1. 2.

A monoprotic acid in 0.1M solution, ionises to 0.001%. Its ionisation constant is (a) 1 10 3 (b) 1 10 6 (c) 1 10 8 The degree of dissociation of 0.1M HCN solution is 0.01%. its ionisation constant would be (a)

[MP PET 1999; CPMT 2003]

(d) 1 10 11
[RPMT 1999]
9

10

(b) 10

(c)

10

(d) 10

3. 4.

Degree of dissociation of 0.1 N CH 3COOH is (Dissociation constant 1 10 ) (a) 10 (b) 10 (c) 10 A monoprotic acid in a 0.1 M solution ionizes to 0.0001%. Its ionization constant is (a)
5 4 3

[MP PET 1997]

(d) 10
8

[MP PET 1985; MP PET/PMT 1988]

1.0 10

(b) 1.0 10

(c)

1.0 10

(d) 1.0 10 13

5.

A weak monobasic acid is 3.5% dissociated in

N solution at 15 o C . The dissociation constant of the acid at this temperature is 20

[UPSEAT 1999]

6.

(a) 6.34 10 5 (b) 5.24 10 5 (c) 3.24 10 5 Which of the following concentrations has the largest degree of dissociation for a weak acid (a) 1.0 M (b) 0.5 M (c) 0.10 M The concentration of [H ] and concentration of [OH ] of a 0.1 aqueous solution of 2% ionised weak acid is [ionic product of water 1 10 14 ] (a)

(d)

2.78 10 5

(d) 0.01 M

7.

[CBSE 1999]

0.02 10 M and 5 10
2 10 M and 5 10
3 12

11

M
5

(b) 1 10 M and 3 10 (d)

2

11
13

M
M
[IIT-JEE (Screening) 2004]

3 10 M and 4 10

8.

A weak acid HX has the dissociation constant 1 10 M . It forms a salt NaX on reaction with alkali. The degree of hydrolysis of 0 . 1 M solution of NaX is (a) 0.0001% (b) 0.01% (c) 0.1% (d) 0.15%

A solution of weak acid HA containing 0.01 moles of acid per litre of solutions has pH 4 . The percentage degree of 91onization of the
[UPSEAT 2001]
4

acid and the 91onization constant of acid are respectively (a) 1 %, 10 10.
6

(b)

0.01 %, 10

(c)

1 %, 10

(d)

0.01 %, 10

The pH of a solution at 25 o C containing 0 . 10 m sodium acetate and 0 . 03 m acetic acid is ( pKa for CH 3COOH 4.57 )
[AIIMS 2002; BHU 2002]

11.

(a) 4.09 (b) 5.09 (c) 6.10 (d) 7.09 In a solution of pH 5 , more acid is added in order to reduce the pH 2 . The increase in hydrogen ion concentration is
[MP PET 1989; CPMT 1990]

(a) 100 times (b) 1000 times (c) 3 times (d) 5 times 12. The pH value of 0.1M HCl is approximately 1. What will be the 91pproximate pH value of 0.05 M H 2 SO 4 (a) 0.05 13. What is the pH value of (a) 10 11 14. The pH of (a) 1 (b) 0.5
N KOH solution 1000

[MP PMT 1991]

(c) 1

(d) 2
[CPMT 1975; MNR 1986, 91]

(b) 3

(c) 2

(d) 11
[CPMT 1971; DPMT 1982, 83; MP PMT 1991; Bihar MEE 1996]

N HCl would be approximately 100

(b) 1.5

(c) 2

(d) 2.5
[MP PET 1994]

15. The pH of a solution is 2. If its pH is to be raised to 4, then the [H ] of the original solution has to be (a) Doubled (b) Halved (c) Increased hundred times 16. When 100 ml of M / 10 NaOH solution and 50 ml of M / 5 HCl solution are mixed, the pH of resulting solution would be (a) 0 (a) 1 (b) 7 (b) 0 (c) Less than 7 (c) 7 (d) More than 7 17.The pH of the solution containing 10 ml of a 0.1 N NaOH and 10 ml of 0 . 05 N H 2 SO 4 would be (d) > 7

(d) Decreased hundred times

[Pb. PMT 2002]