Beruflich Dokumente
Kultur Dokumente
TABLE OF FIGURES
FIG.NO
2.1 2.2 2.3 2.4 2.5 2.6 2.7 2.8 2.9 2.10 4.1 4.2 4.3 4.4 4.5 4.6 4.7 4.8 4.9 4.10 Seebeck arrangement Generation of electricity Peltier effect Thermocouple measuring circuit Block diagram Thermoelectric module Thermoelectric generator Principle of thermoelectric generator Schematic diagram of thermoelectric generator Basic inverter schematic Performance characteristics Wooden stove Heat sink and cooling system Module connection Battery Circuit diagram of inverter Pin configuration of IC3525 MOSFET MOSFET working Transformer
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DEPARTMENT of EEE
CHAPTER 1 INTRODUCTION
Electricity is no longer a luxury; it has become a necessity in our everyday lives. Have you ever imagined the life without electricity for an extended period of time? Every year thousands, even millions have been in this position when a winter storm knocked out power over large areas. Solar panels are a great alternative energy source, but they only produce electricity during daylight hours and their output is significantly reduced during winter months and cloudy days. Using a TEG can provide your homes energy needs and depending on what state you live in, you will begetting a check from the electric company instead off a bill in the future!!
A thermoelectric generator is a system that exploits the Seebeck effect to convert heat energy into electricity. Utilizing several semi-conductors in series, a thermoelectric module exploits a
difference in temperature to capture energy from thermally excited electrons. It is an attractive option for providing small amounts of electricity to homes in the developing world that are not connected to the power grid. Generally, households use biomass stoves for their
cooking needs. Such stoves can be equipped with a thermoelectric. Subsequently, the generator converts waste heat to electricity, providing a household with enough electricity.
The generator system consists of a thermoelectric module, a hot sink, and a cold sink. Heat from the stove is captured by the hot sink and transferred to the hot side of the thermoelectric module. The thermoelectric module converts a fraction of this heat energy into electricity. The remainder of the heat is rejected to the environment, by the cold sink. The electricity produced by the module flows to the load via two leads on the thermoelectric module. The ultimate aim of this project is to convert the waste heat into the useful electrical energy. The Existing wooden stove is modified into multifunctional wooden stove which can be used both for cooking and also for generating of the electricity.
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developing-world households that are not connected to the electrical grid. It is equipped with a hot sink located in the flue to collect heat, a thermoelectric module to generate electricity, and a cold sink with a cooling fan to reject heat to the environment. Three aspects of this
configuration were investigated: the correlation between temperature difference across the module and power output, the impact of the cooling fan on the thermal resistance of the cold
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Project Report 2013 sink, and the effect of matching load impedance to source impedance. Results confirmed the theoretical correlation, in which power output is approximately proportional to the square of temperature difference. The thermal resistance of the cold sink was determined Lastly, maximum power
was extracted from the thermoelectric module when the load and source impedances were equal. These results were used to optimize the stove configuration and it was experimentally
calculated that the stove will operate best with matched impedances and the cooling fan sub-maximally powered with 10.9V. These findings can be used to better design a power
generating cook stove. Additionally, the experimental procedure is repeatable for other cook stove prototypes.
progress made in development of thermoelectric materials having improved performance compared to state of the art materials. BSST has conducted a worldwide survey of
thermoelectric material development efforts, identifying and sampling the most promising developments. These materials were assessed by their assembly and incorporation in
demonstration power generation devices. Experimental methods were employed to assembly device components consisting of multiple types of thermoelectric material to optimize performance. Experimental generator designs were developed and employed to incorporate the thermoelectric components and provide a demonstration of the best possible performance that could be obtained from the materials selected. Bulk segmented materials were used in both nand p-legs of tested couples and prototype generators. A compact cylindrical TEG, comprised of an axial heat source (electrical heater in a demo device), radial segmented TE elements, and a cold side with air or water cooling was developed and used to demonstrate material performance. The inner volume of the device operated in an Argon atmosphere. The design was adaptable to a variety of practical heat sources.
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2.1 THERMOELECTRICITY
Thermoelectricity is a two-way process. It can refer either to the way a temperature difference between one side of a material and the other can produce electricity, or to the reverse: the way applying an electric current through a material can create a temperature difference between its two sides, which can be used to heat or cool things without combustion or moving parts. The fundamental problem in creating efficient thermoelectric materials is that they need to be good at conducting electricity, but not at conducting thermal energy. That way, one side can get hot while the other gets cold, instead of the material quickly equalizing the temperature. But in most materials, electrical and thermal conductivity go hand in hand. New nano-engineered materials provide a way around that, making it possible to fine-tune the thermal and electrical properties of the material.
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The voltages produced by Seebeck effect are small, usually only a few microvolts (millionths of a volt) per kelvin of temperature difference at the junction. If the temperature difference is large enough, some Seebeck-effect devices can produce a few millivolts (thousandths of a volt). Numerous such devices can be connected in series to increase the output voltage or in parallel to increase the maximum deliverable current. Large arrays of Seebeck-effect devices can provide useful, small-scale electrical power if a large temperature difference is maintained across the junctions. The Seebeck effect is responsible for the behavior of thermocouples, which are used to approximately measure temperature differences or to actuate electronic switches that can turn large systems on and off. This capability is employed in thermoelectric cooling technology. Commonly used thermocouple metal combinations include constantan/copper, constantan/iron, constantan/chromel and constantan/alumel.
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and
are the Seebeck coefficients of metals A and B as a function of temperature are the temperatures of the two junctions. The Seebeck coefficients are non-linear
as a function of temperature, and depend on the conductors' absolute temperature, material, and molecular structure. If the Seebeck coefficients are effectively constant for the measured temperature range, the above formula can be approximated as:
The Seebeck effect is caused by charge-carrier diffusion. Charge carriers in the materials will diffuse when one end of a conductor is at a different temperature from the other. Hot carriers diffuse from the hot end to the cold end, since there is a lower density of hot carriers at the cold end of the conductor, and vice versa. If the conductor were left to reach thermodynamic equilibrium, this process would result in heat being distributed evenly throughout the conductor. The movement of heat (in the form of hot charge carriers) from one end to the other is a heat current and an electric current as charge carriers are moving. In a system where both ends are kept at a constant temperature difference, there is a constant diffusion of carriers. If the rate of diffusion of hot and cold carriers in opposite directions is equal, there is no net change in charge. The diffusing charges are scattered by impurities, imperfections, and lattice vibrations or phonons. If the scattering is energy dependent, the hot and cold carriers will diffuse at different rates, creating a higher density of carriers at one end of the material and an electrostatic voltage.
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Fig2.2: Generation of electricity This electric field opposes the uneven scattering of carriers, and equilibrium is reached where the net number of carriers diffusing in one direction is canceled by the net number of carriers moving in the opposite direction. This means the thermo power of a material depends greatly on impurities, imperfections, and structural changes that vary with temperature and electric field; the thermo power of a material is a collection of many different effects. Early thermocouples were metallic, but many more recently developed thermoelectric devices are made from alternating p-type and n-type semiconductor elements connected by metallic connectors. Semiconductor junctions are common in power generation devices. Charge flows through the ntype element, crosses a metallic interconnect, and passes into the p-type element. When a heat source is provided, the thermoelectric device functions as a power generator. The heat source drives electrons in the n-type element toward the cooler region, creating a current through the circuit. Holes in the p-type element then flow in the direction of the current. Therefore, thermal energy is converted into electrical energy.
2.2.2PELTIER EFFECT
The Peltier effect is the presence of heat at an electrified junction of two different metals. The Peltier effect is a temperature difference created by applying a voltage between two electrodes connected to a sample of semiconductor material. This phenomenon can be useful when it is necessary to transfer heat from one medium to another on a small scale. In a Peltier-effect device, the electrodes are typically made of a metal with excellent electrical conductivity. The
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semiconductor material between the electrodes creates two junctions between dissimilar materials, which, in turn, creates a pair of thermocouple voltage is applied to the electrodes to force electrical current through the semiconductor, thermal energy flows in the direction of the charge carriers. Peltier effect, the cooling of one junction and the heating of the other when electric current is maintained in a circuit of material consisting of two dissimilar conductors; the effect is even stronger in circuits containing dissimilar semiconductors. In a circuit consisting of a battery joined by two pieces of copper wire to a length of bismuth wire, a temperature rise occurs at the junction where the current passes from copper to bismuth, and a temperature drop occurs at the junction where the current passes from bismuth to copper.
Fig 2.3: Peltier effect Peltier-effect devices are used for thermoelectric cooling in electronic equipment and computers when more conventional cooling methods are impractical.
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2.3THERMOELECTRIC GENERATOR
Thermoelectric generators (also called Seebeck generators) are devices which convert heat (temperature differences) directly into electrical energy, using a phenomenon called the "Seebeck effect" (or "thermoelectric effect"). Their typical efficiencies are around 5-8%. Older Seebeck-based devices used bimetallic junctions and were bulky while more recent devices use semiconductor p-n junctions made from bismuth telluride (Bi2Te3), lead telluride (PbTe),calcium manganese oxide, or combinations depending on temperature. These are solid state devices and unlike dynamos have no moving parts, with the occasional exception of a fan or pump.
2.3.1THERMOCOUPLES
A thermocouple consists of two conductors of different materials (usually metal alloys) that produce a voltage in the vicinity of the point where the two conductors are in contact. The voltage produced is dependent on, but not necessarily proportional to, the difference of temperature of the junction to other parts of those conductors. Thermocouples are a widely used type of temperature sensor for measurement and control and can also be used to convert a temperature gradient into electricity. Commercial thermocouples are inexpensive,
interchangeable, are supplied with standard connectors, and can measure a wide range of temperatures. In contrast to most other methods of temperature measurement, thermocouples are self powered and require no external form of excitation. The main limitation with thermocouples is accuracy; system errors of less than one degree Celsius (C) can be difficult to achieve. Any junction of dissimilar metals will produce an electric potential related to temperature. Thermocouples for practical measurement of temperature are junctions of specific alloys which have a predictable and repeatable relationship between temperature and voltage. Different alloys are used for different temperature ranges. Properties such as resistance to corrosion may also be important when choosing a type of thermocouple. Where the measurement point is far from the measuring instrument, the intermediate connection can be made by extension wires which are less costly than the materials used to make the sensor. Thermocouples are usually standardized against a reference temperature of 0 degrees Celsius; practical instruments use electronic
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methods of cold-junction compensation to adjust for varying temperature at the instrument terminals. Electronic instruments can also compensate for the varying characteristics of the thermocouple, and so improve the precision and accuracy of measurements. Thermocouples are widely used in science and industry; applications include temperature measurement for kilns, gas turbine exhaust, diesel engines, and other industrial processes.
Fig 2.4: A thermocouple measuring circuit with a heat source, cold junction and a measuring instrument. The principle of operation of the thermocouple is the seebeck effect i.e. the voltage is developed based on the temperature difference between the hot and the cold junctions of the thermocouple.
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Any attempt to measure this voltage necessarily involves connecting another conductor to the "hot" end. This additional conductor will then also experience the temperature gradient, and develop a voltage of its own which will oppose the original. Fortunately, the magnitude of the effect depends on the metal in use. Using a dissimilar metal to complete the circuit creates a circuit in which the two legs generate different voltages, leaving a small difference in voltage available for measurement. That difference increases with temperature, and is between 1 and 70 microvolts per degree Celsius (V/C) for standard metal combinations. The voltage is not generated at the junction of the two metals of the thermocouple but rather along that portion of the length of the two dissimilar metals that is subjected to a temperature gradient. Because both lengths of dissimilar metals experience the same temperature gradient, the end result is a measurement of the difference in temperature between the thermocouple junction and the reference junction.
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Thermocouples can be connected in series to form a thermopile, where all the hot junctions are exposed to a higher temperature and all the cold junctions to a lower temperature. The output is the sum of the voltages across the individual junctions, giving larger voltage and power output. COLD TEM BATTERY HOT WOODEN STOVE
INVERTER
LOAD
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2.4THERMOELECTRIC MODULE
Thermoelectric modules are solid-state devices (no moving parts) that convert electrical energy into a temperature gradient, known as the "Peltier effect" or convert thermal energy from a temperature gradient into electrical energy, the "Seebeck effect." Thermoelectric modules used as TE generators or TEGs are rather inefficient and little power is produced.
Fig 2.6: Thermoelectric module With no moving parts, thermoelectric modules are rugged, reliable and quiet heat pumps, typically 1.5 inches (40 x 40mm) square or smaller and approximately inch (4 mm) thick. The industry standard mean time between failures is around 200,000 hours or over 20 years for modules left in the cooling mode. Because the cold side of the module contracts while the hot side expands modules with a footprint larger than 1.5 - 2 inches square usually suffer from thermally induced stresses, at the electrical connection points inside the module causing a short, so they are not common. Long, thin modules want to bow for the same reason and are also rare. Larger areas than an individual module can maintain are cooled or have the temperature controlled by using multiple modules.
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Fig 2.7: Thermoelectric generator (TEG) Since the energy available from a single thermocouple is very small, arrays of thermocouples must be used to construct thermoelectric devices capable of handing practical amounts of power. Higher power devices can be made by connecting thermocouples in series to increase the voltage capability and in parallel to increase the current capacity. Such an array of thermocouples is called a thermopile. The thermocouples are connected using the conducting material and the thermopile is given a covering using ceramic substances in order to withstand the temperature difference applied .The unit as a whole is called as the thermoelectric module.
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In the thermoelectric module the metal cannot be used since the interconnections between the thermocouples using metal may cause the voltage to be developed in the opposite direction and as a result the net voltage produced id reduced and the output is drastically reduced. In order to avoid the problems while using the metallic conductors we use p and n type semiconductors connected together so that the voltage developed is aiding and the net output produced is increased. The operation is as follows: The temperature at the hot side is more at the hot side than at the cold side and as a result the electrons at the hot side of the n type semiconductor is having more energy and tends to flow towards the cold side. The movement of the electrons from the hot side is more faster than that from the cold side. Hence the flow of electron is from the hot side to the cold side Whereas when the temperature at the hot side is increased for the p type semiconductor the holes or the positive charge particle gets more energy and flow from the hot side to the cold side. Thus in effect the cold side portion of the n type semiconductor contains the negative charge and act as the negative terminal and the cold side portion of the p type semiconductor has the positive charge hence it will be acting as the positive terminal.
By connecting the adjacent n type and p type semiconductors at each side alternately the
effective output increases since they are aiding.
2.6THERMOELECTRIC MATERIALS
Bismuth Telluride (BizTe3) is the most semiconductor material that often used in the thermoelectric module construction. The crystals of bismuth telluride have the layers of atoms forming the sequence as:
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The bismuth and tellurium layers are connected by strong covalent ionic bonds. There are 2 ways to fabricate thermoelectric materials which are either by using directional crystallization from a melt or pressed powder metallurgy. By using the directional crystallization, typically Bismuth Telluride material is fabricated in ingot or boule form and then sliced into wafers of various thicknesses. Then the wafer is diced into blocks that may be assembled into thermoelectric cooling modules after the wafer's surfaces have been properly prepared. The blocks of Bismuth Telluride material, usually are called elements or dice. Beside Bismuth Telluride (Bi2Te3), other thermoelectric materials including Lead Telluride (PbTe), Silicon Germanium (SiGe), Bismuth-Antimony (Bi-Sb), Mercury Telluride and Silver Telluride alloys may be used in specific situations.
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2.8 INVERTER
An inverter, is an electrical power converter that changes direct current (DC) to alternating current (AC); the converted AC can be at any required voltage and frequency with the use of appropriate transformers, switching, and control circuits. Solid-state inverters have no moving parts and are used in a wide range of applications, from small switching power supplies in computers, to large electric utility high-voltage direct current applications that transport bulk power. Inverters are commonly used to supply AC power from DC sources such as solar panels or batteries. The inverter performs the opposite function of a rectifier. The electrical inverter is a highpower electronic oscillator. It is so named because early mechanical AC to DC converters were made to work in reverse, and thus were "inverted", to convert DC to AC. The square wave output has a high harmonic content, not suitable for certain AC loads such as motors. Square wave units were the pioneers of inverter development.
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the other. The alternation of the direction of current in the primary winding of the transformer produces alternating current (AC) in the secondary circuit. The electromechanical version of the switching device includes two stationary contacts and a spring supported moving contact. The spring holds the movable contact against one of the stationary contacts and an electromagnet pulls the movable contact to the opposite stationary contact. The current in the electromagnet is interrupted by the action of the switch so that the switch continually switches rapidly back and forth. This type of electromechanical inverter switch, called a vibrator or buzzer, was once used in vacuum tube automobile radios. A similar mechanism has been used in door bells, buzzers and tattoo guns.
Fig 2.10: Basic inverter schematic As they became available with adequate power ratings, transistors and various other types of semiconductor switches have been incorporated into inverter circuit designs. Certain ratings, especially for large systems (many kilowatts) use thyristors (SCR). SCRs provide large power handling capability in a semiconductor device, and can readily be controlled over a variable firing range.
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CHAPTER3 OBJECTIVES
The main objectives of this project are: The main objective is to find a substitute for general source of electricity Remedy for rural area electrification Incorporation of thermo electric module onto the wooden stove Generation of electricity from the waste heat of the stove Study of the inverter design
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Electrical connections
Inverter Design
Observations
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Among the different thermo electric modules the available one was the TEC12704. The following are the specifications of the TEC12704 Table 4.2: TE module dimension
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The performance characteristics of the TEC12704 with the variation in the temperature are given below:
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4.3.2COOLING SYSTEM
The cooling system is made in order to provide the cooling at the cold junction of the thermocouples in the thermo electric module. The cold water was supplied through the cooling system in order. The steps involved are: The hollow rod of aluminium was cut into the 2 pieces of the required length. Four small hollow tubes were cut and they were placed at the ends of the hollow rod. The two ends of the tubes were connected using a plastic pipe and among the remaining tubes one was given to the water inlet and the other for the outlet of the water.
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4.4.2 BATTERY
A battery is a device consisting of one or more electrochemical cells that convert stored chemical energy into electrical energy. The secondary batteries (rechargeable batteries), which are designed to be recharged and used multiple times are used. The 12v 7Ah battery is used in order to store the electric charge generated from the stove.
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IC 3525
Fig4.7: Pin configuration of IC3525 The IC3525series of pulse width modulator integrated circuits are designed to offer improved performance and lowered external parts count when used in designing all types of switching power supplies. The input common-mode range of the error amplifier includes the reference voltage eliminating external resistors. A sync input to the oscillator al lows multiple units to be slaved or a single unit to be synchronized to an external system clock. A single resistor between the CT and the discharge terminals provide a wide range of dead time adjustment. These devices also feature built in soft-start circuitry with only an external timing capacitor required. A shutdown terminal controls both the soft-start circuitry and the output stages, providing
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Instantaneous turn off through the PWM latch with pulsed shut down, as well as soft-start recycle with longer shut down commands. These functions are also control led by an under voltage lockout which keeps the out puts off and the soft-start capacitor discharged for sub-normal input voltages. This lockout circuitry includes approximately 500 mV of hysteresis for jitter free operation. Another feature of these PWM circuits is a latch following the comparator. Once a PWM pulses has been terminated for any reason the outputs will remain off for the duration of the period. The latch is reset with each clock pulse. The output stages are totem-pole designs capable of sourcing or sinking in excess of 200 mA. The IC3525Aoutput stage features NOR logic, giving a LOW output for an OFF state. Table 4.4: Maximum ratings
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MOSFET is by far the most common transistor in both digital and analog circuits, though the bipolar junction transistor was at one time much more common. In enhancement mode MOSFETs, a voltage drop across the oxide induces a conducting channel between the source and drain contacts via the field effect. The term "enhancement mode" refers to the increase of conductivity with increase in oxide field that adds carriers to the channel, also referred to as the inversion layer. The channel can contain electrons (called an nMOSFET or nMOS), or holes (called a pMOSFET or pMOS), opposite in type to the substrate, so nMOS is made with a p-type substrate, and pMOS with an n-type substrate (see article on semiconductor devices). In the less common depletion mode MOSFET, detailed later on, the channel consists of carriers in a surface impurity layer of opposite type to the substrate, and conductivity is decreased by application of a field that depletes carriers from this surface layer.
Fig 4.8: MOSFET The traditional metaloxidesemiconductor (MOS) structure is obtained by growing a layer of silicon dioxide (SiO2) on top of a silicon substrate and depositing a layer of metal or polycrystalline silicon (the latter is commonly used). As the silicon dioxide is a dielectric material, its structure is equivalent to a planar capacitor, with one of the electrodes replaced by a semiconductor. When a voltage is applied across a MOS structure, it modifies the distribution of charges in the semiconductor. If we consider a p-type semiconductor a positive voltage, ,
from gate to body creates a depletion layer by forcing the positively charged holes away from the
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gate-insulator/semiconductor interface, leaving exposed a carrier-free region of immobile, negatively charged acceptor ions. If is high enough, a high concentration of negative charge
carriers forms in an inversion layer located in a thin layer next to the interface between the semiconductor and the insulator. Unlike the MOSFET, where the inversion layer electrons are supplied rapidly from the source/drain electrodes, in the MOS capacitor they are produced much more slowly by thermal generation through carrier generation and recombination centers in the depletion region. Conventionally, the gate voltage at which the volume density of electrons in the inversion layer is the same as the volume density of holes in the body is called the threshold voltage. When the voltage between transistor gate and source (VGS) exceeds the threshold voltage (Vth), it is known as overdrive voltage.
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12v
Fig4.10: Transformer
Hence RT = 140.857Kohm (150Kohm standard value) The 104micro farad is connected between Vref and Inv.input in order to give a constant input to the error amplifier. The capacitor connected between the soft start and the ground serves the function of controlling the starting current and the gradual increase of the duty cycle to the desired value. The equation governing the soft start is: Tsec = Css *Vout I I = 51 micro amperes Vout = 2.5V
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To get soft start time as 0.1sec the capacitor of 2.2micro farad is chosen. A 2.2Kohm and a 104 micro farad is connected in parallel across the ground and the shut down pin as a filter for the noises. It should be kept low in order to generate the gate pulses for the mosfet to get triggered. The 33ohm resistor is connected between the output pins and the mosfets to limit if any high current flow through it.
4.6 OBSERVATIONS
The firewood was placed in the stove and the ignition was given. The temperature began to rise slowly. At the same time the cold water was passed through the cooling system which was arranged at the cold side of the modules. After sometime the temperature difference at the thermo electric module began to build up. The multimeter showed a deflection. The voltage began to increase rapidly for about 5 minutes. Then the rising of the voltage become slow. After reaching a particular temperature the voltage rise stopped and it began to decrease slowly. In order to prevent the decrease of the voltage the heat sink fins are slowly released from the stove. The electric energy from the modules were stored in a battery. The inverter was driven from the battery. The output from the inverter is 230volt and the wattage was 150w.
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Comparison of the LPG stove and the thermoelectric wooden stove A study was done with the ordinary LPG gas stove and the Thermo Electric wooden stove .The comparison period was taken as one year. The cost for the operation of the two systems were compared and tabulated.
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Table 5.2: cost comparison with LPG ITEM LPG STOVE THERMOELECTRIC WOODEN STOVE LPG WITH SUBSIDY LPG WITHOUT SUBSIDY HARD WOOD 12*90 KG 4 4320 9 3 460 960 4140 2880 QUANTITY 1 1 RATE 5500 8100 AMOUNT 5500 8100
By the above comparison the total cost for the LPG stove for one year is obtained as 12520 Rs. Where as in the case of the wooden stove it costs only 12420 Rs. The electricity generated per day while burning for 3.5 hrs in an average =105watts Electricity generated per month = 105*30 = 3150watts Electricity generated per year = 3000*12 = 37800 watts Thus the thermo electric wooden stove acts as the secondary source of energy for the households.
Table 5.3: Advantage and disadvantages ITEM LPG Ease of use Quick heating Clean burning Non renewable High cost Not easily available THERMO ELECTRIC STOVE ADVANTAGES Renewable Low cost Readily available Pollution Slow heating
DISADVANTAGES
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CHAPTER6 CONCLUSION
From this project we came to the conclusion that thermoelectric wooden stove can be used as a substituent for general source of electricity for households. The construction of the multifunctional wooden stove is very useful since its efficiency is increased by utilizing its waste heat to generate electricity. The thermo electric wooden stove is very useful in the rural area electrification where electricity has not reached yet. The components used in this project are very less and hence can be built easily and fast which is an added advantage to the thermoelectric wooden stove.
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