Glucopon For II Applications Final ICS - April 2009

APG
The Allrounder
for Industrial & Institutional Applications
April 2009
APG for I & I Applications April 2009
APG for I&I Applications

Content APG Product Overview Applications Performance Benefits
Emulsifier and Hydrotrope Potential Cleaning Performance Foaming Properties Anti-streaking Properties Gloss Retention Wetting Behavior Surface and Skin Compatibility
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Chemical Structure
coconut / palmkern
corn, potato, wheat
coconut / palmkernel oil
starch
fatty alcohol
glucose
Alkyl Polyglucoside
4
TM
Cognis Product Portfolio Easy Guide

Systematic Approach
100 % natural, renewable feedstocks
synthetic feedstocks
only physical purification by water/alcohol or energy
chemically processed, catalyst or reaction aids used
renewable & synthetic building blocks combined in a chemical process
chemically processed
70% naturalCbased C <70% natural based C >70% natural <70% natural C

Cognis Natural modified
Cognis Naturals
Cognis Ecohybrids
Cognis Hybrids
Cognis Synthetics
TM
Portfolio Easy Guide Home Care / I&I

Cognis Natural modified Cognis Ecohybrids Cognis Hybrids Cognis Synthetics
Cognis Naturals
Eumulgin VL 75 Gluadin WLM Gluadin W 40 Gluadin WK Glucopon 215 UP Glucopon 225 DK Glucopon 425 N Glucopon 600 CSUP Glucopon 650 EC Glucopon 50 G Plantatex LLE
Comperlan 100 Comperlan COD Comperlan KD Comperlan WB Dehypon G 162 Dehydol LS 2 N Dehyquart AU 46 Dehyquart AU 56 Dehyton AB 30 Euperlan PK 1200 Plantapon 611 L Plantatex HCC Sulfopon 1218 G Texapon LS 35 Texapon N 70
Aminogen CT 2 APG 325 N Araphen K 100 Dehydol LT 7 Dehydol O 4 Dehydol O 10 Dehydol 980 Dehydol HD-FC2 Dehypon LT 104 Dehypon LS 54 Dehypon LS 531 Dehyton PK 45 Deriphat 160 C Eumulgin HRE 40 Eumulgin L Eumulgin O5 Euperlan HCO
Cosmedia HC 40 Dehydran 770 Dehydran 780 Polyquart Ampho 149 Polyquart FDI Polyquart Pro Polyquart CCE
Alkyl Polyglucosides
Cognis Glucopon- Line for Home Care / I&I (EU Production)
Glucopon Line
Product Properties C-Chain DP (approx.) Appearance Active substance [%] Water content [%] Viscosity [mPas] pH value Storage Temperature [ C] Biodegradation (OECD 301 A-F) Compliant with EU- Detergent Regulation Laundry detergents, automatic dish detergents Automatic dish detergents, hard surface cleaners Manual dishwashing, hard surface cleaners Laundry detergents, manual dishwashing Laundry detergents, manual dishwashing 50 G C12-14 1,4 beige granules 45-55 ------< 40 C
readily
215 UP C8-10 1,5 yellowish, slightly cloudy liquid 62 - 65 35 - 38 3.000 4.000 (20 C) 11.5 - 12.5 (10%) < 40 C
readily
225 DK C8-10 1,7 brownish liquid 68 - 72 28 - 32 3.500 5.000 (20 C) 6.0 - 9.0 (10%) < 40 C
readily
425 N/HH C8-14 1,5 yellowish liquid 48 - 52 48 - 52 300 - 600 (20 C) 7.0 - 9.5 (20%) < 40 C
readily
600 CS UP C12-14 1,4 yellowish, slightly cloudy paste 50 - 53 47 - 50 2.000 4.000 (40 C) 11.5 - 12.5 (20%) < 50 C
readily
650 EC C8-14 1,5 yellowish, slightly cloudy liquid 50 - 53 47 - 50 1.500 3.000 (20 C) 11.5 - 12.5 (20%) < 40 C
readily
Main Application
I&I cleaners
Alkyl Polyglucosides
Cognis Glucopon- Line for Home Care / I&I (US Production)
APG
Product Properties C-Chain DP (approx.) Appearance Active substance [%] Water content [%] Viscosity [cps,25 C] pH value [10%] Storage Temperature [ C] Biodegradation (OECD 301 A-F) Compliant with EU- Detergent Regulation Qualified for Bio-based and DFE Cleangredients Hard surface cleaners Automatic dish detergents, hard surface cleaners Manual dishwashing, hard surface cleaners Laundry detergents, manual dishwashing Laundry detergents, manual dishwashing
readily readily readily
Glucopon Line
215 UP C8-10 1,5 yellowish, slightly cloudy liquid 62 65 35 38 3.000 11.5 - 12.5 225 DK C8-10 1,7 brown liquid 68 - 72 28 - 32 4.800 6.0 - 8.0 <40 C
readily readily readily
325 N C9-11 1,5 light yellow, clear liquid 48 - 52 42 - 48 4.000 7.0 - 9.5
425 N C8-14 1,5 clear liquid 48 - 52 42 - 48 550 7.0 - 9.5
600 UP C12-14 1,4 light yellow, hazy paste 48 - 52 42 - 48 18.000 11.5 - 12.5
625 UP C12-14 1,6 light yellow, hazy paste 48 - 52 42 - 48 21.500 11.5 - 12.5
Main Application
I&I cleaners

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Application Areas
Personal Care
Industrial Cleaning in Place CIP Food & Beverage Bottle Cleaning Car Wash
Institutional Hard Surface Cleaning Ware Washing Laundry Floor Cleaning
Home Care
Hair / Body / Oral Care Skin Care
Hard Surface Cleaning Dishwashing Laundry
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Application Areas
Wetting Glucopon 225 DK Hard Surface Cleaning / I&I
Glucopon 215 UP Hard Surface Cleaning / Household
Glucopon
425 N
Glucopon 650 EC Dishwash / Laundry Glucopon 600 UP Emulsifying

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Emulsifying Capacity
Detergent & Cleaner formulations should:
Remove and emulsify soil from surfaces
Maintain the soil in solution
Carry the soil away in the washing and rinsing step
A perfect ingredient with high emulsifying capacity
Avoid soil re-deposition
13

Testing of emulsification properties by observation of the behaviour of different types of oil/grease and a surfactant solution.
Tested Soils 1) 2) 3) 4) Myritol 318 (Caprylic / Capric Trygliceride) Soybean Oil Olive Oil Tesco Lard*
Tested Surfactants 1) 2) 3) 4) 5) 6) 7) Glucopon 215 UP Glucopon 600 CS UP Glucopon 650 EC Texapon N 70 Maranil A 55 Dehydol LT 7 Dehyton K (Alkyl polyglucoside C8-C10) (Alkyl polyglucoside C10-C16) (Alkyl polyglucoside C8-C14) (Sodium Laureth Sulfate) (Sodium dodecylbenzenesulfonate) (Fatty alcohol C12-C18 + 7 EO) (Cocoamidopropyl Betaine)
*Test Temperature 45 C
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Testing of emulsification properties by observation of the behaviour of different types of oil/grease and a surfactant solution.
Test Method 50 ml of oil/grease and 50 ml of surfactant solution (2% AM in water) is mixed 1200 +/-3 rpm for 2 minutes. After 1 and 4 hours observation of the level of remaining test solution.
Principle The lower the remaining level, the better the emulsification properties of the test solution.
15

50 45 40 Aqueous Phase [ml] 35 30 25 20 15 10 5 0 Myritol Soybean Oil Olive Oil Tesco Lard* 318 Glucopon 215 UP Dehyton K Glucopon 650 EC Dehydol LT 7 Myritol Soybean Oil Olive Oil Tesco Lard* 318 Glucopon 600 CS UP Texapon N 70 Maranil A 55
1h
4h
*Test Temperature 45 C
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Hydrophilicity
Glucopon 215 UP C8 / C10 Glucopon 650 EC C8 / C14 Glucopon 600 UP C12 / C14
Myritol 318 C8, C10 Soybean Oil C18, C18, C18 Olive Oil Tesco Lard C18 C18
Hydrophobicity
"Equal solves equal"

17

Hydrotrope Potential
Test Conditions: Example for an alkaline cleaner containing Dehypon LS 54 Evaluation of amount of hydrotrope needed to obtain a clear solution Data for various Dehypon types available
Without Hydrotrope
5% Dehypon LS 54 10% KOH (50%)
With Hydrotrope
5% Dehypon LS 54 10% KOH (50%) 2% Glucopon 225 DK
Phase Separation
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Clear Solution

Primary Cleaning Performance
Automatic Test Equipment for Primary Cleaning
Test equipment for: All Purpose Cleaner Bathroom Cleaner Glass Cleaner Kitchen Cleaner Degreaser
Soil Composition (83/21) 36% Benzine 80/110 17% Myritol 318 40% Mineral Oil (Telura 310, Esso) 7% Carbon Black (Special black 4, Degussa)
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Automatic Test Equipment for Primary Cleaning
(1) Soiling by brush
(2) Analysis of soiled surface
(3) Applying test solution
(4) Wiping with sponge 20
(5) Rinsing with water
(6) Analysis of cleaned surface

Soil removal of single surfactants
(IPP 83/21, 20 Dosage: 20 ml) C,
100 90 80 70 Soil Removal [%] 60 50 40 30 20 10 0 Glucopon Glucopon Glucopon Dehydol 215 UP 650 EC 600 UP LT 7 Texapon Texapon N 70 LS 35
21

Foaming Properties
Test Conditions Trigger spray application Formulations (2% AM) were tested on ceramic tiles Evaluation of foaming behavior without rinsing and wiping the test solution. Comparative Foaming Test
Glucopon 215 UP
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Texapon N 70
Dehydol LT 7

Foaming Properties
Test Conditions Trigger spray application Formulations (2% AM) were tested on ceramic tiles Evaluation of foaming behavior without rinsing and wiping the test solution. Comparative Foaming Test
Glucopon 215 UP
Glucopon 650 EC
Glucopon 600 UP
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Foaming Properties
Self Foaming Performance of APG derivatives
(Dynamic Foam Cell: 400ppm AM in distilled water at 20 - 55 ) C
2100 2000 1900 1800 1700 1600 total volume (min 400mL) [mL] 1500 1400 1300 1200 1100 1000 900 800 700 600 500 400 300 200 15 20 25 30 35 40 45 50 55 60
Temperature [ C]
starting phase/fo am
build-up
Glucopon 215 UP Glucopon 225 DK Glucopon 425 N/HH Glucopon 600 CS UP Glucopon 625 UP Glucopon 650 EC
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Foaming Properties
Foam Suppressing on APG of Dehypon Wet
Dynamic Foam Cell, 250 ppm AM in 1% NaOHaq at 65 C
2200 2000 1800 total volume (300mL V [mL] 2000mL) 1600 1400 1200 1000 800 600
Dehypon Wet Blank Value - without Dehypon
Base Liquor
400 200 0 -50 50 150 250 350 450 550 650 750 850 950 1050 1150 1250 1350 1450 1550 1650 1750 1850 1950
Dosage of Glucopon 650 EC [ppm]
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Foaming Properties
Self Foaming of Glucopon 225 DK : Dehypon Wet
Dynamic Foam Cell, 500ml, 0,1% AM Solution, 20 C
2000 1800 Foam Volume + Liquor [ml] 1600 1400 100:0 1200 1000 800 600 400 200 0 0 5 10 Time [min] 15 20 25 75:25 50:50 25:75 0:100
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Foaming Properties
Self Foaming of Glucopon 600 CS UP : Dehypon Wet
Dynamic Foam Cell, 500ml, 0,1% AM Solution, 20 C
2000 1800 Foam Volume + Liquor [ml] 1600 1400 100:0 1200 1000 800 600 400 200 0 0,5 1 2 5 Time [min] 10 15 20 75:25 50:50 25:75 0:100
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Anti-streaking Properties
Test Conditions: Trigger spray application. Formulations were tested on ceramic tiles. Evaluation of streaking behavior by wiping the surface after application of test solution. Comparative Anti-Streaking Test:
Fatty Alcohol Ethoxylate

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Glucopon 215 UP

Gloss Retention
Test Conditions: Trigger spray application. Formulations were tested on ceramic tiles. Evaluation of gloss retention visually and by reflectometer (BYK Gardner) Comparative Gloss Retention Test:
Fatty Alcohol Ethoxylate

(80% Gloss Retention) 29
Glucopon 215 UP
(98% Gloss retention)

Filming Behavior / Wetting Behavior
Test Conditions Formulations are applied by film applicator (30m thickness) Formulations were tested on ceramic tiles Evaluation of wetting behavior Comparative Filming Test
Glucopon 215 UP
FAES
SAS
FAEO
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Plastic Compatibility
Testing of Plastic Compatibility Spline / Corrosion Test According to the Hansgrohe Method Methodology The plastic test stripe, containing a stainless steal pin in a hole (tension), is dipped five days in a row shortly into the test solution. The test strip is checked visually after 4 hours 3 days 7 days and 14 days test period. Assessment Range
unchanged 31
fissures
through-cracks
fraction

Plastic Compatibility
Test Conditions: Example Plexiglas (PMMA) Other plastic materials proved (e.g. ABS Terez, PC Makrolon, Nonionic surfactants POM Hostaform, PP Novolen)
Concentration: 5% AM Plastic: Plexiglas (PMMA)
unchanged
14d 7d 3d
fissures through-cracks fraction

4h
d En 12 C 12 C 12 C G 13 C W o Is ca de no l8 EO G G c lu c lu c lu e at 4 /1 FA O 4E 4 /1 8 /1 5 /1 FA O 7E
pp ca
op
op
op
on
FA
FA O 7E
on
on
ed
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EO O /P
0 60
5 21
5 42
FA EO
S C
P U
H /H N
U P

Skin Compatibility (Modified Duhring-Chamber Test)
APG C12/14 LAS FAES SAS FAS C12/14 LAS / APG (1:1) FAES / APG (1:1) SAS / APG (1:1) FAS / APG (1:1)
100
200
300
400
Relative irritation score [%]

33

Summary
Very good emulsifier potential Excellent cleaning performance Foaming properties of Glucopon are significantly better than FAEO Significant anti-streaking properties of Glucopon in leave-on applications High gloss retention on treated surface Excellent wetting/filming behavior of Glucopon in contrast to other surfactants Perfect plastic compatibility by showing no stress-cracking behavior Glucopon surfactants are significantly less skin irritating than comparable nonionic surfactants and when used in combination with other surfactants, they can reduce the irritation potential of the surfactant system
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Glucopon For II Applications Final ICS - April 2009

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APG

APG for I & I Applications April 2009

APG for I&I Applications

APG for I&I Applications

APG for I&I Applications

corn, potato, wheat

coconut / palmkernel oil

Cognis Product Portfolio Easy Guide

100 % natural, renewable feedstocks

only physical purification by water/alcohol or energy

chemically processed, catalyst or reaction aids used

renewable & synthetic building blocks combined in a chemical process

70% naturalCbased C <70% natural based C >70% natural <70% natural C

APG for I & I Applications April 2009

Portfolio Easy Guide Home Care / I&I

APG for I & I Applications April 2009

APG for I & I Applications April 2009

425 N C8-14 1,5 clear liquid 48 - 52 42 - 48 550 7.0 - 9.5

APG for I & I Applications April 2009

APG for I&I Applications

APG for I&I Applications

Institutional Hard Surface Cleaning Ware Washing Laundry Floor Cleaning

Hair / Body / Oral Care Skin Care

Hard Surface Cleaning Dishwashing Laundry

APG for I & I Applications April 2009

APG for I&I Applications

Glucopon 215 UP Hard Surface Cleaning / Household

Glucopon 650 EC Dishwash / Laundry Glucopon 600 UP Emulsifying

APG for I&I Applications

APG for I&I Applications

Maintain the soil in solution

Carry the soil away in the washing and rinsing step

A perfect ingredient with high emulsifying capacity

Avoid soil re-deposition

APG for I & I Applications April 2009

APG for I&I Applications

APG for I & I Applications April 2009

APG for I&I Applications

APG for I & I Applications April 2009

APG for I&I Applications

APG for I & I Applications April 2009

APG for I&I Applications

"Equal solves equal"

APG for I&I Applications

APG for I & I Applications April 2009

APG for I&I Applications

APG for I & I Applications April 2009

APG for I&I Applications

(1) Soiling by brush

(2) Analysis of soiled surface

(3) Applying test solution

(4) Wiping with sponge 20

(5) Rinsing with water

(6) Analysis of cleaned surface

APG for I & I Applications April 2009

APG for I&I Applications

APG for I & I Applications April 2009

APG for I&I Applications

APG for I & I Applications April 2009

APG for I&I Applications

APG for I & I Applications April 2009

APG for I&I Applications