3 Novec

Product Information

Engineered Fluid HFE-7100

Introduction
3M Novec Engineered Fluid HFE-7100, methoxy-nonauorobutane (C4F9OCH3), is a clear, colorless and low-odor uid intended to replace ozone-depleting materials in many applications. Its physical properties are compared with several other ODS replacement uid candidate in Table 1. This proprietary uid has zero ozone depletion potential and other favorable environmental properties (see Table 2). It has one of the best toxicological proles of the new CFC replacement materials, with a time-weighted average exposure guideline of 750 ppm (eight hour average). The high boiling point, increased solvency and low surface tension of Novec uid HFE-7100 make it ideal for use in vapor degreasing applications as a neat (pure), azeotropic or co-solvent parts cleaner. In addition, its chemical and thermal stability, non-ammability and low toxicity make it useful for many other industrial and specialty solvent applications (see below).

Typical Applications
Cleaning and rinsing agent Heavy-duty (co-solvent) cleaning heavy oils, greases, uxes Medium-duty cleaning (azeotrope) oils, greases, waxes Light-duty cleaning (neat) particulates, uorolubes, light oils, uoropolymers Lubricant carrier Fluorocarbons Hydrocarbons Silicones Spot-free water drying agent (with surfactants added) Specialty solvents, dispersion medium, reaction medium Spray contact cleaner CFC, HCFC, HFC and PFC replacement Dielectric test media

Material Description
Methoxy-nonauorobutane1 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .99.5% minimum Appearance . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Clear, colorless Non-volatile residue (NVR) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .2.0 ppm maximum
1

HFE-7100 uid (C4F9OCH3) consists of two inseparable isomers with essentially identical properties. These are (CF3)2CFCF2OCH3 (CAS No. 163702-08-7) and CF3CF2CF2CF2OCH3 (CAS No. 163702-07-6).

3M Novec Engineered Fluid HFE-7100 Physical Properties Table 1

Data compiled from published information Not for specication purposes
Properties HFE-7100 CFC-113 HCFC-141b HCFC-225 ca/cb HFC-4310

Formula Molecular Wt. Boiling Pt C Freeze Pt C Flashpoint Flammability Range in Air Liquid Density1 Surface Tension2 Solubility of Solvent in Water3 Solubility of Water in Solvent3
1

C4F9OCH3 250 61 -135 None None 1.52 13.6 12 95

dynes/cm @ 25C

C2Cl3F3 187 48 -35 None None 1.56 17.3 170 110

3

C2Cl2H3F 117 32 -103 None 7.1-18.64 1.23 19.3 210 420

4

C3Cl2HF5 203 54 -131 None None 1.55 16.2 330 310

C5H2F10 252 54 -80 None None 1.58 14.1 140 490

g/ml @ 25C

ppm by weight

Vol % by ASTM E681-94 @ 100C

Environmental Properties Table 2

Data compiled from published information Not for specication purposes
Properties Ozone Depletion Potential1ODP Global Warming Potential2GWP Atmospheric LifetimeALT (yrs)
1

HFE-7100 0.00 320 4.1

CFC-113 HCFC-141b HCFC-225 ca/cb HFC-4310 0.80 6000 85 0.10 700 9.2 0.03 180/620 2.1/6.2 0.00 1700 17.1

CFC-11 = 1.0

GWP100 year Integration Time Horizon (ITH)

NOTE: HCFC-225 ca/cb ratio is 45/55

3M Novec Engineered Fluid HFE-7100 Regulatory Status

3M Novec Engineered Fluid HFE-7100 has been accepted for commercial use by regulatory agencies in the United States, Canada, Japan, Korea, Australia and Europe (under the European List of Notied New Chemical Substances) Novec uid HFE-7100 has been approved under the Signicant New Alternatives Policy (SNAP) of the U.S. EPA. In addition, HFE-7100 uid has been excluded by the U.S. EPA from the denition of a VOC on the basis that this compound has negligible contribution to tropospheric ozone formation. Contact your local 3M representative regarding the regulatory status of HFE-7100 uid in other countries.

Toxicity Prole
The toxicological testing completed on Novec uid HFE-7100 shows the overall toxicity is low. The material is practically non-irritating to the eyes, minimally irritating to the skin and is not a mutagen or cardiac sensitizer. It is rated practically non-toxic through inhalation. A 90-day inhalation study has helped establish a recommended exposure guideline of 750 ppm for an eight-hour average worker exposure per day. This exposure guideline was established by the American Industrial Hygiene Association. Toxicological Test Results

Properties
Acute lethal inhalation concentration Oral Eye irritation Skin irritation Skin sensitization Developmental toxicity Mutagenicity Cardiac sensitization Ecotoxicity testing 90-day inhalation

HFE-7100
>100,000 ppm (4 hour) Practically non-toxic (>5 g/kg) Practically non-irritating Minimally irritating Not a skin sensitizer Detailed results are available Negative in the three assays conducted No signs of sensitization at exposures up to 100,000 ppm Completevery low aquatic toxicity 750 ppm exposure guideline Detailed results are available

3M Novec Engineered Fluid HFE-7100 Vapor Pressure and Density

The variation of vapor pressure and density with temperature for 3M Novec Engineered Fluid HFE-7100 can be calculated using the following formulas: Vapor Pressure: ln P = 22.415 - 3641.9 [1/(t+273)] Density: D = 1.5383 - 0.002269t P = Vapor Pressure in Pascals t = Temperature in C D = Density in g/ml

Materials Compatibility
Testing of Novec uid HFE-7100 demonstrates compatibility with a wide range of metals, plastics and elastomers, similar to the performance of peruorinated liquids. Good compatibility with particularly sensitive plastics such as polycarbonate and PMMA indicates utility in cleaning of assemblies containing many composite materials. As with most uorinated liquids, HFE-7100 uid will absorb into uorinated plastics and elastomers over longer exposures.

Metals
Aluminum Copper Carbon Steel 302 Stainless Steel Brass Molybdenum Tantalum Tungsten Cu/Be Alloy C172 Mg Alloy AZ32B

Plastics
Acrylic (PMMA) Polyethylene Polypropylene Polycarbonate Polyester Epoxy PET Phenolic ABS

Elastomers
Butyl Rubber* Natural Rubber EPDM EPR

Compatible after one hour exposure at boiling temperature. Exceptions: Some swelling of PTFE and silicone rubber. Some surface oxidation of copper during heat aging. *Butyl Rubber best for extended exposure > one month.

3M Novec Engineered Fluid HFE-7100 Safety and Handling

Novec uid HFE-7100 is nonammable and does not exhibit ammability characteristics under normal operating and storage conditions. This uid is highly resistant to thermal breakdown and hydrolysis in storage and during use. Detailed recommended handling procedures are provided in the pertinent Material Safety Data Sheet, which is available from your local 3M representative upon request.

Environmental Policy
3M will continue to recognize and exercise its responsibility to prevent pollution at the source wherever and whenever possible; develop products that will have a minimal effect on the environment; conserve natural resources through the use of reclamation and other appropriate methods; assure that its facilities and products meet and sustain the regulations of all federal, state and local environmental agencies; assist, wherever possible, governmental agencies and other ofcial organizations engaged in environmental activities. Packaging and Availability Novec uid HFE-7100 may be ordered in the following container sizes: 55-gallon drum; 30-gallon drum; 5-gallon pail; 1-gallon pail 4-ounce samples for limited or preliminary test work are available

3M Novec Engineered Fluid HFE-7100 Recycle and Disposal Options Used Fluid Return Program
3M offers a program for free* pickup and return of used 3M specialty uids in the U.S. through Safety-Kleen Corp. A pre-negotiated handling agreement between users and this service provider offers users broad protection against future liability for used 3M product. The uid return program is covered by independent third-party nancial and environmental audits of treatment, storage and disposal facilities. Necessary documentation is provided. A minimum of 30 gallons of used 3M specialty uid is required for participation in this free program.* Safety-Kleen Corp. has a network of 156 branch service centers in the U.S. This large eet will provide timely, economical uid disposal service. For additional information on the 3M Used Fluid Return Program, contact SafetyKleen at this toll-free line: 1.888.932.2731. Contact your local 3M representative for uid return programs outside the U.S.
* Must have a 30 or more gallon purchase to participate in the 3M paid program. Used product of 5-30 gallons can be returned through Safety-Kleen at the users expense.

Resources
3M Novec Engineered Fluids are supported by global sales, technical and customer service resources, with fully-staffed technical service laboratories in the U.S., Europe, Japan, Latin America and Southeast Asia. Users benet from 3Ms broad technology base and continuing attention to product development, performance, safety and environmental issues. For additional technical information on Novec uid HFE-7100 in the United States, call 3M Performance Materials Division, 800.833.5045. For other 3M global ofces, and information on additional 3M uids, visit our web site at: www.3m.com/uids

North America
3M Specialty Materials 3M Center, Building 223-6S-04 St. Paul, MN 55144-1000 800 833 5045

Europe
3M Specialty Materials 3M Belgium N. V . Haven 1005, Canadastraat 11 B-2070 Zwijndrecht 32 3 250 7521

3M Canada Company
Specialty Materials P.O. Box 5757 London, Ontario N6A 4T1 800 364 3477

Sumitomo 3M Limited
33-1, Tamagawadai 2-chome Setagaya-ku, Tokyo 158-8583 Japan 813 3709 8250

Asia Pacic and Latin America

Call (U.S.) 651 736 7123

Important Notice to Purchaser: The information in this publication is based on tests that we believe are reliable. Your results may vary due to differences in test types and conditions. You must evaluate and determine whether the product is suitable for your intended application. Since conditions of product use are outside of our control and vary widely, the following is made in lieu of all express or implied warranties (including the warranties of merchantability or tness for a particular purpose): 3Ms only obligation and your only remedy is replacement of product that is shown to be defective when you receive it. In no case will 3M be liable for any special, incidental, or consequential damages based on breach of warranty or contract, negligence, strict tort, or any other theory.

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Specialty Materials 3M Center, Building 223-6S-04 St. Paul, MN 55144-1000 www.3m.com/uids
Issued: 10/00 2000 3M IPC 98-0212-2430-2 (HB)