Beruflich Dokumente
Kultur Dokumente
An overview
Dictionary
Auger = coclea Bark = corteccia Beech = faggio Chipwood = cippato Digestate = digestato Feedstock = materia prima Fir = abete Fixed grate = griglia fissa Fluidized bed = letto fluido Fuzz = pula Grind milling = macina a mulino Grate = griglia Hopper = tramoggia Landfill = discarica Limestone = calcare Livestock = bestiame Log = tronchetto Manure = concime Pits or stones = noccioli Productive chain = filiera Rice husk = lolla di riso Scrubber = torre di lavaggio Shells = gusci Straw = paglia Tar = catrame
Classification
There are three possible classifications according to
nature of raw material
Forest residues Agricultural waste Livestock and civil (exhaust oil) or industrial sludge Ad hoc energy crops (starch or sugar, ligno-cellulosic, oily, ) Municipal (MSW) and Industrial solid waste
Glossary
BIOMASS: all organic material produced by plants or any process involving life is called biomass. Biomass is labelled as green house gas emission neutral energy source since it has a short carbon cycle, i.e. Emission of carbon from plant to atmosphere and absorbed by plant during growth only takes between one to some tens of years, whereas fossil carbon exists for millions of years. BIOMASS COMBUSTION: Traditional combustion process where biomass is used as a fuel and where the hot exhaust gases are used to produce heat or steam that is processed through a steam turbine to generate electricity. BIOMASS CO-COMBUSTION: Combination of fossil (for example, coal) and bio-energy fuels in conventional power plants. BIOMASS GASIFICATION : Oxygen starved combustion process where biomass is combusted in order to obtain CO and gasses as end products (so called producer gas or synthesis gas). In comparison to solid biomass the electricity produced by feeding gas into a gas turbine or internal combustion engine guarantees higher efficiency (35-40%, against 25-30% of traditional combustion).
Glossary
BIOGAS: a fuel gas produced from biomass feedstock through a low temperature biochemical process named anaerobic digestion. CO-DIGESTION: when the biomass involved in the digestion process is a mix of manure and organic waste or/and agricultural waste. By adding organic waste sources to the manure higher yields of biogas is obtained. DIGESTATE: semi-solid sub-product of anaerobic digestion stabilized in odours, in pathogenic bacteria and in carbon percentage, but with a still too high concentration of nitrates. PELLET: The term pellet identifies the sub-product realized through mechanical mincing of wood and agro-industrial residuals. That material has the right dimension and humidity to assure an optimal combustion performance of every kind of combustor, from big biomass combustion plants to the domestic boilers.
Electricity production in Italy: 100 installations (500 MWe, 1000 M in 2009), Calabria is #1 in Italy. Combustor + Boiler +Power cycle + Flue gas treatment. Power cycle consists in
Organic Rankine Cycle (ORC) (0.3-1.5 MWe) Steam Rankine cycle (>4-5 MWe) Cost of a standard 20 MWe plant is around 60 M (3000 /kW)
New technologies: pyrolisis and gasification (industrially irrelevant) An Italian value chain made by 350 companies (97% operated and 95% supply chain by Italian companies) For electric installations smaller than 1 MWe incentive is 0.28 /kWh
Overview of biogas
Sources: anaerobic digestion of waste waters, MSW organic fraction, waste from agro-food industry, livestock Germany (10 TWh) and UK (7.5 TWh) are the largest biogas users, followewd by Italy with 2.9 TWh produced by 450 MW installed capacity, about 500 installations (70% from MSW organic fraction and 30% from agricultural waste). Biogas is used to produce electricity through a digester and an internal combustion engine (ICE), with size varying between 100 kW and 1 MW or more (for MSW) and cost between 1400 /kW and 800 /kW for large engines. Whole installations costs range between 2500 and 4500 /kW Load factor can exceed 80% (7000 hrs), and electricity cost is between 0.18 and 0.22 /kWh Incentives are the same as for AFB
Overview of MSW
In the EU 53 Mt/yr (22% of total) are used for energy production. Germany has the largest capacity (59 kt/day), followed by France (46 kt/d) and Italy (21 kt/d) Energy recovery from MSW is regulated in Italy by DLgs 11/5/2005 n. 133 implementing directives 1999/31/EC and 2000/76/EC DLgs 133 establishes measures and procedures finalized at preventing atmospheric, water, and soil pollution and protecting human health. All installations require an Environmental Integral Authorisation (a complex and lengthy procedure) The main components of an MSW incineration plant are the same as for an AFB installation, but the cost will be higher. A 20 MW plant will use about 200.000 tons of MSW per year and have a cost of about 6000 /kWe Total MSW in Italy is about 33 Mt (550 kg/person), 14% is used for energy recovery (4.6 Mt, or 886 ktoe), 33 % is recycled (10%) or recovered in other ways (23%), 53% is sent to landfill (garbage dump) In Italy there are 53 plants for energy recovery from MSW with a total capacity of 730 MWe. The average size is 120.000 t/yr. They privilege electricity production, with a few exceptions, like district heating systems of Milano and Brescia (30.000 families). Turnover of this sector in Italy is about 1000 M, with 168 companies operating in the design, construction and operation of plants, waste collection and treatment. 40% of the upstream activities are made by foreign companies
Overview of biofuels
Biodiesel and bioethanol are the two main biofuels. Biodiesel is a mixture of methyl-esters and fat acids derived from vegetal oil or animal fat. Bioethanol is a fuel obtained from sugar (sugar cane, beet) or starch (amido). Before being mixed with gasoline it may be transformed into ETBE (ethyl-ter-buthyl-ether). Second generation bioethanol is made from lignocellulosic (non food) biomass. Third generation is algae fuels Directive 2003/30/EC has introduced reference values of biofuel share on the market (from 2% in 2005 to 5.75% in 2010, now postponed to 2015 by Directive 2009/28/EC). In Italy these levels are 3.5% (2010), 4% (2011) and 4.5% (2012).
There are 15 biodiesel production plants with a capacity of about 2.5 Mt/yr, but only 0.9 Mt (30% imported) have been consumed in 2009. This is due to incentive schemes based on capacity rather than production. Bioethanol and ETBE consumption amounted to 0.1 Mt in 2009, 90% of which comes from imported biomass treated in Italy
5200
Biomass advantages
Renewable or better regenerable source Price not linked to oil price Limited life cycle CO2 emissions (only during crop growing and transportation) Minimum sulphur content in flue gases May improve hydrogeologic territory conditions and socio-economical contest Economically already viable, for thermal use, even if with higher installation and maintenance costs
Productive chain
Forestry management wood
Thermal production Energy crops Grind-milling esterification bio-oil cogeneration biodiesel traction Agriculture waste Anaerobic digestion electrical production
biogas
Direct combustion
Combustor Boiler Power cycle Exhaust gas treatment
Combustion reactions
Combustion technologies:
www.biomassenergyresearch.ca
Fluidized-bed combustor
A fluidized-bed combustor is a furnace chamber whose floor is slotted, perforated, or fitted with nozzles. Air is forced through the floor and upward through the chamber. The chamber is partially filled with particles of either reactive or inert material (sand), which will fluidize at an appropriate air flow rate. When the gas velocity is high enough, fluidization takes place, solid particles are widely separated and circulate freely, creating a fluidized-bed that looks like a boiling liquid and has the physical properties of a fluid As air velocity increases, the particles mix more violently, and the surface of the bed takes on the appearance of a boiling liquid.
FBC is a combustion process able to control pollutant emissions without external emission controls (such as scrubbers* for flue gas desulfurization). The technology burns fuel at temperatures of 750-900 C, well below the threshold where NOx (at approximately 1400 C). The mixing action of the fluidized bed brings the flue gases into contact with a sulphur-absorbing chemical, such as limestone or dolomite. More than 95% of the sulphur pollutants in coal can be captured inside the boiler by the sorbent. A cyclone is used to either return fines to the bed or to remove ash-rich fines from the system.
Wet scrubbers
Inertial separators had the drawback of dust particles not accumulating properly on the collecting surface, resulting in finer particles being swept back into the air stream. Wet scrubbers, use water to absorb the finer dust particles (scrubbed). Water comes into contact with the dust filled air stream and captures dust in water droplets. The dirty water droplets accumulate, and are collected and removed. The cleaned air in air washers contains fine water droplets forming a mist, which can be removed from the cleaned air by a mist eliminator
Scheme of FBC
Carbonization
Carbonization: transforming wood into vegetal coal Process:
Preheating @ 165 without air with emission of C O2, water C vapour and heat Heating @ 250 C
Carbonization is a complex process in which many reactions take place concurrently such as dehydrogenation, condensation, hydrogen transfer and isomerisation*. The final temperature applied controls the degree of carbonization and the residual content of foreign elements
*Isomerisation is the process by which one molecule is transformed into another molecule which has exactly the same atoms, but the atoms are rearranged
Gasification
Converts biomass into a gaseous fuel easily employable in more advanced energy production systems (internal combustion engines, gas turbines). Consists in partial oxidation @ low oxygen rates and @ high temperature (900-1000 of lignocellulosic produ cts. C) Yields a combustible synthesis gas, formed by a mixture of hydrocarbons CxHy, CO, H2, CO2 and H2O. Typical lower calorific value
4 MJ/Nm3 air gasificators gasogen gas 10 MJ/Nm3 steam gasificators 12 MJ/Nm3 oxygen gasificators synthesis gas
Problems: technology still in the experimental phase, especially on small size low calorific value impurities in flue gases (particles and soot)
Anaerobic digestion
Anaerobic digestion is a series of processes in which pathogenic bacteria (Salmonella, Escherichia coli,..) break down biodegradable material in the absence of oxygen. As part of an integrated waste management system, anaerobic digestion reduces the emission of landfill gas into the atmosphere. Anaerobic digesters can also be fed with purpose-grown energy crops, such as maize. The process produces a biogas, consisting of methane, carbon dioxide and traces of other contaminant gases.
Anaerobic digestion
The digestion process begins with
bacterial hydrolysis of the input materials to break down insoluble organic polymers, such as carbohydrates, and make them available for other bacteria. Acidogenic bacteria convert the sugars and amino acids into CO2, H2, NH3, and organic acids. Acetogenic bacteria then convert these resulting organic acids into acetic acid, along with additional ammonia, hydrogen, and carbon dioxide. Finally, methanogens convert these products to methane and carbon dioxide.
This biogas can be used directly as cooking fuel, in CHP gas engines or upgraded to natural gas-quality biomethane. The nutrient-rich digestate also produced can be used as fertilizer. Yields biogas: methane (50-80%) + CO2 Calorific value H = xCH4*36 MJ/Nm3 CO2 may be afterwards eliminated
Aerobic digestion
Aerobic digestion is a bacterial process occurring in the presence of oxygen. Under aerobic conditions, bacteria rapidly consume organic matter and convert it into carbon dioxide (metabolization). Once there is a lack of organic matter, bacteria die and are used as food by other bacteria. This stage of the process is known as endogenous respiration. Solids reduction occurs in this phase. Because the aerobic digestion occurs much faster than anaerobic digestion, the capital costs of aerobic digestion are lower. However, the operating costs are characteristically much greater for aerobic digestion because of energy costs for aeration needed to add oxygen to the process. AD is an exogenous process suitable for sludge depuration installations in which complex substances are converted into simpler ones with CO2 and H2O emission Composting is an example of aerobic process
Alcoholic fermentation
Applied to sugar materials (sugar cane, beet (bietola), sugary sorghum (sorgo zuccherino)) and starch plants (wheat, barley (orzo), maize, potato) Transforms vegetal glucides (carbohydrates) into ethylic alcohol (C2H5OH) or bioethanol C6H12O 6 2C 2H5OH + 2CO2 Reaction May also be produced from lignocellulosic biomass (straw, maize waste) from previous hydrolization Bioethanol may be used as gasoline additive (up to 15% in weight)
methylic ester is called biodiesel Typically 1000 kg of oil + 100 kg of methanol = = 1000 kg of biodiesel + 100 kg of glycerine
emissions (g/kWh)
biogas combustion coal installations bituminous coal combustion coal powder combustion fluidized bed combustion natural gas installations internal combustion engines
gas turbines
0 waste wood fluidized bed poplar tree combustion combustion gasification in boilers MSW combustion biogas combustion bituminous coal combustion coal powder fluidized bed combustion combustion internal combustion engines gas turbines
examples cane, whole maize, gramineous beetrave, sorghum, sugar cane colza, soya, sunflower locust tree, willow, poplar oak, chestnut, conifer, beech
10
8 resa (tep/ha)
Wood biomass
100%
90%
80%
70%
60%
50% Oakwood, Locust tree (robinia) Shrub (arbusti) Pine New woods and underwood Beech (Faggio) Other conifers Chestnut Hygrophile plants
40%
30%
20%
10%
0% forest surface [875.000 ha] available wood [153 Mm3] withdrawable wood mass (820 kt/yr) yearly withdrawable energy [200 ktoe/yr]
Average (100-350 kW): wood chips or pellets (efficiency 75-80%) Large (> 350 kW): wood chips (efficiency 80-85%)
100
90
= 67 + 6 log Pn
Efficiency (%)
80
70
Moisture
Wood is normally not dry, but has a variable moisture content. This may be expressed through moisture on dry wood Udry or as moisture on wet wood (tal quale) Uw, defined as
Udry = Mw Mdry Mdry
Uw =
Mw Mdry Mw
Mw = mass of wet wood Mdry = mass of dry wood Moisture on wet wood is usually between 35% and 50%, depending on the type of wood, time passed since biomass production (new biomass is obviously more humid) and type of storage.
H=
= Hdry Uw (Hdry + r )
MJ/kg
2.4 19.2
H = 19.2 21.6 Uw
[MJ / kg]
20
Udry
80%
15
60%
chipwood
10 40%
20%
0% 60%
Udry (%)
350
300
250
200
150
100
50
0 0 5 10 15 anni 20 25 30
Mass-diameter ratio
18000 16000
10000
8000
6000
4000
2000
1200
1000
800
600
400
200
feature optimal power range (kW) Power control range Moisture on wet (%) ash content (%) efficiency (%)
Storage volume
4000 3500 Volume accumulo (litri) 3000 2500 2000 1500 1000 500 0 0 50 100 150 200 250 300 Prodotto potenza-ore di funzionamento (kWh)
Q/Pmin = 0.8 Q/Pmin = 1 Q/Pmin = 1.2 Q/Pmin = 1.5 Q/Pmin = 2 Q/Pmin = 2.5
No more than 70% of the available space may be used Ensuring complete unload of a truck without waiting that the store-house is completely empty is important (stock breaking should be avoided) useful volume of fuel store-house should be :
> 50% maximum truck load = two weeks fuel need
deposito
Boiler room and store-room have always to be separated for fire protection reasons. Adequate room shoul be provided for around the different components of the installation in order to allow maintenance, loading and repair.
Lower feed boiler for dry fuel Lower feed boiler for moist fuel Fixed grille boiler Mobile grille boiler
The best equipment for wood factories, especially for low-medium capacities. The special combustion chamber structure reduces slag (scorie) formation even for very dry material and wood shavings.
Power range: Power control range Moisture of fuel Ash content up to Nominal efficiency from
V=
E N H vu ,m
Extraction of ashes
Ash quantity depends on biomass typology: beech wood, (faggio) almost without bark, will produce 0,2% ashes, while ash-tree (frassino) will produce 7%. When burning branches, bark, dirty (waste) wood and packing the frequency of removal of ash container will increase Ash extraction systems also include particulate extraction from cyclone flue gas filters and from combustion chamber. They can be manual for small installations automatic for large installations. E.g., scroll or auger or pneumatic extractor.