STD- 11th SCIENCE CHEMISTRY Date: 28/10/2012 (1) What will be value of 318 K in Fahrenheit scale?

(A) 113F (B) 183F (C) 380F (D) 318F Marks: 100

(2) In which of the orbital, last electron entering in Chlorine will make the pair? (A) 3Px (A) 4, 7 (B) 3Py (B) 6, -1 (C) 3Pz (C) 4, -1 (D) 3S

(3) In the compound formed by Silicon and Bromine, the valency of Si and Br respectively will be (D) 4, 3

(4) Identify the element of group-1, period-5. (A) Potassium (B) Rubidium (C) Cesium (D) Francium

(5) Which of the following compound contain nitrogen atom in its +3 oxidation state? (A)NH2-NH2 (A) ethane (B) Ammonium Nitrite (C) Ammonium Nitrate (D) NH2OH

(6) Which of products is available when ethyne react with hydrogen in presence of raney nickel at 390 K? (B) ethanol (C) enthanol (D) ethane 1, 2-diol

(7) Select the product available by thermal decomposition of sodium nitrate. (A) N2 (A) Electrophile (B) NO2 (C) O2 (D) Na2O (C) Only anion (D) A and B

(8) State the product available on hetrolytic fission. (B) nucleophile

(9) "Matter can neither be created nor be destroyed during chemical reaction", the statement define which of the following laws? (A) Atomic theory of Dalton (C) Law of Conservation of mass (B) Law of Chemical combination (D) First Law of Thermodynamics

(10) Which of the following series is belong to infrared region of the spectrum? (A) Paschen (B) Lyman (C) Balmer (D) X-rays

(11) Blue colour of aqueous solution of CuSO4 lightens when Zn-rod is introduced to it because (A) Cu2+ ions of CuSO4 get precipitated. (C) Cu2+ ions are reduced to Cul+ ions. (B) CuSO4 gets converted to Cu(OH)2 (D) A layer of copper metal is deposited on Zn-rod. (C) R-NH3+C1-

(12) Which cation exchange resin is used in order to remove Ca2+ and Mg2+ ions from hard water? (A)Na2Al2Si4O12 (A) Beryllium Peroxide (B) RSO3H (B) Beryllium Nitrate (D) all

(13) Name the product available on burning powdered beryllium in air. (C) Beryllium Nitride (D) (A) and (C) both

(14) In which of the following molecules all the carbon atoms exhibit same type of Hybridisation? (A) Cyclobutane (B) n-butane (C) Isobutane (D) All

(15) Which of the following is the character of 1, 1, 1, 2 tetra fluoro-ethane ? (A) It is harmless pesticide. (B) Molecule is known as HFC-134a is less harmful to ozone layer. (D)It is used in preparing chemical fertilizer.

(C)It is used to prepare medicine for treatment of Cancer.

(16) Give mass of the fundamental particle discovered by Thomson. (A) 1.672 X 10-27 u (B) 0.00054 u (C) 1.674 x 10-27 u (D) 1.00727u

(17) Symbol of the orbit and type of orbltals present in n = 4 respectivelyme? (A)N, 16 (B) N, 9 (C) N,18 (D)N, 4

(18) Identify the Lanthanoids series (A) z = 56 to z=69 (B) z = 58 to z = 71 (C)z = 57 to z = 70 (D) z = 59 to z =72

(19) Distance of both atoms in solid sodium chloride molecule is 198pm. What will be the distance of both atoms in sodium chloride solution? (A) 0 pm (B) 198 pm (C) 99 pm (D) none

(20) Give reactivity correct order of Mg, O, F and Cl with reference to oxidising agent character. (A) F>O>C1>Mg (B) F>C1>O>Mg (C) Cl > F > O > Mg (D) O > F > Mg > Cl

(21) Which element gives purple colour in flame test? (A) Li (B) Cs (C) K (D) Ca

(22) State the oxidation number of sulphur atom in (NH4)2SO4 (A)+4 (B) +6 (C) +7 (D)0 (23) What is atomic no of Uut? (A) 111 (B) 112 (C) 113 (D) 114

(24) Which of the following compounds is not give water in reaction with Hydrogen Peroxide? (A) HNO4 (A) Dicalcium Silicate (B) HOCl (C) PbS (D) H2SO3 Dicalcium Aluminate

(25) Which of the following compounds is not present in Portland cement? (B) Tricalcium Silicate (C) Tricalcium Aluminate (D)

(26) Which of the following group can be used as coolant in atomic reactor? (A) Halogen (B) Alkali metals (C) Alkaline metals (D) Noble gas

(27) Which type of isomer gives C5H12O? (A) Position isomers (B) Functional group isomers (C) both A & B (D) None (28) How many and bonds are present in Hex 2-ene-4 yne respectively? (A) 10, 3 (B) 11, 2 (C) 12, 4 (D) 12, 3

(29) NH3 is of following compound (A) Electrophile (B) Nucleophile (C) none (D) A and B (30) Which of the elements have minimum shielding effect from following groups? (A)Group-13, Period-2 (B) Group-13, Period-3 (B) O2(C) Group-13, Period-4 (D) Group-13, Pcriod-5 (C) F-1

(31) Which of the following ions has minimum ionic radius? (A) O (D) F (32) Give No. of protons, electrons and neutrons respectively in positive 2 charged ion formed by 34Se70. (A) 34, 32, 36 (B) 34, 36, 32 (C) 34, 32, 36 (D) 36, 34, 36 (33) Which element has positive electron gain enthalpy? (A)S (B) O (C) Ne (D) F

(34) Electron configuration of Kr (z = 36) is? (A) [Ar] 3d10 4s2 4p5 (B) [Ar] 3d5 4s2 4p6 (C) [Ar] 3d10 4s2 4p6 (D) [Ar] 3d10 4s1 4p7

(35) The compound is neutral for the statement which is true? (A) Can have positive element (B) Can have negative element (C) Both (D) None

(36) State the total increase in the oxidation number of central atom of oxidising agent in following reaction. Reaction N2H4 + Cu(OH)2 N2 + Cu (37) Which of the Hydride of Nitrogen has basic character? (A)N2H4 (A) Be4C3 (A) Na (B) NH3 (B) Al4C3 (B) Ca (C) N3H (C) Be2C2 (C) Cu (D) N2H2 (D) Al3C3 (D) Fe (A) 2 (B) 4 (C) 8 (D) 0

(38) Methane is available during hydrolysis of?

(39) Which element is cause coagulation of blood?

(40) Which of the following salts give brick red flame? (A)SrCl2 (A)0.1N (B) KC1 (C) CaCl2 (C) 0.2N (D) BaCl2 (D)0.3N (41) 100 ml 0.3N HNO 3 acid is mixed with 200ml 0.6N H 2 SO4 . Calculate normality of H + ion. (B) 0.5N (42) 560 tonns of pure lime is obtained from how much limestone is heated? (A) 5600 tonns (A) 2 X 1010 cm s-1 (B) 440 tonns (B) 0.218 x 1010 cm s-1 (B) (n-2)f(n- l)d1 ns2 (C) 560 tonns (C) 2.5 x 1010 cm s-1 (D) 1000 tonns (D) 2.18 x 1010 cm s -1 (43) Electron revolving in first orbit of hydrogen atom has 0.53 Ao radius. Calculate velocity of electron.

(44) Give the general electron configuration of f-block elements respectively. ( A ) (n-2)f n (n- l)d1 ns2 (C)(n-2)f 1 - 1 4 (n-l)d -1 ns 2 (D)(n-2)f n + 1 ns 2

(45) Give symbol and atomic number respectively for the elements Unu and Uno. (A)
101 Md, l08 Hs

(B)

101 Md, 100 Ds

(C) 103 Lr 108Hs

(D)

104 Rf, 111 Rg

(46) Give the correct order of ionic radius of 3 rd raw elements. (A) P-3 > S-2 > Cl- < Na+1 < Mg+2 < Al+3 < Si+4 (C) Na+ > Mg2+ > Al3+ > Si4+ < P3- > S2- > Cl(B) Na+ > Mg2+ > Al3+ > Si+4 < P-3 < S2- < Cl(D) Na+< Mg2+< Al3+< Si+4 < P-3 < S2-< Cl-

(46) Change in oxidation no. of oxygen in H2O2 when it reacts reducing & oxidising agent respectively (A)-2 to -1 and -1to 2 (B) -l to -2 and -1to 0 (C) l to 0 and -1 to -2 (D) -l to -2 and -2 to -1 (48) What is coefficient a, b, c, d, e, in reaction? aCCI4 + bK2CrO4 cCl2CO + dCrO2Cl2 + eKC1 (A) 1, 2, 1, 2, 1 (B) 2, 1, 2, 1, 2 (C) 1,1, 2, 2, 2 (D) 2, 2, 1, 1, 1 (49) With limited quantity of oxygen and with excess quantity of oxygen, oxides of K respectively are (A)K2O and K2O2 (A) Aluminium Chloride (B) K2O2 and KO2 (B) Aluminium Bichloride (C) K2O and KO2 (C) Aluminium Dichloride (D) KO2 and K2O (D) none

(50) What is Friedel-craft reagent?

(51) Products obtained by reaction between Ca3N2 with excess quantity of water are (A) Ca(OH)3 (B) Ca2(OH)2 (C) CaO (D) None

(52) Oxidation number of O3 (A) -2 (B) 0 (C) -1 (D) +1 (53) What will be value of molarity rity and strength %W/V respectively 30V H2O2 solution? (A) 2.678 M, 18.22% (B) 2.678 M, 9.11% (C) 5.356 M, 18.22% (D) 5.356 M, 9.11% (54) The product of reaction between Propene and chlorine gas is? (A) 2, 2-dichloropropane (B) 1,3- dichloropropane (C) 1,2- dichloropropane (D) 1, 2 - dicopchloropropane (55) IUPAC name of the compounds CH3COOCH3 (A) Methyl methanoate (A) 6.02 x 1020 (57) Name the structure: (A) 9 chloro 3 fluorooctane (B) 1 chloro 6 fluorooctane (C) 6 fluoro 1 chlorooctane (D) 3 fluoro 9 chlorooctane (58) Name the structure: (B) Methyl ethanoate (B) 1.2 x 1020 (C) Methyl ethioate (C) 1.2 x 1022 (D) none (D) 6.02 x 1019 (56) 5.85 g of NaCl is dissolved in water to prepare 1.0 ltr solution. No. of ions in 1.0 ml of this solution is

(A) 1,2 diamine 5 chloro pentane (C) 1 chloro 4,6 diamine pentane

(B) 5 chloro 1,2 diamine pentane (D) 4,6 diamine 1 chloro pentane

(59) Temporary and permanent hardness of hard water can be removed respectively by addition of (A) CaO, NaHCO3 (B) NaHCO3, NaHCO3 CaCl2 (C) Ca(OH)2, Na2CO3 (D) Na2CO3, CaCl2

(60) Choose the correct reactivity order from the following. (A) -CONH2 > -COOR > -NO2 > -x > -R (C) -C=N > -COOH > -NH2 >~-COOR COOR >-CONH2 (61) Which of the following is not an electrophile? (A) ROH (B) CH3CN (C) CH3NH2 (D) all (B) -CHO > -CONH2 > -NH2 > -CO- > -OH (D) -COOR > -CONH2 > -CHO > -C=N >-CO-

(62) Sulphur trioxide is prepared by following two reactions. S6 + 6O2 6SO2 & 2SO2 + O2 2SO3 How many grams of SO3 are produced from 0.5 mole of S6? (A) 480.0 (B) 960.0 (C) 240.0 (D) 120.0 (63) Reaction of Br2 with Na2CO3 in aqueous solution gives sodium bromide (NaBr) and sodium bromate (NaBrO3) with evolution of CO2 gas. The numbers of Br2 and sodium bromide molecule involved in the balanced chemical equation respectively are (A) 3, 5 64. Name the structure: (B) 5, 3 (C) 2, 4 (D) 4, 2

(A) 7 amino 6 bromo 7 chloro 2,5 dimethyl heptane 3,4 dione (B) 7 amino 7 chloro 6 bromo 2,5 dimethyl heptane 3,4 dione (C) 1 amino 2 bromo 1 chloro 3,6 dimethyl heptane 4,5 dione (D) 1 amino 1 chloro 2 bromo 3,6 dimethyl heptane 4,5 dione