
271
10
1990
18
452
2.5
34
2.5
0.13
2.5
134
192
11
173
60.4
481
27.2
0.63
732
650
46.4
3
7.2
0.035
14.0
0.03
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
200
200
10
10
10
10
200
200
4
4
2000
2000
5
5
5000
5000
5
5
500
500
25
25
100
100
3
3
500
500
5000
5000
150
150
400
400
40
40
5000
5000
5
5
5
5
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
430
2000
100
100
100
100
67.5
78.6
3
40
2000
2000
50
50
7200
5450
704
50
11.9
500
40.5
250
7500
468
30
1.3
500
500
1490
1090
104
150
91.8
400
440
400
50000
50000
50
50
50
50
U
NR U
GU
B
GU
GU
GU
J
B
J
B
U
U
U
U
U
B
B
B
U
U
U
U
U
BJ
BJ
U
B
U
B
U
J
B
U
B
U
U
B
B
BJ
U
B
U
U
U
U
U
U
U
U
5
0.01
13.4
692
72.7
1660
7060
540
0.5
1500
0.5
0.035
3.8
5
29800
25.3
604
577
15100
44.7
1.4
36.8
10
22.9
3
7.1
0.027
10.8
0.0505
608
655
24.8
26.8
55.1
62.4
36500
33700
40
40
7850
9150
50
50
430000
494000
31
32
500
500
250
250
16700
18200
54.7
39.9
9500
11300
37500
43200
1280
1420
23.6
25.2
22
22.6
25100
31200
50
50
50
50
Location R
Tyler County, WV
Day 5
7/13/2009
U
NR U
GU
GU
B
U
J
J
J
B
B
B
B
B
B
U
U
U
U
J
J
B
B
U
U
U
U
J
B
B
J
B
B
B
B
B
B
U
U
U
U
5
0.01
41.1
1250
272
3200
32100
501
2.5
8300
2.5
0.053
11.8
655
98400
34.5
388
327
46900
65.6
0.96
1180
1540
18.5
5.6
6.7
0.046
11.6
1.52
1870
2000
39.7
100
43
40.2
686000
603000
40
40
17300
17100
2.2
50
2560000
2610000
152
67.4
500
500
4150
274
172000
93100
606
30
37700
36100
283000
287000
4030
3440
147
104
67
19.9
109000
111000
50
50
50
50
U
NR U
J
J
GU
GU
BJ
J
BJ
J
J
B
U
B
U
B
B
U
U
B
U
J
J
U
U
J
B
B
B
B
U
U
U
U
Day 14
Day 90
7/7/2009
10/28/2009
408
0.01
15
6.2
113
1760
12300
343
0.5
4000
0.5
0.038
3.8
96.1
41500
10
323
85.2
20900
30.5
0.87
286
233
7.3
3.2
4.9
0.059
13.2
1.66
1900
426
100
100
100
100
296000
251000
40
40
5330
5130
50
50
1190000
1130000
65.5
40
500
500
518
387
214000
183000
25.2
30
12500
12100
133000
126000
5100
4780
23.1
400
98.3
93.3
46500
39400
50
50
50
50
GU
GU
B
J
GU
J
B
BJ
U
U
U
U
U
U
U
U
J
J
B
U
U
B
U
BJ
U
B
B
B
B
U
U
U
U
133
0.01
273
1410
809
30600
82200
1560
5
61000
5
0.11
5
469
285000
34.7
1320
64.8
144000
277
0.11
918
1480
4.4
3
5.9
0.027
NA
NA
564
272
100
100
100
100
3770000
3940000
40
40
16900
17900
50
5.5
11000000
11500000
25.6
50
5000
5000
218
107
140000
51600
59.8
30
85400
88700
1150000
1230000
7910
8300
400
400
400
400
321000
347000
50
50
50
50
U
J
J
GU
GU
GU
BJ
J
BG
BJ
U
BJ
BJ
U
U
U
U
U
U
J
U
B
B
U
U
U
B
B
U
J
U
U
U
U
U
U
U
U
Day 0
PARAMETER
Sodium
Sodium-DISS
Strontium
Strontium-DISS
Thallium
Thallium-DISS
Tin
Tin-DISS
Titanium
Titanium-DISS
Trivalent Chrom
Zinc
Zinc-DISS
Hexavalent Chromium
Mercury
Mercury-DISS
1,1-Dichloroethane
1,1-Dichloroethene
1,1-Dichloropropene
1,2-Dichlorobenzene
1,2-Dichloroethane
1,2-Dichloropropane
1,3-Dichlorobenzene
1,3-Dichloropropane
1,4-Dichlorobenzene
1,4-Dioxane
2,2-Dichloropropane
2-Butanone
2-Hexanone
4-Chlorotoluene
Acetone
Acrolein
Acrylonitrile
Benzene
Benzyl chloride
Bromobenzene
Bromoform
Bromomethane
Carbon disulfide
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
Dibromomethane
Ethylbenzene
Isopropylbenzene
Methylene chloride
Naphthalene
n-Butylbenzene
n-Propylbenzene
p-Isopropyltoluene
sec-Butylbenzene
Styrene
UNITS
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
mg/L
mg/L
ug/L
ug/L
PQL
5000
5000
50
50
10
10
1000
1000
500
500
50
20
20
0.01
0.01
0.2
0.2
US EPA Method
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 7196A
SW846 7196A
SW846 7470A
SW846 7470A
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
1000
-5
5
10
5
5
5
20
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
6/22/2009
33300
41900
58.5
73.9
100
100
1000
1000
39.1
22.9
50
67.9
52
0.25
0.25
0.065
0.2
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
1000
#N/A
5
5
10
5
5
5
25
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
1
0.95
5
5
5
5
5
5
5
5
Location R
Tyler County, WV
Day 5
Day 1
B
B
BJE
BJE
U
U
U
U
B
B
U
B
BJ
GU
U
BJ
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
J
U
U
U
U
U
U
U
U
6/23/2009
4280000
4970000
43100
50400
100
25.1
1000
1000
26.3
34.5
32
56.1
61.2
0.05
0.05
0.2
0.2
5
5
5
5
5
5
5
5
5
5
8.1
5
5
5
5
5
5
5
5
5
1000
NA
5
8.1
10
5
5
5
100
100
9.1
4.2
5
5
5
5
5
5
5
5
5
5
150
5
5
5
5
5
1.4
5
5
5
14
5
5
5
5
5
J
J
U
B
U
U
B
B
B
B
BJ
GU
GU
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
ND U
U
U
U
U
U
U
J
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
7/13/2009
16900000
16800000
387000
364000
100
30.5
1000
1000
107
35
67.4
740
122
0.5
0.5
0.2
0.2
5
5
5
5
5
5
5
5
5
5
4
5
5
5
5
5
5
5
5
5
1000
NA
5
5
10
5
5
5
30
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
2.2
2.1
5
5
5
5
5
J
J
U
B
U
U
B
B
BJ
GU
GU
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
J
U
U
U
U
U
Day 14
7/7/2009
5970000
5680000
175000
163000
100
100
23.5
1000
500
500
65.5
1290
1160
0.1
0.25
0.2
0.2
5
5
5
5
5
5
5
5
5
5
3.7
5
5
5
5
5
1
5
5
5
1000
NA
5
5
10
5
5
5
42
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
0.66
5
5
5
5
5
Day 90
J
J
U
U
B
U
U
U
GU
GU
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
10/28/2009
38600000
39900000
1960000
2070000
100
100
1000
26.7
500
500
50
510
471
1
0.38
0.2
0.2
5
5
5
5
5
5
5
5
5
5
1.1
5
5
5
5
5
5
5
5
5
1000
NA
5
5
10
5
5
5
20
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
J
J
J
U
U
U
B
U
U
U
J
J
GU
B
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Day 0
PARAMETER
tert-butyl acetate
tert-Butylbenzene
Tetrachloroethene
tetrahydrofuran
Toluene
Trichloroethene
Vinyl acetate
Vinyl chloride
Xylenes (total)
1,3-Dinitrobenzene
1,4-Naphthoquinone
1-Naphthylamine
2,3,7,8-TCDD
2,4-Dimethylphenol
2,4-Dinitrophenol
2,4-Dinitrotoluene
2,6-Dichlorophenol
2,6-Dinitrotoluene
2-Chloronaphthalene
2-Chlorophenol
2-Methylnaphthalene
2-Methylphenol
2-Naphthylamine
2-Nitroaniline
2-Nitrophenol
2-Picoline
3-Nitroaniline
4-Aminobiphenyl
4-Chloroaniline
4-Nitroaniline
4-Nitrophenol
5-Nitro-o-toluidine
Acenaphthene
Acenaphthylene
Acetophenone
Aniline
Aramite
Benzidine
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(ghi)perylene
Benzyl alcohol
Chlorobenzilate
Chrysene
Diallate
Dibenzofuran
Diethyl phthalate
Dimethoate
Dimethyl phthalate
UNITS
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
PQL
-5
5
-5
5
5
5
5
5
5
15
US EPA Method
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
10
2
10
10
10
10
-10
10
10
40
10
2
10
10
2
10
2
10
10
50
10
10
10
10
10
50
50
10
10
10
10
10
50
50
100
10
2
2
10
10
10
200
10
5
2
2
2
10
10
2
2
10
10
10
2
10
2
10
10
10
10
10
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
Location R
Tyler County, WV
Day 5
Day 1
6/22/2009
NA
5
1.4
NA
1.2
5
5
5
5
5
5
8.4
10
2
10
10
10
10
NA
10
10
10
50
10
2
10
10
2
10
2
10
10
50
10
5.3
10
10
10
50
50
10
10
10
10
10
50
50
100
10
2
2
10
10
10
200
2
2
2
2
2
10
10
2
2
21
10
10
2
10
2
10
10
10
10
1
U
J
J
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
6/23/2009
NA
5
5
NA
3.2
5
5
5
5
5
5
13
11
2.2
11
11
11
11
NA
11
11
11
55
11
2.2
11
11
2.2
11
3.1
11
11
55
11
25
11
11
11
55
55
11
11
11
11
11
55
55
110
11
2.2
2.2
4.9
11
11
220
2.2
2.2
2.2
2.2
2.2
11
11
2.2
2.2
11
11
11
2.2
11
2.2
11
11
11
11
11
U
U
J
U
U
U
U
U
U
J
U
U
U
U
U
U
ND U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
7/13/2009
NA
5
5
NA
2.5
5
5
5
5
5
5
6
19
3.8
19
19
19
19
NA
19
19
19
94
19
3.8
19
19
3.8
19
3.8
19
19
94
19
19
19
19
19
94
94
19
19
19
19
19
94
94
190
19
3.8
3.8
22
19
19
380
3.8
3.8
3.8
3.8
3.8
19
19
3.8
3.8
8.7
19
19
3.8
19
3.8
19
19
19
19
19
U
U
J
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
Day 14
Day 90
7/7/2009
NA
5
5
NA
1.3
5
5
5
5
5
5
6.6
10/28/2009
94
19
94
94
94
94
NA
94
94
94
470
94
19
94
94
19
94
120
94
94
470
94
94
94
94
94
470
470
94
94
94
94
94
470
470
940
94
19
19
94
94
94
1900
19
19
19
19
19
750
94
19
19
49
94
94
19
94
19
94
94
94
94
94
U
U
J
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
NA
5
5
NA
5
5
5
5
5
5
5
15
190
38
190
190
190
190
NA
190
190
190
950
190
38
190
190
38
190
38
190
190
950
190
190
190
190
190
950
950
190
190
190
190
190
950
950
1900
190
38
38
190
190
190
3800
38
38
38
38
38
190
190
38
38
58
190
190
38
190
38
190
190
190
190
190
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
JB
U
U
U
U
U
U
U
U
U
U
Day 0
PARAMETER
Dinoseb
Diphenylamine
Disulfoton
Fluoranthene
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hexachloroethane
Hexachloropropene
Isodrin
Isophorone
Isosafrole
Nitrobenzene
N-Nitrosomorpholine
N-Nitrosopiperidine
o-Toluidine
Parathion
Pentachlorobenzene
Pentachloroethane
Pentachlorophenol
Phenanthrene
Phenol
Phorate
Pronamide
Pyrene
Pyridine
Safrole
Thionazin
UNITS
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
PQL
10
10
2
10
10
2
2
0.05
2
2
10
10
2
10
10
10
10
2
10
10
10
2
2
10
10
10
10
10
10
10
10
10
20
10
10
2
2
10
10
2
10
10
10
10
US EPA Method
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
4,4'-DDD
4,4'-DDE
4,4'-DDT
Aldrin
alpha-BHC
beta-BHC
delta-BHC
Dieldrin
Endosulfan I
Endosulfan II
Endosulfan sulfate
Endrin
Endrin aldehyde
Endrin ketone
gamma-BHC (Lindane)
Heptachlor
Heptachlor epoxide
Methoxychlor
Toxaphene
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.1
2
PCBs
Aroclor 1016
Aroclor 1221
Aroclor 1232
Aroclor 1242
Aroclor 1248
Aroclor 1254
Aroclor 1260
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
0.4
0.4
0.4
0.4
0.4
0.4
0.4
Location R
Tyler County, WV
Day 5
Day 1
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
6/23/2009
11
11
2.2
11
11
2.2
2.2
2.2
2.2
11
11
11
2.2
11
11
11
11
2.2
11
11
11
2.2
2.2
11
11
11
11
11
11
11
11
11
22
11
11
2.2
2.2
11
11
2.2
31
11
11
NA
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
0.05
0.05
0.05
0.05
0.05
0.05
0.5
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.1
2
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.048
0.72
0.048
0.048
0.048
0.87
0.48
0.4
0.31
0.048
0.28
0.048
0.32
0.048
0.048
0.96
0.49
0.22
0.096
1.9
SW846 8082
SW846 8082
SW846 8082
SW846 8082
SW846 8082
SW846 8082
SW846 8082
0.4
0.4
0.4
0.4
0.4
0.4
0.4
U
U
U
U
U
U
U
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.38
0.38
0.38
0.38
8
0.38
0.38
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
7/13/2009
19
19
3.8
19
19
3.8
3.8
3.8
3.8
19
19
19
3.8
19
19
19
19
3.8
19
19
19
3.8
3.8
19
19
19
19
19
19
19
19
19
38
19
19
3.8
3.8
19
19
3.8
10
19
19
NA
Day 14
6/22/2009
10
10
2
10
10
2
2
2
2
10
10
10
2
10
10
10
10
2
10
10
10
2
2
10
10
10
10
10
10
10
10
10
20
10
10
2
2
10
10
2
4.1
10
10
NA
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
7/7/2009
94
94
19
94
94
19
19
19
19
94
94
94
19
94
94
94
94
19
94
94
94
19
19
94
94
94
94
94
94
94
94
94
190
94
94
22
19
94
94
13
94
94
94
NA
Day 90
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
PG
U
PG
PG
U
PG
U
PG
U
U
PG
PG
U
U
U
U
U
U
U
U
10/28/2009
190
190
38
190
190
4.1
38
38
38
190
190
190
38
190
190
190
190
38
190
190
190
38
38
190
190
190
190
190
190
190
190
190
380
190
190
29
38
190
190
24
190
190
190
NA
0.25
0.25
0.25
0.25
0.25
0.41
2.5
0.25
0.25
1.8
0.25
0.25
0.25
0.25
0.25
0.34
0.41
0.31
0.5
10
0.4
0.4
0.4
0.4
0.4
0.4
0.4
U
U
U
U
U
JB
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
JB
U
U
U
JB
U
U
U
U
U
U
U
U
PG
U
U
U
PG
U
U
U
U
U
PG
U
U
U
U
U
U
U
U
U
PARAMETER
Day 0
Day 1
6/22/2009
6/23/2009
Location R
Tyler County, WV
Day 5
UNITS
PQL
US EPA Method
Ethyl parathion
ug/L
0.4
SW846 8141A
0.96 U
NA
Alcohols
2-Propanol
Butyl alcohol
Ethanol
Methanol
n-Propanol
mg/L
mg/L
mg/L
mg/L
mg/L
10
10
10
10
10
SW846 8015
SW846 8015
SW846 8015
SW846 8015
SW846 8015
57
20
20
20
20
41
10
10
220
10
Glycols
Ethylene Glycol
Propylene glycol
mg/L
mg/L
50
50
SW846 8015
SW846 8015
200 U
200 U
100 U
100 U
Acids
Acetic Acid
Butyric Acid
Propionic Acid
Volatile Acids
mg/L
mg/L
mg/L
mg/L
10
10
10
10
SW846 8015
SW846 8015
SW846 8015
10 UJ
10 UJ
10 UJ
300
39
1U
1U
100
J
UJ
UJ
UJ
UJ
7/13/2009
NA
J
UJ
UJ
J
UJ
Day 14
Day 90
7/7/2009
10/28/2009
0.95 U
0.99 U
11
10
10
44
10
J
UJ
UJ
J
UJ
NA
NA
NA
NA
NA
200 UJ
200 UJ
100 UJ
100 UJ
NA
NA
50 UJ
50 UJ
50 UJ
250
450 J
1U
1U
600
NA
NA
NA
NA
57
20
20
380
20
J
UJ
UJ
J
UJ
PARAMETER
Acidity
Amenable cyanide
Ammonia Nitrogen
Bromide
Chloride
Fluoride
Hardness, as CaCO3
Nitrate as N
Nitrate-Nitrite
Nitrite as N
Oil & Grease (HEM)
Sulfate
TOC
Total Alkalinity
Total phosphorus
Turbidity
Cyanide, Total
Total Sulfide
pH
Sulfite
MBAS (mol.wt 320)
Aluminum
Aluminum-DISS
Antimony
Antimony-DISS
Arsenic
Arsenic-DISS
Barium
Barium-DISS
Beryllium
Beryllium-DISS
Boron
Boron-DISS
Cadmium
Cadmium-DISS
Calcium
Calcium-DISS
Chromium
Chromium-DISS
Cobalt
Cobalt-DISS
Copper
Copper-DISS
Iron
Iron-DISS
Lead
Lead-DISS
Lithium
Lithium-DISS
Magnesium
Magnesium-DISS
Manganese
Manganese-DISS
Molybdenum
Molybdenum-DISS
Nickel
Nickel-DISS
Potassium
Potassium-DISS
Selenium
Selenium-DISS
Silver
Silver-DISS
Location S
Centre County, PA
Day 1
Supply Water
Day 0
8/25/2009
8/25/2009
UNITS
PQL
US EPA Method
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
umhos/cm
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
NTU
ug/L
mg/L
No Units
mg/L
mg/L
mg/L
5
0.01
0.1
2
1
10
1
-1
5
0.05
0.1
0.05
5
-1
1
5
10
3
0.1
4
-10
3
-0.01
1
0.05
SM20 2310B (4a)

SM18 4500-CN E
MCAWW 350.1
SM18 5210 B
MCAWW 300.0A
MCAWW 410.4
MCAWW 300.0A
SM20 5310B
MCAWW 300.0A
SM20 2340C
MCAWW 300.0A
MCAWW 353.2
MCAWW 300.0A
CFR136A 1664A HEM
MCAWW 120.1
MCAWW 300.0A
SM20 5310B
SM18 2320 B
SM18 2540 C
MCAWW 351.3
MCAWW 365.2
SM20 2540D
MCAWW 180.1
SW846 9012A
SW846 9030B/9034
SW846 9040
SW846 9066
SM4500-SO3 B
SM5540 C
5
0.01
0.52
2
0.2
18.4
28.1
2.3
0.05
156
1.8
3
0.05
4.6
466
8.4
2.7
88.8
277
3
0.1
4
1.7
10
3.2
7
0.0065
11.2
0.0969
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
200
200
10
10
10
10
200
200
4
4
2000
2000
5
5
5000
5000
5
5
500
500
25
25
100
100
3
3
500
500
5000
5000
150
150
400
400
40
40
5000
5000
5
5
5
5
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
177
2000
15.4
100
100
100
840
734
40
40
18.9
15.8
1.7
2
40100
37500
50
50
500
500
250
250
394
1000
30
30
500
42.1
18300
17000
8.7
150
400
400
400
400
2930
3090
50
50
50
50
U
U
J
U
U
J
J
U
U
U
J
J
U
U
U
U
B
U
B
U
U
U
B
B
U
U
B
B
B
B
BJ
BJ
U
U
U
U
U
U
B
U
U
U
U
B
B
B
B
U
U
U
U
U
B
B
U
U
U
U
5
0.01
3
2220
0.2
4810
58.5
906
0.05
156
2.6
3.1
0.06
158
480
32.6
931
109
280
42.3
0.082
200
308
3.5
3
7.2
0.044
20
0.05
623
203
16.8
100
100
100
410
346
40
40
17.8
13.8
2.1
50
35200
36000
50
50
4.4
5.4
109
123
1790
726
30
30
42
31.1
15700
16200
37.9
30.5
400
400
400
400
2420
2590
50
50
50
50
8/25/2009
U
U
J
U
J
J
U
B
U
B
B
B
U
U
U
B
B
U
U
B
B
B
U
BJ
BJ
U
U
B
B
B
B
B
U
U
B
B
B
B
B
B
U
U
U
U
B
B
U
U
U
U
5
0.01
2.8
1440
0.2
3420
64.2
657
0.077
156
2.7
2.8
0.045
13.7
479
17.7
672
123
680
47.5
0.037
142
300
6.6
3
7.9
0.048
15.2
0.0613
507
165
100
13.5
100
100
332
240
40
40
18.1
14.2
2.2
1.3
35200
37800
7.5
50
5.7
6.2
43.9
37.2
6490
1670
30
30
500
500
16000
17300
146
119
14.2
400
16.7
400
2690
3000
50
50
50
50
U
U
J
U
J
J
B
J
B
U
B
B
U
B
U
U
B
B
U
U
B
B
B
B
BJ
BJ
B
U
B
B
B
B
U
U
U
U
B
B
B
B
B
U
B
U
B
B
U
U
U
U
Day 5
Day 14
8/29/2009
9/8/2009
22.9
0.01
44.8
218
306
1810
36800
217
1.2
15400
1.2
1.2
10.3
7.5
116000
2.4
104
175
58300
75.9
0.053
62
293
10
3
6.4
0.021
38.0
0.189
152
2000
31.3
24.1
100
100
652000
712000
40
40
7920
8950
3.8
50
4080000
4510000
50
50
500
500
71.4
55
77900
34700
21.2
30
34800
37800
373000
412000
1850
2030
39.1
26.8
19
400
301000
354000
50
50
50
50
U
J
J
GU
GU
J
J
BJ
J
U
U
B
U
B
B
U
U
U
U
B
U
J
J
U
U
U
U
B
B
B
U
B
B
B
U
U
U
U
U
90.2
0.01
128
990
602
21900
79000
214
2.5
34000
0.43
0.41
2.5
36.2
266000
33.5
150
74.2
124000
116
0.035
51
460
7.4
1.6
6.6
0.1
9.20
0.0945
2000
2000
49.1
100
100
100
1500000
1510000
40
40
13600
14000
3.9
3
11800000
12000000
10.2
50
2500
2500
35.3
38.8
73200
34000
21.7
30
94900
9310
987000
1000000
2670
2680
400
400
400
400
1020000
1050000
50
50
50
50
U
J
J
GU
B
GU
J
BJ
J
B
B
U
U
B
U
U
U
U
U
B
B
J
J
B
U
U
U
B
B
B
U
U
U
U
U
U
U
U
U
Supply Water
PARAMETER
Sodium
Sodium-DISS
Strontium
Strontium-DISS
Thallium
Thallium-DISS
Tin
Tin-DISS
Titanium
Titanium-DISS
Trivalent Chrom
Zinc
Zinc-DISS
Hexavalent Chromium
Mercury
Mercury-DISS
1,1-Dichloroethane
1,1-Dichloroethene
1,1-Dichloropropene
1,2-Dichlorobenzene
1,2-Dichloroethane
1,2-Dichloropropane
1,3-Dichlorobenzene
1,3-Dichloropropane
1,4-Dichlorobenzene
1,4-Dioxane
2,2-Dichloropropane
2-Butanone
2-Hexanone
4-Chlorotoluene
Acetone
Acrolein
Acrylonitrile
Benzene
Benzyl chloride
Bromobenzene
Bromoform
Bromomethane
Carbon disulfide
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
Dibromomethane
Ethylbenzene
Isopropylbenzene
Methylene chloride
Naphthalene
n-Butylbenzene
n-Propylbenzene
p-Isopropyltoluene
sec-Butylbenzene
Styrene
UNITS
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
mg/L
mg/L
ug/L
ug/L
PQL
5000
5000
50
50
10
10
1000
1000
500
500
50
20
20
0.01
0.01
0.2
0.2
US EPA Method
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 7196A
SW846 7196A
SW846 7470A
SW846 7470A
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
1000
-5
5
10
5
5
5
20
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
Location S
Centre County, PA
Day 1
Day 0
8/25/2009
37700
35300
723
653
100
100
1000
1000
500
500
50
172
156
0.01
0.01
0.2
0.2
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
1000
NA
5
5
10
5
5
5
20
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
B
B
E
JE
U
U
U
U
U
U
U
BJ
BJ
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
8/25/2009
60800
71800
597
624
100
100
1000
1000
500
500
50
164
140
0.0078
0.05
0.2
0.2
5
5
5
5
5
5
5
5
5
5
11
5
5
5
5
5
2.8
5
5
5
1000
NA
5
5
10
5
5
5
5.4
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
0.81
5
5
5
5
5
5
5
5
5
J
U
U
U
U
U
U
U
BJ
BJ
B
GU
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
Day 5
8/25/2009
63800
69200
580
594
100
100
1000
1000
500
500
50
138
73.8
0.05
0.05
0.2
0.2
5
5
5
5
5
5
5
5
5
5
33
5
5
5
5
5
13
5
5
5
1000
NA
5
5
10
5
5
5
14
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
1.8
5
5
5
1.8
5
5
5
5
5
J
U
U
U
U
U
U
U
BJ
BJ
GU
GU
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
J
U
U
U
U
U
8/29/2009
16400000
18000000
1560000
1710000
24.6
100
1000
1000
500
500
50
343
238
0.5
0.42
0.2
0.049
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
10000
NA
50
50
100
50
50
50
1300
1000
1000
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
28
50
50
Day 14
J
B
U
U
U
U
U
U
J
J
GU
BG
U
BJ
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
9/8/2009
32700000
33000000
5020000
4930000
100
100
20.7
1000
500
500
50
604
673
0.5
0.25
0.2
0.2
5
5
5
5
5
5
5
6.5
5
1.5
3.9
5
5
5
5
5
1.1
5
5
5
1000
NA
5
5
10
5
5
5
31
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
2.8
5
5
5
5
5
J
U
U
B
U
U
U
U
J
J
GU
GU
U
U
U
U
U
U
U
U
U
U
J
J
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
PARAMETER
tert-butyl acetate
tert-Butylbenzene
Tetrachloroethene
tetrahydrofuran
Toluene
Trichloroethene
Vinyl acetate
Vinyl chloride
Xylenes (total)
1,3-Dinitrobenzene
1,4-Naphthoquinone
1-Naphthylamine
2,3,7,8-TCDD
2,4-Dimethylphenol
2,4-Dinitrophenol
2,4-Dinitrotoluene
2,6-Dichlorophenol
2,6-Dinitrotoluene
2-Chloronaphthalene
2-Chlorophenol
2-Methylnaphthalene
2-Methylphenol
2-Naphthylamine
2-Nitroaniline
2-Nitrophenol
2-Picoline
3-Nitroaniline
4-Aminobiphenyl
4-Chloroaniline
4-Nitroaniline
4-Nitrophenol
5-Nitro-o-toluidine
Acenaphthene
Acenaphthylene
Acetophenone
Aniline
Aramite
Benzidine
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(ghi)perylene
Benzyl alcohol
Chlorobenzilate
Chrysene
Diallate
Dibenzofuran
Diethyl phthalate
Dimethoate
Dimethyl phthalate
UNITS
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
PQL
-5
5
-5
5
5
5
5
5
5
15
US EPA Method
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
10
2
10
10
10
10
-10
10
10
40
10
2
10
10
2
10
2
10
10
50
10
10
10
10
10
50
50
10
10
10
10
10
50
50
100
10
2
2
10
10
10
200
10
5
2
2
2
10
10
2
2
10
10
10
2
10
2
10
10
10
10
10
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
Supply Water
Day 0
8/25/2009
8/25/2009
NA
5
5
NA
5
5
5
5
5
5
5
15
9.4
1.9
9.4
9.4
9.4
9.4
NA
9.4
9.4
9.4
47
9.4
1.9
9.4
9.4
1.9
9.4
1.9
9.4
9.4
47
9.4
9.4
9.4
9.4
9.4
47
47
9.4
9.4
9.4
9.4
9.4
47
47
94
9.4
1.9
1.9
9.4
9.4
9.4
190
1.9
1.9
1.9
1.9
1.9
9.4
9.4
1.9
1.9
1.9
9.4
9.4
1.9
9.4
1.9
9.4
9.4
9.4
9.4
0.6
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
JB
U
U
U
U
U
U
U
U
U
J
Location S
Centre County, PA
Day 1
Day 5
8/25/2009
NA
5
5
NA
1.6
5
5
5
5
5
5
5.4
9.4
1.9
9.4
9.4
9.4
9.4
NA
9.4
9.4
9.4
47
9.4
1.9
9.4
9.4
1.9
9.4
1.9
9.4
9.4
47
9.4
9.4
9.4
9.4
9.4
47
47
9.4
9.4
9.4
9.4
9.4
47
47
94
9.4
1.9
1.9
9.4
9.4
9.4
190
1.9
1.9
1.9
1.9
1.9
9.4
9.4
1.9
1.9
14
9.4
9.4
1.9
9.4
1.9
9.4
9.4
9.4
9.4
2
U
U
J
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
NA
5
5
NA
3.8
5
5
5
5
5
5
16
9.4
1.9
9.4
9.4
9.4
9.4
NA
9.4
9.4
9.4
47
9.4
1.9
9.4
9.4
1.9
9.4
1.9
9.4
9.4
47
9.4
9.4
9.4
9.4
9.4
47
47
9.4
9.4
9.4
9.4
9.4
47
47
94
9.4
1.9
1.9
9.4
9.4
9.4
190
1.9
1.9
1.9
1.9
1.9
9.4
9.4
1.9
1.9
9.4
9.4
9.4
1.9
9.4
1.9
9.4
9.4
9.4
9.4
9.4
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
8/29/2009
NA
50
50
NA
50
50
50
50
50
50
50
150
94
19
94
94
94
94
NA
94
94
94
470
94
19
94
94
19
94
19
94
94
470
94
94
94
94
1.9
470
470
94
94
94
94
94
470
470
940
94
19
19
94
94
94
1900
19
19
19
19
19
94
94
19
19
94
94
94
19
94
19
94
7.7
94
94
94
Day 14
9/8/2009
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
JB
U
U
U
NA
5
5
NA
5
5
5
5
5
5
5
15
9.5
1.9
9.5
9.5
9.5
9.5
NA
9.5
9.5
9.5
48
9.5
1.9
9.5
9.5
1.9
9.5
1.9
9.5
9.5
48
9.5
9.5
9.5
9.5
9.5
48
48
9.5
9.5
9.5
9.5
9.5
48
48
95
9.5
1.9
1.9
9.5
9.5
9.5
190
1.2
1.1
1
1.2
0.91
9.5
9.5
1.9
1.9
7.5
9.5
9.5
1.1
9.5
2.3
9.5
2.6
9.5
9.5
1.5
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
J
J
J
J
U
U
U
U
JB
U
U
J
U
U
JB
U
U
J
PARAMETER
Dinoseb
Diphenylamine
Disulfoton
Fluoranthene
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hexachloroethane
Hexachloropropene
Isodrin
Isophorone
Isosafrole
Nitrobenzene
N-Nitrosomorpholine
N-Nitrosopiperidine
o-Toluidine
Parathion
Pentachlorobenzene
Pentachloroethane
Pentachlorophenol
Phenanthrene
Phenol
Phorate
Pronamide
Pyrene
Pyridine
Safrole
Thionazin
UNITS
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
PQL
10
10
2
10
10
2
2
0.05
2
2
10
10
2
10
10
10
10
2
10
10
10
2
2
10
10
10
10
10
10
10
10
10
20
10
10
2
2
10
10
2
10
10
10
10
US EPA Method
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
4,4'-DDD
4,4'-DDE
4,4'-DDT
Aldrin
alpha-BHC
beta-BHC
delta-BHC
Dieldrin
Endosulfan I
Endosulfan II
Endosulfan sulfate
Endrin
Endrin aldehyde
Endrin ketone
gamma-BHC (Lindane)
Heptachlor
Heptachlor epoxide
Methoxychlor
Toxaphene
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.1
2
PCBs
Aroclor 1016
Aroclor 1221
Aroclor 1232
Aroclor 1242
Aroclor 1248
Aroclor 1254
Aroclor 1260
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
0.4
0.4
0.4
0.4
0.4
0.4
0.4
Location S
Centre County, PA
Day 1
Supply Water
Day 0
8/25/2009
8/25/2009
Day 5
8/25/2009
9.4
9.4
1.9
9.4
9.4
1.9
1.9
1.9
1.9
9.4
9.4
9.4
1.9
9.4
9.4
9.4
9.4
1.9
9.4
9.4
9.4
1.9
1.9
9.4
9.4
9.4
9.4
9.4
9.4
9.4
9.4
9.4
19
9.4
9.4
1.9
1.9
9.4
9.4
1.9
9.4
9.4
9.4
NA
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
9.4
9.4
1.9
9.4
9.4
1.9
2
1.9
1.9
9.4
9.4
9.4
1.9
9.4
9.4
9.4
9.4
1.9
9.4
9.4
9.4
1.9
1.9
9.4
9.4
9.4
9.4
9.4
9.4
9.4
9.4
9.4
19
9.4
9.4
3.4
1.9
9.4
9.4
0.76
70
9.4
9.4
NA
U
U
U
U
U
U
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
0.047
0.047
0.047
0.047
0.047
0.047
0.47
0.047
0.047
0.047
0.047
0.047
0.047
0.047
0.047
0.047
0.051
0.047
0.094
1.9
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
0.047
0.047
0.047
0.047
0.047
0.047
0.47
0.047
0.047
0.047
0.047
0.047
0.047
0.047
0.047
0.041
0.063
0.047
0.094
1.9
SW846 8082
SW846 8082
SW846 8082
SW846 8082
SW846 8082
SW846 8082
SW846 8082
0.38
0.38
0.38
0.38
0.38
0.38
0.38
U
U
U
U
U
U
U
0.38
0.38
0.38
0.38
0.38
0.38
0.38
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
9.4
9.4
1.9
9.4
9.4
1.9
1.9
1.9
1.9
9.4
9.4
9.4
1.9
9.4
9.4
9.4
9.4
1.9
9.4
9.4
9.4
1.9
1.9
9.4
9.4
9.4
9.4
9.4
9.4
9.4
9.4
9.4
19
9.4
9.4
3.5
1.9
9.4
9.4
0.89
18
9.4
9.4
NA
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
Day 14
8/29/2009
94
94
19
94
94
19
19
19
19
94
94
94
19
94
94
94
94
19
94
94
94
19
19
94
94
94
94
94
94
94
94
94
190
94
94
19
19
94
94
19
530
94
94
NA
9/8/2009
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
9.3
9.5
1.7
9.5
9.5
1.3
1.4
1
1.9
9.5
9.5
9.5
2.4
9.5
9.5
9.5
9.5
1.9
9.5
9.5
9.5
1.9
1.7
9.5
9.5
9.5
9.5
9.5
9.5
9.5
9.5
9.5
19
9.5
9.5
1.3
1.9
9.5
9.5
1.1
280
9.5
9.5
NA
U
U
U
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.049
0.049
0.049
0.049
0.049
0.049
0.49
0.048
0.049
0.5
0.049
0.049
0.049
0.049
0.049
0.049
0.049
0.049
0.098
2
U
U
U
U
U
U
U
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.39
0.39
0.39
0.39
0.39
0.39
0.39
J
U
J
U
U
J
J
J
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
J
U
U
U
U
U
U
U
U
U
J PG
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
PARAMETER
Location S
Centre County, PA
Day 1
Supply Water
Day 0
8/25/2009
8/25/2009
Day 5
Day 14
8/29/2009
9/8/2009
UNITS
PQL
US EPA Method
Ethyl parathion
ug/L
0.4
SW846 8141A
0.94 U
Alcohols
2-Propanol
Butyl alcohol
Ethanol
Methanol
n-Propanol
mg/L
mg/L
mg/L
mg/L
mg/L
10
10
10
10
10
SW846 8015
SW846 8015
SW846 8015
SW846 8015
SW846 8015
10
10
10
10
10
Glycols
Ethylene Glycol
Propylene glycol
mg/L
mg/L
50
50
SW846 8015
SW846 8015
100 U
100 U
200 U
240
200 UJ
200 UJ
100 UJ
150 J
100 UJ
110 J
Acids
Acetic Acid
Butyric Acid
Propionic Acid
Volatile Acids
mg/L
mg/L
mg/L
mg/L
10
10
10
10
SW846 8015
SW846 8015
SW846 8015
1U
1U
1U
15
50 U
50 U
50 U
150
1.4
1U
1U
75
5.8 J
1U
2 UJ
600
6.6 J
2 UJ
2 UJ
600
U
U
U
U
U
8/25/2009
0.95 U
NA
310
20
20
20
20
150
20
20
20
20
U
U
U
U
NA
J
UJ
UJ
UJ
UJ
140
10
10
10
10
0.98 U
J
UJ
UJ
UJ
UJ
83
10
10
10
10
J
UJ
UJ
UJ
UJ
Appendix D
Summary of Detected VOCs, SVOC,
Pesticides and PCBs
49

Location B
Location A
PARAMETER
2-Butanone
Acetone
Acrolein
Acrylonitrile
Benzene
Bromoform
Bromomethane
Carbon disulfide
Chloroform
Chloromethane
Ethylbenzene
Isopropylbenzene
Methylene chloride
Naphthalene
n-Butylbenzene
n-Propylbenzene
p-Isopropyltoluene
sec-Butylbenzene
Tetrachloroethene
Toluene
Xylenes (total)
UNITS
PQL
US EPA Method
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
5
5
5
5
5
20
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
15
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
Day 0
2/7/2009
Day 1
2/8/2009
Day 5
2/11/2009
Day 14
2/20/2009
Day 0
1/26/2009
Day 1
1/29/2009
Day 5
2/2/2009
Day 14
2/10/2009
Day 90
4/29/2009
16 J
16
6
140 J
100 J
82
33
110 J
120
74
65
76
7.7
23 J
19 J
75 J B
8.5 J
240
1200
420
360
1500
28
19 J
14 J
24 J
18 J
84 J
5.1
18
NOTES
NA - Not Applicable
NR - Analytical data has not been reported by the laboratory to date.
ND - The constituent was not detected. The reported concentration is less than the laboratory detection limit.
J - The reported result is an estimated result. The result is less than the laboratory reporting limit.
E - The resported result is an estimated result.
81 J
210 J B
85 J
42 J
54 J
68 J
22 J
340
820
1100
21 J
660
300

Location C
PARAMETER
2-Butanone
Acetone
Acrolein
Acrylonitrile
Benzene
Bromoform
Bromomethane
Carbon disulfide
Chloroform
Chloromethane
Ethylbenzene
Isopropylbenzene
Methylene chloride
Naphthalene
n-Butylbenzene
n-Propylbenzene
p-Isopropyltoluene
sec-Butylbenzene
Tetrachloroethene
Toluene
Xylenes (total)
UNITS
PQL
US EPA Method
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
5
5
5
5
5
20
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
15
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
NOTES
NA - Not Applicable
ND - The constituent was not detected. The reported concentration is l
J - The reported result is an estimated result. The result is less than th
Day 0
2/11/2009
Day 1
2/17/2009
Location D
Day 5
Day 14
Day 0
Day 1
2/20/2009 2/27/2009 2/12/2009 2/13/2009
Day 5
2/17/2009
140 J
Location E
Day 90
5/13/09
Day 0
4/1/2009
Day1
4/3/2009
20
7.8
23000
1400
260
19
54000
7300
Day 5
Day 14
4/7/2009 4/17/2009
5.8
17
7.7
13
400
5.6

Loc G
Location F
PARAMETER
2-Butanone
Acetone
Acrolein
Acrylonitrile
Benzene
Bromoform
Bromomethane
Carbon disulfide
Chloroform
Chloromethane
Ethylbenzene
Isopropylbenzene
Methylene chloride
Naphthalene
n-Butylbenzene
n-Propylbenzene
p-Isopropyltoluene
sec-Butylbenzene
Tetrachloroethene
Toluene
Xylenes (total)
UNITS
PQL
US EPA Method
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
5
5
5
5
5
20
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
15
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
NOTES
NA - Not Applicable
Day 1
3/27/2009
11
5.2 J
Day 5
4/1/2009
52
33 J
14 J
280
7.6 J
Day 14
4/9/2009
33
21 J
Day 90
6/29/2009
170 J
66 J
980
820
98 J
880
29 J
400
23 J
920
340
540
280
Supply Water
4/7/2009
Day 0
4/7/2009
24000
11000
26
66000
290
23
Day 1
4/8/2009
Day 5
4/13/2009
4000
1900
630
280
5800
1600
1400
260
6.7
270
130 J
300
120
Location H
Day 14
4/22/2009
1600
3300
10000
5200 J
860 J
130 J
Day 14
4/22/2009
20

Location I
PARAMETER
2-Butanone
Acetone
Acrolein
Acrylonitrile
Benzene
Bromoform
Bromomethane
Carbon disulfide
Chloroform
Chloromethane
Ethylbenzene
Isopropylbenzene
Methylene chloride
Naphthalene
n-Butylbenzene
n-Propylbenzene
p-Isopropyltoluene
sec-Butylbenzene
Tetrachloroethene
Toluene
Xylenes (total)
UNITS
PQL
US EPA Method
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
5
5
5
5
5
20
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
15
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
NOTES
NA - Not Applicable
Day 0
5/9/2009
Day 1
5/15/2009
Location J
Day 5
Day 14
Day 0
5/19/2009 5/28/2009 5/1/2009
Day 1
5/4/2009
Location K
Day 5
5/8/2009
Day 14
Day 0
Day 1
Day 5
5/18/2009 05/07/2009 5/20/2009 5/22/2009
42
20
7.5
390
130
25
22 B
7.8
330
5.8
13 B
8.9 J
6.7
35
14
7.7
7.7
5.3

Location L
PARAMETER
2-Butanone
Acetone
Acrolein
Acrylonitrile
Benzene
Bromoform
Bromomethane
Carbon disulfide
Chloroform
Chloromethane
Ethylbenzene
Isopropylbenzene
Methylene chloride
Naphthalene
n-Butylbenzene
n-Propylbenzene
p-Isopropyltoluene
sec-Butylbenzene
Tetrachloroethene
Toluene
Xylenes (total)
UNITS
PQL
US EPA Method
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
5
5
5
5
5
20
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
15
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
NOTES
NA - Not Applicable
Supply Water
5/12/2009
Location M
Location N
Day 0
Day 1
Day 5
Day 14
Day 1
Day 14
5/13/2009 5/14/2009 5/18/2009 5/27/2009 6/6/2009 6/19/2009
27
14
38
32
39
Day 1
7/15/2009
Location O
Day 5
7/19/2009
770
670
99
260
17
220
86
Day 0
7/1/2009
67
7.7 J
21
50
Day 0
07/14/09
170
90 J
210
Day 1
7/1/2009
130 J
59
6.7 J
17 J
69 J
820
720
6.2
9.3
5.5 J
46
15
260
220
1500
2700
25 J
19 J
46 J
26 J

Location P
PARAMETER
2-Butanone
Acetone
Acrolein
Acrylonitrile
Benzene
Bromoform
Bromomethane
Carbon disulfide
Chloroform
Chloromethane
Ethylbenzene
Isopropylbenzene
Methylene chloride
Naphthalene
n-Butylbenzene
n-Propylbenzene
p-Isopropyltoluene
sec-Butylbenzene
Tetrachloroethene
Toluene
Xylenes (total)
UNITS
PQL
US EPA Method
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
5
5
5
5
5
20
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
15
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
NOTES
NA - Not Applicable
Day 1
7/15/2009
Day 5
7/20/2009
840
940
320
5200
140
2000
Location Q
Day 14
7/29/2009
710
770
Day 90
Day 0
10/29/2009 6/30/2009
200
230 J
5.9 J
650
160 J
470 J
120 J
46
90 J
92
32
6200
6500
5200
5400
Day 5
Day 14
7/6/2009 7/15/2009
84
79
190
1100
Day 1
7/1/2009
580
530
28
16 J
42
520

Location R
PARAMETER
2-Butanone
Acetone
Acrolein
Acrylonitrile
Benzene
Bromoform
Bromomethane
Carbon disulfide
Chloroform
Chloromethane
Ethylbenzene
Isopropylbenzene
Methylene chloride
Naphthalene
n-Butylbenzene
n-Propylbenzene
p-Isopropyltoluene
sec-Butylbenzene
Tetrachloroethene
Toluene
Xylenes (total)
UNITS
PQL
US EPA Method
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
5
5
5
5
5
20
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
15
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
NOTES
NA - Not Applicable
Location S
Day 0
Day 1
Day 5
Day 14
Day 0
Day 1
6/22/2009 6/23/2009 7/13/2009 7/7/2009 8/25/2009 8/25/2009
Day 5
8/29/2009
Day 14
9/8/2009
6.5
8.1
25
8.1
100
11
30
33
13
42
1300
150
14
28 J
16
31
Semi-Volatile Organic Compounds

Location A
PARAMETER
2,4-Dimethylphenol
2,6-Dichlorophenol
2-Methylnaphthalene
2-Methylphenol
2-Naphthylamine
2-Picoline
Acetophenone
Benzo(a)pyrene
Benzo(ghi)perylene
Benzyl alcohol
Diethyl phthalate
Fluoranthene
Fluorene
Hexachlorobenzene
Phenanthrene
Phenol
Phorate
Pyrene
Pyridine
UNITS
PQL
US EPA Method
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
10
2
2
10
10
10
10
10
10
5
2
2
2
10
2
10
2
10
10
10
2
2
0.05
2
2
2
2
10
2
10
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
Day 0
Day 1
2/7/2009
2/8/2009
Day 5
Day 14
Day 90
2/11/2009 2/20/2009 5/8/2009
35 J
2.7
86
2600
NOTES
NA - Not Applicable
ND - The constituent was not detected. The reported concentration is less than the laboratory detection limit.
J - The reported result is an estimated result. The result is less than the laboratory reporting limit.
1800
860
490

Location B
PARAMETER
2,4-Dimethylphenol
2,6-Dichlorophenol
2-Methylnaphthalene
2-Methylphenol
2-Naphthylamine
2-Picoline
Acetophenone
Benzo(a)pyrene
Benzo(ghi)perylene
Benzyl alcohol
Diethyl phthalate
Fluoranthene
Fluorene
Hexachlorobenzene
Phenanthrene
Phenol
Phorate
Pyrene
Pyridine
UNITS
PQL
US EPA Method
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
10
2
2
10
10
10
10
10
10
5
2
2
2
10
2
10
2
10
10
10
2
2
0.05
2
2
2
2
10
2
10
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
NOTES
NA - Not Applicable
ND - The constituent was not detected. The reported concentration is less than the la
J - The reported result is an estimated result. The result is less than the laboratory re
Day 0
Day 1
1/26/2009
1/29/2009
120
94
Day 5
Day 14
Day 90
2/2/2009 2/10/2009 4/29/2009
11
41 J
14
11
14
9.8
3.2
11 J
8.4 J
0.99 J
3.1
22 J
310
16 J
11 J
350
250
77
260

Location D
PARAMETER
2,4-Dimethylphenol
2,6-Dichlorophenol
2-Methylnaphthalene
2-Methylphenol
2-Naphthylamine
2-Picoline
Acetophenone
Benzo(a)pyrene
Benzo(ghi)perylene
Benzyl alcohol
Diethyl phthalate
Fluoranthene
Fluorene
Hexachlorobenzene
Phenanthrene
Phenol
Phorate
Pyrene
Pyridine
UNITS
PQL
US EPA Method
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
10
2
2
10
10
10
10
10
10
5
2
2
2
10
2
10
2
10
10
10
2
2
0.05
2
2
2
2
10
2
10
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
NOTES
NA - Not Applicable
Day 0
Day 1
Day 5
Day 90
2/12/2009
2/13/2009
2/17/2009
5/13/09
7.5
3.7
0.35 J
1.1 J
9.5
30
2.4
17

Location E
PARAMETER
2,4-Dimethylphenol
2,6-Dichlorophenol
2-Methylnaphthalene
2-Methylphenol
2-Naphthylamine
2-Picoline
Acetophenone
Benzo(a)pyrene
Benzo(ghi)perylene
Benzyl alcohol
Diethyl phthalate
Fluoranthene
Fluorene
Hexachlorobenzene
Phenanthrene
Phenol
Phorate
Pyrene
Pyridine
UNITS
PQL
US EPA Method
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
10
2
2
10
10
10
10
10
10
5
2
2
2
10
2
10
2
10
10
10
2
2
0.05
2
2
2
2
10
2
10
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
NOTES
NA - Not Applicable
Day 0
Day1
Day 5
Day 14
Day 90
4/1/2009
4/3/2009
4/7/2009
4/17/2009
4/17/2009
10
35
2.6 J
3.2
430
310
200
57

Location F
PARAMETER
2,4-Dimethylphenol
2,6-Dichlorophenol
2-Methylnaphthalene
2-Methylphenol
2-Naphthylamine
2-Picoline
Acetophenone
Benzo(a)pyrene
Benzo(ghi)perylene
Benzyl alcohol
Diethyl phthalate
Fluoranthene
Fluorene
Hexachlorobenzene
Phenanthrene
Phenol
Phorate
Pyrene
Pyridine
UNITS
PQL
US EPA Method
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
10
2
2
10
10
10
10
10
10
5
2
2
2
10
2
10
2
10
10
10
2
2
0.05
2
2
2
2
10
2
10
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
NOTES
NA - Not Applicable
Day 0
Day 1
Day 5
Day 14
Day 90
3/24/2009
3/27/2009
4/1/2009
4/9/2009
6/29/2009
11
12 J
11
33
870
14
3J
370
16
15
16
520
250
220
140

Location G
PARAMETER
2,4-Dimethylphenol
2,6-Dichlorophenol
2-Methylnaphthalene
2-Methylphenol
2-Naphthylamine
2-Picoline
Acetophenone
Benzo(a)pyrene
Benzo(ghi)perylene
Benzyl alcohol
Diethyl phthalate
Fluoranthene
Fluorene
Hexachlorobenzene
Phenanthrene
Phenol
Phorate
Pyrene
Pyridine
UNITS
PQL
US EPA Method
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
10
2
2
10
10
10
10
10
10
5
2
2
2
10
2
10
2
10
10
10
2
2
0.05
2
2
2
2
10
2
10
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
NOTES
NA - Not Applicable
Locaction H
Day1
Day 5
Day 14
Day 0
Day 5
Day 14
4/8/2009
4/13/2009
4/22/2009
4/7/2009
4/13/2009
4/22/2009
16
10
2.7
20
11
55
30
14

Location I
PARAMETER
2,4-Dimethylphenol
2,6-Dichlorophenol
2-Methylnaphthalene
2-Methylphenol
2-Naphthylamine
2-Picoline
Acetophenone
Benzo(a)pyrene
Benzo(ghi)perylene
Benzyl alcohol
Diethyl phthalate
Fluoranthene
Fluorene
Hexachlorobenzene
Phenanthrene
Phenol
Phorate
Pyrene
Pyridine
UNITS
PQL
US EPA Method
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
10
2
2
10
10
10
10
10
10
5
2
2
2
10
2
10
2
10
10
10
2
2
0.05
2
2
2
2
10
2
10
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
NOTES
NA - Not Applicable
Day 0
Day 1
Day 5
Day 90
5/9/2009
5/15/2009
5/19/2009
10/20/2009
41 J
6.7
10
6.9
5.9
17
11
5.5
6.1
9.5
640
310
42

Location J
PARAMETER
2,4-Dimethylphenol
2,6-Dichlorophenol
2-Methylnaphthalene
2-Methylphenol
2-Naphthylamine
2-Picoline
Acetophenone
Benzo(a)pyrene
Benzo(ghi)perylene
Benzyl alcohol
Diethyl phthalate
Fluoranthene
Fluorene
Hexachlorobenzene
Phenanthrene
Phenol
Phorate
Pyrene
Pyridine
UNITS
PQL
US EPA Method
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
10
2
2
10
10
10
10
10
10
5
2
2
2
10
2
10
2
10
10
10
2
2
0.05
2
2
2
2
10
2
10
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
NOTES
NA - Not Applicable
Location K
Day0
Day 1
Day 5
Day 14
Day 0
Day 14
5/1/2009
5/4/2009
5/8/2009
5/18/2009
05/07/2009
6/2/2009
13
6.9
11
7.4
6.7
4300
18
17
9.6
12
130
10
2.7
150

Location L
Day 0
PARAMETER
2,4-Dimethylphenol
2,6-Dichlorophenol
2-Methylnaphthalene
2-Methylphenol
2-Naphthylamine
2-Picoline
Acetophenone
Benzo(a)pyrene
Benzo(ghi)perylene
Benzyl alcohol
Diethyl phthalate
Fluoranthene
Fluorene
Hexachlorobenzene
Phenanthrene
Phenol
Phorate
Pyrene
Pyridine
UNITS
PQL
US EPA Method
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
10
2
2
10
10
10
10
10
10
5
2
2
2
10
2
10
2
10
10
10
2
2
0.05
2
2
2
2
10
2
10
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
NOTES
NA - Not Applicable
5/13/2009
Day 1
Day 5
5/14/2009
5/18/2009
16
5.5
10

Location M
PARAMETER
2,4-Dimethylphenol
2,6-Dichlorophenol
2-Methylnaphthalene
2-Methylphenol
2-Naphthylamine
2-Picoline
Acetophenone
Benzo(a)pyrene
Benzo(ghi)perylene
Benzyl alcohol
Diethyl phthalate
Fluoranthene
Fluorene
Hexachlorobenzene
Phenanthrene
Phenol
Phorate
Pyrene
Pyridine
UNITS
PQL
US EPA Method
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
10
2
2
10
10
10
10
10
10
5
2
2
2
10
2
10
2
10
10
10
2
2
0.05
2
2
2
2
10
2
10
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
NOTES
NA - Not Applicable
Location N
Day 1
Day 5
Day 14
Day 1
6/6/2009
6/10/2009
6/19/2009
7/15/2009
2.5
140
100
94

Location O
PARAMETER
2,4-Dimethylphenol
2,6-Dichlorophenol
2-Methylnaphthalene
2-Methylphenol
2-Naphthylamine
2-Picoline
Acetophenone
Benzo(a)pyrene
Benzo(ghi)perylene
Benzyl alcohol
Diethyl phthalate
Fluoranthene
Fluorene
Hexachlorobenzene
Phenanthrene
Phenol
Phorate
Pyrene
Pyridine
UNITS
PQL
US EPA Method
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
10
2
2
10
10
10
10
10
10
5
2
2
2
10
2
10
2
10
10
10
2
2
0.05
2
2
2
2
10
2
10
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
NOTES
NA - Not Applicable
Day 0
Day 1
7/1/2009
7/1/2009
260
52
3.5 J

Location P
PARAMETER
2,4-Dimethylphenol
2,6-Dichlorophenol
2-Methylnaphthalene
2-Methylphenol
2-Naphthylamine
2-Picoline
Acetophenone
Benzo(a)pyrene
Benzo(ghi)perylene
Benzyl alcohol
Diethyl phthalate
Fluoranthene
Fluorene
Hexachlorobenzene
Phenanthrene
Phenol
Phorate
Pyrene
Pyridine
UNITS
PQL
US EPA Method
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
10
2
2
10
10
10
10
10
10
5
2
2
2
10
2
10
2
10
10
10
2
2
0.05
2
2
2
2
10
2
10
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
NOTES
NA - Not Applicable
Location Q
Day 1
Day 5
Day 14
Day 90
Day 0
7/15/2009
7/20/2009
7/29/2009
10/29/2009
6/30/2009
12
15
16
16
16 J
10
15 J
21
9.4 U
360
470
220
340

Location R
PARAMETER
2,4-Dimethylphenol
2,6-Dichlorophenol
2-Methylnaphthalene
2-Methylphenol
2-Naphthylamine
2-Picoline
Acetophenone
Benzo(a)pyrene
Benzo(ghi)perylene
Benzyl alcohol
Diethyl phthalate
Fluoranthene
Fluorene
Hexachlorobenzene
Phenanthrene
Phenol
Phorate
Pyrene
Pyridine
UNITS
PQL
US EPA Method
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
10
2
2
10
10
10
10
10
10
5
2
2
2
10
2
10
2
10
10
10
2
2
0.05
2
2
2
2
10
2
10
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
NOTES
NA - Not Applicable
Day 0
Day 1
Day 5
Day 14
Day 90
6/22/2009
6/23/2009
7/13/2009
7/7/2009
10/28/2009
3.1
120
25
22
750
21
49 J
58 J B
4.1 J B
31
10 J
22
29 J B
13 J
24 J B

Location S
PARAMETER
2,4-Dimethylphenol
2,6-Dichlorophenol
2-Methylnaphthalene
2-Methylphenol
2-Naphthylamine
2-Picoline
Acetophenone
Benzo(a)pyrene
Benzo(ghi)perylene
Benzyl alcohol
Diethyl phthalate
Fluoranthene
Fluorene
Hexachlorobenzene
Phenanthrene
Phenol
Phorate
Pyrene
Pyridine
UNITS
PQL
US EPA Method
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
10
2
2
10
10
10
10
10
10
5
2
2
2
10
2
10
2
10
10
10
2
2
0.05
2
2
2
2
10
2
10
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
NOTES
NA - Not Applicable
Day 0
Day 1
Day 5
Day 14
8/25/2009
8/25/2009
8/29/2009
9/8/2009
14
2.3
2
2.4
3.4
3.5
70
18
530
280
Pesticides
PARAMETER
4,4'-DDE
Aldrin
beta-BHC
delta-BHC
Dieldrin
Endosulfan I
Endosulfan II
Endrin
gamma-BHC (Lindane)
Heptachlor
Heptachlor epoxide
Aroclor 1248
UNITS
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
PQL
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.4
US EPA Method
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8082
Location C
Location D
Location E
Location F
Day 90
5/15/2009
Day 0
2/12/2009
0.11
Day 90
4/17/2009
Day 90
6/29/2009
Location H
Day 0
4/7/2009
Day 14
4/22/2009
0.12 PG
0.35
0.062 PG
0.22 PG
0.42
0.24
PG - indicates that the result is estimated and the sample was diluted due to matrix interference
0.093
Day 90
7/22/2009
Pesticides
PARAMETER
4,4'-DDE
Aldrin
beta-BHC
delta-BHC
Dieldrin
Endosulfan I
Endosulfan II
Endrin
gamma-BHC (Lindane)
Heptachlor
Heptachlor epoxide
Aroclor 1248
UNITS
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
PQL
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.4
US EPA Method
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8082
PG - indicates that the result is estimated and the sample was diluted d
Location I
Location J
Location K
Location L
Day 14
5/28/2009
Day 14
5/18/2009
Day 14
6/2/2009
Day 14
5/27/2009
Location M
Supply Water
5/19/2009
Location O
Day 0
5/19/2009
0.083
Day 0
7/1/2009
0.11 PG
0.37
0.069 PG
0.27
0.38
0.1
0.8 PG
0.84 PG
0.065 PG
Pesticides
Location Q
PARAMETER
4,4'-DDE
Aldrin
beta-BHC
delta-BHC
Dieldrin
Endosulfan I
Endosulfan II
Endrin
gamma-BHC (Lindane)
Heptachlor
Heptachlor epoxide
Aroclor 1248
UNITS
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
PQL
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.4
US EPA Method
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8082
PG - indicates that the result is estimated and the sample was diluted d
Day 0
6/30/2009
0.17 PG
0.26
0.072 PG
Location R
Day 14
7/7/2009
0.72
0.87 PG
0.4 PG
0.31 PG
Location S
Day 90
10/28/2009
Supply Water
8/25/2009
Day 0
8/25/2009
0.41 PG
1.8 PG
0.12
0.26 PG
0.28
0.32
0.96
0.49
0.22
8
0.5
PG
PG
PG
PG
Day 14
9/8/2009
0.34
0.41 PG
0.31
0.051
0.063
ATTACHMENT B
MSC Database for the 8 Northern Pennsylvania Wells
PARAMETER
Acidity
Amenable cyanide
Ammonia Nitrogen
Bromide
Chloride
Fluoride
Hardness, as CaCO3
Nitrate as N
Nitrate-Nitrite
Nitrite as N
Oil & Grease (HEM)
Sulfate
TOC
Total Alkalinity
Total phosphorus
Turbidity
Cyanide, Total
Total Sulfide
pH
Sulfite
MBAS (mol.wt 320)
Aluminum
Aluminum-DISS
Antimony
Antimony-DISS
Arsenic
Arsenic-DISS
Barium
Barium-DISS
Beryllium
Beryllium-DISS
Boron
Boron-DISS
Cadmium
Cadmium-DISS
Calcium
Calcium-DISS
Chromium
Chromium-DISS
Cobalt
Cobalt-DISS
Copper
Copper-DISS
Iron
Iron-DISS
Lead
Lead-DISS
Lithium
Lithium-DISS
Magnesium
Magnesium-DISS
Manganese
Manganese-DISS
Molybdenum
Molybdenum-DISS
Nickel
Nickel-DISS
Potassium
Potassium-DISS
Selenium
Selenium-DISS
Silver
Silver-DISS
Day 0
Day 1
Location G
Lycoming County, PA
Day 5
3/31/2009
4/8/2009
4/13/2009
UNITS
PQL
US EPA Method
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
umhos/cm
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
NTU
ug/L
mg/L
No Units
mg/L
mg/L
mg/L
5
0.01
0.1
2
1
10
1
-1
5
0.05
0.1
0.05
5
-1
1
5
10
3
0.1
4
-10
3
-0.01
1
0.05
SM20 2310B (4a)

SM18 4500-CN E
MCAWW 350.1
SM18 5210 B
MCAWW 300.0A
MCAWW 410.4
MCAWW 300.0A
SM20 5310B
MCAWW 300.0A
SM20 2340C
MCAWW 300.0A
MCAWW 353.2
MCAWW 300.0A
CFR136A 1664A HEM
MCAWW 120.1
MCAWW 300.0A
SM20 5310B
SM18 2320 B
SM18 2540 C
MCAWW 351.3
MCAWW 365.2
SM20 2540D
MCAWW 180.1
SW846 9012A
SW846 9030B/9034
SW846 9040
SW846 9066
SM4500-SO3 B
SM5540 C
1230
0.01
441
189
0.2
502
86
11.6
0.19
130
3.4
2.4
2.5
4.7
6720
2920
11.4
5
1920
400
0.26
4
4.7
10
3
6
0.017
5
0.0933
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
200
200
10
10
10
10
200
200
4
4
2000
2000
5
5
5000
5000
5
5
500
500
25
25
100
100
3
3
500
500
5000
5000
150
150
400
400
40
40
5000
5000
5
5
5
5
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
2000
2000
100
100
100
100
339
348
40
40
59.3
68.7
50
50
32900
31800
50
50
7.9
14.2
120
85.3
14300
13100
30
30
34.1
38.7
6190
6240
67.2
73.7
400
400
457
452
50000
50000
50
50
50
50
U
J
U
J
GU
U
J
J
U
U
U
J
U
U
U
U
U
U
U
B
B
U
U
BJ
BJ
U
U
B
B
U
U
B
B
B
B
U
U
B
B
B
B
B
B
U
U
U
U
U
U
U
U
5
0.01
71.4
302
261
2100
43300
124
2.2
15000
1.6
1.9
2.5
4.6
147000
19
123
124
74600
69.9
0.19
68
126
10
3
7
0.01
5.60
2.94
505
358
100
100
28.2
37.4
1160000
1340000
40
40
3030
3470
50
50
4070000
4360000
50
50
2500
2500
250
250
15700
3690
30
30
80300
93000
271000
293000
1680
1930
8.9
12.1
14.9
20.1
127000
144000
50
50
50
50
U
U
J
J
B
B
J
GU
U
J
BJ
J
U
U
U
B
B
U
U
B
B
U
U
J
J
U
U
U
U
U
U
U
U
U
U
B
B
B
B
U
U
U
U
5
0.01
NA
144
553
4470
77200
58.4
2.4
44000
2
0.63
2.5
10.8
278000
39.2
60.8
72.4
125000
94.9
2.5
260
92
10
3
6.3
0.0084
23.2
0.736
927
508
100
100
54.2
70.5
3220000
3260000
40
40
3840
3890
3
50
9270000
9700000
20.8
50
1000
5000
73.3
250
33500
16700
40.4
150
153000
155000
608000
647000
3440
3550
12.4
400
800
2000
210000
235000
50
50
9.3
50
B
B
J
GU
J
BJ
J
GU
U
U
B
BJ
BJ
U
U
B
B
J
U
U
BJ
U
J
J
BJ
U
U
U
B
U
J
BJ
U
J
J
B
U
U
U
U
U
B
U
Day 15
Day 90
4/22/2009
10/21/2009
19.4
0.01
359
7.3
697
12800
102000
43
2.5
55000
2.5
0.16
2.5
4.6
360000
49.4
42.2
47.7
169000
130
2.5
162
32.9
10
1.6
6.4
0.011
13.6
1.06
835
562
100
100
77.3
82.3
5150000
5070000
40
40
3880
3820
3.8
3.2
13100000
14800000
12.7
6.6
5000
5000
250
250
39200
31500
78
150
201000
202000
781000
875000
4780
5170
400
400
2000
2000
312000
274000
39.4
49.5
8.4
8.1
U
J
J
GU
GU
J
GU
U
J
BJ
J
GU
U
B
J
BJ
BJ
U
U
B
B
J
U
U
BJ
B
J
J
BJ
B
U
U
U
U
J
BJ
U
J
J
U
U
U
U
B
B
B
B
149
0.01
220
2
171
12700
166000
16.4
5
96000
5
0.051
146
4.8
742000
100
63.3
25
298000
157
1
71.5
94.5
10
3
5.8
0.01
NA
NA
173
167
100
100
100
100
8450000
7530000
40
40
2990
2680
50
50
22900000
20500000
50
50
5000
5000
250
250
58700
41700
30
30
262000
230000
1280000
1170000
9740
8760
400
54.4
400
400
547000
477000
50
50
50
50
U
J
U
J
J
GU
GU
B
U
GU
J
J
GU
U
U
U
BJ
BJ
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
J
U
B
U
U
U
U
U
U
Day 0
PARAMETER
Sodium
Sodium-DISS
Strontium
Strontium-DISS
Thallium
Thallium-DISS
Tin
Tin-DISS
Titanium
Titanium-DISS
Trivalent Chrom
Zinc
Zinc-DISS
Hexavalent Chromium
Mercury
Mercury-DISS
1,1-Dichloroethane
1,1-Dichloroethene
1,1-Dichloropropene
1,2-Dichlorobenzene
1,2-Dichloroethane
1,2-Dichloropropane
1,3-Dichlorobenzene
1,3-Dichloropropane
1,4-Dichlorobenzene
1,4-Dioxane
2,2-Dichloropropane
2-Butanone
2-Hexanone
4-Chlorotoluene
Acetone
Acrolein
Acrylonitrile
Benzene
Benzyl chloride
Bromobenzene
Bromoform
Bromomethane
Carbon disulfide
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
Dibromomethane
Ethylbenzene
Isopropylbenzene
Methylene chloride
Naphthalene
n-Butylbenzene
n-Propylbenzene
p-Isopropyltoluene
sec-Butylbenzene
Styrene
UNITS
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
mg/L
mg/L
ug/L
ug/L
PQL
5000
5000
50
50
10
10
1000
1000
500
500
50
20
20
0.01
0.01
0.2
0.2
US EPA Method
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 7196A
SW846 7196A
SW846 7470A
SW846 7470A
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
1000
-5
5
10
5
5
5
20
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
3/31/2009
45000
44700
691
686
100
100
1000
1000
500
500
50
40.7
46.9
0.01
0.01
0.2
0.2
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
1000
NA
5
5
10
5
5
5
20
100
100
2.2
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
Day 1
B
B
U
U
U
U
U
U
U
B
B
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
4/8/2009
18100000
20900000
947000
1090000
100
100
1000
1000
55.9
105
50
200
200
0.5
0.5
0.2
0.2
5
5
5
5
5
5
5
5
5
5
1.3
5
5
5
5
5
5
5
5
5
1000
NA
5
5
10
5
5
5
13
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
1.7
5
5
5
5
5
U
U
U
U
B
B
U
U
U
GU
GU
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
Location G
Lycoming County, PA
Day 5
Day 15
Day 90
4/13/2009
30800000
31400000
2350000
2530000
200
500
1000
1000
133
121
50
67.6
41.6
1
1
0.2
0.2
4/22/2009
40300000
41100000
3650000
3710000
500
500
1000
1000
148
138
50
52.2
49.8
2.5
2.5
0.2
0.2
10/21/2009
58600000
50700000
6390000
5710000
26.4
53.8
1000
29.8
500
500
50
48
42.3
2
2
0.2
0.2
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
1000
NA
5
5
10
5
5
5
16
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
J
J
U
U
U
U
B
B
U
BJ
B
GU
GU
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
1000
NA
5
5
10
5
5
5
26
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
J
J
U
U
U
U
B
B
U
BJ
B
GU
GU
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
1000
NA
5
5
10
5
5
5
12
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
J
J
J
B
B
U
B
U
U
U
BJ
BJ
GU
GU
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Day 0
PARAMETER
tert-butyl acetate
tert-Butylbenzene
Tetrachloroethene
tetrahydrofuran
Toluene
Trichloroethene
Vinyl acetate
Vinyl chloride
Xylenes (total)
1,3-Dinitrobenzene
1,4-Naphthoquinone
1-Naphthylamine
2,3,7,8-TCDD
2,4-Dimethylphenol
2,4-Dinitrophenol
2,4-Dinitrotoluene
2,6-Dichlorophenol
2,6-Dinitrotoluene
2-Chloronaphthalene
2-Chlorophenol
2-Methylnaphthalene
2-Methylphenol
2-Naphthylamine
2-Nitroaniline
2-Nitrophenol
2-Picoline
3-Nitroaniline
4-Aminobiphenyl
4-Chloroaniline
4-Nitroaniline
4-Nitrophenol
5-Nitro-o-toluidine
Acenaphthene
Acenaphthylene
Acetophenone
Aniline
Aramite
Benzidine
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(ghi)perylene
Benzyl alcohol
Chlorobenzilate
Chrysene
Diallate
Dibenzofuran
Diethyl phthalate
Dimethoate
Dimethyl phthalate
UNITS
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
PQL
-5
5
-5
5
5
5
5
5
5
15
US EPA Method
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
10
2
10
10
10
10
-10
10
10
40
10
2
10
10
2
10
2
10
10
50
10
10
10
10
10
50
50
10
10
10
10
10
50
50
100
10
2
2
10
10
10
200
10
5
2
2
2
10
10
2
2
10
10
10
2
10
2
10
10
10
10
10
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
3/31/2009
NA
5
5
NA
5
5
5
5
5
5
5
15
9.4
1.9
9.4
9.4
9.4
9.4
NA
9.4
9.4
9.4
47
9.4
1.9
9.4
9.4
1.9
9.4
1.9
9.4
9.4
47
9.4
9.4
9.4
9.4
9.4
47
47
9.4
9.4
9.4
9.4
9.4
47
47
94
9.4
1.9
1.9
0.21
9.4
9.4
190
1.9
1.9
1.9
1.9
1.9
9.4
9.4
1.9
1.9
9.4
9.4
9.4
1.9
9.4
1.9
9.4
9.4
9.4
9.4
9.4
Day 1
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
4/8/2009
NA
5
5
NA
5
5
5
5
5
5
5
15
9.2
1.8
9.2
9.2
9.2
9.2
NA
9.2
9.2
9.2
46
9.2
1.8
9.2
9.2
1.8
9.2
2.7
9.2
9.2
46
9.2
9.2
9.2
9.2
9.2
46
46
9.2
9.2
9.2
9.2
9.2
46
46
92
9.2
0.22
1.8
0.98
9.2
9.2
180
1.8
1.8
1.8
1.8
1.8
9.2
9.2
1.8
1.8
9.2
9.2
9.2
1.8
9.2
1.8
9.2
9.2
9.2
9.2
9.2
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Location G
Lycoming County, PA
Day 5
Day 15
Day 90
4/13/2009
NA
5
5
NA
5
5
5
5
5
5
5
15
4/22/2009
NA
5
5
NA
5
5
5
5
5
5
5
15
10/21/2009
NA
5
5
NA
5
5
5
5
5
5
5
15
9.4
1.9
9.4
9.4
9.4
9.4
NA
9.4
9.4
9.4
47
9.4
1.9
9.4
9.4
1.9
9.4
1.9
9.4
9.4
47
9.4
9.4
9.4
9.4
9.4
47
47
9.4
9.4
9.4
9.4
9.4
47
47
94
9.4
1.9
1.9
0.81
9.4
9.4
190
1.9
1.9
1.9
1.9
1.9
9.4
9.4
1.9
1.9
9.4
9.4
9.4
1.9
9.4
1.9
9.4
1.1
9.4
9.4
9.4
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
9.5
1.9
9.5
9.5
9.5
9.5
NA
9.5
9.5
9.5
48
9.5
1.9
9.5
9.5
1.9
9.5
1.9
9.5
9.5
48
9.5
9.5
9.5
9.5
9.5
48
48
9.5
9.5
9.5
9.5
9.5
2.6
48
95
9.5
1.9
1.9
0.38
9.5
9.5
190
1.9
1.9
1.9
1.9
1.9
9.5
9.5
1.9
1.9
9.5
9.5
9.5
1.9
9.5
1.9
9.5
9.5
9.5
9.5
9.5
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
10
2
10
10
10
10
NA
10
10
10
50
10
2
10
10
2
10
2
10
10
50
10
10
10
10
10
50
50
10
10
10
10
10
50
50
100
10
2
2
10
10
10
200
2
2
2
2
2
10
10
2
2
10
10
10
2
10
2
10
10
10
10
10
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Day 0
PARAMETER
Dinoseb
Diphenylamine
Disulfoton
Fluoranthene
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hexachloroethane
Hexachloropropene
Isodrin
Isophorone
Isosafrole
Nitrobenzene
N-Nitrosomorpholine
N-Nitrosopiperidine
o-Toluidine
Parathion
Pentachlorobenzene
Pentachloroethane
Pentachlorophenol
Phenanthrene
Phenol
Phorate
Pronamide
Pyrene
Pyridine
Safrole
Thionazin
UNITS
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
PQL
10
10
2
10
10
2
2
0.05
2
2
10
10
2
10
10
10
10
2
10
10
10
2
2
10
10
10
10
10
10
10
10
10
20
10
10
2
2
10
10
2
10
10
10
10
US EPA Method
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
4,4'-DDD
4,4'-DDE
4,4'-DDT
Aldrin
alpha-BHC
beta-BHC
delta-BHC
Dieldrin
Endosulfan I
Endosulfan II
Endosulfan sulfate
Endrin
Endrin aldehyde
Endrin ketone
gamma-BHC (Lindane)
Heptachlor
Heptachlor epoxide
Methoxychlor
Toxaphene
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.1
2
PCBs
Aroclor 1016
Aroclor 1221
Aroclor 1232
Aroclor 1242
Aroclor 1248
Aroclor 1254
Aroclor 1260
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
0.4
0.4
0.4
0.4
0.4
0.4
0.4
Day 1
Location G
Lycoming County, PA
Day 5
Day 15
Day 90
4/13/2009
9.4
9.4
1.9
9.4
9.4
1.9
1.9
1.9
1.9
9.4
9.4
9.4
1.9
9.4
9.4
9.4
9.4
1.9
9.4
9.4
9.4
1.9
1.9
9.4
9.4
9.4
9.4
9.4
9.4
9.4
9.4
9.4
19
9.4
9.4
1.9
1.9
9.4
9.4
1.9
30
9.4
9.4
NA
4/22/2009
9.5
9.5
1.9
9.5
9.5
1.9
1.9
1.9
1.9
9.5
9.5
9.5
1.9
9.5
9.5
9.5
9.5
1.9
9.5
9.5
9.5
1.9
1.9
9.5
9.5
9.5
9.5
9.5
9.5
9.5
9.5
9.5
19
9.5
9.5
1.9
1.9
9.5
9.5
1.9
14
9.5
9.5
NA
10/21/2009
10
10
2
10
10
2
2
2
2
10
10
10
2
10
10
10
10
2
10
10
10
2
2
10
10
10
10
10
10
10
10
10
20
10
10
2
2
10
10
2
10
10
10
NA
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
3/31/2009
9.4
9.4
1.9
9.4
9.4
1.9
1.9
1.9
1.9
9.4
9.4
9.4
1.9
9.4
9.4
9.4
9.4
1.9
9.4
9.4
9.4
1.9
1.9
9.4
9.4
9.4
9.4
9.4
9.4
9.4
9.4
9.4
19
9.4
9.4
1.9
1.9
9.4
9.4
1.9
9.4
9.4
9.4
NA
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
4/8/2009
9.2
9.2
1.8
9.2
9.2
1.8
0.22
1.8
1.8
9.2
9.2
9.2
1.8
9.2
9.2
9.2
9.2
1.8
9.2
9.2
9.2
1.8
1.8
9.2
9.2
9.2
9.2
9.2
9.2
9.2
9.2
9.2
18
9.2
9.2
1.8
1.8
9.2
9.2
1.8
55
9.2
9.2
NA
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
0.048
0.048
0.048
0.048
0.048
0.048
0.48
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.095
1.9
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.047
0.047
0.047
0.047
0.047
0.047
0.47
0.047
0.047
0.047
0.047
0.047
0.047
0.047
0.047
0.047
0.047
0.047
0.094
1.9
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
0.072
0.072
0.072
0.072
0.072
0.072
0.72
0.072
0.072
0.072
0.072
0.072
0.072
0.072
0.072
0.072
0.072
0.072
0.14
2.9
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
SW846 8082
SW846 8082
SW846 8082
SW846 8082
SW846 8082
SW846 8082
SW846 8082
0.38
0.38
0.38
0.38
0.38
0.38
0.38
U
U
U
U
U
U
U
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.38
0.38
0.38
0.38
0.38
0.38
0.38
U
U
U
U
U
U
U
0.4
0.4
0.4
0.4
0.4
0.4
0.4
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
PARAMETER
Day 0
Day 1
Location G
Lycoming County, PA
Day 5
Day 15
Day 90
3/31/2009
4/8/2009
4/13/2009
4/22/2009
10/21/2009
UNITS
PQL
US EPA Method
Ethyl parathion
ug/L
0.4
SW846 8141A
0.94 U
NA
NA
Alcohols
2-Propanol
Butyl alcohol
Ethanol
Methanol
n-Propanol
mg/L
mg/L
mg/L
mg/L
mg/L
10
10
10
10
10
SW846 8015
SW846 8015
SW846 8015
SW846 8015
SW846 8015
5
5
5
8.3
5
UJ
UJ
UJ
J
UJ
NA
NA
NA
NA
NA
10
10
10
58
10
Glycols
Ethylene Glycol
Propylene glycol
mg/L
mg/L
50
50
SW846 8015
SW846 8015
100 UJ
100 UJ
NA
NA
100 UJ
100 UJ
Acids
Acetic Acid
Butyric Acid
Propionic Acid
Volatile Acids
mg/L
mg/L
mg/L
mg/L
10
10
10
10
SW846 8015
SW846 8015
SW846 8015
10 UJ
10 UJ
10 UJ
250
NA
NA
NA
NA
100 U
100 U
100 U
430
0.94 U
UJ
UJ
UJ
J
UJ
10
10
10
39
10
1U
UJ
UJ
UJ
J
UJ
NA
NA
NA
NA
NA
100 UJ
100 UJ
NA
NA
10
18
10
10
J
J
UJ
UJ
NA
NA
NA
NA
PARAMETER
Acidity
Amenable cyanide
Ammonia Nitrogen
Bromide
Chloride
Fluoride
Hardness, as CaCO3
Nitrate as N
Nitrate-Nitrite
Nitrite as N
Oil & Grease (HEM)
Sulfate
TOC
Total Alkalinity
Total phosphorus
Turbidity
Cyanide, Total
Total Sulfide
pH
Sulfite
MBAS (mol.wt 320)
Aluminum
Aluminum-DISS
Antimony
Antimony-DISS
Arsenic
Arsenic-DISS
Barium
Barium-DISS
Beryllium
Beryllium-DISS
Boron
Boron-DISS
Cadmium
Cadmium-DISS
Calcium
Calcium-DISS
Chromium
Chromium-DISS
Cobalt
Cobalt-DISS
Copper
Copper-DISS
Iron
Iron-DISS
Lead
Lead-DISS
Lithium
Lithium-DISS
Magnesium
Magnesium-DISS
Manganese
Manganese-DISS
Molybdenum
Molybdenum-DISS
Nickel
Nickel-DISS
Potassium
Potassium-DISS
Selenium
Selenium-DISS
Silver
Silver-DISS
Supply Water
Day 0
5/9/2009
5/9/2009
UNITS
PQL
US EPA Method
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
umhos/cm
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
NTU
ug/L
mg/L
No Units
mg/L
mg/L
mg/L
5
0.01
0.1
2
1
10
1
-1
5
0.05
0.1
0.05
5
-1
1
5
10
3
0.1
4
-10
3
-0.01
1
0.05
SM20 2310B (4a)

SM18 4500-CN E
MCAWW 350.1
SM18 5210 B
MCAWW 300.0A
MCAWW 410.4
MCAWW 300.0A
SM20 5310B
MCAWW 300.0A
SM20 2340C
MCAWW 300.0A
MCAWW 353.2
MCAWW 300.0A
CFR136A 1664A HEM
MCAWW 120.1
MCAWW 300.0A
SM20 5310B
SM18 2320 B
SM18 2540 C
MCAWW 351.3
MCAWW 365.2
SM20 2540D
MCAWW 180.1
SW846 9012A
SW846 9030B/9034
SW846 9040
SW846 9066
SM4500-SO3 B
SM5540 C
5
0.01
0.064
2
0.22
18.7
49.9
3.2
0.05
38
0.05
0.1
0.05
4.8
247
8.3
4.7
9.3
400
3
0.14
2
3.1
10
1.6
7.3
0.01
21.6
0.240
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
200
200
10
10
10
10
200
200
4
4
2000
2000
5
5
5000
5000
5
5
500
500
25
25
100
100
3
3
500
500
5000
5000
150
150
400
400
40
40
5000
5000
5
5
5
5
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
2000
2000
100
100
100
100
1640
1580
40
40
34.3
44.2
50
50
11600
12000
50
50
500
500
250
250
192
1000
30
30
42.2
32.7
1840
1830
13.9
150
400
400
400
400
50000
2240
50
50
50
50
U
U
B
U
J
U
U
U
U
U
J
J
J
J
U
B
U
B
U
U
U
U
U
U
U
B
BJ
U
U
BJ
BJ
U
U
BJ
BJ
U
U
U
U
U
U
B
U
U
U
B
B
B
B
B
U
U
U
U
U
U
B
U
U
U
U
5
0.01
5.9
578
1
2560
90.2
577
0.05
42
0.02
0.59
0.034
62.2
362
8.4
607
33.4
265
65.4
0.062
192
75.2
4.1
3
7.6
0.028
27.6
0.05
2000
227
100
100
100
100
1170
1500
40
40
33.9
49.9
50
50
9900
13000
50
50
500
500
250
250
198
175
30
30
29.7
51.7
1360
1720
150
11.5
400
400
400
400
50000
3790
50
50
50
50
Location I
Cameron County, PA
Day 1
Day 5
5/15/2009
U
U
U
B
B
J
J
J
B
U
U
B
U
U
U
U
B
BJ
U
U
BJ
BJ
U
U
BJ
BJ
U
U
U
U
U
U
B
B
U
U
B
B
B
B
U
B
U
U
U
U
U
B
U
U
U
U
5
0.01
127
399
238
8790
58700
600
2.5
8600
2.5
1.1
2.5
53.9
200000
36.6
610
175
122000
150
0.084
308
461
10
3
6.6
0.015
NA
NA
1750
286
31.5
18.9
42.9
29.9
516000
532000
40
40
5930
6240
2.9
2.6
2950000
3060000
50.4
18.7
1000
1000
68.3
35
58700
21000
60
60
34600
36500
177000
185000
2840
2870
90
84.2
66.8
66.8
378000
410000
50
50
50
50
5/19/2009
U
U
GU
GU
GU
J
BJ
J
U
U
BJ
BJ
B
B
B
B
J
U
U
J
B
B
B
U
U
B
B
U
U
B
B
B
B
U
U
U
U
123
0.01
199
99.4
901
195
148000
59.6
2.5
42000
2.5
0.1
2.5
4.8
470000
50
48
48.8
238000
160
0.45
696
203
10
3
5.8
0.022
6.80
1.31
418
596
47.2
200
59.6
62.6
1400000
1740000
80
80
11900
15400
9.6
11.4
9400000
11700000
12.2
100
2500
2500
500
500
49700
39100
150
150
97600
125000
604000
765000
5520
6810
27.6
29.2
2000
2000
811000
1040000
100
100
100
100
U
J
GU
GU
U
GU
U
J
GU
J
U
U
BJ
BJ
B
U
B
B
U
U
B
B
J
B
U
U
U
U
U
J
U
U
B
B
U
U
U
U
U
U
Day 14
Day 90
5/28/2009
10/20/2009
216
0.01
229
10.4
1010
12100
181000
26.5
5
50800
5
0.1
52
4.8
570000
100
12.8
37.3
261000
131
0.1
65.2
180
10
3
5.6
0.017
31.2
0.191
846
983
27.2
200
89.2
75.6
2460000
2500000
80
80
16400
16800
11.8
12.2
17300000
17600000
28.8
24.4
2500
2500
79
500
76600
53900
150
150
170000
172000
1100000
1110000
9560
9630
34.4
31.8
2000
2000
1300000
1320000
100
100
100
100
GU
GU
U
U
J
GU
J
U
U
B
B
B
U
B
B
U
U
BJ
B
J
J
B
B
U
U
B
U
U
U
B
B
U
U
U
U
U
U
336
0.01
278
3.4
1510
20200
196000
13.2
5
104000
7.4
0.58
5
4.7
763000
44.2
14
25.3
271000
218
0.08
82
67.2
3.6
3
5.1
0.01
NA
NA
904
130
100
100
100
100
4670000
5810000
3.4
6.8
18700
24300
3.5
3
33000000
41000000
9.7
8
5000
5000
48.1
28.6
131000
152000
13.2
30
323000
323000
2020000
2550000
16900
21200
400
400
400
400
2860000
3850000
50
50
50
50
U
J
GU
GU
BJ
J
B
U
U
BJ
BJ
U
U
U
U
B
B
J
BJ
B
B
B
U
U
B
B
B
U
J
U
U
U
U
U
U
U
U
Supply Water
PARAMETER
Sodium
Sodium-DISS
Strontium
Strontium-DISS
Thallium
Thallium-DISS
Tin
Tin-DISS
Titanium
Titanium-DISS
Trivalent Chrom
Zinc
Zinc-DISS
Hexavalent Chromium
Mercury
Mercury-DISS
1,1-Dichloroethane
1,1-Dichloroethene
1,1-Dichloropropene
1,2-Dichlorobenzene
1,2-Dichloroethane
1,2-Dichloropropane
1,3-Dichlorobenzene
1,3-Dichloropropane
1,4-Dichlorobenzene
1,4-Dioxane
2,2-Dichloropropane
2-Butanone
2-Hexanone
4-Chlorotoluene
Acetone
Acrolein
Acrylonitrile
Benzene
Benzyl chloride
Bromobenzene
Bromoform
Bromomethane
Carbon disulfide
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
Dibromomethane
Ethylbenzene
Isopropylbenzene
Methylene chloride
Naphthalene
n-Butylbenzene
n-Propylbenzene
p-Isopropyltoluene
sec-Butylbenzene
Styrene
UNITS
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
mg/L
mg/L
ug/L
ug/L
PQL
5000
5000
50
50
10
10
1000
1000
500
500
50
20
20
0.01
0.01
0.2
0.2
US EPA Method
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 7196A
SW846 7196A
SW846 7470A
SW846 7470A
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
1000
-5
5
10
5
5
5
20
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
Day 0
5/9/2009
24400
24900
1500
1460
100
100
1000
1000
29.9
29.6
50
25.7
61.5
0.25
0.25
0.053
0.05
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
1000
NA
5
5
10
5
5
5
6.3
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
B
B
J
U
U
U
U
BJ
BJ
U
BJ
BJ
GU
GU
BJ
BJ
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
JB
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
5/9/2009
54200
70800
1070
1340
100
100
1000
1000
27.1
24.4
50
45.7
79.4
0.25
0.25
0.044
0.47
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
1000
NA
5
7.5
10
5
5
5
20
100
100
5
5
5
5
5
5
1.6
5
5
5
5
5
5
5
5
5
5
5
5
5
13
0.95
5
5
5
5
5
Day 1
J
U
U
U
U
BJ
BJ
U
BJ
BJ
GU
GU
BJ
BJ
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
B
J
U
U
U
U
U
Location I
Cameron County, PA
Day 5
5/15/2009
34700000
35000000
492000
500000
200
200
1000
1000
69.9
44.3
50
314
187
0.5
0.27
0.2
0.2
25
25
25
25
25
25
25
25
25
25
3.1
25
25
25
25
25
25
25
25
25
5000
NA
25
25
50
25
25
25
390
500
500
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
J
J
U
U
U
U
B
B
U
B
U
B
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Day 14
5/19/2009
65100000
83400000
1800000
2210000
500
500
2000
2000
143
211
100
269
195
0.25
0.25
0.2
0.2
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
1000
NA
5
5
10
5
5
5
130
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
J
U
U
U
U
B
B
U
BJ
B
GU
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
5/28/2009
85600000
88000000
3120000
3210000
500
500
2000
2000
197
230
24.4
591
566
0.5
0.25
0.2
0.2
5
5
5
5
5
5
5
5
5
5
2.4
5
5
5
5
5
2.3
5
5
5
1000
NA
5
5
10
5
5
5
25
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
Day 90
J
U
U
U
U
B
B
B
J
GU
GU
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
10/20/2009
95500000
117000000
6290000
7820000
26.8
100
1000
1000
500
500
50
810
992
0.5
0.5
0.2
0.2
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
1000
NA
5
5
10
5
5
5
20
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
J
J
J
B
U
U
U
U
U
U
J
J
GU
GU
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Supply Water
PARAMETER
tert-butyl acetate
tert-Butylbenzene
Tetrachloroethene
tetrahydrofuran
Toluene
Trichloroethene
Vinyl acetate
Vinyl chloride
Xylenes (total)
1,3-Dinitrobenzene
1,4-Naphthoquinone
1-Naphthylamine
2,3,7,8-TCDD
2,4-Dimethylphenol
2,4-Dinitrophenol
2,4-Dinitrotoluene
2,6-Dichlorophenol
2,6-Dinitrotoluene
2-Chloronaphthalene
2-Chlorophenol
2-Methylnaphthalene
2-Methylphenol
2-Naphthylamine
2-Nitroaniline
2-Nitrophenol
2-Picoline
3-Nitroaniline
4-Aminobiphenyl
4-Chloroaniline
4-Nitroaniline
4-Nitrophenol
5-Nitro-o-toluidine
Acenaphthene
Acenaphthylene
Acetophenone
Aniline
Aramite
Benzidine
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(ghi)perylene
Benzyl alcohol
Chlorobenzilate
Chrysene
Diallate
Dibenzofuran
Diethyl phthalate
Dimethoate
Dimethyl phthalate
UNITS
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
PQL
-5
5
-5
5
5
5
5
5
5
15
US EPA Method
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
10
2
10
10
10
10
-10
10
10
40
10
2
10
10
2
10
2
10
10
50
10
10
10
10
10
50
50
10
10
10
10
10
50
50
100
10
2
2
10
10
10
200
10
5
2
2
2
10
10
2
2
10
10
10
2
10
2
10
10
10
10
10
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
Day 0
5/9/2009
NA
5
5
NA
5
5
5
5
5
5
5
15
9.4
1.9
9.4
9.4
9.4
9.4
NA
9.4
9.4
9.4
47
9.4
1.9
9.4
9.4
1.9
9.4
1.9
9.4
9.4
47
9.4
9.4
9.4
9.4
9.4
47
47
9.4
9.4
9.4
9.4
9.4
47
47
94
9.4
1.9
1.9
9.4
9.4
9.4
190
1.9
1.9
1.9
1.9
1.9
9.4
9.4
1.9
1.9
9.4
9.4
9.4
1.9
9.4
1.9
9.4
9.4
9.4
9.4
9.4
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
5/9/2009
NA
5
1.3
NA
6.7
5
5
0.81
5
5
5
2.6
9.5
1.9
9.5
9.5
9.5
9.5
NA
9.5
9.5
9.5
48
9.5
1.9
9.5
9.5
1.9
9.5
1.9
9.5
9.5
48
9.5
9.5
9.5
9.5
9.5
48
48
9.5
9.5
9.5
9.5
9.5
48
48
95
9.5
1.9
1.9
9.5
9.5
9.5
190
1.9
1.9
1.9
1.9
1.9
9.5
9.5
1.9
1.9
9.5
9.5
9.5
1.9
9.5
1.9
9.5
9.5
9.5
9.5
9.5
Day 1
U
J
U
U
J
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Location I
Cameron County, PA
Day 5
5/15/2009
NA
25
8.9
NA
25
25
25
25
25
25
25
75
94
19
94
94
94
94
NA
94
94
94
470
94
19
94
94
19
94
19
94
94
470
94
94
94
94
94
470
470
94
94
94
94
94
470
470
940
94
19
19
94
94
94
1900
19
19
19
19
19
41
94
19
19
94
94
94
19
94
19
94
94
94
94
94
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Day 14
5/19/2009
NA
5
5
NA
5
5
5
5
5
5
5
15
9.4
1.9
9.4
9.4
9.4
9.4
NA
9.4
9.4
9.4
47
9.4
1.9
9.4
9.4
1.9
9.4
0.67
0.53
9.4
1.3
9.4
9.4
9.4
9.4
1.2
47
47
9.4
9.4
9.4
9.4
0.75
47
47
94
9.4
0.9
0.84
9.4
9.4
9.4
190
0.97
6.7
10
6.9
5.9
17
9.4
1.9
1.9
6.9
9.4
9.4
0.85
9.4
11
0.87
1.3
9.4
0.87
5.3
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
J
U
J
U
U
U
U
J
U
U
U
U
U
U
J
U
U
U
U
J
J
U
U
U
U
J
U
U
U
J
U
U
J
U
J
J
U
J
J
5/28/2009
NA
5
5
NA
3
5
5
5
5
5
5
6.9
9.7
1.9
9.7
9.7
9.7
9.7
NA
9.7
9.7
9.7
48
9.7
1.9
9.7
9.7
1.9
9.7
1.9
9.7
9.7
48
9.7
9.7
9.7
9.7
8.1
48
48
9.7
9.7
9.7
9.7
9.7
48
48
97
9.7
1.9
1.9
9.7
9.7
9.7
190
1.9
1.9
1.9
1.9
1.9
9.7
9.7
1.9
1.9
4
9.7
9.7
1.9
9.7
1.9
9.7
9.7
9.7
9.7
9.7
Day 90
U
U
J
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
10/20/2009
NA
5
5
NA
5
5
5
5
5
5
5
15
20
4
20
20
20
20
NA
20
20
20
100
20
4
20
20
4
20
4
20
20
100
20
20
20
20
20
100
100
20
20
20
20
20
100
100
200
20
4
4
20
20
20
400
4
4
4
4
4
20
20
4
4
1.4
20
20
0.29
20
4
20
20
20
20
20
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
JB
U
U
U
U
U
U
U
Supply Water
PARAMETER
Dinoseb
Diphenylamine
Disulfoton
Fluoranthene
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hexachloroethane
Hexachloropropene
Isodrin
Isophorone
Isosafrole
Nitrobenzene
N-Nitrosomorpholine
N-Nitrosopiperidine
o-Toluidine
Parathion
Pentachlorobenzene
Pentachloroethane
Pentachlorophenol
Phenanthrene
Phenol
Phorate
Pronamide
Pyrene
Pyridine
Safrole
Thionazin
UNITS
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
PQL
10
10
2
10
10
2
2
0.05
2
2
10
10
2
10
10
10
10
2
10
10
10
2
2
10
10
10
10
10
10
10
10
10
20
10
10
2
2
10
10
2
10
10
10
10
US EPA Method
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
4,4'-DDD
4,4'-DDE
4,4'-DDT
Aldrin
alpha-BHC
beta-BHC
delta-BHC
Dieldrin
Endosulfan I
Endosulfan II
Endosulfan sulfate
Endrin
Endrin aldehyde
Endrin ketone
gamma-BHC (Lindane)
Heptachlor
Heptachlor epoxide
Methoxychlor
Toxaphene
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.1
2
PCBs
Aroclor 1016
Aroclor 1221
Aroclor 1232
Aroclor 1242
Aroclor 1248
Aroclor 1254
Aroclor 1260
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
0.4
0.4
0.4
0.4
0.4
0.4
0.4
Day 0
5/9/2009
Day 1
Location I
Cameron County, PA
Day 5
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
0.048
0.048
0.048
0.048
0.048
0.048
0.48
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.095
1.9
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
0.047
0.047
0.047
0.047
0.047
0.047
0.47
0.047
0.047
0.047
0.047
0.047
0.047
0.047
0.047
0.047
0.047
0.047
0.094
1.9
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.048
0.048
0.048
0.048
0.048
0.37
0.48
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.095
1.9
U
U
U
U
U
SW846 8082
SW846 8082
SW846 8082
SW846 8082
SW846 8082
SW846 8082
SW846 8082
0.38
0.38
0.38
0.38
0.38
0.38
0.38
U
U
U
U
U
U
U
0.38
0.38
0.38
0.38
0.38
0.38
0.38
U
U
U
U
U
U
U
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.38
0.38
0.38
0.38
0.38
0.38
0.38
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
5/19/2009
9.4
9.4
1
9.4
9.4
6.1
0.82
1.9
1.9
9.4
9.4
9.4
9.5
9.4
9.4
9.4
9.4
1.9
9.4
9.4
9.4
1.9
1
9.4
9.4
9.4
9.4
9.4
9.4
9.4
9.4
9.4
19
9.4
9.4
0.89
0.7
9.4
9.4
0.89
310
9.4
9.4
NA
U
U
J
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
J
J
U
U
J
U
U
5/28/2009
9.7
9.7
1.9
9.7
9.7
1.9
1.9
1.9
1.9
9.7
9.7
9.7
1.9
9.7
9.7
9.7
9.7
1.9
9.7
9.7
9.7
1.9
1.9
9.7
9.7
9.7
9.7
9.7
9.7
9.7
9.7
9.7
19
9.7
9.7
1.9
1.9
9.7
9.7
1.9
9.7
9.7
9.7
NA
Day 90
9.4
9.4
1.9
9.4
9.4
1.9
1.9
1.9
1.9
9.4
9.4
9.4
1.9
9.4
9.4
9.4
9.4
1.9
9.4
9.4
9.4
1.9
1.9
9.4
9.4
9.4
9.4
9.4
9.4
9.4
9.4
9.4
19
9.4
9.4
1.9
1.9
9.4
9.4
1.9
9.4
9.4
9.4
NA
U
U
U
U
U
5/15/2009
94
94
19
94
94
19
19
19
19
94
94
94
19
94
94
94
94
19
94
94
94
19
19
94
94
94
94
94
94
94
94
94
190
94
94
19
19
94
94
19
640
94
94
NA
Day 14
5/9/2009
9.5
9.5
1.9
9.5
9.5
5.5
1.9
1.9
1.9
9.5
9.5
9.5
1.9
9.5
9.5
9.5
9.5
1.9
9.5
9.5
9.5
1.9
1.9
9.5
9.5
9.5
9.5
9.5
9.5
9.5
9.5
9.5
19
9.5
9.5
1.9
1.9
9.5
9.5
1.9
4.5
9.5
9.5
NA
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
10/20/2009
20
20
4
20
20
4
4
4
4
20
20
20
4
20
20
20
20
4
20
20
20
4
4
20
20
20
20
20
20
20
20
20
40
20
20
4
4
20
20
4
42
20
20
NA
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
0.05
0.05
0.05
0.05
0.05
0.05
0.5
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.1
2
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
0.4
0.4
0.4
0.4
0.4
0.4
0.4
U
U
U
U
U
U
U
PARAMETER
Location I
Cameron County, PA
Day 5
Supply Water
Day 0
Day 1
5/9/2009
5/9/2009
5/15/2009
UNITS
PQL
US EPA Method
Ethyl parathion
ug/L
0.4
SW846 8141A
0.95 U
Alcohols
2-Propanol
Butyl alcohol
Ethanol
Methanol
n-Propanol
mg/L
mg/L
mg/L
mg/L
mg/L
10
10
10
10
10
SW846 8015
SW846 8015
SW846 8015
SW846 8015
SW846 8015
10
10
10
10
10
Glycols
Ethylene Glycol
Propylene glycol
mg/L
mg/L
50
50
SW846 8015
SW846 8015
100 UJ
100 UJ
200 UJ
200 UJ
100 UJ
100 UJ
Acids
Acetic Acid
Butyric Acid
Propionic Acid
Volatile Acids
mg/L
mg/L
mg/L
mg/L
10
10
10
10
SW846 8015
SW846 8015
SW846 8015
1U
1U
1U
NA
50 UJ
50 UJ
50 UJ
NA
10 UJ
10 UJ
10 UJ
NA
UJ
UJ
UJ
UJ
UJ
0.97 U
NA
20
20
20
130
20
10
10
10
52
10
UJ
UJ
UJ
J
UJ
5/19/2009
NA
UJ
UJ
UJ
J
UJ
10
10
10
59
10
Day 14
Day 90
5/28/2009
10/20/2009
0.95 U
UJ
UJ
UJ
J
UJ
10
10
10
48
10
1U
UJ
UJ
UJ
J
UJ
UJ
UJ
UJ
J
UJ
100 UJ
100 UJ
100 UJ
100 UJ
UJ
UJ
10 UJ
10 UJ
10 UJ
57
100 UJ
100 UJ
100 UJ
460
UJ
UJ
UJ
PARAMETER
Acidity
Amenable cyanide
Ammonia Nitrogen
Bromide
Chloride
Fluoride
Hardness, as CaCO3
Nitrate as N
Nitrate-Nitrite
Nitrite as N
Oil & Grease (HEM)
Sulfate
TOC
Total Alkalinity
Total phosphorus
Turbidity
Cyanide, Total
Total Sulfide
pH
Sulfite
MBAS (mol.wt 320)
Aluminum
Aluminum-DISS
Antimony
Antimony-DISS
Arsenic
Arsenic-DISS
Barium
Barium-DISS
Beryllium
Beryllium-DISS
Boron
Boron-DISS
Cadmium
Cadmium-DISS
Calcium
Calcium-DISS
Chromium
Chromium-DISS
Cobalt
Cobalt-DISS
Copper
Copper-DISS
Iron
Iron-DISS
Lead
Lead-DISS
Lithium
Lithium-DISS
Magnesium
Magnesium-DISS
Manganese
Manganese-DISS
Molybdenum
Molybdenum-DISS
Nickel
Nickel-DISS
Potassium
Potassium-DISS
Selenium
Selenium-DISS
Silver
Silver-DISS
Supply Water
Day 0
5/1/2009
5/1/2009
UNITS
PQL
US EPA Method
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
umhos/cm
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
NTU
ug/L
mg/L
No Units
mg/L
mg/L
mg/L
5
0.01
0.1
2
1
10
1
-1
5
0.05
0.1
0.05
5
-1
1
5
10
3
0.1
4
-10
3
-0.01
1
0.05
SM20 2310B (4a)

SM18 4500-CN E
MCAWW 350.1
SM18 5210 B
MCAWW 300.0A
MCAWW 410.4
MCAWW 300.0A
SM20 5310B
MCAWW 300.0A
SM20 2340C
MCAWW 300.0A
MCAWW 353.2
MCAWW 300.0A
CFR136A 1664A HEM
MCAWW 120.1
MCAWW 300.0A
SM20 5310B
SM18 2320 B
SM18 2540 C
MCAWW 351.3
MCAWW 365.2
SM20 2540D
MCAWW 180.1
SW846 9012A
SW846 9030B/9034
SW846 9040
SW846 9066
SM4500-SO3 B
SM5540 C
5
0.01
0.017
2
0.14
10
42.3
3.2
0.033
140
1.7
1.8
0.05
4.8
380
43.7
2.2
71.4
746
3
0.044
9.6
1.3
10
2.4
7.2
0.01
10.0
0.962
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
200
200
10
10
10
10
200
200
4
4
2000
2000
5
5
5000
5000
5
5
500
500
25
25
100
100
3
3
500
500
5000
5000
150
150
400
400
40
40
5000
5000
5
5
5
5
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
249
2000
100
100
100
100
338
241
40
40
29.8
39.2
50
50
37500
43200
50
50
500
500
250
250
273
1000
30
30
33.8
40.7
5160
6160
145
129
400
400
400
400
2850
2260
50
50
50
50
U
U
BJ
U
B
U
J
B
U
U
J
J
U
B
U
B
J
BJ
U
U
U
U
U
B
BJ
U
U
BJ
B
U
U
BJ
B
U
U
U
U
U
U
B
U
U
U
B
B
B
B
B
B
U
U
U
U
B
B
U
U
U
U
Location J
Tioga County, PA
Day 1
5/4/2009
5
0.01
5.6
47.1
36.6
47400
2180
168
0.05
1300
1.6
2
0.05
29.2
9280
27.7
569
191
4840
17.1
0.072
230
101
4.6
3
7.2
0.027
20.4
0.05
400
2000
100
100
100
100
87100
84400
40
40
156
202
50
50
241000
293000
50
50
500
500
250
250
3080
1510
30
30
2050
2590
21000
25300
395
430
400
400
400
400
11600
13000
50
50
50
50
U
U
J
J
U
U
J
B
U
BJ
U
U
U
U
U
J
U
U
BJ
B
U
U
J
U
U
U
U
U
U
U
U
B
B
U
U
U
U
B
B
U
U
U
U
5
0.01
13.2
36.7
39.1
397
2460
207
0.5
1060
0.83
0.94
0.39
7.3
8740
17.4
56.6
107
5090
14.2
0.14
330
330
15.2
3
7.4
0.03
13.2
0.134
4030
212
100
100
34.3
100
121000
64400
40
40
1120
1180
2.5
50
305000
318000
359
5.8
500
500
41.3
250
55200
14200
26.4
30
4060
3790
25900
25900
1290
1190
372
185
203
24.1
26700
21600
50
50
50
50
U
NR U
J
GU
B
J
J
J
J
B
U
U
B
U
J
U
U
BJ
B
B
U
J
B
U
U
B
U
B
U
B
B
B
B
B
B
B
B
U
U
U
U
Day 5
Day 14
5/8/2009
5/18/2009
5
0.01
36.9
47.5
233
4870
26400
30.7
1.2
7800
2.3
0.89
1.2
4.8
90500
17.6
27.5
187
48700
96.1
0.088
68.8
30.2
10
3
6.6
0.01
6.00
0.0761
111
2000
35.8
29.9
32.1
55.3
1210000
1290000
40
40
3140
3500
50
50
1790000
1950000
15.1
50
500
500
250
250
39000
38200
30
30
37000
40000
154000
167000
1100
1200
400
14.9
400
400
48900
53100
50
50
50
50
U
U
J
GU
GU
U
J
BJ
J
U
U
U
B
U
B
B
B
B
J
U
U
J
J
U
U
J
J
B
U
U
U
U
U
U
U
U
B
U
U
B
U
U
U
U
5
0.01
17.8
20.3
65
8530
8060
82.8
0.5
3100
0.5
0.92
1.8
4.8
32000
10
23.6
119
19100
17.9
0.3
1150
524
10
3
6.8
0.009
9.6
0.137
4680
266
25.7
100
60.4
100
589000
496000
40
40
885
901
1.5
50
847000
928000
460
5.7
500
500
253
250
223000
45800
453
34.7
12200
13300
77600
83800
2810
1710
188
25.6
216
33.3
98900
106000
50
50
50
50
U
U
J
J
GU
GU
U
J
GU
J
U
U
B
J
BJ
B
U
B
U
J
U
U
BJ
B
B
U
B
U
U
U
B
B
B
B
U
U
U
U
PARAMETER
Sodium
Sodium-DISS
Strontium
Strontium-DISS
Thallium
Thallium-DISS
Tin
Tin-DISS
Titanium
Titanium-DISS
Trivalent Chrom
Zinc
Zinc-DISS
Hexavalent Chromium
Mercury
Mercury-DISS
1,1-Dichloroethane
1,1-Dichloroethene
1,1-Dichloropropene
1,2-Dichlorobenzene
1,2-Dichloroethane
1,2-Dichloropropane
1,3-Dichlorobenzene
1,3-Dichloropropane
1,4-Dichlorobenzene
1,4-Dioxane
2,2-Dichloropropane
2-Butanone
2-Hexanone
4-Chlorotoluene
Acetone
Acrolein
Acrylonitrile
Benzene
Benzyl chloride
Bromobenzene
Bromoform
Bromomethane
Carbon disulfide
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
Dibromomethane
Ethylbenzene
Isopropylbenzene
Methylene chloride
Naphthalene
n-Butylbenzene
n-Propylbenzene
p-Isopropyltoluene
sec-Butylbenzene
Styrene
UNITS
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
mg/L
mg/L
ug/L
ug/L
PQL
5000
5000
50
50
10
10
1000
1000
500
500
50
20
20
0.01
0.01
0.2
0.2
US EPA Method
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 7196A
SW846 7196A
SW846 7470A
SW846 7470A
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
1000
-5
5
10
5
5
5
20
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
Location J
Tioga County, PA
Day 1
Supply Water
Day 0
5/1/2009
5/1/2009
17800
21300
588
685
100
100
1000
1000
500
500
50
73.9
52.8
0.01
0.01
0.2
0.2
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
1000
NA
5
5
10
5
5
5
20
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
B
B
J
U
U
U
U
U
U
U
BJ
B
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
884000
1120000
47900
58200
100
100
1000
1000
500
500
50
76.8
45.5
0.05
0.05
0.056
0.051
5
5
5
5
5
5
5
5
5
5
5
5
5
5
2.6
5
5
5
5
5
1000
NA
5
5
10
5
5
5
10
100
100
5
5
5
5
7.8
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
J
U
U
U
U
U
U
U
BJ
B
GU
GU
B
B
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
JB
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Day 5
5/4/2009
1090000
1160000
56700
58600 J
100 U
100 U
1000 U
1000 U
23.5 B
500 U
209
665 J
378
0.086
0.15
0.2 U
0.2 U
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
1000
NA
5
5
10
5
5
5
10
100
100
5
5
5
5
5.8
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
3.7
5
5
5
5
5
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
JB
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
5/8/2009
10700000
11700000
443000
477000
100
100
1000
1000
50.3
62.5
50
91
97.5
0.5
0.5
0.043
0.2
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
1000
NA
5
5
10
5
5
5
22
100
100
0.99
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
Day 14
J
U
U
U
U
BJ
BJ
U
BJ
BJ
GU
GU
BJ
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
B
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
5/18/2009
3940000
4120000
197000
210000
100
100
1000
1000
63.6
500
50
1330
178
0.52
0.5
0.2
0.2
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
2000
NA
10
10
20
10
10
10
330
200
200
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
J
J
U
U
U
U
B
U
U
B
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
PARAMETER
tert-butyl acetate
tert-Butylbenzene
Tetrachloroethene
tetrahydrofuran
Toluene
Trichloroethene
Vinyl acetate
Vinyl chloride
Xylenes (total)
1,3-Dinitrobenzene
1,4-Naphthoquinone
1-Naphthylamine
2,3,7,8-TCDD
2,4-Dimethylphenol
2,4-Dinitrophenol
2,4-Dinitrotoluene
2,6-Dichlorophenol
2,6-Dinitrotoluene
2-Chloronaphthalene
2-Chlorophenol
2-Methylnaphthalene
2-Methylphenol
2-Naphthylamine
2-Nitroaniline
2-Nitrophenol
2-Picoline
3-Nitroaniline
4-Aminobiphenyl
4-Chloroaniline
4-Nitroaniline
4-Nitrophenol
5-Nitro-o-toluidine
Acenaphthene
Acenaphthylene
Acetophenone
Aniline
Aramite
Benzidine
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(ghi)perylene
Benzyl alcohol
Chlorobenzilate
Chrysene
Diallate
Dibenzofuran
Diethyl phthalate
Dimethoate
Dimethyl phthalate
UNITS
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
PQL
-5
5
-5
5
5
5
5
5
5
15
US EPA Method
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
10
2
10
10
10
10
-10
10
10
40
10
2
10
10
2
10
2
10
10
50
10
10
10
10
10
50
50
10
10
10
10
10
50
50
100
10
2
2
10
10
10
200
10
5
2
2
2
10
10
2
2
10
10
10
2
10
2
10
10
10
10
10
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
Supply Water
Day 0
5/1/2009
5/1/2009
NA
5
5
NA
5
5
5
5
5
5
5
15
9.8
2
9.8
9.8
9.8
9.8
NA
9.8
9.8
9.8
49
9.8
2
9.8
9.8
2
9.8
2
9.8
9.8
49
9.8
9.8
9.8
9.8
9.8
49
49
9.8
9.8
9.8
9.8
9.8
49
49
98
9.8
2
2
9.8
9.8
9.8
200
2
2
2
2
2
9.8
9.8
2
2
9.8
9.8
9.8
2
9.8
2
9.8
9.8
9.8
9.8
9.8
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Location J
Tioga County, PA
Day 1
NA
5
5
NA
1.3
5
5
5
5
5
5
2.6
200
40
200
200
200
200
NA
200
200
200
1000
200
40
200
200
40
200
40
200
200
1000
200
200
200
200
200
1000
1000
200
200
200
200
200
1000
1000
2000
200
40
40
200
200
200
4000
40
40
40
40
40
200
200
4300
40
200
200
200
40
200
40
200
200
200
200
200
U
U
J
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Day 5
5/4/2009
NA
5U
5U
NA
5U
5U
5U
5U
5U
5U
5U
15 U
9.6
1.9
9.6
9.6
9.6
9.6
NA
9.6
9.6
25
48
9.6
1.9
9.6
9.6
1.9
9.6
0.82
7.3
9.6
48
9.6
9.6
9.6
9.6
4.5
48
48
9.6
9.6
9.6
9.6
9.6
48
48
96
9.6
1.9
1.9
13
9.6
9.6
190
1.9
1.9
1.9
1.9
1.9
9.6
9.6
18
1.9
1.2
9.6
9.6
1.9
9.6
1.9
9.6
1.6
9.6
9.6
0.3
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
J
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
J
U
U
J
Day 14
5/8/2009
NA
5
5
NA
5
5
5
5
5
5
5
15
9.4
1.9
9.4
9.4
9.4
9.4
NA
9.4
9.4
9.4
47
9.4
1.9
9.4
9.4
1.9
9.4
1.9
9.4
9.4
47
9.4
9.4
9.4
9.4
9.4
47
47
9.4
9.4
9.4
9.4
9.4
47
47
94
9.4
1.9
1.9
1.1
9.4
9.4
190
1.9
1.9
1.9
1.9
1.9
9.4
9.4
17
1.9
1.6
9.4
9.4
1.9
9.4
1.9
9.4
9.4
9.4
9.4
5.3
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
JB
U
U
U
U
U
U
U
U
U
J
5/18/2009
NA
10
10
NA
2.5
10
10
10
10
10
10
30
9.5
1.9
9.5
9.5
9.5
9.5
NA
9.5
9.5
9.5
48
9.5
1.9
9.5
9.5
1.9
9.5
2
0.19
9.5
48
9.5
9.5
9.5
9.5
0.61
48
48
9.5
9.5
9.5
9.5
9.5
48
48
95
9.5
0.67
1.9
1
9.5
9.5
190
1.9
1.9
1.9
1.9
1.9
9.5
9.5
1.9
1.9
9.6
9.5
9.5
1.9
9.5
1.9
9.5
9.5
9.5
9.5
130
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
J
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
PARAMETER
Dinoseb
Diphenylamine
Disulfoton
Fluoranthene
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hexachloroethane
Hexachloropropene
Isodrin
Isophorone
Isosafrole
Nitrobenzene
N-Nitrosomorpholine
N-Nitrosopiperidine
o-Toluidine
Parathion
Pentachlorobenzene
Pentachloroethane
Pentachlorophenol
Phenanthrene
Phenol
Phorate
Pronamide
Pyrene
Pyridine
Safrole
Thionazin
UNITS
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
PQL
10
10
2
10
10
2
2
0.05
2
2
10
10
2
10
10
10
10
2
10
10
10
2
2
10
10
10
10
10
10
10
10
10
20
10
10
2
2
10
10
2
10
10
10
10
US EPA Method
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
4,4'-DDD
4,4'-DDE
4,4'-DDT
Aldrin
alpha-BHC
beta-BHC
delta-BHC
Dieldrin
Endosulfan I
Endosulfan II
Endosulfan sulfate
Endrin
Endrin aldehyde
Endrin ketone
gamma-BHC (Lindane)
Heptachlor
Heptachlor epoxide
Methoxychlor
Toxaphene
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.1
2
PCBs
Aroclor 1016
Aroclor 1221
Aroclor 1232
Aroclor 1242
Aroclor 1248
Aroclor 1254
Aroclor 1260
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
0.4
0.4
0.4
0.4
0.4
0.4
0.4
Supply Water
Day 0
5/1/2009
5/1/2009
Location J
Tioga County, PA
Day 1
9.8
9.8
2
9.8
9.8
2
2
2
2
9.8
9.8
9.8
2
9.8
9.8
9.8
9.8
2
9.8
9.8
9.8
2
2
9.8
9.8
9.8
9.8
9.8
9.8
9.8
9.8
9.8
20
9.8
9.8
2
2
9.8
9.8
2
9.8
9.8
9.8
NA
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
200
200
40
200
200
40
40
40
40
200
200
200
40
200
200
200
200
40
200
200
200
40
40
200
200
200
200
200
200
200
200
200
400
200
200
40
40
200
200
40
200
200
200
NA
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
0.048
0.048
0.048
0.048
0.048
0.048
0.48
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.096
1.9
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
0.049
0.049
0.049
0.049
0.038
0.049
0.49
0.049
0.049
0.049
0.049
0.049
0.049
0.049
0.049
0.049
0.049
0.049
0.098
2
SW846 8082
SW846 8082
SW846 8082
SW846 8082
SW846 8082
SW846 8082
SW846 8082
0.38
0.38
0.38
0.38
0.38
0.38
0.38
U
U
U
U
U
U
U
0.39
0.39
0.39
0.39
0.39
0.39
0.39
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
5/4/2009
9.6 U
9.6 U
1.9 U
9.6 U
9.6 U
1.9 U
1.9 U
1.9 U
1.9 U
9.6 U
9.6 U
9.6 U
1.9 U
9.6 U
9.6 U
9.6 U
9.6 U
1.9 U
9.6 U
9.6 U
9.6 U
1.9 U
1.9 U
9.6 U
9.6 U
9.6 U
9.6 U
9.6 U
9.6 U
9.6 U
9.6 U
9.6 U
19 U
9.6 U
9.6 U
1.9 U
1.9 U
9.6 U
9.6 U
1.9 U
3.2 J
9.6 U
9.6 U
NA
Day 5
Day 14
5/8/2009
9.4
9.4
1.9
9.4
9.4
1.9
1.9
1.9
1.9
9.4
9.4
9.4
1.9
9.4
9.4
9.4
9.4
1.9
9.4
9.4
9.4
1.9
1.9
9.4
9.4
9.4
9.4
9.4
9.4
9.4
9.4
9.4
19
9.4
9.4
1.9
0.76
9.4
9.4
1.9
9.4
9.4
9.4
NA
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
5/18/2009
9.5
9.5
2.7
9.5
9.5
1.9
0.78
1.9
1.9
9.5
9.5
9.5
1.9
9.5
9.5
9.5
9.5
1.9
9.5
9.5
9.5
1.9
2.7
9.5
9.5
9.5
9.5
9.5
9.5
9.5
9.5
9.5
19
9.5
9.5
1
1.9
9.5
9.5
1.9
3.5
9.5
9.5
NA
U
U
U
U
J PG
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.048
0.048
0.048
0.083
0.048
0.048
0.48
0.048
0.048
0.048
0.044
0.048
0.048
0.048
0.048
0.27
0.36
0.052
0.095
1.9
U
U
U
U
U
U
U
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.38
0.38
0.38
0.38
0.38
0.38
0.38
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
J PG
U
U
U
U
PG
PG
U
U
U
U
U
U
U
U
U
PARAMETER
Supply Water
Day 0
5/1/2009
5/1/2009
UNITS
PQL
US EPA Method
Ethyl parathion
ug/L
0.4
SW846 8141A
0.95 U
Alcohols
2-Propanol
Butyl alcohol
Ethanol
Methanol
n-Propanol
mg/L
mg/L
mg/L
mg/L
mg/L
10
10
10
10
10
SW846 8015
SW846 8015
SW846 8015
SW846 8015
SW846 8015
10
10
10
10
10
Glycols
Ethylene Glycol
Propylene glycol
mg/L
mg/L
50
50
Acids
Acetic Acid
Butyric Acid
Propionic Acid
Volatile Acids
mg/L
mg/L
mg/L
mg/L
10
10
10
10
Location J
Tioga County, PA
Day 1
5/4/2009
1U
NA
10
10
10
10
10
Day 5
Day 14
5/8/2009
5/18/2009
NA
UJ
UJ
UJ
UJ
UJ
13
10
10
10
10
0.95 U
UJ
UJ
UJ
UJ
UJ
NA
NA
NA
NA
NA
J
UJ
UJ
UJ
UJ
10
10
10
10
10
UJ
UJ
UJ
UJ
UJ
SW846 8015
SW846 8015
100 UJ
100 UJ
NA
NA
100 UJ
100 UJ
100 UJ
100 UJ
100 UJ
100 UJ
SW846 8015
SW846 8015
SW846 8015
0.15 U
0.16 U
0.17 U
NA
NA
NA
NA
NA
0.15 U
0.16 U
0.17 U
NA
10 UJ
10 UJ
10 UJ
NA
1.5 UJ
1.6 UJ
1.7 JU
110
Location K
Bradford County, PA
Day 1
Day 5
Day 0
PARAMETER
Acidity
Amenable cyanide
Ammonia Nitrogen
Bromide
Chloride
Fluoride
Hardness, as CaCO3
Nitrate as N
Nitrate-Nitrite
Nitrite as N
Oil & Grease (HEM)
Sulfate
TOC
Total Alkalinity
Total phosphorus
Turbidity
Cyanide, Total
Total Sulfide
pH
Sulfite
MBAS (mol.wt 320)
Aluminum
Aluminum-DISS
Antimony
Antimony-DISS
Arsenic
Arsenic-DISS
Barium
Barium-DISS
Beryllium
Beryllium-DISS
Boron
Boron-DISS
Cadmium
Cadmium-DISS
Calcium
Calcium-DISS
Chromium
Chromium-DISS
Cobalt
Cobalt-DISS
Copper
Copper-DISS
Iron
Iron-DISS
Lead
Lead-DISS
Lithium
Lithium-DISS
Magnesium
Magnesium-DISS
Manganese
Manganese-DISS
Molybdenum
Molybdenum-DISS
Nickel
Nickel-DISS
Potassium
Potassium-DISS
Selenium
Selenium-DISS
Silver
Silver-DISS
05/07/2009
UNITS
PQL
US EPA Method
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
umhos/cm
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
NTU
ug/L
mg/L
No Units
mg/L
mg/L
mg/L
5
0.01
0.1
2
1
10
1
-1
5
0.05
0.1
0.05
5
-1
1
5
10
3
0.1
4
-10
3
-0.01
1
0.05
SM20 2310B (4a)

SM18 4500-CN E
MCAWW 350.1
SM18 5210 B
MCAWW 300.0A
MCAWW 410.4
MCAWW 300.0A
SM20 5310B
MCAWW 300.0A
SM20 2340C
MCAWW 300.0A
MCAWW 353.2
MCAWW 300.0A
CFR136A 1664A HEM
MCAWW 120.1
MCAWW 300.0A
SM20 5310B
SM18 2320 B
SM18 2540 C
MCAWW 351.3
MCAWW 365.2
SM20 2540D
MCAWW 180.1
SW846 9012A
SW846 9030B/9034
SW846 9040
SW846 9066
SM4500-SO3 B
SM5540 C
66.7
0.01
14
430
18.9
1260
82
301
0.05
104
1.6
0.37
0.056
4.9
507
21.5
949
116
804
47.2
0.097
26
249
320
1.6
6.3
0.011
10.4
0.05
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
200
200
10
10
10
10
200
200
4
4
2000
2000
5
5
5000
5000
5
5
500
500
25
25
100
100
3
3
500
500
5000
5000
150
150
400
400
40
40
5000
5000
5
5
5
5
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
311
2000
16.7
100
100
100
1220
1360
40
40
71.4
76.4
50
50
26600
22900
50
50
500
500
250
250
745
567
30
21.2
42
56.3
4320
3760
33.2
27.5
400
400
400
400
2750
2790
50
50
50
50
NR U
J
U
U
J
J
J
J
B
U
B
U
U
U
B
BJ
U
U
BJ
BJ
U
U
BJ
BJ
U
U
U
U
U
U
B
B
U
B
B
B
B
B
B
B
U
U
U
U
B
B
U
U
U
U
5/20/2009
5
0.01
16.8
650
117
855
10200
197
0.38
2100
2.4
0.32
1.1
4.8
35700
21.6
124
311
18600
25.2
0.14
172
63.8
16.7
1.6
7.4
0.01
8.8
0.575
420
166
34.9
36.5
32.3
100
251000
224000
40
40
2850
2590
50
50
577000
493000
48.1
50
500
500
250
250
18000
11700
70.9
35.7
23600
20200
52000
44800
519
440
54.4
42.7
176
33.4
35800
31900
50
50
50
50
Day 14
5/22/2009
U
NR U
J
U
J
J
J
B
U
BJ
B
B
B
B
U
U
U
U
U
J
B
U
U
U
U
U
B
B
B
B
B
B
U
U
U
U
6/2/2009
5
0.01
29.4
214
185
1720
34000
158
1.2
5100
1.2
0.2
4.8
4.9
79500
6.6
103
245
39400
38
0.12
61
140
7.4
1.6
6.9
0.052
5
0.012
U
U
J
2000
205
33.7
21.7
28.8
32.6
893000
1010000
40
40
3550
4170
50
50
1440000
1590000
14.6
6.6
500
500
250
250
33600
34400
30
30
41800
47800
135000
150000
881
1020
33.1
34
400
400
54600
64000
50
50
50
50
U
B
B
B
B
B
J
GU
GU
U
J
BJ
J
BJ
B
U
U
U
U
J
B
B
U
U
U
U
U
U
B
B
U
U
U
U
U
U
5
0.01
3.7
30.5
15.8
228
1670
5.2
0.05
630
0.65
0.68
1.7
9.4
6800
0.78
7.2
91.3
3010
5.6
0.17
561
548
10
3
6.6
0.0097
14
0.0733
3990
2000
14.1
100
79.8
100
105000
102000
40
40
464
313
50
50
173000
204000
567
50
10.9
500
493
250
166000
26800
138
30
3410
4000
18500
21900
2170
1230
149
400
769
62.1
8230
8140
50
50
50
50
U
U
J
U
J
BJ
J
U
U
B
U
B
U
B
U
U
U
B
B
U
U
J
J
U
B
U
U
B
B
B
U
B
B
B
U
U
U
U
Location K
Bradford County, PA
Day 1
Day 5
Day 0
PARAMETER
Sodium
Sodium-DISS
Strontium
Strontium-DISS
Thallium
Thallium-DISS
Tin
Tin-DISS
Titanium
Titanium-DISS
Trivalent Chrom
Zinc
Zinc-DISS
Hexavalent Chromium
Mercury
Mercury-DISS
1,1-Dichloroethane
1,1-Dichloroethene
1,1-Dichloropropene
1,2-Dichlorobenzene
1,2-Dichloroethane
1,2-Dichloropropane
1,3-Dichlorobenzene
1,3-Dichloropropane
1,4-Dichlorobenzene
1,4-Dioxane
2,2-Dichloropropane
2-Butanone
2-Hexanone
4-Chlorotoluene
Acetone
Acrolein
Acrylonitrile
Benzene
Benzyl chloride
Bromobenzene
Bromoform
Bromomethane
Carbon disulfide
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
Dibromomethane
Ethylbenzene
Isopropylbenzene
Methylene chloride
Naphthalene
n-Butylbenzene
n-Propylbenzene
p-Isopropyltoluene
sec-Butylbenzene
Styrene
UNITS
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
mg/L
mg/L
ug/L
ug/L
PQL
5000
5000
50
50
10
10
1000
1000
500
500
50
20
20
0.01
0.01
0.2
0.2
US EPA Method
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 7196A
SW846 7196A
SW846 7470A
SW846 7470A
05/07/2009
67800
80700
1310
899 J E
100 U
100 U
1000 U
1000 U
22.3 B J
21.2 B J
50 U
99.7 B J
76.1 B J
0.5 G U
0.5 G U
0.052 B J
0.46 B J
5/20/2009
6630000
5830000 J
117000
99700 J
100 U
100 U
1000 U
1000 U
38.5 B
39.4 B
50 U
198 B J
109 B J
0.1 G U
0.1 G U
0.2 U
0.2 U
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
1000
-5
5
10
5
5
5
20
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
5
5
5
5
5
5
5
5
5
5
42
5
5
5
5
5
20
5
5
5
1000
NA
5
5
10
5
5
5
6.7
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
1.7
5
5
5
3.9
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
14
5
5
5
5
5
7.7
5
5
5
1000
NA
5
5
10
5
5
5
5.9
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
JB
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
5/22/2009
11700000
13200000
357000
390000
100
100
1000
1000
23.9
39.2
50
147
172
0.17
0.17
0.2
0.2
5
5
5
5
5
5
5
5
5
5
7.7
5
5
5
5
5
5.3
5
5
5
1000
NA
5
5
10
5
5
5
6.9
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
Day 14
J
J
U
U
U
U
B
B
U
BJ
BJ
B
B
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
6/2/2009
922000
1100000
39000
46100
100
100
23
1000
119
500
50
517
75.7
0.05
0.047
0.2
0.2
5
5
5
5
5
5
5
5
5
5
3.9
5
5
5
5
5
2.8
5
5
5
1000
NA
5
5
10
5
5
5
20
100
100
1.5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
2.3
J
U
U
B
U
B
U
U
J
B
GU
B
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
Location K
Bradford County, PA
Day 1
Day 5
Day 0
PARAMETER
tert-butyl acetate
tert-Butylbenzene
Tetrachloroethene
tetrahydrofuran
Toluene
Trichloroethene
Vinyl acetate
Vinyl chloride
Xylenes (total)
1,3-Dinitrobenzene
1,4-Naphthoquinone
1-Naphthylamine
2,3,7,8-TCDD
2,4-Dimethylphenol
2,4-Dinitrophenol
2,4-Dinitrotoluene
2,6-Dichlorophenol
2,6-Dinitrotoluene
2-Chloronaphthalene
2-Chlorophenol
2-Methylnaphthalene
2-Methylphenol
2-Naphthylamine
2-Nitroaniline
2-Nitrophenol
2-Picoline
3-Nitroaniline
4-Aminobiphenyl
4-Chloroaniline
4-Nitroaniline
4-Nitrophenol
5-Nitro-o-toluidine
Acenaphthene
Acenaphthylene
Acetophenone
Aniline
Aramite
Benzidine
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(ghi)perylene
Benzyl alcohol
Chlorobenzilate
Chrysene
Diallate
Dibenzofuran
Diethyl phthalate
Dimethoate
Dimethyl phthalate
UNITS
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
PQL
-5
5
-5
5
5
5
5
5
5
15
US EPA Method
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
10
2
10
10
10
10
-10
10
10
40
10
2
10
10
2
10
2
10
10
50
10
10
10
10
10
50
50
10
10
10
10
10
50
50
100
10
2
2
10
10
10
200
10
5
2
2
2
10
10
2
2
10
10
10
2
10
2
10
10
10
10
10
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
05/07/2009
NA
5U
5U
NA
5U
5U
5U
5U
5U
5U
5U
35
9.9
2
9.9
9.9
9.9
9.9
NA
9.9
9.9
9.9
50
9.9
2
9.9
9.9
2
9.9
2
9.9
9.9
50
9.9
9.9
9.9
9.9
9.9
50
50
9.9
9.9
9.9
9.9
9.9
50
50
99
9.9
2
2
9.9
9.9
9.9
200
1.1
6.9
11
7.4
6.7
9.9
9.9
2
2
15
9.9
9.9
1.7
9.9
12
9.9
9.9
9.9
9.9
9.9
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
B
U
U
J
U
U
U
U
U
U
5/20/2009
NA
5U
5U
NA
5U
5U
5U
5U
5U
5U
5U
4.8 J
9.5
1.9
9.5
9.5
9.5
9.5
NA
9.5
9.5
9.5
48
9.5
1.9
9.5
9.5
1.9
9.5
1.9
9.5
9.5
48
9.5
9.5
9.5
9.5
9.5
48
48
9.5
9.5
9.5
9.5
9.5
48
48
95
9.5
1.9
1.9
9.5
9.5
9.5
190
1.9
1.9
1.9
1.9
1.9
9.5
9.5
1.9
1.9
1.8
9.5
9.5
1.9
9.5
1.9
9.5
9.5
9.5
9.5
5
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
J
5/22/2009
NA
5
5
NA
5
5
5
5
5
5
5
3
9.4
1.9
9.4
9.4
9.4
9.4
NA
9.4
9.4
9.4
47
9.4
1.9
9.4
9.4
1.9
9.4
1.9
9.4
9.4
47
9.4
9.4
9.4
9.4
9.4
47
47
9.4
9.4
9.4
9.4
9.4
47
47
94
9.4
1.9
1.9
9.4
9.4
9.4
190
1.9
1.9
1.9
1.9
1.9
9.4
9.4
1.9
1.9
9.4
9.4
9.4
1.9
9.4
1.9
9.4
9.4
9.4
9.4
9.4
Day 14
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
6/2/2009
NA
5
5
NA
1.6
5
5
5
5
5
5
3.7
10
2
10
10
10
10
NA
10
10
10
50
10
2
10
10
2
10
2
10
10
50
10
10
10
10
0.41
50
50
10
10
10
10
10
50
50
100
10
2
2
10
10
10
200
2
2
2
2
2
9.1
10
2
2
10
10
10
2
10
2
10
0.73
10
10
10
U
U
J
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
J
U
U
U
Location K
Bradford County, PA
Day 1
Day 5
Day 0
PARAMETER
Dinoseb
Diphenylamine
Disulfoton
Fluoranthene
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hexachloroethane
Hexachloropropene
Isodrin
Isophorone
Isosafrole
Nitrobenzene
N-Nitrosomorpholine
N-Nitrosopiperidine
o-Toluidine
Parathion
Pentachlorobenzene
Pentachloroethane
Pentachlorophenol
Phenanthrene
Phenol
Phorate
Pronamide
Pyrene
Pyridine
Safrole
Thionazin
Day 14
UNITS
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
PQL
10
10
2
10
10
2
2
0.05
2
2
10
10
2
10
10
10
10
2
10
10
10
2
2
10
10
10
10
10
10
10
10
10
20
10
10
2
2
10
10
2
10
10
10
10
US EPA Method
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
4,4'-DDD
4,4'-DDE
4,4'-DDT
Aldrin
alpha-BHC
beta-BHC
delta-BHC
Dieldrin
Endosulfan I
Endosulfan II
Endosulfan sulfate
Endrin
Endrin aldehyde
Endrin ketone
gamma-BHC (Lindane)
Heptachlor
Heptachlor epoxide
Methoxychlor
Toxaphene
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.1
2
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
0.049
0.049
0.049
0.049
0.049
0.049
0.49
0.049
0.049
0.049
0.049
0.049
0.049
0.049
0.049
0.049
0.049
0.049
0.098
2
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.048
0.048
0.048
0.048
0.048
0.048
0.48
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.036
0.1
0.048
0.097
1.9
PCBs
Aroclor 1016
Aroclor 1221
Aroclor 1232
Aroclor 1242
Aroclor 1248
Aroclor 1254
Aroclor 1260
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
0.4
0.4
0.4
0.4
0.4
0.4
0.4
SW846 8082
SW846 8082
SW846 8082
SW846 8082
SW846 8082
SW846 8082
SW846 8082
0.39
0.39
0.39
0.39
0.39
0.39
0.39
U
U
U
U
U
U
U
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.39
0.39
0.39
0.39
0.39
0.39
0.39
05/07/2009
9.9 U
9.9 U
2U
9.9 U
9.9 U
2U
2U
2U
2U
9.9 U
9.9 U
9.9 U
10
9.9 U
9.9 U
9.9 U
9.9 U
2U
9.9 U
9.9 U
9.9 U
2U
2U
9.9 U
9.9 U
9.9 U
9.9 U
9.9 U
9.9 U
9.9 U
9.9 U
9.9 U
20 U
9.9 U
9.9 U
2U
2U
9.9 U
9.9 U
2U
9.9 U
9.9 U
9.9 U
NA
5/20/2009
9.5 U
9.5 U
1.9 U
9.5 U
9.5 U
1.9 U
1.9 U
1.9 U
1.9 U
9.5 U
9.5 U
9.5 U
1.9 U
9.5 U
9.5 U
9.5 U
9.5 U
1.9 U
9.5 U
9.5 U
9.5 U
1.9 U
1.9 U
9.5 U
9.5 U
9.5 U
9.5 U
9.5 U
9.5 U
9.5 U
9.5 U
9.5 U
19 U
9.5 U
9.5 U
1.9 U
1.9 U
9.5 U
9.5 U
1.9 U
9.5 U
9.5 U
9.5 U
NA
5/22/2009
9.4
9.4
1.9
9.4
9.4
1.9
1.9
1.9
1.9
9.4
9.4
9.4
1.9
9.4
9.4
9.4
9.4
1.9
9.4
9.4
9.4
1.9
1.9
9.4
9.4
9.4
9.4
9.4
9.4
9.4
9.4
9.4
19
9.4
9.4
1.9
1.9
9.4
9.4
1.9
9.4
9.4
9.4
NA
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
6/2/2009
10
10
2
10
10
2
2
2
2
10
10
10
2
10
10
10
10
2
10
10
10
2
2
10
10
10
10
10
10
10
10
10
20
10
10
2
2
10
10
2
150
10
10
NA
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J PG
U
U
U
U
U
U
U
U
U
U
Location K
Bradford County, PA
Day 1
Day 5
Day 0
PARAMETER
Day 14
UNITS
PQL
US EPA Method
Ethyl parathion
ug/L
0.4
SW846 8141A
0.95 U
NA
Alcohols
2-Propanol
Butyl alcohol
Ethanol
Methanol
n-Propanol
mg/L
mg/L
mg/L
mg/L
mg/L
10
10
10
10
10
SW846 8015
SW846 8015
SW846 8015
SW846 8015
SW846 8015
10
10
10
10
10
10
10
10
10
10
Glycols
Ethylene Glycol
Propylene glycol
mg/L
mg/L
50
50
SW846 8015
SW846 8015
100 UJ
220 J
100 UJ
130 J
100 UJ
100 UJ
100 UJ
100 UJ
Acids
Acetic Acid
Butyric Acid
Propionic Acid
Volatile Acids
mg/L
mg/L
mg/L
mg/L
10
10
10
10
SW846 8015
SW846 8015
SW846 8015
50 UJ
50 UJ
50 UJ
2300
42 J
20 UJ
20 UJ
170
39 J
10 UJ
10 UJ
400
10 UJ
10 UJ
10 UJ
110
05/07/2009
UJ
UJ
UJ
UJ
UJ
5/20/2009
5/22/2009
6/2/2009
NA
UJ
UJ
UJ
UJ
UJ
10
10
10
10
10
0.95 U
UJ
UJ
UJ
UJ
UJ
10
10
10
10
10
UJ
UJ
UJ
UJ
UJ
PARAMETER
Acidity
Amenable cyanide
Ammonia Nitrogen
Bromide
Chloride
Fluoride
Hardness, as CaCO3
Nitrate as N
Nitrate-Nitrite
Nitrite as N
Oil & Grease (HEM)
Sulfate
TOC
Total Alkalinity
Total phosphorus
Turbidity
Cyanide, Total
Total Sulfide
pH
Sulfite
MBAS (mol.wt 320)
Aluminum
Aluminum-DISS
Antimony
Antimony-DISS
Arsenic
Arsenic-DISS
Barium
Barium-DISS
Beryllium
Beryllium-DISS
Boron
Boron-DISS
Cadmium
Cadmium-DISS
Calcium
Calcium-DISS
Chromium
Chromium-DISS
Cobalt
Cobalt-DISS
Copper
Copper-DISS
Iron
Iron-DISS
Lead
Lead-DISS
Lithium
Lithium-DISS
Magnesium
Magnesium-DISS
Manganese
Manganese-DISS
Molybdenum
Molybdenum-DISS
Nickel
Nickel-DISS
Potassium
Potassium-DISS
Selenium
Selenium-DISS
Silver
Silver-DISS
UNITS
PQL
US EPA Method
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
umhos/cm
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
NTU
ug/L
mg/L
No Units
mg/L
mg/L
mg/L
5
0.01
0.1
2
1
10
1
-1
5
0.05
0.1
0.05
5
-1
1
5
10
3
0.1
4
-10
3
-0.01
1
0.05
SM20 2310B (4a)

SM18 4500-CN E
MCAWW 350.1
SM18 5210 B
MCAWW 300.0A
MCAWW 410.4
MCAWW 300.0A
SM20 5310B
MCAWW 300.0A
SM20 2340C
MCAWW 300.0A
MCAWW 353.2
MCAWW 300.0A
CFR136A 1664A HEM
MCAWW 120.1
MCAWW 300.0A
SM20 5310B
SM18 2320 B
SM18 2540 C
MCAWW 351.3
MCAWW 365.2
SM20 2540D
MCAWW 180.1
SW846 9012A
SW846 9030B/9034
SW846 9040
SW846 9066
SM4500-SO3 B
SM5540 C
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
200
200
10
10
10
10
200
200
4
4
2000
2000
5
5
5000
5000
5
5
500
500
25
25
100
100
3
3
500
500
5000
5000
150
150
400
400
40
40
5000
5000
5
5
5
5
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
Supply Water
Day 0
5/19/2009
5/19/2009
5
0.01
0.25
2
2
10
4.1
1.4
0.05
18
0.24
0.24
0.21
4.6
54.8
3.8
1.8
6.2
51
2.2
0.1
4
4.3
10
1.6
7.1
0.01
6
0.05
122
160
14.6
100
100
100
271
274
40
40
2000
2000
50
50
4880
3690
50
50
500
500
250
250
605
543
30
30
500
500
1080
1440
134
127
400
400
400
400
50000
50000
50
50
50
50
U
U
J
U
GU
U
B
11.4
0.0097
1.5
137
10
490
29.9
84.3
0.009
26
2.5
0.24
2.5
33.2
177
2.9
86.6
9.6
371
31.3
0.096
110
254
12.5
3
6.2
0.0069
12
0.05
BJ
B
B
U
U
U
B
B
U
U
U
U
U
U
BJ
B
U
U
U
U
U
U
B
B
U
U
U
U
B
B
B
B
U
U
U
U
U
U
U
U
U
U
180
239
100
100
100
100
579
621
40
40
2000
2000
50
50
6690
6080
50
50
500
500
44.5
250
497
460
30
30
500
28.1
1250
1460
127
130
400
400
19.5
400
50000
50000
50
50
50
50
U
B
B
U
J
B
J
B
U
U
U
B
U
Location M
McKean County, PA
Day 1
6/6/2009
B
J
GU
B
B
U
GU
J
B
J
U
B
BJ
B
U
U
U
U
B
B
U
U
U
U
U
U
BJ
B
U
U
U
U
B
U
B
B
U
U
U
B
B
B
B
B
U
U
B
U
U
U
U
U
U
U
NA
0.01
173
36.3
NA
10700
NA
77
2.5
NA
2.5
0.01
NA
NA
NA
50
2.2
NA
NA
158
1.4
NA
NA
10
3
5.9
0.007
24.4
0.241
165
289
13.9
16.9
100
100
1450000
1430000
40
40
12000
11800
50
50
19700000
19700000
15.7
50
5000
5000
255
81.1
67200
37600
30
30
129000
126000
1320000
1310000
5960
5850
48.2
34.7
400
400
923000
1000000
50
50
50
50
GU
GU
B
GU
U
U
B
B
BJ
B
B
U
U
U
U
U
U
J
J
B
U
U
U
B
U
U
J
B
BJ
U
U
U
U
U
U
Day 5
Day 14
6/10/2009
6/19/2009
NA
0.01
192
103
NA
7600
NA
33.1
2.5
NA
2.5
0.049
25.9
NA
NA
50
3.7
NA
NA
178
0.1
NA
NA
10
3
7.2
0.29
11.6
0.291
131
188
17.3
20.9
100
100
1730000
1760000
40
40
10500
11000
50
1.5
23500000
23800000
50
50
5000
5000
78.9
57.7
53100
44800
30
30
137000
154000
1550000
1600000
7040
7170
400
400
400
400
849000
1010000
50
50
50
50
GU
GU
BJ
GU
U
U
B
BJ
B
B
U
U
U
U
U
B
J
J
U
U
U
U
B
B
U
U
J
U
U
U
U
U
U
U
U
200
0.01
268
10.2
1190
9180
151000
5
2.5
95000
2.5
0.11
55.8
7.4
710000
50
1.2
26.1
228000
199
2.2
40.8
67.8
10
3
5.8
0.006
10.4
0.198
158
210
100
15.7
100
100
1970000
1990000
40
40
10000
9740
50
1.5
26400000
26200000
50
50
5000
5000
250
250
61000
53300
30
30
155000
158000
1800000
1740000
8560
8420
400
400
400
400
972000
1010000
50
50
50
50
U
J
GU
GU
J
GU
J
U
U
B
B
BJ
U
B
U
U
U
U
U
B
J
J
U
U
U
U
U
U
U
U
J
U
U
U
U
E
E
U
U
U
U
Supply Water
PARAMETER
Sodium
Sodium-DISS
Strontium
Strontium-DISS
Thallium
Thallium-DISS
Tin
Tin-DISS
Titanium
Titanium-DISS
Trivalent Chrom
Zinc
Zinc-DISS
Hexavalent Chromium
Mercury
Mercury-DISS
1,1-Dichloroethane
1,1-Dichloroethene
1,1-Dichloropropene
1,2-Dichlorobenzene
1,2-Dichloroethane
1,2-Dichloropropane
1,3-Dichlorobenzene
1,3-Dichloropropane
1,4-Dichlorobenzene
1,4-Dioxane
2,2-Dichloropropane
2-Butanone
2-Hexanone
4-Chlorotoluene
Acetone
Acrolein
Acrylonitrile
Benzene
Benzyl chloride
Bromobenzene
Bromoform
Bromomethane
Carbon disulfide
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
Dibromomethane
Ethylbenzene
Isopropylbenzene
Methylene chloride
Naphthalene
n-Butylbenzene
n-Propylbenzene
p-Isopropyltoluene
sec-Butylbenzene
Styrene
UNITS
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
mg/L
mg/L
ug/L
ug/L
PQL
5000
5000
50
50
10
10
1000
1000
500
500
50
20
20
0.01
0.01
0.2
0.2
US EPA Method
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 7196A
SW846 7196A
SW846 7470A
SW846 7470A
5/19/2009
4200 B
3600 B J
352 B
340 B J
100 U
100 U
1000 U
1000 U
500 U
500 U
50 U
56.7 B J
41.1 B J
0.01 U
0.01 U
0.2 U
0.2 U
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
1000
-5
5
10
5
5
5
20
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
1000
NA
5
5
10
5
5
5
20
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Day 0
5/19/2009
32600
34200
768
816
100
100
1000
1000
500
29.8
50
50.2
40.6
0.01
0.05
0.2
0.2
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
1000
NA
5
3.6
10
5
5
5
20
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
Location M
McKean County, PA
Day 1
B
BJ
J
U
U
U
U
U
B
U
BJ
BJ
GU
GU
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Day 5
6/6/2009
6/10/2009
20600000
17200000
31500000
31300000
4330000
4830000
4280000 J
4920000 J
27.2 B
100 U
100 U
100 U
1000 U
1000 U
1000 U
1000 U
500 U
500 U
500 U
500 U
50 U
50 U
391 J
270 J
314 J
240 J
0.5 G U
0.5 G U
0.5 G U
0.5 G U
0.2 U
0.2 U
0.2 U
0.2 U
5
5
5
5
5
5
5
5
5
5
1.6
5
5
5
5
5
1.2
5
5
5
1000
NA
5
5
10
5
5
5
21
100
100
3.5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
5
5
5
5
5
5
5
5
5
5
4
5
5
5
5
5
3.3
5
5
5
1000
NA
5
5
10
5
5
5
18
100
100
3.2
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
0.63
0.53
5
5
5
5
5
5
5
5
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
J
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
J
U
U
U
U
U
U
U
U
Day 14
6/19/2009
23200000
30400000
5570000 E
5350000 J E
100 U
100 U
1000 U
1000 U
500 U
500 U
50 U
223 J
143 B J
1 GU
1 GU
0.2 U
0.2 U
5
5
5
5
5
5
5
5
5
5
0.98
5
5
5
5
5
5
5
5
5
1000
NA
5
5
10
5
5
5
18
100
100
6.2
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Supply Water
PARAMETER
tert-butyl acetate
tert-Butylbenzene
Tetrachloroethene
tetrahydrofuran
Toluene
Trichloroethene
Vinyl acetate
Vinyl chloride
Xylenes (total)
1,3-Dinitrobenzene
1,4-Naphthoquinone
1-Naphthylamine
2,3,7,8-TCDD
2,4-Dimethylphenol
2,4-Dinitrophenol
2,4-Dinitrotoluene
2,6-Dichlorophenol
2,6-Dinitrotoluene
2-Chloronaphthalene
2-Chlorophenol
2-Methylnaphthalene
2-Methylphenol
2-Naphthylamine
2-Nitroaniline
2-Nitrophenol
2-Picoline
3-Nitroaniline
4-Aminobiphenyl
4-Chloroaniline
4-Nitroaniline
4-Nitrophenol
5-Nitro-o-toluidine
Acenaphthene
Acenaphthylene
Acetophenone
Aniline
Aramite
Benzidine
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(ghi)perylene
Benzyl alcohol
Chlorobenzilate
Chrysene
Diallate
Dibenzofuran
Diethyl phthalate
Dimethoate
Dimethyl phthalate
UNITS
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
PQL
-5
5
-5
5
5
5
5
5
5
15
US EPA Method
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
10
2
10
10
10
10
-10
10
10
40
10
2
10
10
2
10
2
10
10
50
10
10
10
10
10
50
50
10
10
10
10
10
50
50
100
10
2
2
10
10
10
200
10
5
2
2
2
10
10
2
2
10
10
10
2
10
2
10
10
10
10
10
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
5/19/2009
NA
5U
5U
NA
5U
5U
5U
5U
5U
5U
5U
15 U
9.6
1.9
9.6
9.6
9.6
9.6
NA
9.6
9.6
9.6
48
9.6
1.9
9.6
9.6
1.9
9.6
1.9
9.6
9.6
48
9.6
9.6
9.6
9.6
9.6
48
48
9.6
9.6
9.6
9.6
9.6
48
48
96
9.6
1.9
1.9
9.6
9.6
9.6
190
1.9
1.9
1.9
1.9
1.9
9.6
9.6
1.9
1.9
6
9.6
9.6
1.9
9.6
1.9
9.6
9.6
9.6
9.6
9.6
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
Day 0
5/19/2009
NA
5
5
NA
5
5
5
5
5
5
5
15
10
2
10
10
10
10
NA
10
10
10
50
10
2
10
10
2
10
2
10
10
50
10
10
10
10
10
50
50
10
10
10
10
10
50
50
100
10
2
2
10
10
10
200
2
2
2
2
2
10
10
2
2
10
10
10
2
10
2
10
10
10
10
10
Location M
McKean County, PA
Day 1
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Day 5
Day 14
6/6/2009
NA
5U
5U
NA
3.8 J
5U
5U
5U
5U
5U
5U
3.2 J
6/10/2009
NA
5U
5U
NA
4.8 J
5U
5U
5U
5U
5U
5U
6J
6/19/2009
NA
5U
5U
NA
3.4 J
5U
5U
5U
5U
5U
5U
6.2 J
9.5
1.9
9.5
9.5
9.5
9.5
NA
9.5
9.5
9.5
48
9.5
1.9
9.5
9.5
1.9
9.5
1.9
0.28
9.5
48
9.5
9.5
9.5
9.5
9.5
48
48
9.5
9.5
9.5
9.5
9.5
48
48
95
9.5
1.9
1.9
9.5
2.2
9.5
190
1.9
1.9
1.9
1.9
1.9
9.5
9.5
1.9
1.9
2.8
9.5
9.5
1.9
9.5
1.9
9.5
2.4
9.5
9.5
1.3
9.4
1.9
9.4
9.4
9.4
9.4
NA
9.4
9.4
9.4
47
9.4
1.9
9.4
9.4
1.9
9.4
1.9
0.26
9.4
47
9.4
9.4
9.4
9.4
0.69
47
47
9.4
9.4
9.4
9.4
9.4
47
47
94
9.4
1.9
1.9
0.8
2.1
9.4
190
1.9
1.9
1.9
1.9
1.9
9.4
9.4
1.9
1.9
9.4
9.4
9.4
1.9
9.4
1.9
9.4
9.4
9.4
9.4
9.4
9.6
1.9
9.6
9.6
9.6
9.6
NA
9.6
9.6
9.6
48
9.6
1.9
9.6
9.6
1.9
9.6
1.9
9.6
9.6
48
9.6
9.6
9.6
9.6
9.6
48
48
9.6
9.6
9.6
9.6
9.6
48
48
96
9.6
1.9
1.9
9.6
2
9.6
190
1.9
1.9
1.9
1.9
1.9
9.6
9.6
1.9
1.9
2.5
9.6
9.6
1.9
9.6
1.9
9.6
9.6
9.6
9.6
9.6
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
JB
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
J
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
Supply Water
PARAMETER
Dinoseb
Diphenylamine
Disulfoton
Fluoranthene
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hexachloroethane
Hexachloropropene
Isodrin
Isophorone
Isosafrole
Nitrobenzene
N-Nitrosomorpholine
N-Nitrosopiperidine
o-Toluidine
Parathion
Pentachlorobenzene
Pentachloroethane
Pentachlorophenol
Phenanthrene
Phenol
Phorate
Pronamide
Pyrene
Pyridine
Safrole
Thionazin
UNITS
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
PQL
10
10
2
10
10
2
2
0.05
2
2
10
10
2
10
10
10
10
2
10
10
10
2
2
10
10
10
10
10
10
10
10
10
20
10
10
2
2
10
10
2
10
10
10
10
US EPA Method
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
4,4'-DDD
4,4'-DDE
4,4'-DDT
Aldrin
alpha-BHC
beta-BHC
delta-BHC
Dieldrin
Endosulfan I
Endosulfan II
Endosulfan sulfate
Endrin
Endrin aldehyde
Endrin ketone
gamma-BHC (Lindane)
Heptachlor
Heptachlor epoxide
Methoxychlor
Toxaphene
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.1
2
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
0.048
0.048
0.048
0.048
0.048
0.048
0.48
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.8
0.048
0.095
1.9
PCBs
Aroclor 1016
Aroclor 1221
Aroclor 1232
Aroclor 1242
Aroclor 1248
Aroclor 1254
Aroclor 1260
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
0.4
0.4
0.4
0.4
0.4
0.4
0.4
SW846 8082
SW846 8082
SW846 8082
SW846 8082
SW846 8082
SW846 8082
SW846 8082
0.38
0.38
0.38
0.38
0.38
0.38
0.38
5/19/2009
9.6 U
9.6 U
1.9 U
9.6 U
9.6 U
1.9 U
1.9 U
1.9 U
1.9 U
9.6 U
9.6 U
9.6 U
1.9 U
9.6 U
2.2 J
9.6 U
9.6 U
1.9 U
9.6 U
9.6 U
9.6 U
1.9 U
1.9 U
9.6 U
9.6 U
9.6 U
9.6 U
9.6 U
9.6 U
9.6 U
9.6 U
9.6 U
19 U
9.6 U
9.6 U
1.9 U
1.9 U
9.6 U
9.6 U
1.9 U
2.6 J
9.6 U
9.6 U
NA
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
PG
U
U
U
U
U
U
U
U
U
U
Day 0
5/19/2009
10
10
2
10
10
2
2
2
2
10
10
10
2
10
10
10
10
2
10
10
10
2
2
10
10
10
10
10
10
10
10
10
20
10
10
2
2
10
10
2
2
10
10
NA
0.049
0.049
0.049
0.049
0.049
0.049
0.49
0.049
0.049
0.049
0.049
0.049
0.049
0.05
0.049
0.049
0.84
0.049
0.098
2
0.39
0.39
0.39
0.39
0.39
0.39
0.39
Location M
McKean County, PA
Day 1
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
6/6/2009
9.5 U
9.5 U
1.9 U
9.5 U
9.5 U
1.9 U
1.9 U
1.9 U
1.9 U
9.5 U
9.5 U
9.5 U
1.9 U
9.5 U
9.5 U
9.5 U
9.5 U
1.9 U
9.5 U
9.5 U
9.5 U
1.9 U
1.9 U
9.5 U
9.5 U
9.5 U
9.5 U
9.5 U
9.5 U
9.5 U
9.5 U
9.5 U
19 U
9.5 U
9.5 U
1.9 U
1.9 U
9.5 U
9.5 U
1.9 U
140
9.5 U
9.5 U
NA
Day 5
Day 14
6/10/2009
9.4 U
9.4 U
1.9 U
9.4 U
9.4 U
1.9 U
1.9 U
1.9 U
1.9 U
9.4 U
9.4 U
9.4 U
1.9 U
9.4 U
9.4 U
9.4 U
9.4 U
1.9 U
9.4 U
9.4 U
9.4 U
1.9 U
1.9 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
19 U
9.4 U
9.4 U
1.9 U
1.9 U
9.4 U
9.4 U
1.9 U
100
9.4 U
9.4 U
NA
6/19/2009
9.6 U
9.6 U
1.9 U
9.6 U
9.6 U
1.9 U
1.9 U
1.9 U
1.9 U
9.6 U
9.6 U
9.6 U
1.9 U
9.6 U
9.6 U
9.6 U
9.6 U
1.9 U
9.6 U
9.6 U
9.6 U
1.9 U
1.9 U
9.6 U
9.6 U
9.6 U
9.6 U
9.6 U
9.6 U
9.6 U
9.6 U
9.6 U
19 U
9.6 U
9.6 U
1.9 U
1.9 U
9.6 U
9.6 U
1.9 U
94
9.6 U
9.6 U
NA
U
U
PG
U
U
U
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.048
0.048
0.048
0.048
0.048
0.048
0.48
0.026
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.096
1.9
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.38
0.38
0.38
0.38
0.38
0.38
0.38
U
U
U
U
U
U
U
PARAMETER
Supply Water
Day 0
5/19/2009
5/19/2009
Location M
McKean County, PA
Day 1
Day 5
Day 14
6/10/2009
6/19/2009
UNITS
PQL
US EPA Method
Ethyl parathion
ug/L
0.4
SW846 8141A
0.95 U
0.97 U
NA
Alcohols
2-Propanol
Butyl alcohol
Ethanol
Methanol
n-Propanol
mg/L
mg/L
mg/L
mg/L
mg/L
10
10
10
10
10
SW846 8015
SW846 8015
SW846 8015
SW846 8015
SW846 8015
10
10
10
10
10
20
20
20
20
20
10
10
10
23
10
Glycols
Ethylene Glycol
Propylene glycol
mg/L
mg/L
50
50
SW846 8015
SW846 8015
100 UJ
100 UJ
200 UJ
200 UJ
100 UJ
100 UJ
100 UJ
100 UJ
Acids
Acetic Acid
Butyric Acid
Propionic Acid
Volatile Acids
mg/L
mg/L
mg/L
mg/L
10
10
10
10
SW846 8015
SW846 8015
SW846 8015
1U
1U
1U
57
100 UJ
100 UJ
100 UJ
2300
10 UJ
10 UJ
10 UJ
1100
500 UJ
500 UJ
500 UJ
1200
UJ
UJ
UJ
UJ
UJ
6/6/2009
UJ
UJ
UJ
UJ
UJ
NA
UJ
UJ
UJ
J
UJ
10
10
10
21
10
1U
UJ
UJ
UJ
J
UJ
10
10
10
16
10
UJ
UJ
UJ
J
UJ
100 U
100 U
10 UJ
10 UJ
10 UJ
52000
Location O
Susquehanna County
Day 1
Day 5
Day 0
PARAMETER
Acidity
Amenable cyanide
Ammonia Nitrogen
Bromide
Chloride
Fluoride
Hardness, as CaCO3
Nitrate as N
Nitrate-Nitrite
Nitrite as N
Oil & Grease (HEM)
Sulfate
TOC
Total Alkalinity
Total phosphorus
Turbidity
Cyanide, Total
Total Sulfide
pH
Sulfite
MBAS (mol.wt 320)
Aluminum
Aluminum-DISS
Antimony
Antimony-DISS
Arsenic
Arsenic-DISS
Barium
Barium-DISS
Beryllium
Beryllium-DISS
Boron
Boron-DISS
Cadmium
Cadmium-DISS
Calcium
Calcium-DISS
Chromium
Chromium-DISS
Cobalt
Cobalt-DISS
Copper
Copper-DISS
Iron
Iron-DISS
Lead
Lead-DISS
Lithium
Lithium-DISS
Magnesium
Magnesium-DISS
Manganese
Manganese-DISS
Molybdenum
Molybdenum-DISS
Nickel
Nickel-DISS
Potassium
Potassium-DISS
Selenium
Selenium-DISS
Silver
Silver-DISS
UNITS
PQL
US EPA Method
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
umhos/cm
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
NTU
ug/L
mg/L
No Units
mg/L
mg/L
mg/L
5
0.01
0.1
2
1
10
1
-1
5
0.05
0.1
0.05
5
-1
1
5
10
3
0.1
4
-10
3
-0.01
1
0.05
SM20 2310B (4a)

SM18 4500-CN E
MCAWW 350.1
SM18 5210 B
MCAWW 300.0A
MCAWW 410.4
MCAWW 300.0A
SM20 5310B
MCAWW 300.0A
SM20 2340C
MCAWW 300.0A
MCAWW 353.2
MCAWW 300.0A
CFR136A 1664A HEM
MCAWW 120.1
MCAWW 300.0A
SM20 5310B
SM18 2320 B
SM18 2540 C
MCAWW 351.3
MCAWW 365.2
SM20 2540D
MCAWW 180.1
SW846 9012A
SW846 9030B/9034
SW846 9040
SW846 9066
SM4500-SO3 B
SM5540 C
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
200
200
10
10
10
10
200
200
4
4
2000
2000
5
5
5000
5000
5
5
500
500
25
25
100
100
3
3
500
500
5000
5000
150
150
400
400
40
40
5000
5000
5
5
5
5
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
7/1/2009
7/1/2009
5
0.01
10
924
20
2420
1060
558
5
570
5
0.1
5
255
4000
100
575
66.1
2670
89.9
0.5
5290
505
10
3
7.2
0.77
47.2
0.05
1030
162
100
100
100
100
72200
62300
40
40
1190
1310
50
50
123000
120000
17.3
50
500
500
79.4
34.1
7400
954
19.4
30
1800
1930
14700
14800
288
196
50.6
58.4
400
400
7840
6850
50
50
50
50
U
U
GU
J
GU
GU
GU
J
GU
J
J
U
U
J
U
B
BJ
U
U
U
U
U
U
B
B
U
U
J
J
B
U
U
U
B
B
B
B
U
B
B
BJ
B
U
U
B
B
U
U
U
U
5
0.01
52
606
69.8
1480
7860
271
2.5
25000
2.5
0.18
6.7
4.6
30700
50
308
114
17400
88.8
21.8
4
152
21.5
3
6.5
0.036
26.8
0.198
1120
274
15.8
15
48
28
387000
447000
40
40
808
944
50
50
676000
800000
37.5
12.9
500
500
250
250
20900
18000
30
30
14200
17300
65700
76400
760
823
25.9
24.1
48.3
39.5
33500
39900
50
50
50
50
Day 14
7/6/2009
U
NR U
GU
GU
U
J
GU
J
U
J
B
B
B
B
B
B
U
U
B
B
U
U
J
J
B
B
U
U
U
U
J
U
U
J
B
B
B
B
B
B
U
U
U
U
48.7
0.01
135
1520
885
7390
86800
240
2.5
36000
2.5
0.1
19.9
40.7
261000
50
237
94.2
125000
147
2.3
302
54.6
5.2
3.2
6.5
0.15
16.8
0.0897
536
172
100
100
100
100
13900000
12700000
40
40
3570
3200
50
50
9250000
8200000
33.4
27.7
25000
25000
250
250
43500
38400
30
30
132000
125000
691000
610000
5550
4960
400
400
400
400
353000
284000
50
50
50
50
07/15/2009
GU
GU
U
J
J
GU
J
B
BJ
U
U
U
U
U
U
U
U
J
J
B
B
U
U
U
U
U
U
U
U
U
U
U
U
U
U
473
0.01
237
725
872
10000
98300
695
2.5
54000
2.5
0.1
25.9
17.5
428000
50
509
95.1
186000
180
0.038
324
244
1.9
3
6.6
0.13
73.6
4.60
845
912
48.8
45
76.6
86.5
12500000
13600000
40
40
2520
2760
3.1
3.3
10300000
11200000
31.2
19.4
5000
5000
54.8
250
77500
58700
60
60
147000
162000
794000
858000
7100
7630
400
400
800
800
233000
253000
34
50
50
50
U
J
J
J
GU
GU
U
J
GU
J
J
B
U
B
B
BJ
BJ
B
B
J
U
U
J
J
B
B
B
B
U
U
B
U
U
U
J
U
U
U
U
B
U
U
U
Location O
Susquehanna County
Day 1
Day 5
Day 0
PARAMETER
Sodium
Sodium-DISS
Strontium
Strontium-DISS
Thallium
Thallium-DISS
Tin
Tin-DISS
Titanium
Titanium-DISS
Trivalent Chrom
Zinc
Zinc-DISS
Hexavalent Chromium
Mercury
Mercury-DISS
1,1-Dichloroethane
1,1-Dichloroethene
1,1-Dichloropropene
1,2-Dichlorobenzene
1,2-Dichloroethane
1,2-Dichloropropane
1,3-Dichlorobenzene
1,3-Dichloropropane
1,4-Dichlorobenzene
1,4-Dioxane
2,2-Dichloropropane
2-Butanone
2-Hexanone
4-Chlorotoluene
Acetone
Acrolein
Acrylonitrile
Benzene
Benzyl chloride
Bromobenzene
Bromoform
Bromomethane
Carbon disulfide
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
Dibromomethane
Ethylbenzene
Isopropylbenzene
Methylene chloride
Naphthalene
n-Butylbenzene
n-Propylbenzene
p-Isopropyltoluene
sec-Butylbenzene
Styrene
UNITS
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
mg/L
mg/L
ug/L
ug/L
PQL
5000
5000
50
50
10
10
1000
1000
500
500
50
20
20
0.01
0.01
0.2
0.2
US EPA Method
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 7196A
SW846 7196A
SW846 7470A
SW846 7470A
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
1000
-5
5
10
5
5
5
20
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
7/1/2009
589000
658000
27000
28200
100
29.5
1000
1000
500
500
50
1610
924
0.1
0.05
0.2
0.17
50
50
50
50
50
50
50
50
50
50
67
50
50
50
50
50
7.7
50
50
50
10000
NA
50
50
100
50
50
50
130
1000
1000
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
820
50
50
50
50
50
JE
JE
U
B
U
U
U
U
U
E
U
U
U
B
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
7/1/2009
3920000
4670000
196000
233000
100
100
1000
1000
33.8
48.6
50
244
287
0.1
0.1
0.2
0.2
25
25
25
25
25
25
25
25
25
25
59
25
25
25
25
25
6.7
25
25
25
5000
NA
25
17
50
25
25
25
69
500
500
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
720
25
25
25
25
25
J
J
U
U
U
U
B
B
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
J
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Day 14
7/6/2009
34100000
30900000
2960000
2660000
100
38
1000
1000
500
500
33.4
211
183
2
2
0.2
0.2
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
1000
NA
5
5
10
5
5
5
20
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
0.5
5
5
5
5
5
J
J
U
B
U
U
U
U
B
B
GU
GU
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
07/15/2009
36800000
39100000
3520000
3580000
200
200
1000
1000
126
152
50
229
127
13.2
2
0.2
0.2
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
1000
NA
5
5
10
5
5
5
20
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
J
J
J
U
U
U
U
B
B
U
J
BJ
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Location O
Susquehanna County
Day 1
Day 5
Day 0
PARAMETER
tert-butyl acetate
tert-Butylbenzene
Tetrachloroethene
tetrahydrofuran
Toluene
Trichloroethene
Vinyl acetate
Vinyl chloride
Xylenes (total)
1,3-Dinitrobenzene
1,4-Naphthoquinone
1-Naphthylamine
2,3,7,8-TCDD
2,4-Dimethylphenol
2,4-Dinitrophenol
2,4-Dinitrotoluene
2,6-Dichlorophenol
2,6-Dinitrotoluene
2-Chloronaphthalene
2-Chlorophenol
2-Methylnaphthalene
2-Methylphenol
2-Naphthylamine
2-Nitroaniline
2-Nitrophenol
2-Picoline
3-Nitroaniline
4-Aminobiphenyl
4-Chloroaniline
4-Nitroaniline
4-Nitrophenol
5-Nitro-o-toluidine
Acenaphthene
Acenaphthylene
Acetophenone
Aniline
Aramite
Benzidine
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(ghi)perylene
Benzyl alcohol
Chlorobenzilate
Chrysene
Diallate
Dibenzofuran
Diethyl phthalate
Dimethoate
Dimethyl phthalate
UNITS
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
PQL
-5
5
-5
5
5
5
5
5
5
15
US EPA Method
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
10
2
10
10
10
10
-10
10
10
40
10
2
10
10
2
10
2
10
10
50
10
10
10
10
10
50
50
10
10
10
10
10
50
50
100
10
2
2
10
10
10
200
10
5
2
2
2
10
10
2
2
10
10
10
2
10
2
10
10
10
10
10
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
7/1/2009
NA
50
50
NA
19
50
50
50
50
50
50
46
190
38
190
190
190
190
NA
190
190
190
940
190
38
190
190
38
190
260
190
190
940
190
190
190
190
190
940
940
190
190
190
190
190
940
940
1900
190
38
38
190
190
190
3800
38
38
38
38
38
190
190
38
38
190
190
190
38
190
38
190
190
190
190
190
U
U
J
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
7/1/2009
NA
25
25
NA
25
25
25
25
25
25
25
26
94
19
94
94
94
94
NA
94
94
94
470
94
19
94
94
19
94
52
94
94
470
94
94
94
94
94
470
470
94
94
94
94
94
470
470
940
94
19
19
94
94
94
1900
19
19
19
19
19
94
94
19
19
94
94
94
19
94
19
94
94
94
94
94
Day 14
7/6/2009
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
07/15/2009
NA
5
5
NA
0.94
5
5
5
5
5
5
15
9.8
2
9.8
9.8
9.8
9.8
NA
9.8
9.8
9.8
49
9.8
2
9.8
9.8
2
9.8
2
9.8
9.8
49
9.8
9.8
9.8
9.8
9.8
49
49
9.8
9.8
9.8
9.8
9.8
49
49
98
9.8
2
2
9.8
9.8
9.8
200
2
2
2
2
2
9.8
9.8
2
2
2.5
9.8
9.8
2
9.8
2
9.8
9.8
9.8
9.8
9.8
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
NA
5
5
NA
5
5
5
5
5
5
5
15
940
190
940
940
940
940
NA
940
940
940
4700
940
190
940
940
190
940
190
940
940
4700
940
940
940
940
940
4700
4700
940
940
940
940
940
4700
4700
9400
940
190
190
940
940
940
19000
190
190
190
190
190
940
940
190
190
940
940
940
190
940
190
940
940
940
940
940
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Location O
Susquehanna County
Day 1
Day 5
Day 0
PARAMETER
Dinoseb
Diphenylamine
Disulfoton
Fluoranthene
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hexachloroethane
Hexachloropropene
Isodrin
Isophorone
Isosafrole
Nitrobenzene
N-Nitrosomorpholine
N-Nitrosopiperidine
o-Toluidine
Parathion
Pentachlorobenzene
Pentachloroethane
Pentachlorophenol
Phenanthrene
Phenol
Phorate
Pronamide
Pyrene
Pyridine
Safrole
Thionazin
UNITS
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
PQL
10
10
2
10
10
2
2
0.05
2
2
10
10
2
10
10
10
10
2
10
10
10
2
2
10
10
10
10
10
10
10
10
10
20
10
10
2
2
10
10
2
10
10
10
10
US EPA Method
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
4,4'-DDD
4,4'-DDE
4,4'-DDT
Aldrin
alpha-BHC
beta-BHC
delta-BHC
Dieldrin
Endosulfan I
Endosulfan II
Endosulfan sulfate
Endrin
Endrin aldehyde
Endrin ketone
gamma-BHC (Lindane)
Heptachlor
Heptachlor epoxide
Methoxychlor
Toxaphene
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.1
2
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
0.051
0.051
0.051
0.11
0.051
0.051
0.51
0.051
0.051
0.051
0.051
0.051
0.051
0.051
0.051
0.051
0.065
0.051
0.1
2
PCBs
Aroclor 1016
Aroclor 1221
Aroclor 1232
Aroclor 1242
Aroclor 1248
Aroclor 1254
Aroclor 1260
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
0.4
0.4
0.4
0.4
0.4
0.4
0.4
SW846 8082
SW846 8082
SW846 8082
SW846 8082
SW846 8082
SW846 8082
SW846 8082
0.41
0.41
0.41
0.41
0.41
0.41
0.41
7/1/2009
190
190
38
190
190
38
38
38
38
190
190
190
38
190
190
190
190
38
190
190
190
38
38
190
190
190
190
190
190
190
190
190
380
190
190
38
38
190
190
38
190
190
190
NA
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
7/1/2009
94
94
19
94
94
19
19
19
19
94
94
94
19
94
94
94
94
19
94
94
94
19
19
94
94
94
94
94
94
94
94
94
190
94
94
19
3.5
94
94
19
94
94
94
NA
Day 14
7/6/2009
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
9.8
9.8
2
9.8
9.8
2
2
2
2
9.8
9.8
9.8
2
9.8
9.8
9.8
9.8
2
9.8
9.8
9.8
2
2
9.8
9.8
9.8
9.8
9.8
9.8
9.8
9.8
9.8
20
9.8
9.8
2
2
9.8
9.8
2
1.1
9.8
9.8
NA
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
07/15/2009
940
940
190
940
940
190
190
190
190
940
940
940
190
940
940
940
940
190
940
940
940
190
190
940
940
940
940
940
940
940
940
940
1900
940
940
190
190
940
940
190
940
940
940
NA
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
PG
U
U
U
U
U
U
U
U
U
U
U
U
PG
U
U
U
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.048
0.048
0.048
0.048
0.048
0.048
0.48
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.095
1.9
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.38
0.38
0.38
0.38
0.38
0.38
0.38
U
U
U
U
U
U
U
Location O
Susquehanna County
Day 1
Day 5
Day 0
PARAMETER
Day 14
UNITS
PQL
US EPA Method
Ethyl parathion
ug/L
0.4
SW846 8141A
Alcohols
2-Propanol
Butyl alcohol
Ethanol
Methanol
n-Propanol
mg/L
mg/L
mg/L
mg/L
mg/L
10
10
10
10
10
SW846 8015
SW846 8015
SW846 8015
SW846 8015
SW846 8015
20
20
120
20
20
Glycols
Ethylene Glycol
Propylene glycol
mg/L
mg/L
50
50
SW846 8015
SW846 8015
200 UJ
200 UJ
200 UJ
200 UJ
100 UJ
100 UJ
100 UJ
100 UJ
Acids
Acetic Acid
Butyric Acid
Propionic Acid
Volatile Acids
mg/L
mg/L
mg/L
mg/L
10
10
10
10
SW846 8015
SW846 8015
SW846 8015
50 UJ
50 UJ
50 UJ
200
1U
1U
1U
200
1U
1U
1U
300
20 UJ
20 UJ
20 UJ
800
7/1/2009
7/1/2009
1U
UJ
UJ
J
UJ
UJ
7/6/2009
NA
10
10
230
10
10
07/15/2009
NA
UJ
UJ
J
UJ
UJ
10
10
110
10
10
4.8 U
UJ
UJ
J
UJ
UJ
10
10
39
10
10
UJ
UJ
J
UJ
UJ
Location Q
Day 1
Day 5
Day 14
Day 0
PARAMETER
Acidity
Amenable cyanide
Ammonia Nitrogen
Bromide
Chloride
Fluoride
Hardness, as CaCO3
Nitrate as N
Nitrate-Nitrite
Nitrite as N
Oil & Grease (HEM)
Sulfate
TOC
Total Alkalinity
Total phosphorus
Turbidity
Cyanide, Total
Total Sulfide
pH
Sulfite
MBAS (mol.wt 320)
Aluminum
Aluminum-DISS
Antimony
Antimony-DISS
Arsenic
Arsenic-DISS
Barium
Barium-DISS
Beryllium
Beryllium-DISS
Boron
Boron-DISS
Cadmium
Cadmium-DISS
Calcium
Calcium-DISS
Chromium
Chromium-DISS
Cobalt
Cobalt-DISS
Copper
Copper-DISS
Iron
Iron-DISS
Lead
Lead-DISS
Lithium
Lithium-DISS
Magnesium
Magnesium-DISS
Manganese
Manganese-DISS
Molybdenum
Molybdenum-DISS
Nickel
Nickel-DISS
Potassium
Potassium-DISS
Selenium
Selenium-DISS
Silver
Silver-DISS
6/30/2009
UNITS
PQL
US EPA Method
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
umhos/cm
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
NTU
ug/L
mg/L
No Units
mg/L
mg/L
mg/L
5
0.01
0.1
2
1
10
1
-1
5
0.05
0.1
0.05
5
-1
1
5
10
3
0.1
4
-10
3
-0.01
1
0.05
SM20 2310B (4a)

SM18 4500-CN E
MCAWW 350.1
SM18 5210 B
MCAWW 300.0A
MCAWW 410.4
MCAWW 300.0A
SM20 5310B
MCAWW 300.0A
SM20 2340C
MCAWW 300.0A
MCAWW 353.2
MCAWW 300.0A
CFR136A 1664A HEM
MCAWW 120.1
MCAWW 300.0A
SM20 5310B
SM18 2320 B
SM18 2540 C
MCAWW 351.3
MCAWW 365.2
SM20 2540D
MCAWW 180.1
SW846 9012A
SW846 9030B/9034
SW846 9040
SW846 9066
SM4500-SO3 B
SM5540 C
5
0.01
1.8
121
4.5
1770
78.1
467
0.25
88
0.25
0.33
0.25
5
426
45.3
410
49
311
11.9
0.034
120
20.7
92.4
4.8
6.9
0.033
12.0
0.501
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
200
200
10
10
10
10
200
200
4
4
2000
2000
5
5
5000
5000
5
5
500
500
25
25
100
100
3
3
500
500
5000
5000
150
150
400
400
40
40
5000
5000
5
5
5
5
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
2000
2000
100
100
100
100
227
294
40
40
2000
33.5
50
50
27800
26800
50
50
500
500
39.7
35.6
429
1000
30
30
500
500
6400
6090
8.2
150
400
400
400
400
50000
4110
50
50
50
50
7/1/2009
U
NR U
J
GU
GU
GU
U
J
J
J
J
U
U
U
U
U
U
B
B
U
U
U
B
U
U
BJ
BJ
U
U
U
U
B
B
BJ
U
U
U
U
U
B
B
BJ
U
U
U
U
U
U
B
U
U
U
U
5
0.01
16.1
184
87.9
1080
8960
341
2.5
2200
2.5
0.51
6.5
4.8
39800
31.8
142
338
16600
24.3
0.16
9.2
11.7
21.2
3.2
7.5
0.0087
12.4
0.05
395
190
24.7
25.2
100
100
37600
43800
40
40
5110
5840
50
50
641000
728000
50
50
500
500
250
250
5830
5000
14.5
14.5
12300
14300
59800
67100
752
826
21.1
24.1
400
400
45400
53500
50
50
50
50
U
NR U
J
J
GU
GU
U
J
BJ
J
J
BJ
U
B
B
B
B
U
U
U
U
U
U
J
J
U
U
U
U
U
U
J
B
B
J
B
B
U
U
B
U
U
U
U
7/6/2009
5
0.01
65.4
144
310
1850
33500
160
2.5
9100
2.5
0.055
13.2
4.6
130000
50
46.5
140
38500
61.7
0.097
95
68.2
72.1
2.4
6.6
0.018
6.4
0.133
246
173
100
100
100
100
415000
401000
40
40
9070
8500
50
50
3120000
2890000
50
50
500
500
28.9
250
37500
30400
30
30
29300
27000
331000
307000
2300
2130
20.6
400
400
400
187000
163000
50
50
50
50
U
NR U
GU
GU
BJ
U
J
GU
J
J
B
J
B
BJ
U
U
U
U
U
U
U
U
J
J
U
U
U
U
B
U
U
U
BJ
U
U
U
U
U
U
U
Day 90
7/15/2009
63.2
0.01
102
98.1
720
14000
71500
25.8
2.5
32000
2.5
0.025
19.9
4.8
249000
50
24
113
120000
83.1
0.055
62
10.5
10
3
6.2
0.01
14.8
0.836
640
737
37.2
38.5
46.4
65
1700000
1730000
40
40
10400
10800
1.4
1.9
8790000
8730000
50
50
1000
1000
250
250
72700
72900
60
60
68700
69100
938000
963000
4790
4890
14.8
400
800
800
265000
267000
50
44.2
50
50
10/27/2009
U
J
GU
GU
B
U
J
GU
J
J
BJ
U
U
U
B
B
BJ
BJ
B
B
J
U
U
J
J
B
B
U
U
U
U
U
U
U
U
J
B
U
U
U
U
B
U
U
698
0.01
215
121
1090
7080
131000
18.4
2.5
90000
2.5
0.069
84.5
6.4
464000
50
34.1
52.9
207000
128
1
534
264
10
3
5.9
0.01
14.8
0.836
271
181
100
100
100
100
3440000
2560000
40
40
13600
10200
2.6
50
18000000
13400000
14.8
50
5000
5000
56.6
250
321000
220000
50
15.7
100000
74500
1690000
1290000
10200
7700
17.5
400
49.9
36.5
858000
611000
50
50
50
50
U
J
GU
GU
B
GU
J
GU
U
U
U
BJ
BJ
U
U
U
U
U
U
J
BJ
U
B
U
U
U
B
U
B
J
B
U
B
B
U
U
U
U
Day 0
PARAMETER
Sodium
Sodium-DISS
Strontium
Strontium-DISS
Thallium
Thallium-DISS
Tin
Tin-DISS
Titanium
Titanium-DISS
Trivalent Chrom
Zinc
Zinc-DISS
Hexavalent Chromium
Mercury
Mercury-DISS
1,1-Dichloroethane
1,1-Dichloroethene
1,1-Dichloropropene
1,2-Dichlorobenzene
1,2-Dichloroethane
1,2-Dichloropropane
1,3-Dichlorobenzene
1,3-Dichloropropane
1,4-Dichlorobenzene
1,4-Dioxane
2,2-Dichloropropane
2-Butanone
2-Hexanone
4-Chlorotoluene
Acetone
Acrolein
Acrylonitrile
Benzene
Benzyl chloride
Bromobenzene
Bromoform
Bromomethane
Carbon disulfide
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
Dibromomethane
Ethylbenzene
Isopropylbenzene
Methylene chloride
Naphthalene
n-Butylbenzene
n-Propylbenzene
p-Isopropyltoluene
sec-Butylbenzene
Styrene
Day 1
Location Q
Day 5
Day 14
UNITS
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
mg/L
mg/L
ug/L
ug/L
PQL
5000
5000
50
50
10
10
1000
1000
500
500
50
20
20
0.01
0.01
0.2
0.2
US EPA Method
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 7196A
SW846 7196A
SW846 7470A
SW846 7470A
6/30/2009
63200
67900
292 B J
254 B J
100 U
100 U
1000 U
1000 U
500 U
500 U
50 U
37.7 B
69 B J
0.5 G U
0.5 G U
0.2 U
0.095 B
7/1/2009
5400000
5960000
86200 J
98800 J
100 U
100 U
1000 U
1000 U
44.5 B
35.4 B
50 U
78.6 B
100 B J
0.5 G U
0.5 G U
0.2 U
0.2 U
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
1000
-5
5
10
5
5
5
20
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
1000
NA
5
5
10
5
5
5
28
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
1000
NA
5
5
10
5
5
5
16
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
7/6/2009
1.7E+07
1.6E+07
422000 J
396000 J
100 U
100 U
1000 U
22.4 B
500 U
500 U
50 U
156 B
159 B
0.1 G U
0.1 G U
0.2 U
0.2 U
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
1000
NA
5
5
10
5
5
5
42
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
4
5
5
5
5
5
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
Day 90
7/15/2009
30800000 J
31300000
1310000 J
1300000 J
200 U
200 U
1000 U
1000 U
139 B
113 B
50 U
144 B J
137 B J
0.25 G U
0.25 U
0.2 U
0.2 U
10/27/2009
49700000
36800000 J
2860000 J
2100000 J
100 U
100 U
1000 U
1000 U
500 U
500 U
50 U
247000 J
182000 J
1 GU
1 GU
0.2 U
0.2 U
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
10000
NA
50
50
100
50
50
50
520
1000
1000
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
5
5
5
5
5
5
5
4.9
5
5
5
5
5
5
5
5
5
5
5
5
1000
NA
5
5
10
5
5
5
20
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Day 0
PARAMETER
tert-butyl acetate
tert-Butylbenzene
Tetrachloroethene
tetrahydrofuran
Toluene
Trichloroethene
Vinyl acetate
Vinyl chloride
Xylenes (total)
1,3-Dinitrobenzene
1,4-Naphthoquinone
1-Naphthylamine
2,3,7,8-TCDD
2,4-Dimethylphenol
2,4-Dinitrophenol
2,4-Dinitrotoluene
2,6-Dichlorophenol
2,6-Dinitrotoluene
2-Chloronaphthalene
2-Chlorophenol
2-Methylnaphthalene
2-Methylphenol
2-Naphthylamine
2-Nitroaniline
2-Nitrophenol
2-Picoline
3-Nitroaniline
4-Aminobiphenyl
4-Chloroaniline
4-Nitroaniline
4-Nitrophenol
5-Nitro-o-toluidine
Acenaphthene
Acenaphthylene
Acetophenone
Aniline
Aramite
Benzidine
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(ghi)perylene
Benzyl alcohol
Chlorobenzilate
Chrysene
Diallate
Dibenzofuran
Diethyl phthalate
Dimethoate
Dimethyl phthalate
UNITS
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
PQL
-5
5
-5
5
5
5
5
5
5
15
US EPA Method
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
10
2
10
10
10
10
-10
10
10
40
10
2
10
10
2
10
2
10
10
50
10
10
10
10
10
50
50
10
10
10
10
10
50
50
100
10
2
2
10
10
10
200
10
5
2
2
2
10
10
2
2
10
10
10
2
10
2
10
10
10
10
10
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
Day 1
6/30/2009
NA
5U
5U
NA
5U
5U
5U
5U
5U
5U
5U
15 U
9.5
1.9
9.5
9.5
9.5
9.5
NA
9.5
9.5
9.5
48
9.5
1.9
9.5
9.5
1.9
9.5
1.9
9.5
9.5
48
9.5
9.5
9.5
9.5
9.5
48
48
9.5
9.5
9.5
9.5
9.5
48
48
95
9.5
1.9
1.9
9.5
9.5
9.5
190
1.9
1.9
1.9
1.9
1.9
9.5
9.5
1.9
1.9
10
9.5
9.5
1.9
9.5
1.9
9.5
9.5
9.5
9.5
1.1
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
7/1/2009
NA
5U
5U
NA
5U
5U
5U
5U
5U
5U
5U
15 U
9.5
1.9
9.5
9.5
9.5
9.5
NA
9.5
9.5
9.5
48
9.5
1.9
9.5
9.5
1.9
9.5
1.9
9.5
9.5
48
9.5
9.5
9.5
9.5
9.5
48
48
9.5
9.5
9.5
9.5
9.5
48
48
95
9.5
1.9
1.9
1.2
9.5
9.5
190
1.9
1.9
1.9
1.9
1.9
9.5
9.5
1.9
1.9
9.5
9.5
9.5
1.9
9.5
1.9
9.5
9.5
9.5
9.5
9.5
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Location Q
Day 5
Day 14
7/6/2009
NA
5U
5U
NA
1.2 J
5U
5U
5U
5U
5U
5U
4.4 J
9.4
1.9
9.4
9.4
9.4
9.4
NA
9.4
9.4
9.4
47
9.4
1.9
9.4
9.4
1.9
9.4
1.9
9.4
9.4
47
9.4
9.4
9.4
9.4
0.2
47
47
9.4
9.4
9.4
9.4
9.4
47
47
94
9.4
1.9
1.9
0.34
9.4
9.4
190
1.9
1.9
1.9
1.9
1.9
9.4
9.4
1.9
1.9
9.4
9.4
9.4
1.9
9.4
1.9
9.4
9.4
9.4
9.4
9.4
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Day 90
7/15/2009
NA
50 U
50 U
NA
50 U
50 U
50 U
50 U
50 U
50 U
50 U
150 U
9.4
1.9
9.4
9.4
9.4
9.4
NA
9.4
9.4
9.4
47
9.4
1.9
9.4
9.4
1.9
9.4
1.9
9.4
9.4
47
9.4
9.4
9.4
9.4
9.4
47
47
9.4
9.4
9.4
9.4
9.4
47
47
94
9.4
1.9
1.9
0.33
9.4
9.4
190
1.9
1.9
1.9
1.9
1.9
4.4
9.4
1.9
1.9
3.7
9.4
9.4
1.9
9.4
1.9
9.4
9.4
9.4
9.4
9.4
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
J
U
U
U
J
U
U
U
U
U
U
U
U
U
U
10/27/2009
NA
5U
5U
NA
5U
5U
5U
5U
5U
5U
5U
15 U
9.4
1.9
9.4
9.4
9.4
9.4
NA
9.4
9.4
9.4
47
9.4
1.9
9.4
9.4
1.9
9.4
1.9
9.4
9.4
47
9.4
9.4
9.4
9.4
9.4
47
47
9.4
9.4
9.4
9.4
9.4
47
47
94
9.4
1.9
1.9
9.4
9.4
9.4
190
1.9
1.9
1.9
1.9
1.9
9.4
9.4
1.9
1.9
2
9.4
9.4
1.9
9.4
1.9
9.4
9.4
9.4
9.4
9.4
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
Day 0
PARAMETER
Dinoseb
Diphenylamine
Disulfoton
Fluoranthene
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hexachloroethane
Hexachloropropene
Isodrin
Isophorone
Isosafrole
Nitrobenzene
N-Nitrosomorpholine
N-Nitrosopiperidine
o-Toluidine
Parathion
Pentachlorobenzene
Pentachloroethane
Pentachlorophenol
Phenanthrene
Phenol
Phorate
Pronamide
Pyrene
Pyridine
Safrole
Thionazin
Day 1
Location Q
Day 5
Day 14
Day 90
UNITS
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
PQL
10
10
2
10
10
2
2
0.05
2
2
10
10
2
10
10
10
10
2
10
10
10
2
2
10
10
10
10
10
10
10
10
10
20
10
10
2
2
10
10
2
10
10
10
10
US EPA Method
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
6/30/2009
9.5 U
9.5 U
1.9 U
9.5 U
9.5 U
1.9 U
1.9 U
1.9 U
1.9 U
9.5 U
9.5 U
9.5 U
1.9 U
9.5 U
9.5 U
9.5 U
9.5 U
1.9 U
9.5 U
9.5 U
9.5 U
1.9 U
1.9 U
9.5 U
9.5 U
9.5 U
9.5 U
9.5 U
9.5 U
9.5 U
9.5 U
9.5 U
19 U
9.5 U
9.5 U
1.9 U
1.9 U
9.5 U
9.5 U
1.9 U
9.5 U
9.5 U
9.5 U
NA
7/1/2009
9.5 U
9.5 U
1.9 U
9.5 U
9.5 U
1.9 U
1.9 U
1.9 U
1.9 U
9.5 U
9.5 U
9.5 U
1.9 U
9.5 U
9.5 U
9.5 U
9.5 U
1.9 U
9.5 U
9.5 U
9.5 U
1.9 U
1.9 U
9.5 U
9.5 U
9.5 U
9.5 U
9.5 U
9.5 U
9.5 U
9.5 U
9.5 U
19 U
9.5 U
9.5 U
1.9 U
1.9 U
9.5 U
9.5 U
1.9 U
9.5 U
9.5 U
9.5 U
NA
7/6/2009
9.4 U
9.4 U
1.9 U
9.4 U
9.4 U
1.9 U
1.9 U
1.9 U
1.9 U
9.4 U
9.4 U
9.4 U
1.9 U
9.4 U
9.4 U
9.4 U
9.4 U
1.9 U
9.4 U
9.4 U
9.4 U
1.9 U
1.9 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
19 U
9.4 U
9.4 U
1.9 U
1.9 U
9.4 U
9.4 U
1.9 U
9.4 U
9.4 U
9.4 U
NA
4,4'-DDD
4,4'-DDE
4,4'-DDT
Aldrin
alpha-BHC
beta-BHC
delta-BHC
Dieldrin
Endosulfan I
Endosulfan II
Endosulfan sulfate
Endrin
Endrin aldehyde
Endrin ketone
gamma-BHC (Lindane)
Heptachlor
Heptachlor epoxide
Methoxychlor
Toxaphene
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.1
2
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
0.048
0.048
0.048
0.17
0.048
0.26
0.48
0.072
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.12
0.26
0.095
1.9
PG
U
U
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.047
0.047
0.047
0.047
0.047
0.047
0.47
0.047
0.047
0.047
0.047
0.047
0.047
0.047
0.047
0.047
0.047
0.047
0.094
1.9
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
0.048
0.048
0.048
0.048
0.048
0.048
0.48
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.096
1.9
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
PCBs
Aroclor 1016
Aroclor 1221
Aroclor 1232
Aroclor 1242
Aroclor 1248
Aroclor 1254
Aroclor 1260
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
0.4
0.4
0.4
0.4
0.4
0.4
0.4
SW846 8082
SW846 8082
SW846 8082
SW846 8082
SW846 8082
SW846 8082
SW846 8082
0.38
0.38
0.38
0.38
0.38
0.38
0.38
U
U
U
U
U
U
U
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.38
0.38
0.38
0.38
0.38
0.38
0.38
U
U
U
U
U
U
U
0.4
0.4
0.4
0.4
0.4
0.4
0.4
U
U
U
U
U
U
U
U
U
U
PG
U
U
PG
U
U
U
U
U
U
U
U
7/15/2009
9.4 U
9.4 U
1.9 U
9.4 U
9.4 U
1.9 U
1.9 U
1.9 U
1.9 U
9.4 U
9.4 U
9.4 U
1.9 U
9.4 U
9.4 U
9.4 U
9.4 U
1.9 U
9.4 U
9.4 U
9.4 U
1.9 U
1.9 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
19 U
9.4 U
9.4 U
1.9 U
1.9 U
9.4 U
9.4 U
1.9 U
9.4 U
9.4 U
9.4 U
NA
10/27/2009
9.4 U
9.4 U
1.9 U
9.4 U
9.4 U
1.9 U
1.9 U
1.9 U
1.9 U
9.4 U
9.4 U
9.4 U
1.9 U
9.4 U
9.4 U
9.4 U
9.4 U
1.9 U
9.4 U
9.4 U
9.4 U
1.9 U
1.9 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
19 U
9.4 U
9.4 U
1.9 U
1.9 U
9.4 U
9.4 U
1.9 U
9.4 U
9.4 U
9.4 U
NA
PARAMETER
Location Q
Day 5
Day 14
Day 0
Day 1
6/30/2009
7/1/2009
7/6/2009
0.95 U
NA
NA
38
5
5
5
5
Day 90
UNITS
PQL
US EPA Method
Ethyl parathion
ug/L
0.4
SW846 8141A
Alcohols
2-Propanol
Butyl alcohol
Ethanol
Methanol
n-Propanol
mg/L
mg/L
mg/L
mg/L
mg/L
10
10
10
10
10
SW846 8015
SW846 8015
SW846 8015
SW846 8015
SW846 8015
110
20
20
20
20
Glycols
Ethylene Glycol
Propylene glycol
mg/L
mg/L
50
50
SW846 8015
SW846 8015
200 UJ
200 UJ
100 UJ
100 UJ
100 UJ
100 UJ
100 UJ
100 UJ
100 UJ
100 UJ
Acids
Acetic Acid
Butyric Acid
Propionic Acid
Volatile Acids
mg/L
mg/L
mg/L
mg/L
10
10
10
10
SW846 8015
SW846 8015
SW846 8015
20 UJ
20 UJ
20 UJ
300
1U
5 UJ
1U
100
33
1U
1U
120
33 J
10 UJ
10 UJ
600
33 J
10 UJ
10 UJ
600
J
UJJ
UJJ
UJ
UJ
J
UJ
UJ
UJ
UJ
28
10
10
10
10
J
UJ
UJ
UJ
UJ
7/15/2009
10/27/2009
0.95 U
0.98 U
20
10
10
10
10
20
10
10
10
10
J
UJ
UJ
UJ
UJ
J
UJ
UJ
UJ
UJ
PARAMETER
Acidity
Amenable cyanide
Ammonia Nitrogen
Bromide
Chloride
Fluoride
Hardness, as CaCO3
Nitrate as N
Nitrate-Nitrite
Nitrite as N
Oil & Grease (HEM)
Sulfate
TOC
Total Alkalinity
Total phosphorus
Turbidity
Cyanide, Total
Total Sulfide
pH
Sulfite
MBAS (mol.wt 320)
Aluminum
Aluminum-DISS
Antimony
Antimony-DISS
Arsenic
Arsenic-DISS
Barium
Barium-DISS
Beryllium
Beryllium-DISS
Boron
Boron-DISS
Cadmium
Cadmium-DISS
Calcium
Calcium-DISS
Chromium
Chromium-DISS
Cobalt
Cobalt-DISS
Copper
Copper-DISS
Iron
Iron-DISS
Lead
Lead-DISS
Lithium
Lithium-DISS
Magnesium
Magnesium-DISS
Manganese
Manganese-DISS
Molybdenum
Molybdenum-DISS
Nickel
Nickel-DISS
Potassium
Potassium-DISS
Selenium
Selenium-DISS
Silver
Silver-DISS
Location S
Centre County, PA
Day 1
Supply Water
Day 0
8/25/2009
8/25/2009
UNITS
PQL
US EPA Method
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
umhos/cm
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
NTU
ug/L
mg/L
No Units
mg/L
mg/L
mg/L
5
0.01
0.1
2
1
10
1
-1
5
0.05
0.1
0.05
5
-1
1
5
10
3
0.1
4
-10
3
-0.01
1
0.05
SM20 2310B (4a)

SM18 4500-CN E
MCAWW 350.1
SM18 5210 B
MCAWW 300.0A
MCAWW 410.4
MCAWW 300.0A
SM20 5310B
MCAWW 300.0A
SM20 2340C
MCAWW 300.0A
MCAWW 353.2
MCAWW 300.0A
CFR136A 1664A HEM
MCAWW 120.1
MCAWW 300.0A
SM20 5310B
SM18 2320 B
SM18 2540 C
MCAWW 351.3
MCAWW 365.2
SM20 2540D
MCAWW 180.1
SW846 9012A
SW846 9030B/9034
SW846 9040
SW846 9066
SM4500-SO3 B
SM5540 C
5
0.01
0.52
2
0.2
18.4
28.1
2.3
0.05
156
1.8
3
0.05
4.6
466
8.4
2.7
88.8
277
3
0.1
4
1.7
10
3.2
7
0.0065
11.2
0.0969
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
200
200
10
10
10
10
200
200
4
4
2000
2000
5
5
5000
5000
5
5
500
500
25
25
100
100
3
3
500
500
5000
5000
150
150
400
400
40
40
5000
5000
5
5
5
5
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
177
2000
15.4
100
100
100
840
734
40
40
18.9
15.8
1.7
2
40100
37500
50
50
500
500
250
250
394
1000
30
30
500
42.1
18300
17000
8.7
150
400
400
400
400
2930
3090
50
50
50
50
U
U
J
U
U
J
J
U
U
U
J
J
U
U
U
U
B
U
B
U
U
U
B
B
U
U
B
B
B
B
BJ
BJ
U
U
U
U
U
U
B
U
U
U
U
B
B
B
B
U
U
U
U
U
B
B
U
U
U
U
5
0.01
3
2220
0.2
4810
58.5
906
0.05
156
2.6
3.1
0.06
158
480
32.6
931
109
280
42.3
0.082
200
308
3.5
3
7.2
0.044
20
0.05
623
203
16.8
100
100
100
410
346
40
40
17.8
13.8
2.1
50
35200
36000
50
50
4.4
5.4
109
123
1790
726
30
30
42
31.1
15700
16200
37.9
30.5
400
400
400
400
2420
2590
50
50
50
50
8/25/2009
U
U
J
U
J
J
U
B
U
B
B
B
U
U
U
B
B
U
U
B
B
B
U
BJ
BJ
U
U
B
B
B
B
B
U
U
B
B
B
B
B
B
U
U
U
U
B
B
U
U
U
U
5
0.01
2.8
1440
0.2
3420
64.2
657
0.077
156
2.7
2.8
0.045
13.7
479
17.7
672
123
680
47.5
0.037
142
300
6.6
3
7.9
0.048
15.2
0.0613
507
165
100
13.5
100
100
332
240
40
40
18.1
14.2
2.2
1.3
35200
37800
7.5
50
5.7
6.2
43.9
37.2
6490
1670
30
30
500
500
16000
17300
146
119
14.2
400
16.7
400
2690
3000
50
50
50
50
U
U
J
U
J
J
B
J
B
U
B
B
U
B
U
U
B
B
U
U
B
B
B
B
BJ
BJ
B
U
B
B
B
B
U
U
U
U
B
B
B
B
B
U
B
U
B
B
U
U
U
U
Day 5
Day 14
8/29/2009
9/8/2009
22.9
0.01
44.8
218
306
1810
36800
217
1.2
15400
1.2
1.2
10.3
7.5
116000
2.4
104
175
58300
75.9
0.053
62
293
10
3
6.4
0.021
38.0
0.189
152
2000
31.3
24.1
100
100
652000
712000
40
40
7920
8950
3.8
50
4080000
4510000
50
50
500
500
71.4
55
77900
34700
21.2
30
34800
37800
373000
412000
1850
2030
39.1
26.8
19
400
301000
354000
50
50
50
50
U
J
J
GU
GU
J
J
BJ
J
U
U
B
U
B
B
U
U
U
U
B
U
J
J
U
U
U
U
B
B
B
U
B
B
B
U
U
U
U
U
90.2
0.01
128
990
602
21900
79000
214
2.5
34000
0.43
0.41
2.5
36.2
266000
33.5
150
74.2
124000
116
0.035
51
460
7.4
1.6
6.6
0.1
9.20
0.0945
2000
2000
49.1
100
100
100
1500000
1510000
40
40
13600
14000
3.9
3
11800000
12000000
10.2
50
2500
2500
35.3
38.8
73200
34000
21.7
30
94900
9310
987000
1000000
2670
2680
400
400
400
400
1020000
1050000
50
50
50
50
U
J
J
GU
B
GU
J
BJ
J
B
B
U
U
B
U
U
U
U
U
B
B
J
J
B
U
U
U
B
B
B
U
U
U
U
U
U
U
U
U
Supply Water
PARAMETER
Sodium
Sodium-DISS
Strontium
Strontium-DISS
Thallium
Thallium-DISS
Tin
Tin-DISS
Titanium
Titanium-DISS
Trivalent Chrom
Zinc
Zinc-DISS
Hexavalent Chromium
Mercury
Mercury-DISS
1,1-Dichloroethane
1,1-Dichloroethene
1,1-Dichloropropene
1,2-Dichlorobenzene
1,2-Dichloroethane
1,2-Dichloropropane
1,3-Dichlorobenzene
1,3-Dichloropropane
1,4-Dichlorobenzene
1,4-Dioxane
2,2-Dichloropropane
2-Butanone
2-Hexanone
4-Chlorotoluene
Acetone
Acrolein
Acrylonitrile
Benzene
Benzyl chloride
Bromobenzene
Bromoform
Bromomethane
Carbon disulfide
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
Dibromomethane
Ethylbenzene
Isopropylbenzene
Methylene chloride
Naphthalene
n-Butylbenzene
n-Propylbenzene
p-Isopropyltoluene
sec-Butylbenzene
Styrene
UNITS
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
mg/L
mg/L
ug/L
ug/L
PQL
5000
5000
50
50
10
10
1000
1000
500
500
50
20
20
0.01
0.01
0.2
0.2
US EPA Method
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 6010B
SW846 7196A
SW846 7196A
SW846 7470A
SW846 7470A
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
1000
-5
5
10
5
5
5
20
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
Location S
Centre County, PA
Day 1
Day 0
8/25/2009
37700
35300
723
653
100
100
1000
1000
500
500
50
172
156
0.01
0.01
0.2
0.2
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
1000
NA
5
5
10
5
5
5
20
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
B
B
E
JE
U
U
U
U
U
U
U
BJ
BJ
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
8/25/2009
60800
71800
597
624
100
100
1000
1000
500
500
50
164
140
0.0078
0.05
0.2
0.2
5
5
5
5
5
5
5
5
5
5
11
5
5
5
5
5
2.8
5
5
5
1000
NA
5
5
10
5
5
5
5.4
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
0.81
5
5
5
5
5
5
5
5
5
J
U
U
U
U
U
U
U
BJ
BJ
B
GU
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
Day 5
8/25/2009
63800
69200
580
594
100
100
1000
1000
500
500
50
138
73.8
0.05
0.05
0.2
0.2
5
5
5
5
5
5
5
5
5
5
33
5
5
5
5
5
13
5
5
5
1000
NA
5
5
10
5
5
5
14
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
1.8
5
5
5
1.8
5
5
5
5
5
J
U
U
U
U
U
U
U
BJ
BJ
GU
GU
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
J
U
U
U
U
U
8/29/2009
16400000
18000000
1560000
1710000
24.6
100
1000
1000
500
500
50
343
238
0.5
0.42
0.2
0.049
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
10000
NA
50
50
100
50
50
50
1300
1000
1000
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
28
50
50
Day 14
J
B
U
U
U
U
U
U
J
J
GU
BG
U
BJ
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
9/8/2009
32700000
33000000
5020000
4930000
100
100
20.7
1000
500
500
50
604
673
0.5
0.25
0.2
0.2
5
5
5
5
5
5
5
6.5
5
1.5
3.9
5
5
5
5
5
1.1
5
5
5
1000
NA
5
5
10
5
5
5
31
100
100
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
2.8
5
5
5
5
5
J
U
U
B
U
U
U
U
J
J
GU
GU
U
U
U
U
U
U
U
U
U
U
J
J
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
PARAMETER
tert-butyl acetate
tert-Butylbenzene
Tetrachloroethene
tetrahydrofuran
Toluene
Trichloroethene
Vinyl acetate
Vinyl chloride
Xylenes (total)
1,3-Dinitrobenzene
1,4-Naphthoquinone
1-Naphthylamine
2,3,7,8-TCDD
2,4-Dimethylphenol
2,4-Dinitrophenol
2,4-Dinitrotoluene
2,6-Dichlorophenol
2,6-Dinitrotoluene
2-Chloronaphthalene
2-Chlorophenol
2-Methylnaphthalene
2-Methylphenol
2-Naphthylamine
2-Nitroaniline
2-Nitrophenol
2-Picoline
3-Nitroaniline
4-Aminobiphenyl
4-Chloroaniline
4-Nitroaniline
4-Nitrophenol
5-Nitro-o-toluidine
Acenaphthene
Acenaphthylene
Acetophenone
Aniline
Aramite
Benzidine
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(ghi)perylene
Benzyl alcohol
Chlorobenzilate
Chrysene
Diallate
Dibenzofuran
Diethyl phthalate
Dimethoate
Dimethyl phthalate
UNITS
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
PQL
-5
5
-5
5
5
5
5
5
5
15
US EPA Method
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
10
2
10
10
10
10
-10
10
10
40
10
2
10
10
2
10
2
10
10
50
10
10
10
10
10
50
50
10
10
10
10
10
50
50
100
10
2
2
10
10
10
200
10
5
2
2
2
10
10
2
2
10
10
10
2
10
2
10
10
10
10
10
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
Supply Water
Day 0
8/25/2009
8/25/2009
NA
5
5
NA
5
5
5
5
5
5
5
15
9.4
1.9
9.4
9.4
9.4
9.4
NA
9.4
9.4
9.4
47
9.4
1.9
9.4
9.4
1.9
9.4
1.9
9.4
9.4
47
9.4
9.4
9.4
9.4
9.4
47
47
9.4
9.4
9.4
9.4
9.4
47
47
94
9.4
1.9
1.9
9.4
9.4
9.4
190
1.9
1.9
1.9
1.9
1.9
9.4
9.4
1.9
1.9
1.9
9.4
9.4
1.9
9.4
1.9
9.4
9.4
9.4
9.4
0.6
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
JB
U
U
U
U
U
U
U
U
U
J
Location S
Centre County, PA
Day 1
Day 5
8/25/2009
NA
5
5
NA
1.6
5
5
5
5
5
5
5.4
9.4
1.9
9.4
9.4
9.4
9.4
NA
9.4
9.4
9.4
47
9.4
1.9
9.4
9.4
1.9
9.4
1.9
9.4
9.4
47
9.4
9.4
9.4
9.4
9.4
47
47
9.4
9.4
9.4
9.4
9.4
47
47
94
9.4
1.9
1.9
9.4
9.4
9.4
190
1.9
1.9
1.9
1.9
1.9
9.4
9.4
1.9
1.9
14
9.4
9.4
1.9
9.4
1.9
9.4
9.4
9.4
9.4
2
U
U
J
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
NA
5
5
NA
3.8
5
5
5
5
5
5
16
9.4
1.9
9.4
9.4
9.4
9.4
NA
9.4
9.4
9.4
47
9.4
1.9
9.4
9.4
1.9
9.4
1.9
9.4
9.4
47
9.4
9.4
9.4
9.4
9.4
47
47
9.4
9.4
9.4
9.4
9.4
47
47
94
9.4
1.9
1.9
9.4
9.4
9.4
190
1.9
1.9
1.9
1.9
1.9
9.4
9.4
1.9
1.9
9.4
9.4
9.4
1.9
9.4
1.9
9.4
9.4
9.4
9.4
9.4
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
8/29/2009
NA
50
50
NA
50
50
50
50
50
50
50
150
94
19
94
94
94
94
NA
94
94
94
470
94
19
94
94
19
94
19
94
94
470
94
94
94
94
1.9
470
470
94
94
94
94
94
470
470
940
94
19
19
94
94
94
1900
19
19
19
19
19
94
94
19
19
94
94
94
19
94
19
94
7.7
94
94
94
Day 14
9/8/2009
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
JB
U
U
U
NA
5
5
NA
5
5
5
5
5
5
5
15
9.5
1.9
9.5
9.5
9.5
9.5
NA
9.5
9.5
9.5
48
9.5
1.9
9.5
9.5
1.9
9.5
1.9
9.5
9.5
48
9.5
9.5
9.5
9.5
9.5
48
48
9.5
9.5
9.5
9.5
9.5
48
48
95
9.5
1.9
1.9
9.5
9.5
9.5
190
1.2
1.1
1
1.2
0.91
9.5
9.5
1.9
1.9
7.5
9.5
9.5
1.1
9.5
2.3
9.5
2.6
9.5
9.5
1.5
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
J
J
J
J
U
U
U
U
JB
U
U
J
U
U
JB
U
U
J
PARAMETER
Dinoseb
Diphenylamine
Disulfoton
Fluoranthene
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hexachloroethane
Hexachloropropene
Isodrin
Isophorone
Isosafrole
Nitrobenzene
N-Nitrosomorpholine
N-Nitrosopiperidine
o-Toluidine
Parathion
Pentachlorobenzene
Pentachloroethane
Pentachlorophenol
Phenanthrene
Phenol
Phorate
Pronamide
Pyrene
Pyridine
Safrole
Thionazin
UNITS
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
PQL
10
10
2
10
10
2
2
0.05
2
2
10
10
2
10
10
10
10
2
10
10
10
2
2
10
10
10
10
10
10
10
10
10
20
10
10
2
2
10
10
2
10
10
10
10
US EPA Method
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
4,4'-DDD
4,4'-DDE
4,4'-DDT
Aldrin
alpha-BHC
beta-BHC
delta-BHC
Dieldrin
Endosulfan I
Endosulfan II
Endosulfan sulfate
Endrin
Endrin aldehyde
Endrin ketone
gamma-BHC (Lindane)
Heptachlor
Heptachlor epoxide
Methoxychlor
Toxaphene
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.1
2
PCBs
Aroclor 1016
Aroclor 1221
Aroclor 1232
Aroclor 1242
Aroclor 1248
Aroclor 1254
Aroclor 1260
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
0.4
0.4
0.4
0.4
0.4
0.4
0.4
Location S
Centre County, PA
Day 1
Supply Water
Day 0
8/25/2009
8/25/2009
Day 5
8/25/2009
9.4
9.4
1.9
9.4
9.4
1.9
1.9
1.9
1.9
9.4
9.4
9.4
1.9
9.4
9.4
9.4
9.4
1.9
9.4
9.4
9.4
1.9
1.9
9.4
9.4
9.4
9.4
9.4
9.4
9.4
9.4
9.4
19
9.4
9.4
1.9
1.9
9.4
9.4
1.9
9.4
9.4
9.4
NA
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
9.4
9.4
1.9
9.4
9.4
1.9
2
1.9
1.9
9.4
9.4
9.4
1.9
9.4
9.4
9.4
9.4
1.9
9.4
9.4
9.4
1.9
1.9
9.4
9.4
9.4
9.4
9.4
9.4
9.4
9.4
9.4
19
9.4
9.4
3.4
1.9
9.4
9.4
0.76
70
9.4
9.4
NA
U
U
U
U
U
U
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
SW846 8081A
0.047
0.047
0.047
0.047
0.047
0.047
0.47
0.047
0.047
0.047
0.047
0.047
0.047
0.047
0.047
0.047
0.051
0.047
0.094
1.9
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
0.047
0.047
0.047
0.047
0.047
0.047
0.47
0.047
0.047
0.047
0.047
0.047
0.047
0.047
0.047
0.041
0.063
0.047
0.094
1.9
SW846 8082
SW846 8082
SW846 8082
SW846 8082
SW846 8082
SW846 8082
SW846 8082
0.38
0.38
0.38
0.38
0.38
0.38
0.38
U
U
U
U
U
U
U
0.38
0.38
0.38
0.38
0.38
0.38
0.38
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
9.4
9.4
1.9
9.4
9.4
1.9
1.9
1.9
1.9
9.4
9.4
9.4
1.9
9.4
9.4
9.4
9.4
1.9
9.4
9.4
9.4
1.9
1.9
9.4
9.4
9.4
9.4
9.4
9.4
9.4
9.4
9.4
19
9.4
9.4
3.5
1.9
9.4
9.4
0.89
18
9.4
9.4
NA
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
Day 14
8/29/2009
94
94
19
94
94
19
19
19
19
94
94
94
19
94
94
94
94
19
94
94
94
19
19
94
94
94
94
94
94
94
94
94
190
94
94
19
19
94
94
19
530
94
94
NA
9/8/2009
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
9.3
9.5
1.7
9.5
9.5
1.3
1.4
1
1.9
9.5
9.5
9.5
2.4
9.5
9.5
9.5
9.5
1.9
9.5
9.5
9.5
1.9
1.7
9.5
9.5
9.5
9.5
9.5
9.5
9.5
9.5
9.5
19
9.5
9.5
1.3
1.9
9.5
9.5
1.1
280
9.5
9.5
NA
U
U
U
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.049
0.049
0.049
0.049
0.049
0.049
0.49
0.048
0.049
0.5
0.049
0.049
0.049
0.049
0.049
0.049
0.049
0.049
0.098
2
U
U
U
U
U
U
U
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.39
0.39
0.39
0.39
0.39
0.39
0.39
J
U
J
U
U
J
J
J
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
J
U
U
U
U
U
U
U
U
U
J PG
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
PARAMETER
Location S
Centre County, PA
Day 1
Supply Water
Day 0
8/25/2009
8/25/2009
Day 5
Day 14
8/29/2009
9/8/2009
UNITS
PQL
US EPA Method
Ethyl parathion
ug/L
0.4
SW846 8141A
0.94 U
Alcohols
2-Propanol
Butyl alcohol
Ethanol
Methanol
n-Propanol
mg/L
mg/L
mg/L
mg/L
mg/L
10
10
10
10
10
SW846 8015
SW846 8015
SW846 8015
SW846 8015
SW846 8015
10
10
10
10
10
Glycols
Ethylene Glycol
Propylene glycol
mg/L
mg/L
50
50
SW846 8015
SW846 8015
100 U
100 U
200 U
240
200 UJ
200 UJ
100 UJ
150 J
100 UJ
110 J
Acids
Acetic Acid
Butyric Acid
Propionic Acid
Volatile Acids
mg/L
mg/L
mg/L
mg/L
10
10
10
10
SW846 8015
SW846 8015
SW846 8015
1U
1U
1U
15
50 U
50 U
50 U
150
1.4
1U
1U
75
5.8 J
1U
2 UJ
600
6.6 J
2 UJ
2 UJ
600
U
U
U
U
U
8/25/2009
0.95 U
NA
310
20
20
20
20
150
20
20
20
20
U
U
U
U
NA
J
UJ
UJ
UJ
UJ
140
10
10
10
10
0.98 U
J
UJ
UJ
UJ
UJ
83
10
10
10
10
J
UJ
UJ
UJ
UJ

The Gas Technology Institute (GTI), Sampling and Analysis of Water Streams Associated with the Development of Marcellus Shale Gas, Final report, prepared for: Marcellus Shale Coalition (Formerly the Marcellus Shale Committee), December 31, 2009.

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The Gas Technology Institute (GTI), Sampling and Analysis of Water Streams Associated with the Development of Marcellus Shale Gas, Final report, prepared for: Marcellus Shale Coalition (Formerly the Marcellus Shale Committee), December 31, 2009.

Hochgeladen von

Copyright:

Verfügbare Formate

Sampling and Analysis of Water Streams

Associated with the Development of Marcellus

December 31, 2009

List of Acronyms and Abbreviations

ASWCMC Appalachian Shale Water

Marcellus Shale Coalition

Barrel (42 gallons)

Billion Cubic Feet

Micrograms per liter (ppb)

Quality Assurance Project Plan

The water stream that

Trillion Cubic Feet

Total Dissolved Solids

Well completion event

Total Petroleum Hydrocarbons

Field Sampling and

Milligrams per liter (ppm)

Publicly Owned Treatment

WVDEP West Virginia Department of

Methods and Procedures ................................................. 10

Results and Discussion .................................................... 19

Flowback Water Collection Characteristics ...................... 22

Implications for Fate and Transport.................................. 37

Measurements and Determinations

Water Use and Flowback Water Collection Associated with Hydraulic

Concentration of Total Dissolved Solids in Flowback Water at 19

Summary of Chemical Characteristics of Influent Water(1) Used for

Summary of Chemical Characteristics of Water Supplies(1) used for

Summary of Chemical Characteristics of Flowback Water Sampled 5

Summary of Chemical Characteristics of Flowback Water Sampled at 14

Total Metals Concentrations in the Influent Water and 5-day Flowback

Comparisons of Metals Levels in Shale Gas Waters with Municipal

companies of the Appalachian Shale Water Conservation and Management

usually below 10 ppb.

Pesticide concentrations measured in the samples were

2.0 Methods and Procedures

Determine whether hydraulic fracturing additives are a source of COI in the

Flowback water samples collected on days 1, 5 and 14 following the fracturing

Water from an existing producing well at 90 days following hydraulic fracturing.

A supply water sample (before the blending of additives);

Flowback water samples collected on 1, 5 and 14 days after hydraulic

Water from the producing well at 90 days after completion.

Table 1. Measurements and Determinations

Total Kjeldahl Nitrogen

Oil & Grease (HEM)

Volatile Organic Compounds

Semivolatile Organic Compounds

Dibenz (a, h) anthracene

Polychlorinated Biphenyls (PCBs)

Table 2. Summary of Methods

SM20 2310 B (4a)

Biochemical Oxygen Demand

Chemical Oxygen Demand

Dissolved Organic Carbon

EPA 901.1 MOD

Mercury in Liquid Waste

N-Hexane Extractable Material

Semivolatile Organic Compounds

Table 2. Summary of Methods

Total Dissolved Solids

Total Kjeldahl Nitrogen

Total Organic Carbon

Total Suspended Solids

Trace Inductively Coupled