'/

,rt'

A+
cAI
MS 200s AY2009 52

Name: t,oqy

hT /"ty T2-

(ruesotol)
z'66>Ev,.4 * , -3111

AIISWER ALL 14 QUESTIONS appendix is on page 4

l.

What is the absolute uncertainty in 15.34 (+/- 0.07) + 10.80 (+/- 0.04)? (3 marks)

t5.sj (t/-o.ut) + 19.EO (r1- o.orr)

33

,'+r.

,L

(#l'nGffi'

sg= ts'lv x
[s

(tl-

o.CIt)

to

o.ooG

An-indicator with pKa 4.1 is best used for which type of titration: ;zfsnongacid - weak base b) strong acid - strong base c) weak acid - strong base d) weak acid - weak base

t/

3.

1s- , r'5 What volume of 0.05 M NaOH is required to neutralise 35 mL of 0.1 M NazHPO+
t.

solution? 35..tLxo.tM

V
4.

a o.osrrtxvr r} = 35nrL
25%o

40.^^U

ffi#ffi#;Jffi;;;;:i"i';h,i;#;F;;:& V.
What will be the potential when
E0r.3*rFrr*

of the equivalence volume of 0.1 M

Cea*

:0.767 V.

E=o:,6'r"F.(Hl)

E0c"avc"t+

1.7

(3 marks)

vo,arccq{

u'J Gtr.r G*t ' J1r( *rl e g-r,rJ-rrrl I ' *\ * e*..-rs tr\t = o.r = ,,,,.-. . o.oos I $L,, ,r,-t.+ c.e = o-oos o o.o>S I
,.^a

9"}r

:o.,"s/

o-r*

| *,fr-}.;*r,*ifu

^) 'll,-

-.&
t"
*

5.

UV absorption bands result from which typek/ansitions?

tft .^."E tn",r."1 ^, A

:ffir--1,*+.*\"\
2Lc

6.

If a I.23 x

lO's M solution in a I cm cell shows 29%o transmittance at254 nm, calculate the molar absorptivity (units are L/mol cm)? (3 marks)

, > - $ ?li : t-tT7''t

/= &ht
I = 4r-t+ ).;J.rl ,,*(;
( t'zcxro-r)1 1.,'.,

6'

') /

>t

7.

How many signals do you expect to see in the co*no-urds? ,,.. ;_\
.;1"

t3C

4 g"l'T5,

NN{R spectra for the following (3 marks)

t!

ll-,3E l
{c)

b 3.r h5.
g.

\, )

What happens to the height of a theoretical plate as the velocity of the mobile phase is increased? $ &c'urclrJ 'flr,rrr. i*.ar-.r*q"r ro ./ Rc-dr^cA * rt What is a contact angle?

9.

i\/ -{--<,'

Ll

(2 marks)

\J,

tt8t\u

a$C

r"'\r'ictn.

tF+*l r\art+rf TF a ,lurfece

t^'r-* usg\ er nol I !e,^\ h^s.d^ 1\* q'AaJ vlrr., *ll[ Ia rrV.+r a Srt\36n11 pll o^{e aniwr (3*,

.rfiil\rqo.

'.*a)

10.
11.

An increase in co4tact angle means the height a liquid rises in a capillary will: d) cannot tell a) increase ufi d""rease c) remain the same

If a plot of surface tension against the natural logarithm of the concentration of a

surfactant at25 "C is linear with a slope of -13.26 mN/m, what is the average area (3 marks) of the surfactant at the surface in square AngsEoms?

[ =-ti (-"-t-L*^nl9 = -1tiffi t-"'or3>6 \h)

s.3s<
^,o-6
12.

A\=
=

ffi
3' I O rlQ{
r'nr'

4rz-t

3roAi/

,i

Which of the following surfactants will have the highest Critical Micelle
Concenffatiop? a) CrzHzsPO+Nag

'

c)

C rzHzs(O

CllzCHz)zOH lou rAt

"diCrrHrrsoNa
s\

v6'"t

z'Pda'lu'

r^^iH trn",Jt 't

\

F, s"ito." fr '{
ioric )
1on' torrC

(V't "ao"tl

13.

For,a polarcompound being eluted through a polar stationary phase which of the following will increase the retention time? lncreasing thepolarity of the mobile r5 t b) Increasing the polarity of the stationary c) Increasiag dre vclocity of the mobile phase d) All of the above

,;f,

phase. phase. '

t4.

If ltrc u ewl#

c a slrface freshly cut under vacuum to air what happens to its surface

gt'r*'c.

t.ill

&c'..garq-

Cts.

-WE:<**

Appcudir

JR=

sl +s3+sZ

*=m
.=iq+)
=f--L-)' " (A/. +V" )
A = 2-lodToT)

A=ebc

H=4 l6t:
r\

tr,B'tr,A
--

2N,
wE+w^

0.5{w,

+*o)
fA

\,,1'

HLB mix =

X IILBAI + [(l-lA.) X

HLBBI H: L/N

a(m2lmorecure)=;-tiffi
E=Eo*RTo,

t=-#[#)
[=- 2vws0
prg
oH = ol(a+loq [A'] -tHA]

nF

[oxJ
[Red]

H=A

+ B/u+Cu

R=8.314JK'l msfr

F=96500Cmol'r

q/

...f.f

F-,
/'

cA2 MS 2003 AY2009 S2

Name: rCorc rANG Mrntcr

Ar\swER ALL

'i).

14 QUESTTONS There are 4 pages. The Appendix is on page 4

Questions are worth

I mark unless otherwise indicated

1.

Which ofthe following is true about chemical adsorption? Its entropy (AS) is negative It enthalpy (AlI) is usually greater than for physisorption i It may be reversible at high temperature.l All of above

a) b) c) d) a) b) c) d)

(d\

"/

2.

Which of the following is not true about physical adsorption? It has negative entroPY (AS). r It produces multilayers. It is reversible at high temperature. -r None ofthe above.

CA/
,r/

J.

Is a surfactant with a low HLB better for stabilizing o/w or w/o emulsions?

U{o cr^,.r,tlstqw9
4.

What mixtute of 2 surfactants with HLBs of 6.3 and 15.9 is needed to make a mixture with HLB of 9.5? Q.t. d.:Pq + ls-t - rs.t pr d) l:2 c) 1:l a)2:l r(\4rs

b)3:2

C4
5.

J/-o'BG fu,
N's (r1) + >c-

6'rp1

tt$

-q.r
I

{-t

CalculatethecellpotentialforthefollowingGalvaniccellat25"C:>
NilNiSO+ (aq,0.004M)llAgNOr (aq,0.02

M)lAg (3 marks)

N;fd->
AJ"C5)

N'Lt (^1)+

)f

eb = -b->5V

ie: + A,gcs) eo = to-?oV

s

-)

Pc.\

-Eort
f-D(v

[ -o->S v)

ft.

t-os

B.3l

C?AS)

>-'Q6S*e

)^1"-..--or1-

u-w\

(\/ *

l-ozV

/
I

)L

6.

Which way are the electrons flowing in the Galvanic cell CulCuSO+ (aq, I M)llNiSO4 (aq, I M)lNi? q^ g'?rJ V a) From left to right in the external circuit -o.>sr/ b) From right to left in the external circuit c) From left to right across the salt bridge G'oll -o'>sv d) From right to left across the salt bridge

Ni

ct) /

-o'3{y'

-o.s? of

7.

How much silver Mw Ag = 107.9 g/mol) will be deposited from a solution AgNOI in an electrolytic cell using a current of 35 A for 2.5 minutes. (3 marks)

b*oJe-'{o atao&

&--

tt = nz'F
:

= fizll'l nn, e( - if ?F-

tt

?5S

rSoS
e&4"1

t xq6f,co

x
/

lo7't

Sl*\

-8.

S.E1o

S ,/

How does Electroless plating differ from normal

9.

hJaJ ebd,,t&/aggro tY-:ra/.-l dkbqJ v-{o6fiD.. 16 ,leruv$e Why do batteries give a steady current whereas an ordinary Galvanic rrl6o-.rt"ttor*u not? ( 2 marks)

Frr{

electroplating? \ r^!es do at n-t 6rc{,^q[<-m e\G{$Acs.I 4\c (sl,lcCr t 4.C..^1, *4 T\ahS 'ac"n-^p.
[.,. r$tc*trJ r dl^. n*-adcA A

""tiu\ i\

.-sLrch ,^^rowb ,1[a4

f'e

:[,t

]ste;i 0 L=
E"

cov$r-a*

$''r"svrr
electrode?

't\t ""*-\tt*

"l

4Y^ l'1.
a-rr$*-f, #"--rtvP

1p[ra.rtg,

*[, tt^^

ocr^crg-ott

n 4 *^A",,q a\ y.^olrra B v.$

10. rrh't#'"?tft.:iirtl"?ffSa cen NilNisoa (aq, I M)ilcusoa (aq, lM)lcu at

25 "C is 0.1 V, what is the overpotential of the copper

L '"..ry'e.,*ut
ll.

marks)

Can nickel be obtained from electrolysis of aqueous solutions of its salts?

= )l ;.ltl
f*o"{

,/
_

( Go =-o'XV) >; - ni (s) I ( v) bX) -o'43 = )fizo *,>a- J ,{,- 5) + )^f A 'tt"\"+/e * n %"s'"' \\" :*t ptr*tt l + wtcbc\ Yt v'\ro\^\ fstlii{e r
gu

0vs/ $adudron Ni*,oX) ,t

-t adt'& a-.:rr{s"J '

(2 -r lH 'r ) -z H, (o V ) L fo s.w^a"rt
.

6o .odrlt1 .

Ni,:bc-( C'.* Az "bf^\\{d a) it-

Cs v\^o\a-

T*F"CI

.}o t'e Otelt^4J.

12.

Define the exchange current density for an electrode and describe how you can determine its value (3 marks)

f"U-6t-

ci.vrer,.4

*^1

\s'

?\"r L us t$t

.^-.rJ la. Ldtl^ "$ryd'c^AS 4-orcss

t\* r$a T* u'+ 4s^ c-\csilroc{a

(
Eo

AAtt\ "lt^^ah

re\acr|.nrJ

-n$oc

cl- elvGlLn.r*t

t tL' attt'6i)
6,.awe.r.f

fiowt y-i.,r"tovtet' I NC con obti.n

ry ::\,* + ;u1f /o, r\

It
.

arJ-

13.

Would coating iron with nickel protect it from corrosion? dmarks)

t4.

l*f-,ra . , Jt eoato6 1o q."dtse e*ot oorrrod*t. A c.*^g$a t.ooh.n1 r.ritl pcarbb a' ****. *rt& 6^ tcr.\b*.lv \vq4, *|\ia\4 sovr i*+l O O"+D" lvcvant \ +-\^ Ccdorisrl . F",*,ar., ..C... t\
Describe how electriciry is produced in a hydrogen-oxygen tuel? (3

l-n = -O-qqV <- cosrqr .!o s;irtasft"f) \).,' - Fots) ("+ Ni b) Nix r >f / : *o-z5N .l.r.orA taas o o^o\^e rnrprtrve go *rcl*c-r.r^t +{r.n ilcch.et -rU*{uru ,0

*;6 _ffi., i.il *l*

\
o+^^r^ .r.oescJ o^d

3*r ceo.gad

o,,.ct

$aJ
rr\l

.t\.-dt4

<.t<cS-tftc

tl

HptrX,n
h{ Aq

dFh^^'

atlrsoolcle r,4r\s H+ ,E*? I

elRo,hr$ I

XnF _,*-__.-.--.-.a.^o'{L

c-.,,{c

dr +Aa orrc&
ica3
\^}$1

n^ove tt^'-?t" 'tfu c,\,tch-\la fl/cr*

t"

&lt\^De{

6.roOl-a3

l^'\\

+h"\$r.r
)ro

d/-w1 ats& t"

eet\A"d.L

ertev"J *lrguiF l{{ to'r *}\

*t^r

$""Ut^ ^
cF c4t^vtr

oe'$"-fu

o6\,^^b.^{

*\+1. a\*a$r.otj

{. -$'*

"^!

0)-

H>O

S*$

Ar,.

a\Ater^^a,

c-l*c.,rlt *,\[

I.
L

H,

- \"*
t-4

L,i
slho4o

r---\<-

fr\--2
\
)r*l+
n 2,q-

l- o,

-)

H,0

APPeadir

HLB mix = [rA X HLBA] +

t(U{)

X HLBBI

E=Eo*RTtn

nF

[Ox]
tRed]

IILB = I|S(rxf/ohydrophilic goup)

R=8.314JK'r mol'r
E = Eo

F=965@Cmofr

-IlmO nF
l

Q=It=nzF
-$FnlRI)l }
q = a+ blogi

i=io {exp(-FFrtlR,T} - expK

AG: - nF4cn
Standard Reduction Potentials
Reaction

Ni"(aq)*2e +Ni(s)

2I*0 +2 + Hr(s) + 2Ot(a,q) Fe'*(ao)+2e-+Fe(s)

CV)

-0.83

-0.4
-0.25

Cu"(as) +2 + Cu(s) Ae"ftq)+ e +Ag(s) Oe(e) + 4Ff(as) + 4 +2H20

Reaction

E, (V) +0.34 +0.80 +1.23

sr

I j-

'i
I

,.r

'l