Chem Service Inc.: Material Safety Data Sheet

Chem Service Inc.
Material Safety Data Sheet

Last Revision Date: 10/20/2011 SECTION 1 - CHEMICAL PRODUCT and COMPANY IDENTIFICATION Catalog Number: N-11203 Description: Bifenthrin Other Names: Capture/Talstar Supplied by CHEM SERVICE, Inc. PO BOX 599, WEST CHESTER, PA 19381 (610)-692-3026 EMERGENCY PHONE: 1-610-692-3026 SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS CAS: 82657-04-3 Description: Bifenthrin EINECS No: Hazard Symbols: Xn N Molecular Weight: 422.90 Molecular Formula: C23H22ClF3O2 SECTION 3 - HAZARDS IDENTIFICATION Contact lenses should not be worn in the laboratory Can cause eye irritation. Can cause skin irritation. Based on the toxicity of compounds of similar structure this material probably is moderately hazardous.
SECTION 4 - FIRST AID MEASURES An antidote is a substance intended to counteract the effect of a poison. It should be administered only by a physician or trained emergency personnel. Medical advice can be obtained from a POISON CONTROL CENTER. In case of contact: Flush eyes continuously with water for 15-20 minutes. Flush skin with water for 15-20 minutes. If no burns have occurred-use soap and water to cleanse skin. If inhaled remove patient to fresh air. Administer oxygen if patient is having difficulty breathing. If patient has stopped breathing administer artificial respirations. If patient is in cardiac arrest administer CPR. Continue life supporting measures until medical assistance has arrived. Remove and wash contaminated clothing. If patient is exhibiting signs of shock - Keep warm and quiet. Get medical attention if necessary. If swallowed DO NOT induce vomiting. If patient is vomiting-watch closely to make sure airway does not become obstructed by vomit. Do not administer liquids or induce vomiting to an unconscious or convulsing person. Contact Poison Control Center immediately if necessary.
SECTION 5 - FIRE AND EXPLOSION DATA Flash Point: 165 C Upper Explosion Limit: N/A NFPA Hazard Rating: Health 2 Extinguishing Media: Carbon dioxide, dry chemical powder or spray. Lower Explosion Limit: N/A Auto Ignition: N/A
Flammability 0
Reactivity 0
Special
0 - Least, 1 - Slight, 2 - Moderate, 3 - High, 4 - Severe SECTION 6 - ACCIDENTAL RELEASE MEASURES Spills or leaks: Evacuate area. Wear appropriate OSHA regulated equipment. Ventilate area. Absorb on vermiculite or similar material. Sweep up and place in an appropriate container. Hold for disposal. Wash contaminated surfaces to remove any residues. Remove contaminated clothing and wash before reuse. SECTION 7 - HANDLING AND STORAGE Handling: This chemical should be handled only in a hood. Eye shields should be worn. Use appropriate OSHA/MSHA approved safety equipment. Avoid contact with skin, eyes and clothing. Avoid ingestion and inhalation Wash thoroughly after handling. Storage:
Store in a cool dry place. Store only with compatible chemicals. Store only with compatible chemicals. Keep tightly closed.
SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION OSHA PEL (TWA): N/A ACGIH TLV (TWA): N/A ACGIH TLV (STEL): N/A
Personal Protective Equipment Eyes: Wear Safety Glasses. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin. Respirators: A respiratory protection program that meets OSHA's 29 CFR 1910.134 requirements must be followed whenever workplace conditions warrant a respirator's use. SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES Color: White Phase: Crystalline solid Melting Point: 68-70.6 C Boiling Point: N/A C
Specific Gravity: 1.210 Vapor Density: N/A Vapor Pressure:0.024mPa @ 25 C Solubility in water: Insoluble (immiscible) Odor: N/A Evaporation Rate: N/A Molecular Weight: 422.90 Molecular Formula: C23H22ClF3O2 SECTION 10 - STABILITY AND REACTIVITY Emits toxic fumes under fire conditions.
SECTION 11 - TOXICOLOGY INFORMATION RTECS: GZ1227800 Oral Rat or Mouse LD50: 55 Carcinogenicity OSHA: No Dermal Rat or Mouse LD50: > N/A Rat or Mouse LC50: N/A
NTP: No
IARC: No
CARC: No
NIOSH: No
ACGIH: No
California Proposition 65 info: Not Listed SECTION 12 - ECOLOGICAL INFORMATION Ecotoxicity: Not Available Environmental Fate: Not Available SECTION 13 - DISPOSAL CONSIDERATIONS Burn in a chemicals incinerator equipped with an afterburner and scrubber. SECTION 14 - TRANSPORTATION INFORMATION UN Number: UN2811 Class: 6.1 Packing Group: III Proper Shipping Name: Toxic solid, organic, nos *
SECTION 15 - REGULATORY INFORMATION European Labeling in Accordance with EC Directives Hazard Symbols: Xn N Risk Phrases: -R20/21/22: Harmful by inhalation, in contact with skin and if swallowed. -R50/53: Very toxic to aquatic organisms and May cause long-term adverse effects in the aquatic environment.
Safety Phrases: -S13: Keep away from food, drink and animal feeding stuffs. -S60: This material and/or it's container must be disposed of as hazardous waste.
-S61: Avoid release to the environment. Refer to special instructions/Safety data sheet.
SECTION 16 - OTHER INFORMATION The above information is believed to be correct on the date it was last revised and must not be considered all inclusive. The information has been obtained only by a search of available literature and is only a guide for handling the chemicals. OSHA regulations require that if other hazards become evident, an upgraded MSDS must be made available to the employee within three months. RESPONSIBILITY for updates lies with the employer and not with CHEM SERVICE, Inc. Persons not specifically and properly trained should not handle this chemical or its container. This product is furnished FOR LABORATORY USE ONLY! Our products may NOT BE USED as drugs, cosmetics, agricultural or pesticide products, food additives or as household chemicals. This Material Safety Data Sheet (MSDS) is intended only for use with Chem Service, Inc. products and should not be relied on for use with materials from any other supplier even if the chemical name(s) on the product are identical! Whenever using an MSDS for a solution or mixture the user should refer to the MSDS for every component of the solution or mixture. Chem Service warrants that this MSDS is based upon the most current information available to Chem Service at the time it was last revised. THIS WARRANTY IS EXCLUSIVE, AND CHEM SERVICE, INC. MAKES NO OTHER WARRANTY, EXPRESSED OR IMPLIED, INCLUDING ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR ANY PARTICULAR PURPOSE. This MSDS is provided gratis and CHEM SERVICE, INC. SHALL NOT BE LIABLE FOR ANY INCIDENTAL, CONSEQUENTIAL OR CONTINGENT DAMAGES. Copyright 2000-2011 Chem Service, Inc. All rights reserved except that this MSDS may be printed for the use of a customer or prospective customer of Chem Service, Inc provided the entire MSDS is printed. The MSDS may not be placed in any database or otherwise stored or distributed in electronic or any other form. This product is furnished FOR LABORATORY USE ONLY!
Chem Service Inc. Material Safety Data Sheet

Last Revision Date: 07/05/2011 SECTION 1 - CHEMICAL PRODUCT and COMPANY IDENTIFICATION Catalog Number: N-11404 Description: Carbendazim Other Names: 2-Methoxycarbonylamino)-benzimidazole Supplied by CHEM SERVICE, Inc. PO BOX 599, WEST CHESTER, PA 19381 (610)-6923026 EMERGENCY PHONE: 1-610-692-3026 SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS CAS: 10605-21-7 Description: Carbendazim EINECS No: 234-232-0 Hazard Symbols: T N Molecular Weight: 191.21 Molecular Formula: C9H9N3O2 SECTION 3 - HAZARDS IDENTIFICATION Contact lenses should not be worn in the laboratory May be harmful if absorbed through the skin. May be harmful if inhaled. May be fatal if absorbed through the skin! Can cause eye irritation. Possible teratogen-causes embryo-fetal damage. Can cause adverse reproductive effects. Possible mutagen-May cause birth defects in future generations. May be harmful if inhaled.
SECTION 4 - FIRST AID MEASURES An antidote is a substance intended to counteract the effect of a poison. It should be administered only by a physician or trained emergency personnel. Medical advice can be obtained from a POISON CONTROL CENTER. In case of contact: Flush eyes continuously with water for 15-20 minutes. Flush skin with water for 15-20 minutes. If no burns have occurred-use soap and water to cleanse skin. If inhaled remove patient to fresh air. Administer oxygen if patient is having difficulty
breathing. If patient has stopped breathing administer artificial respirations. If patient is in cardiac arrest administer CPR. Continue life supporting measures until medical assistance has arrived. Remove and wash contaminated clothing. If patient is exhibiting signs of shock - Keep warm and quiet. Contact Poison Control Center immediately if necessary. Induce vomiting if swallowed. Do not administer liquids or induce vomiting to an unconscious or convulsing person. If patient is vomiting-watch closely to make sure airway does not become obstructed by vomit. Get medical attention if necessary.
SECTION 5 - FIRE AND EXPLOSION DATA Flash Point: Not Available Extinguishing Media: Carbon dioxide, dry chemical powder or spray. Lower Explosion Limit: N/A Auto Ignition: N/A
Upper Explosion Limit: N/A
NFPA Hazard Rating: Health Flammability 0 0
Reactivity 0
Special
0 - Least, 1 - Slight, 2 - Moderate, 3 - High, 4 - Severe SECTION 6 - ACCIDENTAL RELEASE MEASURES Spills or leaks: Evacuate area. Wear appropriate OSHA regulated equipment. Ventilate area. Absorb on vermiculite or similar material. Sweep up and place in an appropriate container. Hold for disposal. Wash contaminated surfaces to remove any residues. Remove contaminated clothing and wash before reuse. SECTION 7 - HANDLING AND STORAGE Handling: This chemical should be handled only in a hood. Eye shields should be worn. Use appropriate OSHA/MSHA approved safety equipment. Avoid contact with skin, eyes and clothing. Avoid ingestion and inhalation Wash thoroughly after handling. Storage: Store in a cool dry place. Store only with compatible chemicals. Store only with compatible chemicals. Keep tightly closed.
Personal Protective Equipment Eyes: Wear Safety Glasses. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin. Respirators: A respiratory protection program that meets OSHA's 29 CFR 1910.134 requirements must be followed whenever workplace conditions warrant a respirator's use. SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES Color: Colorless Phase: Crystalline solid Melting Point: 310 C Boiling Point: N/A C Specific Gravity: N/A Vapor Density: N/A Vapor Pressure:N/A Solubility in water: Insoluble (immiscible) Odor: Odorless Evaporation Rate: N/A Molecular Weight: 191.21 Molecular Formula: C9H9N3O2 SECTION 10 - STABILITY AND REACTIVITY Decomposes under alkaline conditions. Readily absorbed and retained on clothing and/or shoes.
SECTION 11 - TOXICOLOGY INFORMATION RTECS: Not Available Oral Rat or Mouse LD50: Dermal Rat or Mouse LD50: Rat or Mouse LC50: 6400 > 2000mg/kg N/A Carcinogenicity OSHA: NTP: No No
IARC: No
CARC: No
NIOSH: No
ACGIH: No
California Proposition 65 info: Not Listed SECTION 12 - ECOLOGICAL INFORMATION
Ecotoxicity: Not Available Environmental Fate: Not Available SECTION 13 - DISPOSAL CONSIDERATIONS Burn in a chemicals incinerator equipped with an afterburner and scrubber. SECTION 14 - TRANSPORTATION INFORMATION UN Number: UN3077 Class: 9 Packing Group: III Proper Shipping Name: Environmentally hazardous substance, solid, n.o.s.
SECTION 15 - REGULATORY INFORMATION European Labeling in Accordance with EC Directives Hazard Symbols: T N Risk Phrases: -R46: May cause heritable genetic damage. -R50/53: Very toxic to aquatic organisms and May cause long-term adverse effects in the aquatic environment. -R60: May impair fertility. -R61: May Cause harm to the unborn child.
Safety Phrases: -S36/37: Wear suitable protective clothing and gloves. -S45: In case of accident or if you feel unwell, seek medical advice immediately (show label where possible). -S53: Avoid exposure - obtain special instruction before use. -S60: This material and/or it's container must be disposed of as hazardous waste. -S61: Avoid release to the environment. Refer to special instructions/Safety data sheet.
SECTION 16 - OTHER INFORMATION The above information is believed to be correct on the date it was last revised and must not be considered all inclusive. The information has been obtained only by a search of available literature and is only a guide for handling the chemicals. OSHA regulations require that if other hazards become evident, an upgraded MSDS must be made available to the employee within three months. RESPONSIBILITY for updates lies with the employer and not with CHEM SERVICE, Inc. Persons not specifically and properly trained should not handle this chemical or its container. This product is furnished FOR LABORATORY USE ONLY! Our products may NOT BE USED as drugs, cosmetics, agricultural or pesticide products, food additives or as household chemicals.
This Material Safety Data Sheet (MSDS) is intended only for use with Chem Service, Inc. products and should not be relied on for use with materials from any other supplier even if the chemical name(s) on the product are identical! Whenever using an MSDS for a solution or mixture the user should refer to the MSDS for every component of the solution or mixture. Chem Service warrants that this MSDS is based upon the most current information available to Chem Service at the time it was last revised. THIS WARRANTY IS EXCLUSIVE, AND CHEM SERVICE, INC. MAKES NO OTHER WARRANTY, EXPRESSED OR IMPLIED, INCLUDING ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR ANY PARTICULAR PURPOSE. This MSDS is provided gratis and CHEM SERVICE, INC. SHALL NOT BE LIABLE FOR ANY INCIDENTAL, CONSEQUENTIAL OR CONTINGENT DAMAGES. Copyright 2000-2011 Chem Service, Inc. All rights reserved except that this MSDS may be printed for the use of a customer or prospective customer of Chem Service, Inc provided the entire MSDS is printed. The MSDS may not be placed in any database or otherwise stored or distributed in electronic or any other form. This product is furnished FOR LABORATORY USE ONLY!

Last Revision Date: 07/05/2011 SECTION 1 - CHEMICAL PRODUCT and COMPANY IDENTIFICATION Catalog Number: N-11405 Description: Carbofuran Other Names: 2.3-Dihydro-2.2-dimethyl-benzofuran-7-yl methylcarbamate Supplied by CHEM SERVICE, Inc. PO BOX 599, WEST CHESTER, PA 19381 (610)-6923026 EMERGENCY PHONE: 1-610-692-3026 SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS CAS: 1563-66-2 Description: Carbofuran EINECS No: 216-353-0 Hazard Symbols: T+ N Molecular Weight: 221.28 Molecular Formula: C12H15NO3 SECTION 3 - HAZARDS IDENTIFICATION Contact lenses should not be worn in the laboratory May be fatal if absorbed through the skin! May be fatal if inhaled! May be fatal if swallowed! Possible cholinesterase inhibitor-May cause seizures, nausea, vomiting, airway obstruction and/or increased mucous secretions in the lungs. Vapors and/or direct eye contact can cause severe eye burns. Target Organ - Blood. Target Organ - Central Nervous System.
SECTION 4 - FIRST AID MEASURES An antidote is a substance intended to counteract the effect of a poison. It should be administered only by a physician or trained emergency personnel. Medical advice can be obtained from a POISON CONTROL CENTER. In case of contact: Flush eyes continuously with water for 15-20 minutes. Flush skin with water for 15-20 minutes. If no burns have occurred-use soap and water to cleanse skin. If inhaled remove patient to fresh air. Administer oxygen if patient is having difficulty
breathing. If patient has stopped breathing administer artificial respirations. If patient is in cardiac arrest administer CPR. Continue life supporting measures until medical assistance has arrived. Remove and wash contaminated clothing. If patient is exhibiting signs of shock - Keep warm and quiet. Contact Poison Control Center immediately if necessary. Induce vomiting if swallowed. Do not administer liquids or induce vomiting to an unconscious or convulsing person. If patient is vomiting-watch closely to make sure airway does not become obstructed by vomit. Get medical attention if necessary. ANTIDOTE: Atropine sulfate. DO NOT USE 2-PAM (Pralidoxime chloride)!
SECTION 5 - FIRE AND EXPLOSION DATA Flash Point: Not Available Extinguishing Media: Carbon dioxide, dry chemical powder or spray. Lower Explosion Limit: N/A Auto Ignition: N/A
Upper Explosion Limit: N/A
NFPA Hazard Rating: Health Flammability 4 0
Reactivity 0
Special
0 - Least, 1 - Slight, 2 - Moderate, 3 - High, 4 - Severe SECTION 6 - ACCIDENTAL RELEASE MEASURES Spills or leaks: Evacuate area. Wear appropriate OSHA regulated equipment. Ventilate area. Absorb on vermiculite or similar material. Sweep up and place in an appropriate container. Hold for disposal. Wash contaminated surfaces to remove any residues. Remove contaminated clothing and wash before reuse. SECTION 7 - HANDLING AND STORAGE Handling: This chemical should be handled only in a hood. Eye shields should be worn. Use appropriate OSHA/MSHA approved safety equipment. Avoid contact with skin, eyes and clothing. Avoid ingestion and inhalation Wash thoroughly after handling. Storage: Store in a cool dry place. Store in a cool dry place. Store only with compatible chemicals. Store only with compatible
chemicals. Keep tightly closed.
SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION OSHA PEL (TWA): 0.1mg/m3 ACGIH TLV (TWA): 0.1mg/m3 ACGIH TLV (STEL): N/A
Personal Protective Equipment Eyes: Wear Safety Glasses. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin. Respirators: A respiratory protection program that meets OSHA's 29 CFR 1910.134 requirements must be followed whenever workplace conditions warrant a respirator's use. SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES Color: Colorless Phase: Crystalline solid Melting Point: 153-154 C Boiling Point: N/A C Specific Gravity: 1.180 Vapor Density: N/A Vapor Pressure:2E-5mm@33 C Solubility in water: Very slightly soluble Odor: Odorless Evaporation Rate: N/A Molecular Weight: 221.28 Molecular Formula: C12H15NO3 SECTION 10 - STABILITY AND REACTIVITY Decomposes under alkaline conditions. Hazardous combustion or decomposition products include: carbon monoxide, carbon dioxide, and nitrogen oxides.
SECTION 11 - TOXICOLOGY INFORMATION RTECS: FB9450000 Oral Rat or Mouse LD50: Dermal Rat or Mouse LD50: Rat or Mouse LC50: 5 > 120mg/kg 85mg/m3/4H Carcinogenicity OSHA: NTP: No No
IARC: No
CARC: No
NIOSH: No
ACGIH: No
California Proposition 65 info: Not Listed
SECTION 12 - ECOLOGICAL INFORMATION Ecotoxicity: Not Available Environmental Fate: Not Available SECTION 13 - DISPOSAL CONSIDERATIONS Burn in a chemicals incinerator equipped with an afterburner and scrubber. SECTION 14 - TRANSPORTATION INFORMATION UN Number: UN2811 Class: 6.1 Packing Group: I Proper Shipping Name: Toxic solid, organic, nos
SECTION 15 - REGULATORY INFORMATION European Labeling in Accordance with EC Directives Hazard Symbols: T+ N Risk Phrases: -R26/28: Very toxic by inhalation and if swallowed. -R50/53: Very toxic to aquatic organisms and May cause long-term adverse effects in the aquatic environment.
Safety Phrases: -S36/37: Wear suitable protective clothing and gloves. -S45: In case of accident or if you feel unwell, seek medical advice immediately (show label where possible). -S60: This material and/or it's container must be disposed of as hazardous waste. -S61: Avoid release to the environment. Refer to special instructions/Safety data sheet.
SECTION 16 - OTHER INFORMATION The above information is believed to be correct on the date it was last revised and must not be considered all inclusive. The information has been obtained only by a search of available literature and is only a guide for handling the chemicals. OSHA regulations require that if other hazards become evident, an upgraded MSDS must be made available to the employee within three months. RESPONSIBILITY for updates lies with the employer and not with CHEM SERVICE, Inc. Persons not specifically and properly trained should not handle this chemical or its container. This product is furnished FOR LABORATORY USE ONLY! Our products may NOT BE USED as drugs, cosmetics, agricultural or pesticide products, food additives or as household chemicals. This Material Safety Data Sheet (MSDS) is intended only for use with Chem Service, Inc.
products and should not be relied on for use with materials from any other supplier even if the chemical name(s) on the product are identical! Whenever using an MSDS for a solution or mixture the user should refer to the MSDS for every component of the solution or mixture. Chem Service warrants that this MSDS is based upon the most current information available to Chem Service at the time it was last revised. THIS WARRANTY IS EXCLUSIVE, AND CHEM SERVICE, INC. MAKES NO OTHER WARRANTY, EXPRESSED OR IMPLIED, INCLUDING ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR ANY PARTICULAR PURPOSE. This MSDS is provided gratis and CHEM SERVICE, INC. SHALL NOT BE LIABLE FOR ANY INCIDENTAL, CONSEQUENTIAL OR CONTINGENT DAMAGES. Copyright 2000-2011 Chem Service, Inc. All rights reserved except that this MSDS may be printed for the use of a customer or prospective customer of Chem Service, Inc provided the entire MSDS is printed. The MSDS may not be placed in any database or otherwise stored or distributed in electronic or any other form. This product is furnished FOR LABORATORY USE ONLY!

Last Revision Date: 07/07/2011
SECTION 1 - CHEMICAL PRODUCT and COMPANY IDENTIFICATION Catalog Number: Description: Other Names: N-11459 Chlorpyrifos O.O-Diethyl-O-[3.5.6-trichloro-2-pyridyl]phosphorothioate
Supplied by CHEM SERVICE, Inc. PO BOX 599, WEST CHESTER, PA 19381 (610)-692-3026 EMERGENCY PHONE: 1-610-692-3026 SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS CAS: Description: EINECS No: Hazard Symbols: T Molecular Weight: Molecular Formula: 2921-88-2 Chlorpyrifos 220-864-4 ;N 350.59 C9H11Cl3NO3PS
SECTION 3 - HAZARDS IDENTIFICATION Contact lenses should not be worn in the laboratory Can cause skin irritation. Can be irritating to mucous membranes. May be fatal if absorbed through the skin! May be fatal if inhaled! May be fatal if swallowed! Possible cholinesterase inhibitor-May cause seizures, nausea, vomiting, airway obstruction and/or increased mucous secretions in the lungs. SECTION 4 - FIRST AID MEASURES An antidote is a substance intended to counteract the effect of a poison. It should be administered only by a physician or trained emergency personnel. Medical advice can be obtained from a POISON CONTROL CENTER. In case of contact: Flush eyes continuously with water for 15-20 minutes. Flush skin with water for 15-20 minutes. If no burns have occurred-use soap and water to cleanse skin. If inhaled remove patient to fresh air. Administer oxygen if patient is having difficulty breathing. If patient has stopped breathing administer artificial respirations. If patient is in cardiac arrest administer CPR. Continue life supporting measures until medical assistance has arrived. Remove and wash contaminated clothing. If patient is exhibiting signs of shock - Keep warm and quiet. Contact Poison Control Center immediately if necessary. Induce vomiting if swallowed. Do not administer liquids or induce vomiting to an unconscious or convulsing person. If patient is vomiting-watch closely to make sure airway does not become obstructed by vomit. Get medical attention if necessary. ANTIDOTE: Atropine sulfate. SECTION 5 - FIRE AND EXPLOSION DATA Flash Point: 115 C Upper Explosion Limit: N/A Extinguishing Media: Carbon dioxide, dry chemical powder or spray. Lower Explosion Limit: N/A Auto Ignition: N/A
N-11459
Page 1 of 4

NFPA Hazard Rating: Health 2 Flammability 0 Reactivity 0 Special
NFPA Scale: 0 - Least, 1 - Slight, 2 - Moderate, 3 - High, 4 - Severe SECTION 6 - ACCIDENTAL RELEASE MEASURES Spills or leaks: Evacuate area. Wear appropriate OSHA regulated equipment. Ventilate area. Absorb on vermiculite or similar material. Sweep up and place in an appropriate container. Hold for disposal. Wash contaminated surfaces to remove any residues. Remove contaminated clothing and wash before reuse. SECTION 7 - HANDLING AND STORAGE Handling: This chemical should be handled only in a hood. Eye shields should be worn. Use appropriate OSHA/MSHA approved safety equipment. Avoid contact with skin, eyes and clothing. Avoid ingestion and inhalation Wash thoroughly after handling. Storage: Store in a cool dry place. Store only with compatible chemicals. Keep tightly closed. SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION OSHA PEL (TWA): 0.2mg/m3 ACGIH TLV (TWA): .2mg/m3 skin ACGIH TLV (STEL): N/A
Personal Protective Equipment Eyes: Wear Safety Glasses. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin. Respirators: A respiratory protection program that meets OSHA's 29 CFR 1910.134 requirements must be followed whenever workplace conditions warrant a respirator's use. SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES Color: Colorless Phase: Crystalline solid Melting Point: 42-43.5 C Boiling Point: N/A C Specific Gravity: N/A Vapor Density: N/A Vapor Pressure:1.87E-5mm@ C Solubility in water: Insoluble (immiscible) Odor: STENCH! Evaporation Rate: N/A Molecular Weight: 350.59 Molecular Formula: C9H11Cl3NO3PS SECTION 10 - STABILITY AND REACTIVITY Corrodes Brass. Corrodes copper and its alloys. Reacts with water and most reactive hydrogen compounds. Sensitive to heat.
N-11459
Page 2 of 4

Decomposed by moisture. Decomposes under alkaline conditions. Volatile. SECTION 11 - TOXICOLOGY INFORMATION RTECS: TF6300000 Oral Rat or Mouse LD50: 82 Carcinogenicity OSHA: NTP: No No Dermal Rat or Mouse LD50: > 202mg/kg Rat or Mouse LC50: >200mg/m3/4H
IARC: No
CARC: No
NIOSH: No
ACGIH: No
California Proposition 65 info: Not Listed SECTION 12 - ECOLOGICAL INFORMATION Ecotoxicity: Not Available Environmental Fate: Not Available SECTION 13 - DISPOSAL CONSIDERATIONS Disposal: Dispose in accordance with Federal, State and Local regulations. SECTION 14 - TRANSPORTATION INFORMATION UN Number: UN2811 Class: 6.1 Packing Group: III Proper Shipping Name: Toxic solid, organic, n.o.s.* (Chlorpyrifos)
SECTION 15 - REGULATORY INFORMATION European Labeling in Accordance with EC Directives Hazard Symbols: T;N Risk Phrases: -R24/25: Toxic in contact with skin and if swallowed. -R50/53: Very toxic to aquatic organisms and May cause long-term adverse effects in the aquatic environment. Safety Phrases: -S28: After contact with skin, wash immediately with plenty of .... (to be specified by the manufacturer). -S36/37: Wear suitable protective clothing and gloves. -S44/45: Error finding Risk information -S60: This material and/or it's container must be disposed of as hazardous waste. -S61: Avoid release to the environment. Refer to special instructions/Safety data sheet.
SECTION 16 - OTHER INFORMATION The above information is believed to be correct on the date it was last revised and must not be considered all inclusive. The information has been obtained only by a search of available literature and is only a guide for handling the chemicals. OSHA regulations require that if other hazards become evident, an upgraded MSDS must be made available to the employee within three months. RESPONSIBILITY for updates lies with the employer and not with CHEM SERVICE, Inc. Persons not specifically and properly trained should not handle this chemical or its container. This product is furnished FOR LABORATORY USE ONLY! Our products may NOT BE USED as drugs, cosmetics, agricultural or pesticide products, food additives or as household chemicals.
N-11459
Page 3 of 4

This Material Safety Data Sheet (MSDS) is intended only for use with Chem Service, Inc. products and should not be relied on for use with materials from any other supplier even if the chemical name(s) on the product are identical! Whenever using an MSDS for a solution or mixture the user should refer to the MSDS for every component of the solution or mixture. Chem Service warrants that this MSDS is based upon the most current information available to Chem Service at the time it was last revised. THIS WARRANTY IS EXCLUSIVE, AND CHEM SERVICE, INC. MAKES NO OTHER WARRANTY, EXPRESSED OR IMPLIED, INCLUDING ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR ANY PARTICULAR PURPOSE. This MSDS is provided gratis and CHEM SERVICE, INC. SHALL NOT BE LIABLE FOR ANY INCIDENTAL, CONSEQUENTIAL OR CONTINGENT DAMAGES. Copyright 2000-2011 Chem Service, Inc. All rights reserved except that this MSDS may be printed for the use of a customer or prospective customer of Chem Service, Inc provided the entire MSDS is printed. The MSDS may not be placed in any database or otherwise stored or distributed in electronic or any other form. This product is furnished FOR LABORATORY USE ONLY!
N-11459
Page 4 of 4
CHEM SERVICE INC.

Last Revision Date: 3/14/2013
SECTION 1 - CHEMICAL PRODUCT and COMPANY IDENTIFICATION Catalog Number: Description: Other Names: N-11827 Diuron 3-(3.4-Dichlorophenyl)-1.1-dimethylurea
Supplied by CHEM SERVICE, Inc. PO BOX 599, WEST CHESTER, PA 19381 (610)-692-3026 EMERGENCY PHONE: 1-610-692-3026 SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS CAS: Description: EINECS No: Hazard Symbols: Molecular Weight: Molecular Formula: 330-54-1 Diuron 206-354-4 Xn N, F 233.11 C9 H10 Cl2 N2 O
SECTION 3 - HAZARDS IDENTIFICATION Contact lenses should not be worn in the laboratory Can cause skin irritation. May be harmful if absorbed through the skin. May be harmful if inhaled. May be harmful if swallowed. Can be irritating to mucous membranes. Can cause blood disorders. Vapors can cause severe eye inflammation and swelling of adjoining tissues. Dust and/or vapors can cause irritation to respiratory tract. Target Organ - Liver and Kidneys. SECTION 4 - FIRST AID MEASURES An antidote is a substance intended to counteract the effect of a poison. It should be administered only by a physician or trained emergency personnel. Medical advice can be obtained from a POISON CONTROL CENTER. In case of contact: Flush eyes continuously with water for 15-20 minutes. Flush skin with water for 15-20 minutes. If no burns have occurred-use soap and water to cleanse skin. If inhaled remove patient to fresh air. Administer oxygen if patient is having difficulty breathing. If patient has stopped breathing administer artificial respirations. If patient is in cardiac arrest administer CPR. Continue life supporting measures until medical assistance has arrived. Remove and wash contaminated clothing. If patient is exhibiting signs of shock - Keep warm and quiet. Contact Poison Control Center immediately if necessary. Induce vomiting if swallowed. Do not administer liquids or induce vomiting to an unconscious or convulsing person. If patient is vomiting-watch closely to make sure airway does not become obstructed by vomit. Get medical attention if necessary. SECTION 5 - FIRE AND EXPLOSION DATA Flash Point: N/A Upper Explosion Limit: N/A NFPA Hazard Rating: Health 2 Extinguishing Media: Carbon dioxide, dry chemical powder or spray. Lower Explosion Limit: N/A Flammability 0 Reactivity 0 Auto Ignition: N/A Special
0 - Least, 1 - Slight, 2 - Moderate, 3 - High, 4 - Severe

Catalog Number: N-11827 Page 1 of 4
CHEM SERVICE INC.
SECTION 6 - ACCIDENTAL RELEASE MEASURES Spills or leaks: Evacuate area. Wear appropriate OSHA regulated equipment. Ventilate area. Absorb on vermiculite or similar material. Sweep up and place in an appropriate container. Hold for disposal. Wash contaminated surfaces to remove any residues. Remove contaminated clothing and wash before reuse. SECTION 7 - HANDLING AND STORAGE Handling: This chemical should be handled only in a hood. Eye shields should be worn. Use appropriate OSHA/MSHA approved safety equipment. Avoid contact with skin, eyes and clothing. Avoid ingestion and inhalation. Wash thoroughly after handling. Storage: Store in a cool dry place. Store only with compatible chemicals. Keep tightly closed. SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION OSHA PEL (TWA): 10 mg/m3 Personal Protective Equipment Eyes: Wear Safety Glasses. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin. Respirators: A respiratory protection program that meets OSHA's 29 CFR 1910.134 requirements must be followed whenever workplace conditions warrant a respirator's use. SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES Color: Phase: Melting Point: Boiling Point: Specific Gravity: Vapor Density: Vapor Pressure: Solubility in water: Odor: Evaporation Rate: Molecular Weight: Molecular Formula: Colorless Crystalline solid 158-159 C 180-190C 3 1.48 g/cm N/A N/A 0.049g/L @ 20 C N/A N/A 233.11 C9H10Cl2N2O ACGIH TLV (TWA): 10mg/m3 ACGIH TLV (STEL): N/A
SECTION 10 - STABILITY AND REACTIVITY Sensitive to heat. Decomposes under alkaline conditions. Decomposes under acidic conditions. Readily absorbed and retained on clothing and/or shoes.
Catalog Number: N-11827
Page 2 of 4
CHEM SERVICE INC.
SECTION 11 - TOXICOLOGY INFORMATION RTECS: YS8925000 Oral Rat or Mouse LD50: 1,017 mg/kg Carcinogenicity OSHA: No NTP: No Dermal Rat or Mouse LD50: > 5,000 mg/kg IARC: No CARC: No Rat or Mouse LC50: N/A NIOSH: No ACGIH: No
California Proposition 65 info: WARNING: This product contains a chemical known to the State of California to cause cancer through the Authoritative Bodies. SECTION 12 - ECOLOGICAL INFORMATION Ecotoxicity: Toxicity to fish LC50 - Oncorhynchus clarki - 0.53 mg/l - 96.0 h Toxicity to daphnia and other aquatic invertebrates mortality LOEC-Daphnia pulex (Water flea)-7.7mg/l-7d Toxicity to daphnia and other aquatic invertebrates EC50 - Daphnia magna (Water flea) - 1.4 mg/l - 48 h Toxicity to algae mortality NOEC - Chlamydomonas moewusii - 6.99 mg/l - 7 d Toxicity to algae mortality LOEC - Chlamydomonas moewusii - 9.32 mg/l - 7 d Environmental Fate: Bioconcentration factor (BCF): 290 SECTION 13 - DISPOSAL CONSIDERATIONS
Dispose in accordance with Federal, State and Local regulations.

SECTION 14 - TRANSPORTATION INFORMATION UN Number: UN3077 Class: 9 Packing Group: III Proper Shipping Name: Environmentally hazardous substance, solid, n.o.s. (Diuron (ISO))
SECTION 15 - REGULATORY INFORMATION European Labeling in Accordance with EC Directives Hazard Symbols: Xn N F Risk Phrases: -R40: Possible risk of irreversible effects. -R48/22: Harmful: danger of serious damage to health by prolonged exposure if swallowed. -R50/53: Very toxic to aquatic organisms and May cause long-term adverse effects in the aquatic environment. -R36: Irritating to the eyes -R20/21/22: Harmful by inhalation, in contact with skin and if swallowed -R11: Highly Flammable Safety Phrases: -S13: Keep away from food, drink and animal feeding stuffs. -S22: Do not breathe dust. -S23: Do not breathe gas/fumes/vapour/spray. -S36/37: Wear suitable protective clothing and gloves -S46: If swallowed seek medical advice immediately and show this container or label. -S60: This material and/or its container must be disposed of as hazardous waste. -S61: Avoid release to the environment. Refer to special instructions/Safety data sheet. -S2: Keep out of the reach of children -S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
Catalog Number: N-11827 Page 3 of 4
CHEM SERVICE INC.
Catalog Number: N-11827
Page 4 of 4
Chem Service Inc.

Last Revision Date: 09/01/2011 SECTION 1 - CHEMICAL PRODUCT and COMPANY IDENTIFICATION Catalog Number: N-12322 Description: Linuron Other Names: 3-(3.4-Dichlorophenyl)-1-methoxy-1-methylurea Supplied by CHEM SERVICE, Inc. PO BOX 599, WEST CHESTER, PA 19381 (610)-692-3026 EMERGENCY PHONE: 1-610-692-3026 SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS CAS: 330-55-2 Description: Linuron EINECS No: 206-356-5 Hazard Symbols: T, N Molecular Weight: 249.11 Molecular Formula: C9H10Cl2N2O2 SECTION 3 - HAZARDS IDENTIFICATION Contact lenses should not be worn in the laboratory Can cause eye irritation. Can cause skin irritation. Dust and/or vapors can cause irritation to respiratory tract. Can be irritating to mucous membranes. May be harmful if absorbed through the skin. May be harmful if inhaled. May be harmful if swallowed. Target Organ - Liver. Target Organ - Reproductive System. Possible teratogen-causes embryo-fetal damage.
SECTION 4 - FIRST AID MEASURES An antidote is a substance intended to counteract the effect of a poison. It should be administered only by a physician or trained emergency personnel. Medical advice can be obtained from a POISON CONTROL CENTER. In case of contact: Flush eyes continuously with water for 15-20 minutes. Flush skin with water for 15-20 minutes. If no burns have occurred-use soap and water to cleanse skin. If inhaled remove patient to fresh air. Administer oxygen if patient is having difficulty breathing. If patient has stopped breathing administer artificial respirations. If patient is in cardiac arrest administer CPR. Continue life supporting measures until medical assistance has arrived. Remove and wash contaminated clothing.
If patient is exhibiting signs of shock - Keep warm and quiet. Contact Poison Control Center immediately if necessary. Induce vomiting if swallowed. Do not administer liquids or induce vomiting to an unconscious or convulsing person. If patient is vomiting-watch closely to make sure airway does not become obstructed by vomit. Get medical attention if necessary.
SECTION 5 - FIRE AND EXPLOSION DATA Flash Point: Not Available Upper Explosion Limit: N/A NFPA Hazard Rating: Health 2 Extinguishing Media: Carbon dioxide, dry chemical powder or spray. Lower Explosion Limit: N/A Auto Ignition: N/A
Flammability 0
Reactivity 0
Special
0 - Least, 1 - Slight, 2 - Moderate, 3 - High, 4 - Severe SECTION 6 - ACCIDENTAL RELEASE MEASURES Spills or leaks: Evacuate area. Wear appropriate OSHA regulated equipment. Ventilate area. Absorb on vermiculite or similar material. Sweep up and place in an appropriate container. Hold for disposal. Wash contaminated surfaces to remove any residues. Remove contaminated clothing and wash before reuse. SECTION 7 - HANDLING AND STORAGE Handling: This chemical should be handled only in a hood. Eye shields should be worn. Use appropriate OSHA/MSHA approved safety equipment. Avoid contact with skin, eyes and clothing. Avoid ingestion and inhalation Wash thoroughly after handling. Storage: Store in a cool dry place. Store in a cool dry place. Store only with compatible chemicals. Store only with compatible chemicals. Keep tightly closed.
Personal Protective Equipment Eyes: Wear Safety Glasses. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin. Respirators: A respiratory protection program that meets OSHA's 29 CFR 1910.134 requirements must be followed whenever workplace conditions warrant a respirator's use.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES Color: Colorless Phase: Crystalline solid Melting Point: 93-94 C Boiling Point: N/A C Specific Gravity: N/A Vapor Density: N/A Vapor Pressure:0.051mPa@20 C Solubility in water: Very slightly soluble Odor: N/A Evaporation Rate: N/A Molecular Weight: 249.11 Molecular Formula: C9H10Cl2N2O2 SECTION 10 - STABILITY AND REACTIVITY Sensitive to light - dark color does not affect purity. Sensitive to heat. Decomposes under alkaline conditions. Decomposes under acidic conditions. Hazardous combustion or decomposition products include: toxic fumes of hydrogen chloride gas. Incompatible with bases.
SECTION 11 - TOXICOLOGY INFORMATION RTECS: YS9100000 Oral Rat or Mouse LD50: 1146 Carcinogenicity OSHA: No Dermal Rat or Mouse LD50: > >2500 mg/kg Rat or Mouse LC50: >6.15 mg/l air(4h)
NTP: No
IARC: No
CARC: No
NIOSH: No
ACGIH: No
California Proposition 65 info: Not Listed SECTION 12 - ECOLOGICAL INFORMATION Ecotoxicity: Not Available Environmental Fate: Not Available SECTION 13 - DISPOSAL CONSIDERATIONS Burn in a chemicals incinerator equipped with an afterburner and scrubber. SECTION 14 - TRANSPORTATION INFORMATION UN Number: UN3077 Class: 9 Packing Group: III Proper Shipping Name: Environmentally hazardous substance, solid, nos
SECTION 15 - REGULATORY INFORMATION
European Labeling in Accordance with EC Directives Hazard Symbols: T, N Risk Phrases: -R6: Explosive with or without contact with air. -R22: Harmful if swallowed. -R40: Possible risk of irreversible effects. -R48: Danger of serious damage to health by prolonged exposure. -R50: Very toxic to aquatic organisms. -R53: May cause long term adverse effects in the aquatic environment. -R61: May Cause harm to the unborn child.
Safety Phrases: -S36/37: Wear suitable protective clothing and gloves. -S45: In case of accident or if you feel unwell, seek medical advice immediately (show label where possible). -S53: Avoid exposure - obtain special instruction before use. -S60/61: Error finding Risk information
Chem Service Inc.

Date:04/25/2011 Last Revision Date: 12/10/2009 SECTION 1 - CHEMICAL PRODUCT and COMPANY IDENTIFICATION Catalog Number: N-13035 Description: Phorate Other Names: O.O-Diethyl-S-[(ethylthio)-methyl]phosphorodithioate Supplied by CHEM SERVICE, Inc. PO BOX 599, WEST CHESTER, PA 19381 (610)-692-3026 EMERGENCY PHONE: 1-610-692-3026 SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS CAS: 298-02-2 Description: Phorate EINECS No: 206-052-2 Hazard Symbols: T+ N Molecular Weight: 260.39 Molecular Formula: C7H17O2PS3 SECTION 3 - HAZARDS IDENTIFICATION Contact lenses should not be worn in the laboratory May be fatal if absorbed through the skin! May be fatal if inhaled! May be fatal if swallowed! May be harmful if inhaled. Can cause adverse reproductive effects. May be fatal or cause blindness if swallowed. Target Organ - Heart. Target Organ - Central Nervous System.
SECTION 4 - FIRST AID MEASURES An antidote is a substance intended to counteract the effect of a poison. It should be administered only by a physician or trained emergency personnel. Medical advice can be obtained from a POISON CONTROL CENTER. In case of contact: Flush eyes continuously with water for 15-20 minutes. Flush skin with water for 15-20 minutes. If no burns have occurred-use soap and water to cleanse skin. If inhaled remove patient to fresh air. Administer oxygen if patient is having difficulty breathing. If patient has stopped breathing administer artificial respirations. If patient is in cardiac arrest administer CPR. Continue life supporting measures until medical assistance has arrived. Remove and wash contaminated clothing. If patient is exhibiting signs of shock - Keep warm and quiet. Contact Poison Control Center immediately if necessary.
Induce vomiting if swallowed. Do not administer liquids or induce vomiting to an unconscious or convulsing person. If patient is vomiting-watch closely to make sure airway does not become obstructed by vomit. Get medical attention if necessary. ANTIDOTE: Atropine sulfate.
SECTION 5 - FIRE AND EXPLOSION DATA Flash Point: Not Available Upper Explosion Limit: N/A NFPA Hazard Rating: Health 4 Extinguishing Media: Dry Chemical, Carbon Dioxide, Water spray or alcohol-resistant Foam. Lower Explosion Limit: N/A Auto Ignition: N/A
Flammability 0
Reactivity 0
Special
0 - Least, 1 - Slight, 2 - Moderate, 3 - High, 4 - Severe SECTION 6 - ACCIDENTAL RELEASE MEASURES Spills or leaks: Evacuate area. Wear appropriate OSHA regulated equipment. Ventilate area. Absorb on vermiculite or similar material. Sweep up and place in an appropriate container. Hold for disposal. Wash contaminated surfaces to remove any residues. Remove contaminated clothing and wash before reuse. SECTION 7 - HANDLING AND STORAGE Handling: This chemical should be handled only in a hood. Eye shields should be worn. Use appropriate OSHA/MSHA approved safety equipment. Avoid contact with skin, eyes and clothing. Avoid ingestion and inhalation Wash thoroughly after handling. Storage: STORE UNDER NITROGEN AND REFRIGERATION. Store in a cool dry place. Store only with compatible chemicals. Store only with compatible chemicals. Keep tightly closed.
SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION OSHA PEL (TWA): 0.05mg/m3 ACGIH TLV (TWA): 0.05mg/m3 skin ACGIH TLV (STEL): N/A
Personal Protective Equipment Eyes: Wear Safety Glasses. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin. Respirators: A respiratory protection program that meets OSHA's 29 CFR 1910.134 requirements must be followed whenever workplace conditions warrant a respirator's use.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES Color: Colorless Phase: Liquid Melting Point: <-15 C Boiling Point: 308 C Specific Gravity: 1.167 Vapor Density: N/A Vapor Pressure:8.0E-4mm @20 C Solubility in water: Insoluble (immiscible) Odor: N/A Evaporation Rate: N/A Molecular Weight: 260.39 Molecular Formula: C7H17O2PS3 SECTION 10 - STABILITY AND REACTIVITY Sensitive to heat. Decomposes under alkaline conditions. Decomposes under acidic conditions. Hazardous combustion or decomposition products include: carbon monoxide, carbon dioxide and sulfur dioxide. Incompatible with strong oxidizing agents.
SECTION 11 - TOXICOLOGY INFORMATION RTECS: TD9450000 Oral Rat or Mouse LD50: 1 Carcinogenicity OSHA: No Dermal Rat or Mouse LD50: > 2500ug/kg Rat or Mouse LC50: 11mg/mg/m3/1h
NTP: No
IARC: No
CARC: No
NIOSH: No
ACGIH: No
California Proposition 65 info: Not Listed SECTION 12 - ECOLOGICAL INFORMATION Ecotoxicity: Not Available Environmental Fate: Not Available SECTION 13 - DISPOSAL CONSIDERATIONS Burn in a chemicals incinerator equipped with an afterburner and scrubber. SECTION 14 - TRANSPORTATION INFORMATION UN Number: UN3278 Class: 6.1 Packing Group: I Proper Shipping Name: Organophosphorus compound, liquid, toxic, nos *
SECTION 15 - REGULATORY INFORMATION
European Labeling in Accordance with EC Directives Hazard Symbols: T+ N Risk Phrases: -R27/28: Very toxic in contact with skin and if swallowed. -R50/53: Very toxic to aquatic organisms and May cause long-term adverse effects in the aquatic environment.
Safety Phrases: -S28: After contact with skin, wash immediately with plenty of .... (to be specified by the manufacturer). -S36/37: Wear suitable protective clothing and gloves. -S45: In case of accident or if you feel unwell, seek medical advice immediately (show label where possible). -S60: This material and/or it's container must be disposed of as hazardous waste. -S61: Avoid release to the environment. Refer to special instructions/Safety data sheet.

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