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General Chemistry II Exam 1 Practice Problems

Multiple Choice Identify the letter of the choice that best completes the statement or answers the question. ____ 1. How much heat is released when 75 g of octane is burned completely if the enthalpy of combustion is -5,500 kJ/mol C8H18? C8H18 + 25/2 O2 8CO2 + 9H2O a. b. c. d. e. ____ 7200 kJ 8360 kJ 4.1 105 kJ 3600 kJ 5500 kJ

2. Calculate the amount of heat released in the complete combustion of 8.17 grams of Al to form Al2O3(s) at 25C and 1 atm. H for Al2O3(s) = 1676 kJ/mol 4Al(s) + 3O2(g) 2Al2O3(s) a. b. c. d. e. 254 kJ 203 kJ 127 kJ 237 kJ 101 kJ

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3. Given the following at 25C and 1.00 atm: 1/2N2(g) + O2(g) NO2(g) N2(g) + 2O2(g) N2O4(g) Calculate the H0 for the reaction below at 25C. 2NO2(g) N2O4(g) a. b. c. d. e. +11.0 kJ +44.3 kJ +55.3 kJ -22.1 kJ -55.3 kJ H0 33.2 kJ 11.1 kJ

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4. Calculate H0 for the following reaction at 25.0C. Fe3O4(s) -1118 + CO(g) -110.5 3FeO(s) -272 + CO2(g) -393.5

H (kJ/mol) a. b. c. d. e. -263 kJ 54 kJ 19 kJ -50 kJ 109 kJ

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____ 5. How much heat is released when 6.38 grams of Ag(s) reacts by the equation shown below at standard state conditions? 4Ag(s) + 2H2S(g) + O2(g) 2Ag2S(s) + 2H2O(l) Substance Ag(s) H2S(g) O2(g) Ag2S(s) H2O(l) a. b. c. d. e. ____ 8.80 kJ 69.9 kJ 22.1 kJ 90.8 kJ 40.5 kJ 0 -20.6 0 -32.6 -285.8

6. Evaluate H0 for the following reaction from the given bond energies. 2HBr(g) H2(g) + Br2(g) HH-H = 436 kJ/mol, HBr-Br = 193 kJ/mol, HH-Br = 366 kJ/mol a. b. c. d. e. -103 kJ -143 kJ +103 kJ +142 kJ 259 kJ

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7. A 0.900-g sample of toluene, C7H8, was completely burned in a bomb calorimeter containing 4560. g of water which increased in temperature from 23.800C to 25.718C. What is E for the reaction in kJ/mol C7H8? The heat capacity of the calorimeter was 780. J/C. The specific heat of water is 4.184 J/gC. a. - 4520 kJ/mol b. +3500 kJ/mol c. -38.1 kJ/mol d. -2220 kJ/mol e. -3900 kJ/mol 8. Calculate S0 for the reaction below at 25C. S0 for SiH4 = 204.5 J/molK, for O2(g) = 205.0 J/molK, for SiO2(s) = 41.84 J/molK, for H2O(l) = 69.91 J/molK. SiH4(g) + 2O2(g) SiO2(s) + 2H2O(l) a. b. c. d. e. -353.5 J/K - 432.8 J/K 595.0 J/K -677.0 J/K -880.3 J/K

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9. Which one of the following reactions has a positive entropy change? a. H2O(g) H2O(l) b. BF3(g) + NH3(g) F3BNH3(s) c. 2SO2(g) + O2(g) 2SO3(g) d. N2(g) + 3H2(g) 2NH3(g) e. 2NH4 NO3(s) 2N2(g) + 4H2O(g) + O2(g)

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____ 10. Consider the conversion of a substance from solid to liquid. Solid Liquid At one atmosphere pressure and at the melting point of the substance, __________. a. H = 0 for the process b. S = 0 for the process c. E = 0 for the process d. G = 0 for the process e. both H = 0 and E = 0 for the process 11. Calculate the G at 298 K for PbCl2(s) from the following information. G0 for the reaction below is -58.4 kJ at 298 K. PbS(s) -98.7 + 2HCl(g) -95.30 PbCl2(s) ? + H2S(g) -33.6

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G (kJ/mol) a. b. c. d. e. ____ -16.0 kJ/mol - 47.6 kJ/mol -314.1 kJ/mol -36.2 kJ/mol -52.3 kJ/mol

12. For the reaction given below, H0 = -1516 kJ at 25C and S0 = - 432.8 J/K at 25C. This reaction is spontaneous __________. SiH4(g) + 2O2(g) SiO2(s) + 2H2O(l) a. b. c. d. e. only below a certain temperature only above a certain temperature at all temperatures at no temperatures cannot tell from the information available

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13. Which of the following reactions is spontaneous at relatively low temperatures? a. NH4Br(s) + 188 kJ NH3(g) + Br2(l) b. NH3(g) + HCl(g) NH4Cl(s) + 176 kJ c. 2H2O2(l) 2H2O(l) + O2(g) + 196 kJ d. both (a) and (b) e. both (a) and (c) 14. For a certain process at 127C, G = -16.20 kJ and H = -17.0 kJ. What is the entropy change for this process at this temperature? Express your answer in the form, S = __________ J/K. a. -6.3 J/K b. +6.3 J/K c. -2.0 J/K d. +2.0 J/K e. -8.1 J/K 15. Evaluate S0 for the reaction below at 25C. CH4(g) -74.81 -50.75 + 2Cl2(g) 0 0 CCl4(l) -135.4 -65.27 + 2H2(g) 0 0

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H (kJ/mol) G (kJ/mol)

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a. b. c. d. e. ____ -360 J/K -66.9 J/K -155 J/K - 487 J/K -387 J/K

16. Estimate the temperature above which this reaction is spontaneous. S0 = 16.1 J/K. CH4(g) + N2(g) + 163.8 kJ HCN(g) + NH3(g) a. b. c. d. e. 9.91C 1045 K 9.90 103C 10.7 K 10.1C = 0?

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17. For which of the following substances does a. CO2(g) b. H2O(g) c. Na(s) d. Br2(g) e. C(diamond)

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18. Which of the following techniques cannot be used to calculate Hrxn? a. Calorimetry b. Using melting points of reactants and products c. Hess's Law d. Using of Heats of Formation of reactants and products e. Using bond energies of reactants and products 19. Which statement concerning sign conventions for E = q + w is false? a. For heat absorbed by the system, q is positive. b. For work done by the system, w is negative. c. When energy is released by the reacting system, E is negative. d. If E is positive, energy can be written as a product in the equation for the reaction. e. For an expansion, w is negative. 20. A system is compressed from 50.0 L to 5.0 L at a constant pressure of 10.0 atm. What is the amount of work done? a. 2.5 105 J b. 450 J c. 4.6 104 J d. -450 J e. -4.6 104 J

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____ 21. A 1.00-g sample of hexane, C6H14, undergoes complete combustion with excess O2 in a bomb calorimeter. The temperature of the 1500. g of water surrounding the bomb rises from 22.64C to 29.30C. The heat capacity of the calorimeter is 4.04 kJ/C. What is E for the reaction in kJ/mol of C6H14. The specific heat of water is 4.184 J/gC. a. -9.96 103 kJ/mol b. - 4.52 103 kJ/mol c. -1.15 104 kJ/mol d. -7.40 104 kJ/mol e. -5.91 103 kJ/mol

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____ 22. Assuming the gases are ideal, calculate the amount of work done, in joules, for the conversion of 1.00 mole of Ni to Ni(CO)4 at 75C in the reaction below. The value of R is 8.314 J/molK. Ni(s) + 4CO(g) Ni(CO)4(g) a. b. c. d. e. 1.80 103 J 8.68 103 J -1.80 103 J -8.68 103 J - 494 J

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General Chemistry II Answer Section MULTIPLE CHOICE 1. ANS: D 2. ANS: A 3. ANS: E 4. ANS: C 5. ANS: A 6. ANS: C 7. ANS: E 8. ANS: B 9. ANS: E 10. ANS: D 11. ANS: C 12. ANS: A 13. ANS: B 14. ANS: C 15. ANS: C 16. ANS: C 17. ANS: C 18. ANS: B 19. ANS: D 20. ANS: C TOP: Thermochemical Equations TOP: Standard Molar Enthalpies of Formation... TOP: Hess's Law TOP: Hess's Law TOP: Hess's Law TOP: Bond Energies TOP: Changes in Internal Energy, Delta E TOP: Entropy TOP: Entropy TOP: Free Energy Change, Delta G, and Spontaneity TOP: Free Energy Change, Delta G, and Spontaneity TOP: The Temperature Dependence of Spontaneity TOP: The Temperature Dependence of Spontaneity TOP: The Temperature Dependence of Spontaneity TOP: The Temperature Dependence of Spontaneity TOP: The Temperature Dependence of Spontaneity TOP: Standard Molar Enthalpies of Formation,... TOP: Bond Energies TOP: Changes in Internal Energy, Delta E TOP: Relationship Between Delta H and Delta E Exam 1 Practice Problems

21. ANS: E 22. ANS: B

TOP: Changes in Internal Energy, Delta E TOP: Relationship Between Delta H and Delta E