Safety Data Sheet

ZETAG 8814
Revision date : 05.07.2010 Version: 1.2 Page: 1/6 (30481547/SDU_GEN_CA/EN)

1. Product and Company Identification

Company BASF Canada Inc. 100 Milverton Drive Mississauga, ON L5R 4H1, CANADA 24 Hour Emergency Response Information CANUTEC (reverse charges): (613) 996-6666 BASF HOTLINE: (800) 454-COPE (2673)

2. Hazards Identification
Emergency overview

Signal word: Colour: Appearance: State of matter: Odour: Health:

Physical/Chemical hazards:
Potential health effects

CAUTION: ! colourless emulsion liquid mineral oil-like Contact causes eye irritation, Contact causes skin irritation., Contains petroleum distillates and prolonged contact with mists may cause skin, eye and respiratory tract irritation. Continued overexposure may cause headache and dizziness. Ingestion may cause lung complications. Spills are very slippery.

Primary routes of entry: Skin, Eyes, Inhalation, Ingestion Chronic exposure: CAUSES EYE IRRITATION. Vapors may irritate eyes and respiratory tract, and result in headacheor dizziness.

3. Composition/Information on Ingredients
Chemical name Ethanaminium, N,N,N-trimethyl-2-[(1-oxo-2propenyl)oxy]-, chloride, polymer with 2propenamide (9CI) ALCOHOLS, (C=12-14)-SECONDARY, ETHOXYLATED Distillates (petroleum), hydrotreated light CAS Number 69418-26-4 Content (Weight) 15.0 - 40.0 % Hazardous Y

84133-50-6 64742-47-8

1.0 - 5.0 % 10.0 - 30.0 %

Y Y

Safety Data Sheet

ZETAG 8814
Revision date : 05.07.2010 Version: 1.2 1,2,3-Propanetricarboxylic acid, 2-hydroxy77-92-9 Page: 2/6 (30481547/SDU_GEN_CA/EN) 0.0 - 5.0 % Y

4. First-aid Measures
Inhalation: Remove to fresh air, if not breathing give artificial respiration. If breathing is difficult, give oxygen and get immediate medical attention. Skin: If clothing is contaminated, remove and launder before reuse. After contact with skin, wash immediately with plenty of water and soap. Get medical attention if irritation occurs. Eyes: Immediately flush the eye(s) with lukewarm, gently flowing water for 15 minutes or until the chemical is removed. Get immediate medical attention if irritation persists. Ingestion: Do not induce vomiting. If vomiting occurs naturally, have casualty lean forward to reduce the risk of aspiration. Seek medical attention immediately.

5. Fire-fighting Measures
Suitable extinguishing media: carbon dioxide, dry powder, foam Unsuitable Extinguishing Media: If water is used, restrict pedestrian and vehicular traffic in areas where slip hazard may exist. Hazardous combustion products: Burning may produce oxides. Hazards during fire-fighting: Standard procedure for chemical fires. Cool fire-exposed containers with water. Spills can cause very slippery conditions on floors. Protective equipment for fire-fighting: Wear self-contained breathing apparatus and chemical-protective clothing.

6. Accidental Release Measures

Cleanup: Pick up with inert absorbent material (e.g. sand, earth etc.). Place into approved waste containers. Wear suitable protective equipment. Should not be released into the environment.

Safety Data Sheet

ZETAG 8814
Revision date : 05.07.2010 Version: 1.2 Page: 3/6 (30481547/SDU_GEN_CA/EN)

7. Handling and Storage

Handling

General advice: As with all industrial chemicals, use good industrial practices when handling. Avoid eye, skin, and clothing contact. Do not inhale. Do not taste or swallow. Use only with adequate ventilation. Clean up spills promptly Protection against fire and explosion: None known
Storage

General advice: Keep container tightly closed in a dry, cool and well-ventilated place. Avoid extremes of temperature. Keep from freezing. Temperature tolerance: Keep from freezing. > for industrial use only <

8. Exposure Controls and Personal Protection

Exposure Guidelines

Distillates (petroleum), hydrotreated light (64742-47-8)

ACGIH

200 mg/m3 TWA: 200 mg/m3 Non-aerosol (as total hydrocarbon vapor) P: Application restricted to conditions in which there are negligible aerosol exposures. SKIN_DES: Non-aerosol (as total hydrocarbon vapor) Can be absorbed through the skin

Engineering Controls: Work in well ventilated areas. Do not breathe vapors or mist.
Personal protective equipment

Respiratory protection: Use NIOSH approved respirator as needed to mitigate exposure. Eye protection: Tightly fitting safety goggles (splash goggles) (EN 166) Body protection: Wear chemical resistant gloves and protective clothing. General safety and hygiene measures: Eye wash station and safety shower should be available in immediate work area., Select additional protective equipment based upon potential for exposure.

Safety Data Sheet

ZETAG 8814
Revision date : 05.07.2010 Version: 1.2 Page: 4/6 (30481547/SDU_GEN_CA/EN)

9. Physical and Chemical Properties

Colour: Form: State of matter: Odour: pH value: Evaporation rate: Flammability: Flash point: Self-ignition temperature: Melting point: Boiling point: Vapour pressure: Density: Vapour density: Partitioning coefficient noctanol/water (log Pow): Viscosity, dynamic: % Volatiles: Solubility in water: Solubility in other solvents: Autoignition: colourless emulsion liquid mineral oil-like approx.4.0 Not tested Not tested > 93 C Not tested Not tested Not tested Not tested approx. 1.0 g/cm3 Not tested Not applicable approx. 1,000 mPa.s not determined dispersible Not tested Not tested

10. Stability and Reactivity

Stability: Stable Conditions to avoid: Avoid temperature extremes.

Substances to avoid: Strong oxidizing agents, strong acids, strong bases. Possibility of Hazardous Reactions: No hazardous reactions known. Hazardous decomposition products: No decomposition expected under normal storage conditions.

11. Toxicological Information

Acute oral toxicity:

oral / rat: 2,000 mg/kg By analogy with a product of similar composition

Acute inhalation toxicity:

Information on: Distillates (petroleum), hydrotreated light Inhalation of vapors and mists is harmful. ---------------------------------Skin irritation:

Not tested Component(s) in greater than 1 percent concentration is known to be an irritant. Information on: ALCOHOLS, (C=12-14)-SECONDARY, ETHOXYLATED CAUSES SKIN IRRITATION.

Safety Data Sheet

ZETAG 8814
Revision date : 05.07.2010 Version: 1.2 ---------------------------------Information on: Distillates (petroleum), hydrotreated light (Rabbits) Prolonged or repeated contact can cause defatting and drying of the skin resulting in skin irritation and dermatitis. ---------------------------------Eye irritation:

Page: 5/6 (30481547/SDU_GEN_CA/EN)

Product has not been tested. Component(s) in greater than 1 percent concentration is known to be an irritant. Information on: ALCOHOLS, (C=12-14)-SECONDARY, ETHOXYLATED Causes eye burns.

---------------------------------Information on: Distillates (petroleum), hydrotreated light : Irritant. (Rabbits)

---------------------------------Skin Sensitization:

Information on: Distillates (petroleum), hydrotreated light Sensitization: no data available ---------------------------------Carcinogenicity: None of the components in this product at concentrations greater than 0.1% are listed by IARC; NTP, OSHA or ACGIH as a carcinogen.

12. Ecological Information

Toxicity to fish: Oncorhynchus mykiss/96 h/LC50: > 100 mg/l Menidia beryllina/96 h/LC50: 27 mg/l (under static conditions) Toxicity to aquatic invertebrates: Daphnia magna/48 h/LC50: > 100 mg/l (under static conditions) Americamysis bahia/96 h/LC50: 5.8 mg/l (under static conditions) Other ecotoxicological advice: This product contains polymer(s) that may be toxic to aquatic organisms when tested in pure (distilled) water. Toxicity is greatly reduced byparticles in natural water.

13. Disposal Considerations

Waste disposal of substance: Dispose of in accordance with national, state and local regulations.

Safety Data Sheet

ZETAG 8814
Revision date : 05.07.2010 Version: 1.2 Page: 6/6 (30481547/SDU_GEN_CA/EN)

14. Transport Information

TDG (Canada) Road transport

Special shipping information: Special shipping information: Special shipping information:

Not classified as a dangerous good under transport regulations. Not classified as a dangerous good under transport regulations. Not classified as a dangerous good under transport regulations.

International Air Transport Association (IATA) International Maritime Dangerous Goods Code (IMDG)

15. Regulatory Information

US: Toxic Substances Control Act (TSCA): All component(s) comprising this product are either exempt or listed on the TSCA inventory All components either exempt or listed on the DSL

Canada: Domestic Substances List (DSL):

Canada Regulations

Workplace Hazardous Materials Information System (WHMIS Classification): D-2B Materials Causing Other Toxic Effects - Toxic material

This product is WHMIS controlled. Significant New Activity Conditions (SNAC): This product does not contain any components subject to a SNAC Notice.
International Regulations

Chemical Weapons Convention: This product does not contain any component(s) listed under the Chemical Weapons Convention Schedule of Chemicals.

16. Other Information

This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations.

ZETAG 8814 is a registered trademark of BASF Canada or BASF SE Due to the merger of CIBA and BASF Group all Material Safety Data Sheets have been reassessed on the basis of consolidated information. This may have resulted in changes of the Material Safety Data Sheets. In case you have questions concerning such changes please contact us at the address mentioned in Section I. END OF DATA SHEET