Beruflich Dokumente
Kultur Dokumente
IV Part 1
Version: 24.8.2010
Version: 24.8.2010
11/5/12
Human induced changes on major biogeochemical cycles Climate change and global warming Green house effect and green house gases
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Burning
of
Fossil
Fuels
and
Biomass
[2]
Fossil
fuel
combustion
also
produces
aerosols
i.e.
tiny
particles
consisting
of
sulfates,
nitrates,
carbon,
mineral
dusts
and
ash.
Aerosols
enhance
scattering
and
absorption
of
sunlight
in
atmosphere
and
cause
clouds
to
form,
but
less
likely
to
release
their
precipitation.
Both
the
clouds
and
light-scattering
effect
in
atmosphere
cause
a
warming
of
atmosphere
and
a
threefold
reduction
in
the
amount
of
solar
radiation
reaching
Earths
surface,
and
ocean;
ultimately
affect
the
hydrological
cycle
as
well.
5
Burning of Fossil Fuels and Biomass [3] When fossil fuels are burned, the oxygen and nitrogen combine to produce nitrogen oxides which play vital role in producing photochemical smog - mixture of air pollutants that injures plant tissues, irritates eyes, and causes respiratory problems Nitrogen oxides also react with water in atmosphere to form acids that leave the atmosphere as acid deposition and cause the pH of surface waters and soils to decrease. Coal, and to a lesser extent liquid fuel, contain sulfur and upon combustion emit sulfur dioxide a major cause of acid deposition.
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Agricultural
Runoff
Nutrients
in
fertilizers
are
intended
to
become
incorporated
into
the
bodies
of
the
plants
and
animals
that
we
raise
for
food.
Excess
nitrogen
or
phosphorus
is
carried
into
aquatic
ecosystems
and
also
leach
to
groundwater.
Animal
wastes
that
contain
nitrogen
and
phosphorus
compounds
often
enter
local
water
sources.
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Agricultural
Runoff
Addition
of
nitrogen
and
phosphorus
to
aquatic
ecosystems
is
particularly
signiYicant.
Presence
of
large
amounts
of
these
nutrients
in
either
freshwater
or
saltwater
results
in
increased
rates
of
growth
of
bacteria,
algae,
and
aquatic
plants.
Many
algae
are
toxic,
and
when
their
numbers
increase
signiYicantly,
Yish
are
killed
and
incidents
of
human
poisoning
occur.
Increase
in
number
of
plants
and
algae
in
aquatic
ecosystems
can
lead
to
low
oxygen
concentrations
in
water.
9
Global
climate
is
changing,
and
consequently
our
environment
is
changing.
Climate
change
refers
to
any
signiYicant
change
in
the
measures
of
climate
(such
as
temperature,
precipitation
or
wind)
lasting
for
an
extended
period.
Global
Warming
is
an
average
increase
in
temperature
of
atmosphere
near
the
Earths
surface,
which
can
contribute
to
changes
in
global
climate
patterns.
The
term
"global
warming"
is
often
used
instead
of
climate
change
since
it
rapidly
conveys
one
of
the
main
ways
in
which
the
climate
has
changed.
However
global
warming
is
only
one
aspect
of
climate
change.
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Explain radiative forcing, greenhouse gases, and the enhanced greenhouse effect. Explain how climate models project future climate conditions. Describe the importance of extreme and unpredictable climate change.
Anthropogenic
climate
change
is
an
established
phenomenon.
The
question
is
no
longer
whether
climate
change
will
occur,
but
at
what
rate,
with
what
effects,
and
what,
if
anything,
we
can
do
about
it.
Human
produced
greenhouse
gases
are
the
most
plausible
explanation
for
the
warming
that
has
occurred
in
the
recent
century.
Mean annual global temperature (C)
15.0 Earths average temperature is based on daily measurements taken at several thousand land-based meteorological stations around the world, as well as data from 14.8 weather balloons, orbiting satellites, transoceanic ships, and hundreds of sea14.6 surface buoys with temperature sensors. Data show that the 14 warmest years since 14.4 the mid-1800s have occurred since 1990. According to the National Oceanic and 14.2 Atmospheric Administration (NOAA), global temperatures in those years may 14.0 have been the highest in the last millennium. (Although widespread thermome13.8 ter records have been assembled only since the mid-19th century, scientists recon13.6 struct earlier temperatures using indirect climate evidence in tree rings, lake and 13.4 ocean sediments, stalagmites, small air bubbles in ancient ice, and coral reefs.) The last two decades of the 20th century were Earths warmest (Figure 21.1). 13.2 Other evidence conrms the increase in global temperature. Several studies have documented that phenological spring in the Northern Hemisphere now comes about six days earlier than it did in 1959, and autumn is delayed ve days. (Phenological spring is determined by when buds of specic plants open, and autumn by when leaves of specic trees turn color and fall.) Since 1949, the United States has experienced an increased frequency of extreme heat stress events, which are very hot, humid days and nights during summer months; medical records indicate that heat-related deaths among elderly and other vulnerable people increase during these events. In the past few decades, the rate of sea-level rise has increased. For most of the 20th century, the rate of increase was about 1.5 to 2 cm/decadeit is now at about 3 cm/decade. Glaciers worldwide have retreated, and extreme weather events such as severe rainstorms have occurred with increasing frequency in certain regions. Scientists around the world have researched global climate change for several decades. As the evidence has accumulated, those most qualied to address the issue have concluded that temperatures have increased over the past century, that it is extremely unlikely that natural causes can explain the warming, and that humanproduced greenhouse gases are the most plausible explanation for the warming that has occurred. Further, the remainder of this century will experience signicant additional climate change, and human activities will be largely responsible for this change. In response to the growing scientic agreement about both the change and its human
1960
1971
1974
1977
1992
1995
2001
2004
Year
temperature, 19602007. Data are presented as surface temperatures (C) for 1960, 1965, 1970, and every year thereafter. The measurements, which naturally uctuate, clearly show the warming trend of the last several decades. (The dip in global temperatures in the early 1990s, caused by the eruption of Mount Pinatubo in 1991, is discussed later in the chapter.) (Global LandOcean Temperature Index, Goddard Institute of Space Studies, NASA)
12
2017
1980
1983
1986
1989
1998
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These
gases
allow
solar
radiation
to
penetrate
the
atmosphere
and
the
radiation
is
absorbed
by
the
Earths
surface.
The
earths
surface
reradiates
the
absorbed
energy
in
the
form
of
infrared
thermal
radiation,
which
is
absorbed
by
the
greenhouse
gases
in
the
atmosphere.
13
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dioxide in the atmosphere. Measurement of carbon dioxide levels at the Mauna Loa ObserSome solar vatory in Hawaii shows radiation is reflected by the that the carbon dioxide Earth and the level increased from atmosphere. about 315 parts Permillion (ppm) in 1958 to about 384 ppm in 2007. (See figure 16.17.) This E ER is an increase of about PH OS M Infrared 22 percent. Since changes AT radiation is in carbon dioxide levels TH R emitted from the EA in the atmosphere are Earths surface. due to human activity, Solar radiation we can make changes passes through that will stabilize or rethe clear atmosphere. duce atmospheric carbon Most radiation is dioxide. The actions reabsorbed by the quired will be discussed Earths surface later. and warms it. Methane comes primarily from biological 14
sources, although some Figure 16.16 Greenhouse Effect The greenhouse effect naturally warms the Earths surface. Without it, enters the atmosphere Earth would be 33C (60F) cooler than it is todayuninhabitable for life as we know it. from fossil-fuel sources. Source: Data from Climate ChangeState of Knowledge, October 1997, Office of Science and Technology Policy, Washington, D.C. (See figure 16.17.) Several kinds of bacteria that are particularly abundant in radiation (heat), which is absorbed by the greenhouse gases in wetlands and rice paddies release methane into the atmosphere. the atmosphere. Because the effect is similar to what happens in Methane-releasing bacteria are also found in large numbers in the a greenhouse (the glass allows light to enter but retards the loss guts of termites and various kinds of ruminant animals such as catof heat), these gases are called greenhouse gases, and the tle. Control of methane sources is unlikely, since the primary warming from their increase is called the greenhouse effect. sources involve agricultural practices that would be very difficult (See figure 16.16.) The most important greenhouse gases are to change. For example, nations would have to convert rice paddies carbon dioxide (CO2), chlorofluorocarbons (primarily CCl3F to other forms of agriculture and drastically reduce the number of and CCl2F2), methane (CH4), and nitrous oxide (N2O). Table 16.2 animals used for meat production. Neither is likely to occur, since lists the relative contribution of each of these gases to the potenfood production in most parts of the world needs to be intial for global warming. creased, not decreased. The Greenhouse Effect
Some of the infrared radiation passes through the atmosphere, and some is absorbed and re-emitted in all directions by greenhouse gas molecules. The effect of this is to warm the Earths surface and the lower atmosphere.
11/5/12
Life on earth would not be possible without the natural greenhouse effect as it keeps the earth warm (earth temperature would be 33C cooler without it). Emissions of green house gases from human activities is increasing the concentration of green house gases in the atmosphere causing global warming.
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Principal Sources
Burning of fossil fuels Deforestation Produced by bacteria in wetlands, rice fields, and guts of livestock Release of fossil fuels Release from foams, aerosols, refrigerants, and solvents Burning of fossil fuels Fertilizers Deforestation
Chlorofluorocarbons (CFCs)
0.00088
14
0.270
0.321
Source: Data from Intergovernmental Panel on Climate Change, with updates from Oak Ridge National Laboratory.
16
1750 360
CH4 (ppb)
340
8
1200 1400 Year 1600 1800 2000
(a)
(b)
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Carbon
dioxide
Most
abundant
of
the
green
house
gases
and
occurs
as
a
natural
consequence
of
respiration.
Much
larger
quantities
are
put
into
atmosphere
as
a
byproduct
of
energy
production.
Coal,
oil,
natural
gas
and
biomass
used
as
source
of
energy
emit
carbon
dioxide.
Deforestation
is
another
cause
of
increased
CO2
concentration
as
tied
up
carbon
dioxide
are
released
to
the
atmosphere;
and
reduction
in
forest
lessens
its
ability
to
remove
carbon
dioxide
from
the
atmosphere.
17
Carbon dioxide level increased from about 315 parts per million (ppm) in 1958 to about 384 ppm in 2007.
18
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Methane
Comes
primarily
from
biological
sources,
although
some
enter
the
atmosphere
through
fossil
fuel
sources.
Bacteria
that
are
particularly
abundant
in
wetlands
and
rice
paddies
release
methane
into
the
atmosphere.
Primary
sources
involve
agricultural
practices
(eg.
rice,
animals)
methane
emissions
is
very
difYicult
to
control.
19
Nations
would
have
to
convert
rice
paddies
to
other
forms
of
agriculture
and
drastically
reduce
the
number
of
animals
used
for
meat
production
(difYicult
due
to
rising
population).
20
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ChloroJluorocarbons
Minor
component
of
the
principal
greenhouse
gases,
entirely
the
result
of
human
activity,
CFCs
used
intensively
in
refrigeration,
air
conditioners
They
are
extremely
efYicient
as
greenhouse
gases
(about
15,000
times
more
efYicient
at
retarding
heat
loss
than
is
carbon
dioxide).
But,
increased
concentration
threatened
Ozone
layer
already
banned
21
Nitrous
Oxide
Minor
component
of
principal
green
house
gases.
Enters
atmosphere
from
fossil
fuels
and
fertilizers.
22
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Average temperature of earth likely to increase by 1.1-6.4C by the end of 21st century rela9ve to 1980-1990 with a best es9mate of 1.8-4.0 C. Average rate of warming over each inhabited con9nent is very likely to be at least twice as large as that experience during the 20th century.
23
Large
increase
in
average
temperature
could
signiYicantly
alter
the
climate
of
major
regions
of
the
world.
Rising
temperature
will
affect
the
hydrologic
cycle,
sea
level,
human
health,
the
survival
and
distribution
of
organisms,
and
the
use
of
natural
resources
by
people.
Some
natural
ecosystems
and
human
settlements
will
be
able
to
withstand
or
adapt
to
changes
others
will
not.
Poorer
nations
are
more
vulnerable
to
climate
change
- dependence
on
subsistence
agriculture
and
lack
economic
resources
to
buffer
against
changes.
24
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26
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27
Maldives
28
14
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Health
Effects
The
most
direct
effect
of
climate
change
on
health
would
be
the
impacts
of
hotter
temperatures.
Extremely
hot
temperatures
increase
number
of
people
dying
on
a
given
day.
Higher
temperature
increases
the
concentration
of
ozone
at
ground
level
leading
to
injury
of
tissues
and
intensiYies
the
effects
of
airborne
pollen
and
spores
that
cause
respiratory
disease.
29
30
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Changes
to
Ecosystems
Some
of
the
most
dramatic
projections
regarding
global
warming
involve
natural
systems.
Geographic
distribution
of
organisms
could
be
signiYicantly
altered.
Tundra
biomes
will
be
greatly
affected
because
of
melting
of
permafrost.
31
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THE ATMOSPHERE
The atmosphere (air) is composed of 78.1 percent nitrogen, 20.9 percent oxygen, and a number of other gases such as argon, carbon dioxide, methane, and water vapor that total about 1 percent. Most of the atmosphere is held close to the 30 Earth by the pull of gravitational force, so it gets less dense with increasing distance from the Earth. Throughout the various layers of the atmosphere, nitrogen and oxygen are the most common gases present, although the molecules are farther apart at higher altitudes. 0 The atmosphere is composed of four layers. (See figure 16.1.) The troposphere extends from the Earths surface to about 10 kilometers (about 6.2 miles) above the Earth. It actually varies from about 8 to 18 kilometers (511 miles), depending on the position of the Earth and the season of the year. The temperature of the troposphere declines by about 6C (11F) for every kilometer above the surface. The troposphere contains most of the water vapor of the atmosphere and is the layer in which weather takes place. The stratosphere extends from the top of the troposphere to about 50 kilometers (about 31 miles) and contains most of the ozone. The ozone is in a band between 15 and 30 kilometers (919 miles) above the Earths surface. Because the ozone layer absorbs sunlight, the upper layers of the stratosphere are warmer than the lower layers. The mesosphere is a layer with decreasing temperature from 50 to 80 kilometers (3150 miles) above the Earth. The thermosphere is a layer with increasing temperature that extends to about 300 kilometers (186 miles) above the Earths surface.
60 Westerlies
Trade winds
30
60
of air caused by the rotation of the Earth a brought about by temperature difference 35 patterns of world air movement. In Nort westerlies (from the west to the east).
Figure 16.2
Global Wind
100
Even though gravitational force near the Earth, the air is not static Earth, it expands and rises. When it space, the air cools, becomes more Earth. As the air circulates verticall it also moves horizontally over the the Earth rotates on its axis. The ments creates the wind and weather ferent regions of the world. (See fig
90 80 70 60 50 40 30 20 10 0 Ozone
Thermosphere
Mesosphere
POLLUTION OF TH ATMOSPHERE
Stratosphere
Mount Everest
Figure 16.1
The Atmosphere The atmosphere is divided into the troposphere, the relatively dense layer of gases close to the surface of the Earth; the stratosphere, more distant with similar gases but less dense; the mesosphere; and the thermosphere. Weather takes place in the troposphere, and the important ozone layer is present in the stratosphere.
Pollution is any addition of matter o vironment for humans and other orga are the major cause of pollution we c There are several natural sources of g the quality of the air, including mat dust from wind erosion, and gases fr plants and animals. Since these event we cannot do much to control them 36 sions, chemical odors, factory smo considered air pollution and will be The problem of air pollution is of people living in an area and the ki
366
CHAPTER 16
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Air
pollution
refer
to
addition
of
various
chemicals/ substances
to
atmosphere
by
natural
events
or
human
activities,
and
that
degrade
the
environment.
Air
pollution
consists
of
gases,
liquids
or
solids
present
in
the
atmosphere
in
high
enough
levels
to
harm
humans,
organisms
or
materials.
Air
pollutants
can
come
from
natural
sources,
however,
human
activities
make
a
major
contribution
to
air
pollution.
37
Air pollutants can be primary or secondary. Primary air pollutants are harmful chemicals that enter directly into the atmosphere - carbon monoxide,
volatile
organic
compounds
(hydrocarbons),
particulate
matter,
sulfur
dioxide,
and
oxides
of
nitrogen
Secondary
air
pollutants
are
harmful
chemicals
that
form
from
other
substances
released
into
the
atmosphere
ozone
38
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Particulate Matter
Solid or liquid particles suspended in the atmosphere. Consists of variety of Figure Carbon Monoxide The major source of car pollutants, such as s16.4internal combustion engine, which is used to provide bon monoxide oil is the most of our transportation. The more concentrated the number of automobiles, the more concentrated particles, soot, hundred parts per millionthe pollutants. Carbon monoxide concentrations lead, of a are not unusual in rush-hour traffic in large metropolitan areas. These concentrations are high enough to cause fatigue, dizziness, and and asbestos, sea salt, headaches. sulfuric acid droplets. C H A P T E R 1 6 368
processes that involve burning (pow dustry, burning leaves, etc.). Althoug fuel efficiency and the use of catalyti have reduced carbon monoxide em U.S. National European Union kilometer driven, carbon monoxid Measurement Ambient Air Air Quality Air Pollutant Period Quality Standards Standards problem because the number of aut the road and the number of kilom EPA Criteria Air Pollutants have risen. In urban areas, as much a Carbon monoxide (CO) 8-hour average (9 ppm) (10 mg/m3 ) 10 mg/m3 of carbon monoxide is from motor 3 1-hour average (35 ppm) (40 mg/m ) many parts of the world, automobile 3 3 Nitrogen dioxide (NO2) Annual mean (0.053 ppm) (100 g/m ) 40 g/m maintained and may have inoperab 3 1-hour 200 g/m control equipment, resulting in e Ozone (O3) 8-hour average (0.075 ppm) (147 g/m3) 120 g/m3 amounts of carbon monoxide. 3 1-hour average (0.12 ppm) (235 g/m ) Carbon monoxide is dangerou 3 3 Lead (Pb) 3-month average (1.5 g/m ) 0.5 g/m binds to the hemoglobin in blood 3 Particulate matter (PM10) Annual mean 20 g/m the hemoglobin less able to car 24-hour average (150 g/m3) 50 g/m3 Because carbon monoxide remains 3 Particulate matter (PM2.5) Annual mean (15 g/m ) hemoglobin for a long time, even sm 3 3 24-hour average (35 g/m ) (25 g/m ) tend to accumulate and reduce 3 Sulfur dioxide (SO2) Annual mean (0.03 ppm) (78 g/m ) oxygen-carrying capacity. Several 24-hour average (0.14 ppm) (365 g/m3) 125 g/m3 posure to air containing only 0.001 3 3-hour average (0.50 ppm) (1300 g/m ) carbon monoxide can cause dea 3 1-hour average 350 g/m monoxide is most dangerous in encl Other Common Air Pollutants where it is not diluted by fresh air space. The amount of carbon mo Benzene Annual mean No standards set, but 5 g/m3 duced in heavy traffic can cause current levels are below drowsiness, and blurred vision. Ciga 2.5 g/m3 ing is also an important source Volatile organic No standards set, but monoxide because the smoker is compounds reductions needed to directly. A heavy smoker in conges reduce ground-level ozone 39 doubly exposed and may experien Source: U.S. Environmental Protection Agency and European Commission. impaired reaction time compared smoking driver. Fortunately, carbon monoxid persistent pollutant. It readily combines with oxyge to form carbon dioxide (2CO O2 2CO2). There can be cleared of its carbon monoxide if no new carb ide is introduced into it. Control of carbon mono United States has been very good. The U.S. EPA carbon monoxide levels decreased by about 67 perce 1990 and 2007, and nearly all communities now me dards set by the EPA. This was accomplished with controls on industry and, in particular, on moto Catalytic converters reduce the amount of carbon m leased by vehicle engines, and specially formulate produce less carbon monoxide are used in many citi a carbon monoxide problem. Often these special fu used in winter, when car engines run less efficiently a more carbon monoxide.
Table 16.1
PARTICULATE MATTER
Particulate matter consists of minute (10 microns a solid particles and liquid droplets dispersed into the atm micron is one millionth of a meter. Many bacteria are ab in diameter. The Environmental Protection Agency has s
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41
Lead
A
soft
metal
that
is
used
in
industrial
and
chemical
processes,
has
a
variety
of
health
impacts.
Chronic
effects
can
include
permanently
reduced
cognitive
ability,
behavioral
problems,
slowed
growth,
hearing
problems,
and
headaches.
Airborne
lead
can
be
a
problem
both
when
it
is
inhaled
and
when
it
settlesin
water
and
on
surfaces
including
foods.
42
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Nitrogen
Oxides
Nitrogen
oxides
are
gases
produced
by
the
chemical
interactions
between
atmospheric
nitrogen
and
oxygen
when
a
source
of
energy,
such
as
combustion
of
fuels,
produces
high
temperatures.
Nitrogen
oxides
consist
mainly
of
nitric
oxide
(NO),
nitrogen
dioxide
(NO2),
and
nitrous
oxide
(N2O).
Nitrogen
oxides
inhibit
plant
growth,
and
when
breathed
aggravate
health
problems
such
as
asthma.
43
Sulfur
Oxides
Sulfur
oxides
are
gases
produced
by
the
chemical
interactions
between
sulfur
and
oxygen.
Sulfur
dioxide
(SO2),
is
a
major
sulfur
oxide
emitted
as
a
primary
air
pollutant.
Another
major
sulfur
oxide
is
sulfur
trioxide
(SO3),
a
secondary
air
pollutant
that
forms
when
SO2
reacts
with
O2
in
the
air.
Sulfur
trioxide,
in
turn,
reacts
with
water
to
form
another
secondary
air
pollutant,
sulfuric
acid.
44
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Carbon
Oxides
Carbon
monoxide
(CO)
and
carbon
dioxide
(CO2).
Carbon
monoxide,
a
colorless,
odorless,
and
tasteless
gas
produced
in
the
largest
quantities
of
any
atmospheric
pollutant
except
carbon
dioxide,
is
poisonous
and
interferes
with
the
bloods
ability
to
transport
oxygen.
Carbon
dioxide,
also
colorless,
odorless,
and
tasteless,
is
a
greenhouse
gas;
its
excessive
buildup
in
the
atmosphere
is
associated
with
global
climate
change.
45
Hydrocarbons
Hydrocarbons
are
a
diverse
group
of
organic
compounds
that
contain
only
hydrogen
and
carbon.
The
simplest
hydrocarbon
is
methane
(CH4).
Hydrocarbon
molecules
could
be
found
in
either
gaseous,
liquid
or
solid
form.
Hydrocarbons
have
a
variety
of
effects
on
human
and
animal
health.
Some
cause
injury
to
the
respiratory
tract,
and
some
could
cause
cancer
also.
Methane
is
a
potent
greenhouse
gas
linked
to
global
climate
change
.
46
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11/5/12
Ozone
Ozone
(O3)
is
a
form
of
oxygen
considered
a
pollutant
in
one
part
of
the
atmosphere
but
an
essential
component
in
another.
In
the
stratosphere
oxygen
reacts
with
UV
radiation
coming
from
the
sun
to
form
ozone.
Stratospheric
ozone
prevents
much
of
solar
UV
radiation
from
penetrating
to
Earths
surface.
Unlike
stratospheric
ozone,
ozone
in
the
troposphere
is
a
human-made
air
pollutant.
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