FIITJEE Concept Recapitulation Test (Set - V) - PCM-JEE(Main)/13

FIITJEE Ltd.
, FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com

CONCEPT RECAPITULATION TEST
(Set V)

Time Allotted: 3 Hours Maximum Marks: 432
Pl ease r ead t he i nst r uct i ons car ef ul l y. You ar e al l ot t ed 5 mi nut es
speci f i cal l y f or t hi s pur pose.
You ar e not al l owed t o l eave t he Exami nat i on Hal l bef or e t he end of
t he t est .

INSTRUCTIONS

A. General Instructions

1. Attempt ALL the questions. Answers have to be marked on the OMR sheets.
2. This question paper contains Three Parts.
3. Part-I is Physics, Part-II is Chemistry and Part-III is Mathematics.
4. Each part has only one section: Section-A.
5. Rough spaces are provided for rough work inside the question paper. No additional sheets will be
provided for rough work.
6. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic
devices, in any form, are not allowed.

B. Filling of OMR Sheet

1. Ensure matching of OMR sheet with the Question paper before you start marking your answers
on OMR sheet.
2. On the OMR sheet, darken the appropriate bubble with black pen for each character of your
Enrolment No. and write your Name, Test Centre and other details at the designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.

C. Marking Scheme For All Three Parts.

(i) Section-A (01 to 03 and 10 to 12) contains 6 multiple choice questions which have only one
correct answer. Each question carries +8 marks for correct answer and 2 mark for wrong
answer.

Section-A (04 to 09 and 13 to 30) contains 24 multiple choice questions which have only one
correct answer. Each question carries +4 marks for correct answer and 1 mark for wrong
answer.

Name of the Candidate

Enrolment No.

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AITS-CRT(Set-V)-PCM-JEE(Main)/13

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
2

Useful Data

PHYSICS
Acceleration due to gravity g = 10 m/s
2

Planck constant h = 6.6 10
34
J-s
Charge of electron e = 1.6 10
19
C
Mass of electron m
e
= 9.1 10
31
kg
Permittivity of free space
0
= 8.85 10
12
C
2
/N-m
2
Density of water
water
= 10
3
kg/m
3

Atmospheric pressure P
a
= 10
5
N/m
2

Gas constant R = 8.314 J K
1
mol
1
CHEMISTRY

Gas Constant R = 8.314 J K
1
mol
1

= 0.0821 Lit atm K
1
mol
1

= 1.987 2 Cal K
1
mol
1

Avogadro's Number N
a
= 6.023 10
23

Plancks constant h = 6.625 10
34
Js
= 6.625 10
27
ergs
1 Faraday = 96500 coulomb
1 calorie = 4.2 joule
1 amu = 1.66 10
27
kg
1 eV = 1.6 10
19
J

Atomic No: H=1, He = 2, Li=3, Be=4, B=5, C=6, N=7, O=8,
N=9, Na=11, Mg=12, Si=14, Al=13, P=15, S=16,
Cl=17, Ar=18, K =19, Ca=20, Cr=24, Mn=25,
Fe=26, Co=27, Ni=28, Cu = 29, Zn=30, As=33,
Br=35, Ag=47, Sn=50, I=53, Xe=54, Ba=56,
Pb=82, U=92.
Atomic masses: H=1, He=4, Li=7, Be=9, B=11, C=12, N=14, O=16,
F=19, Na=23, Mg=24, Al = 27, Si=28, P=31, S=32,
Cl=35.5, K=39, Ca=40, Cr=52, Mn=55, Fe=56, Co=59,
Ni=58.7, Cu=63.5, Zn=65.4, As=75, Br=80, Ag=108,
Sn=118.7, I=127, Xe=131, Ba=137, Pb=207, U=238.


3
P Ph hy ys si ic cs s PART I

SECTION A
Single Correct Choice Type

This section contains 30 multiple choice questions. Each question has four choices (A), (B), (C) and (D)
out of which ONLY ONE is correct.

1. A block of metal weighing 2 kg is resting on a frictionless plane. It is
struck by a jet releasing water at a rate of 1 kg/s and at a speed of 5
m/s. The initial acceleration of the block is
Block
2kg
(A)
5
3
m/s
2
(B)
25
4
m/s
2

(C)
25
8
m/s
2
(D)
5
2
m/s
2

2. A body is fired from point P and strikes at Q inside a smooth
circular wall as shown in the figure. It rebounds to point S
(diametrically opposite to P). The coefficient of restitution will be
(A) cot (B) 1
(C) tan (D) tan
2

P

Q
S

3. A wedge of mass M resting on a horizontal frictionless surface is
given a force F in the horizontal direction. The net horizontal force
acting on the shaded portion of the wedge is
(A) F (B)
3
F

(C)

6
F
(D) zero
h
3
h
3
h
F
h

Rough work

4

4. Conductor ABC which consist of two rigid quarter circular wires of radius
R, lies in X-Y plane and carries current I as shown. A uniform magnetic
field B
G
is switched on in the region that exert force F
G
= 2 IRB
0
k
on
conductor ABC. B
G
can be
(A) ) i
(
B
2
0
(B) j
B
2
0

(C) ) j
(
2
B
0
+ (D) both (B) and (C)
O
Y
C
R
R
B
R
X
I
I
A
R

5. In the fusion reaction
2 2 3 1
1 1 2 0
H H He n, + + the masses of deuteron, helium and neutron
expressed in amu are 2.015, 3.017 and 1.009 respectively. If 1 kg of deuterium undergoes
complete fusion, find the amount of total energy release (D) 1 amu = 931.5 MeV/c
2

(A)
13
6.02 10 J (B)
13
5.6 10 J
(C)
13
9.0 10 J (D)
13
0.9 10 J

6. The compound unstable nucleus
236
92
U often decays in accordance with the following reaction

236 140 94
92 54 38
U Xe Sr + + other particles
In the nuclear reaction presented above, the other particles might be
(A) an alpha particle, which consists of two protons and two neutrons
(B) two protons
(C) one proton and one neutron
(D) two neutrons

7. A point object is placed at a distance of 1000 mm from a concave mirror of focal length
400 mm. If the object is moved towards the mirror by 200 mm, the image moves by a distance of
(A) 133.3 mm towards mirror (B) 133.3 mm away from the mirror
(C) 30 mm towards mirror (D) 30 mm away from the mirror
Rough work

5

8. If an object is placed 20 cm in front of a half thin convex lens of
focal length 10 cm, as shown in figure, then co-ordinate of image
taking object position as origin
20cm
2mm
0
y
x
(A) [20 cm, 0.2 cm] (B) [40 cm, 0.4 cm]
(C) [40 cm, 0.2 cm] (D) [20 cm, 0.4 cm]

9. When an elastic material with Youngs modulus Y subjected to a stretching stress X, the elastic
energy stored per unit volume of the material is
(A)
2X
Y
(B)
2
Y
2X

(C)
2
X Y
2
(D)
2
X
2Y

10. From a disc of mass 2 kg and radius 4m a small disc of radius 1 m
with center O' is extracted. The new moment of inertia. about an axis
passing through O perpendicular to plane of disc is
(A) 16 kg m
2
(B) 12 kg m
2

(C)
2
255
kg m
16
(D)
2
247
kg m
16

O
O
4m
2m

11. A wire frame AOPQB, lying in the horizontal plane, is free to rotate about a
vertical axis passing through center C of the same circle and to plane of
AOPQB. The mass M of the frame is uniformly distributed over its whole
length. The moment of inertia of the frame about this axis, is (OA = QB = r
and CP = r the radius of semicircular part)
(A)
2
14 3
Mr
3 6
+ | |
|
+
\ .
(B)
2
r
Mr
2r
+ | |
|
+
\ .

(C)
2
3
Mr
4
| |
|
\ .
(D)
2
1
Mr
2

O
A
P
B
Q
r
C
r
r

Rough work

6

12. A block of mass m is suspended from a spring. Its frequency of oscillation is f .
The spring is cut into two identical halves and the same block is suspended from
one of the two pieces of the spring, such that it just touches the other spring
below in its equilibrium position. The frequency of small oscillations of the mass
will be
(A) f (B) 2f
(C) 2f (D) 2(2f 2f )
m

13. The angle between the directions of the particle velocity and the wave velocity, in a transverse
wave, is
(A)
4
(B) zero
(C)
2
(D)
2
.

14. A block of 1 kg is kept on a rough surface of an elevator moving up with
constant velocity of 5 m/s. In 10 second work done by normal reaction
(no sliding on incline surface)
(i) from ground frame is 320 J
(ii) is equal to work done by friction force in elevator frame
(iii) is equal to work done by friction in ground frame
correct answer is
1kg
37
5m/s
(A) (i) (B) (ii), (iii)
(C) (i), (ii) (D) only (iii).

15. Average power delivered by an AC source when a resistor of resistance R, an inductor of
inductance L and a capacitor of capacitance C are connected in series is (choose the most
appropriate option)
(A) minimum when the frequency of the source is
1
2
1
LC
.
(B) maximum when the frequency of the source is
1
2
1
LC
.
(C) zero when there is no resistor in the circuit.
(D) both (B) & (C)
Rough work

7

16. A uniform rod AB of length 1 m is placed at edge of a smooth table as
shown in figure. It is hit horizontally at point B from left. If the magnitude
of the displacement of the centre of mass in 1 s is 5 2 m, the angular
speed of rod is
(A) 30 rad/s (B) 20 rad/s
(C) 10 rad/s (D) 5 rad/s
B
Table
A
17. Four resistors are connected in a square formation. Two
batteries of emf, E and 2E are connected along the diagonals
as shown in the figure. The current flowing in the resistor (R
1
)
is (R
1
= R)
(A)
4
3
E
R
(B)
E
R

(C)
3
2
E
R
(D)
3E
R

R
R
R R
1
2E
E

18. The rate at which heat is dissipated in the 1.5 resistance in the previous question is given by
(A) 37.5 W (B) (37.5 W) . e
-t/2
, where t is the time in S
(C) (37.5 W) e
-t
, where t is time in S (D) (50 W) e
-t/2
, where t is the time in S

19. An electric dipole with dipole moment

p (3i 4j) = +
G
C-m, is kept in electric field
E 0.4kN/ Ci =
G
.
What is the torque acting on it & the potential energy of the dipole ?
(A)
1600(N m)k, 1200J (B)
1600(N m)k, 1200J

(C)
1600(N m)k, 1200J (D)
1600(N m)k, 1200J

20. In the arrangement of a pair of parallel plates having separation 1 cm as
shown. What is electric field in the region between the plates ?
(A) 15 kN/C towards right (B) 15 kN/C towards left
(C) 25 kN/C towards right (D) 25 kN/C towards left
1cm
-50V
+200V
Rough work

8

21. In the figure ab and cd are two long conducting wires kept
parallel to each other at a separation A in a uniform time
varying magnetic field. The ends a and c are connected
together by a resistor of resistance R. The magnetic
induction B perpendicular to the plane of the wires varies
with time according to the relation B = B
0
t, where B
0
is a
positive constant with proper unit and t is the time in
second. A conducting wire PQ placed on the wires ab and
cd and dragged on the wire with constant speed. v along
R
F
a b
c d
P
Q

the length of the wires by applying a constant force F. Find the value of F in terms of the other
given parameters. At time t = 0, PQ is very close to ac. Ignore any resistance (electrical as well
as mechanical) other than R.
(A)
2 2 2
0
B vt
R
A
(B)
2 2 2
0
2B vt
R
A

(C)
2 2 2
0
4B vt
R
A
(D)
2 2 2
0
8B vt
R
A
.

22. A small air bubble of radius r is found to form at a depth of H from the open surface of the liquid
contained in a beaker. If S is the surface tension and , the density of the liquid and p
o
, the
atmospheric pressure the pressure inside the bubble is
(A)
4S
r
+ gH + p
o
(B)
2S
r
gH + p
o

(C)
4S
r
gH + p
o
(D)
2S
r
+ gH + p
o

23. Three identical spheres having mass M and radius R each are kept in contact at
rest as shown in figure. On a frictionless horizontal plane. The net force acting
on any one sphere is
(A)
2
2
GM
R
(B)
2
2
GM
3
4R

(C)
2
2
GM
2R
(D) zero.
(where G is universal gravitational constant)
Rough work


9
24. Two adiabatic vessels, each containing the same mass m of water but at different temperatures,
are connected by a rod of length L, crosssection A, and thermal conductivity K. the ends of the
rod are inserted into the vessels, while the rest of the rod is insulated so that there is negligible
loss of heat into the atmosphere. The specific heat capacity of water is s, while that of the rod is
negligible.
The temperature difference between the two vessels reduces to
1
e
of its original value after a
time, t. The thermal conductivity (K) of the rod may be expressed by
(A)
msL
A t
(B)
emsL
A t

(C)
msL
2eA t
(D)
msL
2A t
.

25. The heat (Q) supplied to a solid, which is otherwise thermally isolated from its surroundings, is
plotted as a function of its absolute temperature, . It is found that they are related by the
equation,
Q = a
2
+ b
4
. (a, b are constants).
The heat capacity of the solid is given by
(A)
3 5
a b
3 5

+ (B)
3
a b +
(C)
3
a b
3 5

+ (D) 2a + 4b
3
.

26. The K.E. (K) of a particle moving along a circle of radius R depends on the distance covered
s as
2
= K as . The force acting on particle is
(A)
2
2as
R
(B)
1/ 2
2
2
1
| |
+
|
\ .
as
s
R

(C)
1/ 2
2
2
2 1
| |
+
|
\ .
s
as
R
(D) none of these.
Rough work


10
27. Two particles are simultaneously projected with the same speed in the same vertical plane, but
perpendicular to each other, in a uniform gravitational field. Their times of flight are
1
T ,
2
T while
the horizontal ranges are
1
R ,
2
R . Then (choose one option)
(A)
1 2
R R = (B)
1 2 1 2
R R gTT + =
(C)
1 2
1 2
R R
T T
= (D) both (A) and (B) are true

28. A block of mass
3
10
kg is placed on a rough horizontal surface as
shown in the figure. A force of 1 N is applied at on end of the block
and the block remains stationary. The normal force exerted by the
surface on the block acts (g = 10 m/s
2
)
(A) through the centre of mass of the block.

(B) through point A.

(C) through point B.

(D) through the point at a distance 5 cm. from A.
30
F = 1N
2
0

c
m
20 cm
B A

29. A uniform conducting rectangular loop of sides A , b and mass
m carrying current i is hanging horizontally with the help of two
vertical strings. There exists a uniform horizontal magnetic
field B which is parallel to the longer side of loop. The value of
tension which is least is
(A)
mg Bb
2
(B)
mg Bb
2
+

b
B
A
(C)
mg 2iBb
2
(D)
mg 2Bb
2
+
.

30. The mean lives of a radio-active substances are 1620 years and 405 years for -emission and -
emission respectively. Find out the time during which three fourth of a sample will decay if it is
decaying both by -emission and -emission simultaneously
(A) 324 years (B) 449 years
(C) 480 years (D) 425 years
Rough work


11
C Ch he em mi is st tr ry y PART II

Straight Objective Type

This section contains 30 multiple choice questions numbered 1 to 30. Each question has 4 choices (A),
(B), (C) and (D), out of which ONLY ONE is correct.

1. In an atomic BCC, what fraction of edge is not covered by atoms:
(A) 0.144 (B) 0.130
(C) 0.279 (D) 0.134

2. A complex [CoA
6
]
3+
red coloured while [CoB
6
]
3+
is green coloured, which of the following is correct
statement?
(A) Ligand A is producing larger crystal field splitting
(B) [CoB
6
]
3+
is easily oxidized
(C) Both are equally oxidized
(D) Ligand and B is producing larger crystal field splitting

3. A solution of H
2
O
2
labelled as 20 V was left open. Due to this, some H
2
O
2
decomposed and
volume strength of the solution decreased. To determined the new volume strength of the H
2
O
2

solution, 10 ml of the solution was taken and it was diluted to 100 ml. 10 ml of this diluted solution
required 25 ml of 0.0245 M KMnO
4
solution for titration under acidic condition. Calculate the new
volume strength of H
2
O
2
solution?
(A) 17.15 V (B) 18.4 V
(C) 19.4 V (D) 16.5 V

4. A white crystalline substance dissolves in water. On passing H
2
S in this solution, a black
precipitate is obtained. The black ppt. dissolves completely in hot HNO
3
. On adding a few drops
of concentrated H
2
SO
4
, a white precipitate is obtained which is soluble in ammonium acetate. The
white precipitate is that of:
(A) BaSO
4
(B) SrSO
4

(C) PbSO
4
(D) Ag
2
SO
4

5. When 1 mole of A (g) is introduced in a closed 1 L vessel maintained at constant temperature.
The following equilibria are established:
( ) ( ) ( )
1
c
A g B g 2C g ; K ? + =
ZZZX
YZZZ

( ) ( ) ( )
2
c
C g 2D g 3B g ; K ? + =
ZZZX
YZZZ

The pressure at equilibrium is
13
6
| |
|
\ .
times the initial pressure.
Calculate
1 2
c c
K &K if
| |
| |
eq.
eq.
C
4
A 9
=
.
(A) 0.14 and 0.14 (B) 0.28 and 0.18
(C) 0.19 and 0.16 (D) 0.11 and 0.14
Rough Work


12
6. For the reaction, ( ) ( )
2 4 2
N O g 2NO g ,
ZZZX
YZZZ
if percentage dissociation of N
2
O
4
are 20%, 45%, 65%
and 80% then the sequence of observed densities at given extent of dissociation are:
(A) (d
20
= d
45
) > (d
65
= d
80
) (B) d
80
> d
65
> d
45
> d
20

(C) d
20
> d
45
> d
65
> d
80
(D) d
20
= d
45
= d
65
= d
80

7. One mole of naphthalene was burnt in oxygen gas at constant volume to give carbondioxide gas
and liquid water at 25
o
C. The heat evolved was found to be 5138.8 kJ. Calculate the enthalpy of
reaction at constant pressure:
(A) - 5143.8 kJ (B) +6538.3 kJ
(C) - 4148 kJ (D) - 3398 kJ

8. For the set of reactions:
(i)
1
1
K
K
A B C
+
ZZZXZ
YZZZZ
(ii)
2
K
C B D +

| || | | | | || |
1 1 2
K A B K C K C B
is equal to:
(A)
| | d A
dt
(B)
| | d B
dt

(C)
| | d C
dt
(D)
| | d D
dt

9.
( ) +
2 4
1. H SO
2 2. conc.HCl 2
CH OEt Product.
OH
NO
2

(A)
Cl
OH
NO
2

(B)
CH
2
Cl
OH
NO
2

(C)
CH
2
Cl
NO
2

(D)
OH
CH
2
Cl

Rough Work


13

10.
C
H
O
OMe
2
KCN,EtOH
H O
Product is:

(A)
C HC
O OH
OMe
MeO
(B)
C HC
O OH
MeO

(C)
C HC
O OH
OMe

(D)
C HC
O OH
OMe
OMe

11.
( )
3 2
CH CO O
H
X Y
+

O
O
Li
X and Y are:
(A)
| | X
O
O
;
O
OCOCH
3
| | Y
(B)
| | X
O
OH
;
O
OCOCH
3
| | Y
(C)
| | X
O
O
;
O
OCH
3
O
| | Y
(D)
| | X
O
OH
;
O
OCOCH
3
| | Y

Rough Work


14
12. For the cell:
Pt | H
2
(g) | sol X || KCl (saturated)| Hg
2
Cl
2
(s) | Hg|Pt
The observed emf at 25
o
C was 612 mV. When solution X was replaced by a standard phosphate
buffer whose assigned pH is 6.86, the emf was 741 mV. Find pH of the solution X.
(A) 4.68 (B) 5.13
(C) 6.12 (D) 4.24

13. The pK
a
of acetylsalicylic acid (aspirin) is 3.5. The pH of gastric juice in human stomach is about
2 3 and the pH in the small instestine is about 8. Aspirin will be:
(A) Unionised in the small intestine and the stomach
(B) Completely ionized in the small intestine and in the stomach
(C) Ionised in the stomach and almost unionized in the small intestine
(D) Ionised in the small intestine and almost unionized in the stomach

14. Calculate wavelength of He atom whose speed is equal to the r.m.s. at 20
o
C?
(A) 7.64 10
-12
m (B) 5.28 10
-11
m
(C) 7.38 10
-11
m (D) 2.28 10
-10
m

15. Which one of the following ylides will be most stable and least reactive for nucleophilic addition
reaction with aldehyde or ketones?
(A)
( )
( ) ( )
6 5 3
3
C H P CH
+
(B)
( )
( ) ( )
6 5 3
3
C H P CH CH
+

(C)
( ) ( )
3 2 3
Ph P CH CH CH
+
(D)
( ) ( )
3 2 5
Ph P CH COOC H
+

16. In the Perkin reaction which one of the following intermediates gives compound (I):

H
5
C
6
CH CH C O C CH
3
O
O
(I)

(A)
H
5
C
6
CH CH
2
C O C CH
3
O
O
O

(B)
H
5
C
6
HC
CH
2
O C
O
CH
3
COO

(C)
H
5
C
6
HC
CH
2
O C
O
CH
2
COOH
(D)
H
5
C
6
HC
CH
2
O COCH
3
C
O
O C
O
CH
3

Rough Work


15
17. When the deuterium labeled compound (I) is subjected to dehydrohalogenation:

H
Br
C H
3
D
H H
2 5
C H O Na
X
+

The only product X is:
(A) Methylcyclohexene (B) 3-Methylcyclohexene
(C) Cycloheptene (D) 2-Methylcyclohexene

18. Which of the following is/are non-reducing sugars?
(A) Fructose (B) Glucose
(C) Sucrose (D) Lactose

19. Which of the following statement is not true?
(A) O-F bond length in OF
2
is less than O-F bond length in O
2
F
2
.
(B) In
3
HCO
, all C O bond length are not identical.

(C) In diborane, two different B H bond lengths are observed although the hybridization of both
boron atoms are same.
(D) In hydrazine, the N N bond length is larger than normal N N bond length.

20. How many stereoisomers are possible for the following molecule

H
C H
3
CH CH CHCOOH

(A) 2 (B) 3
(C) 4 (D) 6

21. The vapour pressure of water at 20
o
C is 17.54 mm Hg. What will be the vapour pressure of the
water, in the apparatus shown after the piston is lowered, decreasing the volume of the gas
above the liquid to one half of its initial volume (assume T constant):

(A) 8.77 mm Hg
(B) 17.54 mm Hg
(C) 35.08 mm Hg
(D) Between 8.77 and 17.54 mm Hg.
Water
vapour
Liquid
water

Rough Work


16
22. Which one of the following is most stable?

(A)
H
H H
H
H Br
NH
2

(B)
H
H H
H
H Br
NH
2
(C)
H
H H
H
H
Br
NH
2

(D)
H
H H
H
NH
2
Br
H

23. The acid strength order is:

I I
COOH
(a)
I
COOH
I
(b)
COOH
I
I
(c)
COOH
I
I
(d)

(A) (a) > (b) > (c) > (d) (B) (a) > (c) > (b) > (d)
(C) (a) > (b) > (d) > (c) (D) (b) > (a) > (d) > (c)

24. In a space shuttle, the CO
2
output per astronaut has been estimated as 44 g per hour. An
experimental catalytic converter reduces CO
2
at a rate of 600 mL (STP) per min into H
2
O. What
fraction of the time would such a converter have to operate in order to keep up the CO
2
output of
one astronaut?
(A) 0.622 (B) 0.782
(C) 0.382 (D) 0.411

25. The correct statements are:
The planar shape of N(SiH
3
)
3
is explained by the
1. Type of hybrid orbitals of nitrogen.
2. Additional p d overlap along the N-Si bond.
3. Higher electronegativity of nitrogen.
(A) 1, 2, and 3 (B) 1 and 2
(C) 2 and 3 (D) 1 and 3

26. The compound (X) obtained in the following reaction is most likely to be:

( )
( )
3
Li/NH
X
A

(A)

(B)

(C)

(D)
CH

Rough Work


17
27. In the acid catalysed dehydration of
OH
the product(s) formed is/are:

CH
2
(I)
CH
3
(II)
(III)
CH
3
(IV)

(A) I and IV (B) II and IV
(C) III and IV (D) I, II and III

28.
C
CH
3
O
Ph
O
( )
( )
4
a NaIO
b H ,
Product is:
+

(A)
O

(B)
O
HOOC
Ph

(C)
O
COOH

(D)
Ph
COOH
OH

29. Consider the following statement:
S
1
: Fluorine does not form any polyhalide as it has low F F bond energy.
S
2
: The chlorine has the most negative electron gain enthalpy.
S
3
: The first ionization potential of N is greater than O.
Which of the above statements are correct?
(A) S
1
, S
2
and S
3
(B) S
1
and S
2

(C) S
1
and S
3
(D) S
2
and S
3

30. ( )
2
4
MnO 1mole
in neutral aqueous medium, disproportionates to:

(A)
2
3
mole of
4
MnO
and
1
3
mole of MnO
2
(B)
1
3
mole of
4
MnO
and
2
3
mole of MnO
2

(C)
1
3
mole of Mn
2
O
7
and
1
3
mole of MnO
2
(D)
2
3
mole of Mn
2
O
7
and
1
3
mole of MnO
2
Rough Work


18

M Ma at th he em ma at ti ic cs s PART III

SECTION A

Straight Objective Type

This section contains 30 multiple choice questions numbered 1 to 30. Each question has 4 choices (A),
(B), (C) and (D), out of which ONLY ONE is correct.

1. The curve y =
2
ax bx + has minimum at (2, 12) then the values of a, b are
(A) 3, 12 (B) 3, 12
(C) 3, 12 (D) 3, 12

2. The point on the curve
2
y x 4x 3 = + + which is nearest from the line y = 3x + 2 is
(A)
1 5
,
2 4
| |
|
\ .
(B)
1 5
,
2 4
| |
|
\ .

(C)
5
2,
3
| |
|
\ .
(D)
5
2,
3
| |
|
\ .

3. The sides of the greatest rectangle that can be inscribed in the ellipse
2 2
2 2
x y
1
a b
+ = are
(A) a 2 , b 2 (B) a , b
(C) a, b (D)
a b
,
2 2

4. The maximum area of the triangle with vertices at (a, 0), (a cos , b sin ) and (a cos , b sin )
is
(A)
3 3 ab
4
(B) 3 ab
(C)
3ab
4
(D) 3 3ab
Rough work


19
5. If the perimeter of a sector of a circle is 16 cms then its maximum area is
(A) 16 sq. cms (B) 32 sq. cms
(C) 48 sq. cms (D) 64 sq. cms

6. The shortest distance of the point (0, c) from the curve
2
y x = , where c
1
2
is
(A) c 4 (B)
1
c
4

(C) 4c 1 (D) c 1

7. The function ( )
sinx
f x
x
= is
(A) increasing in 0,
2
| |
|
\ .
(B) decreasing in 0,
2
| |
|
\ .

(C) stationary at x = /2 (D) both increasing and decreasing at x = /2

8. If
x
y x tan
2
= , then
dy
dx
is equal to
(A)
1 sinx
cos x
+
(B)
x cosx
sinx
+

(C)
x sinx
1 cosx
+
+
(D)
1 cosx
x sinx
+
+

9. If f is a differentiable function with ( ) f 1 8 = , ( )
1
f 1
8
= . If f is invertible and
1
g f

= , then
(A) ( ) g 1 8 = (B) ( )
1
g 1
8
=
(C) ( ) g 8 8 = (D) ( )
1
g 8
8
=
Rough work


20
10. Let ( )
x
f x
1 x tanx
=
+
, then ( ) f x has
(A) one point of minima in 0,
2
| |
|
\ .
(B) one point of maxima in 0,
2
| |
|
\ .

(C) no critical point in 0,
2
| |
|
\ .
(D) exactly one critical point in ,
2 2
| |
|
\ .

11. The critical points of ( ) ( ) ( )
2/ 3
f x x 2 2x 1 = + is(are)
(A) 1 only (B) 1, 2
(C) 2 only (D) 0, 1, 2

12. The height of the right circular cylinder of maximum volume that can be inscribed in a sphere of
radius a is
(A)
a
3
(B)
2a
3

(C)
2
a
(D) a 2

13. The stationary point of
2
250
y x
x
= + is
(A) (1, 51) (B) (5, 1)
(C) (5, 25) (D) (5, 75)

14. The function ( )
2
f x 2x 4x 1 = + in the interval
9
3,
2
(
(

has minimum value
(A) 1 (B) 7
(C) 1 (D) 17

15. The turning points of ( )
1 1
f x sinx sin2x sin3x
2 3
= + + in (0, ) are at
(A) x = /4 only (B) x = /4, /3
(C) x = /4, 2/3 only (D) x = /4, 2/3, 3/4
Rough work


21
16. If a > b, then the maximum and minimum values of
2 2
asin x bcos x + is
(A) a, b (B) b, a
(C)
2 2
a b + ,
2 2
a b + (D) ab , ab

17. The greatest value of ( )
2
2
2
f x 2x
x
= + , for | ) ( | x 2,0 0,2 and ( ) f 0 1 = is
(A)
17
2
(B) 1
(C) 0 (D)
11
2

18. If x and y are strictly positive such that x + y = 1, then the minimum value of x log x + y log y is
(A) log 2 (B) log 2
(C) 2 log 2 (D) 0

19. The minimum value of E(x, y) = cos x + cos y + 2 cos (x + y) where x, y R is equal to
(A)
9
2
(B)
9
4

(C)
3
2
(D)
3
4

20. If A, B, C are interior angles of triangle ABC such that
(cos A + cos B + cos C)
2
+ (sin A + sin B + sin C)
2
= 9 then number of possible triangle is
(A) 0 (B) 1
(C) 3 (D) infinite

21. Let a, b, c R and 1 be a root of the equation ax
2
+ bx + c = 0, then the equation
4ax
2
+ 3bx + 2c = 0 has
(A) imaginary roots (B) real and equal roots
(C) real and unequal roots (D) rational roots
Rough work


22
22. Sandra is writing her Christmas list. If she writes n items in her list, the probability of getting each
item is
1
2n
for example if she writes 3 items, she will get each item with a probability of
1
6
. If
Sandra write infinitely many gifts on her list then the probability of her getting no gifts, is
(A) e
1
(B)
1
2e

(C)
1/ 2
e
(D)
1
2

23. If the roots of cubic equation x
3
6x
2
+
1
x
2
= 0 are in A.P. with positive integral common
difference, them the maximum value of (
1
+
2
), is
(A) 17 (B) 18
(C) 19 (D) 20

24. Let
1
and
2
he two real values of for which the numbers 2
2
,
4
, 24 taken in that order from
an arithmetic progression if
1
and
2
are two real values of for which the numbers 1,
2
, 6
2

taken in that order form a geometric progression, then the value of ( )
2 2 2 2
1 2 1 2
+ + + is equal to
(A) 10 (B) 11
(C) 12 (D) 13

25. Let f(x) = x
2
+ ax + b cos x, a being an integer and b is a real number. Find the number of ordered
pairs (a, b) for which the equations f(x) = 0 and f(f(x)) 0 have the same (nonempty) set of real
roots
(A) 1 (B) 2
(C) 3 (D) 4

26. Number of integral values of a for which every solution of the inequality x
2
+ 1 > 0 is also the
solution of the inequality (a 1)x
2
(a + |a 1| + 2)x + 1 0, is
(A) 0 (B) 1
(C) 2 (D) 3
Rough work


23
27. The expression ( ) ( ) ( ) ( ) ( ) ( )
2 2 2 2 2 2
10 10 10 10 10 10
0 1 2 8 9 10
C C C .......... C C C + + + is equal to
(A) 0 (B) ( )
2
10
5
C
(C)
10
5
C (D)
9
5
2 C

28. If C
0
, C
1
, .., C
2012
are binomial coefficients in the expansion of (1 + x)
2012
and a
0
, a
1
, .., a
2012

are real numbers in arithmetic progression then value of a
0
C
0
a
1
C
1
+ a
2
C
2
a
3
C
3
+ .. +
a
2012
C
2012
, is
(A) 1 (B) 2012
(C) 1 (D) 0

29. If
3
tan9
4
= (where 0 < <
18
) then the value of (3 cosec 3 4 sec 3) is equal to

(A) 3 (B) 4
(C) 5 (D) 10

30. Let n be the number of ordered quadruples (x
1
, x
2
, x
3
, x
4
) of positive odd integers that satisfy
4
i
i 1
x 98
=
=
, then the value of

n
100
is equal to
(A) 144 (B) 169
(C) 196 (D) 225
Rough work

FIITJEE Concept Recapitulation Test (Set - V) - PCM-JEE(Main)/13

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1600(N m)k, 1200J (B)

1600(N m)k, 1200J

1600(N m)k, 1200J (D)

1600(N m)k, 1200J

, all C O bond length are not identical.

in neutral aqueous medium, disproportionates to:

) then the value of (3 cosec 3 4 sec 3) is equal to

, then the value of

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