Beruflich Dokumente
Kultur Dokumente
Cyanotype
AIM To study the photochemical
Blue
Printing
reduction
of ferric
oxalate in cyanotype
blue
printing.
THEORY The quite cyanotype long-lasting or blueprint photographic blue. distinct reactions : complexes ferric to are reduced and with citrate react process is one of several alternative photographic methods, which relies on the normally on in 2 photoreduction of ferric ions. Cyanotypes are
ferric
ferricyanide
Prussian
The structure of Prussian blue has hexacoordinate Fe (II) bound through the carbon atoms, and To hexacoordinate achieve the in Fe (III) bound through the of the nitrogen atoms, forming an extended by also water water cubic framework. stoichiometry, reduces some cubic otherwise one - fourth ligand in the Fe (II) sites thus lattice. ferric oxalate are as created. are occupied and water are There molecules. This occupy molecules the number of bridging empty sites positions crystal cyanide groups, molecules
Under UV light, ferric oxalate (or its ammonium salt) gets reduced to ferrous oxalate, with the release of CO2 ,
(b)
The ferrous
iron
reacts
with
potassium ferricyanide
to form
ferroferricyanide
K 2 (C2O4) 2 K4 Fe(CN)6
8 K Fe [Fe(CN)6]
potassium dichromate,
HCl solution
PROCEDURE 1. Pour 50 ml of 0.5 M oxalic acid into a 250 ml beaker. Add 10 ml of 3.5 M diammonium hydrogen phosphate solution, and 2. mix well.Keep the beaker in subdued light. Add 50 ml of ferric chloride while stirring. If a precipitate is formed, further stirring should dissolve it. Keep this solution inside the cupboard, since the ferric oxalate light. 3. Immerse 4 pieces of bond paper (4 x 2.5) prepared sensitizing solution (ammonium iron in the freshly oxalate solution). is sensitive to
Rotate the beaker and make sure that the paper is thoroughly wet. 4. 5. 6. Remove the wet pieces of paper, and This should be done as quickly as After the paper has dried, between Expose minutes. During printing, do not hold the glass plates, but lay them on the desk, sheets of to sunlight. is about 45 glass. place them between sheets possible. sheets. and compress it sensitized paper, of filter paper.
windowsill, or any flat surface. 7. After the exposure, smoothly in dip the paper into 50 ml of 0.1 M potassium
a wide-mouthed dish.
8. 9.
Remove the paper and dip it in 50 ml of 0.03 M potassium dichromate 1 minute. Wash the paper first in Make a series best conditions. 0.1 M HCl, and then in tap water. to
solution for
of 2 3 exposures,
optimize the
Use
these
conditions the
to
obtain of
the
most for
Record
Time
Exposure