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MATERIAL SAFETY DATA SHEET 1.

CHEMICAL PRODUCT AND COMPANY IDENTIFICATION


PRODUCT NAME: PRODUCT CODE: 6% MANGANESE LIN-ALL P.I. DRIER 115223
DATE REVISED: 01/17/2008 DATE PRINTED: 02/22/2008 CHEMICAL FAMILY/USE: Metal Carboxylate

MANUFACTURING LOCATION:
OMG AMERICAS, INC. TWO MILE RUN ROAD VENANGO COUNTY, FRANKLIN, PA 16323 PLANT TELEPHONE NUMBER: 814-432-2125 CUSTOMER SERVICE, R&D AND SALES: 440-899-2950

IN CASE OF EMERGENCY CONTACT:


CHEMTREC: 800-424-9300 (24 HOURS A DAY, 7 DAYS A WEEK) OUTSIDE THE US: + (703)-527-3887 (COLLECT CALLS ACCEPTED) HMIS: HEALTH: FLAMMABILITY: REACTIVITY: PERSONAL PROTECTION: 2 1 0 B

2. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW: Brown liquid. Manganese compounds can cause central nervous system and pulmonary system damage by inhalation of fumes and dust. Causes skin and eye irritation. May be harmful if swallowed. Causes eye irritation. Symptoms may include stinging, tearing, and redness. Causes skin irritation. Prolonged or repeated skin contact may cause dermatitis. Manganese compounds can cause central nervous system damage by inhalation of fumes and dust. Central nervous system effects may include drowsiness and perioral numbness. Respiratory effects may include "metal fume fever" and pleuritis. Chronic exposure may cause Parkinson-like symptoms (such as muscle weakness, tremor, slurred speech, and gait disturbances). May cause psychiatric symptoms such as nervousness and irritability. May be harmful if swallowed. Aspiration of this material can cause chemical pneumonia.

EYE CONTACT: SKIN CONTACT: INHALATION:

INGESTION:

3. COMPOSITION/INFORMATION ON INGREDIENTS
CHEMICAL NAME Manganese Tallate 8030-70-4 PERCENT ACGIH TLV: ACGIH STEL: >99 0.2** NE OSHA PEL: OSHA STEL: 5** Ceiling NE Units that the TWAs and STELs are in: mg/m3

**For Manganese, fume as Mn 6% MANGANESE LIN-ALL P.I. DRIER

PRODUCT CODE: 115223

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JAPANESE ENCS NUMBER(S): Manganese Tallate: (2)-615 JAPANESE INDUSTRIAL SAFETY HYGIENE AND LABOR (ISHL): Manganese Compounds are regulated under ISHL, number 33, as Manganese and its Compounds.

4. FIRST AID MEASURES


EYES: Flush immediately with large amounts of water and continue flushing for 15 minutes or until irritation subsides, whichever is longer. If irritation persists, seek medical attention. SKIN: Immediately wash thoroughly with water and mild soap or detergent. If skin irritation persists, seek medical attention. INHALATION: Move the exposed person to fresh air at once. If indicated, a qualified pre-hospital medical provider (such as a first responder or EMT) may give oxygen. Contact a physician. INGESTION: Aspiration hazard. Do not induce vomiting or give anything by mouth because this material can enter the lungs and cause severe lung damage. If the victim is drowsy or unconscious, place on left side with head down. If possible, do not leave victim unattended. Seek immediate medical attention. MEDICAL CONDITIONS AGGRAVATED: Conditions aggravated by exposure may include skin disorders and respiratory (asthma-like) disorders. NOTE TO PHYSICIAN: Manganese toxicity following acute ingestion is rare due to poor gastrointestinal absorption. Acute inhalation of high concentrations may result in respiratory symptoms consistent with chemical pneumonitis. Chronic exposure generally requires at least six months for symptoms to develop. Chelation therapy for manganese toxicity may enhance urinary excretion and mobilization of manganese in the blood, but its effectiveness in improving neurological signs and symptoms has not been clearly demonstrated. Levodopa therapy may result in improvement of neurological toxicity.

5. FIRE FIGHTING MEASURES


FLASH POINT ( F) 230, PMCC OSHA FLAMMABILITY CLASSIFICATION: Combustible Liquid-Class III B EXTINGUISHING MEDIA: Carbon dioxide, dry chemicals, foam. SPECIAL FIREFIGHTING PROCEDURES: Water may be ineffective but can be used to cool containers exposed to heat or flame. Caution should be exercised when using water or foam as frothing may occur, especially if sprayed into containers of hot, burning liquid. EXPLOSION LIMITS IN AIR - LOWER (%) Unknown EXPLOSION LIMITS IN AIR - UPPER (%) Unknown AUTOIGNITION TEMP ( F) Unknown UNUSUAL FIRE AND EXPLOSION HAZARDS: None known.

6. ACCIDENTAL RELEASE MEASURES


ACTION TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Contain spill immediately. Do not allow spill to enter sewers or watercourses. Remove all sources of ignition. Provide adequate ventilation during clean-up. Absorb with solvent absorbent material. Large spills may be picked up using vacuum pumps, shovels, buckets, or other means and placed in drums or other suitable containers. Dispose according to federal, state and local regulations.

7. HANDLING AND STORAGE


HANDLING: Keep container closed when not in use. Avoid contact with eyes, skin and clothing. Avoid breathing vapor. Wash thoroughly after handling. Use only with adequate ventilation. STORAGE: Store in a cool, well ventilated area in closed containers away from heat, sparks, open flame or oxidizing materials.

6% MANGANESE LIN-ALL P.I. DRIER

PRODUCT CODE: 115223

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8. EXPOSURE CONTROLS/PERSONAL PROTECTION


ENGINEERING CONTROLS: Local exhaust recommended when generating excessive levels of vapors when heating product. Use explosion-proof equipment if high vapor concentrations and heat environments coexist. RESPIRATORY PROTECTION EQUIPMENT: Use NIOSH approved respiratory protection where airborne level exceeds appropriate occupational exposure limit. PROTECTIVE GLOVES: For operations where prolonged or repeated contact of product with skin can occur, wear impermeable gloves. For heated product use any type impermeable rubber thermal insulating gloves. EYE AND FACE PROTECTION: For operations where eye or face contact can occur, wear splash proof goggles or face shield. OTHER PROTECTIVE EQUIPMENT: Launder soiled clothes. Properly dispose of contaminated leather articles including shoes, which cannot be decontaminated. For prolonged or repeated exposures, use impervious clothing (boots, aprons, etc.) over parts of body subject to exposure. VENTILATION: If vapor or mist is generated when the material is heated or handled, adequate ventilation in accordance with good engineering practice must be provided to maintain concentrations below the specified exposure or flammable limits.

9. PHYSICAL AND CHEMICAL PROPERTIES


Boiling Range/Point Vapor Pressure Vapor Density (AIR=1) Freezing Point Melting Point Physical State Color % Volatile by Weight %Volatile by Volume Evaporation Rate ( Butyl Acetate=1) Specific Gravity @ 25C Weight per gallon 510 F Unknown Heavier than air Unknown Unknown Liquid Brown 1 1 Slower than ether 1.02 8.5 lbs.

10. STABILITY AND REACTIVITY


STABILITY: Stable. HAZARDOUS POLYMERIZATION: Will not occur. HAZARDOUS THERMAL DECOMPOSITION/COMBUSTION PRODUCTS: When product is heated to decomposition, product will emit acrid dense smoke with carbon dioxide, carbon monoxide, trace sulfur oxides, water and other products of combustion. Manganese oxide. INCOMPATIBILITY (MATERIALS TO AVOID): Avoid contact with strong oxidizing agents. Avoid prolonged contact with porous materials. CONDITIONS TO AVOID: Avoid excess heat and incompatibles.

11. TOXICOLOGICAL INFORMATION


TOXICITY DATA: This product is not listed as a carcinogen by IARC, NTP or OSHA. ACUTE ORAL LD50: No data at this time. ACUTE DERMAL LD50: No data at this time. ACUTE INHALATION LC50: No data at this time.

12. ECOLOGICAL INFORMATION


ECOTOXICOLOGICAL INFORMATION: No data at this time. CHEMICAL FATE INFORMATION: No data at this time. 6% MANGANESE LIN-ALL P.I. DRIER PRODUCT CODE: 115223

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13. DISPOSAL CONSIDERATIONS


DISPOSAL METHOD: Disposal should be made in accordance with federal, state and local regulations.

14. TRANSPORT INFORMATION


DOT SHIPPING NAME: DOT HAZARD CLASS: UN/NA NUMBER: DOT PACKING GROUP: AIR TRANSPORTATION: OCEAN TRANSPORTATION: Not Regulated None None None Not Regulated Not Regulated

15. REGULATORY INFORMATION


TSCA STATUS: This product is listed on the US TSCA Inventory. TSCA 12(b) EXPORT NOTIFICATION: This product is not subject to TSCA 12(b) export notification requirements. CALIFORNIA PROPOSITION 65: This product is not known to contain any chemicals known to the state of California to cause cancer or birth defects. However, we do not conduct routine analysis for all listed materials. SARA 302 EXTREMELY HAZARDOUS SUBSTANCE LIST: This product does not contain greater than 1.0% of any chemical substance on the SARA Extremely Hazardous Substance List. CLEAN AIR ACT S112 HAZARDOUS AIR POLLUTANTS: Manganese Compounds. SARA (311, 312) HAZARD CLASS: Acute health hazard. SARA SECTION 313 TOXIC CHEMICALS: Manganese Compounds >99%

AUSTRALIAN INVENTORY CHEMICAL SUBSTANCES: This product is listed on the Australian Core Inventory of Chemical Substances (ACOIN). CANADIAN INVENTORY: This product is listed on the Domestic Substance List (DSL). EINECS REGULATIONS: This product is listed on the European Existing Chemical Substance Inventory (EINECS). JAPAN: This product is listed on the Japanese Existing and New Chemical Substances (ENCS). KOREAN CHEMICAL INVENTORY: This product is listed on the Korean List of Existing Chemical Substances (ECL). PHILIPPINE INVENTORY: This product is listed on the Philippines Inventory of Chemicals and Chemical Substances (PICCS). JAPANESE POLLUTANT RELEASE TRANSFER REGISTER (PRTR): Manganese Compounds are Class 1 regulated substances, number 311, as Manganese and its Compounds. The annual threshold quantity is 1.0 tons.

16. OTHER INFORMATION


DISCLAIMER OF EXPRESSED AND IMPLIED WARRANTIES: The information in this document is believed to be correct as of the date issued. However, no warranty of merchantability, fitness for any particular purpose, or any other warranty is expressed or is to be implied regarding the accuracy or completeness of this information, the results to be obtained from the use of this information or the product, the safety of this product, or the hazards related to its use. This information and product are furnished on the condition that the person receiving them shall make his own determination as to the suitability of the product for his particular purpose and on the condition that he assume the risk of his use thereof. 6% MANGANESE LIN-ALL P.I. DRIER PRODUCT CODE: 115223

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17. LABEL INFORMATION


SIGNAL WORD: CAUTION TARGET ORGANS: Manganese compounds can cause central nervous system and pulmonary damage by inhalation of fumes and dust. Causes skin and eye irritation. May be harmful if swallowed. EYES: Flush immediately with large amounts of water and continue flushing for 15 minutes or until irritation subsides, whichever is longer. If irritation persists, seek medical attention. SKIN: Immediately wash thoroughly with water and mild soap or detergent. If skin irritation persists, seek medical attention. INHALATION: Move the exposed person to fresh air at once. If indicated, a qualified pre-hospital medical provider (such as a first responder or EMT) may give oxygen. Contact a physician. INGESTION: Aspiration hazard. Do not induce vomiting or give anything by mouth because this material can enter the lungs and cause severe lung damage. If the victim is drowsy or unconscious, place on left side with head down. If possible, do not leave victim unattended. Seek immediate medical attention. HANDLING: Keep container closed when not in use. Avoid contact with skin, eyes and clothing. Avoid breathing vapor. Wash thoroughly after handling. Use only with adequate ventilation. STORAGE: Store in a cool, well ventilated area in closed containers away from heat, sparks, open flame or oxidizing materials. ACTION TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Contain spill immediately. Do not allow spill to enter sewers or watercourses. Remove all sources of ignition. Provide adequate ventilation during clean-up. Absorb with solvent absorbent material. Large spills may be picked up using vacuum pumps, shovels, buckets, or other means and placed in drums or other suitable containers. Dispose according to federal, state and local regulations. EXTINGUISHING MEDIA: Carbon dioxide, dry chemicals, foam.

6% MANGANESE LIN-ALL P.I. DRIER

PRODUCT CODE: 115223

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